CN109825386A - A kind of neat soap and environment-friendly soap containing Organic grape sodium saccharate - Google Patents
A kind of neat soap and environment-friendly soap containing Organic grape sodium saccharate Download PDFInfo
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- CN109825386A CN109825386A CN201910087476.6A CN201910087476A CN109825386A CN 109825386 A CN109825386 A CN 109825386A CN 201910087476 A CN201910087476 A CN 201910087476A CN 109825386 A CN109825386 A CN 109825386A
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Abstract
The present invention relates to daily use chemicals perfumed soap technical fields, and in particular to a kind of neat soap and environment-friendly soap containing Organic grape sodium saccharate.The neat soap includes the raw material of following weight percent: 60-80 parts of fatty acid mixed, 27-38 parts of liquid alkaline, 2-10 parts of refined glycerine, 0.2-1.5 parts of metal-chelator, 0.5-1.0 parts of purified salt and 4.5-6.5 parts of deionized water；The metal-chelator is organic gluconic acid sodium salt, or is Organic grape sodium saccharate, the mixture of iminodisuccinic acid and two poly (sodium aspartate)s.Neat soap of the invention is using Organic grape acid sodium as Primary chelating agent, it can be remained to the heavy metal ion chelating in water and in dirt under the conditions of higher ph, and metal ion is avoided to cause the oxidation of neat soap, rotten and peculiar smell, and Organic grape acid sodium has the characteristics that the environmentally friendly of easily biological-degradable, the environment friendly of neat soap is improved, and neat soap has the characteristics that clean effect is good, does not stimulate human skin, is highly-safe.
Description
Technical field
The present invention relates to daily use chemicals perfumed soap technical fields, and in particular to a kind of neat soap containing Organic grape sodium saccharate and environmental protection
Soap.
Background technique
At present in the neat soap and daily chemical products laundry soap and perfumed soap production in basic oiling industry, perfumed soap grain or perfumed soap
Usually have and cause peculiar smell or discoloration because trace metal ion promotes unsaturated fat acid oxidase, is usually added into process of production
Metal-chelator avoids leading to soap because of metal ion for chelating the trace heavy metal ion that may be present in neat soap or soap
Class unsaturated acids occurs oxidation and causes peculiar smell and discoloration, can extend the shelf-life of neat soap and perfumed soap, and can play softened water
The effect of matter.
Mostly use ammonia carboxylic acids chelating agent greatly during producing neat soap at present, ammonia carboxylic acids chelating agent is a kind of existing amino
There is the organic complexing agent of carboxyl again.The ammonia carboxylic complexant studied at present has tens kinds, wherein most widely used is ethylenediamine tetraacetic
Four sodium of acetic acid and its disodium salt, ethylenediaminetetraacetic acid -4Na and EDTA-2Na, under conditions of neat soap alkaline (PH10-11), for weight
Metal iron ion (trivalent) is easy to generate iron hydroxide, and it is sequestering to influence its without being chelated for Precipitation, so in alkalinity
Under the conditions of, for the chelating of heavy metal iron ion, it can not meet the requirement of chelating using propylhomoserin quasi-chelate compound.Other common ammonia
Acids chelating agent mainly there are also diethylene triamine pentacetic acid (DTPA) (DTPA), Hedta (HEDTA), etc. it is also useful
In conventional neat soap and perfumed soap.
But after this quasi-chelate compound and heavy metal ion chelating, the chelate of production cannot be degraded by biochemical treatment,
It always exists in soil, with the accumulation of soap product being widely used with the time, is certain to generate soil bigger dirt
Dye generates destruction to entire ecological environment.
Summary of the invention
In order to overcome shortcoming and defect existing in the prior art, the purpose of the present invention is to provide one kind to contain organic Portugal
The neat soap of grape sodium saccharate, the neat soap substitute currently used ammonia carboxylic using Organic grape acid sodium as primary metal ion chelating agent
Quasi-chelate compound has very strong metal-chelating, especially under alkaline condition, to metal ion (especially iron ion), tool
There is higher chelating ability, inside metal ion inclusion to chelating agent, becomes compound stable, that molecular weight is bigger, from
And metal ion is prevented to work, avoid heavy metal ion from causing the oxidation of neat soap, and then lead to rotten and peculiar smell, and organic Portugal
Grape acid sodium and its chelate have the characteristics that environmental protection and easily biological-degradable, the environment friendly of neat soap are improved, since it belongs to
Natural chelating agent, having does not stimulate human skin, highly-safe characteristic.
Another object of the present invention is to provide a kind of environmental protection as made from the above-mentioned neat soap containing Organic grape sodium saccharate
Soap, the mild safety of the environment-friendly soap raw material, by using plant extracts and moisturizing factor, can improve environment-friendly soap antibacterial anti-inflammatory,
The performance of moisturizing and nourishing, effective protection skin improve the permeability of skin, increase skin elasticity, bright color, and pass through compound
Ferment, improves the dirt-removing power and moisture-retaining capacity of environment-friendly soap, and does not damage skin, and improves the soft and moist of environment-friendly soap by emollients
Property, it cleans and does not generate tight feeling using rear skin, recycle the bubble power and foam stability for improving environment-friendly soap, prevent dirt grain
Sub- reprecipitation, and inhibit perfumed soap to the stimulation of skin, improve the cleaning dirt-removing power of environment-friendly soap.
The purpose of the invention is achieved by the following technical solution: a kind of neat soap containing Organic grape sodium saccharate, the neat soap
Raw material including following weight percent:
The metal-chelator is organic gluconic acid sodium salt, or is Organic grape sodium saccharate, iminodisuccinic acid and two
The mixture of poly (sodium aspartate).
The present invention by using Organic grape acid sodium as primary metal ion chelating agent, can be by the gold in water and in dirt
Belong to ion (such as calcium ion, magnesium ion and iron ion) to be chelated, forms stable chelate, prevent the precipitating of dirt, and
It avoids metal ion from causing the oxidation of neat soap, and then causes rotten or, and environmental protection of the Organic grape acid sodium with easily biological-degradable
Feature effectively increases the environment friendly of neat soap compared with traditional ammonia carboxylic acids chelating agent, keeps the clean effect of neat soap good,
And human skin is not stimulated, it is highly-safe.
Preferably, the mixed proportion of the Organic grape sodium saccharate, iminodisuccinic acid and two poly (sodium aspartate)s is
2-4:1:1.5-2.5。
In addition, by the way that Organic grape sodium saccharate, iminodisuccinic acid and two poly (sodium aspartate) threes are mixed conduct
Metal-chelator uses, and strict control mixed proportion, can significantly improve the metal-chelating effect of neat soap, and easily biological-degradable,
Effectively improve the dirt-removing power and environmental-protecting performance of neat soap；The iminodisuccinic acid non-toxic phosphorus-free wherein used is nuisanceless, Yi Sheng
Object degradation, anion can form coordination geometry with metal cation, to calcium, magnesium, zinc and other transition metal ions
There is very strong chelating ability, and other common chelating agents energy such as sequestering power to heavy metal ion such as copper, iron, manganese, nickel and EDTA
Power is suitable, and Organic grape sodium saccharate, two poly (sodium aspartate)s match can significantly improve chelating ability；And the dimerization asparagus fern used
Propylhomoserin sodium is water-soluble polymer, has without phosphorus, nontoxic, nuisanceless and fully biodegradable characteristic, has to ion extremely strong
Sequestering power, there are inhibition and scale inhibition double effects, have to the scaling salts class such as calcium carbonate, calcium sulfate, barium sulfate, calcium phosphate
Good scale inhibition effect can effectively improve neat soap chelated metal ions, dirt-removing power.
Preferably, every part of fatty acid mixed includes 4-5 parts of lauric acid, 2-4 parts of palmitinic acids, 2-4 parts of oleic acid and 0.2-
0.5 part of linoleic acid；The mass fraction of the liquid alkaline is 32-40%.
For the present invention by using the fatty acid mixed of mentioned kind, the highly effective foaming characteristic for improving neat soap of energy and decontamination are clear
Clean ability makes foam very fine and smooth, and mild pro-skin, does not generate stimulation to skin, improves mild protection of the neat soap to skin
Property, it is highly-safe；Wherein, for the lauric acid used for medium-chain fatty acid, the foaming characteristic of neat soap is can be improved in it, is allowed from its moment
Bubble, while foam is very fine and smooth, feeling for skin is soft, and mildly non-stimulated to skin, lauric acid and palmitinic acid are saturated fat
Fat acid, there is extraordinary oxidation stability to be easy to save, improve environmental protection so that the environment-friendly soap being processed into is not oxidizable
The service life of soap；And use oleic acid to skin as mild as a dove, and have preferable cleaning force, but excessive oleic acid be easy drop
The oxidation stability of low neat soap, thus controlling its dosage is 2-4 parts；There are two double bonds for the linoleic acid of use, all to skin
Abnormal mild and quality is salubrious, improves the salubrious sense of use of environment-friendly soap, and does not damage skin, but excessive linoleic acid is easy
The oxidation stability for reducing neat soap is easy to keep environment-friendly soap obtained weak, thus its dosage of strict control is 0.2-0.5 parts.
Preferably, the neat soap containing Organic grape sodium saccharate is somebody's turn to do to be made by following steps:
Step (1): according to parts by weight by refined glycerine and purified salt be added to account for ion water inventory 25-35% go from
It in sub- water, is stirred, obtains A phase；
Step (2): metal-chelator being added into remaining deionized water according to parts by weight, is stirred to all molten
Solution, obtains B phase；
Step (3): according to parts by weight that A phase made from fatty acid mixed, liquid alkaline, step (1) and step (2) is obtained
B phase squeezes into continuous saponification process system with metering pump respectively, is pre-mixed in a mixer, and the saponification of 55-65% is completed, temperature
Degree is 80-90 DEG C；
Step (4): continuous saponification process tank will be transported to from the partly-hydrolysed soap lye that premixer discharges in step (3)
In, continuous saponification process reaction is carried out, saponification temperature is controlled at 105-125 DEG C, and soap base is made；
Step (5): carrying out vacuum spray drying for soap base made from step (4), obtains the soap that moisture content is 10-13%
Then soap base is refined, squeezes shaping, pelletizing molding, the neat soap containing Organic grape sodium saccharate is made by base.
In the step (5), the inlet temperature of vacuum spray drying is 105-125 DEG C, and vacuum degree is -880mbar, neat soap
Refining out grain temperature is 40-50 DEG C.
The present invention prepares neat soap through the above steps, easy to operate, easy to control, and high production efficiency, production cost is low, can
For being mass produced, by strict control processing step and technological parameter, neat soap chelating with higher obtained can be made to live
Property, and good moldability, do not occur weak phenomenon after use miscible with water, not oxidizable turn yellow goes bad, and improves the stabilization of neat soap
Property；It by the way that refined glycerine and metal-chelator to be dissolved separately in deionized water, then is added into premix, improves
Refined glycerine, metal-chelator, fatty acid mixed and liquid alkaline mixture homogeneity, improve point of the metal-chelator in neat soap
Property is dissipated, it is made to give full play to the clean performance of chelating in cleaning process；And by the way that purified salt is added, glycerol, excessive alkali can be made
Liquid, moisture are separated with soap base, improve the purity and mouldability of soap base.
Another object of the present invention is achieved through the following technical solutions: a kind of by the above-mentioned soap containing Organic grape sodium saccharate
Environment-friendly soap made from grain, which includes the raw material of following parts by weight:
The above-mentioned raw materials that environment-friendly soap of the invention uses are mildly safe, have preferable decontamination ability, and mild parent
Skin, it is non-stimulated to skin, the moisture retention and permeability of skin can be improved for facial soap or laundry soap；Wherein, by using
Plant extracts and moisturizing factor, can improve the antibacterial anti-inflammatory of environment-friendly soap, the performance of moisturizing and nourishing, and effective protection skin improves
The permeability of skin increases skin elasticity, bright color, and passes through composite enzyme, improves the dirt-removing power and moisturizing of environment-friendly soap
Ability, and skin is not damaged, and the soft and moist property of environment-friendly soap is improved by emollients, cleaning does not generate tight feeling using rear skin,
The bubble power and foam stability for improving environment-friendly soap are recycled, prevents dirt particles reprecipitation, and inhibit perfumed soap to the thorn of skin
Swash, improves the cleaning dirt-removing power of environment-friendly soap；The surfactant of use can improve emulsifiability and the cleaning decontamination of environment-friendly soap
Ability.Metal-chelator and water body in neat soap, the metal ion-chelant in dirt, and metal ion, compound is removed in neat soap
After ferment removes surface grease dirt, be conducive to the Cutaneous permeation absorbent properties of subsequent plant extracts and moisturizing factor, improve
Plant extracts and moisturizing factor act on antibacterial anti-inflammatory, the moisturizing and nourishing of skin；And the natural essence used can improve environmental protection
The faint scent of soap, spirit of releiving, and improve the anti-inflammatory of environment-friendly soap, moisturizing, anti-acne, the skin-care effects such as moisten.
The environment-friendly soap of the invention metal-chelator in neat soap carries out metal-chelating, removal metal ion to water body and dirt
Afterwards, the mild decontamination of environment-friendly soap is improved in conjunction with composite enzyme, while clean environment can promote plant extracts, protect
The wet factor and emollients play the effect of nourishes rough skin, realize the cleaning of environment-friendly soap, moisten double action.
Preferably, every part of composite enzyme is by Pepsin, Superoxide dismutase element, lipase, sheath
Phosphatide ferment is with the composition that weight ratio is that 2-3:1:1-2:0.5-1.0 is formed；Every part of plant extracts includes 0.3-0.8
Part chlorella extract, 0.4-0.8 parts of Flos Chrysanthemi Indici extracts and 0.2-0.6 parts of sea grape extracts.
For the present invention by using the composite enzyme of mentioned kind, pro-skin is mild, and cleaning dirt-removing power is good, for facial soap or
Laundry soap does not damage skin；Wherein, the Pepsin of use can hydrolyze keratoprotein, leniently targeting removal skin angle
Matter, tender skin；The Superoxide dismutase element of use can improve the anti-oxidation efficacy of skin, scavenging activated oxygen；It uses
Lipolysis ferment can effectively clear the solidification sebum of skin surface, remove the rubbish fouls such as acne, blackhead；The sphingomyelins ferment of use
Element can improve the balance performance of keeping humidity of environment-friendly soap, infiltrate into skin deep layer, and deep water supplement is moistened, and moisturizing factor is combined to improve ring
There is the phenomenon that water shortage shriveling after avoiding cleaning in the moisture-keeping function for protecting soap；More persons combine complex role composite enzyme, can make to be made
Environment-friendly soap can disintegrate pore grease and be discharged, hydrolysis keratoprotein, removal cutin, scavenging activated oxygen, decompose deep skin
Melanin, and skin permeation deep layer supplements moisture content in time, improves the spatter property, moisture retention and inoxidizability of environment-friendly soap.
And by using the plant extracts of mentioned kind, removal metal ion and composite enzyme removal can be chelated in neat soap
It after surface grease dirt, effectively infiltrates into skin and works, antibacterial anti-inflammatory, moisturizing and nourishing are served to skin；Wherein, it uses
Chlorella extract rich in the nutriments such as protein, lipid, carbohydrate, minerals, vitamin, water, and contain CGF
Active factors, can improve environment-friendly soap to the moisturizing of skin, nourishing, reparative regeneration, whitening spot-removing, resisting age of skin function；It adopts
Flos Chrysanthemi Indici extract can effectively improve the antibacterial and anti-inflammation functions of environment-friendly soap；The sea grape extract of use can make ring obtained
The synthesis aquaporin of human skin can be stimulated by protecting soap, promote the circulation of hydrone, improve the replenishing water and preserving moisture effect of environment-friendly soap.
Preferably, every part of moisturizing factor is acetylation Sodium Hyaluronate, dexpanthenol, maltitol, hydrolysis Portugal
At least one of sugared aminoglycan and PCA acid sodium；Every part of emollients are by 0.2-0.5 parts of glyceryl oleates, 3-5 parts of Portugals
Calciofon, 1-1.5 portion levulic acid and 2-4 parts of octyl dodecanol lauroyl glutamate ester mixing compositions.
The present invention can mend in time by using the moisturizing factor of mentioned kind while environment-friendly soap cleans skin comprehensively
Water-filling part avoids the phenomenon that water shortage shriveling occur clean comprehensively after, improves cleaning, the moisturizing effect of environment-friendly soap；Wherein, use
Acetylation Sodium Hyaluronate is hyaluronic acid-derivative, easy to use due to its amphipathic characteristic, and the soft cuticula of energy, and is protected
Outlet capacity is high (2 times or more higher than convention transparent matter acid), mildly non-stimulated to skin, and is kept securely in the table of skin
Face makes moisturizing water lock effect of the environment-friendly soap for facial soap when to prevent water from evaporating from skin, avoids the occurrence of tight after cleaning
Phenomenon；The effect of dexpanthenol penetration of use is good, mild non-stimulated, can reach deep moisturizing through skin surface, energy
The division growth for stimulating cell, promotes the hyperplasia of elastic fibers, and can assist repairing skin tissue, assists anti-inflammatory and healing impaired
Skin Cell improves the moisturizing, reparation, the effect of skin care of environment-friendly soap；Maltitol performance is mild, and hygroscopicity is high, can inhale
The moisture in air is received, moisture and cell combination are made, environment-friendly soap is improved and the moisturizing water lock of skin is acted on；The hydrolysis of use
Mildly safety, skin-friendly height have excellent water lock effect and osmosis, can increase environment-friendly soap and skin glycosaminoglycan
Hydration levels, improve skin elasticity and the degree of packing, improve the moisturizing of environment-friendly soap, water lock, improve skin elasticity, is anti-oxidant, removing
The effect for anti-aging of wrinkling；The PCA acid sodium of use belongs to natural moisturizing factor, and mild safety can absorb the moisture in air, enable
Make moisture and cell combination, the moisture of keratoderma can be effectively improved, promote the metabolism of cell, if the use of PCA acid sodium
Measure it is very few, then be easy so that PCA acid sodium back suction receive skin in moisture, lead to skin water shortage, therefore strict control moisturizing factor
Dosage be 3-7 parts.
More preferably, every part of moisturizing factor is by acetylation Sodium Hyaluronate, dexpanthenol and hydrolysis glucose
Aminoglycan is with the mixture that weight ratio is that 2-3:1.5-2.5:1 is formed.
And the present invention can improve the soft and moist texture of environment-friendly soap by using the emollients of mentioned kind, and can rise to skin
To soft and moist effect, skin after cleaning is avoided to generate tight phenomenon；Wherein, glyceryl oleate belongs to unsaturated refined glycerine
Ester, can effectively improve the emulsibility and certain viscosity of environment-friendly soap, and can promote dissolving each other between raw material；And calcium gluconate is made
With preferable moisture-keeping function, conditioning cell water and oil balance in Skin Cell can be infiltrated into, skin water humidity and soft and moist degree are increased；
And levulic acid is mildly safe, the pH value and lubricity of skin can be adjusted to a certain extent, so that skin is in water and oil balance, acid
The health status of soda balance.
Preferably, the surfactant is to be with weight ratio by dodecyl sodium sulfate and coconut oil sodium isethionate
The mixture of 2-3:1 composition；The natural essence is tea tree ethereal oil, thyme essential oil, Lavender, sandalwood essential oil, rat-tail
At least one of careless essential oil, eucalyptus quintessence oil and clove oil.
The present invention can improve the amphipathic property of environment-friendly soap by using the surfactant of mentioned kind, promote dirt
Removing, improve the dirt-removing power and dispersibility of environment-friendly soap；Wherein, the coconut oil sodium isethionate of use has excellent parent
Skin mildness, and high bubble property is good, is easy to bubble, foaming abundancy is fine and smooth, can promote the foaming characteristic and soil release performance of environment-friendly soap, with 12
Sodium alkyl sulfonate is used in compounding, and can improve the cleaning decontamination of environment-friendly soap, mild to lubricate, and keeps skin after cleaning smooth moist.
And by using the natural essence of mentioned kind, it can assign environment-friendly soap pure and fresh fragrance, and environment-friendly soap can be improved
The skin-care effects such as anti-inflammatory, moisturizing, anti-acne, moist；The fruity essence such as flavoring apple essence, strawberry essence, cherry essence, lemon
Essence etc..
Preferably, which is made by following steps:
Step A: refined glycerine and the heat preservation factor are added in neat soap according to parts by weight, stirred, control is mixed
The temperature for closing material is 34-36 DEG C, and component A is made；
Surfactant: being added into component A made from step A according to parts by weight, be uniformly mixed by step B, then
It is separately added into plant extracts, emollients and natural essence, mixing time 3-5min is uniformly mixed, and component B is made；
Step C: being cooled to 30-36 DEG C for component B made from step B, and composite enzyme is then added, and stirs 1-3min, then
Successively by purification, grinding, vacuum plodding, environment-friendly soap is made in cooling printing.
The present invention prepares environment-friendly soap through the above steps, easy to operate, easy to control, and high production efficiency, production cost is low,
It can be used for being mass produced, by strict control processing step and technological parameter, environment-friendly soap stock dispersion obtained can be made uniform,
And there is preferable mouldability, do not occur weak phenomenon after use miscible with water, not oxidizable rotten, the stability height that turns yellow；It is logical
It crosses and stirs neat soap and refined glycerine heating, dissolubility of the neat soap in refined glycerine can be promoted, then add surfactant
Enter mixing, improves each stock dispersion of material system, add plant extracts, emollients and natural essence, it is living on surface
Property agent and homogeneous stirring under the action of, it is uniform with the material dispersions such as neat soap, refined glycerine, improve the dispersibility of material；Finally exist
Composite enzyme is added at 30-36 DEG C, ensure that the activity of ferment, ferment is avoided to inactivate at high temperature, and sufficiently activates environment-friendly soap
Ferment cleaning action, improve the mild decontamination of environment-friendly soap；Without being added in homogeneous whipping step, while strict control
Mixing time is avoided that and generates foam in homogeneous stirring or excessive agitation during, is unfavorable for subsequent carrying out the processing such as refining
Molding procedure improves the stability of environment-friendly soap.
The beneficial effects of the present invention are: neat soap of the invention, can be by water using Organic grape acid sodium as Primary chelating agent
It neutralizes inside the metal ion inclusion to chelating agent in dirt, forms stable chelate, prevent the precipitating of dirt, and avoid gold
Belong to the oxidation deterioration that ion causes soap, and Organic grape acid sodium has the characteristics that the environmentally friendly of easily biological-degradable, with traditional ammonia carboxylic class
Chelating agent is compared, and the environment friendly of neat soap is effectively increased, and keeps the clean effect of neat soap good, and do not stimulate human skin, peace
Quan Xinggao.
Present invention environment-friendly soap as made from the above-mentioned neat soap containing Organic grape sodium saccharate, raw material is mildly safe, by adopting
With plant extracts and moisturizing factor, the antibacterial anti-inflammatory of environment-friendly soap, the performance of moisturizing and nourishing can be improved, effective protection skin mentions
The permeability of high skin increases skin elasticity, bright color, and passes through composite enzyme, improves dirt-removing power and the guarantor of environment-friendly soap
Wet ability, and skin is not damaged, and the soft and moist property of environment-friendly soap is improved by emollients, cleaning is not generated tight using rear skin
Sense recycles the bubble power and foam stability for improving environment-friendly soap, prevents dirt particles reprecipitation, and inhibit environment-friendly soap to skin
Stimulation, improve the cleaning dirt-removing power of environment-friendly soap.
Specific embodiment
For the ease of the understanding of those skilled in the art, below with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying refers to not is limitation of the invention.
Embodiment 1
A kind of neat soap containing Organic grape sodium saccharate, the neat soap include the raw material of following weight percent:
The metal-chelator is organic gluconic acid sodium salt.
Every part of fatty acid mixed includes 4 parts of lauric acid, 2 parts of palmitinic acids, 2 parts of oleic acid and 0.2 part of linoleic acid；The liquid
The mass fraction of alkali is 32%.
The neat soap for containing Organic grape sodium saccharate is made by following steps:
Step (1): refined glycerine and purified salt are added to the deionization for accounting for ion water inventory 25% according to parts by weight
It in water, is stirred, obtains A phase；
Step (2): metal-chelator being added into remaining deionized water according to parts by weight, is stirred to all molten
Solution, obtains B phase；
Step (3): according to parts by weight that A phase made from fatty acid mixed, liquid alkaline, step (1) and step (2) is obtained
B phase squeezes into continuous saponification process system with metering pump respectively, is pre-mixed in a mixer, and 55% saponification, temperature are completed
It is 80 DEG C；
Step (4): continuous saponification process tank will be transported to from the partly-hydrolysed soap lye that premixer discharges in step (3)
In, continuous saponification process reaction is carried out, saponification temperature is controlled at 105 DEG C, and soap base is made；
Step (5): carrying out vacuum spray drying for soap base made from step (4), obtains the soap base that moisture content is 10%,
Then soap base refined, squeeze shaping, pelletizing molding, the neat soap containing Organic grape sodium saccharate is made.
In the step (5), the inlet temperature of vacuum spray drying is 105 DEG C, and vacuum degree is -900mbar, neat soap purification
Grain temperature is 40 DEG C out.
A kind of environment-friendly soap as made from the above-mentioned neat soap containing Organic grape sodium saccharate, the environment-friendly soap include following parts by weight
Raw material:
Every part of composite enzyme is by Pepsin, Superoxide dismutase element, lipase, sphingomyelins ferment
It is the composition that 2:1:1:0.5 is formed with weight ratio；Every part of plant extracts includes 0.3 part of chlorella extract, 0.4 part
Flos Chrysanthemi Indici extract and 0.2 part of sea grape extract.
Every part of moisturizing factor is acetylation Sodium Hyaluronate and/or dexpanthenol；Every part of emollients be by
0.2 part of glyceryl oleate, 3 parts of calcium gluconates, 1 portion of levulic acid and 2 parts of octyl dodecanol lauroyl glutamate ester mixing compositions.
The surfactant is made of dodecyl sodium sulfate and coconut oil sodium isethionate with weight ratio for 2:1
Mixture；The natural essence is Fruity type essence.
The environment-friendly soap is made by following steps:
Step A: refined glycerine and the heat preservation factor are added in neat soap according to parts by weight, stirred, control is mixed
The temperature for closing material is 34 DEG C, and component A is made；
Surfactant: being added into component A made from step A according to parts by weight, be uniformly mixed by step B, then
It is separately added into plant extracts, emollients and natural essence, mixing time 3min is uniformly mixed, and component B is made；
Step C: being cooled to 30 DEG C for component B made from step B, and composite enzyme is then added, and stirs 3min, then successively pass through
Purification, grinding, vacuum plodding are crossed, environment-friendly soap is made in cooling printing.
Embodiment 2
A kind of neat soap containing Organic grape sodium saccharate, the neat soap include the raw material of following weight percent:
The metal-chelator is by Organic grape sodium saccharate, iminodisuccinic acid and two poly (sodium aspartate)s with weight
Than the mixture formed for 2:1:1.5.
Every part of fatty acid mixed includes 4.2 parts of lauric acid, 2.5 parts of palmitinic acids, 2.5 parts of oleic acid and 0.3 part of linoleic acid；
The mass fraction of the liquid alkaline is 34%.
The neat soap for containing Organic grape sodium saccharate is made by following steps:
Step (1): refined glycerine and purified salt are added to the deionization for accounting for ion water inventory 28% according to parts by weight
It in water, is stirred, obtains A phase；
Step (2): metal-chelator being added into remaining deionized water according to parts by weight, is stirred to all molten
Solution, obtains B phase；
Step (3): according to parts by weight that A phase made from fatty acid mixed, liquid alkaline, step (1) and step (2) is obtained
B phase squeezes into continuous saponification process system with metering pump respectively, is pre-mixed in a mixer, and 58% saponification, temperature are completed
It is 82 DEG C；
Step (4): continuous saponification process tank will be transported to from the partly-hydrolysed soap lye that premixer discharges in step (3)
In, continuous saponification process reaction is carried out, saponification temperature is controlled at 110 DEG C, and soap base is made；
Step (5): carrying out vacuum spray drying for soap base made from step (4), obtains the soap base that moisture content is 11%,
Then soap base refined, squeeze shaping, pelletizing molding, the neat soap containing Organic grape sodium saccharate is made.
In the step (5), the inlet temperature of vacuum spray drying is 110 DEG C, and vacuum degree is -890mbar, neat soap purification
Grain temperature is 42 DEG C out.
A kind of environment-friendly soap as made from the above-mentioned neat soap containing Organic grape sodium saccharate, the environment-friendly soap include following parts by weight
Raw material:
Every part of composite enzyme is by Pepsin, Superoxide dismutase element, lipase, sphingomyelins ferment
It is the composition that 2.2:1:1.2:0.6 is formed with weight ratio；Every part of plant extracts include 0.4 part of chlorella extract,
0.5 part of Flos Chrysanthemi Indici extract and 0.3 part of sea grape extract.
Every part of moisturizing factor is maltitol and/or hydrolysis glycosaminoglycan；Every part of emollients are by 0.3
Part glyceryl oleate, 3.5 parts of calcium gluconates, 1.1 portions of levulic acids and 2.5 parts of octyl dodecanol lauroyl glutamate ester mixing groups
At.
The surfactant is with weight ratio by dodecyl sodium sulfate and coconut oil sodium isethionate for 2.2:1 group
At mixture；The natural essence is Fruity type essence.
The environment-friendly soap is made by following steps:
Step A: refined glycerine and the heat preservation factor are added in neat soap according to parts by weight, stirred, control is mixed
The temperature for closing material is 34.5 DEG C, and component A is made；
Surfactant: being added into component A made from step A according to parts by weight, be uniformly mixed by step B, then
It is separately added into plant extracts, emollients and natural essence, mixing time 3.5min is uniformly mixed, and component B is made；
Step C: being cooled to 32 DEG C for component B made from step B, and composite enzyme is then added, and stirs 2.5min, then successively
By purification, grinding, vacuum plodding, environment-friendly soap is made in cooling printing.
Embodiment 3
A kind of neat soap containing Organic grape sodium saccharate, the neat soap include the raw material of following weight percent:
The metal-chelator is by Organic grape sodium saccharate, iminodisuccinic acid and two poly (sodium aspartate)s with weight
Than the mixture formed for 3:1:2.
Every part of fatty acid mixed includes 4.5 parts of lauric acid, 3 parts of palmitinic acids, 3 parts of oleic acid and 0.3 part of linoleic acid；It is described
The mass fraction of liquid alkaline is 36%.
The neat soap for containing Organic grape sodium saccharate is made by following steps:
Step (1): refined glycerine and purified salt are added to the deionized water for accounting for ionized water total 30% according to parts by weight
In, it is stirred, obtains A phase；
Step (2): metal-chelator being added into remaining deionized water according to parts by weight, is stirred to all molten
Solution, obtains B phase；
Step (3): according to parts by weight that A phase made from fatty acid mixed, liquid alkaline, step (1) and step (2) is obtained
B phase squeezes into continuous saponification process system with metering pump respectively, is pre-mixed in a mixer, and 560% saponification, temperature are completed
It is 85 DEG C；
Step (4): continuous saponification process tank will be transported to from the partly-hydrolysed soap lye that premixer discharges in step (3)
In, continuous saponification process reaction is carried out, saponification temperature is controlled at 115 DEG C, and soap base is made；
Step (5): carrying out vacuum spray drying for soap base made from step (4), obtains the soap base that moisture content is 12%,
Then soap base refined, squeeze shaping, pelletizing molding, the neat soap containing Organic grape sodium saccharate is made.
In the step (5), the inlet temperature of vacuum spray drying is 115 DEG C, and vacuum degree is -880mbar, neat soap purification
Grain temperature is 45 DEG C out.
A kind of environment-friendly soap as made from the above-mentioned neat soap containing Organic grape sodium saccharate, the environment-friendly soap include following parts by weight
Raw material:
Every part of composite enzyme is by Pepsin, Superoxide dismutase element, lipase, sphingomyelins ferment
It is the composition that 2.5:1:1.5:0.8 is formed with weight ratio；Every part of plant extracts include 0.5 part of chlorella extract,
0.6 part of Flos Chrysanthemi Indici extract and 0.4 part of sea grape extract.
Every part of moisturizing factor is hydrolysis glycosaminoglycan and/or PCA acid sodium；Every part of emollients are by 0.3
Part glyceryl oleate, 4 parts of calcium gluconates, 1.2 portions of levulic acids and 3 parts of octyl dodecanol lauroyl glutamate esters mixing compositions.
The surfactant is with weight ratio by dodecyl sodium sulfate and coconut oil sodium isethionate for 2.5:1 group
At mixture；The natural essence is Fruity type essence.
The environment-friendly soap is made by following steps:
Step A: refined glycerine and the heat preservation factor are added in neat soap according to parts by weight, stirred, control is mixed
The temperature for closing material is 35 DEG C, and component A is made；
Surfactant: being added into component A made from step A according to parts by weight, be uniformly mixed by step B, then
It is separately added into plant extracts, emollients and natural essence, mixing time 4min is uniformly mixed, and component B is made；
Step C: being cooled to 33 DEG C for component B made from step B, and composite enzyme is then added, and stirs 2min, then successively pass through
Purification, grinding, vacuum plodding are crossed, environment-friendly soap is made in cooling printing.
Embodiment 4
A kind of neat soap containing Organic grape sodium saccharate, the neat soap include the raw material of following weight percent:
The metal-chelator is by Organic grape sodium saccharate, iminodisuccinic acid and two poly (sodium aspartate)s with weight
Than the mixture formed for 3.5:1:2.2.
Every part of fatty acid mixed includes 4.8 parts of lauric acid, 3.5 parts of palmitinic acids, 3.5 parts of oleic acid and 0.4 part of linoleic acid；
The mass fraction of the liquid alkaline is 38%.
The neat soap for containing Organic grape sodium saccharate is made by following steps:
Step (1): refined glycerine and purified salt are added to the deionization for accounting for ion water inventory 32% according to parts by weight
It in water, is stirred, obtains A phase；
Step (2): metal-chelator being added into remaining deionized water according to parts by weight, is stirred to all molten
Solution, obtains B phase；
Step (3): according to parts by weight that A phase made from fatty acid mixed, liquid alkaline, step (1) and step (2) is obtained
B phase squeezes into continuous saponification process system with metering pump respectively, is pre-mixed in a mixer, and 63% saponification, temperature are completed
It is 88 DEG C；
Step (4): continuous saponification process tank will be transported to from the partly-hydrolysed soap lye that premixer discharges in step (3)
In, continuous saponification process reaction is carried out, saponification temperature is controlled at 120 DEG C, and soap base is made；
Step (5): carrying out vacuum spray drying for soap base made from step (4), obtains the soap base that moisture content is 12%,
Then soap base refined, squeeze shaping, pelletizing molding, the neat soap containing Organic grape sodium saccharate is made.
In the step (5), the inlet temperature of vacuum spray drying is 120 DEG C, and vacuum degree is -860mbar, neat soap purification
Grain temperature is 48 DEG C out.
A kind of environment-friendly soap as made from the above-mentioned neat soap containing Organic grape sodium saccharate, the environment-friendly soap include following parts by weight
Raw material:
Every part of composite enzyme is by Pepsin, Superoxide dismutase element, lipase, sphingomyelins ferment
It is the composition that 2.8:1:1.8:0.9 is formed with weight ratio；Every part of plant extracts include 0.6 part of chlorella extract,
0.7 part of Flos Chrysanthemi Indici extract and 0.5 part of sea grape extract.
Every part of moisturizing factor is by acetylation Sodium Hyaluronate, dexpanthenol and hydrolysis glycosaminoglycan with weight
Amount is than the mixture for 2:1.5:1 composition；Every part of emollients are by 0.4 part of glyceryl oleate, 4.5 parts of calcium gluconates, 1.3
Part levulic acid and 3.5 parts of octyl dodecanol lauroyl glutamate esters mixing compositions.
The surfactant is with weight ratio by dodecyl sodium sulfate and coconut oil sodium isethionate for 2.8:1 group
At mixture；The natural essence is Fruity type essence.
The environment-friendly soap is made by following steps:
Step A: refined glycerine and the heat preservation factor are added in neat soap according to parts by weight, stirred, control is mixed
The temperature for closing material is 35.5 DEG C, and component A is made；
Surfactant: being added into component A made from step A according to parts by weight, be uniformly mixed by step B, then
It is separately added into plant extracts, emollients and natural essence, mixing time 4.5min is uniformly mixed, and component B is made；
Step C: being cooled to 34 DEG C for component B made from step B, and composite enzyme is then added, and stirs 1.5min, then successively
By purification, grinding, vacuum plodding, environment-friendly soap is made in cooling printing.
Embodiment 5
A kind of neat soap containing Organic grape sodium saccharate, the neat soap include the raw material of following weight percent:
The metal-chelator is by Organic grape sodium saccharate, iminodisuccinic acid and two poly (sodium aspartate)s with weight
Than the mixture formed for 4:1:2.5.
Every part of fatty acid mixed includes 5 parts of lauric acid, 4 parts of palmitinic acids, 4 parts of oleic acid and 0.5 part of linoleic acid；The liquid
The mass fraction of alkali is 40%.
The neat soap for containing Organic grape sodium saccharate is made by following steps:
Step (1): refined glycerine and purified salt are added to the deionization for accounting for ion water inventory 35% according to parts by weight
It in water, is stirred, obtains A phase；
Step (2): metal-chelator being added into remaining deionized water according to parts by weight, is stirred to all molten
Solution, obtains B phase；
Step (3): according to parts by weight that A phase made from fatty acid mixed, liquid alkaline, step (1) and step (2) is obtained
B phase squeezes into continuous saponification process system with metering pump respectively, is pre-mixed in a mixer, and 65% saponification, temperature are completed
It is 90 DEG C；
Step (4): continuous saponification process tank will be transported to from the partly-hydrolysed soap lye that premixer discharges in step (3)
In, continuous saponification process reaction is carried out, saponification temperature is controlled at 125 DEG C, and soap base is made；
Step (5): carrying out vacuum spray drying for soap base made from step (4), obtains the soap base that moisture content is 13%,
Then soap base refined, squeeze shaping, pelletizing molding, the neat soap containing Organic grape sodium saccharate is made.
In the step (5), the inlet temperature of vacuum spray drying is 125 DEG C, and vacuum degree is -850mbar, neat soap purification
Grain temperature is 50 DEG C out.
A kind of environment-friendly soap as made from the above-mentioned neat soap containing Organic grape sodium saccharate, the environment-friendly soap include following parts by weight
Raw material:
Every part of composite enzyme is by Pepsin, Superoxide dismutase element, lipase, sphingomyelins ferment
It is the composition that 3:1:2:1.0 is formed with weight ratio；0.8 part of chlorella extract of every part of plant extracts packet, 0.8 part of open country
Chrysanthemum extract and 0.6 part of sea grape extract.
Every part of moisturizing factor is by acetylation Sodium Hyaluronate, dexpanthenol and hydrolysis glycosaminoglycan with weight
Amount is than the mixture for 3:2.5:1 composition；Every part of emollients are by 0.5 part of glyceryl oleate, 5 parts of calcium gluconates, 1.5 parts
Levulic acid and 4 parts of octyl dodecanol lauroyl glutamate ester mixing compositions.
The surfactant is made of dodecyl sodium sulfate and coconut oil sodium isethionate with weight ratio for 3:1
Mixture；The natural essence is Fruity type essence.
The environment-friendly soap is made by following steps:
Step A: refined glycerine and the heat preservation factor are added in neat soap according to parts by weight, stirred, control is mixed
The temperature for closing material is 36 DEG C, and component A is made；
Surfactant: being added into component A made from step A according to parts by weight, be uniformly mixed by step B, then
It is separately added into plant extracts, emollients and natural essence, mixing time 5min is uniformly mixed, and component B is made；
Step C: being cooled to 36 DEG C for component B made from step B, and composite enzyme is then added, and stirs 1min, then successively pass through
Purification, grinding, vacuum plodding are crossed, environment-friendly soap is made in cooling printing.
Comparative example 1
A kind of environment-friendly soap as made from the above-mentioned neat soap containing Organic grape sodium saccharate, the environment-friendly soap include following parts by weight
Raw material:
The surfactant is by dodecyl sodium sulfate.
Comparative example 2
A kind of environment-friendly soap as made from the above-mentioned neat soap containing Organic grape sodium saccharate, the environment-friendly soap include following parts by weight
Raw material:
Comparative example 3
A kind of environment-friendly soap as made from the above-mentioned neat soap containing Organic grape sodium saccharate, the environment-friendly soap include following parts by weight
Raw material:
Neat soap made from embodiment 1-5 is subjected to oxidation stability test, test method and shown in test result is as follows:
Test method: the neat soap cured made from above-described embodiment 1-5 is divided into three parts, is respectively charged into carton
In, first part is put into 45 DEG C of constant temperature of oven environment, and second part is placed in normal temperature environment, and third part is placed on 4 DEG C of refrigerator cold
It hides in room (standard sample whether third part changes as later observation color).
Observation in one week is primary in one month early period, compares with standard sample, observes the variation of its color, while Wen Qiqi
Taste.It is primary for observation in two weeks after reaching one month, and compared with standard sample, its color change and smell variation are observed, always
It is observed to end in the 100th day.
Test result:
Illustrate neat soap of the invention using Organic grape acid sodium as Primary chelating agent, can by water and dirt in metal from
Attached bag is closed to inside chelating agent, is formed stable chelate, is prevented the precipitating of dirt, and metal ion is avoided to cause the oxygen of neat soap
Change and go bad, improves the oxidation stability of neat soap, not oxidizable xanthochromia and generation peculiar smell.
Environment-friendly soap made from embodiment 1-5 and comparative example 1-3 is subjected to foaming characteristic, hygrochase, wet soap sense of touch and skin table
The water humidity in face is tested, test method and shown in test result is as follows:
Test method:
(1) foaming test: being measured according to the measuring method of GB7462 foaming power, is stopped with the foam of formation in liquid stream
Only ml its result is indicated when 5min.(2) hygrochase is tested: environment-friendly soap is completely soaked in 30 DEG C of constant temperature of water
Then 2h is drained, and the dry 16-24h at 30 DEG C, is observed the crack situation of environment-friendly soap and is classified, and 0 expression soap body is not split
Seam, 5 indicate that the crack of soap body is serious, and situation occurs in the crack of the grade reflection environment-friendly soap of 0-5；
(3) wet soap feeling of grittiness test: environment-friendly soap being placed in 26.7 ± 1 DEG C of tap water, and by environment-friendly soap palm
Gently rub about 1min, and sense of touch judges environment-friendly soap smoothness of the surface and roughening (whether having apparent feeling of grittiness), and divide etc.
Grade, 0 indicates the smooth no feeling of grittiness of soap body, and 1-3 indicates that soap body surface indicates more there are slight feeling of grittiness, more than 4
Feeling of grittiness, feel is coarse, the wet soap sense of touch grade of the grade reflection environment-friendly soap of 0-5；
(4) the water humidity test of skin surface: the skin before above-mentioned environment-friendly soap is used using the detection of Germany's DJM skinanalysis apparatus
Skin water oil value, obtaining initial value is moisture content value 52.16, oil content value 56.89；
Then be utilized respectively above-described embodiment 1-5, the environment-friendly soap of comparative example 1-3 is cleaned, and test cleaning after 10min
Skin water oil value.
Test result:
By above-mentioned date comprision, the surfactant in 1 environment-friendly soap of comparative example is only with dodecyl sodium sulfate, ring
The foam height for protecting soap is lower, and foaming characteristic is poor, illustrates environment-friendly soap of the invention by using dodecyl sodium sulfate and cocounut oil
Surfactant made of sour sodium isethionate compounding, can effectively improve the bubble power and foam stability of environment-friendly soap, and steep
The abundant exquisiteness of foam, can promote the dirt-removing power of environment-friendly soap.
Without using emollients in 2 environment-friendly soap of comparative example, sense of touch of the environment-friendly soap obtained in flowing water exists slight
Foreign particle sense, feel is coarse, illustrates emollients through the invention, the soft and moist texture of environment-friendly soap can be effectively improved, and
Soft and moist effect can be played to skin, and skin after cleaning is avoided to generate tight phenomenon.
Without using moisturizing factor in 3 environment-friendly soap of comparative example, using in the skin surface moisture content value after environment-friendly soap cleaning
It rises seldom, oil content value is higher with respect to other embodiments, illustrates by using moisturizing factor of the invention, can be in environment-friendly soap to skin
Moisture content is replenished in time while cleaning comprehensively, avoids occurring the phenomenon that water shortage shriveling clean comprehensively after (skin being in water shortage shriveling
In the case where can secrete automatically grease epidermal cell is protected, thus there is oil content and be worth slightly higher phenomenon), improve environment-friendly soap
Cleaning, moisturizing effect.
Above-described embodiment is the preferable implementation of the present invention, and in addition to this, the present invention can be realized with other way,
Do not depart under the premise of present inventive concept it is any obviously replace it is within the scope of the present invention.
Claims (10)
1. a kind of neat soap containing Organic grape sodium saccharate, it is characterised in that: the neat soap includes the raw material of following weight percent:
The metal-chelator is organic gluconic acid sodium salt, or is Organic grape sodium saccharate, iminodisuccinic acid and dimerization day
The mixture of aspartic acid sodium.
2. a kind of neat soap containing Organic grape sodium saccharate according to claim 1, it is characterised in that: the Organic grape
The mixed proportion of sodium saccharate, iminodisuccinic acid and two poly (sodium aspartate)s is 2-4:1:1.5-2.5.
3. a kind of neat soap containing Organic grape sodium saccharate according to claim 1, it is characterised in that: every part of mixing
Fatty acid includes 4-5 parts of lauric acid, 2-4 parts of palmitinic acids, 2-4 parts of oleic acid and 0.2-0.5 parts of linoleic acid；The quality of the liquid alkaline point
Number is 32-40%.
4. a kind of neat soap containing Organic grape sodium saccharate according to claim 1, it is characterised in that: organic Portugal should be contained
The neat soap of grape sodium saccharate is made by following steps:
Step (1): refined glycerine and purified salt are added to the deionized water for accounting for ion water inventory 25-35% according to parts by weight
In, it is stirred, obtains A phase；
Metal-chelator: being added into remaining deionized water according to parts by weight, be stirred to whole dissolutions by step (2),
Obtain B phase；
Step (3): according to parts by weight by B phase made from A phase made from fatty acid mixed, liquid alkaline, step (1) and step (2)
Continuous saponification process system is squeezed into metering pump respectively, is pre-mixed in a mixer, the saponification of 55-65%, temperature are completed
It is 80-90 DEG C；
Step (4): will be transported in continuous saponification process tank in step (3) from the partly-hydrolysed soap lye that premixer discharges, into
Row continuous saponification process reaction, saponification temperature are controlled at 105-125 DEG C, and soap base is made；
Step (5): carrying out vacuum spray drying for soap base made from step (4), obtains the soap base that moisture content is 10-13%,
Then soap base refined, squeeze shaping, pelletizing molding, the neat soap containing Organic grape sodium saccharate is made.
5. a kind of neat soap containing Organic grape sodium saccharate according to claim 4, it is characterised in that: the step (5)
In, the inlet temperature of vacuum spray drying is 105-125 DEG C, and vacuum degree is -850~-900mbar, and neat soap refines out grain temperature
It is 40-50 DEG C.
6. a kind of environment-friendly soap as made from claim 1-5 described in any item neat soaps containing Organic grape sodium saccharate, special
Sign is: the environment-friendly soap includes the raw material of following parts by weight:
7. a kind of environment-friendly soap containing Organic grape sodium saccharate according to claim 6, it is characterised in that: every part described multiple
Closing ferment is with weight ratio by Pepsin, Superoxide dismutase element, lipase, sphingomyelins ferment for 2-3:1:1-
2:0.5-1.0 the composition of composition；Every part of plant extracts includes 0.3-0.8 parts of chlorella extracts, 0.4-0.8 parts of open countries
Chrysanthemum extract and 0.2-0.6 parts of sea grape extracts.
8. a kind of environment-friendly soap containing Organic grape sodium saccharate according to claim 6, it is characterised in that: every part of guarantor
The wet factor is acetylation Sodium Hyaluronate, dexpanthenol, maltitol, hydrolyzes in glycosaminoglycan and PCA acid sodium extremely
Few one kind；Every part of emollients be by 0.2-0.5 parts of glyceryl oleates, 3-5 parts of calcium gluconates, 1-1.5 portions of levulic acids and
2-4 parts of octyl dodecanol lauroyl glutamate ester mixing compositions.
9. a kind of environment-friendly soap containing Organic grape sodium saccharate according to claim 6, it is characterised in that: the surface is living
Property agent by dodecyl sodium sulfate and coconut oil sodium isethionate be the mixture that forms of 2-3:1 with weight ratio；The day
Right essence is Fruity type essence.
10. a kind of environment-friendly soap containing Organic grape sodium saccharate according to claim 6, it is characterised in that: the environment-friendly soap
It is made by following steps:
Step A: refined glycerine and the heat preservation factor are added in neat soap according to parts by weight, stirs, controls mixture
Temperature be 34-36 DEG C, be made component A；
Step B: surfactant is added into component A made from step A according to parts by weight, is uniformly mixed, then distinguish
Plant extracts, emollients and natural essence is added, mixing time 3-5min is uniformly mixed, and component B is made；
Step C: being cooled to 30-36 DEG C for component B made from step B, and composite enzyme is then added, and stirs 1-3min, then successively
By purification, grinding, vacuum plodding, environment-friendly soap is made in cooling printing.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113214909A (en) * | 2021-04-02 | 2021-08-06 | 江西车仆实业有限公司 | Concentrated high-foam car washing gel bead and preparation method and application thereof |
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