Summary of the invention
The objective of the invention is for the bath foam poor efficiency that overcomes prior art for preparing expensive, the shortcoming of manufacturing process complexity, and provide a kind of can effectively remove the skin dirt and to skin have moisture-keeping efficacy, cost is low, simple bath foam of manufacturing process and preparation method thereof.
Up-to-date skin protection theory is an oxidation resistance of utilizing plant to have, and the generation that suppresses lipid peroxide to be reaching the purpose of prevention skin aging, olive oil thereby be subjected to people's attention.Wherein olive oil contains a large amount of antioxidant and has the effect that suppresses active oxygen, and has remarkable preserving moisture and the anti-ultraviolet effect.It is leading in all vegetable oil that olive oil is difficult to the characteristic of oxidation.Because it contains a large amount of antioxidant contents, far exceed skin itself so suppress lipid oxidation power.Contained vitamin E is a highest active antioxidant content in the olive oil, and the beta-carotene and the pigment flavone of the benzene analog derivative of generation and formation olive oil color and luster also have strong antioxidant action.The Fructus Canarii albi main body of oil is oleic acid, linoleic acid and Palmic acid.Satisfied fatty acid forms the film shielding of ultraviolet at skin surface, and unsaturated fatty acid absorbs the UV-B ripple simultaneously, stops its infringement to skin.Japan officina is defined as the pharmaceuticals that can protect skin, moistening effect is arranged with " olive oil ".Tea tree oil is a kind of pure natural substance that can effectively treat the skin infection that is caused by antibacterial, fungus or virus.Tea tree oil can reduce growth of microorganism and bacterial infection, it is calm to releive, penetration is strong, gentleness does not stimulate, and is a kind of natural detergent.The use tea tree oil is as safe as a house, and without any side effect, the fragrance of its uniqueness allows the people cannot forget for a long time.What it was the most valuable is not contain any harmful material, in this field the development trend that progressively replaces similar synthetic product will be arranged.
Ethoxylated oil and grease has similar molecular structure (triglyceride) to sebum, therefore very easily merges with sebum, has very strong emulsifying capacity, can effectively remove the dirt on the skin; Another characteristics are to have a hydrophilic group, and porous is to the basic low layer of skin, thereby enhance metabolism, and product is nontoxic, performance is gentle, has advantages such as zest is low, biological degradability is good, belongs to greenization, environmentally friendly machine.Technical scheme of the present invention is: a kind of bath foam of preserving moisture, contain a kind of novel green non-ionic surface active agent---and ethoxylated oil and grease is the first type surface activating agent.
The percentage by weight of bath foam of the present invention consists of as follows:
Non-ionic surface active agent 15~30%
Anion surfactant 1~15%
Amphoteric surfactant 1~5%
Pearling agent 3~5%
PH regulator agent 0.1~0.3%
Electrolyte 0~2%
Wetting agent 0~2%
Spice 0.05~0.1%
Water 45~70%
Aforesaid non-ionic surface active agent is the ethoxylated oil and grease non-ionic surface active agent, and the ethoxylated oil and grease non-ionic surface active agent is water miscible, for Vegetable oil lipoprotein and oxirane direct addition make, has following general formula:
Wherein R is C
1~30Alkyl or their mixture, preferred C
8~18Alkyl or its mixture, x, y, z can be identical or different, and x+y+z=n, n are 1~180, and be preferred 12~90, more preferably 18~60.Typical ethoxylated oil and grease has soybean oil ethoxylate (the average EO adduction several 14~20 of strand), olive oil ethoxylate (the average EO adduction several 6~12 of strand), tea tree oil ethoxylate (the average EO adduction several 6~12 of strand), and concrete preparation method is seen Chinese patent: a kind of greasy ethoxylate and preparation method (CN1730145).
Aforesaid anion surfactant is a sulfur-bearing hydrochlorate type anion surfactant.Comprise water miscible alkyl sulfate or alkyl polyoxyethylene ether sulfate anion surfactant, following form: R-O (A) is arranged
nSO
- 3M
+, wherein R is unsubstituted straight or branched C
6~20Alkyl or hydroxyalkyl group, preferred C
12~20Alkyl or hydroxyalkyl, more preferably C
12~15Perhaps C
12~14Alkyl; A is ethyoxyl or propoxyl group unit, preferred ethoxy unit; N is 0.5~5, preferred 0.5~3; M is an ammonium ion or a metal ion, is more preferably sodium ion.Alkyl ether sulfate generally exists with the R that comprises different chain length and the form of mixtures of different ethoxylation degrees, and ideal sulfate surfactant is C
12~14Polyoxyethylene (3) ether sodium sulfate or C
12~15Polyoxyethylene (2) ether sodium sulfate.
Aforesaid amphoteric surfactant is the betaine type amphoteric surfac-tant, has following general formula:
R wherein
1Be C
10~20Alkyl or their mixture, preferred C
12~18Alkyl, R
2, R
3Be C
1~3Alkyl, preferred CH
3, R
4For having the alkylidene of 1~6 carbon atom.Betanin can be cocoamidopropyl betaine or dodecyldimethylammonium hydroxide inner salt.
Aforesaid pearling agent is an alkanolamide type non-ionic surface active agent, mainly is C
8~18Alkanolamide has following general formula: R
1-CO-N (H)
m(R
2OH)
3-m, wherein, R
1Be to contain 7~21, saturated or the unsaturated no hydroxyl group aliphatic alkyl or their mixture of preferred 11~17 carbon atoms; R
2Expression methylene or ethylidene; M is 1 or 2, preferred 1.It can be coconut monoethanolamide.
Aforesaid pH regulator agent comprises metal carbonate, metal bicarbonate saline solution, organic acid or inorganic acid solution, as Na
2CO
3, NaHCO
3, K
2CO
3, KHCO
3Reach the aqueous solution of citric acid, tartaric acid, sulfonic acid, phosphoric acid etc.
Aforesaid electrolyte comprises salt such as sodium chloride, potassium chloride, sodium citrate, sodium acetate, sodium sulfate or potassium sulfate.Most preferred electrolyte is sodium chloride or potassium chloride.
Aforesaid wetting agent is a glycerol.
Aforesaid spice is the water miscible spice of safety, as Fructus Citri Limoniae essence.
Aforesaid water is deionized water or distilled water.
The preparation method of bath foam of the present invention may further comprise the steps:
Percentage by weight composition by bath foam in mixing kettle joins the ethoxylated oil and grease non-ionic surface active agent in the deionized water, be stirred and heated to 80~85 ℃, add anion surfactant, amphoteric surfactant, pearling agent again after the dissolving fully, stirred 1~2 hour down at 90~95 ℃, stop heating and continue to stir cooling to 60~70 ℃, add pH regulator agent, electrolyte and wetting agent successively, continue to stir and add spice when being cooled to 30~50 ℃, stir, make product.
The invention has the beneficial effects as follows: contain ethoxylated oil and grease in the bath foam of the present invention, it has good moisture absorbability and moisture retentivity and bactericidal effect, low price; Have good water-solubility, stability, conditioning, emulsibility, nontoxic, easily biological-degradable is novel green surfactant.
Bath foam of the present invention makes that equipment needed thereby is few, technology simple, main raw material(s) green natural, low price.Obtained properties of product gentleness, fragrant odour, foam is abundant, is easy to flushing, noresidue and soapy feeling clearly moisten with back skin, moisture retention is good, can not use cutaneous homergy because of frequent, cause skin drying, defat, itch.Life-time service can enhance metabolism, and improves body immunity.
The specific embodiment
Embodiment one:
1. preparation ethoxylated oil and grease.Preparation method is according to Chinese patent: a kind of greasy ethoxylate and preparation method (CN1730145).Concrete preparation method is as follows:
Catalyst 1.5g is joined in the 90g soybean oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 180 ℃, imports oxirane, keep system pressure 0.4MPa, when the oxirane addition is 185g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 277g promptly obtains soybean oil ethoxylate (n=42) sample.
Catalyst 0.3g is joined in the 147.7g olive oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 200 ℃, imports oxirane, keep system pressure 0.5MPa, when the oxirane addition is 159g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 308g promptly obtains Fructus Canarii albi oils and fats ethoxylate (n=18) sample.
Catalyst 0.9g is joined in the 146g tea tree oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 190 ℃, imports oxirane, keep system pressure 0.5MPa, when the oxirane addition is 132g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 280g promptly obtains Camellia sinensis oils and fats ethoxylate (n=18) sample.
2. preparation contains the bath foam 1000g of ethoxylated oil and grease, and it is as follows to fill a prescription:
Soybean oil ethoxylate (n=42) 100g
Fructus Canarii albi oils and fats ethoxylate (n=18) 30g
Camellia sinensis oils and fats ethoxylate (n=18) 20g
Sodium lauryl sulphate 80g
Polyoxyethylenated alcohol sodium sulfate 50g
Cocoamidopropyl betaine 50g
Pearling agent: coconut monoethanolamide 50g
PH regulator agent: citric acid 3g
Electrolyte: sodium chloride 15g
Wetting agent: glycerol 20g
Spice: Fructus Citri Limoniae essence 1g
Deionized water 554g
3. method for making:
In mixing kettle with 100g soybean oil ethoxylate (n=42), 30g Fructus Canarii albi oils and fats ethoxylate (n=18) and 20g Camellia sinensis oils and fats ethoxylate (n=18) join in the 554g deionized water, be stirred and heated to 80 ℃, add the 80g sodium lauryl sulphate again after the dissolving fully, 50g polyoxyethylenated alcohol sodium sulfate, 50g cocoamidopropyl betaine and 50g coconut monoethanolamide, stirred 1 hour down at 90 ℃, stop heating and continue to stir cooling to 60 ℃, add the 3g citric acid successively, 15g sodium chloride and 20g glycerol, continue to stir and add the 1g Fructus Citri Limoniae essence when being cooled to 30 ℃, stir, make product.
Embodiment two:
1. preparation ethoxylated oil and grease.Preparation method is according to Chinese patent: a kind of greasy ethoxylate and preparation method (CN1730145).Concrete preparation method is as follows:
Catalyst 1.8g is joined in the 90g soybean oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 180 ℃, imports oxirane, keep system pressure 0.4MPa, when the oxirane addition is 198g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 290g promptly obtains soybean oil ethoxylate (n=45) sample.
Catalyst 0.5g is joined in the 147.7g olive oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 200 ℃, imports oxirane, keep system pressure 0.5MPa, when the oxirane addition is 185g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 331g promptly obtains Fructus Canarii albi oils and fats ethoxylate (n=21) sample.
Catalyst 1.2g is joined in the 146g tea tree oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 190 ℃, imports oxirane, keep system pressure 0.5MPa, when the oxirane addition is 154g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 303g promptly obtains Camellia sinensis oils and fats ethoxylate (n=21) sample.
2. preparation contains the bath foam 1000g of ethoxylated oil and grease, and it is as follows to fill a prescription
Soybean oil ethoxylate (n=45) 130g
Fructus Canarii albi oils and fats ethoxylate (n=21) 20g
Camellia sinensis oils and fats ethoxylate (n=21) 20g
Sodium lauryl sulphate 40g
Polyoxyethylenated alcohol sodium sulfate 50g
Cocoamidopropyl betaine 40g
Pearling agent: coconut monoethanolamide 40g
PH regulator agent: citric acid 3g
Electrolyte: sodium chloride 10g
Wetting agent: glycerol 20g
Spice: essence 1g
Deionized water 576g
3. method for making:
In mixing kettle with 130g soybean oil ethoxylate (n=45), 20g Fructus Canarii albi oils and fats ethoxylate (n=21) and 20g Camellia sinensis oils and fats ethoxylate (n=21) join in the 576g deionized water, be stirred and heated to 85 ℃, add the 40g sodium lauryl sulphate again after the dissolving fully, 50g polyoxyethylenated alcohol sodium sulfate, 40g cocoamidopropyl betaine and 40g coconut monoethanolamide, stirred 1.5 hours down at 95 ℃, stop heating and continue to stir cooling to 70 ℃, add the 3g citric acid successively, 10g sodium chloride and 20g glycerol, continue to stir and add the 1g Fructus Citri Limoniae essence when being cooled to 40 ℃, stir, make product.
Embodiment three:
1. preparation ethoxylated oil and grease.Preparation method is according to Chinese patent: a kind of greasy ethoxylate and preparation method (CN1730145).Concrete preparation method is as follows:
Catalyst 2.1g is joined in the 90g soybean oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 180 ℃, imports oxirane, keep system pressure 0.4MPa, when the oxirane addition is 212g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 305g promptly obtains soybean oil ethoxylate (n=48) sample.
Catalyst 0.7g is joined in the 147.7g olive oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 200 ℃, imports oxirane, keep system pressure 0.5MPa, when the oxirane addition is 212g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 360g promptly obtains Fructus Canarii albi oils and fats ethoxylate (n=24) sample.
Catalyst 2.1g is joined in the 146g tea tree oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 190 ℃, imports oxirane, keep system pressure 0.5MPa, when the oxirane addition is 176g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 326g promptly obtains Camellia sinensis oils and fats ethoxylate (n=24) sample.
2. preparation contains the bath foam 1000g of ethoxylated oil and grease, and it is as follows to fill a prescription:
Soybean oil ethoxylate (n=48) 140g
Fructus Canarii albi oils and fats ethoxylate (n=24) 30g
Camellia sinensis oils and fats ethoxylate (n=24) 30g
Sodium lauryl sulphate 70g
Polyoxyethylenated alcohol sodium sulfate 40g
Cocoamidopropyl betaine 30g
Pearling agent: coconut monoethanolamide 30g
PH regulator agent: citric acid 2.5g
Electrolyte: sodium chloride 15g
Wetting agent: glycerol 20g
Spice: Fructus Citri Limoniae essence 1g
Deionized water 591.5g
3. method for making:
In mixing kettle with 140g soybean oil ethoxylate (n=48), 30g Fructus Canarii albi oils and fats ethoxylate (n=24) and 30g Camellia sinensis oils and fats ethoxylate (n=24) join in the 591.5g deionized water, be stirred and heated to 85 ℃, add the 70g sodium lauryl sulphate again after the dissolving fully, 40g polyoxyethylenated alcohol sodium sulfate, 30g cocoamidopropyl betaine and 30g coconut monoethanolamide, stirred 2 hours down at 90 ℃, stop heating and continue to stir cooling to 70 ℃, add the 2.5g citric acid successively, 15g sodium chloride and 20g glycerol, continue to stir and add the 1g Fructus Citri Limoniae essence when being cooled to 45 ℃, stir, make product.
Embodiment four:
1. preparation ethoxylated oil and grease.Preparation method is according to Chinese patent: a kind of greasy ethoxylate and preparation method (CN1730145).Concrete preparation method is as follows:
Catalyst 2.3g is joined in the 90g soybean oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 180 ℃, imports oxirane, keep system pressure 0.4MPa, when the oxirane addition is 225g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 317g promptly obtains soybean oil ethoxylate (n=51) sample.
Catalyst 0.9g is joined in the 147.7g olive oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 200 ℃, imports oxirane, keep system pressure 0.5MPa, when the oxirane addition is 238g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 385g promptly obtains Fructus Canarii albi oils and fats ethoxylate (n=27) sample.
Catalyst 2.3g is joined in the 146g tea tree oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 190 ℃, imports oxirane, keep system pressure 0.5MPa, when the oxirane addition is 198g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 347g promptly obtains Camellia sinensis oils and fats ethoxylate (n=27) sample.
2. preparation contains the bath foam 1000g of ethoxylated oil and grease, and it is as follows to fill a prescription
Soybean oil ethoxylate (n=51) 100g
Fructus Canarii albi oils and fats ethoxylate (n=27) 50g
Camellia sinensis oils and fats ethoxylate (n=27) 50g
Sodium lauryl sulphate 70g
Polyoxyethylenated alcohol sodium sulfate 70g
Cocoamidopropyl betaine 20g
Pearling agent: coconut monoethanolamide 50g
PH regulator agent: citric acid 3g
Electrolyte: sodium chloride 10g
Wetting agent: glycerol 20g
Spice: Fructus Citri Limoniae essence 1g
Deionized water 556g
3. method for making:
In mixing kettle with 100g soybean oil ethoxylate (n=51), 50g Fructus Canarii albi oils and fats ethoxylate (n=27) and 50g Camellia sinensis oils and fats ethoxylate (n=27) join in the 556g deionized water, be stirred and heated to 85 ℃, add the 70g sodium lauryl sulphate again after the dissolving fully, 70g polyoxyethylenated alcohol sodium sulfate, 20g cocoamidopropyl betaine and 20g coconut monoethanolamide, stirred 2 hours down at 95 ℃, stop heating and continue to stir cooling to 70 ℃, add the 3g citric acid successively, 10g sodium chloride and 20g glycerol, continue to stir and add the 1g Fructus Citri Limoniae essence when being cooled to 50 ℃, stir, make product.
Embodiment five:
1. preparation ethoxylated oil and grease.Preparation method is according to Chinese patent: a kind of greasy ethoxylate and preparation method (CN1730145).Concrete preparation method is as follows:
Catalyst 2.6 is joined in the 90g soybean oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 180 ℃, imports oxirane, keep system pressure 0.4MPa, when the oxirane addition is 238g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 329.5 promptly obtains soybean oil ethoxylate (n=54) sample.
Catalyst 1.2g is joined in the 147.7g olive oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 200 ℃, imports oxirane, keep system pressure 0.5MPa, when the oxirane addition is 264g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 413g promptly obtains Fructus Canarii albi oils and fats ethoxylate (n=30) sample.
Catalyst 2.5 is joined in the 146g tea tree oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 190 ℃, imports oxirane, keep system pressure 0.5MPa, when the oxirane addition is 220g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 369g promptly obtains Camellia sinensis oils and fats ethoxylate (n=30) sample.
2. preparation contains the bath foam 1000g of ethoxylated oil and grease, and it is as follows to fill a prescription
Soybean oil ethoxylate (n=54) 180g
Fructus Canarii albi oils and fats ethoxylate (n=30) 50g
Camellia sinensis oils and fats ethoxylate (n=30) 50g
Sodium lauryl sulphate 30g
Polyoxyethylenated alcohol sodium sulfate 30g
Cocoamidopropyl betaine 15g
Pearling agent: coconut monoethanolamide 30g
PH regulator agent: citric acid 3g
Electrolyte: sodium chloride 8g
Wetting agent: glycerol 18g
Spice: essence 1g
Deionized water 595g
3. method for making: in mixing kettle with 130g soybean oil ethoxylate (n=54), 20g Fructus Canarii albi oils and fats ethoxylate (n=30) and 20g Camellia sinensis oils and fats ethoxylate (n=30) join in the 576g deionized water, be stirred and heated to 85 ℃, add the 70g sodium lauryl sulphate again after the dissolving fully, 70g polyoxyethylenated alcohol sodium sulfate, 20g cocoamidopropyl betaine and 20g coconut monoethanolamide, stirred 2 hours down at 95 ℃, stop heating and continue to stir cooling to 65 ℃, the 3g citric acid, 10g sodium chloride and 20g glycerol, continue to stir and add the 1g Fructus Citri Limoniae essence when being cooled to 50 ℃, stir, make product.
Embodiment six:
1. preparation ethoxylated oil and grease.Preparation method is according to Chinese patent: a kind of greasy ethoxylate and preparation method (CN1730145).Concrete preparation method is as follows:
Catalyst 2.9 is joined in the 90g soybean oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 180 ℃, imports oxirane, keep system pressure 0.4MPa, when the oxirane addition is 264g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 357 promptly obtains soybean oil ethoxylate (n=60) sample.
Catalyst 1.5g is joined in the 147.7g olive oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 200 ℃, imports oxirane, keep system pressure 0.5MPa, when the oxirane addition is 317g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 466g promptly obtains Fructus Canarii albi oils and fats ethoxylate (n=36) sample.
Catalyst 2.8 is joined in the 146g tea tree oil, drop into while stirring in the 1L autoclave, open and stir, the inflated with nitrogen displaced air is warming up to 190 ℃, imports oxirane, keep system pressure 0.5MPa, when the oxirane addition is 264g, closed loop oxidative ethane inlet valve, aging 10 minutes, be cooled to 70 ℃, emit material, product weighing 413g promptly obtains Camellia sinensis oils and fats ethoxylate (n=36) sample.
2. preparation contains the bath foam 1000g of ethoxylated oil and grease, and it is as follows to fill a prescription
Soybean oil ethoxylate (n=60) 190g
Fructus Canarii albi oils and fats ethoxylate (n=36) 55g
Camellia sinensis oils and fats ethoxylate (n=36) 55g
Sodium lauryl sulphate 75g
Polyoxyethylenated alcohol sodium sulfate 75g
Cocoamidopropyl betaine 50g
Pearling agent: coconut monoethanolamide 50g
PH regulator agent: citric acid 3g
Electrolyte: sodium chloride 10g
Wetting agent: glycerol 20g
Spice: essence 1g
Distilled water 484g
3. method for making: in mixing kettle with 190g soybean oil ethoxylate (n=60), 55g Fructus Canarii albi oils and fats ethoxylate (n=36) and 55g Camellia sinensis oils and fats ethoxylate (n=36) join in the 484g deionized water, be stirred and heated to 90 ℃, add the 75g sodium lauryl sulphate again after the dissolving fully, 75g polyoxyethylenated alcohol sodium sulfate, 50g cocoamidopropyl betaine and 30g coconut monoethanolamide, stirred 2 hours down at 95 ℃, stop heating and continue to stir cooling to 70 ℃, the 3g citric acid, 10g sodium chloride and 20g glycerol, continue to stir and add the 1g Fructus Citri Limoniae essence when being cooled to 50 ℃, stir, make product.