JP2008247782A - Face-cleansing cosmetic composition - Google Patents

Face-cleansing cosmetic composition Download PDF

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Publication number
JP2008247782A
JP2008247782A JP2007089934A JP2007089934A JP2008247782A JP 2008247782 A JP2008247782 A JP 2008247782A JP 2007089934 A JP2007089934 A JP 2007089934A JP 2007089934 A JP2007089934 A JP 2007089934A JP 2008247782 A JP2008247782 A JP 2008247782A
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Prior art keywords
fatty acid
acid soap
cosmetic composition
temperature
cleansing cosmetic
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Japanese (ja)
Inventor
Kumiko Katsuyama
久美子 勝山
Mikito Ihara
幹人 伊原
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Naris Cosmetics Co Ltd
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Naris Cosmetics Co Ltd
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Priority to JP2007089934A priority Critical patent/JP2008247782A/en
Publication of JP2008247782A publication Critical patent/JP2008247782A/en
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a new fatty acid soap-based cream-shaped face-cleansing cosmetic composition having excellent stability by preventing the temperature-dependent viscosity increase with time in the fatty acid soap-based cream-shaped face-cleansing cosmetic composition. <P>SOLUTION: The fatty acid soap-based cream-shaped face-cleansing cosmetic composition contains dipotassium glycyrrhizinate and/or potassium acetate to prevent the temperature-dependent viscosity increase. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、脂肪酸石けん系クリーム状洗顔料組成物に関し、特に、当該組成物が経時で粘度上昇することを防止するための成分を含有した脂肪酸石けん系クリーム状洗顔料組成物に関する。   The present invention relates to a fatty acid soap-based cream facial cleansing composition, and in particular, to a fatty acid soap-based cream facial cleansing composition containing a component for preventing the composition from increasing in viscosity over time.

脂肪酸石けん系クリーム状洗顔料組成物は、スキンケアの分野において、液状や固形状等の他の性状の洗顔料に比べ、機能、使用性、使用感触において有用な製剤として広く使用されている。   Fatty acid soap cream cleansing compositions are widely used in the skin care field as preparations that are useful in terms of function, usability, and feel in use, as compared with other properties such as liquid and solid.

これは、洗浄剤主成分である脂肪酸石けんを中和により製造する際、脂肪酸の中和を100%行なわず、使用する脂肪酸の一部を遊離脂肪酸の状態で残存させることにより、洗顔等に使用した際に、皮膚を脱脂し過ぎず、皮膚にマイルドな洗浄性と滑らかな使用感触を作り出している。   This is used for facial cleansing, etc., by neutralizing the fatty acid soap, which is the main component of the detergent, by neutralizing the fatty acid, leaving some of the fatty acid used in the state of free fatty acid. When done, it does not degrease the skin too much, creating a mild cleanability and a smooth feel to the skin.

ところが、脂肪酸の中和を100%行なわず、使用する脂肪酸の一部を遊離脂肪酸の状態で残存させることが逆に安定性に大きく影響を及ぼすこととなる。これは、脂肪酸石けん系クリーム状洗顔料が安定系ではないため、些細な環境(温度)の変化が直ちに製剤に影響を及ぼすためである。とりわけ30℃以上の高温環境下で長期間保存された後、常温から低温環境下のもとで使用する場合、主として前記の遊離脂肪酸による結晶化析出や脂肪酸石けん自体の再結晶化(固化)などにより、脂肪酸石けん系クリーム状洗顔料組成物の構造粘度が経時的に上昇し、使用する際、チューブなどの容器から非常に出し難くなり、商品価値を損なうものとなっていた。   However, the neutralization of the fatty acid is not performed 100%, and leaving a part of the fatty acid to be used in the state of free fatty acid adversely affects the stability. This is because the fatty acid soap-based cream facial cleanser is not a stable system, so that a slight change in the environment (temperature) immediately affects the preparation. In particular, when stored under a high temperature environment of 30 ° C. or higher for a long period of time and then used under a normal temperature to a low temperature environment, crystallization precipitation due to the free fatty acid or recrystallization (solidification) of the fatty acid soap itself, etc. As a result, the structural viscosity of the fatty acid soap-based cream cleansing composition increases with time, and when used, it becomes very difficult to remove from a container such as a tube, and the commercial value is impaired.

この様な問題について、未だ満足する解決策は存在せず、製剤化研究の際の試行錯誤により個々の処方で応急的に対応しているのが現状である。また、洗浄剤や化粧料には、系の安定化や増粘に関して、グリチルリチン酸ジカリウム又は酢酸カリウムを含有した先行技術がある。(特許文献1及び2参照)しかし、特許文献1は、水系固化化粧料の固形化の安定性に関する特許であり、グリチルリチン酸ジカリウムが固化作用成分として含まれており、脂肪酸石けん系クリーム状洗顔料の温度依存性経時粘度上昇の防止に関して何ら示唆する記載は見当たらない。また、特許文献2は、液体洗浄組成物に関する系の安定化技術であり、脂肪酸石けん系クリーム状洗顔料に関して何ら示唆する記載は見当たらない。従って、前記の温度依存性経時粘度上昇によるチューブなどの容器から出し難くなる問題点を示唆及び解決させるものではなかった。
特開平9−100212号公報 特許第3217357号公報
There is no satisfactory solution for such a problem yet, and the current situation is that the individual prescription is urgently dealt with by trial and error in the formulation research. In addition, detergents and cosmetics have a prior art containing dipotassium glycyrrhizinate or potassium acetate with respect to stabilization and thickening of the system. However, Patent Document 1 is a patent relating to the solidification stability of water-based solidified cosmetics, which contains dipotassium glycyrrhizinate as a solidifying component, and is a fatty acid soap-based cream facial cleanser. There is no suggestion regarding prevention of temperature-dependent viscosity increase with time. Further, Patent Document 2 is a system stabilization technique related to a liquid cleaning composition, and no description suggesting any fatty acid soap-based cream facial cleansing is found. Therefore, it has not suggested or solved the problem that it becomes difficult to remove from a container such as a tube due to the temperature-dependent viscosity increase with time.
Japanese Patent Laid-Open No. 9-100212 Japanese Patent No. 3217357

本発明の課題は、脂肪酸石けん系クリーム状洗顔料組成物において、温度依存性経時粘度上昇を防止し、如何なる環境化においても温度依存性経時粘度上昇が少なく、使用性に優れた新規脂肪酸石けん系クリーム状洗顔料の提供することである。   The object of the present invention is to provide a fatty acid soap-based cream facial cleansing composition that prevents temperature-dependent viscosity increase with time, has little temperature-dependent viscosity increase in any environment, and is a novel fatty acid soap that is excellent in usability It is to provide a creamy facial cleanser.

本発明者らは、鋭意研究の結果、脂肪酸石けん系クリーム状洗顔料組成物において、グリチルリチン酸ジカリウム及び/又は酢酸カリウムが温度依存性粘度上昇を防ぐ効果を有することを見出し、本発明に至った。即ち、脂肪酸石けん系クリーム状洗顔料組成物にグリチルリチン酸ジカリウム及び/又は酢酸カリウムを含有させることにより、如何なる環境化においても温度依存性経時粘度上昇が少なく、使用性に優れた新規脂肪酸石けん系クリーム状洗顔料の提供を可能とした。   As a result of diligent research, the present inventors have found that dipotassium glycyrrhizinate and / or potassium acetate has an effect of preventing temperature-dependent viscosity increase in a fatty acid soap-based cream facial cleansing composition, and has led to the present invention. . That is, by adding dipotassium glycyrrhizinate and / or potassium acetate to a fatty acid soap-based cream facial cleansing composition, a temperature-dependent viscosity increase with time is small in any environment, and a novel fatty acid soap-based cream excellent in usability It was possible to provide a facial cleanser.

本発明によれば、安定性に優れる新規脂肪酸石けん系クリーム状洗顔料組成物を提供することができる。とりわけ30℃以上の高温環境下で長期間保存された後、常温から低温環境下のもとで使用する場合、粘度上昇によりチューブ容器から出し難くくなるという問題を防止することができ、如何なる環境化においても温度依存性経時粘度上昇が少なく、使用性に優れた新規脂肪酸石けん系クリーム状洗顔料の提供を可能とした。   ADVANTAGE OF THE INVENTION According to this invention, the novel fatty-acid soap type cream face wash composition excellent in stability can be provided. In particular, after being stored for a long time in a high temperature environment of 30 ° C. or higher, when used under a normal temperature to a low temperature environment, it is possible to prevent the problem that it becomes difficult to remove from the tube container due to an increase in viscosity. In addition, the temperature-dependent viscosity increase with time was small, and it was possible to provide a novel fatty acid soap-based cream facial cleanser with excellent usability.

本発明に用いるグリチルリチン酸ジカリウムは、一般式(I)で表わされるものであれば特に限定はされない。また、好ましい含有量は洗顔料組成物全量に対して、0.025〜0.5重量%であり、特に好ましくは、0.05〜0.3重量%である。   The dipotassium glycyrrhizinate used in the present invention is not particularly limited as long as it is represented by the general formula (I). Moreover, preferable content is 0.025 to 0.5 weight% with respect to the face-washing composition whole quantity, Most preferably, it is 0.05 to 0.3 weight%.

本発明に用いる酢酸カリウムは、一般式(II)で表わされるものであれば特に限定はされない。また、好ましい含有量は、洗顔料組成物全量に対して、0.001〜1.0重量%であり、特に好ましくは、0.025〜0.5重量%である。 The potassium acetate used in the present invention is not particularly limited as long as it is represented by the general formula (II). Moreover, preferable content is 0.001-1.0 weight% with respect to the face wash composition whole quantity, Most preferably, it is 0.025-0.5 weight%.

本発明の組成物には、前述の脂肪酸に加えて、必要に応じて、本発明の効果を損なわない範囲で化粧料に一般に用いられる各種成分、例えば、油性成分、界面活性剤、保湿剤、酸化防止剤、防腐剤、増粘剤等々を配合することができる。   In the composition of the present invention, in addition to the above-mentioned fatty acids, if necessary, various components generally used in cosmetics within a range not impairing the effects of the present invention, for example, oily components, surfactants, humectants, Antioxidants, preservatives, thickeners and the like can be blended.

以下、実施例を挙げて本発明を具体的に説明する。なお、本発明はこれに限定されるものではない。   Hereinafter, the present invention will be specifically described with reference to examples. Note that the present invention is not limited to this.

表1に示す成分にて、本発明の洗顔料組成物である実施例1〜実施例4を調整した。同時に、この実施例の洗顔料組成物よりグリチルリチン酸ジカリウム及び酢酸カリウムを除いた処方にて比較例1を調製した。   With the components shown in Table 1, Examples 1 to 4 which are the facial cleansing compositions of the present invention were prepared. At the same time, Comparative Example 1 was prepared with a formulation in which dipotassium glycyrrhizinate and potassium acetate were removed from the face wash composition of this example.

実施例1〜実施例4及び比較例1の洗顔料の処方例を表1に示す。なお、洗顔料は通常の製法にて製造し、試料を得た。   Table 1 shows formulation examples of the face wash of Examples 1 to 4 and Comparative Example 1. In addition, the face wash was manufactured by the normal manufacturing method, and the sample was obtained.

実施例1〜実施例4及び比較例1を40℃1ヶ月の保存試験にかけ、段落0019の評価基準にて評価した。なお、粘度測定は30℃条件下に4時間静置した後測定した。   Examples 1 to 4 and Comparative Example 1 were subjected to a storage test at 40 ° C. for one month and evaluated according to the evaluation criteria in paragraph 0019. The viscosity was measured after standing for 4 hours at 30 ° C.

〔評価基準〕
◎:0〜2Pa・sの範囲で上昇、あるい減少する。
○:3〜5Pa・sの範囲で上昇する。
△:6〜8Pa・sの範囲で上昇する。
×:9〜11Pa・sの範囲で上昇する。
××:12Pa・s以上上昇する。
〔Evaluation criteria〕
A: Increases or decreases in the range of 0 to 2 Pa · s.
○: Increased in the range of 3 to 5 Pa · s.
(Triangle | delta): It raises in the range of 6-8 Pa.s.
X: It rises in the range of 9-11 Pa.s.
XX: Increased by 12 Pa · s or more.

実施例1〜実施例4は、比較例1に比べ温度による粘度変化が少なかった。これにより、本発明の洗顔料組成物が、グリチルリチン酸ジカリウム又は酢酸カリウムが含まれていない比較例1と比べ、温度依存性経時粘度上昇を防止する効果を有していることが判る。このことは、脂肪酸石けん系クリーム状洗顔料組成物において、グリチルリチン酸ジカリウム又は酢酸カリウムを含有させることで、温度依存性経時粘度上昇が無い洗顔料を提供することができることを示している。 In Examples 1 to 4, the viscosity change due to temperature was smaller than that in Comparative Example 1. Thereby, it turns out that the face-washing composition of this invention has the effect which prevents a temperature dependent viscosity rise with time compared with the comparative example 1 which does not contain dipotassium glycyrrhizinate or potassium acetate. This indicates that a fatty acid soap-based cream facial cleansing composition can provide a facial cleansing that does not have a temperature-dependent increase in viscosity over time by containing dipotassium glycyrrhizinate or potassium acetate.

更に、実施例1〜実施例4及び比較例1を用いて、40℃1週間の保存試験にかけ、5℃に4時間静置した後、チューブ容器からの使用性試験(「チューブからの出し易さ試験」)を行なった。なお、本試験の評価は段落0022に記載の評価基準により専門パネラーが判定し、その結果を表1に示した。   Furthermore, it was subjected to a storage test at 40 ° C. for 1 week using Examples 1 to 4 and Comparative Example 1, and after standing at 5 ° C. for 4 hours, a usability test from a tube container (“Easy to remove from tube” Satisfaction test) was conducted. The evaluation of this test was determined by a specialized panel according to the evaluation criteria described in paragraph 0022, and the results are shown in Table 1.

〔評価基準〕
◎:出し易い。
○:違和感なく出すことができる。
△:やや出し難い。
×:出し難い。
××:非常に出し難い。
〔Evaluation criteria〕
A: Easy to take out.
○: Can be produced without a sense of incongruity
Δ: Slightly difficult to produce
X: It is difficult to put out.
XX: It is very difficult to take out.

その結果、チューブ容器からの使用性について、チューブからの出し易さの評価を行なったところ、実施例はチューブからの出し易さに問題はなかったのに対し、比較例は顕著にチューブ容器から出し難いことが認められた。これにより、特に高温から低温環境に移行させた時の固化によりチューブ容器から出しにくくなるという問題を防止することができるものであることが判る。   As a result, the ease of taking out from the tube was evaluated for usability from the tube container, while the example had no problem with the ease of taking out from the tube, whereas the comparative example was noticeably from the tube container. It was recognized that it was difficult to put out. Thereby, it turns out that the problem that it becomes difficult to take out from a tube container by solidification especially when making it transfer to high temperature environment from low temperature can be prevented.

本発明は、温度依存性経時粘度変化の少ない洗顔料組成物である為、化粧料や洗浄料に広く応用が期待できる。
Since the present invention is a face wash composition with little temperature-dependent viscosity change with time, it can be widely applied to cosmetics and cleaning products.

Claims (1)

グリチルリチン酸ジカリウム及び/又は酢酸カリウムを含有することを特徴とする、炭素数がC12〜C18の脂肪酸石けんで構成される洗顔料組成物。 A facial cleansing composition comprising a fatty acid soap having C12 to C18, which contains dipotassium glycyrrhizinate and / or potassium acetate.
JP2007089934A 2007-03-29 2007-03-29 Face-cleansing cosmetic composition Pending JP2008247782A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109825386A (en) * 2019-01-29 2019-05-31 丰益油脂科技(东莞)有限公司 A kind of neat soap and environment-friendly soap containing Organic grape sodium saccharate

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63154616A (en) * 1986-12-17 1988-06-27 Lion Corp Creamy or liquid skin detergent composition and production thereof
JP2001072573A (en) * 1999-09-02 2001-03-21 Pola Chem Ind Inc Cosmetic for face washing
JP2001072574A (en) * 1999-09-02 2001-03-21 Pola Chem Ind Inc Cosmetic for face cleansing
JP3217357B2 (en) * 1991-03-05 2001-10-09 ザ、プロクター、エンド、ギャンブル、カンパニー Liquid soap cosmetic detergent
JP2002356417A (en) * 2001-05-30 2002-12-13 Tsumura & Co Liquid body cleanser
JP2005298455A (en) * 2004-04-16 2005-10-27 Kanebo Cosmetics Inc Skin cleanser
JP2007008881A (en) * 2005-06-30 2007-01-18 Kanebo Cosmetics Inc Skin cleansing agent

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63154616A (en) * 1986-12-17 1988-06-27 Lion Corp Creamy or liquid skin detergent composition and production thereof
JP3217357B2 (en) * 1991-03-05 2001-10-09 ザ、プロクター、エンド、ギャンブル、カンパニー Liquid soap cosmetic detergent
JP2001072573A (en) * 1999-09-02 2001-03-21 Pola Chem Ind Inc Cosmetic for face washing
JP2001072574A (en) * 1999-09-02 2001-03-21 Pola Chem Ind Inc Cosmetic for face cleansing
JP2002356417A (en) * 2001-05-30 2002-12-13 Tsumura & Co Liquid body cleanser
JP2005298455A (en) * 2004-04-16 2005-10-27 Kanebo Cosmetics Inc Skin cleanser
JP2007008881A (en) * 2005-06-30 2007-01-18 Kanebo Cosmetics Inc Skin cleansing agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109825386A (en) * 2019-01-29 2019-05-31 丰益油脂科技(东莞)有限公司 A kind of neat soap and environment-friendly soap containing Organic grape sodium saccharate

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