CN109796809A - A kind of writing charcoal liquid and preparation method thereof - Google Patents
A kind of writing charcoal liquid and preparation method thereof Download PDFInfo
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- CN109796809A CN109796809A CN201910118901.3A CN201910118901A CN109796809A CN 109796809 A CN109796809 A CN 109796809A CN 201910118901 A CN201910118901 A CN 201910118901A CN 109796809 A CN109796809 A CN 109796809A
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Abstract
The invention belongs to prepared Chinese ink technical fields, disclose a kind of writing charcoal liquid, formula are as follows: gelatine, hide glue, carbon ink, borneol, sodium benzoate, sodium lignin sulfonate, nano diatomite, water.Each component compatibility of the present invention is reasonable, preparation process simple possible, and the writing charcoal liquid comprehensive performance of preparation is high, is suitble to large-scale production.
Description
Technical field
The invention belongs to prepared Chinese ink technical fields, and in particular to a kind of writing charcoal liquid and preparation method thereof.
Background technique
The primary raw material of prepared Chinese ink is soot, sizing material, additive and solution etc., is generally process via mechanical.Soot
It is many kinds of, including various mine plants and animal material burnt or thermally decomposed.Glue then in addition to animal glue, adopts plant more
Glue (Arabic gum) or various rubber polymers such as acryl glue, polyalcohols resin etc..Additive then has various stabilizer, bleeding agent, wet
Moisten agent, preservative, aromatic etc..The main method for preparing prepared Chinese ink includes conventional method and modernism.Currently, commercially available ink
The generally existing shortcomings of juice: writing blackness, brightness are not high enough, it is difficult to meet artist and want to high-quality artistic work creation
It asks, and prepared Chinese ink stability is poor, is also easy to produce precipitating, it is difficult to which freezeout easily occur in long-term preservation, when low temperature.
CN105219157A is related to a kind of calligraphy prepared Chinese ink in the prior art, consisting of 1-5 parts of colour carbon black, water-reducing agent
0.2-0.5 parts, it is 40-60 parts of carrier, 50 parts of water, 1-5 parts of adhesive, 0.1-0.2 parts of surfactant, 0-0.1 parts of preservative, sweet
0-0.3 parts oily, the above component is uniformly mixed.The present invention can use brush writing, it is also possible to which container is poured on paper and writes；Its
Preparation method is simple, but the holding time is shorter, has precipitating and generates, and intolerant to jelly.Currently, prepared Chinese ink available on the market is big
There are various technical problems more, needs to improve the prepared Chinese ink of the prior art.
Summary of the invention
The present invention develops new product-calligraphy charcoal liquid according to the national policy of students in middle and primary schools' " calligraphy entering classrooms ".This charcoal liquid
On the basis of traditional handicraft, the principle performance of glue is improved, blends with water, is well arranged, has the characteristics that old ink stick is write, charcoal
Liquid ink flat flavor, fluent writing, not only can be used for pen writing, but also can be used for brush writing, to popularize students in middle and primary schools' calligraphy
Education, whole people's calligraphy provide convenience.The research and development of this charcoal liquid build up the business for Chinese ink processed and improve one layer of new frame, winter
It can be antifreeze, does not influence to use.
The present invention is achieved by the following technical solution.
A kind of writing charcoal liquid, formula are as follows: gelatine, hide glue, carbon ink, borneol, sodium benzoate, sodium lignin sulfonate, nanometer
Diatomite, water.
Further,
The formula for writing charcoal liquid are as follows: gelatine 50Kg, hide glue 50Kg, carbon ink 100Kg, borneol 1Kg, sodium benzoate 1Kg are wooden
Plain sodium sulfonate 1Kg, nano diatomite 1Kg, water 796Kg.
Further,
The preparation method for writing charcoal liquid includes the following steps: that step 1) boils, step 2 stirring, step 3) grinding, step
4) disperse.
Further,
The preparation method for writing charcoal liquid includes the following steps:
Step 1) tanning: being put into gelatine 50Kg, hide glue 50Kg in electrothermal reaction kettle, and 150 Kg water are added and carry out tanning 4 hours,
Obtain glue；
Step 2 stirring: glue 150Kg is taken out from reaction kettle, with carbon black 100Kg with the speed of 100-400rpm in agitator tank
Degree is stirred 30 minutes, adds borneol 1Kg, sodium lignin sulfonate 1Kg and nano diatomite 1Kg, continues 10 points of stirring
Clock stops stirring, then arrest reaction 6 hours；
Step 3) grinding: after reaction 6 hours, being ground with grinder, and milling time is 4 hours or so；
The feed liquid ground: being added to dispersion machine by step 4) dispersion, and glue remaining in reaction kettle is added to point together
Machine is dissipated, then sodium benzoate 1Kg is added to dispersion machine, with 500rpm stirring 20-30 minutes, feed liquid is sufficiently stirred finely, so
Remaining water is added in dispersion machine afterwards, is continued with 500rpm stirring 2 hours.
Preferably, the tanning temperature control is at 70-100 DEG C.
Compared with prior art, the present invention has the advantages that following but be not restricted to that the following aspects:
Each component compatibility of the present invention is reasonable, preparation process simple possible, is suitble to large-scale production；
The present invention carries out compatible use using gelatine and hide glue, blends with water, well arranged, and stability is high；
Suitable nano diatomite can increase adsorption capacity, increase the absorption with paper, avoid dizzy dye, be also equipped with certain corrosion resistant
Function is lost, the addition of preservative is reduced, environmental protection is harmless to the body, reduces cost；
Suitable sodium lignin sulfonate dispersibility and chelating ability are preferable, can be improved adhesiveness, improve mobility, so that ink marks
It is uniformly dispersed, and effect can be crosslinked with colloid, improve compactness；
This charcoal liquid improves the principle performance of glue on the basis of traditional handicraft, blends with water, is well arranged, there is old ink stick to write
The characteristics of, charcoal liquid ink flat flavor, fluent writing not only can be used for pen writing, but also can be used for brush writing, in universal
Pupil's calligraphy education, whole people's calligraphy provide convenience；The research and development of this charcoal liquid build up the business for Chinese ink processed and improve one layer
New frame, winter can be antifreeze, do not influence to use.
Present invention writing charcoal liquid room temperature, which is sealed, will not generate precipitating for 24 months, and each performance indicator does not change, and meets water
It will not dizzy dye.
Specific embodiment
In order to keep the purposes, technical schemes and advantages of the embodiment of the present invention clearer, implement below in conjunction with the present invention
Technical solution in example carries out clear, complete description, it is clear that and described embodiment is section Example of the invention, and
It is not all of embodiment.Based on the embodiment of the present invention, those of ordinary skill in the art are not before making the creative labor
Every other embodiment obtained is put, protection scope of the present invention is belonged to.
Therefore, requirement is not intended to limit to the detailed description of the embodiment of the present invention provided in embodiment below to protect
The scope of the present invention of shield, but it is merely representative of selected embodiment of the invention.Based on the embodiments of the present invention, this field is general
Logical technical staff every other embodiment obtained without creative efforts, belongs to protection of the present invention
Range.
Embodiment 1
A kind of writing charcoal liquid, formula are as follows: gelatine 50Kg, hide glue 50Kg, carbon ink 100Kg, borneol 1Kg, sodium benzoate 1Kg, wood
Quality sodium sulfonate 1Kg, nano diatomite 1Kg, water 796Kg.
The preparation method for writing charcoal liquid includes the following steps:
1) gelatine 50Kg, hide glue 50Kg are put into electrothermal reaction kettle, 150 Kg water are added and carry out tanning 4 hours, obtain glue,
Temperature is controlled at 75 DEG C；
2) 30 points are stirred from taking-up glue 150Kg and speed of the carbon black 100Kg in agitator tank with 200rpm in reaction kettle
Clock adds borneol 1Kg, sodium lignin sulfonate 1Kg and nano diatomite 1Kg, continues stirring 10 minutes, stops stirring, so
Arrest reaction 6 hours afterwards；
3) it after reacting 6 hours, is ground with grinder, milling time is 4 hours or so；
4) feed liquid ground is added to dispersion machine, and glue remaining in reaction kettle is added to dispersion machine together, then
Sodium benzoate 1Kg is added to dispersion machine, with 500rpm stirring 20 minutes, feed liquid is sufficiently stirred finely, then remaining water
It is added in dispersion machine, continues with 500rpm stirring 2 hours.
The present invention writes charcoal liquid, names are as follows: Jin Mofang charcoal liquid.
Testing graininess: it is tested with laser particle analyzer；Average grain diameter is 197nm；Particle diameter distribution is uniform, is distributed in 100-
Between 500nm.
Comparative example 1
Hide glue is not used, gelatine additive amount is 100Kg, remaining is the same as embodiment 1.
Comparative example 2
Gelatine is not used, hide glue additive amount is 100Kg, remaining is the same as embodiment 1.
Comparative example 3
Sodium lignin sulfonate is not used, remaining is the same as embodiment 1.
Comparative example 4
Nano diatomite is not used, remaining is the same as embodiment 1.
Embodiment 2
By embodiment 1, comparative example 1-4 and commercially available prepared Chinese ink (one obtains pavilion) are tested.
One, testing standard: referring to the People's Republic of China's light industry standard QB/T2860-2007.
Specific performance parameter is shown in Table 1:
Table 1
| Group | Water resistance | Diffusivity | Anti-corrosive properties |
| Embodiment 1 | After for 24 hours, no race ink | Free of glue spots, watermark, diffusion are uniform | Without mildew and corrupt smell |
| Comparative example 1 | After for 24 hours, no race ink | Slight gum spot, watermark, diffusion are uniform | Without mildew and corrupt smell |
| Comparative example 2 | It is slight to run ink after for 24 hours | Free of glue spots, watermark, diffusion are uniform | Without mildew and corrupt smell |
| Comparative example 3 | After for 24 hours, no race ink | Free of glue spots, watermark, diffusion are uneven | Without mildew and corrupt smell |
| Comparative example 4 | After for 24 hours, no race ink | Slight gum spot, watermark, diffusion are uneven | Without mildew and corrupt smell |
| Commercially available prepared Chinese ink | After for 24 hours, micro- race ink | Free of glue spots, watermark, diffusion are uniform | Without mildew and corrupt smell |
Two, stability and anti-freezing property test, are specifically shown in Table 2.
Table 2
| Group | Stability (6 months) room temperature | Stability (24 months) room temperature | Frost resistance |
| Embodiment 1 | Without precipitating | Without precipitating | 0 DEG C is not freezed |
| Comparative example 1 | Without precipitating | A small amount of precipitating | 0 DEG C is not freezed |
| Comparative example 2 | Without precipitating | A small amount of precipitating | 0 DEG C is not freezed |
| Comparative example 3 | Without precipitating | Without precipitating | 0 DEG C of consistency increases on a small quantity |
| Comparative example 4 | Without precipitating | Without precipitating | 0 DEG C is not freezed |
| Commercially available prepared Chinese ink | Without precipitating | A small amount of precipitating | 0 DEG C of consistency increases on a small quantity |
Conclusion: by table 1-2 data it is found that water resistance, diffusivity, anticorrosion, the stability of the writing charcoal liquid of the embodiment of the present invention 1
And anti-freezing property is prominent, is better than comparative example 1-4 and commercially available prepared Chinese ink, illustrates each component and component ratio that the present invention uses
Rationally, preparation process is simple, has preferable market popularization value for example collocation.
The above description of the embodiment is only used to help understand the method for the present invention and its core ideas.It should be pointed out that pair
For those skilled in the art, without departing from the principle of the present invention, the present invention can also be carried out
Some improvements and modifications, these improvements and modifications also fall within the scope of protection of the claims of the present invention.
Claims (5)
1. a kind of writing charcoal liquid, formula are as follows: gelatine, hide glue, carbon ink, borneol, sodium benzoate, sodium lignin sulfonate, nano-silicon
Diatomaceous earth, water.
2. writing charcoal liquid according to claim 1, which is characterized in that the formula for writing charcoal liquid are as follows: gelatine 50Kg, skin
Glue 50Kg, carbon ink 100Kg, borneol 1Kg, sodium benzoate 1Kg, sodium lignin sulfonate 1Kg, nano diatomite 1Kg, water 796Kg.
3. writing charcoal liquid according to claim 2, which is characterized in that the preparation method for writing charcoal liquid includes following step
It is rapid: step 1) tanning, step 2 stirring, step 3) grinding, step 4) dispersion.
4. writing charcoal liquid according to claim 3, which is characterized in that the preparation method for writing charcoal liquid includes following step
It is rapid:
Step 1) tanning: being put into gelatine 50Kg, hide glue 50Kg in electrothermal reaction kettle, and 150 Kg water are added and carry out tanning 4 hours,
Obtain glue；
Step 2 stirring: glue 150Kg is taken out from reaction kettle, with carbon black 100Kg with the speed of 100-400rpm in agitator tank
Degree is stirred 30 minutes, adds borneol 1Kg, sodium lignin sulfonate 1Kg and nano diatomite 1Kg, continues 10 points of stirring
Clock stops stirring, then arrest reaction 6 hours；
Step 3) grinding: after reaction 6 hours, being ground with grinder, and milling time is 4 hours or so；
The feed liquid ground: being added to dispersion machine by step 4) dispersion, and glue remaining in reaction kettle is added to point together
Machine is dissipated, then sodium benzoate 1Kg is added to dispersion machine, with 500rpm stirring 20-30 minutes, feed liquid is sufficiently stirred finely, so
Remaining water is added in dispersion machine afterwards, is continued with 500rpm stirring 2 hours.
5. writing charcoal liquid according to claim 3, which is characterized in that the tanning temperature control is at 70-100 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910118901.3A CN109796809A (en) | 2019-02-18 | 2019-02-18 | A kind of writing charcoal liquid and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910118901.3A CN109796809A (en) | 2019-02-18 | 2019-02-18 | A kind of writing charcoal liquid and preparation method thereof |
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| Publication Number | Publication Date |
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| CN109796809A true CN109796809A (en) | 2019-05-24 |
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ID=66560965
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| CN201910118901.3A Pending CN109796809A (en) | 2019-02-18 | 2019-02-18 | A kind of writing charcoal liquid and preparation method thereof |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798478A (en) * | 2010-03-11 | 2010-08-11 | 齐成森 | Leftover ink |
| CN102492332A (en) * | 2011-12-05 | 2012-06-13 | 天津市鸵鸟墨水有限公司 | Novel ink and production method thereof |
| CN102533003A (en) * | 2012-03-01 | 2012-07-04 | 黄山市歙县聚墨堂墨业有限公司 | Non-cracking ink |
| CN104559391A (en) * | 2014-12-19 | 2015-04-29 | 天津市天津墨水厂 | Colorful ink composition and preparation method thereof for traditional Chinese paintings |
| CN105219157A (en) * | 2015-11-06 | 2016-01-06 | 赵方琦 | A kind of calligraphy prepared Chinese ink |
| CN107043573A (en) * | 2017-03-17 | 2017-08-15 | 四会市恒星智能科技有限公司 | A kind of water resistance prepared Chinese ink and preparation method thereof |
| CN108912833A (en) * | 2018-08-23 | 2018-11-30 | 蚌埠市奥特纸箱机械有限公司 | A kind of corrugated paper printing ink |
-
2019
- 2019-02-18 CN CN201910118901.3A patent/CN109796809A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798478A (en) * | 2010-03-11 | 2010-08-11 | 齐成森 | Leftover ink |
| CN102492332A (en) * | 2011-12-05 | 2012-06-13 | 天津市鸵鸟墨水有限公司 | Novel ink and production method thereof |
| CN102533003A (en) * | 2012-03-01 | 2012-07-04 | 黄山市歙县聚墨堂墨业有限公司 | Non-cracking ink |
| CN104559391A (en) * | 2014-12-19 | 2015-04-29 | 天津市天津墨水厂 | Colorful ink composition and preparation method thereof for traditional Chinese paintings |
| CN105219157A (en) * | 2015-11-06 | 2016-01-06 | 赵方琦 | A kind of calligraphy prepared Chinese ink |
| CN107043573A (en) * | 2017-03-17 | 2017-08-15 | 四会市恒星智能科技有限公司 | A kind of water resistance prepared Chinese ink and preparation method thereof |
| CN108912833A (en) * | 2018-08-23 | 2018-11-30 | 蚌埠市奥特纸箱机械有限公司 | A kind of corrugated paper printing ink |
Non-Patent Citations (3)
| Title |
|---|
| 吴来明等: "古墨保存自然老化问题的调查研究", 《文物保护与考古科学》 * |
| 孙宏哲: "《木工粘接技术》", 31 December 1985, 中国建筑工业出版社 * |
| 金锐: "《建材农用生产资料》", 31 August 1993, 中国计量出版社 * |
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Application publication date: 20190524 |