CN111410868A - Erasable water-based paint ink for marker pen and preparation method thereof - Google Patents
Erasable water-based paint ink for marker pen and preparation method thereof Download PDFInfo
- Publication number
- CN111410868A CN111410868A CN202010284387.3A CN202010284387A CN111410868A CN 111410868 A CN111410868 A CN 111410868A CN 202010284387 A CN202010284387 A CN 202010284387A CN 111410868 A CN111410868 A CN 111410868A
- Authority
- CN
- China
- Prior art keywords
- water
- percent
- paint ink
- erasable
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000003973 paint Substances 0.000 title claims abstract description 19
- 239000003550 marker Substances 0.000 title claims description 15
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 8
- 239000002270 dispersing agent Substances 0.000 claims abstract description 8
- 239000003906 humectant Substances 0.000 claims abstract description 8
- 239000003755 preservative agent Substances 0.000 claims abstract description 8
- 238000009736 wetting Methods 0.000 claims abstract description 8
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 6
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 6
- 230000002335 preservative effect Effects 0.000 claims abstract description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 3
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 3
- 229920000570 polyether Polymers 0.000 claims abstract description 3
- 238000003756 stirring Methods 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 15
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000003607 modifier Substances 0.000 claims description 2
- 239000008399 tap water Substances 0.000 claims description 2
- 235000020679 tap water Nutrition 0.000 claims description 2
- 239000002671 adjuvant Substances 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 239000011521 glass Substances 0.000 abstract description 7
- 238000001035 drying Methods 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 239000004744 fabric Substances 0.000 abstract description 4
- 230000036541 health Effects 0.000 abstract description 3
- 231100000956 nontoxicity Toxicity 0.000 abstract description 3
- 241001122767 Theaceae Species 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 31
- 238000005562 fading Methods 0.000 description 8
- 239000003086 colorant Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000123 paper Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
Abstract
An erasable water-based paint ink for a mark pen and a preparation method thereof comprise the following components in percentage by mass: 15-40% of water; 0.1 to 0.5 percent of defoaming agent; 0.3 to 1 percent of wetting dispersant; 5-15% of water-based acrylic resin; 5-15% of waterborne polyurethane resin; 30-80% of water-based color paste; 0.1 to 0.3 percent of preservative; 3-6% of a humectant; 0.1 to 1 percent of anti-settling agent; 0.05 to 10 percent of other auxiliary agents; the aqueous polyurethane resin is aqueous aliphatic polyether polyurethane resin. The erasable water-based paint ink for the mark pen can be erased by dry cloth after being written on smooth surfaces such as glass and the like, and has the characteristics of strong covering power, good sun resistance, good water resistance and high drying speed; the environment-friendly and nontoxic environment-friendly tea also has the advantages of environmental protection and no toxicity, and is very friendly to the environment and the health of consumers.
Description
Technical Field
The invention relates to the technical field of ink, in particular to erasable water-based paint ink for a mark pen and a preparation method thereof.
Background
At present, ink for marker pens in the market is mainly divided into erasable ink and non-erasable ink, wherein the erasable ink mainly comprises white board pen ink, and the white board pen ink can be easily erased after being written on a smooth surface. However, the white board marker has poor covering ability and water resistance of ink, and has few colors (generally, four colors of black, red, blue and green), so the white board marker can only be used for writing on a white board, and the application range is narrow.
The indelible ink mainly comprises paint pen ink which has good covering capability and stability and wide application range. However, the ink of the existing paint pen cannot be erased without a solvent after being written on a smooth surface such as glass.
Disclosure of Invention
In view of the above problems, an object of the present invention is to provide an erasable aqueous paint ink for a marker, which is easily erased with a dry cloth after writing on a smooth surface such as glass, and which has the characteristics of strong covering power, good light fastness, good water resistance and high drying speed.
In order to achieve the purpose, the invention adopts the technical scheme that:
an erasable water-based paint ink for a mark pen, which is characterized in that:
comprises the following components in percentage by mass: 15-40% of water; 0.1 to 0.5 percent of defoaming agent; 0.3 to 1 percent of wetting dispersant; 5-15% of water-based acrylic resin; 5-15% of waterborne polyurethane resin; 30-80% of water-based color paste; 0.1 to 0.3 percent of preservative; 3-6% of a humectant; 0.1 to 1 percent of anti-settling agent; 0.05 to 10 percent of other auxiliary agents.
Preferably, the aqueous polyurethane resin is an aqueous aliphatic polyether polyurethane resin.
Preferably, the water is any one of pure water, deionized water or tap water.
Preferably, the humectant is any one or combination of glycerin, propylene glycol and 1, 3-butanediol.
Preferably, the water-based color paste is water-based color paste with any color.
Preferably, the wetting dispersant is BYK-190; the anti-settling agent is AQ-633E; the defoaming agent is BYK-024; the preservative was Troy Mergal K9N.
Preferably, the other auxiliary agents include, but are not limited to, leveling agents, co-solvents, PH modifiers.
The invention also discloses a preparation method of the erasable water paint ink for marker pens, which comprises the following steps:
(1) adding water into a dispersing device, sequentially adding a defoaming agent and a wetting dispersant under low-speed stirring, and continuously stirring for 10 minutes until the mixture is uniformly stirred;
(2) then adding the waterborne acrylic resin and the waterborne polyurethane resin under low-speed stirring, and continuously stirring for 10 minutes until the mixture is uniformly stirred;
(3) then adding the anti-settling agent and the water-based color paste in sequence under low-speed stirring, and stirring at a high speed for 30 minutes until the mixture is completely and uniformly stirred;
(4) finally adding the mixture in turn under low-speed stirringPreservativeThe humectant and other auxiliary agents are continuously stirred for 10 minutes until the mixture is uniformly stirred;
the low speed is 400-600RPM, and the high speed is 800-1200 RPM.
Compared with the prior art, the invention has the following beneficial effects:
1. the covering power is strong, and the covering power is good on a dark color base material or a light color base material;
2. the sun resistance is good, and the color of the product is not faded after being tested by 24hrs ultraviolet irradiation;
3. the water resistance is good, and the color of the product is not faded after passing a 24hrs water resistance test;
4. the drying speed is high, and the drying time of the glass surface after writing is less than 4 minutes;
5. the erasability is good, and after writing on smooth surfaces such as glass and the like, the erasability can be erased by dry cloth;
6. no smell, environmental protection, no toxicity and environmental and health protection.
Detailed Description
It should be noted that the raw materials used in the technical scheme provided by the present invention, except for the specific description, are prepared by conventional means or purchased through commercial channels.
Examples 1, 2, 3, 4 respectively comprise the following components in mass percent:
the method of making the erasable aqueous paint ink for a marker of examples 1-4 above, comprising the steps of:
(1) adding water into a dispersing device, sequentially adding a defoaming agent and a wetting dispersant under low-speed stirring, and continuously stirring for 10 minutes until the mixture is uniformly stirred;
(2) then adding the waterborne acrylic resin and the waterborne polyurethane resin under low-speed stirring, and continuously stirring for 10 minutes until the mixture is uniformly stirred;
(3) then adding the anti-settling agent and the water-based color paste in sequence under low-speed stirring, and stirring at a high speed for 30 minutes until the mixture is completely and uniformly stirred;
(4) finally adding the mixture in turn under low-speed stirringPreservativeThe humectant and other auxiliary agents are continuously stirred for 10 minutes until the mixture is uniformly stirred;
the low speed is 400-600RPM, and the high speed is 800-1200 RPM.
The dispersing equipment used in the method can be common equipment such as a high-speed disperser, a stirrer, a mixer and the like.
Inks 1, 2, 3, 4 prepared in examples 1, 2, 3, 4, respectively, had the following characteristics:
1. the prepared ink has rich colors and can be mixed according to the requirement.
2. The covering power is strong, and the covering power is good on a dark color and light color base material. (test method: writing on white and black cardboard respectively, observing whether the ground color can be covered after the writing is dried.)
3. The light fastness is good, and the test of 24hrs ultraviolet irradiation can be passed.
| Ink 1 | Ink 2 | Ink 3 | Ink 4 | |
| Light fastness | No fading | No fading | No fading | No fading |
4. The water resistance is good, and the water resistance can pass a 24-hrs water resistance test (test method: 5 consecutive circles with a diameter of 20-30 mm are drawn on the writing paper, after 1min, the writing paper is immersed in distilled water for 24hrs, and is taken out and naturally dried, and whether the trace fades or not is checked).
| Ink 1 | Ink 2 | Ink 3 | Ink 4 | |
| Water resistance | No fading | No fading | No fading | No fading |
5. Fast drying (writing medium: glass, test conditions: 23 ℃, 60% RH)
| Ink 1 | Ink 2 | Ink 3 | Ink 4 | |
| Drying Property | <3.5mins | <4mins | <3.5mins | <3.5mins |
6. Erasability (writing medium: glass, erased with dry cloth after 0.5 hour, 1 hour, 4 hours, 8 hours, 24 hours after writing).
7. No smell, environmental protection, no toxicity and environmental and health protection.
The technical solutions provided by the embodiments of the present invention are described in detail above, and the principles and embodiments of the present invention are explained herein by using specific examples, and the descriptions of the embodiments are only used to help understanding the principles of the embodiments of the present invention; meanwhile, for a person skilled in the art, according to the embodiments of the present invention, there may be variations in the specific implementation manners and application ranges, and in summary, the content of the present description should not be construed as a limitation to the present invention.
Claims (8)
1. An erasable water-based paint ink for a mark pen, which is characterized in that: the composite material comprises the following components in percentage by mass:
15-40% of water; 0.1 to 0.5 percent of defoaming agent; 0.3 to 1 percent of wetting dispersant; 5-15% of water-based acrylic resin; 5-15% of waterborne polyurethane resin; 30-80% of water-based color paste; 0.1 to 0.3 percent of preservative; 3-6% of a humectant; 0.1 to 1 percent of anti-settling agent; 0.05 to 10 percent of other auxiliary agents.
2. An erasable aqueous paint ink for a marker pen as claimed in claim 1, wherein: the aqueous polyurethane resin is aqueous aliphatic polyether polyurethane resin.
3. An erasable aqueous paint ink for a marker pen as claimed in claim 1, wherein: the water is any one of pure water, deionized water or tap water.
4. An erasable aqueous paint ink for a marker pen as claimed in claim 1, wherein: the humectant is any one or combination of glycerol, propylene glycol and 1, 3-butanediol.
5. An erasable aqueous paint ink for a marker pen as claimed in claim 1, wherein: the water-based color paste is any color.
6. An erasable aqueous paint ink for a marker pen as claimed in claim 1, wherein: the wetting dispersant is BYK-190; the anti-settling agent is AQ-633E; the defoaming agent is BYK-024; the preservative was Troy MergalK 9N.
7. An erasable aqueous paint ink for marker pens as claimed in claim 1 wherein said other adjuvants include but are not limited to leveling agents, co-solvents, PH modifiers.
8. A process for preparing an erasable aqueous paint ink for a marker pen according to any one of claims 1 to 7, comprising the steps of:
(1) adding water into a dispersing device, sequentially adding a defoaming agent and a wetting dispersant under low-speed stirring, and continuously stirring for 10 minutes until the mixture is uniformly stirred;
(2) then adding the waterborne acrylic resin and the waterborne polyurethane resin under low-speed stirring, and continuously stirring for 10 minutes until the mixture is uniformly stirred;
(3) then adding the anti-settling agent and the water-based color paste in sequence under low-speed stirring, and stirring at a high speed for 30 minutes until the mixture is completely and uniformly stirred;
(4) finally adding the mixture in turn under low-speed stirringPreservativeThe humectant and other auxiliary agents are continuously stirred for 10 minutes until the mixture is uniformly stirred;
the low speed is 400-600RPM, and the high speed is 800-1200 RPM.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010284387.3A CN111410868A (en) | 2020-04-13 | 2020-04-13 | Erasable water-based paint ink for marker pen and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010284387.3A CN111410868A (en) | 2020-04-13 | 2020-04-13 | Erasable water-based paint ink for marker pen and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111410868A true CN111410868A (en) | 2020-07-14 |
Family
ID=71489816
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010284387.3A Pending CN111410868A (en) | 2020-04-13 | 2020-04-13 | Erasable water-based paint ink for marker pen and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111410868A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112358777A (en) * | 2020-09-28 | 2021-02-12 | 湖南松井新材料股份有限公司 | Water-based PU self-drying erasable protective coating and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050143486A1 (en) * | 2002-02-18 | 2005-06-30 | Sakura Color Products Corporation | Erasable ink composition |
| CN104893420A (en) * | 2015-06-09 | 2015-09-09 | 山西大学 | Colored ink for light-colored teaching board and preparation method of colored ink |
-
2020
- 2020-04-13 CN CN202010284387.3A patent/CN111410868A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050143486A1 (en) * | 2002-02-18 | 2005-06-30 | Sakura Color Products Corporation | Erasable ink composition |
| CN104893420A (en) * | 2015-06-09 | 2015-09-09 | 山西大学 | Colored ink for light-colored teaching board and preparation method of colored ink |
Non-Patent Citations (2)
| Title |
|---|
| 曾晓鹰等: "《电子束固化涂料及应用》", 31 December 2014, 天津大学出版社 * |
| 李永强: "《实用胶印技术指南》", 30 November 2005, 印刷工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112358777A (en) * | 2020-09-28 | 2021-02-12 | 湖南松井新材料股份有限公司 | Water-based PU self-drying erasable protective coating and preparation method and application thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| CB03 | Change of inventor or designer information |
Inventor after: Huang Jing Inventor after: Zhou Yanping Inventor after: Zhao Lina Inventor after: Li Fuan Inventor before: Huang Jing Inventor before: Zhou Yanping Inventor before: Li Fuan |
|
| CB03 | Change of inventor or designer information | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200714 |
|
| RJ01 | Rejection of invention patent application after publication |