CN110105808A - A kind of Chinese painting ink and preparation method thereof with transparent ink trace - Google Patents
A kind of Chinese painting ink and preparation method thereof with transparent ink trace Download PDFInfo
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- CN110105808A CN110105808A CN201910279683.1A CN201910279683A CN110105808A CN 110105808 A CN110105808 A CN 110105808A CN 201910279683 A CN201910279683 A CN 201910279683A CN 110105808 A CN110105808 A CN 110105808A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
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Abstract
The invention discloses a kind of Chinese painting ink and preparation method thereof with transparent ink trace, is made: 20~40 parts of Arabic gum by following parts by weight of component raw material；15~50 parts of deionized water；10~30 parts of black pigment；1~2 part of dispersing agent；0.2~0.5 part of phthalic acid ester.Chinese painting ink with transparent ink trace of the invention, can make each pen drawn a picture that can show nature dispersion effect, more have three-dimensional sense than existing ink, stereovision can more protrude the appeal of painting art, attraction.
Description
Technical field
The invention belongs to traditional Chinese Painting prepared Chinese ink technical fields, and in particular to a kind of Chinese painting ink with transparent ink trace and its
Preparation method.
Background technique
It is well known that ink and wash reaches the variation such as dense, light, burnt, wet, broken, long-pending, bold and vigorous using the ratio of water and prepared Chinese ink.It is various
The method of the use of ink and water, the integrated use in picture is dense, light, dry, wet to be contrasted, to embody the irregular variation of picture entirety.But it is right
A certain pen in part, the adjusting for only relying on moisture are but difficult to accomplish well-bedded effect.Thus, in composition exquisiteness, details
Demanding to draw a picture, on the one hand traditional skill and technique is difficult to meet, on the other hand existing on the market also without can be not satisfactory
Prepared Chinese ink, this brings regret and inconvenience to the person of drawing a picture.
Summary of the invention
It draws a picture to solve existing traditional Chinese Painting with prepared Chinese ink and lacks stereovision, relief technical problem, the purpose of the present invention exists
In providing a kind of Chinese painting ink and preparation method thereof with transparent ink trace, it can make each pen drawn a picture that can present
Nature dispersion effect out more has three-dimensional sense than existing ink, and stereovision can more protrude the appeal of painting art, inhales
Gravitation.
In order to achieve the above technical purposes, the present invention adopts the following technical scheme:
A kind of Chinese painting ink with transparent ink trace, is made by following parts by weight of component raw material:
Preferably, the raw material further includes the borneol of 0.2~0.5 parts by weight.
Preferably, the black pigment is carbon black.
Preferably, the dispersing agent is selected from dodecyl sodium sulfonate ammonium, betanaphthol Cresol formaldehyde sulfonation condensate sulfonates, the moon
At least one of cinnamic alcohol ether phosphate, sorbitan ester and diffusion agent N B.
The present invention also provides the preparation methods of above-mentioned Chinese painting ink, comprising the following steps:
(1) first Arabic gum and phthalic acid ester are added in deionized water, are stirred to react at 70-100 DEG C obtained
The binder solution of carbon containing quanta point material；
(2) it is uniform that black pigment stirring at normal temperature is added into obtained binder solution, sequentially adds dispersing agent, borneol,
It is stirred to react at 70-90 DEG C up to Chinese painting ink.
Preferably, in step (1), speed of agitator 200-300r/min, time 12-18h.
Preferably, in step (2), speed of agitator 200-300r/min, time 12-18h.
Preferably, it in step (2), is stood after being stirred to react, deionized water is added, floats on deionized water on ink, and
Layering.The ink obtained after present invention reaction is saved so that deionized water floats on ink, is prevented by the way that deionized water is added
Ink, which dries out, influences ink quality
The principle of the present invention:
The present invention for primary raw material, prepares carbon quantum dot by hydro-thermal method with Arabic gum (providing carbon source and nitrogen source)
(CDs) material, while the phthalic acid ester added can modify the structure of carbon quantum dot material.Secondly, strict control is reacted
The diameter grain of temperature, one side CDs will have extensive distribution, carbon quantum dot material on the other hand can be inhibited to generate excessive, in order to avoid
Light tone is left after in conjunction with prepared Chinese ink, destroys the atmosphere of traditional Chinese painting.Finally, carbon quantum dot material is sufficiently mixed with prepared Chinese ink,
The Chinese painting ink with transparent ink trace can be obtained.
Compared with prior art, beneficial effects of the present invention:
Each pen that the present invention draws a picture can show nature dispersion effect, more have three-dimensional sense, level than existing ink
Sense, can more protrude the appeal of painting art, attraction.
Detailed description of the invention
Fig. 1 is using lines figure drawn by existing commercially available ordinary ink；
Fig. 2 is using lines figure drawn by ink of the invention.
By the comparison of Fig. 1 and Fig. 2, under identical environment, pointed with the finger or gesticulate with same writing brush and rice paper, the institute after 30min
The pattern of formation: ordinary ink although adjustable prepared Chinese ink and water ratio, achieve the effect that deep or light alternate, but cannot leave
Bright ink trace；And the visual effect of dispersion can be presented in this ink, enhance ink and wash three-dimensional sense, stereovision.
Specific embodiment
Present invention will be further explained below with reference to specific examples.It is worth explanation, these embodiments are merely to illustrate this hair
It is bright, rather than limit the scope of protection of the present invention.The improvement and tune that technical staff makes according to the present invention in practical applications
It is whole, still fall within protection scope of the present invention.
The present invention detects the color of prepared Chinese ink using following methods, if has transparent ink trace and quantum yield:
1, color and transparent ink trace are tested
Prepared Chinese ink point, picture on rice paper are dipped with writing brush, carries out intuition observation comparison, it is intended to which the color for testing prepared Chinese ink is saturating with it
The characteristics of bright ink trace.
The measurement of 2 fluorescence quantum yields
The fluorescence quantum yield value (QY) of carbon quantum dot material is calculated by relative method, using quinine sulfate as standard
Object.If the quantity symbol of QY is Y, the calculation formula of Y is as follows:
In formula: the QY value of Y expression CQDs；Y0Indicate the QY value of quinine sulfate, Y0=54%；G is integrated fluorescence intensities；N is
Refractive index (refractive index of water is 1.33)；Subscript S and X respectively indicate reference substance quinine sulfate dilution heat of sulfuric acid and CQDs to be measured
Sample solution.
Embodiment 1
The Chinese painting ink of the present embodiment, raw material composition are as follows:
20 parts of Arabic gum, 30 parts of deionized water, 15 parts of black pigment, 1.35 parts of dodecyl sodium sulfonate ammonium, O-phthalic
0.25 part of acid esters, 0.15 part of borneol.
When preparation, 20 parts of Arabic gum are taken to put into 30 parts of deionized waters with 0.25 part of phthalic acid ester at 80 DEG C first
Under stirred with 200r/min the binder solution of carbon containing quanta point material be made within 12 hours, be cooled to room temperature；Add black face
15 parts of material stirs 0.5 hour at normal temperature；Then 1.35 parts of dodecyl sodium sulfonate ammonium are sequentially added, 0.15 part of borneol, at 70 DEG C
Under with 300r/min stirring 18 hours after stands 24 hours, add deionized water, float on deionized water on ink, and divide
Layer.
Embodiment 2
The Chinese painting ink of the present embodiment, raw material composition are as follows:
40 parts of Arabic gum, 50 parts of deionized water, 30 parts of black pigment, 1.35 parts of dodecyl sodium sulfonate ammonium, O-phthalic
0.5 part of acid esters, 0.15 part of borneol.
When preparation, 40 parts of Arabic gum are taken to put into 30 parts of deionized waters with 0.5 part of phthalic acid ester at 100 DEG C first
Under stirred with 250r/min the binder solution of carbon containing quanta point material be made within 12 hours, be cooled to room temperature；Add black face
30 parts of material stirs 0.5 hour at normal temperature；Then 1.35 parts of dodecyl sodium sulfonate ammonium are sequentially added, 0.15 part of borneol, at 90 DEG C
Under with 250r/min stirring 18 hours after stands 24 hours, add deionized water, float on deionized water on ink, and divide
Layer.
Comparative example 1
The Chinese painting ink of this comparative example, raw material composition are as follows:
20 parts of animal gelatin, 30 parts of deionized water, 15 parts of black pigment, 1.35 parts of dodecyl sodium sulfonate ammonium, O-phthalic
0.25 part of acid esters, 0.15 part of borneol.
When preparation, 20 parts of animal gelatin are taken to put into 30 parts of deionized waters with 0.25 part of phthalic acid ester at 80 DEG C first
Under stirred with 200r/min the binder solution of carbon containing quanta point material be made within 12 hours, be cooled to room temperature；Add black face
15 parts of material stirs 0.5 hour at normal temperature；Then 1.35 parts of dodecyl sodium sulfonate ammonium are sequentially added, 0.15 part of borneol, at 70 DEG C
Under with 300r/min stirring 18 hours after stands 24 hours, add deionized water, float on deionized water on ink, and divide
Layer.
Comparative example 2
The Chinese painting ink of this comparative example, raw material composition are as follows:
20 parts of Arabic gum, 30 parts of deionized water, 15.0 parts of black pigment, 1.35 parts of borneol 0.15 of dodecyl sodium sulfonate ammonium
Part.
When preparation, take first small with 200r/min stirring 12 at 80 DEG C in 20 parts of Arabic gum investments, 30 parts of deionized waters
When the binder solution of carbon containing quanta point material is made, be cooled to room temperature；15 parts of black pigment are added, is stirred at normal temperature
0.5 hour；Then 1.35 parts of dodecyl sodium sulfonate ammonium are sequentially added, 0.15 part of borneol, stirs 18 at 70 DEG C with 300r/min
24 hours are stood after hour, deionized water is added, floats on deionized water on ink, and be layered.
Comparative example 3
The Chinese painting ink of this comparative example, raw material composition are as follows:
20 parts of Arabic gum, 30 parts of deionized water, 15.0 parts of black pigment, 1.35 parts of dodecyl sodium sulfonate ammonium, adjacent benzene two
0.25 part of formic acid esters, 0.15 part of borneol.
When preparation, 20 parts of Arabic gum are taken to put into 30 parts of deionized waters with 0.25 part of phthalic acid ester 120 first
The binder solution that carbon containing quanta point material is made for 12 hours is stirred at DEG C with 200r/min, is cooled to room temperature；Add black
It 15.0 parts of pigment, stirs 0.5 hour at normal temperature；Then 1.35 parts of dodecyl sodium sulfonate ammonium are sequentially added, 0.15 part of borneol,
24 hours are stood after stirring 18 hours at 70 DEG C with 300r/min, deionized water is added, floats on deionized water on ink, and
Layering.
Comparative example 4
The Chinese painting ink of this comparative example, raw material composition are as follows:
20 parts of Arabic gum, 30 parts of deionized water, 15 parts of black pigment, 1.35 parts of dodecyl sodium sulfonate ammonium, O-phthalic
0.25 part of acid esters, 0.15 part of borneol.
When preparation, 20 parts of Arabic gum are taken to put into 30 parts of deionized waters with 0.25 part of phthalic acid ester at 80 DEG C first
Under stirred with 200r/min the binder solution of carbon containing quanta point material be made within 12 hours, be cooled to room temperature；Add black face
15.0 parts of material stirs 0.5 hour at normal temperature；Then 1.35 parts of dodecyl sodium sulfonate ammonium are sequentially added, 0.15 part of borneol,
24 hours are stood after stirring 18 hours at 110 DEG C with 300r/min, deionized water is added, floats on deionized water on ink,
And it is layered.
The performance parameter of ink made from table 1 embodiment 1-2 and comparative example 1-4
Note: reference substance is commercially available general black prepared Chinese ink
By embodiment 1 and comparative example 1 it is found that the ingredient of animal gelatin is based on protein, Arabic gum is with carbohydrate fibre
Based on dimension, under 80 DEG C of such a lower temperatures, protein is more difficult reaction than carbohydrate and generates carbon quantum dot material, and carbohydrate is fine
Dimension expands under the action of hot water, is more advantageous to generation dehydration condensation, generates carbon quantum dot material.In addition, protein with
The functional group that carbohydrate is formed by carbon quantum dot material will be different, thus will affect its color, and the present invention selects Arabic
Glue technical ability guarantees to generate suitable quantity carbon quantum dot material, while can also form good color.
There is blue-green appearance it is found that not adding phthalic acid ester and will lead to ink by embodiment 1 and comparative example 2, leads
Cause ink black impure, phthalic acid ester has modified the surface of carbon quantum dot material, so that mass colour is presented in transparent ink trace.
It was generated by embodiment 1 and comparative example 3 it is found that preparing the excessively high carbon quantum dot material that will lead to of adhesive temperature
More, fluorescence quantum yield increases, and fluorescent characteristic shows.
Carbon quantum is also resulted in it is found that the mixing temperature of adhesive and black pigment is excessively high by embodiment 1 and comparative example 4
Point material generates excessively, and fluorescence quantum yield increases, and fluorescent characteristic shows.The structure of black pigment itself can also be broken simultaneously
Bad, the prepared Chinese ink of generation is loosely not solidifying real, and diffusion is easy on rice paper, generates color spot.
Claims (7)
1. a kind of Chinese painting ink with transparent ink trace, it is characterised in that: be made by following parts by weight of component raw material:
2. the Chinese painting ink according to claim 1 with transparent ink trace, it is characterised in that: the raw material further includes
The borneol of 0.2~0.5 parts by weight.
3. the Chinese painting ink according to claim 1 with transparent ink trace, it is characterised in that: the dispersing agent is selected from ten
Dialkyl group ichthyodin, betanaphthol Cresol formaldehyde sulfonation condensate sulfonates, laurel alcohol ether phosphate, sorbitan ester and diffusion
At least one of agent NB.
4. the preparation method of the described in any item Chinese painting inks with transparent ink trace of claim 1-3, which is characterized in that packet
Include following steps:
(1) first Arabic gum and phthalic acid ester are added in deionized water, are stirred to react at 70-100 DEG C and are made carbon containing
The binder solution of quanta point material；
(2) it is uniform that black pigment stirring at normal temperature is added into obtained binder solution, dispersing agent, borneol are sequentially added, in 70-
It is stirred to react at 90 DEG C up to Chinese painting ink.
5. the preparation method of the Chinese painting ink according to claim 4 with transparent ink trace, it is characterised in that: step
(1) in, speed of agitator 200-300r/min, time 12-18h.
6. the preparation method of the Chinese painting ink according to claim 4 with transparent ink trace, it is characterised in that: step
(2) in, speed of agitator 200-300r/min, time 12-18h.
7. the preparation method of the Chinese painting ink according to claim 4 with transparent ink trace, it is characterised in that: step
(2) it in, is stood after being stirred to react, deionized water is added, floats on deionized water on ink, and be layered.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910279683.1A CN110105808B (en) | 2019-04-09 | 2019-04-09 | Chinese painting ink with transparent ink marks and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910279683.1A CN110105808B (en) | 2019-04-09 | 2019-04-09 | Chinese painting ink with transparent ink marks and preparation method thereof |
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| CN110105808A true CN110105808A (en) | 2019-08-09 |
| CN110105808B CN110105808B (en) | 2021-07-16 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111087851A (en) * | 2019-12-31 | 2020-05-01 | 南京柚香创意文化产业有限公司 | Preparation method of printer painting and calligraphy ink suitable for rice paper |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102796420A (en) * | 2012-09-11 | 2012-11-28 | 上海实业马利画材有限公司 | Water-based ink color painting pigment with shading effect used on rice paper |
| CN104569375A (en) * | 2015-01-29 | 2015-04-29 | 三诺生物传感股份有限公司 | Method for preparing fluorescent carbon quantum dot |
-
2019
- 2019-04-09 CN CN201910279683.1A patent/CN110105808B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102796420A (en) * | 2012-09-11 | 2012-11-28 | 上海实业马利画材有限公司 | Water-based ink color painting pigment with shading effect used on rice paper |
| CN104569375A (en) * | 2015-01-29 | 2015-04-29 | 三诺生物传感股份有限公司 | Method for preparing fluorescent carbon quantum dot |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111087851A (en) * | 2019-12-31 | 2020-05-01 | 南京柚香创意文化产业有限公司 | Preparation method of printer painting and calligraphy ink suitable for rice paper |
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| CN110105808B (en) | 2021-07-16 |
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