CN109790039B - 选择性催化还原制品和系统 - Google Patents

选择性催化还原制品和系统 Download PDF

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Publication number
CN109790039B
CN109790039B CN201780061410.9A CN201780061410A CN109790039B CN 109790039 B CN109790039 B CN 109790039B CN 201780061410 A CN201780061410 A CN 201780061410A CN 109790039 B CN109790039 B CN 109790039B
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molecular sieve
substrate
containing molecular
catalytic reduction
selective catalytic
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CN109790039A (zh
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薛文梅
J·杨
S·罗斯
K·E·福斯
S·沙
J·L·莫哈南
Q·傅
S·普拉萨德
B·斯拉夫斯基
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BASF Corp
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BASF Corp
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    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/14—Nitrogen oxides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/18—Ammonia
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

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Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3281699A1 (de) * 2016-08-11 2018-02-14 Umicore AG & Co. KG Partikelfilter mit scr-aktiver beschichtung
JP6693406B2 (ja) * 2016-12-20 2020-05-13 三菱自動車工業株式会社 排気ガス浄化装置
CN110240178B (zh) * 2018-03-09 2021-04-23 中国科学院大连化学物理研究所 选择性吸分子筛及其制备方法
JP7150496B2 (ja) * 2018-06-27 2022-10-11 株式会社キャタラー 排ガス浄化用触媒及び排ガス浄化システム
WO2021198276A1 (en) * 2020-03-30 2021-10-07 Basf Corporation A selective catalytic reduction catalyst and a process for preparing a selective catalytic reduction catalyst
WO2021203121A1 (en) * 2020-03-31 2021-10-07 Johnson Matthey Public Limited Company Ammonia slip catalyst with in-situ pt fixing
US12296322B2 (en) * 2020-04-01 2025-05-13 Basf Mobile Emissions Catalysts Llc High ammonia storage capacity SCR catalysts
WO2022122799A1 (en) * 2020-12-09 2022-06-16 Basf Corporation Preparation process of scr catalyst comprising cu and fe-exchanged zeolite, said catalyst, system comprising said catalyst and exhaust gas treatment using such
EP4095093A1 (en) * 2021-05-28 2022-11-30 Casale Sa Process for production of nitric acid provided with a secondary abatement treatment
CN114433202A (zh) * 2021-12-23 2022-05-06 惠州市瑞合环保科技有限公司 一种柴油机尾气净化scr催化剂及其涂敷工艺
CN114950576B (zh) * 2022-06-20 2023-08-22 济南大学 一种提高金属基小孔分子筛水热稳定性的方法及所得产品和应用
EP4414052A1 (en) * 2023-02-10 2024-08-14 Johnson Matthey Public Limited Company Scr catalyst article and systems for reducing n2o in exhaust gas
CN117299196B (zh) * 2023-11-30 2024-02-20 无锡威孚环保催化剂有限公司 一种低n2o生成量的scr催化剂及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104736243A (zh) * 2012-10-19 2015-06-24 巴斯夫公司 混合金属8环小孔分子筛催化剂组合物、催化制品、体系和方法
CN104755164A (zh) * 2012-10-19 2015-07-01 巴斯夫公司 作为高温scr催化剂的8环小孔分子筛

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4861739A (en) * 1987-06-04 1989-08-29 Uop Microporous crystalline composite compositions
US6689709B1 (en) * 2000-11-15 2004-02-10 Engelhard Corporation Hydrothermally stable metal promoted zeolite beta for NOx reduction
KR101394774B1 (ko) 2005-12-14 2014-05-15 바스프 카탈리스트 엘엘씨 ＳＣＲ에서의 ＮＯｘ 환원이 개선된 제올라이트 촉매
US10384162B2 (en) * 2007-03-26 2019-08-20 Pq Corporation High silica chabazite for selective catalytic reduction, methods of making and using same
CN102764590B (zh) * 2007-08-13 2015-05-13 Pq公司 含铁铝硅酸盐沸石及其制备和使用方法
WO2010121257A1 (en) * 2009-04-17 2010-10-21 Johnson Matthey Public Limited Company Small pore molecular sieve supported copper catalysts durable against lean/rich aging for the reduction of nitrogen oxides
DE102009040352A1 (de) 2009-09-05 2011-03-17 Johnson Matthey Catalysts (Germany) Gmbh Verfahren zur Herstellung eines SCR aktiven Zeolith-Katalysators sowie SCR aktiver Zeolith-Katalysator
GB2475740B (en) * 2009-11-30 2017-06-07 Johnson Matthey Plc Catalysts for treating transient NOx emissions
US8293198B2 (en) * 2009-12-18 2012-10-23 Basf Corporation Process of direct copper exchange into Na+-form of chabazite molecular sieve, and catalysts, systems and methods
KR102078083B1 (ko) 2011-12-02 2020-02-20 피큐 코포레이션 안정화된 미세다공성 결정상 물질, 이의 제조 방법 및 ＮＯｘ의 선택적 촉매 환원을 위한 용도
CA2900291A1 (en) * 2013-03-14 2014-10-02 Basf Corporation Selective catalytic reduction catalyst system
JP6532826B2 (ja) 2013-12-11 2019-06-19 株式会社キャタラー 排ガス浄化材
BR112016019834B1 (pt) 2014-02-28 2021-09-28 Johnson Matthey Public Limited Company Método para produzir um catalisador, e, ferrierita
DE112015001008T5 (de) 2014-02-28 2017-04-20 Johnson Matthey Public Limited Company SCR-Katalysatoren mit verbesserter Niedertemperaturleistung und Verfahren zur Herstellung und Verwendung derselben
GB2530129B (en) 2014-05-16 2016-10-26 Johnson Matthey Plc Catalytic article for treating exhaust gas
KR20170038927A (ko) 2014-08-07 2017-04-07 존슨 맛쎄이 퍼블릭 리미티드 컴파니 배기가스를 처리하기 위한 구역화된 촉매
MX388605B (es) * 2014-10-30 2025-03-20 Basf Mobile Emissions Catalysts Llc Composiciones catalizadoras de tamices moleculares de cristales grandes con metales mixtos, articulos cataliticos, sistemas y metodos.
BR112017021069B1 (pt) 2015-04-09 2022-03-29 Pq Corporation Material cristalino microporoso e métodos de produção e de redução catalítica seletiva de óxidos de nitrogênio em gás de exaustão

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104736243A (zh) * 2012-10-19 2015-06-24 巴斯夫公司 混合金属8环小孔分子筛催化剂组合物、催化制品、体系和方法
CN104755164A (zh) * 2012-10-19 2015-07-01 巴斯夫公司 作为高温scr催化剂的8环小孔分子筛

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
The effect of iron loading and hydrothermal aging on one-pot synthesized Fe/SAPO-34 for ammonia SCR;Stanislava等;《Applied Catalysis B: Environmental》;20150715;第180卷;第775-787页 *
The impact of urea on the performance of metal-exchanged zeolites for the selective catalytic reduction of NOx—Part II. Catalytic, FTIR, and NMR studies;Maik Eichelbaum等;《Applied Catalysis B: Environmental》;20100327;第97卷;98-207页 *

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