CN109789071A - Hair care composition - Google Patents
Hair care composition Download PDFInfo
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- CN109789071A CN109789071A CN201780059866.1A CN201780059866A CN109789071A CN 109789071 A CN109789071 A CN 109789071A CN 201780059866 A CN201780059866 A CN 201780059866A CN 109789071 A CN109789071 A CN 109789071A
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- hair
- acid
- care composition
- hair care
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/362—Polycarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Abstract
The present invention relates to hair care compositions, more particularly, to the hair care composition of the aliphatic diamine compound of binary aliphatic acid compound and C2-C6 comprising C2-C4.Hair care composition according to the present invention is shown can not only restore impaired hair inside hair, but also the hair reinforcing effect with semipermanent, therefore can be widely applied to various dosage forms.
Description
Technical field
This application claims in the submission Koran Office on the 27th of September in 2016, application No. is 10-2016-0124305 and
In the submission Koran Office on the 8th of August in 2017, application No. is the priority of the South Korea patent application of 10-2017-0100148,
Full content is hereby incorporated by reference in the application.
The present invention relates to a kind of hair care compositions, with excellent nursing efficacy and persistence.
Background technique
In general, the hair of people is by cuticula, cortex and medullary substance up of three-layer.Cuticula is outermost layer, plays cladding and guarantor
The undamaged cutin layer surface of the effect of sheath matter, healthy hair is smooth, and has refracted light, reduces between hair
The effect of frictional force.
Hair is easily affected by, specifically, due to dry cold wind, room heater, excessively combing, pressure,
The factors such as malnutritive and sleep insufficiency influence, and will lead to damaged hair.In addition, recently, hair is considered as one kind by modern
Fashion, due to the hair treatments such as often being dyed, perming, decolourize, excessively using Hair Stying Products, for a long time using hair dryer
The increase of situation makes hair also continually be damaged.
When hair is impaired because of various physics, chemistry or environmental factor, the damage of hair cuticula will cause, in hair
Protein and lipid are lost, to keep hair roughening, are tarnished, and as the increase of frictional force occurs to be easy to knot, easily
The phenomenon that disconnected or end jag.In addition, there is also, because losing, elastic force causes to lose plentiful sense due to hair is sagging or hair becomes
Thin problem.So usually needing careful nursing since impaired hair is difficult to be repaired.
Therefore, demand of the consumer to nursing (improvement of the hair situation) product for being able to maintain hair luster and elastic force and partially
Well increasingly increase.
Conventional care product contains cation interfacial active agent or cationic polymer to improve the appearance and touching of hair
Feel and obtain lasting effect, specifically, is prepared to be adsorbed on due to damage and have in anion hair surface, to change
The state on the surface of kind hair manages drying hair and wet hair all more easily later by inhibiting the generation of hair damages and electrostatic
Reason.
However, currently, due to using the care product of cationic substance to act only on hair surface, so in cleaning hair
Effect can be lost after just.In particular, in the case where hair attenuates or is roughening, since the intensity inside hair is greatly lowered,
So being only difficult to obtain sufficient effect by the improvement of hair surface.
In this regard, the composition or the new chemical combination of exploitation by changing cation interfacial active agent, higher alcohol, oil etc. has been carried out
Object come improve hair situation and improve endurance various trials.
It, can be with it includes having for example, Korean Patent No. No.2014-0090007 discloses a kind of care composition
The specific residue of hair forms the compound of the reactive residue of covalent bond, to make hair surface hydrophiling, is providing health
Endurance is maximized while hair characteristics.
Although above-mentioned patent has certain effect to the improvement of hair situation, effect is simultaneously insufficient, and due to worrying
Human safety and processing stability cause difficult using limited or manufacturing process.Therefore, it is also desirable to develop a kind of with excellent
Nursing efficacy and novel hair care composition with endurance.
[existing technical literature]
[patent document]
Korean Patent Publication No. the 2014-0090007th (2014.07.16), the semipermanent for forming hydrophobic surface are protected
Wet therapeutic agent.
Summary of the invention
Technical problem
Based on this, the present inventor has carried out various researchs to solve the above-mentioned problems, as a result, it has been found that working as hair care composition
When object contains specific diacid compound and diamine compound, it can be improved inside hair care composition and hair and whole
Binding force so that confirmation can not only improve the characteristic of hair, and maintains the effect for a long time.
In this regard, the object of the present invention is to provide a kind of with excellent hair-care effect and efficacy lasting hair-care
Composition.
Technical solution
To achieve the goals above, the present invention provides a kind of hair care composition, and it includes the binary aliphatics of C2-C4
The aliphatic diamine compound of acid compound and C2-C6.
The binary aliphatic acid compound of the C2-C4, which is characterized in that it includes be selected from succinic acid, aspartic acid, horse
Come sour, malic acid, tartaric acid, fumaric acid, glutaric acid, glutamic acid, glutaconate, 1,3- acetone dicarboxylic acid, adipic acid and oneself two
One of enedioic acid is a variety of.
The C2-C6 aliphatic diamine compound, which is characterized in that it includes selected from tetrahydroxypropyl ethylenediamine, sub- essence
Bis- (the dimethylaminomethyl)-cyclohexanone dihydrochlorides of amine, histidine, ornithine, arginine, 2,6-, lysine and 1,6- oneself
One of diamines is a variety of.
The C2-C4 binary aliphatic acid compound, which is characterized in that its content accounts for the shield of the hair based on 100 weight %
Manage the 0.3-20 weight % in composition.
The C2-C4 aliphatic diamine compound, which is characterized in that its content accounts for the hair-care based on 100 weight %
0.3-20 weight % in composition.
Beneficial effect
Hair care composition according to the present invention includes specific diacid compound and diamine compound, so that described
Inside hair care composition and hair and strong ionic bond is integrally formed, to not restore damaged hair only effectively, also has
The effect of the reinforcing hair of semipermanent, therefore can be widely used in the product of a variety of dosage forms.
Detailed description of the invention
Fig. 1 shows the chart of the assessment result of the hair tensile strength of EXPERIMENTAL EXAMPLE 1 according to the present invention.
Fig. 2 shows the charts of the assessment result of the hair surface frictional force of EXPERIMENTAL EXAMPLE 1 according to the present invention.
Fig. 3 shows the chart of the assessment result of the elastic force of the hair of EXPERIMENTAL EXAMPLE 1 according to the present invention.
Fig. 4 shows the chart of the assessment result of the hair tensile strength of EXPERIMENTAL EXAMPLE 2 according to the present invention.
Fig. 5 shows the chart of the assessment result of the hair surface frictional force of EXPERIMENTAL EXAMPLE 2 according to the present invention.
Fig. 6 shows the chart of the assessment result of the hair elastic force of EXPERIMENTAL EXAMPLE 2 according to the present invention.
Specific embodiment
Hereinafter, the present invention is described in further detail.
In the present specification, term " nursing efficacy " refers to, restores damaged hair or prevents healthy hair impaired.Specifically
Ground refers to by keeping hair thicker or improving tensile strength and strengthens hair, so that hair limbers up, water moistens, is smooth, rich in bullet
Power and plentiful, to maintain the hair condition of health.
The present invention provides a kind of hair care composition strong with excellent nursing efficacy and endurance.
With the raising of the diversity and educational level of modern society, people increasingly increase the care of appearance.In particular, by
It in individual is the part and parcel as face in person in hair, so the hair treatments such as hair-waving and dyeing are very universal.So
And due to a variety of physics, chemistry or the environmental factor of frequent hair treatment, moulding etc., it is easy to make damaged hair.But because
Impaired hair does not have self-repairing capability, therefore is not only difficult to be restored to original health status, and the extent of damage can be with
The passage of time and accelerate, it is therefore desirable to the health of hair is maintained using care product.
Since the cuticula on damaged hair surface is destroyed, causes protein and lipid in hair to be lost, formed porous.
Therefore, make hair attenuate and it is coarse, tarnish, and since frictional force increase causes to send out tip jag, and then final fracture.So
And due to existing care product be for the purpose of improving hair surface characteristic, can not become fundamentally improve it is hairy
The solution of condition, and can only provide and clean preceding effect of short duration for the moment to next time after using, it needs to carry out again after cleaning
Secondary processing, it is not easy enough.
Therefore, the present invention provides a kind of hair care composition, and it includes aliphatic diamine compound and aliphatic diamines
Compound can form ionic bond with the constituent of hair by reacting with inside hair or surface, so that it is guaranteed that excellent hair
Send out the persistence of nursing efficacy and effect.
Specifically, hair care composition according to the present invention includes the aliphatic dibasic acid (aliphatic of C2-C4
Dibasic acid) compound and C2-C6 aliphatic diamine (aliphatic diamine) compound.
The binary aliphatic acid compound of the C2-C4 is to have in the aliphatic hydrocarbon chain end with 2-4 carbon atom
The compound of two carboxylic acid groups.Wherein, the aliphatic hydrocarbon chain can be saturated or unsaturated.In addition, in the aliphatic hydrocarbon chain
The one or more hydrogen atoms for including can be arbitrarily replaced one or more substituent groups.
In general, damaged hair and normal hair the difference is that, damaged hair loses fat due to hair surface
Acid and anionic property is presented.At this point, by the binary aliphatic acid compound of the C2-C4 and because damage shows anion
Property hair inside form ionic bond, to fill up damaged hair position, to strengthen hair to obtain nursing efficacy, moreover,
The effect can also be maintained for a long time by forming the ionic bond of excellent binding force.
For example, the C2-C4 binary aliphatic acid compound, which can be used, is selected from succinic acid (succinic acid), asparagus fern
Propylhomoserin (aspartic acid), maleic acid (maleic acid), malic acid (malic acid), tartaric acid (Tartaric
Acid), fumaric acid (fumaric acid), glutaric acid (glutaric acid), glutamic acid (glutamic acid), amylene two
Acid (glutaconic acid), 1,3- acetone dicarboxylic acid (1,3-acetonedicarboxylic acid), adipic acid
One of (adipic acid) and muconic acid (muconic acid) or many kinds of substance.Preferably, the C2-C4 rouge
Fat race diacid compound can be used selected from one of maleic acid, malic acid, glutamic acid and 1,3- acetone dicarboxylic acid or more
Kind.It is highly preferred that the C2-C4 binary aliphatic acid compound can be used selected from one of maleic acid and malic acid or more
Kind.
The binary aliphatic acid compound of the C2-C4 can directly be synthesized by method commonly used in the art, Huo Zheke
Commercial product is used with purchase.
The dosage of the binary aliphatic acid compound of the C2-C4 can account for total hair-care group based on 100 weight %
The 0.3-20 weight % in object is closed, 1-10 weight % is preferably accounted for.When the content of the binary aliphatic acid compound of the C2-C4
When lower than above range, then there are problems that being difficult to present hair damages recovery effects, whereas if the content is more than above-mentioned
When range, then it is difficult to that preparation is made, and most probably generate stimulation to scalp.
The aliphatic diamine compound of the C2-C6 is to have in the end of the aliphatic hydrocarbon chain with 2-6 carbon atom number
There are two the compounds of amido, and by reacting with above-mentioned diacid compound, further enhance and hair hair to play
Send out the effect of whole binding force.Wherein, since the reaction is realized by forming ionic bond, in generally cleaning process
In, it will not be washed off easily because of shampoo, soap etc., and even if can also have endurance stronger partly forever after the cleaning
The additional effect of long property nursing.
The aliphatic diamine compound of the C2-C6, which can be used, is selected from tetrahydroxypropyl ethylenediamine
(tetrahydroxypropyl ethylenediamine), spermidine (spermidine), histidine (histidine), bird
Propylhomoserin (ornithine), arginine (arginine), bis- (the dimethylaminomethyl)-cyclohexanone dihydrochloride (2,6- of 2,6-
BIS- (dimethylaminomethyl)-cyclohexanone dihydrochloride), lysine (lysine) and 1,6-
One of hexamethylene diamine (1,6-hexadiamine) or many kinds of substance.Preferably, the aliphatic diamine compound of the C2-C6
It can be used and be selected from one of tetrahydroxypropyl ethylenediamine, arginine, lysine and 1,6- hexamethylene diamine or a variety of.More preferably
Ground, the aliphatic diamine compound of the C2-C6 can be used selected from one of tetrahydroxypropyl ethylenediamine and arginine or
It is a variety of.
The aliphatic diamine compound of the C2-C6 can be synthesized directly or commercially available use commercially peddles product.
The dosage of the aliphatic diamine compound of the C2-C6 can account for total hair care composition based on 100 weight %
In 0.3 to 20 weight %, preferably 1-10 weight %.When the content of the binary aliphatic acid compound of the C2-C4 is less than
When the range, it will lead to be not enough to generate and be able to the effect strengthened with the hair binding force of hair, on the contrary, when content is more than upper
When stating range, with content increase, increased effect is very small, and is unfavorable for that preparation is made.
In the present invention, the aliphatic diamine compound of the binary aliphatic acid compound of the C2-C4 and C2-C6 can be with
It is used by the weight ratio of 1:1, but not limited to this.The weight ratio of described two ingredients can be according to the compound and composition used
PH value and change.Since the pH value range of hair care composition according to the present invention is 3-9, preferably 5-8, therefore can be with
Suitably regulating weight ratio, with corresponding with the pH range.
It is strong can also to further include hair other than comprising mentioned component for hair care composition according to the present invention
Chemical conversion point.The hair, which strengthens ingredient, to be acted on outside hair, to increase the rugosity of hair or fill the substance of affected area,
For example, the hair strengthen ingredient can be selected from the natural materials such as animal, plant, minerals extract, amino acid, peptide, protein,
One of high-molecular compound, organo-silicon compound, fatty alcohol, fatty acid, wax and ester type compound are a variety of.
In addition, hair care composition of the invention is other than containing mentioned component, it can also include art technology
Well known to personnel and what is used is used to maintain any ingredient of the routine of essential attribute and quality, such as can further include blistering
Agent, detergent, care agent, pearling agent, preservative, thickener, viscosity modifier, pH adjusting agent, fragrance etc., and may include
Deionized water, organic solvent as solvent.
The foaming agent and detergent may include teepol, amphoteric ion (zwitter) or both sexes interface
Activating agent, non-ionic surfactant or their compositions.
The teepol can be from alkyl sulfate system, alkylsulfonate system, alkyl carboxylate system, alkyl ether
Sulfate system, alkyl isethionate system, alkyltaurate system, alkyl sulfo succinate system, alkyl sulfoacetate,
Alkyl phosphate system, anionic amino acid derivative, anionic polypeptides derivative, alkyl polyglucoside anionic derivative,
It selects and uses in fatty acid soaps and their mixture.Wherein, ammonium lauryl sulfate can be used in alkyl sulfate
(Ammonium Lauryl Sulfate, ALS), dodecyl ethyl sulfuric acid ammonium (Ammonium Laurylethyl
Sulfate, ALES), lauryl sodium sulfate (Sodium Lauryl Sulfate, SLS) and dodecyl sodium ethylsulfate
(Sodium Laurylethyl Sulfate, SLES) etc..
(C8-C20) alkyl betaine, N- (C8-C20) alkyl acyl can be used in the amphoteric ion or zwitterionic surfactant
Base glycine betaine and its derivative, glycine derivative, sulfobetaines and its derivative, (C8-C20) alkyl polyaminocarboxylic acid
Salt, (C8-C20) alkyl both sexes acetate, lauroyl sodium acetate and its mixture, it is preferable that can be selected from amine oxide, cocounut oil both sexes
Carboxyl glycinate, Cocoamidopropyl betaine and its mixture, but not limited to this.
The block copolymer of the optional autohemagglutination of non-ionic surfactant (ethylene oxide) and poly- (propylene oxide) gathers
The alkyl and poly alkyl ester of (ethylene oxide), the alkyl and poly alkyl ether, D-sorbite polyoxy for aoxidizing enol, poly- (ethylene oxide)
Alkyl and poly alkyl ester, the D-sorbite of vinylation polyoxyethylated alkyl and poly alkyl ether, alkyl and poly- alkyl glycosides or
The alkane of polysaccharide glycosides, the alkyl of sucrose and multi-alkyl ester, the alkyl of glycerin polyoxyethylene and poly alkyl ester, glycerin polyoxyethylene
Base and poly alkyl ether, Shuangzi interfacial agent, alkylol and its mixture.
The care agent can be living from dimethyl silicone polymer base, Nexbase 2004 and cationic polymer, cationic interface
It selects and uses in property agent.
The pearling agent may be selected and use glycol distearate, ethylene glycol monostearate, fatty acid etc..It is described
Preservative includes methyl p-hydroxybenzoate, methyl p-hydroxybenzoate, butyl p-hydroxybenzoate, P-hydroxybenzoic acid second
Ester, propylparaben, benzyl alcohol, phenoxetol, phenoxy group isopropanol, phenyl propanol, methylchloroisothiazandnone
With the mixture of methyl-isothiazol alkanone.The thickener or viscosity modifier include fatty acid alcohol, fatty acid, hydroxypropyl methyl
Cellulose, hydroxymethyl cellulose, sodium chloride, ammonium chloride, propylene glycol and hexylene glycol.
The pH adjusting agent includes being selected from acetic acid, lactic acid, adipic acid, amino-ethyl propylene glycol, amino-methyl-propanediol, ammonia
Ylmethyl propyl alcohol, amino-propanediol, ascorbic acid, azelaic acid, benzoic acid, butyl diethanolamine, butylethanolamine, citric acid,
Dibutylethanolamine, diethanol amine, diisopropylamine, diisopropanolamine (DIPA), dimethylisopro panolamine, decyl alcohol amine, galacturonic
Acid (Galacturonic acid), glycolic (Glycolic acid), triisopropanolamine, isopropylamine, malic acid, malonic acid
(Malonic acid) and methylethanolamine (Methylethanolamine).
The organic solvent include n-butanol, the tert-butyl alcohol, benzylalcohol, benzyl carbinol, hexanol, isopropanol, methanol, oleyl alcohol, propyl alcohol,
Cyclohexanedimethanol, Phenoxyethanol, ethylene glycol monobutyl ether, moral ethyoxyl, ethylene glycol monomethyl ether, methoxyl group diethylene glycol (DEG), butanediol, third
Glycol, pentanediol, hexylene glycol, benzyl ethylene glycol diethylene glycol (DEG), dipropylene glycol, 1,2- butanediol, 1,4- butanediol, 2,3- fourth two
Alcohol, propylene glycol, 1,5- pentanediol, isoprene, hexylene glycol ethyl ester, 1,2- hexylene glycol, 1,2,6- hexane, 1,10- decanediol, 3-
Methoxybutanol, methoxyl group isopropanol, methoxy butanol, ethylene carbonate, propylene carbonate and its mixture.
In addition, wherein glycerol, polyalcohol, propylene glycol, 1,3- fourth can be used in moisturizer in the ingredient that can further include
Glycol, dipropylene glycol, D-sorbite etc., but not limited to this, pigment can be used in the preparation for being usually used in scalp and hair at
Point, it is not particularly limited.
Hair care composition according to the present invention comprising said components passes through the aliphatic dibasic acid chemical combination with C2-C4
Object and hair form ionic bond, then react with the aliphatic diamine compound of C2-C6, and then strong ion is integrally formed with hair
Key.It is reacted, can not only be filled inside hair by the ionic bond repeatedly with these compounds, and enhance the whole knot of hair
With joint efforts, thus make hair is glossy, water profit, it is smooth, rich in elastic force, plentiful.Therefore, because being combined with compound formation strong
Stronger ionic bond is spent, so said effect can be maintained after cleaning, semipermanent can be obtained when to persistently using
Nursing efficacy.
Hair care composition of the invention be applicable to shampoo, hair softener, hair conditioner, hair care frost, conditioner milk,
Scalp hair film, hair tonic (hair tonic), hair sprays, trichotrophy toner, hair therapy agent (hair
Treatment), ampulla, hair-care essence, mousse, pomade, hair jelly, modeling agent or scalp care therapeutic agent etc. are all is used for hair
Dosage form.Wherein it is possible to carry out preparation using conventional method known in the art, it is not particularly limited.
Embodiment
Hereinafter, the present invention is described in more details in reference implementation example.It should be appreciated by those skilled in the art that this
A little embodiments are only used for that the present invention will be described in more detail, and purport according to the present invention, and the scope of the present invention is not by these realities
Apply the limitation of example.
Embodiment 1-5 and comparative example 1-3: the preparation of hair care composition
According to composition and content shown in following table 1, the hair care composition of creme is prepared.
Firstly, putting into the various composition of aqueous portion in blender, and made it completely dissolved at 70 DEG C.
Then, it in another blender, after cetostearyl alcohol is heated to 70 DEG C, is put into above-mentioned aqueous portion
In, and stirred 3 minutes with high speed agitator with the speed of 3600rpm.
Finally, being stirred for after sequentially adding the ingredient that remaining oil phase part is divided with high speed agitator with the speed of 3600rpm
3 minutes, it is cooled to 30 DEG C later, to prepare the hair care composition of creme.
[table 1]
EXPERIMENTAL EXAMPLE 1: the assessment to the hair of disposable state
In order to assess the nursing efficacy of the hair care composition prepared in the embodiment and comparative example, with the group of preparation
After closing object processing hair, the tensile strength of hair, skin-friction force and hair elastic force are then measured by the following method.
Wherein, used topknot (phoenixkorea corporation is cleaned with the basic shampoo of not nursing function
Make), after cleaning 1 minute and drying 2 minutes, the embodiment of 0.3g and the hair care composition of comparative example are smeared respectively.
1) tensile strength
The embodiment is coated with the measurement of multi-functional hair detector MTT175 (Diastron company manufactures) and is compared
The tensile strength of a hair in the hair of the composition of example.The tensile strength refers to that hair is applied to before being pulled off
The weight of power on hair, the higher expression hair of weight value are more tough, healthy.Its result is as shown in Figure 1.
2) skin-friction force
The embodiment is coated with the measurement of multi-functional hair detector MTT175 (Diastron company manufactures) and is compared
The skin-friction force of the topknot of the composition of example.The skin-friction force refers to, roughness when comparing by hair surface
Value, the smaller expression hair of the value are more smooth.Its result is as shown in Figure 2.
3) hair elastic force
The topknot for being coated with the composition of the embodiment and comparative example is fixed into the arch of 1.5cm high.Then, using pushing away
Piston is drawn, with since 0.001N, the power per second for increasing 0.001N pressurizes to it.At this point, from the vertex of arch along vertical
Direction applies the power, and measures pressure while pressurizeing to the measuring part configured with the push-and-pull piston.It surveys
Measure the power at the point of collapse of arch hair, then duplicate measurements 30 times.Wherein, hair elastic force refers to, hair is being bent arching
After shape, the support force of hair when pressing central point, support force is bigger, and the elastic force for indicating hair is stronger.Its result such as Fig. 3 institute
Show.
As shown in Figure 1-3, compared with the hair of the compositions-treated of comparative example, with the hair of the compositions-treated of embodiment
The tensile strength and elastic force of hair have increase, and skin-friction force has reduction.Particularly, maleic acid and malic acid are being used respectively
Embodiment 4 and 7 in, show excellent tensile strength and hair elastic force and low-frictional force.It can be true from these results
Recognize, composition according to the present invention is when for disposable state with excellent nursing efficacy.
EXPERIMENTAL EXAMPLE 2: the assessment to the hair after cleaning
In the EXPERIMENTAL EXAMPLE 1, using the basic shampoo cleaning embodiment without nursing function and compare
The topknot of the compositions-treated of example, after then cleaning 1 minute and being 2 minutes dry, with identical side in the EXPERIMENTAL EXAMPLE 1
Formula measures the tensile strength of hair, mantle friction and hair elastic force.Its result is as Figure 4-Figure 6.
As shown in Figs. 4-6, it after the hair for cleaning and crossing via compositions-treated according to the present invention can be confirmed, stretches strong
The raising of degree, the reduction of frictional force and the raising of hair elastic force still keep similar level with EXPERIMENTAL EXAMPLE 1.Therefore, may be used
The nursing efficacy of phase same level is kept to confirm composition according to the present invention after the cleaning.
Prepare embodiment 1: hair sprays
It include the head of hair care composition of the invention with conventional method preparation according to the composition and content of following table 2
Hair is spraying.
[table 2]
Prepare embodiment 2: hair conditioner
It include the shield of hair care composition of the invention with conventional method preparation according to the composition and content of following table 3
Hair element.
[table 3]
| Ingredient | Hair conditioner (unit: weight %) |
| The composition of diamine compound and diacid compound | 4 |
| Trimethyl ammonium chloride | 1.0 |
| Polyvinyl alcohol | 0.05 |
| Hexadecanol | 1.0 |
| Glycerol monolaurate | 0.05 |
| Fragrance, pigment | 1.0 |
| Sodium benzoate | 0.1 |
| Pure water | Surplus |
Prepare embodiment 3: modeling agent
According to the composition and content of following table 4, with conventional method preparation making comprising hair care composition of the invention
Type agent.
[table 4]
Industrial applicability
Hair care composition according to the present invention, which is shown, can not only effectively restore damaged hair, but also have half
Permanent hair strengthening effect, therefore can be widely applied to various dosage forms.
Claims (7)
1. including the hair care composition of C2-C4 binary aliphatic acid compound and C2-C6 aliphatic diamine compound.
2. hair care composition according to claim 1, which is characterized in that the C2-C4 aliphatic dibasic acid chemical combination
Object include selected from succinic acid, aspartic acid, maleic acid, malic acid, tartaric acid, fumaric acid, glutaric acid, glutamic acid, glutaconate,
One of 1,3- acetone dicarboxylic acid, adipic acid and muconic acid are a variety of.
3. hair care composition according to claim 1, which is characterized in that the C2-C6 aliphatic diamine compound
Comprising being selected from tetrahydroxypropyl ethylenediamine, spermidine, histidine, ornithine, arginine, 2,6- bis- (dimethylaminomethyls)-
One of cyclohexanone dihydrochloride, lysine and 1,6- hexamethylene diamine are a variety of.
4. hair care composition according to claim 1, which is characterized in that the C2-C4 aliphatic dibasic acid chemical combination
The content of object accounts for the 0.3-20 weight % in total hair care composition based on 100 weight %.
5. hair care composition according to claim 1, which is characterized in that the C2-C6 aliphatic diamine compound
Content account for the 0.3-20 weight % in total hair care composition based on 100 weight %.
6. hair care composition according to claim 1, which is characterized in that the hair care composition by with hair
Association reaction between hair can not only fill inside hair, and enhance the whole binding force of hair, to enhance the stretching of hair
Slightly, assign hair luster, softness, it is smooth, rich in elastic force, plentiful effect.
7. hair care composition according to claim 1, which is characterized in that the hair care composition can be produced
At shampoo, hair softener, hair conditioner, hair care frost, conditioner milk, scalp hair film, hair tonic, hair sprays, trichotrophy
Toner, hair therapy agent, ampulla, hair-care essence, mousse, pomade, hair jelly, modeling agent or scalp care therapeutic agent.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20160124305 | 2016-09-27 | ||
| KR10-2016-0124305 | 2016-09-27 | ||
| KR10-2017-0100148 | 2017-08-08 | ||
| KR1020170100148A KR101998102B1 (en) | 2016-09-27 | 2017-08-08 | Composition for hair care |
| PCT/KR2017/009347 WO2018062697A1 (en) | 2016-09-27 | 2017-08-28 | Composition for hair care |
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| CN109789071A true CN109789071A (en) | 2019-05-21 |
| CN109789071B CN109789071B (en) | 2022-03-15 |
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Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1383377A (en) * | 2000-06-26 | 2002-12-04 | 株式会社资生堂 | Hair grooming compsns. |
| CN1682680A (en) * | 2004-04-15 | 2005-10-19 | 花王株式会社 | Hair cosmetic composition |
| KR20060007079A (en) * | 2004-07-13 | 2006-01-24 | 주식회사 엘지생활건강 | Hairdye composition comprising cationic surfactant |
| CN101018540A (en) * | 2004-09-09 | 2007-08-15 | 威娜股份有限公司 | Hair-conditioning composition |
| US20080299063A1 (en) * | 2007-05-31 | 2008-12-04 | Kao Corporation | Hair cosmetic composition |
| CN101336103A (en) * | 2005-12-16 | 2008-12-31 | 荷兰联合利华有限公司 | Hair treatment compositions |
| JP4865574B2 (en) * | 2007-01-15 | 2012-02-01 | ホーユー株式会社 | Hair treatment composition and hair treatment method |
| KR20120095321A (en) * | 2011-02-18 | 2012-08-28 | 가부시키가이샤 써니 플레이스 | Hair treatment |
| US20120230935A1 (en) * | 2011-03-08 | 2012-09-13 | Somang Cosmetics Co., Ltd. | Solvent composition for one-step permanent wave and hair straightener |
| KR20130114468A (en) * | 2012-04-09 | 2013-10-18 | 주식회사 엘지생활건강 | Cosmetic compositon for hair and method for hair tretments using the same |
| KR20140090007A (en) * | 2013-01-08 | 2014-07-16 | 주식회사 엘지생활건강 | Semi-permanent moisturizing treatment composition making hydrophobic surface |
| CN104540495A (en) * | 2012-06-04 | 2015-04-22 | Elc管理有限责任公司 | Compositions and methods for enhancing the structure of hair fibers |
| CN104622706A (en) * | 2008-04-25 | 2015-05-20 | 欧莱雅 | Use of a cosmetic composition combined with a composition for treating and/or washing keratinous fibres |
| CN105902404A (en) * | 2016-06-14 | 2016-08-31 | 知识产权全资有限公司 | Hair strengthening ingredient and method |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4522020B2 (en) * | 2000-06-26 | 2010-08-11 | 株式会社資生堂 | Hair treatment composition |
-
2017
- 2017-08-28 WO PCT/KR2017/009347 patent/WO2018062697A1/en active Application Filing
- 2017-08-28 CN CN201780059866.1A patent/CN109789071B/en active Active
Patent Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1383377A (en) * | 2000-06-26 | 2002-12-04 | 株式会社资生堂 | Hair grooming compsns. |
| CN1682680A (en) * | 2004-04-15 | 2005-10-19 | 花王株式会社 | Hair cosmetic composition |
| KR20060007079A (en) * | 2004-07-13 | 2006-01-24 | 주식회사 엘지생활건강 | Hairdye composition comprising cationic surfactant |
| CN101018540A (en) * | 2004-09-09 | 2007-08-15 | 威娜股份有限公司 | Hair-conditioning composition |
| CN101336103A (en) * | 2005-12-16 | 2008-12-31 | 荷兰联合利华有限公司 | Hair treatment compositions |
| JP4865574B2 (en) * | 2007-01-15 | 2012-02-01 | ホーユー株式会社 | Hair treatment composition and hair treatment method |
| US20080299063A1 (en) * | 2007-05-31 | 2008-12-04 | Kao Corporation | Hair cosmetic composition |
| CN104622706A (en) * | 2008-04-25 | 2015-05-20 | 欧莱雅 | Use of a cosmetic composition combined with a composition for treating and/or washing keratinous fibres |
| KR20120095321A (en) * | 2011-02-18 | 2012-08-28 | 가부시키가이샤 써니 플레이스 | Hair treatment |
| US20120230935A1 (en) * | 2011-03-08 | 2012-09-13 | Somang Cosmetics Co., Ltd. | Solvent composition for one-step permanent wave and hair straightener |
| KR20130114468A (en) * | 2012-04-09 | 2013-10-18 | 주식회사 엘지생활건강 | Cosmetic compositon for hair and method for hair tretments using the same |
| CN104540495A (en) * | 2012-06-04 | 2015-04-22 | Elc管理有限责任公司 | Compositions and methods for enhancing the structure of hair fibers |
| KR20140090007A (en) * | 2013-01-08 | 2014-07-16 | 주식회사 엘지생활건강 | Semi-permanent moisturizing treatment composition making hydrophobic surface |
| CN105902404A (en) * | 2016-06-14 | 2016-08-31 | 知识产权全资有限公司 | Hair strengthening ingredient and method |
Non-Patent Citations (3)
| Title |
|---|
| TOMOTAKE MORITA等: "Glycolipid Biosurfactants, Mannosylerythritol Lipids, Repair the Damaged Hair", 《JOURNAL OF OLEO SCIENCE》 * |
| 徐淑芹: "美发护发化妆品中的植物蛋白", 《日用化学工业》 * |
| 福建片仔癀化妆品有限公司: "网址：http://ftba.nmpa.gov.cn:8181/ftban/itownet/hzp_ba/fw/pz.jsp?processid=20160531085911dk8dh&nid=20160531085911dk8dh", 《片仔癀养润调理护发素》 * |
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| Publication number | Publication date |
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| CN109789071B (en) | 2022-03-15 |
| WO2018062697A1 (en) | 2018-04-05 |
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