CN105640790B - Cosmetic composition for hair containing maleic acid as active ingredient - Google Patents
Cosmetic composition for hair containing maleic acid as active ingredient Download PDFInfo
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/362—Polycarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
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Abstract
The present invention relates to a cosmetic composition for hair containing maleic acid (maleic acid) as an active ingredient, and more particularly, to a cosmetic composition for hair which thickens hair by increasing the diameter of hair after entering the interior of hair, thereby increasing the volume of hair. By the cosmetic composition of the present invention comprising maleic acid (maleic acid) as an active ingredient, an increase in the diameter of hair is induced in a short time, so that an effect capable of increasing the volume of hair can be obtained.
Description
Technical Field
The present invention relates to a cosmetic composition for hair containing maleic acid (maleic acid) as an active ingredient, and more particularly, to a cosmetic composition for hair which thickens hair by increasing the diameter of hair after entering the interior of hair, thereby increasing the volume of hair.
Background
Hair has the characteristic of being susceptible to external environmental influences. Factors such as ultraviolet rays, cold dry wind, indoor heating and unreasonable combing, mental stress, insufficient nutrition, insufficient sleep or excessive dyeing can greatly advance or delay the aging of hair. Once aged hair needs to be managed carefully on a regular basis due to its lack of self-healing ability.
In modern society, there are few people who are not under mental stress. Among hair aging factors in men and women, mental stress has gradually increased in proportion. Stress in the society aggravates stress in modern people, and such stress acts as an important factor that promotes hair aging.
Further, recently, as modern people regard hair as fashion, concern about styling has increased, and situations in which styling-related products are used excessively or a hair dryer is used for a long time have increased, thereby accelerating aging of hair. The aging of hair caused by the above factors causes the phenomena of increased hair loss and hair thinning. As hair loss increases and hair becomes thinner, the need for exuberant hair fullness is greatly increasing.
In order to meet the demand for exuberant hair fullness as described above, various attempts have been made. Although it is intended to solve the problem of hair loss and hair thinning by using an anti-alopecia agent, a hair tonic, or the like, it actually takes a long time to obtain an effect on the hair loss and hair thinning. At present, as a method for solving the phenomenon of hair thinning in a short time, a method of coating the outside of hair with a polymer is mainly used. However, in the case of thinned hair, it is actually difficult to effectively increase the fullness of the hair only by the external coating of the hair because the strength inside the hair is greatly reduced, and there is a limit in maintaining the effect thereof for a long time. Therefore, compounds that are absorbed into the hair to solve the phenomenon of hair thinning have recently been reported. However, in most cases, the following chemical formulas I to III hold potential amine groups, and thus there is a problem in that the application is limited. There is a problem that the neutralization with an acid is troublesome and the effect cannot be maintained when the neutralization with an acid is carried out.
[ chemical formula I ] 3-aminopropyltriethoxysilane ((3-aminopropy) triethoxysilane)
[ chemical formula II ] caffeine (caffeine)
[ chemical formula III ] Niacinamide
Further, in korean laid-open patent publication No. 2001-0104681, korean registered patent publication No. 1038423 and korean registered patent publication No. 0459636, a copolymer containing a maleic acid repeating unit is often used in a polymer form for preventing hair or skin from aging and damage. On the other hand, U.S. patent publication No. 2013-309190 discloses a cosmetic composition containing a copolymer having a maleic acid repeating unit, a polyamine, a neutralizer and the like for hair styling. However, when a polyamine is used, there is a disadvantage that a neutralizing agent must be used, and when a polymer is used, there is a disadvantage that the styling effect is reduced for a long time because the polymer hardly penetrates into the hair. In this case, since the polymer is used in a polymer form and has a large molecular weight, it cannot be directly absorbed into the hair, and it is difficult to expect an effect of increasing the hair diameter by such a form of transmission.
Further, in Korean laid-open patent publication Nos. 2006-: the lifted cuticle of the hair is injured by straightening, and the surface state of the hair is made soft or tight (straining).
Disclosure of Invention
In order to solve the above problems, the present invention provides a cosmetic composition comprising maleic acid (maleic acid) corresponding to a low-molecular monomer compound as an active ingredient, and a method for inducing an increase in hair diameter in a short time by rapid penetration of the monomer compound into hair, thereby effectively increasing the volume of hair and delaying aging.
The present invention relates to a cosmetic hair composition containing maleic acid (maleic acid) as an active ingredient.
In the present invention, although not limited, the above-described cosmetic composition for hair may be used to induce an increase in hair diameter.
In the present invention, the above maleic acid may be contained in an amount of 0.001 to 10% by weight relative to the total weight of the composition, although not limited thereto.
In the present invention, the cosmetic composition may be in the form of a hair lotion, a hair tonic lotion, a hair essence
Hair-care essence
Shampoo and hair conditioner
Hair care liquid
Hair cream, styling agent, hair dye, hair bleach or hair mousse.
In the present invention, although not limited thereto, the above composition may further comprise a foaming agent, a cleansing agent, a conditioning agent selected from the group consisting of
One or more of pH regulator, pearling agent, antiseptic, perfume and viscosity regulator.
In the present invention, the above cosmetic composition is absorbed into the hair to play a role of increasing the diameter of the hair.
Furthermore, the present invention relates to a method for treating hair, comprising a step of drying after treating the hair with the cosmetic composition.
By the cosmetic composition of the present invention comprising maleic acid (maleic acid) as an active ingredient, an increase in hair diameter is induced in a short time, so that an effect of being able to increase the volume of hair can be obtained.
Drawings
Fig. 1 is a hair bundle used for measuring hair diameter.
Detailed Description
The present invention relates to a cosmetic hair composition containing maleic acid (maleic acid) as an active ingredient.
Maleic acid (also called maleic acid) has the formula HOOCCH ═ CHCOOH as an unsaturated organic dibasic acid. It is used for the production of reinforcing fibers or paints (paint vehicle) for laminated molds, fumaric acid, and various chemicals, and maleic acid and maleic anhydride are industrially produced by oxidizing benzene in the presence of a catalyst. Maleic acid is widely used as a raw material for producing a polyester by a reaction with ethylene glycol, and also as a raw material for producing an anhydride by a dehydration reaction.
Fumaric acid (fumaric acid), a fumaric acid, which is a geometric isomer of maleic acid, is found in medicinal viola globosa (Fumaria officinalis) and various fungi and sea sedge icelandica (Iceland moss). It is known as a starting material for producing polyesters and the like, such as maleic acid, and also as a sour seasoning for foods. Fumaric acid can be obtained by isomerization of maleic acid or fermentation of molasses, and does not form an anhydride. But has the following characteristics: the amount of dissolution in water or most other solvents is significantly less than in maleic acid.
In the present invention, although not limited, the above-described cosmetic composition for hair may be used to induce an increase in hair diameter.
In the present invention, the above maleic acid may be contained in an amount of 0.001 to 10% by weight relative to the total weight of the composition, although not limited thereto.
The cosmetic hair composition according to the present invention may be contained in an amount of 0.001 to 10 wt%, more preferably 0.1 to 5 wt%, based on the total weight of the composition, in order to be absorbed into the hair and exhibit an effect of preventing hair aging. When the content of the cosmetic hair composition is less than 0.001 wt%, the intended effect cannot be normally exhibited due to the small content, and when the content exceeds 10 wt%, the formulation is difficult, and therefore, the content is preferably in the above range.
In the present invention, the cosmetic hair composition may contain, as an active ingredient, at least one selected from the group consisting of 3-aminopropyltriethoxysilane (3-aminopropy), caffeine (caffeine), nicotinamide (niacinamide), succinic acid (succinic acid), fumaric acid (fumaric acid), maleamic acid (maleamic acid), and maleimide (maleimide) together with maleic acid (maleic acid). From the results obtained in one example of the present invention, it was confirmed that, in the case where only maleic acid was used as the active ingredient of the cosmetic composition for hair among the above-mentioned compounds, the remaining hair ratio (%) and the hair diameter increase ratio (%) were remarkably excellent as compared with the composition containing only the remaining compounds excluding maleic acid, and that, as a result of measuring the remaining hair ratio (%) and the hair diameter increase ratio (%) using the cosmetic composition for hair containing maleic acid and the mixture of maleic acid and other compounds as described above as the active ingredient, the hair diameter increase effect was more improved as compared with the case where only maleic acid was used as the active ingredient. It is thus possible to obtain a significant synergistic effect which cannot be predicted from compositions consisting of monomeric compounds by mixing maleic acid with the remaining compounds.
In the present invention, the formulation of the cosmetic composition may be a hair lotion, a hair tonic, a hair essence, a hair conditioner, a hair lotion, a hair conditioner, a hair cream, a styling agent, a hair dye, a hair bleach or a hair mousse, and preferably, it may be prepared into a shampoo or a hair conditioner by a method known in the art.
In the present invention, although not limited thereto, the above composition may further comprise one or more selected from the group consisting of foaming agents, cleansing agents, conditioning agents, pH adjusting agents, pearlizing agents, preservatives, perfumes, and viscosity adjusting agents. In the present invention, the above cosmetic composition is absorbed into the hair to play a role of increasing the diameter of the hair.
As an example, although not limited, the shampoo containing the hair cosmetic composition according to the present invention may further contain antibiotics, binders, disintegrants, diluents, lubricants, stabilizers, moisturizers, lower alcohols, viscosity increasing agents, chelating agents, pigments, etc. together with foaming agents, cleansing agents, conditioners, pH regulators, pearlescers, preservatives, perfumes, and viscosity regulators, which are generally used in the art.
The foaming agent and the cleansing agent may contain an anionic surfactant, a amphoteric (zwitter) ionic or amphoteric surfactant, a nonionic surfactant, or a combination thereof.
The anionic surfactant may be selected from the group consisting of alkyl sulfates, alkyl sulfonates, alkyl carboxylates, alkyl ether sulfates, alkyl isethionates, alkyl taurates, alkyl sulfosuccinates, alkyl sulfoacetates, alkyl phosphates, anionic amino acid derivatives, anionic polypeptide derivatives, anionic derivatives of alkylpolyglucosides, fatty acid soaps, and mixtures thereof, and the alkyl sulfates may be Ammonium Lauryl Sulfate (ALS), Ammonium Lauryl Sulfate (ALES), Sodium Lauryl Sulfate (SLS), Sodium Lauryl Sulfate (SLES), or the like. The anionic surfactant is preferably used alone or in combination of 2 or more, and is used in an amount of 1 to 25 wt%, preferably 5 to 20 wt%, based on the total weight of the entire composition.
The zwitterionic or amphoteric surfactant is not limited but may be (C)8-C20) Alkyl betaines, N- (C)8-C20) Alkyl radicalAmide betaine and its derivatives, glycine derivatives, sulfobetaine and its derivatives, (C)8-C20) Alkyl polyaminocarboxylates, (C)8-C20) The alkylamphoacetates, sodium lauroamphoacetates and mixtures thereof can be preferably used as selected from the group consisting of amine oxides, cocoamphocarboxyglycinates, cocamidopropyl betaines and mixtures thereof, and are preferably used in an amount of less than 10% by weight relative to the total weight of the total composition.
The nonionic surfactant can be selected from block copolymer of polyethylene oxide and polypropylene oxide, alkyl and polyalkyl esters of polyethylene oxide, and oxyalkylene alcohol
Alkyl and polyalkyl ethers of polyethylene oxide, alkyl and polyalkyl esters of sorbitan polyoxyethylated, alkyl and polyalkyl ethers of sorbitan polyoxyethylated, alkyl and polyalkyl glycosides or polyglycosides, alkyl and polyalkyl esters of sucrose, alkyl and polyalkyl esters of glycerol polyoxyethylated, alkyl and polyalkyl ethers of glycerol polyoxyethylated, Gemini Surfactants, alkyl alcohol systems and mixtures thereof, and is preferably used in an amount of less than 10% by weight relative to the total weight of the total composition.
The conditioning agent may be selected from among polydimethylsiloxane bases (dimethicone bases), hydrogenated polyprenes, and cationic polymers, and these are used alone or in combination of 2 or more, and are used in an amount of 0.1 to 10 wt%, preferably 0.5 to 5 wt%, based on the total weight of the entire composition.
The pH adjuster is not limited, but a known pH adjuster such as sulfonic acid, hydrochloric acid, phosphoric acid, acetic acid, lactic acid, sodium phosphate, disodium phosphate, citric acid, sodium citrate, and the like can be used, and these can be used alone or in combination of 2 or more, and is used in an amount of 0.1 to 2 wt% based on the total weight of the entire composition.
As the pearlizing agent, ethylene glycol distearate, ethylene glycol monostearate, fatty acid, and the like can be mentioned. As the antiseptic, methyl paraben, propyl paraben, sodium benzoate, methylchloroisothiazolinone, methylisothiazolinone, etc. may be used singly or in admixture of 2 or more. As the viscosity modifier, cocamide MEA, cocamide DEA, sodium chloride, or the like, which is an amide-based nonionic surfactant, can be used.
In addition, among the components that can be additionally contained, as the humectant, glycine, propylene glycol, 1, 3-butylene glycol, dipropylene glycol, sorbitol, and the like can be used without limitation, and as the thickener, a water-soluble polymer compound such as methyl cellulose, hydroxyethyl cellulose, carrageenan, carboxymethyl cellulose, hydroxymethyl cellulose, xanthan gum and derivatives thereof, guar gum and derivatives thereof, acacia gum and derivatives thereof, gum arabic and derivatives thereof, carbomer (carbopol) and derivatives thereof, and the like can be used without limitation. As the pigment, a base for a general scalp and hair preparation can be used without particular limitation.
As another example, in the hair care composition containing the hair cosmetic composition according to the present invention, appropriate components may be added depending on the kind thereof, and for example, a cationic surfactant, i.e., tertiary amidoamine and quaternary ammonium compound, a high melting point compound, a silicone compound, and a preservative, a thickener, a viscosity modifier, a pH modifier, a perfume, and the like as general hair care composition components may be contained.
In the above-mentioned hair care liquid for preventing hair damage, the quaternary ammonium compound as the cationic surfactant may contain an alkyl group (C)14-C22) Trimethyl ammonium chloride, dialkyl (C)14-C22) Dimethyl ammonium chloride, hydrogenated tallow alkyl trimethyl ammonium chloride, ditallow alkyl dimethyl ammonium chloride, and the like. Tertiary amidoamines include, for example, cocamidopropyl dimethylamine, stearamidopropyl dimethylamine, behenamidopropyl dimethylamine, oleamidopropyl dimethylamine and isostearoyl dimethylamineAminopropyldimethylamine, and the like. Further, the amines are preferably neutralized with an acid such as L-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, citric acid, or EDTA. These cationic surfactants are suitably used singly or in admixture of 2 or more, and are used in an amount of 1 to 30% by weight, preferably 5 to 20% by weight, relative to the total weight of the entire composition.
The high melting point compound is a compound formed of a fatty alcohol, a fatty acid, a fatty alcohol derivative, a hydrocarbon, and the like, and a mixture thereof, and may include, for example, cetyl alcohol, stearyl alcohol, and cetostearyl alcohol, and the like, and the content thereof may be 1 to 10% by weight relative to the total weight of the hair care liquid. The above-mentioned silicone compound may include polyalkylsiloxane-based, polyarylsiloxane-based, polyalkylarylsiloxane-based, polyether siloxane copolymer and a mixture thereof, and cyclic polysiloxane, an appropriate alkylamino-substituted compound, and amino-terminated polydimethylsiloxane, etc., and may be contained in an amount of 1 to 10% by weight relative to the total weight of the hair care liquid.
The above-mentioned optional components are generally optional components for maintaining basic physical properties and qualities, and are widely known to experts in the field. As specific examples, antibiotics, binders, disintegrants, diluents, lubricants, stabilizers, humectants, lower alcohols, viscosity increasing agents, chelating agents, pigments, and the like can be appropriately selected and used together with preservatives, viscosity increasing agents, viscosity adjusting agents, pH adjusting agents, and perfumes.
The method for preparing the composition of the present invention into the form of a hair rinse, a hair tonic lotion, a hair essence, a hair conditioner, a hair cream, a styling agent, a hair dye, a hair bleach or a hair mousse using the above-mentioned components is not particularly limited, and a conventional method known in the art may be used without limitation.
Furthermore, the present invention relates to a method for treating hair with a composition comprising a step of drying after treating hair with the above composition.
The present invention will be described in more detail below with reference to examples. These examples are provided only to assist understanding of the present invention and the scope of the present invention is not limited to these examples in any sense.
In the present invention, the term "main component substance" is used to mean the compounds described in the following table 1 including maleic acid, which is the most important factor in the hair diameter increasing composition, for the sake of naming.
[ Experimental example 1] measurement of remaining Hair percentage
The hair tress (phoenix korea, korea) of fig. 1 was sufficiently washed with a conventional shampoo, dried in the dark, and then measured for mass 3 times using an electronic scale (AG204, Mettler Toledo), and an average value thereof was calculated.
The main component substance 1g was dissolved in distilled water 100g, and the above-mentioned dried hair strands were immersed for 30 minutes each. The hair tresses were taken out, the mass was measured 3 times as described above, and the average value thereof was calculated.
The remaining hair ratio was determined from the following equation I using the data obtained by the above measurement.
[ mathematical formula I ]
Hair survival rate (%) { (M-M)0)/M0}*100(％)
M: quality of hair strand treated with principal component substance
M0: quality of hair tresses before treatment with principal component substances
Experimental example 2 Hair diameter measurement
The same hair tresses as used in the above experimental example 1 were thoroughly washed with a conventional shampoo, dried in the dark, and then measured for the average diameter with an electron microscope (Eclipse 80i, Nikon) for 10 strands of hair. The 10 hair strands were removed from the bundle and fixed to a slide showing graduations.
After 1g of the main component substance was dissolved in 100g of distilled water, the strands of hair fixed as described above were immersed for 30 minutes each, washed 5 times with a shampoo, and then dried. Thereafter, the strand was subjected to the immersion treatment for 30 minutes and then to the drying process, and finally treated 10 times.
Thereafter, the average diameter of the strands of hair was measured in the same manner as described above.
The hair diameter increase rate was determined from the following equation II using the data obtained by the above measurement.
[ mathematical formula II ]
Hair diameter increase rate (%) { (D-D)0)/D0}*100(％)
D: diameter of hair treated with main component substance
D0: diameter of hair before treatment with the main component substance.
Experimental example 3 Hair diameter measurement 2
The same hair tresses as used in the above experimental example 1 were thoroughly washed with a conventional shampoo, dried in the dark, and then measured for the average diameter with an electron microscope (Eclipse 80i, Nikon) for 10 strands of hair. The 10 hair strands were removed from the bundle and fixed to a slide showing graduations.
After 0.5g of the primary component substance 1 time was dissolved in 100g of distilled water, the strands of hair fixed as described above were immersed for 30 minutes each, washed 5 times with a shampoo, and then dried. Thereafter, the strand was subjected to the immersion treatment for 30 minutes and then to the drying process, and finally treated 10 times.
Thereafter, 0.5g of the secondary main component substance was dissolved in 100g of distilled water, and then the strand of hair treated with the primary main component substance 1 was subjected to the immersion treatment repeatedly for 30 minutes each and then dried, and finally treated 10 times.
Thereafter, the average diameter of the strands of hair was measured in the same manner as described above.
The hair diameter increase rate was determined from the above equation II using the measured data.
[ example 1]
The remaining hair ratio (%) and the increase in hair diameter (%) were measured by the methods of the above experimental examples 1 and 2 using maleic acid (maleic acid) as a main component.
Comparative example 1
The remaining hair ratio (%) and the hair diameter increase ratio (%) were measured by the same procedures as in example 1, except that the main component substance was not used and only distilled water was used for the treatment.
Comparative example 2
The remaining hair ratio (%) and the hair diameter increase ratio (%) were measured by the same procedure as in example 1, except that 3-aminopropyltriethoxysilane of the above chemical formula I was used as a main component substance.
Comparative example 3
The remaining hair ratio (%) and the hair diameter increase ratio (%) were measured by the same procedure as in example 1, except that caffeine (caffeine) of the above chemical formula II was used as a main component.
Comparative example 4
The remaining hair ratio (%) and the hair diameter increase ratio (%) were measured by the same procedure as in example 1, except that nicotinamide of the above chemical formula III was used as the main component substance.
Comparative example 5
The remaining hair ratio (%) and the hair diameter increase ratio (%) were measured by the same procedure as in example 1, except that succinic acid (succinic acid) in a form having no double bond in maleic acid was used as a main component.
Comparative example 6
The remaining hair ratio (%) and the hair diameter increase ratio (%) were measured by the same procedures as in example 1, except that fumaric acid (fumaric acid) in which the double bond of maleic acid was changed from cis (cis) to trans (trans) was used as the main component.
Comparative example 7
The remaining hair ratio (%) and the hair diameter increase ratio (%) were measured by the same procedure as in example 1, except that maleic amide acid (maleamic acid) in which 1 carboxyl group of maleic acid was changed to an amide group was used as the main component.
Comparative example 8
The remaining hair ratio (%) and the hair diameter increase ratio (%) were measured by the same procedure as in example 1, except that maleimide (maleimide) in which 2 carboxyl groups of maleic acid were changed to amide groups was used as the main component.
The results of example 1, comparative example 1 to comparative example 8 are shown in tables 1 and 2.
[ Table 1]
(mass: g)
[ Table 2]
(diameter: μm)
| Principal component substance | D0 | D | The rate of increase in diameter% | |
| Example 1 | Maleic acid | 97.02 | 101.73 | 4.85％ |
| Comparative example 1 | Water (W) | 74.33 | 74.48 | 0.20％ |
| Comparative example 2 | 3-aminopropyltriethoxysilane | 79.12 | 81.74 | 3.31％ |
| Comparative example 3 | Caffeine | 84.10 | 84.51 | 0.49％ |
| Comparative example 4 | Nicotinamide | 83.72 | 84.10 | 0.45％ |
| Comparative example 5 | Succinic acid | 83.42 | 83.75 | 0.40％ |
| Comparative example 6 | Fumaric acid | 86.95 | 87.41 | 0.53％ |
| Comparative example 7 | Maleamic acid | 83.11 | 83.46 | 0.42％ |
| Comparative example 8 | Maleimide | 83.31 | 83.69 | 0.46％ |
As can be seen from the results of tables 1 and 2, the results of hair treatment with the composition for hair containing maleic acid according to the present invention were 5.2% and 4.85%, respectively, and the residual rate (%) and the diameter increase rate (%) were increased by 53% at the maximum and 10 times or more at the maximum, compared to the control group, thereby providing significantly excellent effects.
In particular, when compared with the results of treatment with the main component substance compounds of comparative examples 2 to 4 having an amine group, which have been used as compounds that are absorbed into hair after coating the outside of hair to solve the phenomenon of hair thinning, it was also confirmed that the remaining rate (%) of hair was increased to about 20% with respect to comparative example 2 and the hair diameter increase rate was increased by about 10 times or more with respect to comparative example 4, and surprisingly, the hair diameter increase rate was increased by about 47% with respect to comparative example 2, and the effect of hair diameter increase was remarkable as compared with the main component substance that has been widely used in the past.
Further, it has significantly excellent effects compared to the maleic acid-like compounds of comparative examples 5 to 8, and thus it can be seen that the effect of increasing hair diameter of maleic acid is due to the unique structural features of maleic acid.
[ example 2]
The remaining hair ratio (%) was measured by the methods of the above-mentioned experimental examples 1 and 3 using 3-aminopropyltriethoxysilane of the above-mentioned chemical formula I as a 1-order main component substance and maleic acid (maleic acid) as a 2-order main component substance.
Comparative example 9
The remaining hair ratio (%) was measured by the same procedure as in example 2, except that 3-aminopropyltriethoxysilane of the above chemical formula I was used as the 2-fold main component substance.
Comparative example 10
The remaining hair ratio (%) was measured by the same procedure as in example 2, except that caffeine (caffeine) of the above chemical formula II was used as the 2 nd order major component.
Comparative example 11
The remaining hair ratio (%) was measured in the same manner as in example 2 except that nicotinamide of the above chemical formula III was used as the 2-time main component substance.
Comparative example 12
The remaining hair ratio (%) was measured by the same procedure as in example 2, except that succinic acid (succinic acid) was used as the 2 nd primary component.
Comparative example 13
The remaining hair ratio (%) was measured by the same procedure as in example 2, except that fumaric acid (fumaric acid) was used as the 2-time main component substance.
The results of example 2, comparative example 9 to comparative example 13 are shown in table 3.
[ Table 3]
(mass: g)
From the results of table 3, it was confirmed that the results of treating hair with the conventional hair diameter-increasing compound such as 3-aminopropyltriethoxysilane of the above chemical formula I and the composition for hair containing maleic acid of the present invention in this order have a combined synergistic effect in which the remaining rate (%) of hair is significantly higher than that of the control group currently in use. In example 2, although maleic acid showed a synergistic effect with 3-aminopropyltriethoxysilane of the above formula I, the synergistic effect is not limited to 3-aminopropyltriethoxysilane.
Formulation example 1 shampoo
Hair shampoos were prepared according to a usual method with the following components and contents.
Maleic acid 5.0g
Sodium lauryl sulfate 1.0g
Polyvinyl alcohol 0.05g
Cetyl alcohol 1.0g
Lauric acid glyceride 0.05g
Incense 0.5g
Sodium benzoate 0.1g
Refined water balance (to 100g)
Formulation example 2 Hair conditioner
The hair care liquid for hair was produced according to a usual method with the following components and contents.
Maleic acid 3.0g
Trimethyl ammonium chloride 1.0g
Polyvinyl alcohol 0.05g
Cetyl alcohol 1.0g
Lauric acid glyceride 0.05g
Incense 1.0g
Sodium benzoate 0.1g
Refined water balance (to 100g)
Formulation example 3 Hair mousse
The hair mousse was produced according to a usual method with the following components and contents
Maleic acid 8.0g
Trimethyl ammonium chloride 1.0g
Polyvinyl alcohol 0.05g
Cetyl alcohol 1.0g
Lauric acid glyceride 0.05g
Incense 1.0g
Sodium benzoate 0.1g
Refined water balance (to 100g)
[ formulation example 4] Hair lotion
The hair rinse is prepared by a usual method with the following components and contents.
Maleic acid 6.0g
Ammonium lauryl sulfate 1.0g
Polyvinyl alcohol 0.05g
Cetyl alcohol 1.0g
Lauric acid glyceride 0.05g
Incense 1.0g
Sodium benzoate 0.1g
Refined water balance (to 100g)
[ formulation example 5] Hair restorer
Maleic acid 5.0g
Ethanol 60.0g
Castor oil 5.0g
Glycerol 3.0g
Strychnos nux-vomica glycoside 0.1g
Proper amount of perfume and pigment
Refined water balance (to 100g)
Formulation example 6 Hair nourishing toning lotion
Maleic acid 5.0g
Trimethyl ammonium chloride 1.0g
Polyvinyl alcohol 0.05g
Cetyl alcohol 1.0g
Lauric acid glyceride 0.05g
Incense 1.0g
Sodium benzoate 0.1g
Refined water balance (to 100g)
[ formulation example 7] Hair-caring essence
Maleic acid 10.0g
Liquid Paraffin 30.0g
Polyethylene glycol 1.0g
Strychnos nux-vomica glycoside 0.2g
Perfume and pigment 0.1g
Refined water balance (to 100g)
[ formulation example 8] Hair-caring essence
Maleic acid 5.0g
3.5g of squalane
Cetyl 2-ethylhexanoate 1.0g
Polyglycerin-2 distearate 0.5g
PEG-10 glyceryl stearate 1.0g
Hexaoctadecanol 1.6g
Glycerol 20.0g
1, 3-butanediol 20.0g
Dipropylene glycol 4.5g
Alkyl methacrylate copolymer 0.07g
Carboxyvinyl Polymer 0.08g
Refined water balance (to 100g)
[ formulation example 9] Hair conditioner
Maleic acid 5.0g
Isobutyl (meth) acrylate 25.0g
Polydimethylsiloxane, a-butyldimethylsilyloxy-w- (d-methacryloxypropyl) 0.1g
Acrylic acid 0.7g
Octadecyl (meth) acrylate 15.0g
Isoparaffin (Isoparaffin hydrocarbon) 50g
Refined water balance (to 100g)
[ formulation example 10] Hair cream
Maleic acid 5.0g
Liquid Paraffin 40.0g
Polyethylene glycol 1.0g
Tween 200.1
Strychnos nux-vomica glycoside 0.2g
Perfume and pigment 0.1g
Refined water balance (to 100g)
Formulation example 11 modeling agent
Maleic acid 10.0g
Hexadecyltrimethylammonium chloride 0.5g
Stearyl trimethyl ammonium chloride 0.5g
Stearyltrimethylammonium hydrolyzed animal protein
0.5g
15.0g of glycerol
Proper amount of perfume and pigment
Refined water balance (to 100g)
[ formulation example 12] Hair dye
Maleic acid 5.0g
Trimethyl ammonium chloride 1.0g
Polyvinyl alcohol 0.05g
Cetyl alcohol 1.0g
Lauric acid glyceride 0.05g
Incense 1.0g
Pigment 5.0g
Sodium benzoate 0.1g
Refined water balance (to 100g)
[ formulation example 13] Hair bleaching agent
Maleic acid 5.0g
Ammonium lauryl sulfate 1.0g
Polyvinyl alcohol 0.05g
Cetyl alcohol 1.0g
Lauric acid glyceride 0.05g
Sodium benzoate 0.1g
Refined water balance (to 100g)
Claims (8)
1. Use of a cosmetic composition for hair comprising maleic acid as a single active ingredient for inducing an increase in hair diameter,
the maleic acid is contained in an amount of 0.001 to 10 wt% based on the total weight of the composition.
2. Use of a cosmetic composition according to claim 1 for inducing an increase in hair diameter, in the form of a rinse, a hair tonic, a shampoo, a conditioner, a hair cream, a styling agent, a hair dye, or a hair bleach.
3. Use of a cosmetic composition according to claim 1 for inducing an increase in hair diameter, characterized in that the cosmetic composition is in the form of a hair care lotion or a hair mousse.
4. Use of a cosmetic composition according to claim 1, in the form of a hair conditioner, for inducing an increase in hair diameter.
5. Use of a cosmetic composition according to claim 1 for inducing an increase in hair diameter, characterized in that the cosmetic composition is in the form of a hair care lotion.
6. Use of a cosmetic composition according to claim 1 for inducing an increase in hair diameter, characterized in that the composition further comprises one or more selected from the group consisting of lathering agents, cleansing agents, conditioning agents, pH adjusting agents, pearlizing agents, preservatives, fragrances and viscosity adjusting agents.
7. Use of a cosmetic composition according to claim 1 for inducing an increase in hair diameter, characterized in that the cosmetic composition is absorbed into the hair to act to increase hair diameter.
8. A method for treating hair, characterized by comprising a step of drying after treating hair with the cosmetic composition according to claim 1 for inducing an increase in hair diameter.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2014-0168005 | 2014-11-28 | ||
| KR1020140168005A KR101922543B1 (en) | 2014-11-28 | 2014-11-28 | Hair cosmetic composition comprising maleic acid as active ingredient |
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| Publication Number | Publication Date |
|---|---|
| CN105640790A CN105640790A (en) | 2016-06-08 |
| CN105640790B true CN105640790B (en) | 2021-04-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510608641.XA Active CN105640790B (en) | 2014-11-28 | 2015-09-22 | Cosmetic composition for hair containing maleic acid as active ingredient |
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| Country | Link |
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| KR (1) | KR101922543B1 (en) |
| CN (1) | CN105640790B (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9095518B2 (en) | 2013-08-01 | 2015-08-04 | Liqwd, Inc. | Methods for fixing hair and skin |
| CN107847400A (en) | 2015-05-01 | 2018-03-27 | 欧莱雅 | Purposes of the activating agent in chemical treatment |
| WO2017091796A1 (en) | 2015-11-24 | 2017-06-01 | L'oreal | Compositions for treating the hair |
| US11213470B2 (en) | 2015-11-24 | 2022-01-04 | L'oreal | Compositions for treating the hair |
| MX2018005829A (en) | 2015-11-24 | 2018-08-01 | Oreal | Compositions for treating the hair. |
| US11135150B2 (en) | 2016-11-21 | 2021-10-05 | L'oreal | Compositions and methods for improving the quality of chemically treated hair |
| US11433011B2 (en) | 2017-05-24 | 2022-09-06 | L'oreal | Methods for treating chemically relaxed hair |
| EP3731801B1 (en) | 2017-12-29 | 2022-03-09 | L'oreal | Compositions for altering the color of hair |
| CN111698982B (en) * | 2018-02-09 | 2024-09-27 | 株式会社资生堂 | Hair treatment composition |
| US11090249B2 (en) | 2018-10-31 | 2021-08-17 | L'oreal | Hair treatment compositions, methods, and kits for treating hair |
| US11419809B2 (en) | 2019-06-27 | 2022-08-23 | L'oreal | Hair treatment compositions and methods for treating hair |
| WO2023227364A1 (en) * | 2022-05-25 | 2023-11-30 | Wella Germany Gmbh | Improving hair structure |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1261090C (en) * | 2001-06-01 | 2006-06-28 | 田中雅也 | Acidic composition for external use and agent for accelerating infiltration of cosmetic preparation, hair-growing agent, and preparation for external use each containing the composition into skin or t |
| CN101062050A (en) * | 2006-04-29 | 2007-10-31 | 北京尼奥克斯生物科技有限公司 | Novel product for improving hair-growing based on nitric oxide and the preparing method thereof |
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| KR100507612B1 (en) * | 1997-12-27 | 2006-04-17 | 주식회사 엘지생활건강 | Color long lasting shampoo compositions |
| KR100761217B1 (en) * | 2001-07-04 | 2007-10-04 | 주식회사 엘지생활건강 | Hair Dyeing Composition |
| JP4313245B2 (en) * | 2004-05-06 | 2009-08-12 | 花王株式会社 | Hair cosmetics |
| KR20060059564A (en) * | 2004-11-29 | 2006-06-02 | 건국대학교 산학협력단 | A hair treatment agent comprising weak acid |
| FR2930438B1 (en) * | 2008-04-25 | 2012-09-21 | Oreal | COSMETIC COMPOSITION COMPRISING AT LEAST ONE ORGANIC COMPOUND OF THE SILICON, AT LEAST ONE CATIONIC SURFACTANT AND AT LEAST ONE ORGANIC ACID, AND A COSMETIC TREATMENT PROCESS USING THE SAME |
| EP2340010B1 (en) * | 2008-10-29 | 2017-08-16 | L'Oréal | Process for relaxing or straightening hair, using weak mono-, di- or tricarboxylic acids with heat |
| US20110104093A1 (en) * | 2009-11-02 | 2011-05-05 | Living Proof, Inc | Hair volumizing compositions and methods |
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2014
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1261090C (en) * | 2001-06-01 | 2006-06-28 | 田中雅也 | Acidic composition for external use and agent for accelerating infiltration of cosmetic preparation, hair-growing agent, and preparation for external use each containing the composition into skin or t |
| CN101062050A (en) * | 2006-04-29 | 2007-10-31 | 北京尼奥克斯生物科技有限公司 | Novel product for improving hair-growing based on nitric oxide and the preparing method thereof |
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|---|---|
| KR101922543B1 (en) | 2018-11-28 |
| KR20160064420A (en) | 2016-06-08 |
| CN105640790A (en) | 2016-06-08 |
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