KR20160064420A - Hair cosmetic composition comprising maleic acid as active ingredient - Google Patents

Abstract

The present invention relates to a cosmetic composition for hair comprising maleic acid as an active ingredient and, more specifically, to a cosmetic composition which enhances hair volume by thickening hair through increasing the hair diameter after entering inside hairs. The cosmetic composition comprising maleic acid of the present invention as an active ingredient induces increase in the diameter of the hairs in a rapid time, and can obtain effects capable of increasing the hair volume.

Description

A hair cosmetic composition comprising maleic acid as an active ingredient (Hair cosmetic composition containing maleic acid as active ingredient)

The present invention relates to a cosmetic composition for hair containing maleic acid as an active ingredient, and more particularly, to a cosmetic composition for increasing the hair volume by increasing the hair diameter by increasing the hair diameter.

Hair has characteristics that are easily affected by the external environment. The aging of the hair may be much earlier or may be delayed due to factors such as ultraviolet light, cold and dry wind, indoor heating and excessive combing, stress, malnutrition, lack of sleep, or excessive dyeing. Once aged hair has no self-healing ability, it needs to be carefully managed on a regular basis.

In modern society, few people are not stressed. In addition to men, stress accounts for a growing proportion of women's hair aging. Social pressure is increasing the stress of modern people, and this stress is an important factor in promoting the aging of hair.

Also, recently, modern people perceive hair as a fashion, and the interest in styling also increases, so that excessive use of styling related products or use of hair dryers for a long time is increasing, and the aging of hair is accelerating . The aging of the hair caused by the above factors causes the hair to fall off and the hair to become thin. The need for a rich hair volume feeling has been greatly increased with the increase of hair removal and thinning of hair.

Various attempts have been made to satisfy the needs for such a rich hair volume feeling. A hair loss preventing agent or a hair restorer is used to solve the problem of thinning of the hair along with the decrease in hair loss. However, it takes a long time to see the effect. Currently, a method of coating the outside of the hair by using a polymer mainly is used as a method for solving the tapering of the hair in a short time. However, in the case of tapered hair, the strength of the inside of the hair is lowered so that it is difficult to realize effective hair volume enhancement only by the external coating of the hair, and there is a limit in maintaining the effect for a long time. Recently, there has been reported a compound which is absorbed in the hair to solve the thinning of the hair. However, in most cases, the compound has a potential amine group as shown in the following general formulas (I) to (III), which is limited in application. If necessary, there is a need to neutralize with acid and there is a possibility that the effect can not be maintained when neutralized with acid.

(3-aminopropyl) triethoxysilane < RTI ID = 0.0 >

Caffeine

[Formula III] niacinamide

Korean Patent Laid-Open Nos. 2001-0104681, 1038423, and 0459636 disclose a copolymer comprising maleic acid repeating units to form a polymer in order to prevent hair or skin aging and damage It is often used. On the other hand, US Patent Publication No. 2013-309190 discloses a cosmetic composition comprising a copolymer containing maleic acid repeating units, a polyamine, a neutralizing agent and the like for hair styling. However, when a polyamine is used, there is a disadvantage in that a neutralizing agent must be used indispensably, and when a polymer is used, there is little penetration into the hair, resulting in a deterioration of styling effect for a long time. In this case, since it is used in the form of a polymer, it can not be absorbed directly into the hair because of its high molecular weight, and therefore it is difficult to expect to obtain the effect of increasing the hair diameter through such transfer.

Korean Patent Laid-Open Publication Nos. 2006-0059564, 2011-0079825, and 2003-0003970 disclose that maleic acid is used in cosmetic compositions for hair, but the horny cuticle layer of damaged hair is prepared to soften the surface state of hair, It is for the purpose of training.

In order to solve the above problems, the present invention provides a cosmetic composition comprising maleic acid corresponding to a single low-molecular compound as an active ingredient, thereby increasing the diameter of the hair within a short period of time To thereby provide a means for effectively increasing the volume of the hair and delaying the aging.

The present invention relates to a hair cosmetic composition comprising maleic acid as an active ingredient.

In the present invention, the hair cosmetic composition is not limited, but may be for inducing an increase in hair diameter.

In the present invention, the maleic acid is not limited, but it may contain 0.001 to 10% by weight based on the total weight of the composition.

The formulation of the cosmetic composition according to the present invention may be a hair lotion, a hair tonic, a hair nutrition lotion, a hair serum, a hair essence, a shampoo, a rinse, a hair conditioner, a hair cream, a styling agent, a hair coloring agent, have.

In the present invention, the composition may further include at least one selected from the group consisting of foaming agents, detergents, conditioning agents, pH adjusting agents, pearlizing agents, preservatives, perfumes and viscosity controlling agents.

In the present invention, the cosmetic composition is absorbed into the hair to increase the diameter of the hair.

The present invention also relates to a method of treating hair comprising treating the hair with a cosmetic composition and then drying the same.

The cosmetic composition comprising the maleic acid of the present invention as an active ingredient can induce an increase in the diameter of the hair within a short period of time and thereby increase the volume of hair through the hair.

Figure 1 is a hair tress used for measuring the hair diameter.

The present invention relates to a hair cosmetic composition comprising maleic acid as an active ingredient.

Maleic acid is also referred to as cis-butenedic acid, which is an unsaturated organic dibasic acid having the structural formula HOOCCH = CHCOOH. Fumaric acid, and many chemicals, and anhydrides of maleic acid and maleic acid are industrially produced by oxidation of benzene in the presence of a catalyst. Maleic acid is widely used as a raw material for producing polyester by reacting with glycol, and is also used as a raw material for producing an anhydride through dehydration reaction.

The geometric isomer of fumaric acid, trans-butenedic acid, is found in Fumaria officinalis and various fungi and Icelandic moss. It is known as a starting material used for the production of polyester such as maleic acid, and is also used as an acidulant for food. Fumaric acid can be obtained by isomerization reaction of maleic acid or by fermentation of molasses and can not form an anhydride. However, there is a characteristic that far less amount is dissolved in water or most other solvents than maleic acid.

In the present invention, the hair cosmetic composition is not limited, but may be for inducing an increase in hair diameter.

In the present invention, the maleic acid is not limited, but it may contain 0.001 to 10% by weight based on the total weight of the composition.

The cosmetic composition for hair according to the present invention may be contained in an amount of 0.001 to 10% by weight, preferably 0.1 to 5% by weight, based on the total weight of the composition, in order to absorb the hair and prevent aging of hair. If the content of the hair cosmetic composition is less than 0.001% by weight, the intended effect can not be exhibited properly because the content is too small. If the content exceeds 10% by weight, it is difficult to formulate the composition.

In the present invention, the cosmetic composition for hair may comprise (3-Aminopropyl) triethoxysilane, caffeine, niacinamide, succinic acid, fumaric acid, maleamic acid, And maleimide as an active ingredient. From the results obtained in one embodiment of the present invention, it can be seen that when only the maleic acid among the above compounds is used as an active ingredient of the hair cosmetic composition, the hair remaining percentage (%) and the hair diameter increasing rate (%) And hair growth rate (%) were measured by using a cosmetic composition for hair including maleic acid and a mixture of maleic acid and another compound as an active ingredient, as described above. As a result, , And the effect of increasing the hair diameter was further improved as compared with the case where maleic acid alone was used as the active ingredient. From this, it was possible to obtain an unpredictable remarkable synergistic effect that could not be obtained from a composition composed of a single compound by mixing maleic acid with the remaining compound.

The formulation of the cosmetic composition according to the present invention may be a hair lotion, a hair tonic, a hair nutrition lotion, a hair serum, a hair essence, a shampoo, a rinse, a hair conditioner, a hair cream, a styling agent, a hair coloring agent, And may be formulated into a shampoo or conditioner, preferably by methods well known in the art.

In the present invention, the composition may further include at least one selected from the group consisting of foaming agents, detergents, conditioning agents, pH adjusting agents, pearlizing agents, preservatives, perfumes and viscosity controlling agents. In the present invention, the cosmetic composition is absorbed into the hair to increase the diameter of the hair.

As an example, the shampoo containing the cosmetic composition for hair according to the present invention may be in the form of an antibiotic, a preservative, a pH adjuster, a pearlizing agent, an antiseptic, a fragrance and a viscosity controlling agent, A binder, a disintegrant, a diluent, a lubricant, a stabilizer, a moisturizer, a lower alcohol, a thickener, a chelating agent, a pigment and the like.

The foaming agent and detergent may include an anionic surfactant, a zwitter ionic or amphoteric surfactant, a nonionic surfactant, or a combination thereof.

Examples of the anionic surfactant include alkyl sulfates, alkyl sulfonates, alkyl carboxylates, alkyl ether sulfates, alkyl isethionates, alkyltaurates, alkyl sulfosuccinates, alkyl sulfoacetates, alkyl phosphates A fatty acid soap, and a mixture thereof. Of these, the alkyl sulfate-based surfactant may be selected from the group consisting of ammonium lauryl sulfate (hereinafter, referred to as " ammonium lauryl sulfate "), anionic surfactant, anionic surfactant, anionic surfactant, anionic surfactant, Sodium lauryl sulfate (ALS), ammonium lauryl ethyl sulfate (ALES), sodium lauryl sulfate (SLS), and sodium lauryl ethyl sulfate (SLES). The anionic surfactant may be used alone or in admixture of two or more thereof in an amount of 1 to 25% by weight, preferably 5 to 20% by weight based on the total weight of the composition.

Also, the zwitterionic or amphoteric surfactants include, but are not limited to, (C ₈ -C ₂₀ ) alkyl betaine, N- (C ₈ -C ₂₀ ) alkylamidobetaine and derivatives thereof, glycine derivatives, and other derivatives thereof, (C ₈ -C ₂₀₎ alkyl polyamino carboxylate, (C ₈ -C ₂₀₎ may be used ammonium acetate, and mixtures thereof with alkyl ampo acetate, sodium laurate, preferably an amine-oxide, Coco amphocarboxy glycinate, cocamidopropyl betaine, and mixtures thereof. It is preferable to use less than 10% by weight based on the total weight of the total composition.

Nonionic surfactants include block copolymers of poly (ethylene oxide) and poly (propylene oxide), alkyl and polyalkyl esters of poly (ethylene oxide), oxyalkylene alcohols, alkyl of poly (ethylene oxide) Polyoxyethylenated alkyl and polyalkyl esters of sorbitan, polyoxyethylene alkyl and polyalkyl ethers of sorbitan, alkyl and polyalkyl glycosides or polyglycosides, alkyl and polyalkyl esters of sucrose , Glycerol may be selected from polyoxyethylenated alkyl and polyalkyl esters, glycerol is selected from polyoxyethylenated alkyl and polyalkyl ethers, gemini surfactants, alkyl alcoholic and mixtures thereof, and the total weight of the composition Less than 10% by weight is preferred.

The conditioning agent may be selected from the group consisting of dimethicone base, hydrogenated polydecene and cationic polymer, and they may be used alone or in admixture of two or more so as to be added in an amount of 0.1 to 10% by weight, preferably 0.5 By weight to 5% by weight.

The pH adjusting agent is not limited, and known pH adjusting agents such as sulfuric acid, hydrochloric acid, phosphoric acid, acetic acid, lactic acid, sodium phosphate, disodium phosphate, citric acid and sodium citrate may be used. By weight based on the total weight of the composition.

As the pearlizing agent, glycol distearate, glycol monostearate, fatty acid and the like can be used. As the preservative, methyl paraoxybenzoate, propyl paraoxybenzoate, sodium benzoate, methylchloroisothiazolinone, methylisothiazolinone, etc. may be used alone or in combination of two or more. As the viscosity modifier, an amide type nonionic surfactant such as cocamide MEA, cocamide DEA, sodium chloride and the like can be used.

The moisturizing agent may be, but not limited to, glycerin, propylene glycol, 1,3-butylene glycol, dipropylene glycol, sorbitol and the like. The thickening agent may be selected from the group consisting of methyl cellulose, hydroxyethyl Water-soluble polymeric compounds such as cellulose, carrageenan, carboxymethyl cellulose, hydroxymethyl cellulose, xanthan gum and derivatives thereof, guar gum and derivatives thereof, acacia gum and derivatives thereof, gum arabic and its derivatives, carboplan and derivatives thereof have. The pigments may be used with any of the bases used in common scalp and hair formulations without any particular limitation.

As another example, suitable conditioners may be added to the conditioner containing the cosmetic composition for hair according to the present invention, for example, as a typical conditioner component, a cationic surfactant such as tertiary amidoamine and 4 A quaternary ammonium compound, a high melting point compound, a silicone compound and optional components such as preservatives, thickeners, viscosity regulators, pH adjusting agents and perfumes.

In the conditioner for preventing hair damage, the quaternary ammonium compound which is a cationic surfactant is alkyl (C ₁₄ -C ₂₂ ) trimethylammonium chloride, dialkyl (C ₁₄ -C ₂₂ ) is methylammonium chloride, hydrogenated tallowalkyltrimethylammonium chloride, And tertiary amidoamines such as cocoamidopropyldimethylamine, stearamidopropyldimethylamine, behenylamidopropyldimethylamine, oleamidopropyldimethylamine, and the like, and the like. Isostearamidopropyldimethylamine, and the like. The amines are preferably neutralized with acids such as L-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, citric acid and EDTA. These cationic surfactants may be used singly or in combination of two or more thereof in an amount of 1 to 30% by weight, preferably 5 to 20% by weight based on the total weight of the composition.

Examples of the high melting point compound include a compound consisting of a fatty alcohol type, a fatty acid type, a fatty alcohol derivative, a hydrocarbon type, etc., and a mixture thereof, for example, cetyl alcohol, stearyl alcohol and cetostearyl alcohol, Can be from 1 to 10% by weight based on the total weight of the conditioner. The silicone compound may include a polyalkylsiloxane-based, polyarylsiloxane-based, polyalkylarylsiloxane-based, polyether siloxane copolymer, and mixtures thereof with a cyclopolysiloxane, a suitable alkylamino substituted compound, and an amodimethicone, The content may be from 1 to 10% by weight based on the total weight of the conditioner.

Such optional ingredients are well known to those skilled in the art as conventional optional ingredients for maintaining basic properties and quality. Specific examples thereof include antibiotics, binders, disintegrants, diluents, lubricants, stabilizers, moisturizers, lower alcohols, thickeners, chelating agents, pigments and the like in combination with preservatives, thickeners, viscosity regulators, pH adjusting agents and perfumes .

The respective components described above can be used to formulate compositions of the present invention in the form of hair lotions, hair tonics, hair nutritional lotion, hair serum, hair essence, rinse, hair cream, styling agent, hair coloring agent, hair bleach or hair mousse The method of formulating is not particularly limited, and general methods known in the art can be used without limitation.

The present invention also relates to a method of treating a hair composition comprising treating the hair with the composition and drying the hair.

Hereinafter, the present invention will be described in more detail by way of examples. However, these embodiments are provided to aid understanding of the present invention, and the scope of the present invention is not limited to these examples in any sense.

The term " main component material " in the present invention is used to mean the compound described in the following Table 1, including maleic acid, which is the most important element in the composition for increasing hair diameter.

[Experimental Example 1] Measurement of residual ratio of hair

The hair tress shown in Fig. 1 (Phoenix Korea, Korea) was thoroughly washed with general shampoo, dried in a dark place, and then mass was measured three times with an electronic balance (AG204; Mettler Toledo).

1 g of the active ingredient was dissolved in 100 g of distilled water, and the dried hair tress was immersed for 30 minutes. The hair tress was taken out, the mass was measured three times as above, and the average value was calculated.

Using the measured data, the hair remaining ratio was calculated from the following formula (I).

≪ RTI ID = 0.0 >

Hair remaining ratio (%) = {(MM ₀ ) / M ₀ } * 100 (%)

  M: mass of hair tress after treatment of main ingredient material

M ₀ : mass of hair tress before treatment of active ingredient material.

[Experimental Example 2] Measurement of hair diameter

The same hair tress used in Experimental Example 1 was thoroughly washed with ordinary shampoo, dried in a dark place, and then the average diameter of 10 hair strands was measured with an electron microscope (Eclipse 80i, Nikon). Ten hair strands were taken from the hair tress and fixed on a slide glass marked with a scale.

1 g of the active ingredient substance was dissolved in 100 g of distilled water, and the thus fixed hair strands were immersed for 30 minutes, washed five times with shampoo, and dried. Then, the process of immersing the hair strand in the hair strand for 30 minutes and then drying was repeated 10 times.

Then, the average diameter of the hair strands was measured in the same manner as described above.

Using the measured data, the hair growth rate was calculated from the following formula (II).

(II)

Hair growth rate (%) = {(DD ₀ ) / D ₀ } * 100 (%)

  D: Diameter of hair after treatment with active ingredient material

D ₀ : Diameter of hair before treatment of active ingredient.

[Experimental Example 3] Measurement of hair diameter 2

The same hair tress used in Experimental Example 1 was thoroughly washed with ordinary shampoo, dried in a dark place, and then the average diameter of 10 hair strands was measured with an electron microscope (Eclipse 80i, Nikon). Ten hair strands were taken from the hair tress and fixed on a slide glass marked with a scale.

0.5 g of the primary active ingredient was dissolved in 100 g of distilled water, and the fixed hair strands were immersed for 30 minutes, washed five times with shampoo, and dried. Then, the process of immersing the hair strand in the hair strand for 30 minutes and then drying was repeated 10 times.

Thereafter, 0.5 g of the secondary active ingredient was dissolved in 100 g of distilled water, and the resulting mixture was immersed in the hair strands treated with the primary active ingredient for 30 minutes and then dried until the hair was finally treated 10 times.

Then, the average diameter of the hair strands was measured in the same manner as described above.

Using the measured data, the hair growth rate was calculated from the formula (II).

[Example 1]

The percentage of hair remaining (%) and the percentage of increase of hair diameter (%) were measured by the methods of Experimental Example 1 and Experiment 2 using maleic acid as a main ingredient material.

[Comparative Example 1]

The hair remaining ratio (%) and the hair growth rate (%) were measured in the same manner except that only the distilled water was used without using the main ingredient material in the above Example 1.

[Comparative Example 2]

In the same manner as in Example 1, except for using (3-Aminopropyl triethoxysilane) represented by the above formula (I), the residual percentage of hair (%) and the percentage of increase of hair diameter (%) were measured.

[Comparative Example 3]

The hair remaining ratio (%) and the hair growth rate (%) were measured in the same manner except that the main ingredient material was the caffeine of the above formula (II).

[Comparative Example 4]

The hair remaining ratio (%) and the hair growth rate (%) were measured by the same procedure except that niacinamide of the formula (III) was used as the main ingredient material in Example 1.

[Comparative Example 5]

In the same manner as in Example 1, except for using succinic acid as a main component material in maleic acid without a double bond, the percentage of hair remaining (%) and the percentage of increasing hair diameter (%) were measured by the same procedure.

[Comparative Example 6]

In the same manner as in Example 1, except that fumaric acid, in which the double bond of maleic acid was changed from cis to trans, was used in the same procedure, and the hair remaining ratio (%) and hair diameter Growth rate (%) was measured.

[Comparative Example 7]

In the same manner as in Example 1, except for using maleamic acid in which one carboxyl group of maleic acid was changed to an amide group, the remaining percentage of hair (%) and percent increase of hair diameter (%) were measured Respectively.

[Comparative Example 8]

The hair remaining ratio (%) and the hair growth rate (%) were measured by the same procedure except that maleimide whose main carboxyl group in the maleic acid was changed to amide group in Example 1 was used .

The results of Example 1 and Comparative Examples 1 to 8 are shown in Tables 1 and 2.

[Table 1]

(Mass: g)

 [Table 2]

                                                        (Diameter: μm)

The results of Table 1 and Table 2 show that the composition for hair containing maleic acid of the present invention was treated with hair to show that the percentage of hair remaining (%) and the percentage of increasing hair diameter (%) were 5.2% and 4.85% , The survival rate was 53% and the diameter increase rate was 10 times or more higher than that of the control group.

(%) In the hair when compared with the results obtained by treating the main component material compounds of Comparative Examples 2 to 4 having an amine group, which has been used as a compound to be absorbed into the hair after coating the outside of the hair and thereby tapering the hair, Was increased to about 20%, the hair diameter increase rate was about 10 times higher than that of Comparative Example 4, and surprisingly, about 47% was increased compared to Comparative Example 2, It was confirmed that there was a remarkable effect of increasing the hair diameter.

In addition, the effect of increasing the hair diameter of the maleic acid appears to be due to the unique structural characteristics of the maleic acid, as it is far superior to the maleic acid-like compounds of Comparative Examples 5 to 8.

[Example 2]

The percentage of hair remaining (%) was measured by the method of Experimental Example 1 and Experimental Example 3 with the primary active material as (3-Aminopropyl triethoxysilane) and the secondary active material as maleic acid.

[Comparative Example 9]

The remaining percentage (%) of hair was measured in the same manner as in Example 2 except that (3-Aminopropyl triethoxysilane) represented by Formula (I) was used as the secondary active ingredient.

[Comparative Example 10]

The hair remaining ratio (%) was measured in the same manner as in Example 2, except that the caffeine of Formula II was used as the secondary active material.

[Comparative Example 11]

The remaining percentage (%) of hair was measured by the same procedure except that niacinamide of the formula (III) was used as the secondary active material in Example 2 above.

[Comparative Example 12]

The hair remaining ratio (%) was measured in the same manner as in Example 2, except that succinic acid was used as the secondary active material.

[Comparative Example 13]

The remaining percentage (%) of hair was measured in the same manner as in Example 2 except that fumaric acid was used as a secondary active material.

The results of Example 2 and Comparative Examples 9 to 13 are shown in Table 3.

[Table 3]

                                                           (Mass: g)

From the results of Table 3, it was found that, when hair was treated sequentially with a compound for increasing hair diameter such as (3-Aminopropyl triethoxysilane) of Formula I and a composition for hair including maleic acid of the present invention, The survival rate (%) was confirmed to be synergistic by the combination which is much higher than the control group currently used. In Example 2, maleic acid synergized with (3-Aminopropyl triethoxysilane) of the above formula (I), but the synergistic effect is not limited to (3-Aminopropyl triethoxysilane).

[Formulation Example 1] Shampoo

Hair shampoos were prepared according to the usual methods with the ingredients and ingredients described below.

5.0 g of maleic acid

1.0 g of sodium lauryl sulfate

0.05 g of polyvinyl alcohol

Cetyl alcohol 1.0 g

0.05 g of glycerin laurylate

Incense 0.5 g

Sodium benzoate 0.1 g

Purified water balance (to 100 g)

[Formulation Example 2] Hair conditioner

A hair conditioner for hair was prepared according to a conventional method with the components and contents described below.

3.0 g of maleic acid

1.0 g of trimethyl ammonium chloride

0.05 g of polyvinyl alcohol

Cetyl alcohol 1.0 g

0.05 g of glycerin laurylate

Fragrance 1.0 g

Sodium benzoate 0.1 g

Purified water balance (to 100 g)

[Formulation Example 3] Hair mousse

A hair mousse for hair was prepared according to a conventional method in terms of the components and contents described below.

8.0 g of maleic acid

1.0 g of trimethyl ammonium chloride

0.05 g of polyvinyl alcohol

Cetyl alcohol 1.0 g

0.05 g of glycerin laurylate

Fragrance 1.0 g

Sodium benzoate 0.1 g

Purified water balance (to 100 g)

[Formulation Example 4] Hair lotion

A hair mousse for hair was prepared according to a conventional method in terms of the components and contents described below.

6.0 g of maleic acid

1.0 g of ammonium lauryl sulfate

0.05 g of polyvinyl alcohol

Cetyl alcohol 1.0 g

0.05 g of glycerin laurylate

Fragrance 1.0 g

Sodium benzoate 0.1 g

Purified water balance (to 100 g)

[Formulation Example 5] Hair tonic

5.0 g of maleic acid

Ethanol 60.0 g

5.0 g of castor oil

3.0 g of glycerin

Roganin 0.1 g

Fragrance, coloring

Purified water balance (to 100g)

[Formulation Example 6] Hair nutritional lotion

5.0 g of maleic acid

1.0 g of trimethyl ammonium chloride

0.05 g of polyvinyl alcohol

Cetyl alcohol 1.0 g

0.05 g of glycerin laurylate

Fragrance 1.0 g

Sodium benzoate 0.1 g

Purified water balance (to 100 g)

[Formulation Example 7] Hair serum

10.0 g of maleic acid

30.0 g of liquid paraffin

1.0 g of polyethylene glycol

0.2 g

Fragrance, coloring 0.1 g

Purified water balance (to 100 g)

[Formulation Example 8] Hair essence

5.0 g of maleic acid

Squalane 3.5 g

Cetyl 2-ethylhexanoate 1.0 g

0.5 g of polyglyceryl-distearate

≪ RTI ID = 0.0 > 10g < / RTI > glyceryl stearate

1.6 g of cetostearyl alcohol

Glycerin 20.0 g

1,3-butylene glycol 20.0 g

4.5 g of dipropylene glycol

0.07 g of an alkyl methacrylate copolymer

0.08 g of carboxyvinyl polymer

Purified water balance (to 100 g)

[Formulation Example 9] Rinse

5.0 g of maleic acid

25.0 g of isobutyl (meth) acrylate

Polydimethylsiloxane, 0.1 g of a-butyldimethylsiloxy-w- (d-methacryloxypropyl)

Acrylic acid 0.7 g

15.0 g of stearyl (meth) acrylate

50 g of isoparaffin hydrocarbon

Purified water balance (to 100 g)

[Formulation Example 10] Hair cream

5.0 g of maleic acid

40.0 g of liquid paraffin

1.0 g of polyethylene glycol

Twin 200.1

0.2 g

Fragrance, coloring 0.1 g

Purified water balance (to 100 g)

[Formulation Example 11] Styling agent

10.0 g of maleic acid

0.5 g of tetiltrimethylammonium chloride

0.5 g of stearyl trimethylammonium chloride

0.5 g of stearatrimethylammonium hydrolyzed animal protein

Glycerin 15.0 g

Fragrance, coloring

Purified water balance (to 100 g)

[Formulation Example 12] Hair coloring agent

5.0 g of maleic acid

1.0 g of trimethyl ammonium chloride

0.05 g of polyvinyl alcohol

Cetyl alcohol 1.0 g

0.05 g of glycerin laurylate

Fragrance 1.0 g

Dye 5.0 g

Sodium benzoate 0.1 g

Purified water balance (to 100 g)

[Formulation Example 13] Hair bleaching agent

5.0 g of maleic acid

1.0 g of ammonium lauryl sulfate

0.05 g of polyvinyl alcohol

Cetyl alcohol 1.0 g

0.05 g of glycerin laurylate

Sodium benzoate 0.1 g

Purified water balance (to 100 g)

Claims (7)

A cosmetic composition for hair comprising maleic acid as an active ingredient. The method according to claim 1,
Wherein the hair cosmetic composition is for inducing an increase in hair diameter. The method according to claim 1,
Wherein the maleic acid is contained in an amount of 0.001 to 10% by weight based on the total weight of the composition. 4. The method according to any one of claims 1 to 3,
Wherein the formulation of the cosmetic composition is a hair lotion, a hair tonic, a hair nutrition lotion, a hair serum, a hair essence, a shampoo, a rinse, a hair conditioner, a hair cream, a styling agent, a hair coloring agent, Cosmetic composition. 4. The method according to any one of claims 1 to 3,
Wherein the composition further comprises at least one member selected from the group consisting of a foaming agent, a detergent, a conditioning agent, a pH adjusting agent, a pearlizing agent, a preservative, a flavoring agent and a viscosity controlling agent. 4. The method according to any one of claims 1 to 3,
Wherein the cosmetic composition is absorbed into the hair to increase the diameter of the hair. A method for treating hair comprising treating the hair with the cosmetic composition according to any one of claims 1 to 3, followed by drying.

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