KR100507612B1 - Color long lasting shampoo compositions - Google Patents
Color long lasting shampoo compositions Download PDFInfo
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- KR100507612B1 KR100507612B1 KR1019970075238A KR19970075238A KR100507612B1 KR 100507612 B1 KR100507612 B1 KR 100507612B1 KR 1019970075238 A KR1019970075238 A KR 1019970075238A KR 19970075238 A KR19970075238 A KR 19970075238A KR 100507612 B1 KR100507612 B1 KR 100507612B1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
Abstract
본 발명은 염색이나 코팅한 모발의 색상을 유지시켜 주는 샴푸 조성물에 관한 것으로, 본 발명에 따른 칼라 지속성 샴푸 조성물은 조성물 총 중량에 대하여 유기산을 0.01 내지 5 중량% 및 아모디메티온을 0.1 내지 6 중량% 포함하여 구성되어 염색한 모발의 칼라를 선명하게 오랫동안 지속시키는데 탁월한 효과를 나타내는 샴푸 조성물을 제공한다.The present invention relates to a shampoo composition for maintaining the color of the dyed or coated hair, the color-lasting shampoo composition according to the present invention is 0.01 to 5% by weight of organic acid and 0.1 to 6 of the amodimethion based on the total weight of the composition It comprises a weight percent to provide a shampoo composition that exhibits an excellent effect for lasting the color of dyed hair vividly long.
Description
본 발명은 염색이나 코팅한 모발의 색상을 유지시켜 주는 샴푸 조성물에 관한 것이다.The present invention relates to a shampoo composition for maintaining the color of the dyed or coated hair.
최근에는 다양한 모발 형태나 색상이 젊은이들에게 개성을 강조해 주는 수단으로 사용되고 있기에 모발 염색이나 코팅이 급격히 증가되고 있다. 그러나 코팅한 모발을 일반 샴푸로 반복적으로 세발하는 경우에는 샴푸시 모발속에 침투한 염모제가 빠져나와 모발의 색상이 코팅한 직후의 선명하고 윤기있는 상태로 지속되지 않는 문제점이 있었다. 이러한 모발 색상의 변화 요인은 주 3-4회의 세발에 의하여 모발에 결합된 염모제가 떨어져 나오기 때문이며 또한 햇빛이나 파마에 의하여 모발이 탈색되기 때문이다.Recently, various hair types and colors have been used as a means of emphasizing individuality among young people, and thus hair dyeing and coating are rapidly increasing. However, in the case of repeatedly washing the coated hair with a general shampoo, there was a problem in that the hair dye penetrated into the hair during shampooing did not come out and the color of the hair did not remain clear and shiny immediately after coating. The reason for the change in hair color is that hair dye bound to the hair is released by three to four times a week, and the hair is discolored by sunlight or perm.
한편, 상기 염모제는 3000년 전의 고대 이집트에서 천연의 광물이나 식물을 이용하여 모발을 염색했던 것을 시작으로 한 것으로 산화염모제는 19세기 후반 파라페닐렌디아민이 발명되어지고 난 후부터 현재까지 널리 사용되고 있다. 일본에서는 명치시대 중반까지는 탄닌산과 철염을 이용한 백발염색이 행하여졌으나 명치후기에는 파라페닐렌디아민을 이용하는 염모제가 사용되어졌다. 이와같은 염모제는 모발에 대하여 우선 색제와 모발의 최외면, 즉 큐티클(cuticle)의 최외층(epicuticle)과의 접촉으로 액체-고체 계면에서의 웨팅(wetting), 어드솝션(adsorption)이라는 계면 현상이 일어나고 다음으로 세포막(cell membrane complex)을 통하여 큐티클, 콜텍스(cortex)내로의 침투, 확산 현상이 일어나며 경우에 따라서는 중합이라는 화학반응이 일어난다.On the other hand, the hair dye is a hair dye using natural minerals and plants in ancient Egypt 3,000 years ago, the oxidation hair dye has been widely used since the invention of paraphenylenediamine in the late 19th century. In Japan, gray hair dyeing with tannic acid and iron salts was carried out until the middle of the Ming Dynasty. However, hair dyes using paraphenylenediamine were used in the late Ming Dynasty. Hair dyes like this are first contacted with the colorant and the outermost surface of the hair, ie the outermost layer of the cuticle, and the interweaving phenomenon called wetting and adsorption at the liquid-solid interface. And then penetrate and diffuse into the cuticle and cortex through the cell membrane complex. In some cases, a chemical reaction called polymerization occurs.
상기 염모제는 염모효과의 지속성에 의하여 일시염모제, 반영구염모제, 영구염무제로 분류되며 염색의 메카니즘도 각각 다른 형태를 취한다. 먼저, 일시염모제는 큐티클 최외층 표면에 안료 또는 염료를 고정함으로써 모발을 염색하는바, 고정단계에 따라서 유지로 부착시키는 칼라스틱, 수용성 폴리머의 젤로 부착시키는 칼라젤, 고분자 수지로 접착시키는 칼라스프레이, 칼라무스 등이 있다. 또한 반영구염모제는 산성염료를 큐티클 및 콜텍스내의 일부가지 침투되어 이온 결합에 의해 침착, 염색된다. 이때 분자량이 큰 염료의 경우에는 벤질 알코올 등의 용제의 캐리어 효과에 의해 침투가 용이해진다. 이러한 메카니즘에 의한 염모제의 지속효과는 1개월 정도이다. 제형으로는 액상, 젤상, 크림상이 있으며, 주로 아조계의 산성 염료가 사용되어진다. 또한 영구염모제는 저분자량의 산화염료인 아민계, 페놀계 화합물을 모발 내부에 침투시켜 산화제가 작용하는 것에 의해 산화 중합과 동시에 고분자체의 색소를 형성하고 콜텍스내에 침착시키는 것으로 콜텍스내에 생성된 색소는 고분자로 되어 있어 모발내로부터 외부로 빠져나가는 것이 불가능하여 염색의 지속성이 영구적이다.The hair dyes are classified into temporary hair dyes, semi-permanent hair dyes, and permanent hair dyes by the persistence of the hair dye effect. The dyeing mechanisms also take different forms. First, the temporary hair dye dyes hair by fixing pigments or dyes on the outermost surface of the cuticle; color sticks attached to fats and oils according to a fixing step, color gels attached with gels of water-soluble polymers, color sprays bonded with polymer resins, Calamus and the like. Semipermanent hair dyes also deposit and dye acidic dyes by ionic bonds through some of the cuticles and cortex in the cortex. At this time, in the case of dye with a large molecular weight, penetration becomes easy by the carrier effect of solvents, such as benzyl alcohol. The lasting effect of hair dye by this mechanism is about 1 month. Formulations include liquid, gel, and cream, and azo acid dyes are mainly used. Permanent hair dyes are also produced in the cortex by infiltrating low-molecular-weight oxidizing dyes, such as amine-based and phenol-based compounds, into the hair to form oxidative polymerizations and to form polymer pigments and to deposit them in the cortex. Since the pigment is made of a polymer, it is impossible to escape from the inside of the hair to the outside, so the persistence of the dye is permanent.
이와같은 염모제를 사용하여 염색한 모발의 색상을 선명하고 오래 지속시키는 방법으로는 샴푸의 pH를 산성으로 낮추는 방법, 계면활성제의 세정력을 낮게 조정하는 방법, 자외선에 의한 탈색을 방지하기 위해 자외선 차단제를 사용하는 방법 등이 있다. 통상 샴푸의 pH는 5.0 내지 7.0 정도이고 이 범위내에 존재하는 샴푸로 반영구염모제로 염색한 모발을 세발할 경우에는 염색한 모발의 색상이 빠지고 윤기를 잃어 염색 초기와 같은 선명한 색상을 유지하기 어려워 모발의 외관이 나빠진다. 이는 염기성 조건하에서는 염모제와 모발의 결합이 약화되어 염모제가 떨어져 나오므로 칼라지속효과가 현저히 감소되기 때문이다.Using such hair dyes to make hair color dyed bright and long lasting can be done by lowering the pH of the shampoo to acidity, adjusting the cleaning power of the surfactant low, and using sunscreen to prevent discoloration by UV rays. How to use, etc. Normally, the pH of the shampoo is about 5.0 to 7.0. When shampooing hairs dyed with semi-permanent hair dye with shampoo existing within this range, the color of the dyed hair is lost and it is difficult to maintain the vivid color as the initial dyeing. Appears worse This is because, under basic conditions, the binding of the hair dye to the hair is weakened, and the hair dye is released, and thus the color sustaining effect is significantly reduced.
이에 본 발명은 상기의 문제점을 해결하기 위해 안출된 것으로, 반영구염모제로 염색한 모발의 칼라를 선명하게 오래 지속시키는 샴푸 조성물을 제공하는 것을 그 목적으로 한다.The present invention has been made to solve the above problems, it is an object of the present invention to provide a shampoo composition that lasts vividly long hair color dyed with a semi-permanent hair dye.
상기 목적을 달성하기 위한 본 발명에 따른 칼라지속성 샴푸 조성물은, 유기산을 조성물 총 중량당 0.01 내지 5 중량%, 아모디메티콘(Amodimethicone)을 0.1 내지 6 중량% 포함하여 구성되는 것을 특징으로 한다.Color persisting shampoo composition according to the present invention for achieving the above object, characterized in that comprises an organic acid 0.01 to 5% by weight, total weight of the composition, 0.1 to 6% by weight of amodimethicone (Amodimethicone).
또한 본 발명에 따른 칼라지속성 샴푸 조성물에 있어서, 상기 유기산은 시트르산, 포름산, 글리콜산, 젖산, 말레인산 살리실산, 소르브산, 숙신산, 타르타르산으로 구성된 군으로부터 선택된 하나 이상인 것을 특징으로 한다.In addition, in the color persistent shampoo composition according to the present invention, the organic acid is characterized in that at least one selected from the group consisting of citric acid, formic acid, glycolic acid, lactic acid, maleic acid salicylic acid, sorbic acid, succinic acid, tartaric acid.
이하 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.
본 발명에 따른 칼라지속성 샴푸 조성물은, 유기산을 조성물 중에 포함하여 샴푸의 pH를 산성 조건으로 조정하여 반영구염모제와 모발과의 이온 결합을 돕고 모발내부에서 염모제의 탈착을 방지해 줌으로써 모발의 색상을 염색 초기와 같이 선명하고 윤기있게 유지시켜 준다.Color-continuous shampoo composition according to the present invention, including the organic acid in the composition to adjust the pH of the shampoo to acidic conditions to help the ionic bond between the semi-permanent hair dye and the hair and to prevent the desorption of the hair dye in the hair dyeing the color of the hair It keeps you clear and shiny like the early days.
또한 본 발명에 따른 칼라지속성 샴푸 조성물은 상기 유기산외에 아민기를 함유한 실리콘인 아모디메티콘(Amodimethicone)을 함께 포함하여 구성될 경우 아모디메티콘의 모발에의 흡착으로 인해 모발 외부를 실리콘으로 코팅해 줌으로써 염모제와 모발의 이온 결합을 보호해 준다.In addition, the color-sustained shampoo composition according to the present invention is coated with the silicone outside of the hair due to the adsorption of the amodimethicone to the hair when it is configured to include amodimethicone which is a silicone containing an amine group in addition to the organic acid This protects the hair's ionic bond from hair.
상기 본 발명에 따른 칼라지속성 샴푸 조성물에 있어서, 상기 유기산은 조성물 총 중량 당 0.01 내지 5 중량%인 것이 바람직하다. 유기산의 함량이 0.01 중량% 미만인 경우에는 그 효과가 미미하고 5중량%를 초과하는 경우에는 그 효과의 현저한 상승이 없었다. 또한 본 발명에 따른 칼라지속성 샴푸 조성물은 상기 유기산과 함께 상기 아모디메티콘을 0.1 내지 6 중량% 포함하여 구성되는바, 아모디메티콘을 0.1 중량% 미만으로 포함하는 경우에는 그 효과가 미미하고 6중량% 초과시에는 조성물의 점도를 떨어뜨려 상안정성에 나쁜 영향을 끼칠 뿐만 아니라 기포가 발생되지 않는다.In the color persistent shampoo composition according to the present invention, the organic acid is preferably 0.01 to 5% by weight per total weight of the composition. When the content of the organic acid is less than 0.01% by weight, the effect is insignificant, and when it exceeds 5% by weight, there is no significant increase in the effect. In addition, the color-lasting shampoo composition according to the present invention comprises 0.1 to 6% by weight of the amodimethicone together with the organic acid, the effect is insignificant when it contains less than 0.1% by weight of amodimethicone. When it exceeds 6% by weight, the viscosity of the composition is lowered, which adversely affects the phase stability and bubbles are not generated.
또한 본 발명에 따른 칼라지속성 샴푸 조성물에 있어서, 상기 유기산은 분자량이 400이하인 시트르산, 포름산, 글리콜산, 젖산, 말레인산 살리실산, 소르브산, 숙신산, 타르타르산으로 구성된 군으로부터 선택된 하나 이상을 포함한다.In addition, in the color-sustained shampoo composition according to the present invention, the organic acid includes at least one selected from the group consisting of citric acid, formic acid, glycolic acid, lactic acid, maleic acid salicylic acid, sorbic acid, succinic acid, tartaric acid having a molecular weight of 400 or less.
이하 본 발명을 실시예 및 비교예에 의하여 상세히 설명한다. 그러나 본 발명은 하기 실시예에 국한되지 않는다. 하기에서 별다른 언급이 없는 한 모든 수치의 단위는 중량%이다.Hereinafter, the present invention will be described in detail by Examples and Comparative Examples. However, the present invention is not limited to the following examples. Unless otherwise stated below, all units are in weight percent.
실시예 1 및 2와 비교예 1 및 2Examples 1 and 2 and Comparative Examples 1 and 2
하기 표 1의 성분 및 비율로 30% 라우릴황산나트륨, 30% 폴리옥시에틸렌라우릴황산나트륨, 야자유지방산디에탄올아미드 및 프로필렌글리콜을 정제수에 첨가하였다. 그런 다음 상기 혼합물에 아모디메티콘을 첨가하여 온도가 60℃가 될 때까지 가온하여 균일하게 용해시킨 후 40℃로 냉각하였다. 그 후 상기 혼합물에 색소, 파라옥시안식향산에스테르, 향료 및 솔빈산을 가한다음 혼합하였다. 이를 냉각시켜 샴푸를 제조하였다.30% sodium lauryl sulfate, 30% polyoxyethylene lauryl sulfate, palm oil fatty acid diethanolamide and propylene glycol were added to the purified water in the components and ratios of Table 1 below. Amodimethicone was then added to the mixture, warmed until it was 60 ° C., uniformly dissolved, and cooled to 40 ° C. Thereafter, a dye, paraoxybenzoic acid ester, perfume and sorbic acid were added to the mixture, followed by mixing. This was cooled to produce a shampoo.
실험예Experimental Example
상기 실시예 및 비교예에 따라 제조한 샴푸의 칼라지속 효과를 알아보기 위하여 다음과 같은 실험을 수행하였다.이때 모발에 직접 일시염모제를 처리하여 칼라지속성을 비교할 경우 실험결과를 객관화시키기 어렵기에 모발에 일시염모제를 처리하는 것과 유사한 메카니즘을 가지는 울(wool)포에 일시염모제를 처리하여 샴푸로 반복처리한 후의 색차를 비교하였다.In order to find out the color persistence effect of the shampoo prepared according to the above Examples and Comparative Examples, the following experiment was performed. In this case, when the hair dye was directly treated on the hair and the color persistence was compared, it was difficult to objectify the experimental results. The color difference after repeated treatment with shampoo by treating the temporary hair dye to a wool fabric having a mechanism similar to that of the temporary hair dye was treated.
즉, 울포를 5cm×5cm 크기로 잘라서 일시염모제를 처리하여 염색한 후 물로 세척하여 건조시켰다. 색도계를 이용하여 염색한 상기 울포의 색상을 측정하였다. 그런 다음 각 샴푸 용액에 상기 울포 5장씩을 넣어 5분간 세척한 후 1분간 물에 씻어내고 건조시켰다. 건조된 울포를 색도계를 이용하여 색상을 측정한 후 그 평균값을 구했다. 상기 조작을 4회 반복하여 초기 색상과 4회 처리 후의 색상과의 색차를 구했다.In other words, the woolen cloth was cut into 5cm × 5cm size, treated with a temporary hair dye, dyed, washed with water and dried. The color of the wool cloth dyed using a colorimeter was measured. Then, 5 pieces of wool cloth were added to each shampoo solution and washed for 5 minutes, and then washed with water for 1 minute and dried. The average color value of the dried woolen cloth was measured using a colorimeter. The above operation was repeated four times to determine the color difference between the initial color and the color after four treatments.
그 결과는 표 2에 나타내었다.The results are shown in Table 2.
상기 표 2에서 △ E는 샴푸용액으로 처리하기 전의 울포의 색도계 측정치에서 샴푸용액으로 4회 처리한 후의 울포의 색도계 측정치를 뺀 값이다. 따라서 상기 값은 수치가 작을수록 칼라지속 효과가 우수한 것을 의미한다.In Table 2, ΔE is a value obtained by subtracting the colorimeter measurement of the woolen cloth after four treatments with the shampoo solution from the colorimeter measurement of the woolen cloth before the treatment with the shampoo solution. Therefore, the smaller the value, the better the color persistence effect.
상기 표 2에서 볼 수 있는 바와 같이 본 발명에 따른 솔빈살과 아모디메티콘이 함유된 샴푸 조성물은 이를 함유하지 않는 기존의 샴푸에 비해 칼라지속 효과가 탁월하였다.As can be seen in Table 2, the shampoo composition containing solval meat and amodimethicone according to the present invention was excellent in color lasting effect compared to the existing shampoo that does not contain it.
이상에서 설명한 바와 같이 본 발명에 따른 칼라지속성 샴푸 조성물은, 유기산 및 실리콘인 아모디메티콘을 포함하여 구성되어 염색한 모발의 칼라를 선명하게 오랫동안 지속시키는데 탁월한 효과를 나타낸다.As described above, the color-lasting shampoo composition according to the present invention comprises an organic acid and silicone amodimethicone, and exhibits an excellent effect of sustaining the color of dyed hair vividly for a long time.
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Publication number | Priority date | Publication date | Assignee | Title |
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KR20190033321A (en) | 2017-09-21 | 2019-03-29 | 주식회사 엘지생활건강 | Hair conditioning composition |
KR20210080162A (en) | 2019-12-20 | 2021-06-30 | 주식회사 엘지생활건강 | Dye dripping relief composition |
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KR101922543B1 (en) * | 2014-11-28 | 2018-11-28 | (주)아모레퍼시픽 | Hair cosmetic composition comprising maleic acid as active ingredient |
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US4526781A (en) * | 1984-04-25 | 1985-07-02 | Revlon, Inc. | Hair care compositions |
US4529586A (en) * | 1980-07-11 | 1985-07-16 | Clairol Incorporated | Hair conditioning composition and process |
US5106613A (en) * | 1990-04-09 | 1992-04-21 | Colgate-Palmolive Company | Hair conditioning shampoo |
US5340367A (en) * | 1993-02-11 | 1994-08-23 | Shiseido Co. Ltd. | Permanent waving and color enhancing composition and method |
US5415857A (en) * | 1989-06-21 | 1995-05-16 | Colgate-Palmolive Company | Hair conditioning shampoos containing aminosilicone conditioning agent |
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US4529586A (en) * | 1980-07-11 | 1985-07-16 | Clairol Incorporated | Hair conditioning composition and process |
US4526781A (en) * | 1984-04-25 | 1985-07-02 | Revlon, Inc. | Hair care compositions |
US5415857A (en) * | 1989-06-21 | 1995-05-16 | Colgate-Palmolive Company | Hair conditioning shampoos containing aminosilicone conditioning agent |
US5106613A (en) * | 1990-04-09 | 1992-04-21 | Colgate-Palmolive Company | Hair conditioning shampoo |
US5340367A (en) * | 1993-02-11 | 1994-08-23 | Shiseido Co. Ltd. | Permanent waving and color enhancing composition and method |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20190033321A (en) | 2017-09-21 | 2019-03-29 | 주식회사 엘지생활건강 | Hair conditioning composition |
KR20210080162A (en) | 2019-12-20 | 2021-06-30 | 주식회사 엘지생활건강 | Dye dripping relief composition |
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