CN109777287A - A kind of anticolodal and its application - Google Patents
A kind of anticolodal and its application Download PDFInfo
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- CN109777287A CN109777287A CN201711111973.2A CN201711111973A CN109777287A CN 109777287 A CN109777287 A CN 109777287A CN 201711111973 A CN201711111973 A CN 201711111973A CN 109777287 A CN109777287 A CN 109777287A
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Abstract
The invention discloses a kind of anticolodals, belong to field of metal surface treatment.Its ingredient and mass fraction are as follows: 5-8 parts of silicone oil, 1-5 parts of glycerine, 0.5-2 parts of polyamide, 1-3 parts of sodium pyrophosphate, 3-5 parts of acetic acid, 3-8 parts of oil-soluble phenolic resin, 7-12 parts of aluminum sulfate, 1-3 parts of citric acid, 3-5 parts of zinc dialkyl dithiophosphate, 70-80 parts of deionized water.Advantages of nontoxic raw materials of the present invention; body will not be damaged in process of production; preservative treatment is carried out to metal using the present invention; layer protecting film can be formed in metal surface, the antiseptic property of metal can not only be enhanced, extend the service life of metal material and device; and no pollution to the environment; it is degradable, it is at low cost, in particular for the incision of galvanized steel plain sheet.
Description
Technical field
The invention belongs to field of metal surface treatment, specifically, being related to a kind of anticolodal and its application.
Background technique
Corrosion of metal often occurs in carrying out processing and use process to metal, to make metal material or metal
The service life of equipment reduces, and there are at high cost, raw material to endanger worker's body due to toxicity for existing anticolodal
The problems such as body health, pollution environment, therefore, it is badly in need of a kind of no pollution to the environment, does not damage the anticolodal of human body health,
Enhance the antiseptic property of metal by the preservative treatment to metal, extend the service life of metal material, workpiece and instrument, saves
The energy, especially very common galvanized steel plain sheet, purposes is wide, but anti-corrosion effect is undesirable, and especially galvanized steel plain sheet is in metal plate
It is sheared and is punched etc. in gold process processing in the case where having destruction to matrix, incision is easiest to be damaged, kindred circumstances
Under corroded at first, become the erosion-resisting short slab of galvanized steel plain sheet.
Summary of the invention
1, it to solve the problems, such as
For existing preservative during the preparation process due to raw material have toxicity and damage human health, pollution environment and cost compared with
High problem, the present invention provide a kind of anticolodal and its application, can effectively prevent the anti-corrosive properties of the raising metal of metal
Can, environmental pollution is minimum, human health will not be damaged in use process, and at low cost, easy to spread.
2, technical solution
To solve the above problems, the technical solution of the present invention is as follows:
A kind of anticolodal and its application, ingredient and mass fraction are as follows:
5-8 parts of silicone oil；
1-5 parts of glycerine；
0.5-2 parts of polyamide；
1-3 parts of sodium pyrophosphate；
3-5 parts of acetic acid；
3-8 parts of oil-soluble phenolic resin；
7-12 parts of aluminum sulfate；
1-3 parts of citric acid；
70-80 parts of deionized water.
Preferably, the silicone oil is methyl-silicone oil, and oil-soluble phenolic resin is the short oil using dimethylbenzene as solvent
Oil-soluble phenolic resin.
Preferably, component and its mass fraction are as follows:
5 parts of silicone oil；
3 parts of glycerine；
2 parts of polyamide；
3 parts of sodium pyrophosphate；
4 parts of acetic acid；
3 parts of oil-soluble phenolic resin；
7 parts of aluminum sulfate；
1 part of citric acid；
75 parts of deionized water.
The application of sodium pyrophosphate or glycerine or zinc dialkyl dithiophosphate in anti-corrosion of metal.
Application of the preservative of previous methods preparation in panel beating.
3, beneficial effect
Compared with the prior art, the invention has the benefit that
(1) present invention is by silicone oil, glycerine, polyamide, sodium pyrophosphate, acetic acid, oil-soluble phenolic resin, aluminum sulfate, citric acid
It is formed with deionized water, advantages of nontoxic raw materials of the present invention in process of production will not damage body, use this hair
It is bright that preservative treatment is carried out to metal, layer protecting film can be formed in metal surface, the antiseptic property of metal can not only be enhanced, prolonged
It is the service life of long metal material and device, and no pollution to the environment, degradable, it is at low cost, in particular for cutting for galvanized steel plain sheet
At mouthful；
(2) the silicone oil heat resistance and chemical stability that the present invention uses are good, and oil-soluble phenolic resin not only has water-fast well
Property, acid resistance, the addition of sodium pyrophosphate, glycerine and zinc dialkyl dithiophosphate, so that the film hardness of made preservative is high
And flexible, fast drying, adhesive force are good, can form one layer of fine and close protective film in metal surface, effectively prevent extraneous ring
Damage of the border to metal, in particular for the incision of galvanized steel plain sheet during metal plate；
(3) present invention is at low cost, degradable, and use is safe, no pollution to the environment, is conducive to promote the use of well.
Specific embodiment
Specific embodiment is of the invention to be discussed in detail below.
Embodiment 1
A kind of non-ferrous metal surface inorganic agent, using 5 parts of silicone oil, 3 parts of glycerine, 2 parts of polyamide, 3 parts of sodium pyrophosphate, acetic acid 4
Part, 3 parts of oil-soluble phenolic resin, 7 parts of aluminum sulfate, 1 part of citric acid, 4 parts of zinc dialkyl dithiophosphate and 75 parts of deionized water.
Preparation method, its step are as follows:
(a) it is weighed by mass fraction, taking 5 parts of silicone oil and 3 parts of oil-soluble phenolic resins, (silicone oil that the present invention uses is methyl silicon
Oil, oil-soluble phenolic resin are using dimethylbenzene as the oil-soluble phenolic resin of the short oil of solvent) it is stirred under the conditions of 80 DEG C of water-bath
It mixes 50 minutes, standing is cooled to 38 DEG C；
(b) 3 parts of glycerine, 4 parts of acetic acid, 4 parts of zinc dialkyl dithiophosphates and 1 are added into solution obtained in step (a)
Part citric acid stirs 30 minutes under the conditions of 36 DEG C, keeps the temperature 18 minutes；
(c) solution obtained in step (b) is cooled to 23 DEG C, be added 2 parts of polyamide, 3 parts of sodium pyrophosphates, 7 parts of aluminum sulfate and
75 parts of deionized waters stir 13 minutes up to anticolodal.
When in use, application method includes the following steps: anticolodal
(d) anticolodal prepared in step (c) is heated to 75 DEG C, stirs 4min；
(e) galvanized steel plain sheet to be processed (will be cut into the rectangle that side length is 200mm with a thickness of the galvanized steel plain sheet of 2.5mm, together
When plate on stamped out the through-hole that 2 diameters are 10mm) in the solution that is added in step (d), impregnate 40s, pull workpiece out；
(f) speed is used to dry up for the cold wind of 10m/s the workpiece pulled out in step (e), the temperature of cold wind is 2-6 DEG C；
(g) workpiece after drying in step (f) is placed in dark environment and places 36h, the workpiece that obtains that treated.
Found after salt mist experiment, treated workpiece than do not have the anti-corrosion time of treated workpiece improve 28%,
And the place that treated workpiece corrodes at first is not the edge sheared with through-hole, shearing of the present invention to galvanized steel plain sheet
Mouth can play apparent antisepsis.The galvanized steel plain sheet workpiece handled using the present invention extends 1 than the service life not handled
Year, the substance corrosion resistance of oxidant and acid-base property is significantly increased, treated waste water easily biological-degradable, to environment without dirt
Dye, and it is harmless to the health of operator.
Embodiment 2
With embodiment 1, except that the content of each substance and preparation method parameter change, its step are as follows:
(a) it is weighed by mass fraction, 6 parts of silicone oil and 5 parts of oil-soluble phenolic resins is taken to stir 60 minutes under the conditions of 80 DEG C of water-bath,
Standing is cooled to 30 DEG C；
(b) 5 parts of glycerine, 5 parts of acetic acid, 3 parts of zinc dialkyl dithiophosphates and 2 are added into solution obtained in step (a)
Part citric acid stirs 40 minutes under the conditions of 30 DEG C, keeps the temperature 15 minutes；
(c) solution obtained in step (b) is cooled to 20 DEG C, 0.5 part of polyamide, 1 part of sodium pyrophosphate, 12 parts of aluminum sulfate is added
15 minutes are stirred with 70 parts of deionized waters up to anticolodal.
When in use, application method includes the following steps: anticolodal
(d) anticolodal prepared in step (c) is heated to 80 DEG C, stirs 3min；
(e) galvanized steel plain sheet to be processed (will be cut into the rectangle that side length is 200mm with a thickness of the galvanized steel plain sheet of 2.5mm, together
When plate on stamped out the through-hole that 2 diameters are 7mm) in the solution that is added in step (d), impregnate 30s, pull workpiece out；
(f) speed is used to dry up for the cold wind of 10m/s the workpiece pulled out in step (e), the temperature of cold wind is 2-6 DEG C；
(g) workpiece after drying in step (f) is placed in dark environment and is placed for 24 hours, the workpiece that obtains that treated.
Found after salt mist experiment, treated workpiece than do not have the anti-corrosion time of treated workpiece improve 23%,
And the place that treated workpiece corrodes at first is not the edge sheared with through-hole, shearing of the present invention to galvanized steel plain sheet
Mouth can play apparent antisepsis.
Embodiment 3
With embodiment 1, except that the content of each substance and preparation method parameter change, its step are as follows:
(a) it is weighed by mass fraction, 8 parts of silicone oil and 8 parts of oil-soluble phenolic resins is taken to stir 45 minutes under the conditions of 80 DEG C of water-bath,
Standing is cooled to 45 DEG C；
(b) 1 part of glycerine, 3 parts of acetic acid, 5 parts of zinc dialkyl dithiophosphates and 3 are added into solution obtained in step (a)
Part citric acid stirs 20 minutes under the conditions of 45 DEG C, keeps the temperature 20 minutes；
(c) solution obtained in step (b) is cooled to 25 DEG C, be added 1 part of polyamide, 2 parts of sodium pyrophosphates, 9 parts of aluminum sulfate and
80 parts of deionized waters stir 10 minutes up to anticolodal.
When in use, application method includes the following steps: anticolodal
(d) anticolodal prepared in step (c) is heated to 70-80 DEG C, stirs 5min；
(e) galvanized steel plain sheet to be processed (will be cut into the rectangle that side length is 200mm with a thickness of the galvanized steel plain sheet of 2.5mm, together
When plate on stamped out the through-hole that 2 diameters are 10mm) in the solution that is added in step (d), impregnate 50s, pull workpiece out；
(f) speed is used to dry up for the cold wind of 10m/s the workpiece pulled out in step (e), the temperature of cold wind is 2-6 DEG C；
(g) workpiece after drying in step (f) is placed in dark environment and places 48h, the workpiece that obtains that treated.
Found after salt mist experiment, treated workpiece than do not have the anti-corrosion time of treated workpiece improve 25%,
And the place that treated workpiece corrodes at first is not the edge sheared with through-hole, shearing of the present invention to galvanized steel plain sheet
Mouth can play apparent antisepsis.
Claims (5)
1. a kind of non-ferrous metal surface inorganic agent, ingredient and mass fraction are as follows:
5-8 parts of silicone oil；
1-5 parts of glycerine；
0.5-2 parts of polyamide；
1-3 parts of sodium pyrophosphate；
3-5 parts of acetic acid；
3-8 parts of oil-soluble phenolic resin；
7-12 parts of aluminum sulfate；
1-3 parts of citric acid；
3-5 parts of zinc dialkyl dithiophosphate；
70-80 parts of deionized water.
2. a kind of non-ferrous metal surface inorganic agent according to claim 1, which is characterized in that the silicone oil is methyl silicon
Oil, oil-soluble phenolic resin are using dimethylbenzene as the oil-soluble phenolic resin of the short oil of solvent.
3. a kind of non-ferrous metal surface inorganic agent according to claim 1, which is characterized in that component and its mass fraction are such as
Under:
5 parts of silicone oil；
3 parts of glycerine；
2 parts of polyamide；
3 parts of sodium pyrophosphate；
4 parts of acetic acid；
3 parts of oil-soluble phenolic resin；
7 parts of aluminum sulfate；
1 part of citric acid；
4 parts of zinc dialkyl dithiophosphate；
75 parts of deionized water.
4. the application of sodium pyrophosphate or glycerine or zinc dialkyl dithiophosphate in anti-corrosion of metal.
5. the application of preservative prepared by claim 1 in panel beating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711111973.2A CN109777287A (en) | 2017-11-13 | 2017-11-13 | A kind of anticolodal and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711111973.2A CN109777287A (en) | 2017-11-13 | 2017-11-13 | A kind of anticolodal and its application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109777287A true CN109777287A (en) | 2019-05-21 |
Family
ID=66484821
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711111973.2A Pending CN109777287A (en) | 2017-11-13 | 2017-11-13 | A kind of anticolodal and its application |
Country Status (1)
| Country | Link |
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| CN (1) | CN109777287A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111187572A (en) * | 2019-10-31 | 2020-05-22 | 张继 | Metal preservative |
| CN112940613A (en) * | 2021-02-04 | 2021-06-11 | 上海神洁环保科技股份有限公司 | Metal preservative and preparation method thereof |
-
2017
- 2017-11-13 CN CN201711111973.2A patent/CN109777287A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111187572A (en) * | 2019-10-31 | 2020-05-22 | 张继 | Metal preservative |
| CN111187572B (en) * | 2019-10-31 | 2023-11-03 | 四川省安可防腐保温工程有限公司 | Metal preservative's user equipment |
| CN112940613A (en) * | 2021-02-04 | 2021-06-11 | 上海神洁环保科技股份有限公司 | Metal preservative and preparation method thereof |
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Application publication date: 20190521 |