CN104357849A - Non-ferrous metal surface treating agent - Google Patents
Non-ferrous metal surface treating agent Download PDFInfo
- Publication number
- CN104357849A CN104357849A CN201410647802.1A CN201410647802A CN104357849A CN 104357849 A CN104357849 A CN 104357849A CN 201410647802 A CN201410647802 A CN 201410647802A CN 104357849 A CN104357849 A CN 104357849A
- Authority
- CN
- China
- Prior art keywords
- parts
- metal surface
- ferrous metal
- treating agent
- surface treating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Chemical Treatment Of Metals (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a non-ferrous metal surface treating agent and belongs to the field of metal surface treatment. The non-ferrous metal surface treating agent contains the ingredients in parts by mass: 5-8 parts of sodium polyacrylate, 1-5 parts of sodium pyrophosphate, 0.5-2 parts of carboxymethyl cellulose, 1-3 parts of sodium dodecyl sulfonate, 3-5 parts of acetic acid, 3-8 parts of chitosan, 7-12 parts of alumina, 1-3 parts of triethanolamine and 70-80 parts of deionized water. Through treating the surface of metal by using the non-ferrous metal surface treating agent, the metal can be effectively prevented from oxidation and corrosion, and the surface of the metal can be kept bright; the non-ferrous metal surface treating agent is pollution-free to environment, is degradable, is low in cost and safe in use, and is beneficial to very good popularization.
Description
Technical field
The invention belongs to field of metal surface treatment, specifically, relate to a kind of non-ferrous metal surface treatment agent.
Background technology
Oxidation, corrosion etc. in various degree often can be there is in metal in processing, process and use procedure; reduce the work-ing life of metallic substance or hardware, therefore, need to process metallic surface; increase its anti-oxidant, erosion-resisting ability, increase the service life.Application is the technology that metal finishing is commonly used, and in coating process, phosphatization can produce a large amount of phosphorus-containing wastewaters, and needs to carry out under strong acid or strong alkaline condition, causes great harm to the healthy of people and environment.Therefore, be badly in need of a kind of environmentally safe, do not damage the metal conditioner of person health.
Summary of the invention
the problem that 1, will solve
Exist seriously polluted for application processing method in existing metal surface treatment technology, to problems such as human health damage are very big, the invention provides a kind of non-ferrous metal surface treatment agent, effectively can prevent oxidation, the corrosion of metal, environmental pollution is minimum, can not damage HUMAN HEALTH in use procedure, and cost is low, is easy to promote.
2, technical scheme
For solving the problem, technical scheme of the present invention is:
A kind of non-ferrous metal surface treatment agent, its composition and mass fraction are:
Sodium polyacrylate 5-8 part;
Trisodium phosphate 1-5 part;
Carboxymethyl cellulose 0.5-2 part;
Sodium laurylsulfonate 1-3 part;
Acetic acid 3-5 part;
Chitosan 3-8 part;
Aluminum oxide 7-12 part;
Trolamine 1-3 part;
Deionized water 70-80 part.
Preferably, the granular size of described aluminum oxide is nano level.
Preferably, its component and massfraction as follows:
Sodium polyacrylate 5 parts;
Trisodium phosphate 3 parts;
Carboxymethyl cellulose 2 parts;
Sodium laurylsulfonate 3 parts;
Acetic acid 4 parts;
Chitosan 3 parts;
7 parts, aluminum oxide;
Trolamine 1 part;
Deionized water 75 parts.
The preparation method of above-mentioned non-ferrous metal surface treatment agent, the steps include:
A () gets the mixing of 5-8 part sodium polyacrylate, 1-5 part trisodium phosphate, 0.5-2 part carboxymethyl cellulose and 1-3 part sodium laurylsulfonate by mass fraction, add 70-80 part deionized water, stir, be under agitation heated to 45 DEG C, insulation 30min;
B solution that step (a) obtains by () is cooled to 25 DEG C, adds 3-8 part chitosan and 7-12 part aluminum oxide, stirs 20min;
Add 3-5 part acetic acid and 1-3 part trolamine in c solution that () obtains to step (b), stir and obtain non-ferrous metal surface treatment agent.
3, beneficial effect
Compared to prior art, beneficial effect of the present invention is:
(1) the present invention is made up of sodium polyacrylate, sodium phosphate, carboxymethyl cellulose, sodium laurylsulfonate, acetic acid, chitosan, aluminum oxide, trolamine and deionized water, the present invention is used to carry out metallic surface processing oxidation, the corrosion that effectively can prevent metal, keep metallic surface light, and environmentally safe, degradable, cost is low;
(2) the present invention uses nano level aluminum oxide, can form the protective membrane of one deck densification, effectively prevent external environment to the infringement of metal in metallic surface;
(3) trisodium phosphate of the present invention's use is except having derusting action, tensio-active agent sodium polyacrylate can also be made to reduce surface tension and interfacial tension further, sodium polyacrylate is a kind of tensio-active agent with multifrequency nature, can fixing metal ions, insensitive to temperature variation, stability is fine;
(4) low, the degradable of cost of the present invention, use safety, environmentally safe, is conducive to well promoting the use of.
Embodiment
Specific embodiment introduces the present invention in detail below.
embodiment 1
A kind of non-ferrous metal surface treatment agent, its component and mass fraction as follows: sodium polyacrylate 5 parts; Trisodium phosphate 3 parts; Carboxymethyl cellulose 2 parts; Sodium laurylsulfonate 3 parts; Acetic acid 4 parts; Chitosan 3 parts; 7 parts, aluminum oxide; Trolamine 1 part and deionized water 75 parts.
Use the stainless steel work-piece of process of the present invention than not having extend 5 months the work-ing life processed, surface can keep light, significantly strengthens, the waste water readily biodegradable after process to the material erosion resistance of oxygenant and acid-basicity, environmentally safe, and healthy harmless to operator.
embodiment 2
With embodiment 1, difference is the content of each material: sodium polyacrylate 8 parts; Trisodium phosphate 1 part; Carboxymethyl cellulose 1 part; Sodium laurylsulfonate 1 part; Acetic acid 5 parts; Chitosan 6 parts; 12 parts, aluminum oxide; Trolamine 2 parts and deionized water 80 parts.Its preparation method is: (a) gets 5 parts of sodium polyacrylates, 3 parts of trisodium phosphates, 2 parts of carboxymethyl celluloses and 3 parts of sodium laurylsulfonate mixing by mass fraction, add 75 parts of deionized waters, stir, be under agitation heated to 45 DEG C, insulation 30min; B solution that step (a) obtains by () is cooled to 25 DEG C, adds 3 parts of chitosans and 7 parts of aluminum oxide, stirs 20min; Add 4 parts of acetic acid and 1 part of trolamine in c solution that () obtains to step (b), stir and obtain non-ferrous metal surface treatment agent.
Use the stainless steel work-piece of process of the present invention than not having extend 3 months the work-ing life processed, surface can keep light, significantly strengthens, the waste water readily biodegradable after process to the material erosion resistance of oxygenant and acid-basicity, environmentally safe, and healthy harmless to operator.
embodiment 3
With embodiment 1, difference is the content of each material: sodium polyacrylate 6.5 parts; Trisodium phosphate 5 parts; Carboxymethyl cellulose 0.5 part; Sodium laurylsulfonate 2 parts; Acetic acid 3 parts; Chitosan 8 parts; 9 parts, aluminum oxide; Trolamine 3 parts and deionized water 70 parts.
Use the stainless steel work-piece of process of the present invention than not having extend 4 months the work-ing life processed, surface can keep light, significantly strengthens, the waste water readily biodegradable after process to the material erosion resistance of oxygenant and acid-basicity, environmentally safe, and healthy harmless to operator.
Claims (3)
1. a non-ferrous metal surface treatment agent, its composition and mass fraction are:
Sodium polyacrylate 5-8 part;
Trisodium phosphate 1-5 part;
Carboxymethyl cellulose 0.5-2 part;
Sodium laurylsulfonate 1-3 part;
Acetic acid 3-5 part;
Chitosan 3-8 part;
Aluminum oxide 7-12 part;
Trolamine 1-3 part;
Deionized water 70-80 part.
2. a kind of non-ferrous metal surface treatment agent according to claim 1, is characterized in that, the granular size of described aluminum oxide is nano level.
3. a kind of non-ferrous metal surface treatment agent according to claim 1, is characterized in that, component and massfraction as follows:
Sodium polyacrylate 5 parts;
Trisodium phosphate 3 parts;
Carboxymethyl cellulose 2 parts;
Sodium laurylsulfonate 3 parts;
Acetic acid 4 parts;
Chitosan 3 parts;
7 parts, aluminum oxide;
Trolamine 1 part;
Deionized water 75 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410647802.1A CN104357849B (en) | 2014-11-17 | 2014-11-17 | Non-ferrous metal surface treating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410647802.1A CN104357849B (en) | 2014-11-17 | 2014-11-17 | Non-ferrous metal surface treating agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104357849A true CN104357849A (en) | 2015-02-18 |
| CN104357849B CN104357849B (en) | 2017-01-11 |
Family
ID=52525152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410647802.1A Active CN104357849B (en) | 2014-11-17 | 2014-11-17 | Non-ferrous metal surface treating agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104357849B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105002506A (en) * | 2015-08-07 | 2015-10-28 | 苏州云舒新材料科技有限公司 | Rust-proof corrosion inhibitor and preparing method thereof |
| CN106191872A (en) * | 2016-08-24 | 2016-12-07 | 合肥东方节能科技股份有限公司 | A kind of metal dusting-resistant and preparation method thereof |
| CN107059017A (en) * | 2017-04-21 | 2017-08-18 | 马鞍山纽泽科技服务有限公司 | A kind of highly effective antirust liquid and its synthesis technique |
| CN107955945A (en) * | 2017-10-30 | 2018-04-24 | 芜湖辉灿电子科技有限公司 | A kind of anti-corrosion mobile phone shell metal conditioner |
| CN107987723A (en) * | 2017-10-30 | 2018-05-04 | 芜湖辉灿电子科技有限公司 | A kind of anti-oxidant surface conditioning agent of mobile phone metal-back |
| CN108085671A (en) * | 2017-12-27 | 2018-05-29 | 洛阳神佳窑业有限公司 | Novel colored metal conditioner |
| CN108149235A (en) * | 2017-12-27 | 2018-06-12 | 洛阳神佳窑业有限公司 | A kind of non-ferrous metal surface inorganic agent |
| CN108165996A (en) * | 2017-12-27 | 2018-06-15 | 洛阳神佳窑业有限公司 | Novel colored metal conditioner |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080108537A1 (en) * | 2006-11-03 | 2008-05-08 | Rees Wayne M | Corrosion inhibitor system for mildly acidic to ph neutral halogen bleach-containing cleaning compositions |
| CN102051611A (en) * | 2010-12-31 | 2011-05-11 | 大连工业大学 | Metal surface treating agent |
| WO2012085830A2 (en) * | 2010-12-21 | 2012-06-28 | Ecolab Usa Inc. | CORROSION INHIBITION OF HYPOCHLORITE SOLUTIONS USING POLYACRYLATE AND Ca, Zn AND Ca, SUGAR ACIDS AND Ca |
| CN103695879A (en) * | 2013-12-19 | 2014-04-02 | 栾晓健 | Environment-friendly non-ferrous metal treating agent |
-
2014
- 2014-11-17 CN CN201410647802.1A patent/CN104357849B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080108537A1 (en) * | 2006-11-03 | 2008-05-08 | Rees Wayne M | Corrosion inhibitor system for mildly acidic to ph neutral halogen bleach-containing cleaning compositions |
| WO2012085830A2 (en) * | 2010-12-21 | 2012-06-28 | Ecolab Usa Inc. | CORROSION INHIBITION OF HYPOCHLORITE SOLUTIONS USING POLYACRYLATE AND Ca, Zn AND Ca, SUGAR ACIDS AND Ca |
| CN102051611A (en) * | 2010-12-31 | 2011-05-11 | 大连工业大学 | Metal surface treating agent |
| CN103695879A (en) * | 2013-12-19 | 2014-04-02 | 栾晓健 | Environment-friendly non-ferrous metal treating agent |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105002506A (en) * | 2015-08-07 | 2015-10-28 | 苏州云舒新材料科技有限公司 | Rust-proof corrosion inhibitor and preparing method thereof |
| CN106191872A (en) * | 2016-08-24 | 2016-12-07 | 合肥东方节能科技股份有限公司 | A kind of metal dusting-resistant and preparation method thereof |
| CN107059017A (en) * | 2017-04-21 | 2017-08-18 | 马鞍山纽泽科技服务有限公司 | A kind of highly effective antirust liquid and its synthesis technique |
| CN107955945A (en) * | 2017-10-30 | 2018-04-24 | 芜湖辉灿电子科技有限公司 | A kind of anti-corrosion mobile phone shell metal conditioner |
| CN107987723A (en) * | 2017-10-30 | 2018-05-04 | 芜湖辉灿电子科技有限公司 | A kind of anti-oxidant surface conditioning agent of mobile phone metal-back |
| CN108085671A (en) * | 2017-12-27 | 2018-05-29 | 洛阳神佳窑业有限公司 | Novel colored metal conditioner |
| CN108149235A (en) * | 2017-12-27 | 2018-06-12 | 洛阳神佳窑业有限公司 | A kind of non-ferrous metal surface inorganic agent |
| CN108165996A (en) * | 2017-12-27 | 2018-06-15 | 洛阳神佳窑业有限公司 | Novel colored metal conditioner |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104357849B (en) | 2017-01-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104357849A (en) | Non-ferrous metal surface treating agent | |
| CN104400853B (en) | A kind of timber make old inorganic agent | |
| CN103756452A (en) | Metal antirust paint and preparation method thereof | |
| CN103668256A (en) | Preparation method of metal surface treating agent | |
| CN104451727A (en) | Anti-rusting agent | |
| CN105018949A (en) | Rust remover suitable for steel precision part and rust removing process of rust remover | |
| MX2016004805A (en) | Method for preparing shaped metal bodies for cold working. | |
| CN105624703A (en) | Non-ferrous metal surface treatment agent and preparation method thereof | |
| CN110818101A (en) | Low-phosphorus composite corrosion and scale inhibitor | |
| CN104342710A (en) | Anti-corrosion metal surface cleaning agent and preparation method of anti-corrosion metal surface cleaning agent | |
| CN104357830A (en) | Method for preparing non-ferrous metal surface treating agent | |
| CN103668257A (en) | Metal surface treatment method | |
| CN104451713B (en) | Novel rust remover | |
| CN104140162B (en) | With the non-phosphorus scale and corrosion inhibitor and preparation method thereof of seawater as recirculated cooling water | |
| CN102850831A (en) | Novel anticorrosive coating for grid fitting | |
| CN108754473A (en) | A kind of magnesium alloy surface chromium-free passivator and its application | |
| CN103436873A (en) | Environment-friendly non-phosphorus pretreatment filming agent | |
| CN103695943A (en) | Application method of metal surface treatment agent for forming protective film | |
| CN104451729B (en) | Rust cleaning reagent | |
| CN103343337A (en) | Aqueous cleaning and rust-proof agent | |
| CN108914134A (en) | A kind of rust remover and derusting method with antirust function | |
| CN105039954A (en) | Preparation method for steel surface treatment agent | |
| CN104843877A (en) | Efficient corrosion and scale inhibitor for high-halogen ion circulating cooling water system | |
| CN107720921A (en) | Efficient heavy waste water treating agent and preparation method thereof | |
| CN102021590B (en) | Metal scale remover and using method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 241000, Wuhu economic and Technological Development Zone, Hengshan Road, No. 35, electronic Pioneer Park, room 605-606 Applicant after: WUHU MINTAI COPPER INDUSTRY CO., LTD. Address before: 241000 Anhui city of Wuhu province Jiujiang Economic Development Zone East Road No. 3 leap Applicant before: WUHU MINTAI COPPER INDUSTRY CO., LTD. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Su Xude Inventor before: Yan Chenglong |
|
| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171212 Address after: Kuizhou road 404600 Yongan town Chongqing city Fengjie County No. 22 Patentee after: Chongqing Fengjie Hong Yao metal products manufacturing Co., Ltd. Address before: 241000, Wuhu economic and Technological Development Zone, Hengshan Road, No. 35, electronic Pioneer Park, room 605-606 Patentee before: WUHU MINTAI COPPER INDUSTRY CO., LTD. |
|
| TR01 | Transfer of patent right |