CN104451727A - Anti-rusting agent - Google Patents

Anti-rusting agent Download PDF

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Publication number
CN104451727A
CN104451727A CN201410716491.XA CN201410716491A CN104451727A CN 104451727 A CN104451727 A CN 104451727A CN 201410716491 A CN201410716491 A CN 201410716491A CN 104451727 A CN104451727 A CN 104451727A
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China
Prior art keywords
mass fraction
parts
steel
ammonium molybdate
phosphoric acid
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CN201410716491.XA
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CN104451727B (en
Inventor
张一帆
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FOSHAN HAIMINGWEI ECOLOGICAL TECHNOLOGY Co.,Ltd.
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Chengdu Jinhui Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/08Iron or steel
    • C23G1/083Iron or steel solutions containing H3PO4

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Detergent Compositions (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The invention belongs to the field of health maintenance, and in particular discloses an anti-rusting agent which is prepared from the following components in parts by mass: 5-15 parts of sodium silicate, 15-25 parts of phosphoric acid, 20-40 parts of lauryl sodium sulfate, 15-35 parts of calcium hypophosphite, 5-25 parts of tertpotassium borate, 4-24 parts of ammonium molybdate and 500-1200 parts of deionized water. The anti-rusting agent does not corrode or damage steel, rust on steel can be well removed, the advantage that the steel is not damaged even when the anti-rusting agent is used for a long time is ensured, the anti-rusting agent can be widely popularized and applied, and the costs of the components are low; and compared with a conventional anti-rusting agent, the investment cost of a user is greatly reduced by using the anti-rusting agent.

Description

Rust remover
Technical field
The invention belongs to industrial circle, specifically a kind of rust remover.
Background technology
Traditional chemical rust removing uses strong acid usually, acid can with iron rust and metal oxide generation chemical reaction, generate solubility salt, thus reach the object of rust cleaning, while rust cleaning, acid to react releasing hydrogen with underlying metal again, the oxide skin of Hydrogen Energy to iron rust and indissoluble produces pressure, be conducive to their reduction with high price iron of peeling off, accelerate the process of pickling, but traditional acid solution treatment process also also exists obvious defect: namely in treating processes, the generation of a large amount of hydrogen can make steel produce Hydrogen Brittleness Phenomena, cause the mechanical properties decrease of metal, affect the intensity of iron and steel itself, easily form acid mist simultaneously, affect the health of operator and corrode equipment around and environment, the consumption of acid solution is also comparatively large, increases processing cost, this kind of acid can form excessive erosion to steel.In addition a large amount of residue produced, need often discharge, both heavy corrosion industrial pipeline, again contaminated soil and environment.If number of patent application is CN200710150668.4, the applying date is 2007-12-03, the patent of invention that name is called " novel method with the iron rust on concentrated hydrochloric acid or vitriol oil removing steel device ", its technical scheme is: the novel method that the present invention relates to the iron rust on a kind of concentrated hydrochloric acid or vitriol oil removing steel device.In hydrochloric acid or sulfuric acid, add urea, or add ammonium sulfate in sulfuric acid, be used for removing the rust on iron and steel.Just hydrochloric acid or the sulfuric acid that consume, urea or ammonium sulfate do not consume, but play and prevent acid mist from occurring, reduce the inhibitor effect that acid is corroded iron itself.When acid is depleted to similar, supplement concentrated hydrochloric acid or the vitriol oil one after another, rust cleaning is just constantly carried out.
But above-mentioned patent is when life-time service, can damage iron and steel itself, although rust has been removed, iron and steel has also received damage, loses more than gain.
Summary of the invention
In order to overcome the problem of the meeting injury iron and steel that existing rust remover exists itself, now a kind of rust remover that can not injure iron and steel is proposed.。
For realizing above-mentioned technique effect, technical solution of the present invention is as follows:
A kind of rust remover, it is characterized in that: include water glass, phosphoric acid, sodium lauryl sulphate, calcium propionate, potassium tetraborate, ammonium molybdate and deionized water, the mass fraction of described water glass is 5-15 part, the mass fraction of described phosphoric acid is 15-25 part, the mass fraction of described sodium lauryl sulphate is 20-40 part, the mass fraction of described calcium propionate is 15-35 part, the mass fraction of described potassium tetraborate is 5-25 part, the mass fraction of described ammonium molybdate is 4-24 part, and the mass fraction of described deionized water is 500-1200 part.
The mass fraction of described water glass is 7-12 part, the mass fraction of described phosphoric acid is 17-21 part, the mass fraction of described sodium lauryl sulphate is 30-35 part, the mass fraction of described calcium propionate is 26-31 part, the mass fraction of described potassium tetraborate is 10-20 part, the mass fraction of described ammonium molybdate is 13-20 part, and the mass fraction of described deionized water is 700-1000 part.
The mass fraction of described water glass is 11 parts, the mass fraction of described phosphoric acid is 19 parts, the mass fraction of described sodium lauryl sulphate is 33 parts, the mass fraction of described calcium propionate is 28 parts, the mass fraction of described potassium tetraborate is 14 parts, the mass fraction of described ammonium molybdate is 17 parts, and the mass fraction of described deionized water is 900 parts.
Also include trolamine and ethylenediamine tetraacetic acid (EDTA), the mass fraction of described trolamine is 10-30 part, and the mass fraction of described ethylenediamine tetraacetic acid (EDTA) is 20-35 part.
The mass fraction of described trolamine is 19 parts, and the mass fraction of described ethylenediamine tetraacetic acid (EDTA) is 26 parts.
The concentration of described phosphoric acid, sodium lauryl sulphate, calcium propionate, potassium tetraborate, ammonium molybdate, trolamine and ethylenediamine tetraacetic acid (EDTA) is 30-50%.
The invention has the advantages that:
1, the present invention can not cause corrosion or other injuries to iron and steel, and can the rust on iron and steel well be eliminated, even if ensure that life-time service also can not destroy the advantage of iron and steel, utilize and apply on a large scale, and each composition is with low cost, compared to existing rust remover, the input cost of user greatly can be reduced.
Embodiment
A kind of rust remover includes water glass, phosphoric acid, sodium lauryl sulphate, calcium propionate, potassium tetraborate, ammonium molybdate and deionized water, the mass fraction of described water glass is 5-15 part, the mass fraction of described phosphoric acid is 15-25 part, the mass fraction of described sodium lauryl sulphate is 20-40 part, the mass fraction of described calcium propionate is 15-35 part, the mass fraction of described potassium tetraborate is 5-25 part, the mass fraction of described ammonium molybdate is 4-24 part, and the mass fraction of described deionized water is 500-1200 part.
The present invention can not cause corrosion or other injuries to iron and steel, and can the rust on iron and steel well be eliminated, even if ensure that life-time service also can not destroy the advantage of iron and steel, utilize and apply on a large scale, and each composition is with low cost, compared to existing rust remover, the input cost of user greatly can be reduced.
Embodiment 2
A kind of rust remover, it is characterized in that: include water glass, phosphoric acid, sodium lauryl sulphate, calcium propionate, potassium tetraborate, ammonium molybdate and deionized water, the mass fraction of described water glass is 7-12 part, the mass fraction of described phosphoric acid is 17-21 part, the mass fraction of described sodium lauryl sulphate is 30-35 part, the mass fraction of described calcium propionate is 26-31 part, the mass fraction of described potassium tetraborate is 10-20 part, the mass fraction of described ammonium molybdate is 13-20 part, and the mass fraction of described deionized water is 700-1000 part.Also include trolamine and ethylenediamine tetraacetic acid (EDTA), the mass fraction of described trolamine is 10-30 part, and the mass fraction of described ethylenediamine tetraacetic acid (EDTA) is 20-35 part.The present invention can not cause corrosion or other injuries to iron and steel, and can the rust on iron and steel well be eliminated, even if ensure that life-time service also can not destroy the advantage of iron and steel, utilize and apply on a large scale, and each composition is with low cost, compared to existing rust remover, the input cost of user greatly can be reduced.The concentration of described phosphoric acid, sodium lauryl sulphate, calcium propionate, potassium tetraborate, ammonium molybdate, trolamine and ethylenediamine tetraacetic acid (EDTA) is 50%.
Embodiment 3
A kind of rust remover, it is characterized in that: include water glass, phosphoric acid, sodium lauryl sulphate, calcium propionate, potassium tetraborate, ammonium molybdate and deionized water, the mass fraction of described water glass is 11 parts, the mass fraction of described phosphoric acid is 19 parts, the mass fraction of described sodium lauryl sulphate is 33 parts, and the mass fraction of described calcium propionate is 28 parts, and the mass fraction of described potassium tetraborate is 14 parts, the mass fraction of described ammonium molybdate is 17 parts, and the mass fraction of described deionized water is 900 parts.Also include trolamine and ethylenediamine tetraacetic acid (EDTA), the mass fraction of described trolamine is 19 parts, and the mass fraction of described ethylenediamine tetraacetic acid (EDTA) is 26 parts.The present invention can not cause corrosion or other injuries to iron and steel, and can the rust on iron and steel well be eliminated, even if ensure that life-time service also can not destroy the advantage of iron and steel, utilize and apply on a large scale, and each composition is with low cost, compared to existing rust remover, the input cost of user greatly can be reduced.
The concentration of described phosphoric acid, sodium lauryl sulphate, calcium propionate, potassium tetraborate, ammonium molybdate, trolamine and ethylenediamine tetraacetic acid (EDTA) is 50%.
Embodiment 4
A kind of rust remover, it is characterized in that: include water glass, phosphoric acid, sodium lauryl sulphate, calcium propionate, potassium tetraborate, ammonium molybdate and deionized water, the mass fraction of described water glass is 12 parts, the mass fraction of described phosphoric acid is 18 parts, the mass fraction of described sodium lauryl sulphate is 34 parts, and the mass fraction of described calcium propionate is 27 parts, and the mass fraction of described potassium tetraborate is 14 parts, the mass fraction of described ammonium molybdate is 18 parts, and the mass fraction of described deionized water is 950 parts.Also include trolamine and ethylenediamine tetraacetic acid (EDTA), the mass fraction of described trolamine is 18 parts, and the mass fraction of described ethylenediamine tetraacetic acid (EDTA) is 27 parts.The present invention can not cause corrosion or other injuries to iron and steel, and can the rust on iron and steel well be eliminated, even if ensure that life-time service also can not destroy the advantage of iron and steel, utilize and apply on a large scale, and each composition is with low cost, compared to existing rust remover, the input cost of user greatly can be reduced.
The concentration of described phosphoric acid, sodium lauryl sulphate, calcium propionate, potassium tetraborate, ammonium molybdate, trolamine and ethylenediamine tetraacetic acid (EDTA) is 50%.

Claims (6)

1. a rust remover, it is characterized in that: include water glass, phosphoric acid, sodium lauryl sulphate, calcium propionate, potassium tetraborate, ammonium molybdate and deionized water, the mass fraction of described water glass is 5-15 part, the mass fraction of described phosphoric acid is 15-25 part, the mass fraction of described sodium lauryl sulphate is 20-40 part, the mass fraction of described calcium propionate is 15-35 part, the mass fraction of described potassium tetraborate is 5-25 part, the mass fraction of described ammonium molybdate is 4-24 part, and the mass fraction of described deionized water is 500-1200 part.
2. rust remover according to claim 1, it is characterized in that: the mass fraction of described water glass is 7-12 part, the mass fraction of described phosphoric acid is 17-21 part, the mass fraction of described sodium lauryl sulphate is 30-35 part, the mass fraction of described calcium propionate is 26-31 part, the mass fraction of described potassium tetraborate is 10-20 part, and the mass fraction of described ammonium molybdate is 13-20 part, and the mass fraction of described deionized water is 700-1000 part.
3. rust remover according to claim 2, it is characterized in that: the mass fraction of described water glass is 11 parts, the mass fraction of described phosphoric acid is 19 parts, the mass fraction of described sodium lauryl sulphate is 33 parts, the mass fraction of described calcium propionate is 28 parts, the mass fraction of described potassium tetraborate is 14 parts, and the mass fraction of described ammonium molybdate is 17 parts, and the mass fraction of described deionized water is 900 parts.
4. the rust remover according to claim 1,2 or 3, is characterized in that: also include trolamine and ethylenediamine tetraacetic acid (EDTA), and the mass fraction of described trolamine is 10-30 part, and the mass fraction of described ethylenediamine tetraacetic acid (EDTA) is 20-35 part.
5. rust remover according to claim 4, is characterized in that: the mass fraction of described trolamine is 19 parts, and the mass fraction of described ethylenediamine tetraacetic acid (EDTA) is 26 parts.
6. rust remover according to claim 4, is characterized in that: the concentration of described phosphoric acid, sodium lauryl sulphate, calcium propionate, potassium tetraborate, ammonium molybdate, trolamine and ethylenediamine tetraacetic acid (EDTA) is 50%.
CN201410716491.XA 2014-12-02 2014-12-02 Anti-rusting agent Active CN104451727B (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105951109A (en) * 2016-07-13 2016-09-21 南通中兴多元复合钢管有限公司 Rust remover
CN106011898A (en) * 2016-07-14 2016-10-12 南通中兴多元复合钢管有限公司 Rust removing agent
CN107326380A (en) * 2017-07-17 2017-11-07 安徽华翎羽毛制品有限公司 A kind of shuttlecock club rust remover
CN108531917A (en) * 2017-03-05 2018-09-14 长沙丰畅车辆工程技术有限公司 A kind of loosening agent
CN108531915A (en) * 2017-03-05 2018-09-14 长沙丰畅车辆工程技术有限公司 A kind of environment-friendly rust remover
CN108531918A (en) * 2017-03-05 2018-09-14 长沙丰畅车辆工程技术有限公司 A kind of Deruster for metal
CN108531916A (en) * 2017-03-05 2018-09-14 长沙丰畅车辆工程技术有限公司 A kind of potent rust remover
CN108531928A (en) * 2017-03-05 2018-09-14 长沙丰畅车辆工程技术有限公司 A kind of explosion-proof rust remover
CN109746648A (en) * 2019-03-04 2019-05-14 黄山中链科技有限公司 A kind of engine chain production technology of high-strength abrasion-proof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030114328A1 (en) * 2001-09-22 2003-06-19 Kwon-Taeg Kim Water-soluble composition for removing rust from steel bar and steel frame
CN1624201A (en) * 2004-12-07 2005-06-08 山东省科学院新材料研究所 Anticorrosion rust eliminating agent and its preparation method and application
CN1778995A (en) * 2005-08-03 2006-05-31 夏光甫 Multifunctional high-efficient metal anti-rusting liquid for removing oil
JP2012180562A (en) * 2011-03-01 2012-09-20 Yushiro Chemical Industry Co Ltd Aqueous solution of rust-removing agent
CN102943258A (en) * 2012-09-18 2013-02-27 上海金兆节能科技有限公司 Environment-friendly rust-removing anti-rust agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030114328A1 (en) * 2001-09-22 2003-06-19 Kwon-Taeg Kim Water-soluble composition for removing rust from steel bar and steel frame
CN1624201A (en) * 2004-12-07 2005-06-08 山东省科学院新材料研究所 Anticorrosion rust eliminating agent and its preparation method and application
CN1778995A (en) * 2005-08-03 2006-05-31 夏光甫 Multifunctional high-efficient metal anti-rusting liquid for removing oil
JP2012180562A (en) * 2011-03-01 2012-09-20 Yushiro Chemical Industry Co Ltd Aqueous solution of rust-removing agent
CN102943258A (en) * 2012-09-18 2013-02-27 上海金兆节能科技有限公司 Environment-friendly rust-removing anti-rust agent

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105951109A (en) * 2016-07-13 2016-09-21 南通中兴多元复合钢管有限公司 Rust remover
CN106011898A (en) * 2016-07-14 2016-10-12 南通中兴多元复合钢管有限公司 Rust removing agent
CN108531917A (en) * 2017-03-05 2018-09-14 长沙丰畅车辆工程技术有限公司 A kind of loosening agent
CN108531915A (en) * 2017-03-05 2018-09-14 长沙丰畅车辆工程技术有限公司 A kind of environment-friendly rust remover
CN108531918A (en) * 2017-03-05 2018-09-14 长沙丰畅车辆工程技术有限公司 A kind of Deruster for metal
CN108531916A (en) * 2017-03-05 2018-09-14 长沙丰畅车辆工程技术有限公司 A kind of potent rust remover
CN108531928A (en) * 2017-03-05 2018-09-14 长沙丰畅车辆工程技术有限公司 A kind of explosion-proof rust remover
CN107326380A (en) * 2017-07-17 2017-11-07 安徽华翎羽毛制品有限公司 A kind of shuttlecock club rust remover
CN109746648A (en) * 2019-03-04 2019-05-14 黄山中链科技有限公司 A kind of engine chain production technology of high-strength abrasion-proof

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Inventor after: Liu Bing

Inventor before: Zhang Yifan

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Effective date of registration: 20170410

Address after: 528311 Guangdong City, Shunde Province, Beijiao Town, Xin Village East Industrial Zone, No. 5

Applicant after: Foshan Hemingway Ecological Technology Co., Ltd.

Address before: 610000 Jinjiang District, Chengdu, No. 1 East Ring Road, Sichuan No. five, building 1-1, layer 108, No. 21, No. 2106

Applicant before: CHENGDU JINHUI TECHNOLOGY CO., LTD.

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Address after: 528311 Guangdong City, Shunde Province, Beijiao Town, Xin Village East Industrial Zone, No. 5

Patentee after: FOSHAN HAIMINGWEI ECOLOGICAL TECHNOLOGY Co.,Ltd.

Address before: 528311 Guangdong City, Shunde Province, Beijiao Town, Xin Village East Industrial Zone, No. 5

Patentee before: FOSHAN CITY HAIMINGWEI ECOLOGICAL TECHNOLOGY Co.,Ltd.

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Denomination of invention: rust remover

Effective date of registration: 20211208

Granted publication date: 20170503

Pledgee: Beijiao sub branch of Guangdong Shunde Rural Commercial Bank Co., Ltd

Pledgor: FOSHAN HAIMINGWEI ECOLOGICAL TECHNOLOGY Co.,Ltd.

Registration number: Y2021980014477