CN105177600B - A kind of rust remover - Google Patents

A kind of rust remover Download PDF

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Publication number
CN105177600B
CN105177600B CN201510516628.1A CN201510516628A CN105177600B CN 105177600 B CN105177600 B CN 105177600B CN 201510516628 A CN201510516628 A CN 201510516628A CN 105177600 B CN105177600 B CN 105177600B
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Prior art keywords
parts
rust remover
acid
sodium
vinegar
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CN105177600A (en
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欧阳名化
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Wenzhou Aoyang Technology Co ltd
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Wenzhou Oryang Science And Technology Co Ltd
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Abstract

The invention belongs to metal-derusting field, specially a kind of rust remover, include the material that following weight is divided:10 21 parts of polyglutamic acid, 20 31 parts of complexing agent, 7 21 parts of sodium carbonate, 58 parts of pure water, 7 17 parts of sodium chloride, 3 15 parts of vinegar.The rust remover of the present invention substantially does not produce smog and pernicious gas when in use, does not stimulate skin, the advantages that allergic phenomena will not occur to human body, the basic generation without waste liquid in descaling process, does not pollute the environment, and convenience is brought to environmental protection work.

Description

A kind of rust remover
Technical field
The invention belongs to metal-derusting field, specially a kind of rust remover.
Background technology
Metal is placed under outdoor or open-air condition and got rusty easily, and not only influences presentation quality, and the work such as can also influence to paint, be bonded Skill is normally carried out, and is such as handled not in time, can more be caused scrapping for material, cause unnecessary economic loss.The conventional derusting of metal Mode one is physics derusting, i.e., the rust of metal surface is removed using modes such as frosted, sandblastings, but this mode derusts and is only applicable to letter Either simplex part, and derusting quality cannot be guaranteed;Another way is chemical derusting, and chemical derusting is usually using strong acid, sour energy Chemically reacted with iron rust and metal oxide, generate solubility salt, so as to reach the purpose of derusting, while derusting, acid is again It can be reacted with underlying metal and release hydrogen, Hydrogen Energy produces pressure to the oxide skin of iron rust and indissoluble, is advantageous to their peeling and height The reduction of valency iron, accelerate the process of pickling.Such as Chinese patent CN104087965A " a kind of rust remover ", by the raw material components of following number Composition:30-35 parts phosphoric acid, 18-22 parts formic acid, 10-12 parts ethanol, 15-18 parts hydrochloric acid, 5-6 parts boric acid, 7-8 parts polyethylene glycol, 3-5 parts Dodecyl sodium sulfate, 5-8 parts cocoanut fatty acid diethanolamide, 6-8 parts odium stearate, 5-7 parts polyvinyl alcohol, 4-5 parts are stearic Acid glyceride, 2-3 parts sodium metasilicate, 3-4 parts methanol, 6-7 parts acetic acid, the pure pure water of 50-55 parts.And for example Chinese patent Chinese patent CN103774158A " a kind of rust remover ", by hydrochloric acid 36.2%-74.5%, dilute sulfuric acid 9%-35%, neopelex 2%-11% are double Oxygen pure water 1%-7.5%, triethanolamine 1%-5%, citric acid 0.3%-2%, sodium chloride 0.6%-3%, acetone 5%-35% compositions, the percentage Than for mass percent.But traditional acid solution processing method there is also it is obvious the defects of:The generation of a large amount of hydrogen i.e. in processing procedure Steel can be made to produce Hydrogen Brittleness Phenomena, cause the mechanical properties decrease of metal, influence the intensity of steel in itself;Acid mist, shadow are easily formed simultaneously Ring the equipment and environment around the health and corrosion of operating personnel;The consumption of acid solution is also larger, increases processing cost;This kind of acid meeting pair Steel form excessive erosion.In addition a large amount of caused residues, need to often be discharged, both heavy corrosion industrial pipeline, and contaminated soil and environment.
The content of the invention
In order to solve the above technical problems, the present invention provides a kind of rust remover, realized by improving formula in descaling process not Smog and pernicious gas are produced, and disposably can be derusted comprehensively, improves rust cleaning efficiency.
The concrete technical scheme of the present invention is a kind of rust remover, includes the material of following weight point:
Polyglutamic acid 10-21 parts
Complexing agent 20-31 parts
Sodium carbonate 7-21 parts
Pure water 5-8 parts
Sodium chloride 7-17 parts
Vinegar 3-15 parts.
As the preferable technical scheme of the present invention, a kind of rust remover also includes the additive of 10-30 parts, the addition Material be caffeic acid, sinapic acid, cinnamic acid or citrate in one kind or any weight than it is a variety of.
As the preferable technical scheme of the present invention, the citrate is preferably sodium citrate.
As the preferable technical scheme of the present invention, the complexing agent is EDTA, the methene phosphate of amino two, carboxylic ethylenediamine Any weight of four acetic acid or three compare mixture.
As the preferable technical scheme of the present invention, the preferred methene sodium phosphate of amino two of the methene phosphate of amino two.
Beneficial effects of the present invention are
The present invention makes full use of the adsorption function of polyglutamic acid and faintly acid removes rusty scale, and is gone back using complexing agent absorption Metal ion in former rusty scale;Using vinegar, sodium chloride and sodium carbonate, can aid in promoting in the pure aqueous solution of polyglutamic acid Derusting, derusting are complete.
The rust remover of the present invention using polyglutamic acid and other additives, when in use it is obvious do not produce smog with Pernicious gas, skin is not stimulated, the advantages that allergic phenomena will not be occurred to human body, the basic production without waste liquid in descaling process It is raw, do not pollute the environment, very big benefit is brought to environmental protection work.
Embodiment
In order to preferably explain technical scheme, it is described below in conjunction with embodiment.
Embodiment 1
A kind of rust remover, include the material of following weight point:
10 parts of polyglutamic acid
20 parts of EDTA
7 parts of sodium carbonate
5 parts of pure water
7 parts of sodium chloride
3 parts of vinegar
10 parts of sinapic acid.
Embodiment 2
A kind of rust remover, include the material of following weight point:
21 parts of polyglutamic acid
31 parts of carboxylic EDTA
21 parts of sodium carbonate
8 parts of pure water
17 parts of sodium chloride
15 parts of vinegar
30 parts of cinnamic acid.
Embodiment 3
A kind of rust remover, include the material of following weight point:
11 parts of polyglutamic acid
9 parts of EDTA
11 parts of carboxylic EDTA
11 parts of sodium carbonate
7 parts of pure water
15 parts of sodium chloride
12 parts of vinegar
13 parts of potassium citrate.
Embodiment 4
A kind of rust remover, include the material of following weight point:
17 parts of polyglutamic acid
27 parts of two methene phosphate of amino
14 parts of sodium carbonate
6 parts of pure water
13 parts of sodium chloride
12 parts of vinegar
10 parts of sinapic acid
5 parts of cinnamic acid
15 parts of sodium citrate.
Embodiment 5
A kind of rust remover, include the material of following weight point:
12 parts of polyglutamic acid
9 parts of EDTA
11 parts of two methene sodium phosphate of amino
4 parts of carboxylic EDTA
17 parts of sodium carbonate
7 parts of pure water
10 parts of sodium chloride
7 parts of vinegar
30 parts of caffeic acid.
Embodiment 6
A kind of rust remover, include the material of following weight point:
18 parts of polyglutamic acid
11 parts of EDTA
12 parts of two methene sodium phosphate of amino
19 parts of sodium carbonate
6 parts of pure water
15 parts of sodium chloride
7 parts of vinegar
11 parts of sinapic acid
12 parts of cinnamic acid or sodium citrate.
Embodiment 7
A kind of rust remover, include the material of following weight point:
10 parts of polyglutamic acid
10 parts of two methene sodium phosphate of amino
15 parts of carboxylic EDTA
17 parts of sodium carbonate
7 parts of pure water
8 parts of sodium chloride
13 parts of vinegar
4 parts of caffeic acid
4 parts of sinapic acid
4 parts of cinnamic acid
4 parts of sodium citrate.
Embodiment 8
A kind of rust remover, include the material of following weight point:
11 parts of polyglutamic acid
21 parts of EDETATE SODIUM
17 parts of sodium carbonate
5.8 parts of pure water
17 parts of sodium chloride
9 parts of vinegar.
Embodiment 9
A kind of rust remover, include the material of following weight point:
16 parts of polyglutamic acid
23 parts of sodium nitrilo triacetate
13 parts of sodium carbonate
6.7 parts of pure water
12 parts of sodium chloride
13 parts of vinegar
15 parts of caffeic acid
7 parts of sodium citrate.
Embodiment 10
A kind of rust remover, include the material of following weight point:
11 parts of polyglutamic acid
21 parts of carboxylic EDTA
21 parts of sodium carbonate
8 parts of pure water
7.7 parts of sodium chloride
3.5 parts of vinegar
7 parts of sinapic acid
13 parts of potassium citrate.
Embodiment 11
A kind of rust remover, include the material of following weight point:
13 parts of polyglutamic acid
27 parts of carboxylic EDTA
19 parts of sodium carbonate
7 parts of pure water
10 parts of sodium chloride
9 parts of vinegar
13 parts of cinnamic acid.
Embodiment 12
A kind of rust remover, include the material of following weight point:
17 parts of polyglutamic acid
21 parts of two methene sodium phosphate of amino
19 parts of sodium carbonate
6 parts of pure water
12 parts of sodium chloride
8 parts of vinegar
18 parts of sodium citrate.
It rust remover described in embodiment 1-7,7-12, when on wheel hub, can derust, and can derust completely in 10s; Embodiment 8 can derust completely in 12s.
The present invention will not cause corrosion or other injuries to wheel hub, and the rust on wheel hub can be disappeared well Remove, ensure that the advantages of will not also destroying wheel hub even if long-term use, using large-scale popularization and application, and each composition into This is cheap, compared to existing rust remover, can substantially reduce the input cost of user.
The technological thought of above example only to illustrate the invention, it is impossible to protection scope of the present invention is limited with this, it is every According to technological thought proposed by the present invention, any change done on the basis of technical scheme, the scope of the present invention is each fallen within Within.

Claims (5)

1. a kind of rust remover, it is characterised in that include the material of following weight point:
Polyglutamic acid 10-21 parts
Complexing agent 20-31 parts
Sodium carbonate 7-21 parts
Pure water 5-8 parts
Sodium chloride 7-17 parts
Vinegar 3-15 parts.
A kind of 2. rust remover according to claim 1, it is characterised in that:Also include the additive of 10-30 parts, it is described to add Add material be caffeic acid, sinapic acid, cinnamic acid or citrate in one kind or any weight than it is a variety of.
A kind of 3. rust remover according to claim 2, it is characterised in that:The citrate is preferably sodium citrate.
A kind of 4. rust remover according to claim 1, it is characterised in that:The complexing agent is EDTA, the methene phosphorus of amino two Hydrochlorate, carboxylic EDTA or any weight of three compare mixture.
A kind of 5. rust remover according to claim 4, it is characterised in that:The preferred amino two of the methene phosphate of amino two Methene sodium phosphate.
CN201510516628.1A 2015-08-21 2015-08-21 A kind of rust remover Active CN105177600B (en)

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CN105177600B true CN105177600B (en) 2018-02-06

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106011898A (en) * 2016-07-14 2016-10-12 南通中兴多元复合钢管有限公司 Rust removing agent
CN106637238A (en) * 2016-12-29 2017-05-10 柳州市凯夕贸易有限公司 Efficient anti-rusting agent and preparation method thereof
CN109280870A (en) * 2018-09-05 2019-01-29 安徽鸿杰威尔停车设备有限公司 A kind of Multilayer garage steel structure surface processing mode
CN113105956A (en) * 2021-04-22 2021-07-13 程泉熠 Compound treating agent for cleaning glass products in chemical laboratory and preparation method thereof
CN114774942A (en) * 2021-12-29 2022-07-22 苏州盈得化学科技有限公司 Stainless steel pipe surface treating agent and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101787536A (en) * 2009-11-10 2010-07-28 南通飞拓生物科技有限公司 Normal temperature hydrochloric acid-washing rust-removing additive
CN102031531A (en) * 2010-12-13 2011-04-27 天津万起帅先工贸有限公司 Sewage disposal and rust removal agent for metal surface

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10200727C1 (en) * 2002-01-11 2003-06-12 Clariant Gmbh External cleaner for means of transport, e.g. car, lorry, train, tram and especially aircraft, contains tertiary amine oxide and alkali metal polyaspartate and/or polyglutamate

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101787536A (en) * 2009-11-10 2010-07-28 南通飞拓生物科技有限公司 Normal temperature hydrochloric acid-washing rust-removing additive
CN102031531A (en) * 2010-12-13 2011-04-27 天津万起帅先工贸有限公司 Sewage disposal and rust removal agent for metal surface

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Inventor after: Ouyang Minghua

Inventor before: Qian Guodong

CB03 Change of inventor or designer information
TA01 Transfer of patent application right

Effective date of registration: 20171229

Address after: Longwan District of Wenzhou City, Zhejiang province Yongzhong Street Village 325000 of Ji Feng Road No. 228 (B building, third floor)

Applicant after: WENZHOU AOYANG TECHNOLOGY CO.,LTD.

Address before: 214000 Huang Xing Road, Zhengyang village, Wuxi, Xishan District, Jiangsu, China

Applicant before: WUXI LEHUA AUTOMATION TECHNOLOGY Co.,Ltd.

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EE01 Entry into force of recordation of patent licensing contract
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Application publication date: 20151223

Assignee: Zhejiang Aoyang New Material Co.,Ltd.

Assignor: WENZHOU AOYANG TECHNOLOGY CO.,LTD.

Contract record no.: X2022980006109

Denomination of invention: A rust remover

Granted publication date: 20180206

License type: Common License

Record date: 20220526

EE01 Entry into force of recordation of patent licensing contract

Application publication date: 20151223

Assignee: Aoyang New Materials (Zhongshan) Co.,Ltd.

Assignor: WENZHOU AOYANG TECHNOLOGY CO.,LTD.

Contract record no.: X2024980007610

Denomination of invention: A rust remover

Granted publication date: 20180206

License type: Common License

Record date: 20240619