CN104789955B - A kind of anticolodal and its application - Google Patents
A kind of anticolodal and its application Download PDFInfo
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- CN104789955B CN104789955B CN201410839276.9A CN201410839276A CN104789955B CN 104789955 B CN104789955 B CN 104789955B CN 201410839276 A CN201410839276 A CN 201410839276A CN 104789955 B CN104789955 B CN 104789955B
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Abstract
The invention discloses a kind of anticolodal and its application, belong to field of metal surface treatment.Its composition and mass fraction are：58 parts of silicone oil, 15 parts of glycerine, 0.5 2 parts of polyamide, 13 parts of sodium pyrophosphate, 35 parts of acetic acid, 38 parts of oil-soluble phenolic resin, 7 12 parts of aluminum sulfate, 13 parts of citric acid, 35 parts of zinc dialkyl dithiophosphate, 70 80 parts of deionized water.Advantages of nontoxic raw materials of the present invention; body will not be caused damage in process of production; preservative treatment is carried out to metal using the present invention; layer protecting film can be formed in metal surface, the antiseptic property of metal can not only be strengthened, extend the life-span of metal material and device; it is and environmentally safe; degradable, cost is low, in particular for the incision of galvanized steel plain sheet.
Description
Technical field
The invention belongs to field of metal surface treatment, specifically, is related to a kind of anticolodal and its application.
Background technology
Metal is processed and use during corrosion of metal often occurs so that metal material or metal
The service life of equipment reduces, and existing anticolodal has cost height, raw material because endangering worker's body with toxicity
The problems such as body health, pollution environment, therefore, urgent need is a kind of environmentally safe, does not damage the anticolodal of human body health,
Strengthen the antiseptic property of metal by the preservative treatment to metal, extend the service life of metal material, workpiece and instrument, save
The energy, especially very conventional galvanized steel plain sheet, its purposes is wide, but antiseptic effect is undesirable, and especially galvanized steel plain sheet is in metal plate
Sheared and punched etc. in gold process processing in the case of having destruction to matrix, incision is easiest to be damaged, kindred circumstances
Under corroded at first, turn into the erosion-resisting short slab of galvanized steel plain sheet.
The content of the invention
1st, to solve the problems, such as
For existing preservative in preparation process due to raw material has toxicity and damage health, pollution environment and into
The problem of this is higher, the present invention provide a kind of anticolodal and its application, and can effectively prevent metal improves the anti-of metal
Rotten performance, environmental pollution is minimum, and health will not be damaged during use, and cost is low, easy to spread.
2nd, technical scheme
To solve the above problems, the technical scheme is that：
A kind of anticolodal, its composition and mass fraction are：
Silicone oil 5-8 parts；
Glycerine 1-5 parts；
Polyamide 0.5-2 parts；
Sodium pyrophosphate 1-3 parts；
Acetic acid 3-5 parts；
Oil-soluble phenolic resin 3-8 parts；
Aluminum sulfate 7-12 parts；
Citric acid 1-3 parts；
Deionized water 70-80 parts.
Preferably, described silicone oil is methyl-silicone oil, and oil-soluble phenolic resin is the short oil using dimethylbenzene as solvent
Oil-soluble phenolic resin.
Preferably, its component and its mass fraction are as follows：
5 parts of silicone oil；
3 parts of glycerine；
2 parts of polyamide；
3 parts of sodium pyrophosphate；
4 parts of acetic acid；
3 parts of oil-soluble phenolic resin；
7 parts of aluminum sulfate；
1 part of citric acid；
75 parts of deionized water.
The application of sodium pyrophosphate or glycerine or zinc dialkyl dithiophosphate in anti-corrosion of metal.
Application of the foregoing preservatives in panel beating.
3rd, beneficial effect
Compared to prior art, beneficial effects of the present invention are：
(1) present invention is by silicone oil, glycerine, polyamide, sodium pyrophosphate, acetic acid, oil-soluble phenolic resin, aluminum sulfate, lemon
Lemon acid and deionized water composition, advantages of nontoxic raw materials of the present invention, will not cause damage to body, use in process of production
The present invention carries out preservative treatment to metal, can form layer protecting film in metal surface, can not only strengthen the anti-corrosive properties of metal
Can, the life-span of extension metal material and device, and it is environmentally safe, and degradable, cost is low, in particular for galvanized steel plain sheet
Incision；
(2) the silicone oil heat resistance and chemical stability that the present invention uses are good, and oil-soluble phenolic resin not only has good
Water resistance, acid resistance, the addition of sodium pyrophosphate, glycerine and zinc dialkyl dithiophosphate so that the film of made preservative is hard
Degree is high and flexible, fast drying, adhesive force are good, can form one layer of fine and close diaphragm in metal surface, effectively prevent outer
Infringement of boundary's environment to metal, in particular for the incision of galvanized steel plain sheet during metal plate；
(3) cost of the present invention is low, degradable, safe to use, environmentally safe, is advantageous to promote the use of well.
Embodiment
Specific embodiment is of the invention to be discussed in detail below.
Embodiment 1
A kind of anticolodal, using 5 parts of silicone oil, 3 parts of glycerine, 2 parts of polyamide, 3 parts of sodium pyrophosphate, 4 parts of acetic acid, oil
75 parts of 3 parts of dissolubility phenolic resin, 7 parts of aluminum sulfate, 1 part of citric acid, 4 parts of zinc dialkyl dithiophosphate and deionized water.
Preparation method, its step are as follows：
(a) weighed by mass fraction, taking 5 parts of silicone oil and 3 parts of oil-soluble phenolic resins, (silicone oil that the present invention uses is methyl
Silicone oil, oil-soluble phenolic resin are the oil-soluble phenolic resins using dimethylbenzene as the short oil of solvent) under the conditions of 80 DEG C of water-bath
Stirring 50 minutes, standing are cooled to 38 DEG C；
(b) 3 parts of glycerine, 4 parts of acetic acid, 4 parts of zinc dialkyl dithiophosphates are added in the solution obtained into step (a)
Stirred 30 minutes under the conditions of 36 DEG C with 1 part of citric acid, be incubated 18 minutes；
(c) solution obtained in step (b) is cooled to 23 DEG C, adds 2 parts of polyamide, 3 parts of sodium pyrophosphates, 7 parts of sulfuric acid
Aluminium and 75 parts of deionized waters stir 13 minutes and produce anticolodal.
When in use, application method comprises the following steps anticolodal：
(d) anticolodal prepared in step (c) is heated to 75 DEG C, stirs 4min；
(e) by pending galvanized steel plain sheet, (it is the rectangular of 200mm that the galvanized steel plain sheet that thickness is 2.5mm is cut into the length of side
Shape, while 2 a diameter of 10mm through hole has been stamped out on sheet material) be added in the solution in step (d), 40s is soaked, is pulled out
Workpiece；
(f) speed is used to be dried up for 10m/s cold wind the workpiece pulled out in step (e), the temperature of cold wind is 2-6 DEG C；
(g) workpiece after being dried up in step (f) is placed in the environment of dark and places 36h, the workpiece after being handled.
Found after salt mist experiment, treated workpiece is not than having the raising of the anti-corrosion time of treated workpiece
28%, and the place of treated workpiece corrosion at first is not the edge of shearing and through hole, and the present invention is to galvanized steel plain sheet
Sheared edge can play obvious antisepsis.Use service life of the galvanized steel plain sheet workpiece that the present invention is handled than no processing
Extend 1 year, the material corrosion resistance of oxidant and acid-base property is significantly increased, the waste water easily biological-degradable after processing, to environment
It is pollution-free and harmless to the health of operator.
Embodiment 2
With embodiment 1, except that the content of each material and preparation method parameter change, its step is as follows：
(a) weighed by mass fraction, take 6 parts of silicone oil and 5 parts of oil-soluble phenolic resins to stir 60 under the conditions of 80 DEG C of water-bath
Minute, standing is cooled to 30 DEG C；
(b) 5 parts of glycerine, 5 parts of acetic acid, 3 parts of zinc dialkyl dithiophosphates are added in the solution obtained into step (a)
Stirred 40 minutes under the conditions of 30 DEG C with 2 parts of citric acids, be incubated 15 minutes；
(c) solution obtained in step (b) is cooled to 20 DEG C, adds 0.5 part of polyamide, 1 part of sodium pyrophosphate, 12 parts of sulphur
Sour aluminium and 70 parts of deionized waters stir 15 minutes and produce anticolodal.
When in use, application method comprises the following steps anticolodal：
(d) anticolodal prepared in step (c) is heated to 80 DEG C, stirs 3min；
(e) by pending galvanized steel plain sheet, (it is the rectangular of 200mm that the galvanized steel plain sheet that thickness is 2.5mm is cut into the length of side
Shape, while 2 a diameter of 7mm through hole has been stamped out on sheet material) be added in the solution in step (d), 30s is soaked, is pulled out
Workpiece；
(f) speed is used to be dried up for 10m/s cold wind the workpiece pulled out in step (e), the temperature of cold wind is 2-6 DEG C；
(g) workpiece after being dried up in step (f) is placed in the environment of dark and places 24h, the workpiece after being handled.
Found after salt mist experiment, treated workpiece is not than having the raising of the anti-corrosion time of treated workpiece
23%, and the place of treated workpiece corrosion at first is not the edge of shearing and through hole, and the present invention is to galvanized steel plain sheet
Sheared edge can play obvious antisepsis.
Embodiment 3
With embodiment 1, except that the content of each material and preparation method parameter change, its step is as follows：
(a) weighed by mass fraction, take 8 parts of silicone oil and 8 parts of oil-soluble phenolic resins to stir 45 under the conditions of 80 DEG C of water-bath
Minute, standing is cooled to 45 DEG C；
(b) 1 part of glycerine, 3 parts of acetic acid, 5 parts of zinc dialkyl dithiophosphates are added in the solution obtained into step (a)
Stirred 20 minutes under the conditions of 45 DEG C with 3 parts of citric acids, be incubated 20 minutes；
(c) solution obtained in step (b) is cooled to 25 DEG C, adds 1 part of polyamide, 2 parts of sodium pyrophosphates, 9 parts of sulfuric acid
Aluminium and 80 parts of deionized waters stir 10 minutes and produce anticolodal.
When in use, application method comprises the following steps anticolodal：
(d) anticolodal prepared in step (c) is heated to 70-80 DEG C, stirs 5min；
(e) by pending galvanized steel plain sheet, (it is the rectangular of 200mm that the galvanized steel plain sheet that thickness is 2.5mm is cut into the length of side
Shape, while 2 a diameter of 10mm through hole has been stamped out on sheet material) be added in the solution in step (d), 50s is soaked, is pulled out
Workpiece；
(f) speed is used to be dried up for 10m/s cold wind the workpiece pulled out in step (e), the temperature of cold wind is 2-6 DEG C；
(g) workpiece after being dried up in step (f) is placed in the environment of dark and places 48h, the workpiece after being handled.
Found after salt mist experiment, treated workpiece is not than having the raising of the anti-corrosion time of treated workpiece
25%, and the place of treated workpiece corrosion at first is not the edge of shearing and through hole, and the present invention is to galvanized steel plain sheet
Sheared edge can play obvious antisepsis.
Claims (4)
1. a kind of anticolodal, its composition and mass fraction are：
Silicone oil 5-8 parts；
Glycerine 1-5 parts；
Polyamide 0.5-2 parts；
Sodium pyrophosphate 1-3 parts；
Acetic acid 3-5 parts；
Oil-soluble phenolic resin 3-8 parts；
Aluminum sulfate 7-12 parts；
Citric acid 1-3 parts；
Zinc dialkyl dithiophosphate 3-5 parts；
Deionized water 70-80 parts.
2. a kind of anticolodal according to claim 1, it is characterised in that described silicone oil is methyl-silicone oil, and oil is molten
Property phenolic resin is the oil-soluble phenolic resin using dimethylbenzene as the short oil of solvent.
3. a kind of anticolodal according to claim 1, it is characterised in that component and its mass fraction are as follows：
5 parts of silicone oil；
3 parts of glycerine；
2 parts of polyamide；
3 parts of sodium pyrophosphate；
4 parts of acetic acid；
3 parts of oil-soluble phenolic resin；
7 parts of aluminum sulfate；
1 part of citric acid；
4 parts of zinc dialkyl dithiophosphate；
75 parts of deionized water.
4. application of the preservative of claim 1 in panel beating.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410839276.9A CN104789955B (en) | 2014-12-30 | 2014-12-30 | A kind of anticolodal and its application |
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| CN201410839276.9A CN104789955B (en) | 2014-12-30 | 2014-12-30 | A kind of anticolodal and its application |
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| CN104789955A CN104789955A (en) | 2015-07-22 |
| CN104789955B true CN104789955B (en) | 2017-12-05 |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105463470A (en) * | 2015-11-25 | 2016-04-06 | 安徽红桥金属制造有限公司 | Non-ferrous metal antiseptic treating agent and application thereof |
| CN105350002A (en) * | 2015-11-25 | 2016-02-24 | 安徽红桥金属制造有限公司 | Corrosion-inhibiting treatment agent for metal part and application thereof |
| CN105624631A (en) * | 2015-12-31 | 2016-06-01 | 芜湖市金宇石化设备有限公司 | Anti-corrosion treatment technology for bottom plate of automobile seat |
| CN105543830A (en) * | 2015-12-31 | 2016-05-04 | 芜湖市金宇石化设备有限公司 | Anti-corrosion precursor composition for anti-corrosion treatment on automobile seat bottom plate |
| CN105623441A (en) * | 2015-12-31 | 2016-06-01 | 芜湖市金宇石化设备有限公司 | Preparation method of anti-corrosion precursor composition for anti-corrosion treatment of car seat base plate |
| CN105648392A (en) * | 2015-12-31 | 2016-06-08 | 芜湖市金宇石化设备有限公司 | Thermal treatment method for gearbox housing |
| CN106399987A (en) * | 2016-09-29 | 2017-02-15 | 广州市汇吉科技企业孵化器有限公司 | Anhydrous phosphating agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724836A (en) * | 2009-10-23 | 2010-06-09 | 启东市合成化工厂有限公司 | Passivating treating agent for environment-friendly galvanized steel sheets |
| CN103726043A (en) * | 2012-10-12 | 2014-04-16 | 日本巴卡黎神谷股份有限公司 | Water-based metal surface treatment agent, metal surface processing envelope and metal material with same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS5913595B2 (en) * | 1977-10-21 | 1984-03-30 | 日本農薬株式会社 | Metal corrosion inhibitor and corrosion prevention method |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724836A (en) * | 2009-10-23 | 2010-06-09 | 启东市合成化工厂有限公司 | Passivating treating agent for environment-friendly galvanized steel sheets |
| CN103726043A (en) * | 2012-10-12 | 2014-04-16 | 日本巴卡黎神谷股份有限公司 | Water-based metal surface treatment agent, metal surface processing envelope and metal material with same |
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Address after: 241000 Anhui Province, Wuhu City Fumin Jiujiang Road Economic Development Zone Applicant after: ANHUI XIECHENG INDUSTRY CO., LTD. Address before: 241000 Anhui Province, Wuhu City Fumin Jiujiang Road Economic Development Zone Applicant before: WUHU XIECHENG METAL PRODUCTS CO., LTD. |
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Denomination of invention: A metal anticorrosion agent and applications thereof Effective date of registration: 20191220 Granted publication date: 20171205 Pledgee: Wuhu Xinwu sub branch of Huishang bank Pledgor: ANHUI XIECHENG INDUSTRY CO., LTD. Registration number: Y2019980001192 |