CN106046868A - Falling-off-preventing metal coating and preparation method thereof - Google Patents
Falling-off-preventing metal coating and preparation method thereof Download PDFInfo
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- CN106046868A CN106046868A CN201610392475.9A CN201610392475A CN106046868A CN 106046868 A CN106046868 A CN 106046868A CN 201610392475 A CN201610392475 A CN 201610392475A CN 106046868 A CN106046868 A CN 106046868A
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- parts
- metal coating
- antirust agent
- preventing metal
- slip
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a falling-off-preventing metal coating and a preparation method thereof. The falling-off-preventing metal coating comprises raw materials in parts by weight as follows: 10-20 parts of polyether silicate ester, 20-30 parts of gamma-valerolactone, 40-60 parts of 2-ethyl-1,6-hexanediol, 10-50 parts of zinc, 10-20 parts of calcium oxide, 2-5 parts of an anti-rusting agent, 100-120 parts of nano-silica, 50-80 parts of nano-titania, 10-60 parts of thiourea, 20-30 parts of diammonium hydrogen phosphate and 40-50 parts of water. The preparation method of the falling-off-preventing metal coating comprises steps as follows: polyether silicate ester, gamma-valerolactone, 2-ethyl-1,6-hexanediol, zinc, calcium oxide, the anti-rusting agent, thiourea, diammonium hydrogen phosphate and water are mixed uniformly, then the remaining components are added, and a metal surface subjected to deoiling, annealing and borax processing is coated with an obtained solution and is dried and sintered. The coating can be effectively attached to the metal surface, thereby preventing metal from rusting and oxidation.
Description
Technical field
The present invention relates to a kind of slip-off preventing metal coating and preparation method thereof.
Background technology
Coating (coating) is that coating once applies obtained solid-state continuous film, is to protect, insulation, decoration etc.
Purpose, coats metal, fabric, the plastic sheet on the matrix such as plastics.Coating can be gaseous state, liquid, solid-state, generally according to
The substrate needing spraying determines kind and the state of coating.
It is resistance to that the Chinese patent application of Application No. CN201410411117.9 discloses a kind of steel structure arc spraying aluminum base
The method of erosion metal coating, described aluminum base corrosion resistant metal coating is aluminum, nickel composite metal coating, and described spraying method includes as follows
Step: (1) matrix surface pretreatment；(2) matrix surface spray metal coating；(3) metal coating sealing treatment.By above-mentioned side
Formula, the thickness of aluminum nickel corrosion resistant metal coating prepared by this invention is 0.3～0.5mm, soaks 100h and do not produce in 5%NaCl solution
Raw corrosion phenomena.The preparation method of this invention a kind of steel construction corrosion resistant aluminium Base Metal coating, easy to operate, low cost, spray matter
Measuring safe and reliable, prepared aluminum nickel composite metal coating has the corrosion resisting property of excellence, and practicality is high.But this coating is easy
Peel off, and the adhesive force between metal is poor.
Summary of the invention
The present invention is directed to the deficiencies in the prior art, it is provided that a kind of slip-off preventing metal coating and preparation method thereof, this coating
Can firmly be attached to metal surface, thus prevent the corrosion of metal surface.
The present invention is by the following technical solutions:
Slip-off preventing metal coating, including the raw material of following weight portion meter: vinegar 20～30 in polyethers esters of silicon acis 10～20 parts, γ mono-penta
Part, 2-ethyl-1,6-HD 40～60 parts, zinc 10～50 parts, calcium oxide 10～20 parts, antirust agent 2～5 parts, nano-silica
SiClx 100～120 parts, nano titanium oxide 50～80 parts, thiourea 10～60 parts, diammonium phosphate 20～30 parts, water 40～50
Part.
As preferably, slip-off preventing metal coating, including the raw material of following weight portion meter: polyethers esters of silicon acis 15 parts, γ mono-penta
Interior vinegar 25 parts, 2-ethyl-1,6-HD 50 parts, 30 parts of zinc, calcium oxide 15 parts, antirust agent 3 parts, nano silicon 110 parts,
Nano titanium oxide 60 parts, thiourea 40 parts, diammonium phosphate 25 parts, 45 parts of water.
As preferably, slip-off preventing metal coating, including the raw material of following weight portion meter: polyethers esters of silicon acis 10 parts, γ mono-penta
Interior vinegar 20 parts, 2-ethyl-1,6-HD 40 parts, 10 parts of zinc, calcium oxide 10 parts, antirust agent 2 parts, nano silicon 100 parts,
Nano titanium oxide 50 parts, thiourea 10 parts, diammonium phosphate 20 parts, 40 parts of water.
As preferably, slip-off preventing metal coating, including the raw material of following weight portion meter: polyethers esters of silicon acis 20 parts, γ mono-penta
Interior vinegar 30 parts, 2-ethyl-1,6-HD 60 parts, 50 parts of zinc, calcium oxide 20 parts, antirust agent 5 parts, nano silicon 120 parts,
Nano titanium oxide 80 parts, thiourea 60 parts, diammonium phosphate 30 parts, 50 parts of water.
As preferably, antirust agent is water-based antirust agent.
As preferably, antirust agent is silane coupled antirust agent or polyol ester antirust agent.
The preparation method of above-mentioned slip-off preventing metal coating, comprises the following steps: by vinegar, 2-in polyethers esters of silicon acis, γ mono-penta
Ethyl-1, after 6-hexanediol, zinc, calcium oxide, antirust agent, thiourea, diammonium phosphate, water mix homogeneously, adds nano-silica
SiClx, nano titanium oxide, be coated in the metal surface after oil removing annealing Borax processes, be dried 30～40 at 1300～1500 DEG C
Minute, sinter 2～3 minutes at 900～1000 DEG C, to obtain final product.
Beneficial effect
The coating of the present invention can effectively be attached to metal surface, thus prevents metal rusting from aoxidizing.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further described in detail.
Embodiment 1
Slip-off preventing metal coating, including the raw material of following weight portion meter: vinegar 25 parts, 2-second in polyethers esters of silicon acis 15 parts, γ mono-penta
Base-1,6-HD 50 parts, 30 parts of zinc, calcium oxide 15 parts, antirust agent 3 parts, nano silicon 110 parts, nano titanium oxide
60 parts, thiourea 40 parts, diammonium phosphate 25 parts, 45 parts of water.
Antirust agent is silane coupled antirust agent.
The preparation method of above-mentioned slip-off preventing metal coating, comprises the following steps: by vinegar, 2-in polyethers esters of silicon acis, γ mono-penta
Ethyl-1, after 6-hexanediol, zinc, calcium oxide, antirust agent, thiourea, diammonium phosphate, water mix homogeneously, adds nano-silica
SiClx, nano titanium oxide, be coated in the metal surface after oil removing annealing Borax processes, be dried 30～40 at 1300～1500 DEG C
Minute, sinter 2～3 minutes at 900～1000 DEG C, to obtain final product.
Embodiment 2
Slip-off preventing metal coating, including the raw material of following weight portion meter: vinegar 20 parts, 2-second in polyethers esters of silicon acis 10 parts, γ mono-penta
Base-1,6-HD 40 parts, 10 parts of zinc, calcium oxide 10 parts, antirust agent 2 parts, nano silicon 100 parts, nano titanium oxide
50 parts, thiourea 10 parts, diammonium phosphate 20 parts, 40 parts of water.
Antirust agent is polyol ester antirust agent.
The preparation method of above-mentioned slip-off preventing metal coating, comprises the following steps: by vinegar, 2-in polyethers esters of silicon acis, γ mono-penta
Ethyl-1, after 6-hexanediol, zinc, calcium oxide, antirust agent, thiourea, diammonium phosphate, water mix homogeneously, adds nano-silica
SiClx, nano titanium oxide, be coated in the metal surface after oil removing annealing Borax processes, be dried 30～40 at 1300～1500 DEG C
Minute, sinter 2～3 minutes at 900～1000 DEG C, to obtain final product.
Embodiment 3
Slip-off preventing metal coating, including the raw material of following weight portion meter: vinegar 30 parts, 2-second in polyethers esters of silicon acis 20 parts, γ mono-penta
Base-1,6-HD 60 parts, 50 parts of zinc, calcium oxide 20 parts, antirust agent 5 parts, nano silicon 120 parts, nano titanium oxide
80 parts, thiourea 60 parts, diammonium phosphate 30 parts, 50 parts of water.
Antirust agent is silane coupled antirust agent.
The preparation method of above-mentioned slip-off preventing metal coating, comprises the following steps: by vinegar, 2-in polyethers esters of silicon acis, γ mono-penta
Ethyl-1, after 6-hexanediol, zinc, calcium oxide, antirust agent, thiourea, diammonium phosphate, water mix homogeneously, adds nano-silica
SiClx, nano titanium oxide, be coated in the metal surface after oil removing annealing Borax processes, be dried 30～40 at 1300～1500 DEG C
Minute, sinter 2～3 minutes at 900～1000 DEG C, to obtain final product.
Comparative example 1
Same as in Example 1, difference is: be not added with diammonium phosphate.
Performance test
The product of embodiment 1 ~ 3 and comparative example 1 is carried out adhesive force detection, by the metal of applying coating with steel sharp knife from the teeth outwards
Mark the cut being spaced apart 2mm, and guarantee that cut, as deep as matrix, the most each six, obtains the lattice of 25 2mm × 2mm；
Afterwards, use adhesive tape sticking experiment, the lattice number that statistics is stuck out, come whereby adhesive force is marked.Standards of grading are altogether
Be divided into 5 grades: the lattice number ＜ 5 come off for 5 points；The lattice number ＜ 10 come off for 4 points；The lattice number come off
＜ 15 for 3 points；The lattice number ＜ 20 that 15 ＜ come off for 2 points；The lattice number ＞ 20 come off for 1 point, the results are shown in Table
1。
Table 1
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | |
| Adhesive force | 5 points | 5 points | 5 points | 2 points |
Conclusion: the lattice number that comes off of the present invention is within 5, and adhesive force is substantially better than comparative example 1, and the coating of the present invention is described
Can effectively be attached to metal surface, thus prevent metal rusting from aoxidizing.
Claims (7)
1. slip-off preventing metal coating, it is characterised in that include the raw material of following weight portion meter: polyethers esters of silicon acis 10～20 parts, γ
Vinegar 20～30 parts, 2-ethyl-1,6-HD 40～60 parts, zinc 10～50 parts, calcium oxide 10～20 parts, antirust agent 2 in one penta
～5 parts, nano silicon 100～120 parts, nano titanium oxide 50～80 parts, thiourea 10～60 parts, diammonium phosphate 20～
30 parts, water 40～50 parts.
Slip-off preventing metal coating the most according to claim 1, it is characterised in that include the raw material of following weight portion meter: poly-
Vinegar 25 parts, 2-ethyl-1,6-HD 50 parts, 30 parts of zinc, calcium oxide 15 parts, antirust agent 3 in ether esters of silicon acis 15 parts, γ mono-penta
Part, nano silicon 110 parts, nano titanium oxide 60 parts, thiourea 40 parts, diammonium phosphate 25 parts, 45 parts of water.
Slip-off preventing metal coating the most according to claim 1, it is characterised in that include the raw material of following weight portion meter: poly-
Vinegar 20 parts, 2-ethyl-1,6-HD 40 parts, 10 parts of zinc, calcium oxide 10 parts, antirust agent 2 in ether esters of silicon acis 10 parts, γ mono-penta
Part, nano silicon 100 parts, nano titanium oxide 50 parts, thiourea 10 parts, diammonium phosphate 20 parts, 40 parts of water.
Slip-off preventing metal coating the most according to claim 1, it is characterised in that include the raw material of following weight portion meter: poly-
Vinegar 30 parts, 2-ethyl-1,6-HD 60 parts, 50 parts of zinc, calcium oxide 20 parts, antirust agent 5 in ether esters of silicon acis 20 parts, γ mono-penta
Part, nano silicon 120 parts, nano titanium oxide 80 parts, thiourea 60 parts, diammonium phosphate 30 parts, 50 parts of water.
Slip-off preventing metal coating the most according to claim 1, it is characterised in that antirust agent is water-based antirust agent.
Slip-off preventing metal coating the most according to claim 1, it is characterised in that antirust agent is silane coupled antirust agent or many
Unit's alcohol ester antirust agent.
7. preparation method based on the slip-off preventing metal coating described in claim 1, it is characterised in that comprise the following steps: will
In polyethers esters of silicon acis, γ mono-penta, vinegar, 2-ethyl-1,6-HD, zinc, calcium oxide, antirust agent, thiourea, diammonium phosphate, water mix
After closing uniformly, add nano silicon, nano titanium oxide, be coated in the metal surface after oil removing annealing Borax processes,
It is dried 30～40 minutes at 1300～1500 DEG C, sinters 2～3 minutes at 900～1000 DEG C, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610392475.9A CN106046868A (en) | 2016-06-06 | 2016-06-06 | Falling-off-preventing metal coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610392475.9A CN106046868A (en) | 2016-06-06 | 2016-06-06 | Falling-off-preventing metal coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106046868A true CN106046868A (en) | 2016-10-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610392475.9A Pending CN106046868A (en) | 2016-06-06 | 2016-06-06 | Falling-off-preventing metal coating and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634128A (en) * | 2016-12-21 | 2017-05-10 | 苏州劲元油压机械有限公司 | Anti-corrosion metal coating for hydraulic cylinder and preparation method thereof |
| CN106752145A (en) * | 2016-12-21 | 2017-05-31 | 钦州太平电子科技有限公司 | A kind of anti-foaming, the coating of electronic elements for coming off |
| CZ307644B6 (en) * | 2017-05-04 | 2019-01-30 | TESORO Spin off, s.r.o. | An anticorrosion and protection agent based on trivalent titanium compounds and a method of its preparation |
| US11008500B2 (en) | 2018-07-12 | 2021-05-18 | Championx Usa Inc. | Alkyl lactone-derived corrosion inhibitors |
| US11414588B2 (en) | 2018-07-12 | 2022-08-16 | Championx Usa Inc. | Alkyl lactone-derived hydroxyamides and alkyl lactone-derived hydroxyesters for the control of natural gas hydrates |
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| JP2001106781A (en) * | 1999-10-12 | 2001-04-17 | Arakawa Chem Ind Co Ltd | Curable composition and method for producing the same |
| CN1357583A (en) * | 2001-12-26 | 2002-07-10 | 曾庆衿 | Heat resistant and wear resistant power-saving metallic paint |
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| JP2001106781A (en) * | 1999-10-12 | 2001-04-17 | Arakawa Chem Ind Co Ltd | Curable composition and method for producing the same |
| CN1357583A (en) * | 2001-12-26 | 2002-07-10 | 曾庆衿 | Heat resistant and wear resistant power-saving metallic paint |
| CN101343506A (en) * | 2008-08-28 | 2009-01-14 | 胡仲寅 | Zinc metallic coating |
| CN104650729A (en) * | 2015-03-10 | 2015-05-27 | 江苏欣安新材料技术有限公司 | Preparation method of anti-falling corrosion-resistant double-metal composite coating |
Non-Patent Citations (1)
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634128A (en) * | 2016-12-21 | 2017-05-10 | 苏州劲元油压机械有限公司 | Anti-corrosion metal coating for hydraulic cylinder and preparation method thereof |
| CN106752145A (en) * | 2016-12-21 | 2017-05-31 | 钦州太平电子科技有限公司 | A kind of anti-foaming, the coating of electronic elements for coming off |
| CZ307644B6 (en) * | 2017-05-04 | 2019-01-30 | TESORO Spin off, s.r.o. | An anticorrosion and protection agent based on trivalent titanium compounds and a method of its preparation |
| US11008500B2 (en) | 2018-07-12 | 2021-05-18 | Championx Usa Inc. | Alkyl lactone-derived corrosion inhibitors |
| US11414588B2 (en) | 2018-07-12 | 2022-08-16 | Championx Usa Inc. | Alkyl lactone-derived hydroxyamides and alkyl lactone-derived hydroxyesters for the control of natural gas hydrates |
| US11459498B2 (en) | 2018-07-12 | 2022-10-04 | Championx Usa Inc. | Alkyl lactone-derived corrosion inhibitors |
| US12037539B2 (en) | 2018-07-12 | 2024-07-16 | Championx Llc | Alkyl lactone-derived hydroxyamides and alkyl lactone-derived hydroxyesters for the control of natural gas hydrates |
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Application publication date: 20161026 |