CN109757494A - A kind of Herbicidal combinations of the humulone of sulphur containing triazole and its application - Google Patents
A kind of Herbicidal combinations of the humulone of sulphur containing triazole and its application Download PDFInfo
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- CN109757494A CN109757494A CN201910163574.3A CN201910163574A CN109757494A CN 109757494 A CN109757494 A CN 109757494A CN 201910163574 A CN201910163574 A CN 201910163574A CN 109757494 A CN109757494 A CN 109757494A
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- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
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- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
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- A01N41/10—Sulfones; Sulfoxides
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- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
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- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
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- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
- A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
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- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
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- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
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Abstract
The invention belongs to pesticide fields, and in particular to a kind of Herbicidal combinations of the humulone of sulphur containing triazole and its application.The Herbicidal combinations include the active components A and active constituent B of herbicidally effective amount, wherein, active components A is triazole sulphur humulone, and active constituent B is selected from one of following compound or a variety of: indanofan, bromacil, 2 first, 4 chlorine sodium salt, prometryn, symetryne, halosulfuronmethyl, molinate, benthiocarb, metamifop, clefoxidim, benzobicylon, pentoxazone, isoproturon, pyrazosulfuron, furans sulphur humulone, penoxsuam.The composition can effectively prevent and kill off the weed problems such as barnyard grass, rice barnyard grass, semen euphorbiae in crop, have the characteristics that expand degrass spectrum, reduce amount of application, to crop safety, synergistic effect can be generated and solve resistant weed.
Description
The application be on 09 19th, 2017 the applying date, it is entitled " a kind of application No. is 201710852148.1
The divisional application of the Chinese invention patent application of the Herbicidal combinations of the humulone of sulphur containing triazole and its application ".
Technical field
The invention belongs to pesticide fields, and in particular to a kind of Herbicidal combinations of the humulone of sulphur containing triazole and its application.
Background technique
Chemical weed control is means the most economical and effective during farmland weed is prevented and kill off, but uses list to continuous high dose for a long time
The chemical herbicide of one kind or the single mode of action, the problems such as be easy to causeing weeds drug resistance and resistance evolution.Herbicide chemical combination
Object it is reasonable compounding or mixture have expand weeds spectrum, improve preventive effect, delay the generation of weeds drug resistance and drug resistance with
The advantages that development is one of the most effective methods to solve the above problems.
Patent CN105724390A discloses a variety of Herbicidal combinations containing pyrazole compound, including active group
Divide triazole sulphur humulone, chemical structural formula isIt is newly developed paddy field stem and leaf treatment after seedling
HPPD inhibitor class herbicide has excellent bioactivity, can effectively prevent and kill off a variety of malignant weeds of paddy field, but wherein
Cooperative synergism effect can be generated by not recording all combinations.
Therefore it needs to develop highly-safe, broad weed-killing spectrum, synergistic effect can be generated and solve resistant weed to ask in production
The Herbicidal combinations kind of topic.
Summary of the invention
To solve the above-mentioned problems in the prior art, the present invention provides a kind of Herbicidal combinations of humulone of sulphur containing triazole
And its application, the composition can effectively prevent and kill off the weed problems such as barnyard grass, rice barnyard grass, semen euphorbiae in crop, have expand degrass spectrum,
Reduce amount of application, to crop safety, synergistic effect can be generated and solve resistant weed the features such as.
A kind of Herbicidal combinations of the humulone of sulphur containing triazole, active components A and active constituent B including herbicidally effective amount,
In, active components A is triazole sulphur humulone, and active constituent B is selected from one of following compound or a variety of: indanofan, piperophos,
Fentrazamide, bromacil, anilofos, 2 first, 4 chlorine sodium salt, prometryn, symetryne, halosulfuronmethyl, molinate, benthiocarb, evil
Azole amide, clefoxidim, mefenacet, benzobicylon, pentoxazone, isoproturon, pyrazosulfuron, furans sulphur grass
Ketone, penoxsuam.
Wherein, active components A and the weight ratio of B are 1:60-60:1, preferably 1:50-50:1 and 1:40-40:1, more preferably
1:30-30:1 and 1:20-20:1, further preferred 1:10-10:1.
Preferably, the weight ratio of A and indanofan is 1:30-12:1
The weight ratio of A and piperophos is 1:40-12:1
The weight ratio of A and fentrazamide is 1:30-12:1
The weight ratio of A and bromacil is 1:30-12:1
The weight ratio of A and anilofos is 1:36-12:1
The weight ratio of 4 chlorine sodium salt of A and 2 first is 1:32-32:1
The weight ratio of A and prometryn is 1:30-6:1
The weight ratio of A and symetryne is 1:12-12:1
The weight ratio of A and halosulfuronmethyl is 1:4-24:1
The weight ratio of A and molinate is 1:24-4:1
The weight ratio of A and benthiocarb is 1:24-1:1
The weight ratio of A and metamifop is 1:12-12:1
The weight ratio of A and clefoxidim is 1:4-20:1
The weight ratio of A and mefenacet is 1:24-2:3
The weight ratio of A and benzobicylon is 1:24-18:1
The weight ratio of A and pentoxazone is 1:24-36:1
The weight ratio of A and isoproturon is 1:36-24:1
The weight ratio of A and pyrazosulfuron is 2:1-16:1
The weight ratio of A and furans sulphur humulone is 1:16-12:1
The weight ratio of A and penoxsuam is 1:8-48:1.
The mass percentage of A, B account for the 1-95% of total amount, preferably 10-80% in the Herbicidal combinations.
The Herbicidal combinations further comprise safener C, and safener C is selected from one of following compound or a variety of:
C1: isoxadifen (CAS:163520-33-0)
C2:cyprosulfamide (No. CAS: 221667-31-8)
C3: mefenpyrdiethyl (No. CAS: 135590-91-9)
C4: cloquintocetmexyl (No. CAS: 99607-70-2)
C5: gibberellic acid (No. CAS: 77-06-5)
C6:furilazole (No. CAS: 121776-33-8)
C7:metcamifen (No. CAS: 129531-12-0).
It include also conven-tional adjuvants in the Herbicidal combinations, the conven-tional adjuvants include carrier, surfactant.
Term " carrier " herein indicates a kind of organic or inorganic, natural or synthetic substance.They facilitate activity
The application of ingredient, the carrier be usually it is inert and must be it is agriculturally acceptable, especially processed plant is received.
Carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer；Or liquid
Body, such as water, alcohols, ketone, petroleum distillate, aromatic hydrocarbons or wax hydrocarbon, chlorohydrocarbon, liquefied gas.
Surfactant may include emulsifier, dispersing agent or wetting agent, it can be ionic or non-ionic.It can mention
And example be the salt of polyacrylic acid, lignosulfonates, phenolsulfonic acid or naphthalene sulfonic acids salt, ethylene oxide and aliphatic alcohol or
Polymer, sulfosuccinic acid with aliphatic acid or with aliphatic amine and fortified phenol (especially alkylphenol or aryl phenol)
Phosphate, the alkyl of the phenol of salt, taurine derivatives (especially taurine alkane rouge) and alcohol phosphate or multi-hydroxy ethyl
Sulfonate, alkylaryl sulfonates, alkyl sulfate, lauryl ether sulfate, aliphatic alcohol sulfate and sulphation 16-,
17-and octadecanol and sulphated fatty alcohol glycol ether, in addition there are the condensations of naphthalene or naphthalene sulfonic acids and phenol and formaldehyde
Object, NONIN HS 240, ethoxylated isooctyl-phenol, octyl phenol or nonyl phenol, alkyl phenyl polyglycol ether, three fourths
Base phenyl polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol, pure and mild fatty alcohol/ethylene oxide contracting
Close object, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylation polyoxypropylene, laruyl alcohol polyglycol ether acetal, sorb
Alcohol ester, lignin sulfite waste liquor and protein, albuminate, polysaccharide (such as methylcellulose), Hydrophobic Modified Starch,
Polyvinyl alcohol, polycarboxylate, poly-alkoxyl compound, polyvinylamine, polyvinylpyrrolidone and its copolymer.At least need one kind
Surfactant exists, to be conducive to active constituent dispersion in water and be conducive to enable them to correctly be applied to plant.
Above-mentioned composition contains various other components, such as protecting colloid, adhesive, thickener, thixotropic agent, infiltration
Agent, stabilizer, chelating agent, dyestuff, colorant and polymer.
Composition of the invention can used before through dilution or directly by user.It, which is prepared, to be added by common
Work method preparation, i.e., after active material being mixed with liquid solvent or solid carrier, add surfactant such as dispersing agent, surely
Determine one or more of agent, wetting agent, adhesive, defoaming agent etc..
The specific preparation of the Herbicidal combinations is dispersible oil-suspending agent, aqueous suspension agent, suspoemulsion, missible oil, water dispersion
Granula (dry suspending agent), aqueous emulsion, microemulsion.
In brief, composition of the invention can be added with conventional use of solid in the formula of the prior art and liquid
Agent mixing.
In addition, the composition of active components A and active constituent B can be mixed with following active material, such as " world pesticide
New varieties technologies is complete works of ", Scientia Agricultura Sinica technology publishing house, 2010.9 and document incorporated herein in known substance.Example
Such as herbicidal activity substance mentioned below, (remarks: the title of compound, or for according to International Organization for standardization (ISO)
Common name, or be chemical name, have code name when appropriate): Acetochlor, butachlor, alachlor, propisochlor, isopropyl
The left-handed naphthalene propionyl grass amine of alachlor, S-metolachlor, pretilachlor, propachlor, kecaoan, naphthalene propionyl grass amine, R-, propanil, benzene
Thiophene acyl grass amine, diphenamide, diflufenican, N-alpha-chloroacetyl-N-isopropyl-o ethylaniline, beflubutamid, bromobutide, dimethenamid, efficient two
First fenacet, ethobenzanid, flufenacet, thenylchlor, metazachlor, isoxaben, flampropMmethyl, efficient wheat
Grass volt propyl ester, allidochlor, pethoxamid, chloranocryl, ring pretilachlor, mefluidide, monalide, delachlor, third
Alkynes grass amine, terbuchlor, xylachlor, dimethachlor, amine of taking to the greenwood, front three ring grass amine, clomeprop, propyzamide,
Valeryl benzene grass amine blocks careless amine, suffer, tricyclic match careless amine, butenachlor, tebutam, benzyl grass amine, quinone duckweed amine, dichlofluanid, naphthalene
Propylamine, acetyl alachlor, quinclorac, fenacet, pyrrole cyanogen grass amine, benzene grass more grams of dead, chlorothiamid, chlorine phthalimides, fourth amidine amine, fluorine pyrrole
Careless amine, atrazine, Simanex, prometryn, cyanatryn, symetryne, ametryn, propazine, dipropetryn, flur, terbutryn, spy
Ding Jin, triaziflam, cyprazine, proglinazine, trietazine, prometon, Gesadrual, nitrine be net, desmetryn, dimethametryn, ring
Third green saliva, green bristlegrass of going out saliva, another Ding Jin, Zhong Dingtong, Te Dingtong, methoxy third be net, cyanatryn, ipazine, chlorazine, atraton, weed eradication
Logical, Radix Glycyrrhizae saliva, cyanuric acid, Indaziflam, green sulphur is grand, metsulfuron-methyl, bensulfuron-methyl, chlorimuron, tribenuron-methyl, thifensulfuron methyl,
Pyrazosulfuron, mesosulfuron, iodosulfuron-methyl-sodium, formamido group Sulfometuron Methyl, cinosulfuron, triasulfuron, sulfometuronmethyl, cigarette
Sulfometuron Methyl, ethametsulfuron, amidosulfuron, ethoxysulfuron, cypromisulfuron, rimsulfuron, azimsulfuron, pyridine ethyl methyl,
Monosulfmeturon, single phonetic sulphur ester, flucarbazone, flupyrsulfuron-methyl-sodium, fluorine pyrazosulfuron, oxasulfuron, imazosulfuron, the phonetic sulphur of fluorine
Grand, procarbazone, prosulfuron, Sulfosulfuron, trifloxysulfuron, triflusulfuronmethyl, tritosulfuron, metsulfuron-methyl sodium salt, fluorine
Pyrrole sulphur is grand, Sulfonylurea, orthosulfamuron, Propyrisulfuron (proxazuron-methyl), piperazine pyrazosulfuron, trifluoro carboxylic grass
Ether, fomesafen, lactofen, fluoroglycofen-ethyl, Oxyfluorfen, Mo 9 granular, aclonifen, ethoxyfen-ethyl, first
Carboxylic nitrofen, fluoroform grass ether, chlomethoxyfen, fluorodifen, fluorination nitrofen, fluorine furan grass ether, nitrofen, first grass ether,
Diformazan grass ether, fluorine lactazone grass ether, fluofazone ester, Halosafen, chlortoluron, isoproturon, linuron, diuron, Sha flutter grand, fluorine
Careless grand, benzthiazuron, methabenzthiazuron, cumyluron, ethidimuron, isouron, terbufos benzthiazuron, buturon, bromax, methyl herbicide
Grand, phenobenzuron, methoxy daimuron, metobromuron, metoxuron, afesin, telvar, Tupersan, fenuron, fluorine sulphur is grand, neburea,
Chloroxifenidium, herban, isonoruron, Alipur-O, thiazfluron, tebuthiuron, difenoxuron, to fluon, methylamine methabenz thiazuron, Long Caote,
Front three isourea, dimefuron, Monisouron, Anisuron, Methiuron, Chloreturon, four fluon, phenmedipham, beet
The careless spirit of rather-ethyl ester, desmedipham, sulphur, terbucarb, oatax, Chem hoe, chlorpropham, benzyl dichloride grass ester, swep, chlorbufam,
Carboxazole, Chlorprocarb, Fenasulam, BCPC, CPPC, Carbasulam, Ding Caote, benthiocarb, vernolate,
Molinate, tri-allate, dimepiperate, esprocarb, pyributicarb, cycloate, Avadex, bactericide, second sulphur careless spy, orbencarb, gram grass
Suddenly, prosulfocarb, tiocarbazil, sulfuric acid, dimexan, Isopolinate, Methiobencarb, 2,4- d butyl ester, 2 first, 4 chlorine
Sodium, the different monooctyl ester of 2,4- drop, the different monooctyl ester of 2 first, 4 chlorine, 2,4- drop sodium salt, 2,4- drop dimethylamine salt, 2 first, 4 chloroethene thioesters, 2 first, 4 chlorine, 2,
4- drop propionic acid, high 2,4- drop propionate, 2,4- Embutox, Vi par, Vi par salt, Thistrol, 2,4,5-
Tears, 2,4,5- tears propionic acid, 2,4,5- tears butyric acid, 2 first, 4 chloramines salt, dicamba, erbon, Fenac, match pine, trichlorobenzoic acid, ammonia
Dichloro benzoic acid, methoxy trichlorobenzoic acid, diclofop-methyl, fluazifop, efficient fluazifop, haloxyfop-P-methyl, efficient pyrrole fluorine chlorine standing grain
Spirit, quizalofop-ethyl, Quizalotop-ethyl, fenoxaprop-P, fenoxapropPethyl, propaquizafop, cyhalofop-butyl, metamifop, clodinafop-propargyl,
Diclofop-methyl thiazole, chloroazifoppropynyl, the spirit of penta standing grain of hydroxyl, trifluoro dogstail oxime, isoxapyrifop, paraquat, diquat dibromide, oryzalin, second butylene fluorine
Spirit, isopropalin, nitralin, profluralin, prodiamine, benfluralin, fluchloraline, the spirit of amino second fluorine, dipropalin,
Chloroethene dipropalin, Methalpropalin, the third nitre phenol, glyphosate, Sha barnyard grass phosphine, glufosinate-ammonium, amiprophos-methyl, sulphosate, piperazine grass
Phosphine, bensulide, butamifos, creeping weed phosphorus, cuts down ridge phosphorus, double first amiprophos, dow crabgrass killer, imazapyr, imidazoles second cigarette at bialaphos
Acid, imazaquin, imazamox, imazamox ammonium salt, AC 263222, miaow grass ester, fluroxypyr, chlorine fluorine pyrrole
The different monooctyl ester of fluoroacetic acid, clopyralid, picloram, trichlopyr, dithiopyr, halogen grass be fixed, phenolate trichloropyridine, thiophene
Careless pyridine, fluridone, chlorine Fampridine acid, diflufenzopyr, triclopyr butoxyethyl ester, Cliodinate, sethoxydim, alkene
Humulone, cycloxydim, alloxydimsodium, clefoxidim, butroxydim, tralkoxydim, tepraloxydim, Buthidazole, metribuzin, ring piperazine
Ketone, metamitron, ethiozin, Ametridione, Amibuzin, Brominal, bromoxynil octanoate, ioxynil octanoate, iodobenzene
Nitrile, dichlobenil, diphenatril, pyraclonil, chloroxynil, Iodobonil, Flumetsulam, florasulam, penoxsulam
Amine, metosulam, cloransulammethyl, diclosulam, pyroxsulam, fluorine straw colour, bispyribac-sodium, pyribenzoxim, pyriftalid,
KIH 6127, pyrithiobacsodium, benzobicylon, mesotrione, sulphur humulone, Tembotrione, Tefuryltrione,
It is Bicyclopyrone, Ketodpiradox, isoxaflutole, isoxachlorotole, Fenoxasulfone, Methiozolin, different
Third pyrrole grass ester, pyraflufen-ethyl, pyrazolate, difenzoquat, pyrazoxyfen, benzofenap, pyrrole chlorine grass amine, Pyrasulfotole, topramezone,
Pyroxasulfone, cafenstrole, flupoxam, Amrol, amicarbazone, azafenidin, profluazone, sulfentrazone,
Bencarbazone, benzfendizone, butafenacil, bromacil, isoprocil, lenacil, terbacil, Flupropacil, Yin
Diindyl ketone grass ester, Flumiclorac pentyl, flumioxazin, alkynes grass amine, phthalein benzyl oxide, Flumezin, pentachlorophenol (sodium), dinoseb, dinoterb,
Dinoterb acetate, dinosam, Chemox PE, chlorine nitre phenol, medinoterb acetate, Di Lete, oxadiargyl, oxadiazon, pentoxazone, fluorine azoles grass
Amine, fluthiacet, fentrazamide, flufenpyrethyl, pyrazon, brompyrazon, diformazan reach careless volt, Kusakira, careless pyridazone, grass
It rattles away pine, norflurazon, Pyridafol, dichloro quinolinic acid, quinmerac, Bentazon, pyridate, oxaziclomefone, benazolin, different
Oxadiazon, cinmethylin, iso-propyl-ester nitrofen, propyl-ester nitorfen, indanofan, sodium chlorate, Dalapon, trichloroacetic acid, monochloroacetic acid, six
Chlroacetone, tetrafluoro propionic acid, herbage are fast, bromofenoxim, triazole sulphur, kill azoles, flurtamone, benfuresate, ethofumesate, phonetic careless amine, chlorine
Phthalandione, fluorochloridone, barnyard grass, methacrylaldehyde, bentranil, tridiphane, Bidisin, thiadiazoles grass amine, phenisopham, hydroxyl humulone, first
Oxybenzone, benzene flumetsulam, chlorine acyl grass phosphine, chloropon, Alorac, Diethamquat, Etnipromid, Iprymidam,
Ipfencarbazone、Thiencarbazone-methyl、Pyrimisulfan、Chlorflurazole、
Tripropindan, Sulglycapin, first sulphur nitralin, Cambendichlor, cyclopropyl pyrimidine acid, rodethanii, benoxacor,
Fenclorim, fenchlorazole, solves careless quinoline, oxabetrinil, oxalane, cyometrinil, desorpenic, mefenpyrdiethyl, furans solution grass at flurazole
Azoles, fluxofenim, isoxadifen, allyl dichloride amine, fluorine chloropyridine ester, DOW chlorine fluorine pyridine ester, UBH-509, D489, LS 82-
556、KPP-300、NC-324、NC-330、KH-218、DPX-N8189、SC-0744、DOWCO535、DK-8910、V-53482、
PP-600, MBH-001, KIH-9201, ET-751, KIH-6127 and KIH-2023.
Composition of the invention can be applied on plant leaf blade to be processed by spraying method, that is, be applied to weeds,
It is especially invaded and harassed on the harmful weed infestation of plant growth or easily on the surface of influence.
When applying Herbicidal combinations of the invention, unexpected synergistic effect is obtained, and activity of weeding ratio makes
It is individually active more significant with the expected summation of the activity of single herbicide, and single herbicide.Synergistic effect shows as applying
Measure reductions, broader weeds distribution spectrum, herbicide effect faster, it is more longlasting, these characteristics are required in Weeds distribution practice process
It wants.For described characteristic, these new compositions are significantly superior to existing herbicide.
Herbicidal combinations of the invention also have advantages in that
(1) composition of the invention is environmentally friendly, is easy to degrade in the environment, very safe to crop.
(2) Herbicidal combinations of the invention are at low cost, easy to use, and popularization and application have huge economic benefit and society
Benefit.
(3) compared with prior art, Herbicidal combinations of the present invention can prevent and kill off non-resistance gramineae weed and prevent
Except generating the barnyard grass of resistance, difformed galingale herb to ALS inhibitor and generate the grass family such as the semen euphorbiae of resistance to ACCase inhibitor
Weeds are the effective schemes of paddy field weed resistance management.
Specific embodiment
The following example not limits the present invention, and is used only to illustrate how the present invention realizes.For certain miscellaneous
Grass, these embodiments show especially significant validity.It is exemplified below:
(A), embodiment
A+ symetryne
1) aqueous suspension agent formula composition are as follows:
+ 3% fatty alcohol polyoxy second of+4% polycarboxylic acid salt dispersing agent+3%EO-PO block polyether of 12%A+7% symetryne
+ 1.5%+5% glycerine of aluminium-magnesium silicate of+0.2% xanthan gum of alkene ether+water is supplied.
2) oil-suspending agent formula composition can be dispersed are as follows:
+ 5% castor oil polyoxy of+7% aliphatic acid polyethenoxy ether of+6% calcium dodecyl benzene sulfonate of 15%A+5% symetryne
+ 1.0% fumed silica+10%150# solvent naphtha of+1.5% organobentonite of vinethene+methyl oleate is supplied.
3) wettable powder formula composition are as follows:
+ 6%+10% precipitated silica of pull open powder of+8% naphthalenesulfonate dispersing agent of 21%A+9% symetryne+diatomite
Supply A+ halosulfuronmethyl
4) aqueous suspension agent formula composition are as follows:
+ 4%+3% fatty alcohol polyoxyethylene ether of polycarboxylic acid salt's dispersing agent of 18%A+3% halosulfuronmethyl+0.25% is yellow
+ 1.5%+5% glycerine of aluminium-magnesium silicate of virgin rubber+water is supplied.
5) oil-suspending agent formula composition can be dispersed are as follows:
+ 5% castor oil of+7% aliphatic acid polyethenoxy ether of+6% calcium dodecyl benzene sulfonate of 12%A+2% halosulfuronmethyl
+ 2.5% fumed silica+5%150# solvent naphtha of+2.5% organobentonite of polyoxyethylene ether+methyl oleate is supplied.
6) wettable powder formula composition are as follows:
+ 10% precipitated silica of+6% pull open powder of+10% naphthalenesulfonate dispersing agent of 30%A+5% halosulfuronmethyl+
Diatomite is supplied
7) water dispersible granules formula composition are as follows:
+ 1% disintegrating agent of+3% lauryl sodium sulfate of+10% polycarboxylic acid salt's dispersing agent of 42%A+7% halosulfuronmethyl
+ 5% precipitated silica of polyvinyl alcohol+filler diatomite is supplied.
A+ anilofos
8) emulsifiable concentrate formulation forms are as follows:
+ 7% nonylphenol polyoxyethylene ether of+7% calcium dodecyl benzene sulfonate of+20% cyclohexanone of 4%A+12% anilofos+
150# aromatic solvent naphtha is supplied
9) micro-emulsion formulation forms are as follows:
+ 8% benzene second of+8% maleic di-sec-octyl sodium sulfonate of+10% isooctanol of+20% cyclopentanone of 3%A+9% anilofos
+ 3% phenethyl phenol polyethenoxy ether formaldehyde resin condensation product of base phenol polyethenoxy ether+water is supplied
10) water emulsion formula forms are as follows:
+ 3% phenethyl phenol polyethenoxy ether phosphate of+25% cyclohexanone+15%200# solvent naphtha of 5%A+15% anilofos
+ 0.2%+3% ethylene glycol of xanthan gum of+3% castor oil polyoxyethylene ether of+4% phenethyl phenol polyethenoxy ether of triethanolamine salt+water
It supplies
11) oil-suspending agent formula composition can be dispersed are as follows:
+ 4% castor oil polyoxy of+8% nonylphenol polyoxyethylene ether of+6% calcium dodecyl benzene sulfonate of 6%A+18% anilofos
+ 2.5% organobentonite+10%200# solvent naphtha of vinethene+methyl oleate is supplied.
12) wettable powder formula composition are as follows:
+ 5%+35% precipitated silica of pull open powder of+10% naphthalenesulfonate dispersing agent of 2%A+3% anilofos+diatomite
It supplies
13) water dispersible granules formula composition are as follows:
+ 1% disintegrating agent of+4% lauryl sodium sulfate of+15% polycarboxylic acid salt's dispersing agent of 4.5%A+13.5% anilofos
+ 30% precipitated silica of polyvinyl alcohol+filler calcined kaolin is supplied.
A+ molinate
14) emulsifiable concentrate formulation forms are as follows:
+ 7% polyoxyethylene nonyl phenyl of+5% calcium dodecyl benzene sulfonate of 2%A+24% molinate+20%N- methyl pyrrolidone
Vinethene+150# aromatic solvent naphtha is supplied
15) micro-emulsion formulation forms are as follows:
+ 8% maleic di-sec-octyl sodium sulfonate of+20% cyclopentanone+10%100# solvent naphtha of 1.5%A+18% molinate+
+ 3% phenethyl phenol polyethenoxy ether formaldehyde resin condensation product of 8% phenethyl phenol polyethenoxy ether+water is supplied
16) water emulsion formula forms are as follows:
+ 3% phenethyl phenol polyethenoxy ether phosphate of+20% cyclohexanone+15%200# solvent naphtha of 9%A+12% molinate
+ 0.2%+3% ethylene glycol of xanthan gum of+3% castor oil polyoxyethylene ether of+4% phenethyl phenol polyethenoxy ether of triethanolamine salt+water
It supplies
17) oil-suspending agent formula composition can be dispersed are as follows:
+ 4% castor oil polyoxy of+8% nonylphenol polyoxyethylene ether of+7% calcium dodecyl benzene sulfonate of 4%A+24% molinate
+ 2% organobentonite+10%200# solvent naphtha of vinethene+methyl oleate is supplied.
18) wettable powder formula composition are as follows:
+ 5%+35% precipitated silica of pull open powder of+10% naphthalenesulfonate dispersing agent of 10%A+24% molinate+calcining
Kaolin is supplied
19) water dispersible granules formula composition are as follows:
+ 1% disintegrating agent of+4% lauryl sodium sulfate of+10% polycarboxylic acid salt's dispersing agent of 7.5%A+30% molinate is poly-
+ 30% precipitated silica of vinyl alcohol+calcined kaolin is supplied.
A+ benthiocarb
20) emulsifiable concentrate formulation forms are as follows:
+ 8% nonylphenol polyoxyethylene ether of+5% calcium dodecyl benzene sulfonate of+20% cyclopentanone of 3%A+24% benthiocarb+
200# aromatic solvent naphtha is supplied
21) micro-emulsion formulation forms are as follows:
+ 8% maleic di-sec-octyl sodium sulfonate of+25% cyclopentanone+10%100# solvent naphtha of 1.5%A+18% benthiocarb+
+ 2% phenethyl phenol polyethenoxy ether formaldehyde resin condensation product of 8% phenethyl phenol polyethenoxy ether+water is supplied
22) oil-suspending agent formula composition can be dispersed are as follows:
+ 2% castor oil polyoxy of+8% nonylphenol polyoxyethylene ether of+7% calcium dodecyl benzene sulfonate of 6%A+24% benthiocarb
+ 1.5% organobentonite+10%200# solvent naphtha of vinethene+methyl oleate is supplied.
23) wettable powder formula composition are as follows:
+ 6%+30% precipitated silica of pull open powder of+10% naphthalenesulfonate dispersing agent of 8%A+24% benthiocarb+calcining
Kaolin is supplied
24) water dispersible granules formula composition are as follows:
+ 1% poly- second of disintegrating agent of+4% lauryl sodium sulfate of+10% polycarboxylic acid salt's dispersing agent of 9%A+30% benthiocarb
+ 30% precipitated silica of enol+diatomite is supplied.
A+ metamifop
25) emulsifiable concentrate formulation forms are as follows:
+ 7% nonylphenol polyoxyethylene ether of+7% calcium dodecyl benzene sulfonate of+15% cyclohexanone of 3%A+4% metamifop
+ 100# aromatic solvent naphtha is supplied
26) micro-emulsion formulation forms are as follows:
+ 8% maleic di-sec-octyl sodium sulfonate of+10% isooctanol of+10% cyclopentanone of 1.5%A+2% metamifop+
+ 2% phenethyl phenol polyethenoxy ether formaldehyde resin condensation product of 8% phenethyl phenol polyethenoxy ether+water is supplied
27) water emulsion formula forms are as follows:
+ 3% phenethyl phenol polyethenoxy ether phosphorus of+20% cyclohexanone+15%200# solvent naphtha of 3%A+4% metamifop
+ 3% second two of+0.2% xanthan gum of acid esters triethanolamine salt+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether
Alcohol+water supplies dispersible oil-suspending agent formula composition are as follows:
28)+3% castor of+8% nonylphenol polyoxyethylene ether of+6% calcium dodecyl benzene sulfonate of 9%A+12% metamifop
+ 2% organobentonite+10%200# solvent naphtha of sesame oil polyoxyethylene ether+methyl oleate is supplied.
29)+4% lauryl sodium sulfate+1% of+12% polycarboxylic acid salt's dispersing agent of 15%A+20% metamifop collapses
Solution+30% precipitated silica of agent polyvinyl alcohol+filler calcined kaolin is supplied.
A+ clefoxidim
30) emulsifiable concentrate formulation forms are as follows:
+ 5% nonylphenol polyoxyethylene ether of+5% calcium dodecyl benzene sulfonate of+20% cyclohexanone of 5%A+1% clefoxidim+
150# aromatic solvent naphtha is supplied
31) micro-emulsion formulation forms are as follows:
+ 8% maleic di-sec-octyl sodium sulfonate+8% of+10% isooctanol of+25% cyclopentanone of 4%A+0.8% clefoxidim
+ 2% phenethyl phenol polyethenoxy ether formaldehyde resin condensation product of phenethyl phenol polyethenoxy ether+water is supplied
32) water emulsion formula forms are as follows:
+ 3% phenethyl phenol polyethenoxy ether phosphoric acid of+25% cyclohexanone+15%100# solvent naphtha of 5%A+1% clefoxidim
+ 3% ethylene glycol of+0.2% xanthan gum of ester triethanolamine salt+3% castor oil polyoxyethylene ether of+3% phenethyl phenol polyethenoxy ether+
Water is supplied
32) oil-suspending agent formula composition can be dispersed are as follows:
+ 4% castor oil of+7% nonylphenol polyoxyethylene ether of+6% calcium dodecyl benzene sulfonate of 15%A+3% clefoxidim is poly-
+ 2.5% organobentonite+5%200# solvent naphtha of ethylene oxide ether+methyl oleate is supplied.
33) water dispersible granules formula composition are as follows:
+ 1% disintegrating agent of+4% lauryl sodium sulfate of+15% polycarboxylic acid salt's dispersing agent of 40%A+10% clefoxidim is poly-
+ 10% precipitated silica of vinyl alcohol+filler calcined kaolin is supplied.
A+ mefenacet
35) emulsifiable concentrate formulation forms are as follows:
+ 7% phenethyl phenol polyoxy second of+7% calcium dodecyl benzene sulfonate of+20% cyclohexanone of 2%A+12% mefenacet
Alkene ether+100# aromatic solvent naphtha is supplied
36) water emulsion formula forms are as follows:
+ 3% phenethyl phenol polyethenoxy ether phosphorus of+25% cyclohexanone+15%200# solvent naphtha of 3%A+12% mefenacet
+ 3% second two of+0.2% xanthan gum of acid esters triethanolamine salt+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether
Alcohol+water is supplied
37) aqueous suspension agent formula composition are as follows:
+ 0.2% xanthan of+3% fatty alcohol polyoxyethylene ether of+4% polycarboxylic acid salt's dispersing agent of 2%A+24% mefenacet
+ 1.5%+5% glycerine of aluminium-magnesium silicate of glue+water is supplied.
38) wettable powder formula composition are as follows:
+ 15% precipitated silica of+5% pull open powder of+10% naphthalenesulfonate dispersing agent of 2%A+24% mefenacet+
Diatomite is supplied
39) water dispersible granules formula composition are as follows:
The disintegration of+5% lauryl sodium sulfate+1% of+11% polycarboxylic acid salt's dispersing agent of 2.5%A+30% mefenacet
+ 10% precipitated silica of agent polyvinyl alcohol+filler calcined kaolin is supplied.
4 chlorine sodium salt of A+2 first
40) micro-emulsion formulation forms are as follows:
+ 8% benzene second of+8% maleic di-sec-octyl sodium sulfonate of 4%A+2%2 first+10% ethyl alcohol of+20% cyclopentanone of 4 chlorine sodium
+ 2% phenethyl phenol polyethenoxy ether formaldehyde resin condensation product of base phenol polyethenoxy ether+water is supplied
41) aqueous suspension agent formula composition are as follows:
+ 0.25% xanthan of+3% fatty alcohol polyoxyethylene ether of 10%A+5%2 first+4% polycarboxylic acid salt's dispersing agent of 4 chlorine sodium
+ 2.5%+5% glycerine of aluminium-magnesium silicate of glue+water is supplied.
42) oil-suspending agent formula composition can be dispersed are as follows:
+ 4% castor oil of+8% nonylphenol polyoxyethylene ether of 12%A+6%2 first+3% calcium dodecyl benzene sulfonate of 4 chlorine sodium is poly-
+ 2% organobentonite+10%200# solvent naphtha of ethylene oxide ether+methyl oleate is supplied.
43) wettable powder formula composition are as follows:
+ 5%+10% precipitated silica of pull open powder of+10% naphthalenesulfonate dispersing agent of 4 chlorine sodium of 20%A+10%2 first+silicon
Diatomaceous earth is supplied
44) water dispersible granules formula composition are as follows:
+ 1% disintegrating agent of+4% lauryl sodium sulfate of 30%A+10%2 first+12% polycarboxylic acid salt's dispersing agent of 4 chlorine sodium is poly-
+ 10% precipitated silica of vinyl alcohol+filler calcined kaolin is supplied.
A+ benzobicylon
45) aqueous suspension agent formula composition are as follows:
+ 2% poly alkyl alcohol of+3% polycarboxylic acid salt dispersing agent+1%EO-PO block polyether of 10%A+30% benzobicylon
+ 1.5%+5% glycerine of aluminium-magnesium silicate of+0.12% xanthan gum of ethylene oxide ether+water is supplied.
Dispersible oil-suspending agent formula composition are as follows:
46)+5% castor of+7% aliphatic acid polyethenoxy ether of+5% calcium dodecyl benzene sulfonate of 5%A+15% benzobicylon
+ 2% fumed silica+10%150# solvent naphtha of+2% organobentonite of sesame oil polyoxyethylene ether+methyl oleate is supplied.
47)+1% poly- second of disintegrating agent of+5% pull open powder of+10% polycarboxylic acid salt's dispersing agent of 10%A+30% benzobicylon
+ 5% precipitated silica of enol+calcined kaolin is supplied.
A+ pentoxazone
48) emulsifiable concentrate formulation forms are as follows:
+ 7% nonylphenol polyoxyethylene ether of+5% calcium dodecyl benzene sulfonate of+20% cyclohexanone of 2%A+4% pentoxazone
+ 100# aromatic solvent naphtha is supplied
49) aqueous suspension agent formula composition are as follows:
+ 4%+2% fatty alcohol polyoxyethylene ether of polycarboxylic acid salt's dispersing agent of 10%A+20% pentoxazone+0.2% is yellow
+ 1.5%+5% glycerine of aluminium-magnesium silicate of virgin rubber+water is supplied.
50) oil-suspending agent formula composition can be dispersed are as follows:
+ 3% castor oil of+8% nonylphenol polyoxyethylene ether of+6% calcium dodecyl benzene sulfonate of 6%A+12% pentoxazone
+ 2.5% organobentonite+10%200# solvent naphtha of polyoxyethylene ether+methyl oleate is supplied.
51) wettable powder formula composition are as follows:
+ 15% precipitated silica of+5% pull open powder of+10% naphthalenesulfonate dispersing agent of 18%A+36% pentoxazone+
Diatomite is supplied
52) water dispersible granules formula composition are as follows:
+ 1% disintegrating agent of+4% lauryl sodium sulfate of+10% polycarboxylic acid salt's dispersing agent of 20%A+40% pentoxazone
+ 10% precipitated silica of polyethylene glycol+filler calcined kaolin is supplied.
A+ isoproturon
53) aqueous suspension agent formula composition are as follows:
+ 0.2% xanthan gum of+1.5% fatty alcohol polyoxyethylene ether of+4% polycarboxylic acid salt's dispersing agent of 10%A+5% isoproturon
+ 2%+5% glycerine of aluminium-magnesium silicate+water is supplied.
54) oil-suspending agent formula composition can be dispersed are as follows:
+ 3% castor oil polyoxy of+7% nonylphenol polyoxyethylene ether of+4% calcium dodecyl benzene sulfonate of 5%A+3% isoproturon
+ 2% fumed silica+8%150# solvent naphtha of+2% organobentonite of vinethene+methyl oleate is supplied.
55) wettable powder formula composition are as follows:
+ 4%+10% precipitated silica of pull open powder of+8% sodium lignin sulfonate dispersing agent of 15%A+10% isoproturon+silicon
Diatomaceous earth is supplied
56) water dispersible granules formula composition are as follows:
+ 1% disintegrating agent polyvinyl alcohol of+6% pull open powder of+10% polycarboxylic acid salt's dispersing agent of 10%A+20% isoproturon+
15% precipitated silica+filler calcined kaolin is supplied.
A+ pyrazosulfuron
57) aqueous suspension agent formula composition are as follows:
+ 2% fatty alcohol polyoxy of+4% polycarboxylic acid salt dispersing agent+2%EO-PO block polyether of 24%A+3% pyrazosulfuron
+ 1.5%+5% glycerine of aluminium-magnesium silicate of+0.2% xanthan gum of vinethene+water is supplied.
58) oil-suspending agent formula composition can be dispersed are as follows:
+ 5% castor oil of+7% aliphatic acid polyethenoxy ether of+5% calcium dodecyl benzene sulfonate of 16%A+2% pyrazosulfuron is poly-
+ 2% fumed silica+10%150# solvent naphtha of+2% organobentonite of ethylene oxide ether+methyl oleate is supplied.
59) wettable powder formula composition are as follows:
+ 5%+10% precipitated silica of pull open powder of+10% naphthalenesulfonate dispersing agent of 32%A+4% pyrazosulfuron+silicon
Diatomaceous earth supplies 60) water dispersible granules formula composition are as follows:
+ 1% disintegrating agent polyvinyl alcohol of+6% pull open powder of+12% polycarboxylic acid salt's dispersing agent of 32%A+4% pyrazosulfuron+
5% precipitated silica+filler diatomite is supplied.
A+ furans sulphur humulone
61) aqueous suspension agent formula composition are as follows:
+ 2% poly alkyl alcohol of+4% polycarboxylic acid salt dispersing agent+1%EO-PO block polyether of 15%A+10% furans sulphur humulone
+ 2%+5% glycerine of aluminium-magnesium silicate of+0.2% xanthan gum of ethylene oxide ether+water is supplied.
62) oil-suspending agent formula composition can be dispersed are as follows:
+ 5% castor oil of+7% aliphatic acid polyethenoxy ether of 9%A+6% furans sulphur+4% calcium dodecyl benzene sulfonate of humulone
+ 2% fumed silica+10%150# solvent naphtha of+2% organobentonite of polyoxyethylene ether+methyl oleate is supplied.
63) wettable powder formula composition are as follows:
+ 10% precipitation method of+6% lauryl sodium sulfate of 27%A+3% furans sulphur+8% naphthalenesulfonate dispersing agent of humulone
White carbon black+diatomite is supplied
64) water dispersible granules formula composition are as follows:
+ 1% disintegrating agent polyvinyl alcohol of+6% pull open powder of 24%A+4% furans sulphur+10% polycarboxylic acid salt's dispersing agent of humulone+
5% precipitated silica+filler diatomite is supplied.
A+ penoxsuam
65) aqueous suspension agent formula composition are as follows:
+ 2% poly alkyl alcohol of+4% polycarboxylic acid salt dispersing agent+1%EO-PO block polyether of 20%A+2% penoxsuam
+ 2%+5% glycerine of aluminium-magnesium silicate of+0.2% xanthan gum of ethylene oxide ether+water is supplied.
66) oil-suspending agent formula composition can be dispersed are as follows:
+ 5% castor oil of+7% aliphatic acid polyethenoxy ether of+4% calcium dodecyl benzene sulfonate of 15%A+2% penoxsuam
+ 2.5% fumed silica+10%150# solvent naphtha of+2.5% organobentonite of polyoxyethylene ether+methyl oleate is supplied.
67) wettable powder formula composition are as follows:
+ 6%+10% precipitated silica of pull open powder of+8% naphthalenesulfonate dispersing agent of 24%A+3% penoxsuam+silicon
Diatomaceous earth is supplied
68) water dispersible granules formula composition are as follows:
+ 1% disintegrating agent polyethylene of+6% pull open powder of+12% polycarboxylic acid salt's dispersing agent of 30%A+2.5% penoxsuam
+ 5% precipitated silica of alcohol+filler calcined kaolin is supplied.
A+ prometryn
69) aqueous suspension agent formula composition are as follows:
+ 3% fatty alcohol polyoxy second of+4% polycarboxylic acid salt dispersing agent+3%EO-PO block polyether of 10%A+7% prometryn
+ 1.5%+5% glycerine of aluminium-magnesium silicate of+0.2% xanthan gum of alkene ether+water is supplied.
70) oil-suspending agent formula composition can be dispersed are as follows:
+ 5% castor oil polyoxy of+7% aliphatic acid polyethenoxy ether of+6% calcium dodecyl benzene sulfonate of 6%A+5% prometryn
+ 1.0% fumed silica+10%150# solvent naphtha of+1.5% organobentonite of vinethene+methyl oleate is supplied.
71) wettable powder formula composition are as follows:
+ 6%+10% precipitated silica of pull open powder of+8% naphthalenesulfonate dispersing agent of 12%A+9% prometryn+diatomite
Supply A+ piperophos
72) emulsifiable concentrate formulation forms are as follows:
+ 7% nonylphenol polyoxyethylene ether of+7% calcium dodecyl benzene sulfonate of+20% cyclohexanone of 3%A+12% piperophos+
150# aromatic solvent naphtha is supplied
73) micro-emulsion formulation forms are as follows:
+ 8% benzene second of+8% maleic di-sec-octyl sodium sulfonate of+10% isooctanol of+20% cyclopentanone of 3%A+15% piperophos
+ 3% phenethyl phenol polyethenoxy ether formaldehyde resin condensation product of base phenol polyethenoxy ether+water is supplied
74) water emulsion formula forms are as follows:
+ 3% phenethyl phenol polyethenoxy ether phosphate of+25% cyclohexanone+15%200# solvent naphtha of 5%A+15% piperophos
+ 0.2%+3% ethylene glycol of xanthan gum of+3% castor oil polyoxyethylene ether of+4% phenethyl phenol polyethenoxy ether of triethanolamine salt+water
It supplies
75) oil-suspending agent formula composition can be dispersed are as follows:
+ 4% castor oil polyoxy of+8% nonylphenol polyoxyethylene ether of+6% calcium dodecyl benzene sulfonate of 6%A+24% piperophos
+ 2.5% organobentonite+10%200# solvent naphtha of vinethene+methyl oleate is supplied.
76) wettable powder formula composition are as follows:
+ 5%+35% precipitated silica of pull open powder of+10% naphthalenesulfonate dispersing agent of 2%A+6% piperophos+diatomite
It supplies
77) water dispersible granules formula composition are as follows:
+ 1% disintegrating agent of+4% lauryl sodium sulfate of+15% polycarboxylic acid salt's dispersing agent of 4.5%A+13.5% piperophos
+ 30% precipitated silica of polyvinyl alcohol+filler calcined kaolin is supplied.
A+ fentrazamide
78) emulsifiable concentrate formulation forms are as follows:
+ 7% phenethyl phenol polyoxy second of+7% calcium dodecyl benzene sulfonate of+20% cyclohexanone of 6%A+12% fentrazamide
Alkene ether+100# aromatic solvent naphtha is supplied
79) aqueous suspension agent formula composition are as follows:
+ 0.2% xanthan of+3% fatty alcohol polyoxyethylene ether of+4% polycarboxylic acid salt's dispersing agent of 4%A+16% fentrazamide
+ 1.5%+5% glycerine of aluminium-magnesium silicate of glue+water is supplied.
80) wettable powder formula composition are as follows:
+ 15% precipitated silica of+5% pull open powder of+10% naphthalenesulfonate dispersing agent of 5%A+12% fentrazamide+
Diatomite is supplied
81) water dispersible granules formula composition are as follows:
+ 1% disintegrating agent of+5% lauryl sodium sulfate of+11% polycarboxylic acid salt's dispersing agent of 12%A+12% fentrazamide
+ 10% precipitated silica of polyvinyl alcohol+filler calcined kaolin is supplied.
A+ bromacil
82) aqueous suspension agent formula composition are as follows:
+ 0.2% xanthan gum of+1.5% fatty alcohol polyoxyethylene ether of+4% polycarboxylic acid salt's dispersing agent of 10%A+8% bromacil
+ 2%+5% glycerine of aluminium-magnesium silicate+water is supplied.
83) oil-suspending agent formula composition can be dispersed are as follows:
+ 3% castor oil polyoxy of+7% nonylphenol polyoxyethylene ether of+4% calcium dodecyl benzene sulfonate of 5%A+10% bromacil
+ 2% fumed silica+8%150# solvent naphtha of+2% organobentonite of vinethene+methyl oleate is supplied.
84) wettable powder formula composition are as follows:
+ 4%+10% precipitated silica of pull open powder of+8% sodium lignin sulfonate dispersing agent of 15%A+10% bromacil+silicon
Diatomaceous earth is supplied
85) water dispersible granules formula composition are as follows:
+ 1% disintegrating agent polyvinyl alcohol of+6% pull open powder of+10% polycarboxylic acid salt's dispersing agent of 10%A+20% bromacil+
15% precipitated silica+filler calcined kaolin is supplied.
A+ indanofan
86) emulsifiable concentrate formulation forms are as follows:
+ 7% nonylphenol polyoxyethylene ether of+5% calcium dodecyl benzene sulfonate of+20% cyclohexanone of 6%A+4% indanofan+
100# aromatic solvent naphtha is supplied
87) aqueous suspension agent formula composition are as follows:
+ 0.2% xanthan gum of+2% fatty alcohol polyoxyethylene ether of+4% polycarboxylic acid salt's dispersing agent of 10%A+5% indanofan+
1.5%+5% glycerine of aluminium-magnesium silicate+water is supplied.
88) oil-suspending agent formula composition can be dispersed are as follows:
+ 3% castor oil polyoxy of+8% nonylphenol polyoxyethylene ether of+6% calcium dodecyl benzene sulfonate of 6%A+12% indanofan
+ 2.5% organobentonite+10%200# solvent naphtha of vinethene+methyl oleate is supplied.
89) wettable powder formula composition are as follows:
+ 5%+15% precipitated silica of pull open powder of+10% naphthalenesulfonate dispersing agent of 18%A+20% indanofan+diatom
Soil supplies 90) water dispersible granules formula composition are as follows:
+ 1% poly- second of disintegrating agent of+4% lauryl sodium sulfate of+10% polycarboxylic acid salt's dispersing agent of 20%A+10% indanofan
+ 10% precipitated silica of glycol+filler calcined kaolin is supplied.
(B), pharmacodynamic test
Cauline leaf spraying treatment after seedling:
1) experimental condition
1.1), for trying target
Barnyard grass (Echinochloa crusgalli) picks up from Hunan Hanshou county paddy field, semen euphorbiae (Leptochloa
Chinensis Jiashan of Zhejiang) is picked up from, difformed galingale herb (Cyperus difformis) picks up from Hubei Jing Zhou, angustifolia arrowhead herb
(Sagittaria trifolia L.), rice barnyard grass (Echinochloa phyllopogon (stapf) Koss.) pick up from Liao Ningying
Mouthful, above-mentioned weeds are placed in enamel tray using pot-culture method culture with 180 х 140mm plastic nutrition bowls, built-in to adopt from farmland
The topsoil (at 4/5) for air-drying sieving is backed through, soil moisture initial stage controls 20%, selects the uniform weeds of full seed
Seed is impregnated 6 hours with 25 DEG C of warm water, and the vernalization in 28 DEG C of biochemical cultivation cases (dark) is equal by the weed seed just to have showed money or valuables one carries unintentionally
It is even to be placed in soil surface, according to seed particle size size and then earthing 0.5-1cm.
1.2), condition of culture
It is carried out in controllable heliogreenhouse, 20~30 DEG C of temperature, natural lighting, relative humidity 57%~72%.
Soil types is loam, the content of organic matter 1.63%, pH=7.1, alkali-hydrolyzable nitrogen 84.3mg/kg, rapid available phosphorus
38.5mg/kg, available potassium 82.1mg/kg.
1.3), instrument and equipment
3WP-2000 type walking spray tower, Nanjing Agricultural Machinery Inst., Ministry of Agriculture.GA10 type a ten thousandth electronics day
Flat (Germany)；ZDR2000 intelligent data recorder (Hangzhou Ze great Instrument Ltd.)；SPX type Intelligent biochemistry incubator (Ningbo
Jiangnan instrument plant).
2) experimental design
2.1), reagent
2.1.1), test medicine
Required active constituent B is commercially available raw medicine, and A is our company's production.
Raw medicine is all made of acetone as solvent, is diluted with 0.1% emulsifier T-80 aqueous solution of content, current existing dilution.
2.2), test process
2.2.1), dosage is arranged
Determining A and when active constituent B each group distribution ratio or content, it should be from the action character of two kinds of medicaments and its virulence etc.
It measures, it is also contemplated that the main of the formula uses purpose.This research is on the basis of prerun early period, if A, B activity ingredient are applied alone
And mixing dosage is shown in Table lattice respectively.Using without medicament, the water containing same solvent and emulsifier as blank control.
2.2.2), test repeats
Every processing is repeated 4 times, 3 basins of each every processing, and every basin sows weed seed 20, totally 60 plants of every processing.
2.3), processing mode
2.3.1), time and number are handled
It tests and shares medicine 1 time.To 1 heart stage of 2 leaf of weeds, thinning keeps 15 plants of weeds in every basin, and every processing retains 45 plants,
Culture is then proceeded to barnyard grass, semen euphorbiae, 1 heart stage of 3 leaf of rice barnyard grass, difformed galingale herb, 3 leaf phase of angustifolia arrowhead herb are handled.
2.3.2), using instrument and administrated method
Cultured test material is uniformly placed in area 0.5m2Platform on, with 3WP-2000 type walking spray tower stem
Foliar spray mist, spouting liquid is based on 30 kilograms/hectare.Atomisation pressure 0.3MPa.After whole liquid medicine jets are complete, air valve is closed, after 30 seconds,
Spraying pyller is opened, nutritive cube is taken out.Then air valve is opened, clear water 50ml is sprayed, cleans sparge pipe.
3) test method
Using pot-culture method.Weeds culture is shown in 1.1, carries out referring to " farm-chemical indoor determination test rule herbicide ".With
Prescription method is shown in 2.3.2, using cauline leaf process method.Greenhouse routine culture is moved into after processing, and 1-2cm water is remained during test
Layer.
4), data survey and statistical analysis
4.1), investigation method
Using absolute number investigation method, the survival whole strain seedling of weeds is cut off along soil surface with blade, is weighed with assay balance
Weeds fresh weight.It is based on zero by fresh weight for dead weeds.
4.2), control time and number
It investigates within 20 days after processing, investigates 1 time altogether.
4.3), data statistic analysis
With Gowing method calculate it is each processing hybrid combining theoretical fresh weight inhibition rate (E0=X+Y-X*Y/100), then with
Actual measurement inhibiting rate (E) compares, and the mixed synergy type to weeds of both evaluations is made when E-E0 value is greater than 10% for synergy
With, be antagonism less than -10%, be addition between -10%~10%.And it is special according to practical preventive effect and herbicide
The factors such as the balance of point, formula determine optimum proportioning.
The fresh weight inhibition rate that X is A dosage in formula when being P；The fresh weight inhibition rate that Y is active constituent B dosage when being Q.
Closed soil treatment:
1) experimental condition
1.1), for trying target
Barnyard grass (Echinochloa crusgalli) picks up from Hunan Hanshou paddy field；Semen euphorbiae (Leptochloa
Chinensis county, Hubei province) is picked up from, cyperus iria (Cyperus iria L.) picks up from Hubei Jing Zhou, Monochoria vaginalis
(Monochoria vaginalis) picks up from Liaoning Yingkou, rice barnyard grass (Echinochloa phyllopogon (stapf) Koss.),
Firefly Lin (Scirpus juncoides Roxb) acquires Heilungkiang Hulin.
1.2), condition of culture
It is carried out in controllable heliogreenhouse, 20~30 DEG C of temperature, natural lighting, relative humidity 57%~72%.
Soil types is loam, the content of organic matter 1.63%, pH=7.1, alkali-hydrolyzable nitrogen 84.3mg/kg, rapid available phosphorus
38.5mg/kg, available potassium 82.1mg/kg.Test soil is quantitatively filled at the 3/4 of basin alms bowl, is then poured from basin alms bowl bottom, is made soil
Earth is moistened completely to saturation state.By pretreated for trying weed seed, equal and quantitative broadcasts sowing surface, according to seed size earthing
0.5-2cm, after planting 24 hours spare.
1.3), instrument and equipment
GA10 type a ten thousandth electronic balance (Germany)；ZDR2000 intelligent data recorder (the limited public affairs of the big instrument in Hangzhou pool
Department)；SPX type Intelligent biochemistry incubator (Ningbo Jiangnan instrument plant), pipettor etc..
2) experimental design
2.1), reagent
2.1.1), test medicine
Required active constituent B is commercially available raw medicine, and A is our company's production.
Raw medicine is all made of acetone as solvent, is diluted with 0.1% emulsifier T-80 aqueous solution of content, current existing dilution.
2.2), test process
2.2.1), dosage is arranged
Determining A and when active constituent B each group distribution ratio or content, it should be from the action character of two kinds of medicaments and its virulence etc.
It measures, it is also contemplated that the main of the formula uses purpose.This research is on the basis of prerun early period, if A, B activity ingredient are applied alone
And mixing dosage is shown in Table lattice respectively.Using without medicament, the water containing same solvent and emulsifier as blank control.
2.2.2), test repeats
Every processing is repeated 4 times, and 3 basins of each every processing, every basin sows weed seed 30.
2) test method
It is poured before processing, keeps 1-2cm water layer.Quantitative liquid medicine is taken with pipettor, according to experimental design from low dosage to height
Dosage carries out pouring processing, 4 repetitions per treatment respectively；Greenhouse routine culture is moved into after processing, is remained during test
1-2cm water layer.
3), data survey and statistical analysis
3.1), investigation method
Using absolute number investigation method, the survival whole strain seedling of weeds is cut off along soil surface with blade, is weighed with assay balance
Weeds fresh weight.It is based on zero by fresh weight for dead weeds.
3.2), control time and number
It investigates within 20 days after processing, investigates 1 time altogether.
3.3), data statistic analysis
With Gowing method calculate it is each processing hybrid combining theoretical fresh weight inhibition rate (E0=X+Y-X*Y/100), then with
Actual measurement inhibiting rate (E) compares, and the mixed synergy type to weeds of both evaluations is made when E-E0 value is greater than 10% for synergy
With, be antagonism less than -10%, be addition between -10%~10%.And it is special according to practical preventive effect and herbicide
The factors such as the balance of point, formula determine optimum proportioning.In general, evaluation is mutually improved effect under low dosage.With with
The increase of amount, after some component is more than doses, single component reaches compared with high preventive effect, and synergistic effect is no longer significant.
The fresh weight inhibition rate that X is A dosage in formula when being P；The fresh weight inhibition rate that Y is active constituent B dosage when being Q.
Statistical result see the table below.
1 A of table and symetryne mixture are to the practical preventive effect (soil closing) of barnyard grass and synergy evaluation (Gowing)
2 A of table and halosulfuronmethyl mixture are to the practical preventive effect of difformed galingale herb and synergy evaluation (Gowing)
3 A of table and anilofos mixture are to the practical preventive effect of semen euphorbiae and synergy evaluation (Gowing)
4 A of table and anilofos mixture are to the practical preventive effect of barnyard grass and synergy evaluation (Gowing)
5 A of table and molinate mixture are to the practical preventive effect of barnyard grass and synergy evaluation (Gowing)
6 A of table and benthiocarb mixture are to the practical preventive effect of barnyard grass and synergy evaluation (Gowing)
7 A of table and metamifop mixture are to the practical preventive effect of barnyard grass and synergy evaluation (Gowing)
8 A of table and clefoxidim mixture are to the practical preventive effect of barnyard grass and synergy evaluation (Gowing)
9 A of table and mefenacet mixture are to the practical preventive effect (soil closing) of barnyard grass and synergy evaluation (Gowing)
10 A of table and 2 first, 4 chlorine sodium salt mixture are to the practical preventive effect of angustifolia arrowhead herb and synergy evaluation (Gowing)
11 A of table and benzobicylon mixture evaluate the practical preventive effect (soil closing) of firefly Lin and synergy
(Gowing)
12 A of table and pentoxazone mixture evaluate the practical preventive effect (soil closing) of semen euphorbiae and synergy
(Gowing)
13 A of table and isoproturon mixture are to the practical preventive effect of barnyard grass and synergy evaluation (Gowing)
14 A of table and pyrazosulfuron mixture evaluate the practical preventive effect (soil closing) of Monochoria vaginalis and synergy
(Gowing)
15 A of table is compounded with furans sulphur humulone to the practical preventive effect (soil closing) of barnyard grass and synergy evaluation
(Gowing)
16 A of table and penoxsuam mixture evaluate the practical preventive effect (soil closing) of cyperus iria and synergy
(Gowing)
17 A of table and indanofan mixture are to the practical preventive effect of rice barnyard grass and synergy evaluation (Gowing)
18 A of table and piperophos mixture are to the practical preventive effect of semen euphorbiae and synergy evaluation (Gowing)
19 A of table and fentrazamide mixture evaluate the practical preventive effect (soil closing) of semen euphorbiae and synergy
(Gowing)
20 A of table and bromacil mixture are to the practical preventive effect of rice barnyard grass and synergy evaluation (Gowing)
21 A of table and prometryn mixture are to the practical preventive effect (soil closing) of rice barnyard grass and synergy evaluation (Gowing)
(C), field demonstration
Utilize embodiment 1) -90) made from herbicidal composition prevent and kill off paddy field weed test.
Exemplary promote is carried out in 4, Jiangxi Poyang late rice area testing site within 2016 to test.
Test method: after 3 leaf of rice, 1 heart, the weeds 3-4 leaf phase, hand sprayer, 30 kilograms/667m of the amount of being watered2, use
Cauline leaf is sprayed even spraying, and see Table 2 for details 2 for specific test medicine and dosage, and 50 square metres of plot area, every processing is repeated 4 times.It applies
45 days investigation preventive effects are shown in Table 22 after medicine.
22 field demonstration effect situation of table
Note: space indicates non-test data.
By a large number of experiments and exploration, it is an unexpected discovery of the invention that the composition removes grass for paddy field seedling rear defence
Section weeds have surprising, unexpected synergistic effect, especially to gramineae weeds such as barnyard grass, rice barnyard grass, semen euphorbiaes
There is particularly evident synergistic effect with broad leaved weeds such as Monochoria vaginalis, angustifolia arrowhead herbs, this synergistic effect shows under low dosage
It is more significant, dosage can be reduced, and to rice safety, reduce the pollution to environment, and rationally compounding reduces agricultural cost,
It is efficient to ALS, ACCase inhibitor resistant weed, it has a good application prospect.Simultaneously by test in wheat paddock, corn
The lawns such as field, soybean, cotton, vegetables, annual bluegrass, Festuca Arundinacea, Korea lawn grass and crop show good selective and excellent increasing
Effect effect, can develop into the herbicide combination product of extensive market value.
Claims (10)
1. a kind of Herbicidal combinations of the humulone of sulphur containing triazole, which is characterized in that active components A and activity including herbicidally effective amount
Ingredient B, wherein active components A is triazole sulphur humulone, and active constituent B is selected from one of following compound or a variety of: indenes grass
Ketone, bromacil, 2 first, 4 chlorine sodium salt, prometryn, symetryne, halosulfuronmethyl, molinate, benthiocarb, metamifop, ring benzene grass
Ketone, benzobicylon, pentoxazone, isoproturon, pyrazosulfuron, furans sulphur humulone, penoxsuam.
2. a kind of Herbicidal combinations of humulone of sulphur containing triazole according to claim 1, which is characterized in that active components A and B
Weight ratio be 1:60-60:1, preferably 1:50-50:1 and 1:40-40:1, more preferable 1:30-30:1 and 1:20-20:1, into one
Walk preferred 1:10-10:1.
3. a kind of Herbicidal combinations of humulone of sulphur containing triazole according to claim 1, which is characterized in that
The weight ratio of A and indanofan is 1:30-12:1
The weight ratio of A and bromacil is 1:30-12:1
The weight ratio of 4 chlorine sodium salt of A and 2 first is 1:32-32:1
The weight ratio of A and prometryn is 1:30-6:1
The weight ratio of A and symetryne is 1:12-12:1
The weight ratio of A and halosulfuronmethyl is 1:4-24:1
The weight ratio of A and molinate is 1:24-4:1
The weight ratio of A and benthiocarb is 1:24-1:1
The weight ratio of A and metamifop is 1:12-12:1
The weight ratio of A and clefoxidim is 1:4-20:1
The weight ratio of A and benzobicylon is 1:24-18:1
The weight ratio of A and pentoxazone is 1:24-36:1
The weight ratio of A and isoproturon is 1:36-24:1
The weight ratio of A and pyrazosulfuron is 2:1-16:1
The weight ratio of A and furans sulphur humulone is 1:16-12:1
The weight ratio of A and penoxsuam is 1:8-48:1.
4. a kind of Herbicidal combinations of humulone of sulphur containing triazole according to claim 2 or 3, which is characterized in that the weeding
The mass percentage of A, B account for the 1-95% of total amount in composition.
5. a kind of Herbicidal combinations of humulone of sulphur containing triazole according to claim 4, which is characterized in that the Herbicidal combination
The mass percentage of A, B account for the 10-80% of total amount in object.
6. according to claim 1 to a kind of Herbicidal combinations of sulphur containing triazole humulone described in 5 any one, which is characterized in that
It further include carrier, surfactant in the Herbicidal combinations.
7. according to claim 1 to a kind of Herbicidal combinations of sulphur containing triazole humulone described in 5 any one, which is characterized in that
The specific preparation of the Herbicidal combinations is dispersible oil-suspending agent, aqueous suspension agent, suspoemulsion, missible oil, water dispersible granules, water and milk
Agent or microemulsion.
8. according to claim 1 to a kind of Herbicidal combinations of sulphur containing triazole humulone described in 5 any one, which is characterized in that
The Herbicidal combinations further comprise safener C.
9. a kind of Herbicidal combinations of humulone of sulphur containing triazole according to claim 8, which is characterized in that the safener
C is selected from one of following compound or a variety of:
C1: isoxadifen
C2:cyprosulfamide
C3: mefenpyrdiethyl
C4: cloquintocetmexyl
C5: gibberellic acid
C6:furilazole
C7:metcamifen.
10. the Herbicidal combinations of the humulone of sulphur containing triazole are in prevention and treatment paddy field injurious weed as described in claim 1 to 9 any one
In application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910163574.3A CN109757494B (en) | 2017-09-19 | 2017-09-19 | Weeding composition containing triazasulam and application thereof |
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| CN201910163574.3A CN109757494B (en) | 2017-09-19 | 2017-09-19 | Weeding composition containing triazasulam and application thereof |
| CN201710852148.1A CN107568230B (en) | 2017-09-19 | 2017-09-19 | Weeding composition containing triazasulam and application thereof |
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| CN201710852148.1A Division CN107568230B (en) | 2017-09-19 | 2017-09-19 | Weeding composition containing triazasulam and application thereof |
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| CN115363031A (en) * | 2022-09-30 | 2022-11-22 | 北京金泰毅农作物科技有限公司 | Herbicide composition containing Lancotrione-sodium salt and propanil |
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| CN112998022B (en) * | 2017-11-09 | 2021-09-21 | 青岛清原化合物有限公司 | Weeding composition containing triazasulam and application thereof |
| CN114521562B (en) * | 2018-02-01 | 2023-12-01 | 青岛清原化合物有限公司 | Ternary weeding composition and application thereof |
| CN113142217B (en) * | 2018-07-21 | 2022-04-22 | 青岛清原化合物有限公司 | Ternary herbicidal composition containing HPPD inhibitor herbicide and application thereof |
| CN109479888A (en) * | 2018-12-19 | 2019-03-19 | 青岛清原化合物有限公司 | Ternary weeding composition and its application comprising cyclopyrimorate |
| CN109497075B (en) * | 2018-12-19 | 2021-12-07 | 青岛清原化合物有限公司 | Ternary herbicidal composition containing trifludimoxazin and application thereof |
| CN109452300B (en) * | 2019-01-11 | 2020-08-18 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Ternary weeding composition containing halosulfuron-methyl and application thereof |
| CN113387926B (en) * | 2020-03-13 | 2023-12-12 | 沈阳中化农药化工研发有限公司 | Heterocyclic carboxylic ester compound and application thereof as herbicide |
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| CN115363031B (en) * | 2022-09-30 | 2024-02-02 | 北京金泰毅农作物科技有限公司 | Herbicide composition containing Lancotrione-sodium salt and propanil |
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| CN113016810B (en) | 2021-11-16 |
| CN113180051A (en) | 2021-07-30 |
| CN109757494B (en) | 2021-06-15 |
| CN107568230A (en) | 2018-01-12 |
| WO2019056537A1 (en) | 2019-03-28 |
| CN113016810A (en) | 2021-06-25 |
| CN107568230B (en) | 2021-05-14 |
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