CN109735868A

CN109735868A - A kind of electrolysis unit

Info

Publication number: CN109735868A
Application number: CN201910107983.1A
Authority: CN
Inventors: 靳北彪
Original assignee: Entropy Zero Technology Logic Engineering Group Co Ltd
Current assignee: Entropy Zero Technology Logic Engineering Group Co Ltd
Priority date: 2018-08-26
Filing date: 2019-02-02
Publication date: 2019-05-10

Abstract

The invention discloses a kind of electrolysis unit, including electrochemistry region, the electrochemistry region is connected to setting with compound feed channel, and the electrochemistry region includes the area alternating current Jie electricity, and the electrochemistry region is connected to setting with electrolysate export channel.Electrolysis unit disclosed in this invention will terminate traditional electrolyte device with the history for existing for necessary condition of electrolyte, and the exploitation for efficient, long-life, inexpensive electrolysis unit provides new approach.

Description

A kind of electrolysis unit

Technical field

The present invention relates to electricity field, electrochemical field more particularly to a kind of electrolysis units.

Background technique

Electrolysis unit is using very extensive, but all electrolysis units so far between electrode to transmit non-electronic band Charged particle (such as proton, negative oxygen ion etc.) is necessary condition, mean that so all electrolysis units so far with It the use of the electrolyte that non-electronic charged particle is connected is necessary condition, and the electrolyte that non-electronic charged particle is connected not only manufactures It is difficult, using difficulty, and will be greatly reduced electrolytic efficiency.If can invent one kind does not exist for necessary item with electrolyte The electrolysis unit of part will be of great significance.Therefore, it is necessary to invent a kind of novel electrolytic device.

Summary of the invention

To solve the above-mentioned problems, technical solution proposed by the present invention is as follows:

A kind of electrolysis unit of scheme 1., including electrochemistry region, the electrochemistry region are connected to compound feed channel Setting, the electrochemistry region include the area alternating current Jie electricity, and the electrochemistry region is connected to electrolysate export channel and sets It sets；

Or, the electrochemistry region is connected to setting with compound feed channel, the electrochemistry region includes alternating current The area Jie electricity, the electrochemistry region are connected to setting with electrolysate export channel；The electrochemistry region and non-electronic band electrochondria Sub- transmitter have non-electronic conducting electrical relation or the electrochemistry region successively with electronic conduction area and non-electronic band electrochondria There is sub- transmitter non-electronic conducting electrical relation or the electrochemistry region and dielectric to close with non-electronic conducting electricity System；

Or, the electrochemistry region is connected to setting with compound feed channel, the electrochemistry region includes alternating current The area Jie electricity, the electrochemistry region are connected to setting with electrolysate export channel；The electrochemistry region and insulation, isolation sky Between, in electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area at least One kind having non-electronic conducting electrical relation.

A kind of electrolysis unit of scheme 2., including electrochemistry region and region B, the electrochemistry region and compound feed are logical Road connection setting, the electrochemistry region includes alternating current Jie electricity area A, and the region B includes alternating current Jie electricity area B, institute It states electrochemistry region and is connected to setting with electrolysate export channel；

Or, the electrochemistry region is connected to setting with compound feed channel, the electrochemistry region includes alternating current The area Jie electricity A, the region B include alternating current Jie electricity area B, and the electrochemistry region is connected to electrolysate export channel and sets It sets；The electrochemistry region has non-electronic conducting electrical relation or the electricity through non-electronic charged particle transmitter and region B Chemical regions successively have non-electronic conducting electrical relation through electronic conduction area and non-electronic charged particle transmitter and region B, Or the electrochemistry region has non-electronic conducting electrical relation through dielectric and region B；

Or, the electrochemistry region is connected to setting with compound feed channel, the electrochemistry region includes alternating current The area Jie electricity A, the region B include alternating current Jie electricity area B, and the electrochemistry region is connected to electrolysate export channel and sets It sets；The electrochemistry region is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion At least one of gas, solion and electronic conduction area have non-electronic conducting electrical relation with the region B.

A kind of electrolysis unit of scheme 3., including electrochemistry region A and electrochemistry region B, the electrochemistry region A and chemical combination The connection setting of object feed channel, the electrochemistry region A includes alternating current Jie electricity area A, the electrochemistry region B and compound The connection setting of feed channel, the electrochemistry region B includes alternating current Jie electricity area B, the electrochemistry region A and electrolysate Channel connection setting is exported, the electrochemistry region B is connected to setting with electrolysate export channel；

Or, the electrochemistry region A is connected to setting with compound feed channel, the electrochemistry region A includes alternation electricity The area Liu Jie electricity A, the electrochemistry region B are connected to setting with compound feed channel, and the electrochemistry region B includes alternating current The area Jie electricity B, the electrochemistry region A are connected to setting with electrolysate export channel, and the electrochemistry region B is led with electrolysate Channel connection setting out；The electrochemistry region A has non-electrical through non-electronic charged particle transmitter and the electrochemistry region B Son conducting electrical relation or the electrochemistry region A successively through electronic conduction area and non-electronic charged particle transmitter with it is described Electrochemistry region B has non-electronic conducting electrical relation or the electrochemistry region A through dielectric and the electrochemistry region B With non-electronic conducting electrical relation；

Or, the electrochemistry region A is connected to setting with compound feed channel, the electrochemistry region A includes alternation electricity The area Liu Jie electricity A, the electrochemistry region B are connected to setting with compound feed channel, and the electrochemistry region B includes alternating current The area Jie electricity B, the electrochemistry region A are connected to setting with electrolysate export channel, and the electrochemistry region B is led with electrolysate Channel connection setting out；The electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, At least one of ionic liquid, ionized gas, solion and electronic conduction area have non-electronic with the electrochemistry region B Electrical relation is connected.

A kind of electrolysis unit of scheme 4., including electrochemistry region A and electrochemistry region B, the electrochemistry region A and described Electrochemistry region B is connected to setting with compound feed channel, and the electrochemistry region A includes alternating current Jie electricity area A, the electricity Chemical regions B includes alternating current Jie electricity area B, and the electrochemistry region A is connected to setting, the electricity with electrolysate export channel Chemical regions B is connected to setting with electrolysate export channel；

Or, the electrochemistry region A and the electrochemistry region B are connected to setting, the electrification with compound feed channel School district domain A includes alternating current Jie electricity area A, and the electrochemistry region B includes alternating current Jie electricity area B, the electrochemistry region A It is connected to setting with electrolysate export channel, the electrochemistry region B is connected to setting with electrolysate export channel；The electrification School district domain A has non-electronic conducting electrical relation or the electricity through non-electronic charged particle transmitter and the electrochemistry region B Chemical regions A successively has non-electronic lead with the electrochemistry region B through electronic conduction area and non-electronic charged particle transmitter Leading to electrical relation or the electrochemistry region A has non-electronic conducting electrical relation through dielectric and the electrochemistry region B；

Or, the electrochemistry region A and the electrochemistry region B are connected to setting, the electrification with compound feed channel School district domain A includes alternating current Jie electricity area A, and the electrochemistry region B includes alternating current Jie electricity area B, the electrochemistry region A It is connected to setting with electrolysate export channel, the electrochemistry region B is connected to setting with electrolysate export channel；The electrification School district domain A is molten through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, ion At least one of liquid and electronic conduction area have non-electronic conducting electrical relation with the electrochemistry region B.

A kind of electrolysis unit of scheme 5., including electrochemistry region A and electrochemistry region B, the electrochemistry region A and described Electrochemistry region B is connected to setting with compound feed channel, and the electrochemistry region A includes alternating current Jie electricity area A, the electricity Chemical regions B includes that alternating current Jie electricity area B, the electrochemistry region A and the electrochemistry region B and electrolysate export are logical Road connection setting；

Or, the electrochemistry region A and the electrochemistry region B are connected to setting, the electrification with compound feed channel School district domain A includes alternating current Jie electricity area A, and the electrochemistry region B includes alternating current Jie electricity area B, the electrochemistry region A Setting is connected to the electrochemistry region B with electrolysate export channel；The electrochemistry region A is passed through non-electronic charged particle Leading object and the electrochemistry region B has non-electronic conducting electrical relation or the electrochemistry region A successively through electronic conduction area There is non-electronic conducting electrical relation or the electrochemical school district with non-electronic charged particle transmitter and the electrochemistry region B Domain A has non-electronic conducting electrical relation through dielectric and the electrochemistry region B；

Or, the electrochemistry region A and the electrochemistry region B are connected to setting, the electrification with compound feed channel School district domain A includes alternating current Jie electricity area A, and the electrochemistry region B includes alternating current Jie electricity area B, the electrochemistry region A Setting is connected to the electrochemistry region B with electrolysate export channel；The electrochemistry region A through insulation, isolation space, At least one in electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area Kind has non-electronic conducting electrical relation with the electrochemistry region B.

A kind of electrolysis unit of scheme 6., including electrochemistry region, the electrochemistry region are arranged in the cavity, the cavity Setting is connected to compound feed channel, the electrochemistry region includes the area alternating current Jie electricity, the cavity and electrolysate Export channel connection setting；

Or, the electrochemistry region setting is in the cavity, the cavity is connected to setting, the electricity with compound feed channel Chemical regions include the area alternating current Jie electricity, and the cavity is connected to setting with electrolysate export channel；The electrochemistry region With non-electronic charged particle transmitter have non-electronic conducting electrical relation or the electrochemistry region successively with electronic conduction area With non-electronic charged particle transmitter there is non-electronic conducting electrical relation or the electrochemistry region and dielectric to have non-electrical Son conducting electrical relation；

Or, the electrochemistry region setting is in the cavity, the cavity is connected to setting, the electricity with compound feed channel Chemical regions include the area alternating current Jie electricity, and the cavity is connected to setting with electrolysate export channel；The electrochemistry region With insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electricity At least one of son conducting area has non-electronic conducting electrical relation.

A kind of electrolysis unit of scheme 7., including electrochemistry region and region B, the electrochemistry region are arranged in the cavity, The cavity is connected to setting with compound feed channel, and the electrochemistry region includes alternating current Jie electricity area A, the region B Including alternating current Jie electricity area B, the cavity is connected to setting with electrolysate export channel；

Or, the electrochemistry region setting is in the cavity, the cavity is connected to setting, the electricity with compound feed channel Chemical regions include alternating current Jie electricity area A, and the region B includes alternating current Jie electricity area B, and the cavity is led with electrolysate Channel connection setting out；The electrochemistry region has non-electronic conducting electricity through non-electronic charged particle transmitter and region B Relationship or the electrochemistry region successively have through electronic conduction area and non-electronic charged particle transmitter with region B non-electronic Electrical relation or the electrochemistry region, which is connected, has non-electronic conducting electrical relation through dielectric and region B；

Or, the electrochemistry region setting is in the cavity, the cavity is connected to setting, the electricity with compound feed channel Chemical regions include alternating current Jie electricity area A, and the region B includes alternating current Jie electricity area B, and the cavity is led with electrolysate Channel connection setting out；The electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, from At least one of sub- liquid, ionized gas, solion and electronic conduction area have non-electronic conducting electricity with the region B Relationship.

A kind of electrolysis unit of scheme 8., including electrochemistry region A and electrochemistry region B, the electrochemistry region A setting exist In cavity A, the cavity A is connected to setting with compound feed channel, and the electrochemistry region A includes alternating current Jie electricity area A, The electrochemistry region B is arranged in cavity B, and the cavity B is connected to setting, the electrochemistry region with compound feed channel B includes alternating current Jie electricity area B, and the cavity A is connected to setting, the cavity B and electrolysate with electrolysate export channel Export channel connection setting；

Or, the electrochemistry region A is arranged in cavity A, the cavity A is connected to setting, institute with compound feed channel Stating electrochemistry region A includes alternating current Jie electricity area A, and the electrochemistry region B is arranged in cavity B, the cavity B and chemical combination The connection setting of object feed channel, the electrochemistry region B include alternating current Jie electricity area B, and the cavity A and electrolysate export Channel connection setting, the cavity B are connected to setting with electrolysate export channel；The electrochemistry region A is through non-electronic electrification Particle conduction object and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A successively through electronics Area and non-electronic charged particle transmitter and the electrochemistry region B, which is connected, has non-electronic conducting electrical relation or the electricity Chemical regions A has non-electronic conducting electrical relation through dielectric and the electrochemistry region B；

Or, the electrochemistry region A is arranged in cavity A, the cavity A is connected to setting, institute with compound feed channel Stating electrochemistry region A includes alternating current Jie electricity area A, and the electrochemistry region B is arranged in cavity B, the cavity B and chemical combination The connection setting of object feed channel, the electrochemistry region B include alternating current Jie electricity area B, and the cavity A and electrolysate export Channel connection setting, the cavity B are connected to setting with electrolysate export channel；The electrochemistry region A is through insulation, isolation In space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area extremely A kind of few and electrochemistry region B has non-electronic conducting electrical relation.

A kind of electrolysis unit of scheme 9., including electrochemistry region A and electrochemistry region B, the electrochemistry region A setting exist In cavity A, the electrochemistry region B is arranged in cavity B, and the cavity A and the cavity B are connected to compound feed channel Setting, the electrochemistry region A includes alternating current Jie electricity area A, and the electrochemistry region B includes alternating current Jie electricity area B, institute It states cavity A and is connected to setting with electrolysate export channel, the cavity B is connected to setting with electrolysate export channel；

Or, the electrochemistry region A is arranged in cavity A, the electrochemistry region B is arranged in cavity B, the cavity The A and cavity B is connected to setting with compound feed channel, and the electrochemistry region A includes alternating current Jie electricity area A, described Electrochemistry region B includes alternating current Jie electricity area B, and the cavity A is connected to setting, the cavity B with electrolysate export channel Setting is connected to electrolysate export channel；The electrochemistry region A is through non-electronic charged particle transmitter and the electrochemistry Region B has non-electronic conducting electrical relation or the electrochemistry region A successively through electronic conduction area and non-electronic charged particle Transmitter and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A through dielectric with it is described Electrochemistry region B has non-electronic conducting electrical relation；

Or, the electrochemistry region A is arranged in cavity A, the electrochemistry region B is arranged in cavity B, the cavity The A and cavity B is connected to setting with compound feed channel, and the electrochemistry region A includes alternating current Jie electricity area A, described Electrochemistry region B includes alternating current Jie electricity area B, and the cavity A is connected to setting, the cavity B with electrolysate export channel Setting is connected to electrolysate export channel；The electrochemistry region A is through insulation, isolation space, electrolyte, dielectric, electricity At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemical school district Domain B has non-electronic conducting electrical relation.

A kind of electrolysis unit of scheme 10., including electrochemistry region A and electrochemistry region B, the electrochemistry region A setting In cavity A, the electrochemistry region B is arranged in cavity B, and the cavity A and the cavity B and compound feed channel connect Logical setting, the electrochemistry region A includes alternating current Jie electricity area A, and the electrochemistry region B includes alternating current Jie electricity area B, The cavity A and cavity B is connected to setting with electrolysate export channel；

Or, the electrochemistry region A is arranged in cavity A, the electrochemistry region B is arranged in cavity B, the cavity The A and cavity B is connected to setting with compound feed channel, and the electrochemistry region A includes alternating current Jie electricity area A, described Electrochemistry region B, which includes alternating current Jie electricity area B, the cavity A and the cavity B, to be connected to electrolysate export channel and sets It sets；The electrochemistry region A is closed through non-electronic charged particle transmitter and the electrochemistry region B with non-electronic conducting electricity System or the electrochemistry region A successively have through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B There are non-electronic conducting electrical relation or the electrochemistry region A that there is non-electronic conducting through dielectric and the electrochemistry region B Electrical relation；

Or, the electrochemistry region A is arranged in cavity A, the electrochemistry region B is arranged in cavity B, the cavity The A and cavity B is connected to setting with compound feed channel, and the electrochemistry region A includes alternating current Jie electricity area A, described Electrochemistry region B, which includes alternating current Jie electricity area B, the cavity A and the cavity B, to be connected to electrolysate export channel and sets It sets；The electrochemistry region A is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion At least one of gas, solion and electronic conduction area have non-electronic conducting electrical relation with the electrochemistry region B.

A kind of electrolysis unit of scheme 11., including electrochemistry region A and electrochemistry region B, the electrochemistry region A and institute State electrochemistry region B setting in the cavity, the cavity is connected to setting, the electrochemistry region A packet with compound feed channel Alternating current Jie electricity area A is included, the electrochemistry region B includes alternating current Jie electricity area B, and the cavity and electrolysate export are logical Road connection setting；

Or, the electrochemistry region A and electrochemistry region B setting is in the cavity, the cavity and compound feed Channel connection setting, the electrochemistry region A includes alternating current Jie electricity area A, and the electrochemistry region B includes that alternating current connects Electric area B, the cavity are connected to setting with electrolysate export channel；The electrochemistry region A is conducted through non-electronic charged particle Object and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A successively through electronic conduction area and Non-electronic charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A There is non-electronic conducting electrical relation through dielectric and the electrochemistry region B；

Or, the electrochemistry region A and electrochemistry region B setting is in the cavity, the cavity and compound feed Channel connection setting, the electrochemistry region A includes alternating current Jie electricity area A, and the electrochemistry region B includes that alternating current connects Electric area B, the cavity are connected to setting with electrolysate export channel；The electrochemistry region A is through insulation, isolation space, electricity At least one of Xie Zhi, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area There is non-electronic conducting electrical relation with the electrochemistry region B.

The compound on the basis of either a program, is further selectively set as mixed in scheme 1 to 11 by scheme 12. Close the compound in object；Or, the compound is set as water, the reducing agent is hydrogen, and the oxidant is oxygen；Or, described Compound is set as water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is alcohol compound, and the oxidant is oxygen Gas；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is ether compound, described Oxidant is oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is alkane Class compound, the oxidant are oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, described Reducing agent is alkenes compounds, and the oxidant is oxygen；Or, the compound is set as water, and water and carbon dioxide are common Reaction is participated in, the reducing agent is alkynes compound, and the oxidant is oxygen.

Scheme 13. on the basis of either a program, is further selectively arranged the electrolysate and leads in scheme 1 to 12 Channel includes reducing agent export channel and oxidant export channel out；

Or, electrolysate export channel includes reducing agent export channel and oxidant export channel, in the reduction Agent exports setting reducing agent on channel and switchs, and setting oxidant switchs on oxidant export channel, and the reducing agent is opened It closes and oxidant switch is controlled by control device and alternately opened and closed；

Or, electrolysate export channel includes reducing agent export channel and oxidant export channel, in the reduction Agent exports setting reducing agent on channel and switchs, and setting oxidant switchs on oxidant export channel, and the reducing agent is opened It closes and oxidant switch is controlled by control device and alternately opened and closed, the reducing agent switch and oxidant switch The frequency and phase alternately opened and closed matches with the frequency of alternating current and phase applied to the area alternating current Jie electricity；

Or, electrolysate export channel is set as the molar mixture export channel of Oxidizing and Reducing Agents.

It, can be into the above-mentioned all schemes including the electrochemistry region of the present invention of scheme 14. on the basis of either a program Selectively the electrochemistry area rotation is arranged for one step.

Appoint in the 15. above-mentioned all schemes including the electrochemistry region A and electrochemistry region B of the present invention of scheme On the basis of one scheme, further selectively the electrochemistry region A can be rotated and be arranged, the electrochemistry region B rotation Setting.

In the present invention, there is non-electronic electric conduction through electronic conduction area and the region B including the electrochemistry region In the scheme of relationship, be selectively chosen make one in the electrochemistry region and the region B through capacitor or through non- Electronic conduction area (such as the electrolyte such as proton exchange membrane) is again through external circuit and another electric communication, it is possible to realize normality Work.

It is non-electronic having including the electrochemistry region A through electronic conduction area and the electrochemistry region B in the present invention In the scheme that electrical relation is connected, it is selectively chosen one made in the electrochemistry region A and the electrochemistry region B Through capacitor or through non-electronic conducting Qu Zaijing external circuit and another electric communication, it is possible to realize that normality works.

In the present invention, so that charged particle is stored in the means in electrochemistry region as realizing, be selectively chosen and pass through Make electrochemistry region and participates in two kinds of metabolies contact of electrochemical reaction and the alternating of electric current changes to realize, it can also be with Selectively selection contacts the two kinds of substances and the electrochemistry region that participate in electrochemical reaction alternately and the variation of the alternating of electric current It realizes, however two electrodes of electrochemical reaction are (for example, the electrochemistry region and electric conductor, the electrochemistry region A and institute State electrochemistry region B, the electrochemistry region and the region B) between the conducting of non-electronic charged particle then may exist It can also be not present.

In the present invention, charged particle is set to be stored in the means in electrochemistry region as realizing, being selectively chosen makes electricity The mixture contact of two kinds of substances of chemical regions and participation electrochemical reaction and the alternating of electric current change to realize, may be selected Property select to make electrochemistry region and participate in the mixture makes discontinuous contact of two kinds of substances of electrochemical reaction and the alternating of electric current Variation is to realize, however the conducting of the non-electronic charged particle between two electrodes of electrochemical reaction then may or may not In the presence of.

The electrolysis unit disclosed in this invention is corresponding with alternating electromotive force and alternating current, i.e., electrochemistry region with Alternating electromotive force and alternating current are corresponding.

In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen through non-electronic Relationship is connected in the direct electricity that charged particle is formed, and relationship, warp is connected in the electricity formed through non-electronic charged particle reciprocating vibration One of electricity conducting relationship that capacitance relation is formed, secondly conjunction or thirdly conjunction.

In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen including through exhausted The electrical relation that alternating current can be made to be connected of edge body, dielectric and the conducting body isolation of non-electronic charged particle.

In the present invention, in two electrodes (for example, the electrochemistry region and electric conductor, the electrochemistry region A and the electricity Chemical regions B, the electrochemistry region and the region B) between there are in the scheme of electrolyte, non-electronic charged particle can both be worn More electrolyte reaches another electrode from an electrode, can also realize the work that alternating current is connected by reciprocating vibration in the electrolyte With.

In the present invention, electrochemistry region corresponding with alternating electromotive force and alternating current is essence feature of the invention, This feature eliminates the necessity of charged particle non-electronic between two electrodes transmission, thus no matter make between two electrodes in electronics every Exhausted state, non-electronic charged particle state of isolation have the state for the electrolyte that non-electronic charged particle is connected between two electrodes, also It is that can be worked normally in other states as long as can be realized the Oscillating flow of electronics.There are electrolyte between two electrodes In scheme, non-electronic charged particle can both pass through electrolyte, reach another electrode from an electrode, can also be past in the electrolyte Complex oscillation realizes the effect of alternating current conducting.This provides brand-new method for the manufacture and use of novel electrolytic device.

In the present invention, the alternation of electric current and substance replace and the effect of the alternation and substance of electric current is formed by alternation work It is a kind of lasting course of work as process, is a kind of work normality, and its purpose is to eliminate non-electronic charged particle In the necessity of two interelectrode transmitting, to promote the science of electrolysis unit, and then promoted and scheme disclosed in this invention Service life, reliability, low cost and the efficiency of corresponding electrolysis unit.The principle and purpose and tradition of this electrolysis unit are fired The purpose of material battery is catalyst regeneration temporary exchange Oxidizing and Reducing Agents feed channel forms temporary polarity of electrode and becomes The principle and purpose of change has essential distinction, also and to prevent, weaken and the frequently pole-reversing electroosmosis of clearing electrode attachment Principle and purpose have essential distinction.

In the present invention, it is formed by that the capacitance the big more to be conducive to electrolysis anti-between the electrochemistry region and the region B Answer the promotion of density, therefore when carrying out cell reaction using scheme disclosed in this invention, should make the electrochemistry region and Capacitance between the region B increases as much as possible.

It, can be in the electrochemical school district in order to increase the capacitance between the electrochemistry region and the region B in the present invention Plasma, ionic liquid, ionized gas or solion are set between domain and the region B, and make ion in the electrification It is vibrated between school district domain and the region B, and/or vibrates in the electrochemistry areas adjacent and oscillated around in the region B, To realize the purpose for increasing the capacitance between the electrochemistry region and the region B.

In the present invention, it is more big more be conducive to electricity that the electrochemistry region A and the electrochemistry region B are formed by capacitance The promotion of reaction density is solved, therefore when carrying out cell reaction using scheme disclosed in this invention, the electrochemical school district should be made Capacitance between domain A and the electrochemistry region B increases as much as possible.

It, can be described in order to increase the capacitance between the electrochemistry region A and the electrochemistry region B in the present invention Plasma, ionic liquid, ionized gas or solion are set between electrochemistry region A and the electrochemistry region B, and made Ion vibrates between the electrochemistry region A and the electrochemistry region B, and/or oscillates around in the electrochemistry region A And oscillated around in the electrochemistry region B, to realize the electricity between increasing the electrochemistry region A and electrochemistry region B The purpose of capacity.

In the present invention, between the electrochemistry region and the region B and in the electrochemistry region A and the electrification It is more big more be conducive to the promotion of electrochemical reaction density that capacitance is formed by between the B of school district domain, therefore public using present invention institute When the scheme opened is electrochemically reacted, should make between the electrochemistry region and the region B and the electrochemistry region A and Capacitance between the electrochemistry region B increases as much as possible.

Electrolysis unit disclosed in this invention, it is negative there are electrolyte can be reduced in the case where electrolyte between two electrodes Lotus extends its service life and is conducive to the balance and stability operation of system.

In the present invention, reducing agent and oxidant is can be generated under electro ultrafiltration in the compound.

In the present invention, reducing agent and oxidant is can be generated through electro ultrafiltration in other materials presence in the compound.

In the present invention, the reducing agent is the substance for having reproducibility for the oxidant.

In the present invention, the oxidant is the substance for having oxidisability for the reducing agent.

In the present invention, electrochemistry region alternative selects one of the electrode for being set as electrochemical reaction or electrode Point, the region B alternative selection is set as the electrode of electrochemical reaction or a part of electrode, and the electrochemistry region A can Selectivity selection is set as the electrode of electrochemical reaction or a part of electrode, and the electrochemistry region B alternative selection is set as The electrode of electrochemical reaction or a part of electrode.

In the present invention, the electrochemistry region, which is selectively chosen, is set as three-diemsnional electrode.

In the present invention, the electrochemistry region A, which is selectively chosen, is set as three-diemsnional electrode.

In the present invention, the electrochemistry region B, which is selectively chosen, is set as three-diemsnional electrode.

In the present invention, such as refer to J feed channel for J and K as synonym, J feed channel and the setting of K regional connectivity Interior substance can contact the structural relation of setting with the region K.

In the present invention, such as using J and K as synonym, the region K is arranged in the cavity, and J feed channel is connected to the cavity The structural relation for referring to that the substance in J feed channel can contact setting with the region K is set.

In the present invention, such as there is non-electronic conducting electrical relation using Y and X as synonym, Y and X, the electronics of the Y is led The form of presentation imported out refers to that the Y, the X and electronics export import the composition that circuit three is same closed circuit Part is selectively chosen electronics export importing circuit being set as external circuit, and non-electronic conducting electrical relation is formed Circuit be set as interior circuit.

In the present invention, such as using U, W and V as synonym, U has non-electronic conducting electrical relation through W and V, and electronics is in institute The form of presentation for exporting importing between U and the V is stated, refers to that the U, the W, the V and electronics export import circuit It is the component part of same closed circuit, is selectively chosen and electronics export importing circuit is set as external circuit, and will be non- Electronic conduction electrical relation is formed by circuit and is set as interior circuit.

In the present invention, the area Jie electricity that so-called " area alternating current Jie electricity " refers to alternating current is selectively chosen and sets For a part of relative subject, also alternative selection is set as the conduction region contacted with relative subject, it is also an option that property select Select the conduction region for being set as that there is capacitance relation with relative subject.So-called relative subject be exactly A include the area alternating current Jie electricity this A in kind description.

In the present invention, so-called " alternating electromotive force " refers to that the changed electromotive force of electromotive force, such as direction become The changed electromotive force of electromotive force or size of change.

In the present invention, so-called " alternating current " refers to the changed electric current of electric current, such as the changed electricity in direction Stream, the changed electric current of size or alternating current.

In the present invention, so-called " alternating current " is selectively chosen the electric current for being set as the variation of electric current generating period, Such as electric current or alternating current that electric current, the size generating period of direction generating period variation change.

In the present invention, so-called alternating current refers to the alternating current changed by sinusoidal rule.

In the present invention, so-called AC power source refers to the alternating source that electric current is changed by sinusoidal rule.

In the present invention, there is so-called A and B non-electronic conducting electrical relation to refer to having on interior circuit between A and B Non-electronic conducting electrical relation, and its external circuit is selectively chosen electronic conduction relationship；Or, so-called A and B has non-electrical Son conducting electrical relation, which refers to, has non-electronic conducting electrical relation on external circuit between A and B, and its interior circuit may be selected Select electronic conduction relationship to property.

In the present invention, it is so-called " the electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, etc. At least one of gas ions, ionic liquid, ionized gas, solion and electronic conduction area have non-electrical with the region B Son conducting electrical relation " include the electrochemistry region and the region B through electronic conduction area, insulator, dielectric and/or from The non-electronic conducting electrical relation that two solion ponds of son conducting body isolation have.In this device, optionally select Selecting makes at least one in the electrochemistry region and the region B and capacitive region and/or non-electronic charged particle transmitter shape At electrical relation.

In the present invention, it is so-called " the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, At least one of plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemistry region B With non-electronic conducting electrical relation " it include the electrochemistry region A and the electrochemistry region B through electronic conduction area, insulation The non-electronic conducting electrical relation that two solion ponds of body, dielectric and/or ion conducting body isolation have.In this device In, be selectively chosen make at least one in the electrochemistry region A and the electrochemistry region B with capacitive region and/or Non-electronic charged particle transmitter forms electrical relation.

In the present invention, so-called " electronic conduction area " refers to that conduct electrons are not turned on the region of non-electronic charged particle, can Selectively selection is set as metallic conductor area, carbon conductor region etc..

In the present invention, so-called " non-electronic charged particle transmitter " refer to non-conducting electronics but proton conducting or it is specific from The substance of son, i.e. electrolyte in conventional electrochemical device, can be according to the electrochemical properties of the reducing agent and the oxidant Non-electronic charged particle transmitter is selected, such as when the reducing agent is H₂, the oxidant is O₂When, the non-electronic electrification Particle conduction object alternative selects proton exchange membrane.

In the present invention, select electronic conduction area shape when, should for the purpose of increasing its capacitance with neighbors into Row selection.

In this present invention, so-called " non-electronic conducting electrical relation " refers to the electricity formed through the charged particle other than electronics Conducting relationship is learned or the electricity to be formed conducting relationship of standing facing each other through electronics, for example, relationship, non-electronic band is connected in the electricity that capacitor is formed The electricity conducting relationship etc. that charged particle reciprocating vibration is formed.

In the present invention, so-called electrochemistry region, so-called region B, so-called electrochemistry region A, so-called electrochemistry Region B is equal with electrode.

In the present invention, the region that electronics export imports is equal with electrode.

It in the present invention, is selectively chosen, there is dielectric capacitance relationship between electrode.

In the present invention, it is selectively chosen, the electrochemistry region and the region B have dielectric capacitance relationship, Dielectric can be gas, liquid, solid or vacuum.

It in the present invention, is selectively chosen, the electrochemistry region A and the electrochemistry region B have dielectric capacitance Relationship, dielectric can be gas, liquid, solid or vacuum.

In the present invention, so-called dielectric capacitance relationship refers to the capacitance relation through dielectric formation, and dielectric can be Gas, liquid, solid or vacuum.

In the present invention, so-called " capacitor " be selectively chosen be set as electrolytic capacitor, super capacitor, electric double layer capacitance, All capacitors such as pseudo capacitance, fake capacitance.

The present invention in specific implementation, is selectively chosen using the electrochemistry region as an electrode, will be conductive Body is completed the conversion of chemical energy electric energy, is selectively chosen an electricity as another electrode, two electrode cooperatings Chemical regions are as an electrode, and using another described electrochemistry region as another electrode, two electrode cooperatings are completed The conversion of chemical energy electric energy.

In the present invention, so that charged particle is stored in the means in electrochemistry region as realizing, be selectively chosen and pass through The alternating of the contact of two kinds of metabolies and electric current that make electrochemistry region and participation electrochemical reaction changes to realize, also optional Select to selecting property to make that two kinds of substances for participating in electrochemical reaction alternately contacts with electrochemistry region and the alternating of electric current changes It realizes, however two electrodes of electrochemical reaction are (for example, the electrochemistry region and electric conductor, the electrochemistry region A and described Electrochemistry region B, the electrochemistry region and the region B) between the conducting of non-electronic charged particle then may exist It can be not present.

In the present invention, charged particle is set to be stored in the means in electrochemistry region as realizing, being selectively chosen makes electricity The mixture contact of two kinds of substances of chemical regions and participation electrochemical reaction and the alternating of electric current change to realize, may be selected Property select to make electrochemistry region and participate in the mixture makes discontinuous contact of two kinds of substances of electrochemical reaction and the alternating of electric current Variation is to realize, however two electrodes of electrochemical reaction are (for example, the electrochemistry region and electric conductor, the electrochemistry region A And the electrochemistry region B, the electrochemistry region and the region B) between the conducting of non-electronic charged particle then can be with In the presence of can also be not present.

In the present invention, so-called " electrolyte " refer to all be arranged between two electrode of electrochemical appliance only allow it is specific The substance that charged particle passes through but electronics is not allowed to pass through can be solid, liquid or membranous body etc., such as the proton of PEMFC Film and solid oxide electrolyte etc..

In the present invention, so-called " electrochemistry region " refers to that the region of electrochemical reaction can occurs in all, for example including Catalyst, ultra microstructure and/or region (such as electrode in fuel cell etc.) at a set temperature, then for example in setting temperature Metallic region under degree.

It is so-called to refer to " including catalyst, ultra microstructure and/or electrochemistry region at a set temperature " in the present invention The electrochemistry region or including catalyst or including ultra microstructure or under the set temperature or the electrification School district domain includes two or three in these three conditions.

In the present invention, so-called " ultra microstructure " refers to the microcosmic knot that can cause electrochemical reaction under setting condition Structure.

In the present invention, so-called " explosion limit " refers under conditions of the electrochemistry region, the reducing agent and institute State the concentration ratio that oxidant cannot explode.

In the present invention, include the catalyst scheme in, the catalyst be set as include noble metal catalyst, or The catalyst be set as include rare earth element catalyst.

In the present invention, so-called " non-electronic charged particle " refers to the charged particle other than electronics, such as proton or ion.

In the present invention, there is non-electronic electric conduction through electronic conduction area and the region B including the electrochemistry region In the scheme of relationship, one in the electrochemistry region and the region B passes through outside again through capacitor or through non-electronic conducting area Circuit and another electric communication, it is possible to realize that normality works.

It is non-electronic having including the electrochemistry region A through electronic conduction area and the electrochemistry region B in the present invention In the scheme that electrical relation is connected, one in the electrochemistry region A and the electrochemistry region B is through capacitor or through non-electronic Qu Zaijing external circuit and another electric communication is connected, it is possible to realize that normality works.

In the present invention, positive and negative non-electronic charged particle mixing is selectively chosen as non-electronic charged particle transmitter Object.

In the present invention, the non-electronic charged particle transmitter A and the non-electronic charged particle transmitter B are alternative Ground selection is set as same non-electronic charged particle transmitter, is also selectively chosen and is set as non-electronic charged particle not of the same race How on earth transmitter selects, and should be determined according to the conductance calls of corresponding non-electronic charged particle.

It is the electrochemistry region, the non-electronic charged particle transmitter, the electronic conduction area, described in the present invention When getting along near any the two in dielectric and the region B, at least one of neighbour the two got along is got along neighbour Locate have ultra microstructure to increase the neighbour area got along, and then increases capacitance.

It is the electrochemistry region A, the non-electronic charged particle transmitter, the electronic conduction area, described in the present invention When getting along near any the two in dielectric and the electrochemistry region B, at least one of neighbour the two got along than It is adjacent mutually to have ultra microstructure to increase the neighbour area got along everywhere, and then increase capacitance.

In the present invention, the non-electronic charged particle transmitter A and the non-electronic charged particle transmitter B can be identical It can also be different, but alternative when non-electronic charged particle transmitter A and non-electronic charged particle transmitter B are directly contacted Selection is different, such as non-electronic charged particle transmitter A is proton conductive object, non-electronic charged particle transmitter B be negative oxygen from Son conducting object.

In the present invention, so-called interpolar spacer refers to make to have required for non-electronic conducting electrical relation between electrode Substance (including vacuum), for example, electrolyte, dielectric etc..

In the present invention, the selection of interpolar spacer alternative is set as insulation, isolation space, electrolyte, dielectric, electricity At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area.

In the present invention, so-called interpolar spacer, which is selectively chosen, is set as interior circuit, is also selectively chosen and sets For external circuit.

In the present invention, so-called electro ultrafiltration is a kind of selectivity selection.

In the present invention, " the non-electronic charged particle " refers to the charged particle other than electronics, including proton and ion.

In the present invention, after a certain component names plus the letter such as so-called " A ", " B " is merely to distinguish two or several The identical component of title or substance.

In the present invention, necessary portion should be set in necessary place according to electricity field, the well-known technique of electrochemical field Part, unit or system etc..

Beneficial effects of the present invention are as follows: electrolysis unit disclosed in this invention will terminate traditional electrolyte device with electrolyte The history for existing for necessary condition, for efficiently, the exploitation of long-life, inexpensive electrolysis unit provide new approach.

Detailed description of the invention

Fig. 1 is the structural schematic diagram of the embodiment of the present invention 1；

Fig. 2 is the structural schematic diagram of the embodiment of the present invention 2；

Fig. 3 is the structural schematic diagram of the embodiment of the present invention 3；

Fig. 4 is the structural schematic diagram of the embodiment of the present invention 4；

Fig. 5 is the structural schematic diagram of the embodiment of the present invention 5；

Fig. 6 is the structural schematic diagram of the embodiment of the present invention 6；

Fig. 7 is the structural schematic diagram of the embodiment of the present invention 7；

Fig. 8 is the structural schematic diagram of the embodiment of the present invention 8；

Fig. 9 is the structural schematic diagram of the embodiment of the present invention 9；

Figure 10 is the structural schematic diagram of the embodiment of the present invention 10；

Figure 11 is the structural schematic diagram of the embodiment of the present invention 11；

In figure:

1 electrochemistry region, 11 electrochemistry region A, 2 region B, 21 electrochemistry region B, 3 compound feed channels, 4 electrolysis Product exports channel, 5 cavitys, 51 cavity A, 52 cavity B.

Specific embodiment

Technical solution of the present invention is further illustrated in the following with reference to the drawings and specific embodiments.

Embodiment 1

Electrolysis unit as shown in Figure 1, including electrochemistry region 1, the electrochemistry region 1 and compound feed channel 3 Connection setting, the electrochemistry region 1 include the area alternating current Jie electricity, and the electrochemistry region 1 exports channel 4 with electrolysate Connection setting.

As can embodiment in conversion, the electrochemistry region 1 and non-electronic band further can be selectively set Charged particle transmitter has non-electronic conducting electrical relation, or the electrochemistry region 1 is selectively arranged and successively leads with electronics Logical area and non-electronic charged particle transmitter have non-electronic conducting electrical relation, or the electrochemistry region is selectively arranged 1 has non-electronic conducting electrical relation with dielectric.

As can embodiment in conversion, further can selectively be arranged the electrochemistry region 1 and insulation, every In exhausted space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area At least one has non-electronic conducting electrical relation.

Embodiment 2

Electrolysis unit as shown in Figure 2, including electrochemistry region 1 and region B2, the electrochemistry region 1 are supplied with compound The connection setting of channel 3 is sent, the electrochemistry region 1 includes alternating current Jie electricity area A, and the region B2 includes that alternating current connects electricity Area B, the electrochemistry region 1 are connected to setting with electrolysate export channel 4.

As can embodiment in conversion, the electrochemistry region 1 further can be selectively set through non-electronic band Charged particle transmitter and region B2 have non-electronic conducting electrical relation, or the electrochemistry region 1 is selectively arranged successively There is non-electronic conducting electrical relation through electronic conduction area and non-electronic charged particle transmitter and region B2, or selectively set Setting the electrochemistry region 1 has non-electronic conducting electrical relation through dielectric and region B2.

As can embodiment in conversion, further can selectively be arranged the electrochemistry region 1 through insulation, every In exhausted space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area It is at least one that there is non-electronic conducting electrical relation with the region B2.

Embodiment 3

Electrolysis unit as shown in Figure 3, including electrochemistry region A11 and electrochemistry region B21, the electrochemistry region A11 is connected to setting with compound feed channel 3, and the electrochemistry region A11 includes alternating current Jie electricity area A, the electrochemistry Region B21 is connected to setting with compound feed channel 3, and the electrochemistry region B21 includes alternating current Jie electricity area B, the electricity Chemical regions A11 is connected to setting with electrolysate export channel 4, and the electrochemistry region B21 and electrolysate export channel 4 connect Logical setting.

As can embodiment in conversion, the electrochemistry region A11 further can be selectively set through non-electronic Charged particle transmitter and the electrochemistry region B21 have non-electronic conducting electrical relation, or the electricity is selectively arranged Chemical regions A11 successively has non-electrical through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B21 Son conducting electrical relation, or the electrochemistry region A11 is selectively set has through dielectric and the electrochemistry region B21 Non-electronic conducting electrical relation.

As can embodiment in conversion, further can selectively be arranged the electrochemistry region A11 through insulation, Completely cut off in space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area At least one with the electrochemistry region B21 have non-electronic conducting electrical relation.

Embodiment 4

Electrolysis unit as shown in Figure 4, including electrochemistry region A11 and electrochemistry region B21, the electrochemistry region The A11 and electrochemistry region B21 is connected to setting with compound feed channel 3, and the electrochemistry region A11 includes alternating current The area Jie electricity A, the electrochemistry region B21 include alternating current Jie electricity area B, and the electrochemistry region A11 and electrolysate export The connection setting of channel 4, the electrochemistry region B21 are connected to setting with electrolysate export channel 4.

Embodiment 5

Electrolysis unit as shown in Figure 5, including electrochemistry region A11 and electrochemistry region B21, the electrochemistry region The A11 and electrochemistry region B21 is connected to setting with compound feed channel 3, and the electrochemistry region A11 includes alternating current The area Jie electricity A, the electrochemistry region B21 include alternating current Jie electricity area B, the electrochemistry region A11 and the electrochemical school district Domain B21 is connected to setting with electrolysate export channel 4.

Embodiment 6

Electrolysis unit as shown in FIG. 6, including electrochemistry region 1, the electrochemistry region 1 is arranged in cavity 5, described Cavity 5 is connected to setting with compound feed channel 3, and the electrochemistry region 1 includes the area alternating current Jie electricity, the cavity 5 with Electrolysate exports the connection setting of channel 4.

Embodiment 7

Electrolysis unit as shown in Figure 7, including electrochemistry region 1 and region B2, the electrochemistry region 1 are arranged in cavity In 5, the cavity 5 is connected to setting with compound feed channel 3, and the electrochemistry region 1 includes alternating current Jie electricity area A, institute Stating region B2 includes alternating current Jie electricity area B, and the cavity 5 is connected to setting with electrolysate export channel 4.

Embodiment 8

Electrolysis unit as shown in Figure 8, including electrochemistry region A11 and electrochemistry region B21, the electrochemistry region A11 is arranged in cavity A51, and the cavity A51 is connected to setting with compound feed channel 3, and the electrochemistry region A11 includes Alternating current Jie electricity area A, the electrochemistry region B21 setting is in cavity B52, the cavity B52 and compound feed channel 3 Connection setting, the electrochemistry region B21 include alternating current Jie electricity area B, and the cavity A51 and electrolysate export channel 4 Connection setting, the cavity B52 are connected to setting with electrolysate export channel 4.

Embodiment 9

Electrolysis unit as shown in Figure 9, including electrochemistry region A11 and electrochemistry region B21, the electrochemistry region A11 is arranged in cavity A51, and the electrochemistry region B21 is arranged in cavity B52, the cavity A51 and the cavity B52 Setting is connected to compound feed channel 3, the electrochemistry region A11 includes alternating current Jie electricity area A, the electrochemistry region B21 includes alternating current Jie electricity area B, and the cavity A51 is connected to setting, the cavity B52 and electricity with electrolysate export channel 4 Solve the connection setting of product export channel 4.

Embodiment 10

Electrolysis unit as shown in Figure 10, including electrochemistry region A11 and electrochemistry region B21, the electrochemistry region A11 is arranged in cavity A51, and the electrochemistry region B21 is arranged in cavity B52, the cavity A51 and the cavity B52 Setting is connected to compound feed channel 3, the electrochemistry region A11 includes alternating current Jie electricity area A, the electrochemistry region B21, which includes alternating current Jie electricity area B, the cavity A51 and the cavity B52, is connected to setting with electrolysate export channel 4.

Embodiment 11

Electrolysis unit as shown in figure 11, including electrochemistry region A11 and electrochemistry region B21, the electrochemistry region The A11 and electrochemistry region B21 is arranged in cavity 5, and the cavity 5 is connected to setting, the electricity with compound feed channel 3 Chemical regions A11 includes alternating current Jie electricity area A, and the electrochemistry region B21 includes alternating current Jie electricity area B, the cavity 5 Setting is connected to electrolysate export channel 4.

As can embodiment in conversion, the above-mentioned all embodiments of the present invention and its convertible ground embodiment can be into The compound is selectively set as the compound in mixture by one step；Or, the compound is set as water, the reducing agent is Hydrogen, the oxidant are oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, it is described to go back Former agent is alcohol compound, and the oxidant is oxygen；Or, the compound is set as water, and water participates in jointly with carbon dioxide Reaction, the reducing agent are ether compound, and the oxidant is oxygen；Or, the compound is set as water, and water and dioxy Change carbon to participate in reacting jointly, the reducing agent is alkane derivative, and the oxidant is oxygen；Or, the compound is set For water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is alkenes compounds, and the oxidant is oxygen；Or, The compound is set as water, and water participates in reacting jointly with carbon dioxide, the reducing agent is alkynes compound, the oxygen Agent is oxygen.

As can embodiment in conversion, the above-mentioned all embodiments of the present invention and its convertible ground embodiment can be into It includes reducing agent export channel and oxidant export channel that electrolysate export channel 4, which is selectively arranged, in one step；

Or be further selectively arranged, electrolysate export channel 4 includes reducing agent export channel and oxidant Channel is exported, setting reducing agent switchs on reducing agent export channel, and oxidation is arranged on oxidant export channel Agent switch, the reducing agent switch and oxidant switch are controlled by control device and are alternately opened and closed；

Or be further selectively arranged, electrolysate export channel 4 includes reducing agent export channel and oxidant Channel is exported, setting reducing agent switchs on reducing agent export channel, and oxidation is arranged on oxidant export channel Agent switch, the reducing agent switch and oxidant switch are controlled by control device and are alternately opened and closed, the reducing agent The frequency and phase that switch and oxidant switch alternately open and close and the alternation electricity that the area alternating current Jie electricity is applied The frequency and phase of stream match；

Or be further selectively arranged, electrolysate export channel 4 is set as the molar ratio of Oxidizing and Reducing Agents Mixture exports channel.

As can embodiment in conversion, the above-mentioned all embodiments including the electrochemistry region 1 of the present invention and its Convertible ground embodiment, which can further selectively rotate the electrochemistry region 1, to be arranged.

As can embodiment in conversion, the present invention it is above-mentioned it is all include the electrochemistry region A11 and the electrification The embodiment and its convertible ground embodiment of school district domain B21 can further selectively turn the electrochemistry region A11 Dynamic setting, the electrochemistry region B21 rotation setting.

As disposable embodiment, the electrolysis unit in only electrochemistry region disclosed in this invention is being embodied When, being selectively chosen cooperates two electrodes using electric conductor as another electrode using electrochemistry region as an electrode The conversion of chemical energy electric energy is completed in work；It is also selectively chosen using electrochemistry region as an electrode, by another electrification As another electrode, two electrode cooperatings complete the conversion of chemical energy electric energy in school district domain.

Attached drawing of the invention is only a kind of signal, and any technical solution for meeting the application literature record belongs to the application Protection scope.

It is clear that the invention is not restricted to above embodiments, according to techniques known and technology disclosed in this invention Scheme, can derive or associate many variant schemes out, and all these variant schemes also are regarded as being protection model of the invention It encloses.

Claims

1. a kind of electrolysis unit, including electrochemistry region (1), it is characterised in that: the electrochemistry region (1) and compound feed Channel (3) connection setting, the electrochemistry region (1) includes the area alternating current Jie electricity, and the electrochemistry region (1) and electrolysis produce Object exports channel (4) connection setting；

Or, the electrochemistry region (1) is connected to setting with compound feed channel (3), the electrochemistry region (1) includes alternation The area electric current Jie electricity, the electrochemistry region (1) are connected to setting with electrolysate export channel (4)；The electrochemistry region (1) with Non-electronic charged particle transmitter have non-electronic conducting electrical relation or the electrochemistry region (1) successively with electronic conduction There is non-electronic conducting electrical relation or the electrochemistry region (1) and dielectric to have for area and non-electronic charged particle transmitter There is non-electronic conducting electrical relation；

Or, the electrochemistry region (1) is connected to setting with compound feed channel (3), the electrochemistry region (1) includes alternation The area electric current Jie electricity, the electrochemistry region (1) are connected to setting with electrolysate export channel (4)；The electrochemistry region (1) with Insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronics At least one of area, which is connected, has non-electronic conducting electrical relation.

2. a kind of electrolysis unit, including electrochemistry region (1) and region B (2), it is characterised in that: the electrochemistry region (1) with Compound feed channel (3) connection setting, the electrochemistry region (1) includes alternating current Jie electricity area A, region B (2) packet Alternating current Jie electricity area B is included, the electrochemistry region (1) is connected to setting with electrolysate export channel (4)；

Or, the electrochemistry region (1) is connected to setting with compound feed channel (3), the electrochemistry region (1) includes alternation Electric current Jie electricity area A, the region B (2) include alternating current Jie electricity area B, and the electrochemistry region (1) and electrolysate export are logical Road (4) connection setting；The electrochemistry region (1) has non-electronic conducting through non-electronic charged particle transmitter and region B (2) Electrical relation or the electrochemistry region (1) are successively through electronic conduction area and non-electronic charged particle transmitter and region B (2) There is non-electronic electric conduction through dielectric and region B (2) with non-electronic conducting electrical relation or the electrochemistry region (1) Relationship；

Or, the electrochemistry region (1) is connected to setting with compound feed channel (3), the electrochemistry region (1) includes alternation Electric current Jie electricity area A, the region B (2) include alternating current Jie electricity area B, and the electrochemistry region (1) and electrolysate export are logical Road (4) connection setting；The electrochemistry region (1) through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, At least one of ionic liquid, ionized gas, solion and electronic conduction area have non-electronic lead with the region B (2) Logical electrical relation.

3. a kind of electrolysis unit, including electrochemistry region A (11) and electrochemistry region B (21), it is characterised in that: the electrochemistry Region A (11) is connected to setting with compound feed channel (3), and the electrochemistry region A (11) includes alternating current Jie electricity area A, The electrochemistry region B (21) is connected to setting with compound feed channel (3), and the electrochemistry region B (21) includes alternation electricity The area Liu Jie electricity B, the electrochemistry region A (11) are connected to setting, the electrochemistry region B with electrolysate export channel (4) (21) setting is connected to electrolysate export channel (4)；

Or, the electrochemistry region A (11) is connected to setting with compound feed channel (3), the electrochemistry region A (11) includes Alternating current Jie electricity area A, the electrochemistry region B (21) are connected to setting, the electrochemistry region with compound feed channel (3) B (21) includes alternating current Jie electricity area B, and the electrochemistry region A (11) is connected to setting, institute with electrolysate export channel (4) It states electrochemistry region B (21) and is connected to setting with electrolysate export channel (4)；The electrochemistry region A (11) is through non-electronic band Charged particle transmitter and the electrochemistry region B (21) have non-electronic conducting electrical relation or the electrochemistry region A (11) Successively there is non-electronic conducting electricity through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B (21) Relationship or the electrochemistry region A (11) are closed through dielectric and the electrochemistry region B (21) with non-electronic conducting electricity System；

Or, the electrochemistry region A (11) is connected to setting with compound feed channel (3), the electrochemistry region A (11) includes Alternating current Jie electricity area A, the electrochemistry region B (21) are connected to setting, the electrochemistry region with compound feed channel (3) B (21) includes alternating current Jie electricity area B, and the electrochemistry region A (11) is connected to setting, institute with electrolysate export channel (4) It states electrochemistry region B (21) and is connected to setting with electrolysate export channel (4)；The electrochemistry region A (11) through insulation, every In exhausted space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area It is at least one that there is non-electronic conducting electrical relation with the electrochemistry region B (21).

4. a kind of electrolysis unit, including electrochemistry region A (11) and electrochemistry region B (21), it is characterised in that: the electrochemistry Region A (11) and the electrochemistry region B (21) is connected to setting, the electrochemistry region A (11) with compound feed channel (3) Including alternating current Jie electricity area A, the electrochemistry region B (21) includes alternating current Jie electricity area B, the electrochemistry region A (11) setting is connected to electrolysate export channel (4), the electrochemistry region B (21) and electrolysate export channel (4) are even Logical setting；Or, the electrochemistry region A (11) and the electrochemistry region B (21) are connected to compound feed channel (3) and set It sets, the electrochemistry region A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes that alternating current connects electricity Area B, the electrochemistry region A (11) are connected to setting, the electrochemistry region B (21) and electricity with electrolysate export channel (4) Solve product export channel (4) connection setting；The electrochemistry region A (11) is through non-electronic charged particle transmitter and the electrification School district domain B (21) has non-electronic conducting electrical relation or the electrochemistry region A (11) successively through electronic conduction area and non-electrical Subband charged particle transmitter and the electrochemistry region B (21) have non-electronic conducting electrical relation or the electrochemistry region A (11) there is non-electronic conducting electrical relation through dielectric and the electrochemistry region B (21)；

Or, the electrochemistry region A (11) and the electrochemistry region B (21) are connected to setting, institute with compound feed channel (3) Stating electrochemistry region A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes alternating current Jie electricity area B, The electrochemistry region A (11) is connected to setting with electrolysate export channel (4), and the electrochemistry region B (21) and electrolysis produce Object exports channel (4) connection setting；The electrochemistry region A (11) is through insulation, isolation space, electrolyte, dielectric, electricity At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemical school district Domain B (21) has non-electronic conducting electrical relation.

5. a kind of electrolysis unit, including electrochemistry region A (11) and electrochemistry region B (21), it is characterised in that: the electrochemistry Region A (11) and the electrochemistry region B (21) is connected to setting, the electrochemistry region A (11) with compound feed channel (3) Including alternating current Jie electricity area A, the electrochemistry region B (21) includes alternating current Jie electricity area B, the electrochemistry region A (11) channel (4) are exported with electrolysate and are connected to setting with the electrochemistry region B (21)；

Or, the electrochemistry region A (11) and the electrochemistry region B (21) are connected to setting, institute with compound feed channel (3) Stating electrochemistry region A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes alternating current Jie electricity area B, The electrochemistry region A (11) and the electrochemistry region B (21) export channel (4) with electrolysate and are connected to setting；The electricity Chemical regions A (11) is closed through non-electronic charged particle transmitter and the electrochemistry region B (21) with non-electronic conducting electricity System or the electrochemistry region A (11) are successively through electronic conduction area and non-electronic charged particle transmitter and the electrochemical school district Domain B (21) has non-electronic conducting electrical relation or the electrochemistry region A (11) through dielectric and the electrochemistry region B (21) there is non-electronic conducting electrical relation；

Or, the electrochemistry region A (11) and the electrochemistry region B (21) are connected to setting, institute with compound feed channel (3) Stating electrochemistry region A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes alternating current Jie electricity area B, The electrochemistry region A (11) and the electrochemistry region B (21) export channel (4) with electrolysate and are connected to setting；The electricity Chemical regions A (11) through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, At least one of solion and electronic conduction area have non-electronic conducting electrical relation with the electrochemistry region B (21).

6. a kind of electrolysis unit, including electrochemistry region (1), it is characterised in that: the electrochemistry region (1) is arranged in cavity (5) in, the cavity (5) is connected to setting with compound feed channel (3), and the electrochemistry region (1) includes that alternating current connects Electric area, the cavity (5) are connected to setting with electrolysate export channel (4)；

Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is connected to compound feed channel (3) to be set It sets, the electrochemistry region (1) includes the area alternating current Jie electricity, and the cavity (5) is connected to electrolysate export channel (4) and sets It sets；The electrochemistry region (1) and non-electronic charged particle transmitter have non-electronic conducting electrical relation or the electrochemistry Region (1) successively has non-electronic conducting electrical relation or the electricity with electronic conduction area and non-electronic charged particle transmitter Chemical regions (1) and dielectric have non-electronic conducting electrical relation；

Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is connected to compound feed channel (3) to be set It sets, the electrochemistry region (1) includes the area alternating current Jie electricity, and the cavity (5) is connected to electrolysate export channel (4) and sets It sets；The electrochemistry region (1) and insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, from At least one of sub- gas, solion and electronic conduction area have non-electronic conducting electrical relation.

7. a kind of electrolysis unit, including electrochemistry region (1) and region B (2), it is characterised in that: the electrochemistry region (1) sets It sets in cavity (5), the cavity (5) is connected to setting with compound feed channel (3), and the electrochemistry region (1) includes handing over Time-dependent current Jie electricity area A, the region B (2) include alternating current Jie electricity area B, and the cavity (5) and electrolysate export channel (4) connection setting；

Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is connected to compound feed channel (3) to be set It sets, the electrochemistry region (1) includes alternating current Jie electricity area A, and the region B (2) includes alternating current Jie electricity area B, described Cavity (5) is connected to setting with electrolysate export channel (4)；The electrochemistry region (1) is through non-electronic charged particle transmitter Have non-electronic conducting electrical relation or the electrochemistry region (1) successively through electronic conduction area and non-electronic with region B (2) Charged particle transmitter and region B (2) have non-electronic conducting electrical relation or the electrochemistry region (1) through dielectric with Region B (2) has non-electronic conducting electrical relation；

Or, electrochemistry region (1) setting is in cavity (5), the cavity (5) is connected to compound feed channel (3) to be set It sets, the electrochemistry region (1) includes alternating current Jie electricity area A, and the region B (2) includes alternating current Jie electricity area B, described Cavity (5) is connected to setting with electrolysate export channel (4)；The electrochemistry region (1) is through insulation, isolation space, electrolysis At least one of matter, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area with The region B (2) has non-electronic conducting electrical relation.

8. a kind of electrolysis unit, including electrochemistry region A (11) and electrochemistry region B (21), it is characterised in that: the electrochemistry In cavity A (51), the cavity A (51) is connected to setting, the electrification with compound feed channel (3) for region A (11) setting School district domain A (11) includes alternating current Jie electricity area A, and electrochemistry region B (21) setting is in cavity B (52), the cavity B (52) setting is connected to compound feed channel (3), the electrochemistry region B (21) includes alternating current Jie electricity area B, the chamber Body A (51) is connected to setting with electrolysate export channel (4), and the cavity B (52) is connected to electrolysate export channel (4) and sets It sets；

Or, electrochemistry region A (11) setting is interior in cavity A (51), the cavity A (51) and compound feed channel (3) Connection setting, the electrochemistry region A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) is arranged in cavity In B (52), the cavity B (52) is connected to setting with compound feed channel (3), and the electrochemistry region B (21) includes alternation Electric current Jie electricity area B, the cavity A (51) are connected to setting with electrolysate export channel (4), and the cavity B (52) and electrolysis produce Object exports channel (4) connection setting；The electrochemistry region A (11) is through non-electronic charged particle transmitter and the electrochemical school district Domain B (21) has non-electronic conducting electrical relation or the electrochemistry region A (11) successively through electronic conduction area and non-electronic band Charged particle transmitter and the electrochemistry region B (21) have non-electronic conducting electrical relation or the electrochemistry region A (11) There is non-electronic conducting electrical relation through dielectric and the electrochemistry region B (21)；

Or, electrochemistry region A (11) setting is interior in cavity A (51), the cavity A (51) and compound feed channel (3) Connection setting, the electrochemistry region A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) is arranged in cavity In B (52), the cavity B (52) is connected to setting with compound feed channel (3), and the electrochemistry region B (21) includes alternation Electric current Jie electricity area B, the cavity A (51) are connected to setting with electrolysate export channel (4), and the cavity B (52) and electrolysis produce Object exports channel (4) connection setting；The electrochemistry region A (11) is through insulation, isolation space, electrolyte, dielectric, electricity At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemical school district Domain B (21) has non-electronic conducting electrical relation.

9. a kind of electrolysis unit, including electrochemistry region A (11) and electrochemistry region B (21), it is characterised in that: the electrochemistry Region A (11) setting is in cavity A (51), and electrochemistry region B (21) setting is in cavity B (52), the cavity A (51) Setting is connected to compound feed channel (3) with the cavity B (52), the electrochemistry region A (11) includes that alternating current connects Electric area A, the electrochemistry region B (21) include alternating current Jie electricity area B, and the cavity A (51) and electrolysate export channel (4) connection setting, the cavity B (52) are connected to setting with electrolysate export channel (4)；

Or, electrochemistry region A (11) setting is in cavity A (51), the electrochemistry region B (21) is arranged in cavity B (52) in, the cavity A (51) and the cavity B (52) are connected to setting, the electrochemistry region with compound feed channel (3) A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes alternating current Jie electricity area B, the cavity A (51) Setting is connected to electrolysate export channel (4), the cavity B (52) is connected to setting with electrolysate export channel (4)；It is described Electrochemistry region A (11) has non-electronic conducting electricity through non-electronic charged particle transmitter and the electrochemistry region B (21) Relationship or the electrochemistry region A (11) are successively through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry Region B (21) has non-electronic conducting electrical relation or the electrochemistry region A (11) through dielectric and the electrochemistry region B (21) has non-electronic conducting electrical relation；

Or, electrochemistry region A (11) setting is in cavity A (51), the electrochemistry region B (21) is arranged in cavity B (52) in, the cavity A (51) and the cavity B (52) are connected to setting, the electrochemistry region with compound feed channel (3) A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes alternating current Jie electricity area B, the cavity A (51) Setting is connected to electrolysate export channel (4), the cavity B (52) is connected to setting with electrolysate export channel (4)；It is described Electrochemistry region A (11) is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion-gas At least one of body, solion and electronic conduction area are closed with the electrochemistry region B (21) with non-electronic conducting electricity System.

10. a kind of electrolysis unit, including electrochemistry region A (11) and electrochemistry region B (21), it is characterised in that: the electrification School district domain A (11) setting is in cavity A (51), and electrochemistry region B (21) setting is in cavity B (52), the cavity A (51) and the cavity B (52) is connected to setting with compound feed channel (3), and the electrochemistry region A (11) includes alternation electricity The area Liu Jie electricity A, the electrochemistry region B (21) include alternating current Jie electricity area B, the cavity A (51) and the cavity B (52) Setting is connected to electrolysate export channel (4)；

Or, electrochemistry region A (11) setting is in cavity A (51), the electrochemistry region B (21) is arranged in cavity B (52) in, the cavity A (51) and the cavity B (52) are connected to setting, the electrochemistry region with compound feed channel (3) A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes alternating current Jie electricity area B, the cavity A (51) Setting is connected to the cavity B (52) with electrolysate export channel (4)；The electrochemistry region A (11) is through non-electronic electrification Particle conduction object and the electrochemistry region B (21) have non-electronic conducting electrical relation or the electrochemistry region A (11) according to It is secondary to be closed through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B (21) with non-electronic conducting electricity System or the electrochemistry region A (11) have non-electronic conducting electrical relation through dielectric and the electrochemistry region B (21)；

Or, electrochemistry region A (11) setting is in cavity A (51), the electrochemistry region B (21) is arranged in cavity B (52) in, the cavity A (51) and the cavity B (52) are connected to setting, the electrochemistry region with compound feed channel (3) A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes alternating current Jie electricity area B, the cavity A (51) Setting is connected to the cavity B (52) with electrolysate export channel (4)；The electrochemistry region A (11) is through insulation, isolation In space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area extremely A kind of few and electrochemistry region B (21) has non-electronic conducting electrical relation.

11. a kind of electrolysis unit, including electrochemistry region A (11) and electrochemistry region B (21), it is characterised in that: the electrification School district domain A (11) and the electrochemistry region B (21) setting is in cavity (5), the cavity (5) and compound feed channel (3) connection setting, the electrochemistry region A (11) includes alternating current Jie electricity area A, and the electrochemistry region B (21) includes handing over Time-dependent current Jie electricity area B, the cavity (5) are connected to setting with electrolysate export channel (4)；

Or, the electrochemistry region A (11) and the electrochemistry region B (21) setting be in the cavity (5), the cavity (5) with Compound feed channel (3) connection setting, the electrochemistry region A (11) includes alternating current Jie electricity area A, the electrification school district Domain B (21) includes alternating current Jie electricity area B, and the cavity (5) is connected to setting with electrolysate export channel (4)；The electrification School district domain A (11) has non-electronic conducting electrical relation through non-electronic charged particle transmitter and the electrochemistry region B (21), Or the electrochemistry region A (11) is successively through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B (21) have non-electronic conducting electrical relation or the electrochemistry region A (11) through dielectric and the electrochemistry region B (21) With non-electronic conducting electrical relation；

Or, the electrochemistry region A (11) and the electrochemistry region B (21) setting be in the cavity (5), the cavity (5) with Compound feed channel (3) connection setting, the electrochemistry region A (11) includes alternating current Jie electricity area A, the electrification school district Domain B (21) includes alternating current Jie electricity area B, and the cavity (5) is connected to setting with electrolysate export channel (4)；The electrification School district domain A (11) through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, from At least one of sub- solution and electronic conduction area have non-electronic conducting electrical relation with the electrochemistry region B (21).

12. the electrolysis unit as described in any one of claims 1 to 11, it is characterised in that: the compound is set as in mixture Compound；Or, the compound is set as water, the reducing agent is hydrogen, and the oxidant is oxygen；Or, the compound It is set as water, and water participates in reacting jointly with carbon dioxide, the reducing agent is alcohol compound, and the oxidant is oxygen；Or, The compound is set as water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is ether compound, the oxidant For oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, and the reducing agent is alkanes chemical combination Object, the oxidant are oxygen；Or, the compound is set as water, and water participates in reacting jointly with carbon dioxide, the reducing agent For alkenes compounds, the oxidant is oxygen；Or, the compound is set as water, and water and carbon dioxide participate in instead jointly It answers, the reducing agent is alkynes compound, and the oxidant is oxygen.

13. the electrolysis unit as described in any one of claims 1 to 11, it is characterised in that: the electrolysate exports channel (4) Channel is exported including reducing agent and oxidant exports channel；

Or, electrolysate export channel (4) includes reducing agent export channel and oxidant export channel, in the reducing agent It exports setting reducing agent on channel to switch, setting oxidant switchs on oxidant export channel, the reducing agent switch It is controlled with oxidant switch by control device and is alternately opened and closed；

Or, electrolysate export channel (4) includes reducing agent export channel and oxidant export channel, in the reducing agent It exports setting reducing agent on channel to switch, setting oxidant switchs on oxidant export channel, the reducing agent switch It is controlled with oxidant switch by control device and is alternately opened and closed, the reducing agent switch and oxidant switch are handed over Match for the frequency and phase of open and close with the frequency of alternating current and phase applied to the area alternating current Jie electricity；

Or, electrolysate export channel (4) is set as the molar mixture export channel of Oxidizing and Reducing Agents.

14. electrolysis unit as claimed in claim 12, it is characterised in that: electrolysate export channel (4) includes reducing agent It exports channel and oxidant exports channel；

15. the electrolysis unit as described in any one of claim 1 to 11 and 14, it is characterised in that: the electrochemistry region (1) turns Dynamic setting；Or, in the device for including the electrochemistry region A (11) and the electrochemistry region B (21), the electrification school district Domain A (11) rotation setting, electrochemistry region B (21) the rotation setting.

16. electrolysis unit as claimed in claim 12, it is characterised in that: electrochemistry region (1) the rotation setting；Or, wrapping In the device for including the electrochemistry region A (11) and the electrochemistry region B (21), electrochemistry region A (11) rotation is set It sets, electrochemistry region B (21) the rotation setting.

17. electrolysis unit as claimed in claim 13, it is characterised in that: electrochemistry region (1) the rotation setting；Or, wrapping In the device for including the electrochemistry region A (11) and the electrochemistry region B (21), electrochemistry region A (11) rotation is set It sets, electrochemistry region B (21) the rotation setting.