CN109536983A - A kind of electrochemical method for synthesizing - Google Patents

A kind of electrochemical method for synthesizing Download PDF

Info

Publication number
CN109536983A
CN109536983A CN201910107799.7A CN201910107799A CN109536983A CN 109536983 A CN109536983 A CN 109536983A CN 201910107799 A CN201910107799 A CN 201910107799A CN 109536983 A CN109536983 A CN 109536983A
Authority
CN
China
Prior art keywords
substance
electrochemistry region
region
electrochemistry
make
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910107799.7A
Other languages
Chinese (zh)
Inventor
靳北彪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Entropy Zero Technology Logic Engineering Group Co Ltd
Original Assignee
Entropy Zero Technology Logic Engineering Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Entropy Zero Technology Logic Engineering Group Co Ltd filed Critical Entropy Zero Technology Logic Engineering Group Co Ltd
Publication of CN109536983A publication Critical patent/CN109536983A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00Electrolytic production of organic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)

Abstract

The invention discloses a kind of electrochemical method for synthesizing, electrochemistry region is set alternately to contact or make substance A and substance B alternately to contact with electrochemistry region with substance A and substance B, so that the substance A is generated positive charged particle and electronics in the electrochemistry region, exports the electronics in the electrochemistry region and import.Electrochemical method for synthesizing disclosed in this invention will terminate Conventional electrochemical synthetic method and electrochemistry formated device to the history of electrolyte demand, provide new approach for efficient, long-life, Low-cost electric chemical synthesizer exploitation.

Description

A kind of electrochemical method for synthesizing
Technical field
The present invention relates to electricity field, electrochemical field more particularly to a kind of electrochemical method for synthesizing.
Background technique
Electrochemical method for synthesizing is using very extensive, but all electrochemical method for synthesizing so far are between electrode Transmitting non-electronic charged particle (such as proton, negative oxygen ion etc.) is necessary condition, means that so far all in this way Non-electronic band electrochondria is connected to use the electrolyte that non-electronic charged particle is connected as necessary condition in electrochemical method for synthesizing The electrolyte of son not only manufactures difficulty, using difficulty, but also will be greatly reduced electrolytic efficiency.If one kind can be invented not with electricity The electrochemical method for synthesizing for existing for necessary condition of solution matter will be of great significance.Therefore, it is necessary to invent a kind of novel electrochemical Learn synthetic method.
Summary of the invention
To solve the above-mentioned problems, technical solution proposed by the present invention is as follows:
Scheme 1: a kind of electrochemical method for synthesizing makes electrochemistry region alternately contact or make substance A with substance A and substance B Alternately contacted with substance B and electrochemistry region, or so that electrochemistry region and substance A is contacted with each other and make the electrochemistry region with The mutual makes discontinuous contact of substance B, or so that electrochemistry region is contacted with each other with substance B and keep the electrochemistry region and substance A mutual Makes discontinuous contact makes the substance A generate positive charged particle and electronics in the electrochemistry region, makes the electricity in the electrochemistry region Son export imports.
Scheme 2: a kind of electrochemical method for synthesizing makes electrochemistry region alternately contact or make substance A with substance A and substance B Alternately contacted with substance B and electrochemistry region, or so that electrochemistry region and substance A is contacted with each other and make the electrochemistry region with The mutual makes discontinuous contact of substance B, or so that electrochemistry region is contacted with each other with substance B and keep the electrochemistry region and substance A mutual Makes discontinuous contact makes the substance A generate positive charged particle and electronics in the electrochemistry region, makes electronics in the electrochemical school district It exports and imports between domain and region B;
Or, electrochemistry region is made alternately to contact or make substance A and substance B to replace with electrochemistry region with substance A and substance B Contact, or so that electrochemistry region and substance A is contacted with each other and is made the electrochemistry region and the mutual makes discontinuous contact of substance B, or make Electrochemistry region and substance B contact with each other and make the electrochemistry region and the mutual makes discontinuous contact of substance A, the substance A to be made to exist The electrochemistry region generates positive charged particle and electronics, and electronics is made to export importing between the electrochemistry region and region B, The electrochemistry region is correspondingly arranged with the region B;
Or, electrochemistry region is made alternately to contact or make substance A and substance B to replace with electrochemistry region with substance A and substance B Contact, or so that electrochemistry region and substance A is contacted with each other and is made the electrochemistry region and the mutual makes discontinuous contact of substance B, or make Electrochemistry region and substance B contact with each other and make the electrochemistry region and the mutual makes discontinuous contact of substance A, the substance A to be made to exist The electrochemistry region generates positive charged particle and electronics, and electronics is made to export importing between the electrochemistry region and region B; The electrochemistry region and the region B have non-electronic conducting electrical relation, or, the electrochemistry region through insulation, every In exhausted space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area It is at least one that there is non-electronic conducting electrical relation with the region B.
Scheme 3: a kind of electrochemical method for synthesizing makes electrochemistry region A alternately contact or make substance A with substance A and substance B Alternately contacted with substance B and electrochemistry region A and make electrochemistry region B replace with the substance B and the substance A contact or It contacts substance B and substance A alternately with electrochemistry region B, or electrochemistry region A and substance A is made to contact with each other and make the electricity Chemical regions A and the mutual makes discontinuous contact of substance B and so that electrochemistry region B and substance A is contacted with each other and make the electrochemical school district Domain B and the mutual makes discontinuous contact of substance B, or electrochemistry region A and substance B is made to contact with each other and make the electrochemistry region A and object The mutual makes discontinuous contact of matter A and so that electrochemistry region B is contacted with each other with substance B and keep the electrochemistry region B and substance A mutual Makes discontinuous contact, or electrochemistry region A and substance B is made to contact with each other and make the electrochemistry region A and the mutual makes discontinuous contact of substance A And electrochemistry region B and substance A is made to contact with each other and make the electrochemistry region B and the mutual makes discontinuous contact of substance B, make described Substance A generates positive charged particle and electronics in the electrochemistry region A, generates the substance A just in the electrochemistry region B Charged particle and electronics make electronics export importing between the electrochemistry region A and the electrochemistry region B;
Or, electrochemistry region A is made alternately to contact or make substance A and substance B and electrochemistry region A to hand over substance A and substance B Substance B and substance A and electrochemistry are contacted or made for contacting and replacing electrochemistry region B with the substance B and the substance A Region B is alternately contacted, or so that electrochemistry region A and substance A is contacted with each other and kept the electrochemistry region A and substance B mutually disconnected Continued access is touched and is made electrochemistry region B and substance A to contact with each other and makes the electrochemistry region B and the mutual makes discontinuous contact of substance B, Or so that electrochemistry region A and substance B is contacted with each other and make the electrochemistry region A and the mutual makes discontinuous contact of substance A and make electricity Chemical regions B and substance B contact with each other and make the electrochemistry region B and the mutual makes discontinuous contact of substance A, or make electrochemistry region A and substance B contact with each other and make the electrochemistry region A and the mutual makes discontinuous contact of substance A and make electrochemistry region B and substance A contacts with each other and makes the electrochemistry region B and the mutual makes discontinuous contact of substance B, makes the substance A in the electrochemistry region A Positive charged particle and electronics are generated, so that the substance A is generated positive charged particle and electronics in the electrochemistry region B, makes electronics It exports and imports between the electrochemistry region A and the electrochemistry region B, the electrochemistry region A and the electrochemical school district Domain B is correspondingly arranged;
Or, electrochemistry region A is made alternately to contact or make substance A and substance B and electrochemistry region A to hand over substance A and substance B Substance B and substance A and electrochemistry are contacted or made for contacting and replacing electrochemistry region B with the substance B and the substance A Region B is alternately contacted, or so that electrochemistry region A and substance A is contacted with each other and kept the electrochemistry region A and substance B mutually disconnected Continued access is touched and is made electrochemistry region B and substance A to contact with each other and makes the electrochemistry region B and the mutual makes discontinuous contact of substance B, Or so that electrochemistry region A and substance B is contacted with each other and make the electrochemistry region A and the mutual makes discontinuous contact of substance A and make electricity Chemical regions B and substance B contact with each other and make the electrochemistry region B and the mutual makes discontinuous contact of substance A, or make electrochemistry region A and substance B contact with each other and make the electrochemistry region A and the mutual makes discontinuous contact of substance A and make electrochemistry region B and substance A contacts with each other and makes the electrochemistry region B and the mutual makes discontinuous contact of substance B, makes the substance A in the electrochemistry region A Positive charged particle and electronics are generated, so that the substance A is generated positive charged particle and electronics in the electrochemistry region B, makes electronics It exports and imports between the electrochemistry region A and the electrochemistry region B;The electrochemistry region A and the electrochemical school district Domain B have non-electronic conducting electrical relation, or, the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, At least one of capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemistry Region B has non-electronic conducting electrical relation.
Scheme 4: a kind of electrochemical method for synthesizing makes electrochemistry region that object is contacted or made with the mixture of substance A and substance B The mixture of matter A and substance B is contacted with electrochemistry region, and the substance A is made to generate positive charged particle in the electrochemistry region And electronics, it exports the electronics in the electrochemistry region and imports;
Or, making the mixture makes discontinuous contact of electrochemistry region and substance A and substance B or making the mixture of substance A and substance B With electrochemistry region makes discontinuous contact, so that the substance A is generated positive charged particle and electronics in the electrochemistry region, make the electricity The electronics of chemical regions, which exports, to be imported.
Scheme 5: a kind of electrochemical method for synthesizing makes electrochemistry region that object is contacted or made with the mixture of substance A and substance B The mixture of matter A and substance B is contacted with electrochemistry region, and the substance A is made to generate positive charged particle in the electrochemistry region And electronics, so that electronics is exported importing between the electrochemistry region and region B;
Or, making the mixture makes discontinuous contact of electrochemistry region and substance A and substance B or making the mixture of substance A and substance B With electrochemistry region makes discontinuous contact, so that the substance A is generated positive charged particle and electronics in the electrochemistry region, electronics is made to exist It exports and imports between the electrochemistry region and region B;
Or, making electrochemistry region that the mixture of substance A and substance B and electricity are contacted or made with the mixture of substance A and substance B Chemical regions contact, makes the substance A generate positive charged particle and electronics in the electrochemistry region, makes electronics in the electrification It exports and imports between school district domain and region B, the electrochemistry region and the region B are correspondingly arranged;
Or, making the mixture makes discontinuous contact of electrochemistry region and substance A and substance B or making the mixture of substance A and substance B With electrochemistry region makes discontinuous contact, so that the substance A is generated positive charged particle and electronics in the electrochemistry region, electronics is made to exist It exports and imports between the electrochemistry region and region B, the electrochemistry region and the region B are correspondingly arranged;
Or, making electrochemistry region that the mixture of substance A and substance B and electricity are contacted or made with the mixture of substance A and substance B Chemical regions contact, makes the substance A generate positive charged particle and electronics in the electrochemistry region, makes electronics in the electrification It exports and imports between school district domain and region B;The electrochemistry region and the region B have non-electronic conducting electrical relation, or, The electrochemistry region is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion-gas At least one of body, solion and electronic conduction area have non-electronic conducting electrical relation with the region B;
Or, making the mixture makes discontinuous contact of electrochemistry region and substance A and substance B or making the mixture of substance A and substance B With electrochemistry region makes discontinuous contact, so that the substance A is generated positive charged particle and electronics in the electrochemistry region, electronics is made to exist It exports and imports between the electrochemistry region and region B;The electrochemistry region and the region B have non-electronic conducting electricity Relationship, or, the electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, At least one of ionized gas, solion and electronic conduction area have non-electronic conducting electrical relation with the region B.
Scheme 6: a kind of electrochemical method for synthesizing makes electrochemistry region A contact or make with the mixture of substance A and substance B The mixture of substance A and substance B is contacted with electrochemistry region A, contacts electrochemistry region B and the mixture of substance A and substance B Or contact the mixture of substance A and substance B with electrochemistry region B, generate the substance A just in the electrochemistry region A Charged particle and electronics make the substance A generate positive charged particle and electronics in the electrochemistry region B, make electronics described It exports and imports between electrochemistry region A and the electrochemistry region B;
Or, make electrochemistry region A contact or make with the mixture of substance A and substance B the mixture of substance A and substance B with Electrochemistry region A contact, makes electrochemistry region B that the mixing of substance A and substance B is contacted or made with the mixture of substance A and substance B Object is contacted with electrochemistry region B, so that the substance A is generated positive charged particle and electronics in the electrochemistry region A, is made the object Matter A generates positive charged particle and electronics in the electrochemistry region B, makes electronics in the electrochemistry region A and the electrochemistry It exports and imports between the B of region, the electrochemistry region A is correspondingly arranged with the electrochemistry region B;
Or, make electrochemistry region A contact or make with the mixture of substance A and substance B the mixture of substance A and substance B with Electrochemistry region A contact, makes electrochemistry region B that the mixing of substance A and substance B is contacted or made with the mixture of substance A and substance B Object is contacted with electrochemistry region B, so that the substance A is generated positive charged particle and electronics in the electrochemistry region A, is made the object Matter A generates positive charged particle and electronics in the electrochemistry region B, makes electronics in the electrochemistry region A and the electrochemistry It exports and imports between the B of region;The electrochemistry region A and electrochemistry region B has non-electronic conducting electrical relation, or, The electrochemistry region A is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion-gas At least one of body, solion and electronic conduction area have non-electronic conducting electrical relation with the electrochemistry region B;
Or, making the mixture makes discontinuous contact of electrochemistry region A and substance A and substance B or making the mixing of substance A and substance B Object and electrochemistry region A makes discontinuous contact make the mixture makes discontinuous contact of electrochemistry region B and substance A and substance B or make substance A With the mixture and electrochemistry region B makes discontinuous contact of substance B, the substance A is made to generate just band electrochondria in the electrochemistry region A Son and electronics make the substance A generate positive charged particle and electronics in the electrochemistry region B, make electronics in the electrochemistry It exports and imports between region A and the electrochemistry region B;
Or, making the mixture makes discontinuous contact of electrochemistry region A and substance A and substance B or making the mixing of substance A and substance B Object and electrochemistry region A makes discontinuous contact make the mixture makes discontinuous contact of electrochemistry region B and substance A and substance B or make substance A With the mixture and electrochemistry region B makes discontinuous contact of substance B, the substance A is made to generate just band electrochondria in the electrochemistry region A Son and electronics make the substance A generate positive charged particle and electronics in the electrochemistry region B, make electronics in the electrochemistry It exports and imports between region A and the electrochemistry region B, the electrochemistry region A is correspondingly arranged with the electrochemistry region B;
Or, making the mixture makes discontinuous contact of electrochemistry region A and substance A and substance B or making the mixing of substance A and substance B Object and electrochemistry region A makes discontinuous contact make the mixture makes discontinuous contact of electrochemistry region B and substance A and substance B or make substance A With the mixture and electrochemistry region B makes discontinuous contact of substance B;The substance A is set to generate just band electrochondria in the electrochemistry region A Son and electronics make the substance A generate positive charged particle and electronics in the electrochemistry region B, make electronics in the electrochemistry It exports and imports between region A and the electrochemistry region B;The electrochemistry region A and electrochemistry region B has non-electronic Be connected electrical relation, or, the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, At least one of ionic liquid, ionized gas, solion and electronic conduction area have non-electronic with the electrochemistry region B Electrical relation is connected.
The aforementioned all schemes of the present invention optionally use alternating source during electronics is exported and imported.
The aforementioned all schemes of the present invention further can selectively select the export for making electronics to import as work normality.
The aforementioned all schemes of the present invention further can selectively select that the substance A is made to be set as hydrogen, the substance B It is set as carbon;Or the substance A is made to be set as hydrogen, the substance B is set as carbon, and makes the product first of the electrochemical method for synthesizing Alkane, ethane, propane are octane.
The aforementioned all schemes containing the electrochemistry region of the present invention further can selectively select to make the electricity Chemical regions rotation setting.
The aforementioned all schemes containing the electrochemistry region A and the electrochemistry region B of the present invention can be selected further It selects to selecting property to make the electrochemistry region A rotation setting, and makes the electrochemistry region B rotation setting.
In the present invention, the substance A and substance B reaction generate the substance A and the substance B reaction product Process is to absorb the process of energy.
In the present invention, it is work normality that the export of the electronics in the electrochemistry region, which imports,.
In the present invention, it is that work is normal that export of the electronics between the electrochemistry region A and the electrochemistry region B, which imports, State.
In the present invention, it is work normality that export of the electronics between the electrochemistry region and the region B, which imports,.
In the present invention, so-called " it is work normality that the export of the electronics in the electrochemistry region, which imports, " refers to from the electricity It is to continue working process that chemical regions, which export electronics and import electronics to the electrochemistry region, i.e., electrification disclosed in this invention Synthetic method is learned in working condition, exporting electronics from the electrochemistry region and import electronics to the electrochemistry region is one The lasting process of kind.In other words, corresponding and described electrochemistry region and alternation are electric with alternating current in the electrochemistry region Stream is opposite to should be the process of continuing working.
In the present invention, it is work normality that the export of the electronics between the electrochemistry region and the region B, which imports,.
In the present invention, so-called " it is that work is normal that the export of the electronics between the electrochemistry region and the region B, which imports, State " refers to export of the electronics from the electrochemistry region to the region B and electronics from the region B to the electrochemistry region It imports to continue working process, i.e., electrochemical method for synthesizing disclosed in this invention is in working condition, from the electrochemical school district Domain exports electronics, the region Xiang Suoshu B imports electronics, electronics is exported from the region B and imports electronics to the electrochemistry region For a kind of lasting process.In other words, the electrochemistry region and the region B electrification corresponding and described with alternating current The school district domain and region B is opposite with alternating current should be the process of continuing working.
In the present invention, it is that work is normal that the export of the electronics between the electrochemistry region A and the electrochemistry region B, which imports, State.
In the present invention, so-called " export of the electronics between the electrochemistry region A and the electrochemistry region B is imported For the normality that works " refer to electronics from the electrochemistry region A to the electrochemistry region B and electronics from the electrochemistry region B It is imported to the export of the electrochemistry region A to continue working process, i.e., electrochemical method for synthesizing disclosed in this invention is in work When making state, electronics is imported, from the electrochemistry region from electrochemistry region A export electronics, Xiang Suoshu electrochemistry region B It is a kind of lasting process that B, which exports electronics and imports electronics to the electrochemistry region A,.In other words, the electrochemistry region A With the electrochemistry region B with alternating current the corresponding and described electrochemistry region A and electrochemistry region B and alternating current It is opposite to should be the process of continuing working.
In the present invention, disclosed method is the chemical energy electric energy conversion method at single electrode, in specific implementation, optional It selects to selecting property using the electrochemistry region as an electrode, using electric conductor as another electrode, two electrode cooperatings, The conversion of chemical energy electric energy is completed, is selectively chosen using an electrochemistry region as an electrode, by another institute Electrochemistry region is stated as another electrode, two electrode cooperatings complete the conversion of chemical energy electric energy.
In the present invention, disclosed a part of method, which is selectively chosen, serves as manufacture half electrochemical appliance (i.e. electricity Include the device region of an electrode in chemical devices), it is also selectively chosen and serves as manufacture electrochemical appliance.
In the present invention, disclosed method, which is selectively chosen, serves as manufacture half electrochemistry formated device (i.e. electrification Include the device region of an electrode in method), it is also selectively chosen and serves as manufacture electrochemistry formated device.
In the present invention, there is non-electronic electric conduction through electronic conduction area and the region B including the electrochemistry region In the method for relationship, be selectively chosen make one in the electrochemistry region and the region B through capacitor or through non- Electronic conduction area (such as the electrolyte such as proton exchange membrane) is again through external circuit and another electric communication, it is possible to realize normality Work.
It is non-electronic having including the electrochemistry region A through electronic conduction area and the electrochemistry region B in the present invention In the method that electrical relation is connected, it is selectively chosen one made in the electrochemistry region A and the electrochemistry region B Through capacitor or through non-electronic conducting area (such as the electrolyte such as proton exchange membrane) again through external circuit and another electric communication, so Normality work may be implemented.
In the present invention, so that charged particle is stored in the means in electrochemistry region as realizing, be selectively chosen and pass through The alternating of the contact of two kinds of metabolies and electric current that make electrochemistry region and participation electrochemical reaction changes to realize, also optional Select to selecting property to make that two kinds of substances for participating in electrochemical reaction alternately contacts with electrochemistry region and the alternating of electric current changes It realizes, however two electrodes of electrochemical reaction are (for example, the electrochemistry region and electric conductor, the electrochemistry region A and described Electrochemistry region B, the electrochemistry region and the region B) between the conducting of non-electronic charged particle then may exist It can be not present.
In the present invention, charged particle is set to be stored in the means in electrochemistry region as realizing, being selectively chosen makes electricity The mixture contact of two kinds of substances of chemical regions and participation electrochemical reaction and the alternating of electric current change to realize, may be selected Property select to make electrochemistry region and participate in the mixture makes discontinuous contact of two kinds of substances of electrochemical reaction and the alternating of electric current Variation is to realize, however two electrodes of electrochemical reaction are (for example, the electrochemistry region and electric conductor, the electrochemistry region A And the electrochemistry region B, the electrochemistry region and the region B) between the conducting of non-electronic charged particle then can be with In the presence of can also be not present.
In the present invention, the substance A used in the electrochemical method for synthesizing and substance B are with the substance A and the object In the presence of the form of the mixture of matter B, rubbing with the substance A and the substance B further can be selectively selected You exist than the form of mixture, or to deposit in the form of the mixture of the explosion limit substance A below and the substance B , or to exist in the form of the mixture of the local explosion limit substance A below and the substance B, or with explosion limit The form of the mixture of the above substance A and the substance B exists, or with the substance A more than local explosion limit Exist with the form of the mixture of the substance B.
In the present invention, the mixture of so-called substance A and substance B further can selectively select to be set as substance A and object Molar mixture, the explosion limit substance A below of matter B and mixture, the local explosion limit substance A below of substance B With it is more than the mixture of more than mixture of substance B, explosion limit substance A and substance B or local explosion limit substance A and The mixture of substance B.
In the present invention, so-called molar mixture refers to that the molar concentration rate of mixture is positive and negative in chemical reaction molar ratio Mixture within 10%.
In the present invention, electrochemistry region state corresponding with alternating electromotive force and alternating current is to continue working Journey.
In the present invention, electrochemistry region A state corresponding with alternating electromotive force and alternating current is to continue working Process.
In the present invention, electrochemistry region B state corresponding with alternating electromotive force and alternating current is to continue working Process.
The electrochemical method for synthesizing disclosed in this invention is corresponding with alternating electromotive force and alternating current, i.e. electrochemistry Region is corresponding with alternating electromotive force and alternating current.
In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen through non-electronic Relationship is connected in the direct electricity that charged particle is formed, and relationship, warp is connected in the electricity formed through non-electronic charged particle reciprocating vibration One of electricity conducting relationship that capacitance relation is formed, secondly conjunction or thirdly conjunction.
In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen including through exhausted The electrical relation that alternating current can be made to be connected of edge body, dielectric and the conducting body isolation of non-electronic charged particle.
In the present invention, in two electrodes (for example, the electrochemistry region and electric conductor, the electrochemistry region A and the electricity Chemical regions B, the electrochemistry region and the region B) between there are in the method for electrolyte, non-electronic charged particle can both be worn More electrolyte reaches another electrode from an electrode, can also realize the work that alternating current is connected by reciprocating vibration in the electrolyte With.
In the present invention, it is more big more be conducive to electrochemistry that capacitance is formed by between the electrochemistry region and the region B The promotion of reaction density, therefore when being electrochemically reacted using the method disclosed in the present, the electrochemical school district should be made Capacitance between domain and the region B increases as much as possible.
It, can be in the electrochemical school district in order to increase the capacitance between the electrochemistry region and the region B in the present invention Plasma, ionic liquid, ionized gas or solion are set between domain and the region B, and make ion in the electrification It is vibrated between school district domain and the region B, and/or vibrates in the electrochemistry areas adjacent and oscillated around in the region B, To realize the purpose for increasing the capacitance between the electrochemistry region and the region B.
In the present invention, it is more big more be conducive to electricity that the electrochemistry region A and the electrochemistry region B are formed by capacitance The promotion of density is chemically reacted, therefore when being electrochemically reacted using the method disclosed in the present, the electrification should be made Capacitance between school district domain A and the electrochemistry region B increases as much as possible.
It, can be described in order to increase the capacitance between the electrochemistry region A and the electrochemistry region B in the present invention Plasma, ionic liquid, ionized gas, solion and electronics are set between electrochemistry region A and the electrochemistry region B At least one of area is connected, and vibrates ion between the electrochemistry region A and the electrochemistry region B, and/or The electrochemistry region A is oscillated around and is oscillated around in the electrochemistry region B, increases the electrochemistry region A to realize The purpose of capacitance between the electrochemistry region B.
In the present invention, between the electrochemistry region and the region B and in the electrochemistry region A and the electrification It is more big more be conducive to the promotion of electrochemical reaction density that capacitance is formed by between the B of school district domain, therefore public using present invention institute When the method opened is electrochemically reacted, should make between the electrochemistry region and the region B and the electrochemistry region A and Capacitance between the electrochemistry region B increases as much as possible.
Electrochemical method for synthesizing disclosed in this invention, there are electrolysis can be reduced in the case where electrolyte between two electrodes Matter load extends its service life and is conducive to the balance and stability operation of system.
In the present invention, in the method that electrochemistry region only has electronic conduction channel (the i.e. described electrochemistry region with it is described Between the B of region, interior circuit or external circuit between the electrochemistry region A and the electrochemistry region B are in electronics and non-electronic band Charged particle state of isolation), the electrochemistry region participate in electrochemical reaction different material between alternate change physical environment and The electrochemistry region is contacted with the mixture for the different material for participating in electrochemical reaction, and non-electronic charged particle can stored In the electrochemistry region, the change of physical environment or makes the electrochemistry region and participate in the different material of electrochemical reaction Mixture contact can make the non-electronic charged particle for being stored in the electrochemistry region participate in reaction realization in the next step Electrochemical process eliminates the necessity that non-electronic charged particle is removed from electrochemistry region.Express herein, in traditional electrification It learns in synthetic method, electrochemistry region (i.e. electrode) includes at least two kinds of charged particle conductings, such as an electronic conduction channel, One proton conductive channel.
In the present invention, electrochemistry region alternative selects one of the electrode for being set as electrochemical reaction or electrode Point, the region B alternative selection is set as the electrode of electrochemical reaction or a part of electrode, and the electrochemistry region A can Selectivity selection is set as the electrode of electrochemical reaction or a part of electrode, and the electrochemistry region B alternative selection is set as The electrode of electrochemical reaction or a part of electrode.
In the present invention, it can be selected according to the operating temperature of the property and the electrochemistry region of the substance A and the substance B Select different catalyst.
In the present invention, Xiang Suoshu electrochemistry region import concentration proportion in the local explosion limit substance A below and The mixture of the substance B may include fire retardant, such as nitrogen, carbon dioxide etc. are added in the mixture of hydrogen and oxygen.
In the present invention, the substance A and the substance B refer to that electrochemical reaction occurs in the electrochemistry region Substance.
In the present invention, it can react after the substance A and substance B absorption electric energy and generate compound, or external It can react after feed electric energy and generate compound.
In the present invention, eliminating from the necessity that electrochemistry region removes non-electronic charged particle means only to need to remove electricity Son, rather than electronics charged particle (such as proton) can store in the electrochemistry region that it is generated and the participation electricity during next Chemical reaction, it means that It is not necessary to the interior circuit or outer that centainly there is non-electronic charged particle channel to constitute between two electrodes Circuit, it is only necessary to which electrochemical process can be realized in electronic conduction circuit, in this approach, is selectively chosen electricity in it The conducting on road is that the reciprocating vibration of charged particle in capacitor and/or its internal part by being formed between its internal part is realized , and using external circuit output electric energy and/or absorb electric energy.
In the present invention, eliminating from the necessity that electrochemistry region removes two kinds of charged particles means only to need to remove electricity Son, and another charged particle (such as proton) can store in the electrochemistry region that it is generated and the participation electricity during next Chemical reaction, it means that It is not necessary to the interior circuit or outer that centainly there is non-electronic charged particle channel to constitute between two electrodes Circuit, it is only necessary to which electrochemical process can be realized in electronic conduction circuit, and in this approach, the conducting of interior circuit is to pass through The reciprocating vibration of charged particle is realized in the capacitor and/or its internal part formed between its internal part, and utilizes dispatch from foreign news agency Road exports electric energy and/or absorbs electric energy.
In the present invention, the electrochemistry region, which is selectively chosen, is set as three-diemsnional electrode.
In the present invention, the electrochemistry region A, which is selectively chosen, is set as three-diemsnional electrode.
In the present invention, the electrochemistry region B, which is selectively chosen, is set as three-diemsnional electrode.
In the present invention, the region B, which is selectively chosen, is set as three-diemsnional electrode.
In the present invention, such as there is non-electronic conducting electrical relation using Y and X as synonym, Y and X, the electronics of the Y is led The form of presentation imported out refers to that the Y, the X and electronics export import the composition that circuit three is same closed circuit Part is selectively chosen electronics export importing circuit being set as external circuit, and non-electronic conducting electrical relation is formed Circuit be set as interior circuit.
In the present invention, such as using U, W and V as synonym, U has non-electronic conducting electrical relation through W and V, and electronics is in institute The form of presentation for exporting importing between U and the V is stated, refers to that the U, the W, the V and electronics export import circuit It is the component part of same closed circuit, is selectively chosen and electronics export importing circuit is set as external circuit, and will be non- Electronic conduction electrical relation is formed by circuit and is set as interior circuit.
In the present invention, the area Jie electricity that so-called " area alternating current Jie electricity " refers to alternating current is selectively chosen and sets For a part of relative subject, also alternative selection is set as the conduction region contacted with relative subject, is also selectively chosen It is set as the conduction region that there is capacitance relation with relative subject.It includes that the area alternating current Jie electricity is this that so-called relative subject, which is exactly in A, A in description.
In the present invention, so-called " alternating electromotive force " refers to that the changed electromotive force of electromotive force, such as direction become The changed electromotive force of electromotive force or size of change.
In the present invention, so-called " alternating current " refers to the changed electric current of electric current, such as the changed electricity in direction Stream, the changed electric current of size or alternating current.
In the present invention, so-called " alternating current " is selectively chosen the electric current for being set as the variation of electric current generating period, Such as electric current or alternating current that electric current, the size generating period of direction generating period variation change.
In the present invention, so-called alternating current refers to the alternating current changed by sinusoidal rule.
In the present invention, so-called AC power source refers to the alternating source that electric current is changed by sinusoidal rule.
In the present invention, there is so-called A and B non-electronic conducting electrical relation to refer to having on interior circuit between A and B Non-electronic conducting electrical relation, and its external circuit is selectively chosen electronic conduction relationship;Or, so-called A and B has non-electrical Son conducting electrical relation, which refers to, has non-electronic conducting electrical relation on external circuit between A and B, and its interior circuit may be selected Select electronic conduction relationship to property.
In the present invention, it is so-called " the electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, etc. At least one of gas ions, ionic liquid, ionized gas, solion and electronic conduction area have non-electrical with the region B Son conducting electrical relation " include the electrochemistry region and the region B through electronic conduction area, insulator, dielectric and/or from The non-electronic conducting electrical relation that two solion ponds of son conducting body isolation have.In this approach, it optionally selects Selecting makes at least one in the electrochemistry region and the region B and capacitive region and/or non-electronic charged particle transmitter shape At electrical relation.
In the present invention, it is so-called " the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, At least one of plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemistry region B With non-electronic conducting electrical relation " it include the electrochemistry region A and the electrochemistry region B through electronic conduction area, insulation The non-electronic conducting electrical relation that two solion ponds of body, dielectric and/or ion conducting body isolation have.In this method In, be selectively chosen make at least one in the electrochemistry region A and the electrochemistry region B with capacitive region and/or Non-electronic charged particle transmitter forms electrical relation.
In the present invention, so-called " electronic conduction area " refers to that conduct electrons are not turned on the region of non-electronic charged particle, can Selectively selection is set as metallic conductor area, carbon conductor region etc..
In the present invention, so-called " non-electronic charged particle transmitter " refer to non-conducting electronics but proton conducting or it is specific from The substance of son, i.e. electrolyte in Conventional electrochemical method, can be according to the electrochemical properties of the reducing agent and the oxidant Non-electronic charged particle transmitter is selected, such as when the reducing agent is H2, the oxidant is O2When, the non-electronic electrification Particle conduction object alternative selects proton exchange membrane.
In the present invention, select electronic conduction area shape when, should for the purpose of increasing its capacitance with neighbors into Row selection.
In the present invention, so-called " non-electronic conducting electrical relation " refers to the electricity formed through the charged particle other than electronics Conducting relationship or the electricity to be formed conducting relationship of standing facing each other through electronics, for example, relationship, non-electronic electrification is connected in the electricity that capacitor is formed The electricity conducting relationship etc. that particle reciprocating vibration is formed.
In the present invention, so-called " capacitor " be selectively chosen be set as electrolytic capacitor, super capacitor, electric double layer capacitance, All capacitors such as pseudo capacitance, fake capacitance.
In the present invention, so-called " electrolyte " refer to all be arranged between two electrode of electrochemical appliance only allow it is specific The substance that charged particle passes through but electronics is not allowed to pass through can be solid, liquid or membranous body etc., such as the proton of PEMFC Film and solid oxide electrolyte etc..
In the present invention, so-called " electrochemistry region " refers to that the region of electrochemical reaction can occurs in all, for example including Catalyst, ultra microstructure and/or region at a set temperature, then metallic region for example at a set temperature.
It is so-called to refer to " including catalyst, ultra microstructure and/or electrochemistry region at a set temperature " in the present invention The electrochemistry region or including catalyst or including ultra microstructure or under the set temperature or the electrification School district domain includes two or three in these three conditions.
In the present invention, so-called " ultra microstructure " refers to the microcosmic knot that can cause electrochemical reaction under setting condition Structure.
In the present invention, so-called electrochemistry region, so-called region B, so-called electrochemistry region A, so-called electrochemistry Region B, so-called electric conductor are equal with electrode.
In the present invention, the region that electronics export imports is equal with electrode.
In the present invention, it is selectively chosen between electrode with dielectric capacitance relationship.
It in the present invention, is selectively chosen, the electrochemistry region and electric conductor have dielectric capacitance relationship, and electricity is situated between Matter can be gas, liquid, solid or vacuum.
In the present invention, it is selectively chosen, the electrochemistry region and the region B have dielectric capacitance relationship, Dielectric can be gas, liquid, solid or vacuum.
It in the present invention, is selectively chosen, the electrochemistry region A and the electrochemistry region B have dielectric capacitance Relationship, dielectric can be gas, liquid, solid or vacuum.
In the present invention, so-called " dielectric capacitance relationship " refers to the capacitance relation through dielectric formation, and dielectric can be with It is gas, liquid, solid or vacuum.
In the present invention, so-called " local explosion limit " refers under conditions of the electrochemistry region, the substance A and The concentration ratio that the substance B cannot explode.
In the present invention, include the catalyst method in, the catalyst be set as include noble metal catalyst, or The catalyst be set as include rare earth element catalyst.
In the present invention, so-called interpolar spacer refers to make to have required for non-electronic conducting electrical relation between electrode Substance (including vacuum), such as electrolyte, dielectric etc..
In the present invention, the selection of interpolar spacer alternative is set as insulation, isolation space, electrolyte, dielectric, electricity At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area.
In the present invention, so-called interpolar spacer, which is selectively chosen, is set as interior circuit, is also selectively chosen and sets For external circuit.
In the present invention, so-called electro ultrafiltration is a kind of selectivity selection.
In the present invention, so-called " non-electronic charged particle " refers to the charged particle other than electronics, such as proton or ion.
In the present invention, after a certain component names plus the letter such as so-called " A ", " B " is merely to distinguish two or several The identical component of title or substance.
In the present invention, necessary portion should be set in necessary place according to electricity field, the well-known technique of electrochemical field Part, unit or system etc..
Beneficial effects of the present invention are as follows: electrochemical method for synthesizing disclosed in this invention will termination Conventional electrochemical synthesis Method and electrochemistry formated device to the history of electrolyte demand, for efficiently, long-life, Low-cost electric chemical synthesizer open Hair provides new approach.
Specific embodiment
Technical solution of the present invention is further illustrated combined with specific embodiments below.
Embodiment 1
The invention discloses a kind of electrochemical method for synthesizing, and electrochemistry region can specifically replaced with substance A and substance B and connects It touches or makes substance A and substance B alternately to contact with electrochemistry region, or so that electrochemistry region and substance A is contacted with each other and make described Electrochemistry region and the mutual makes discontinuous contact of substance B, or electrochemistry region and substance B is made to contact with each other and make the electrochemistry region With the mutual makes discontinuous contact of substance A, so that the substance A is generated positive charged particle and electronics in the electrochemistry region, make the electricity The electronics of chemical regions, which exports, to be imported.
As disposable embodiment, the embodiment of the present invention 1 and its disposable embodiment can be selected further It is correspondingly arranged the electrochemistry region with electric conductor to property;It also further can selectively select to make the electrochemistry region There is non-electronic conducting electrical relation with electric conductor, also further can selectively select to make the electrochemistry region through completely cutting off Body, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction At least one of area has non-electronic conducting electrical relation with electric conductor.
Embodiment 2
The electrochemical method for synthesizing disclosed in this invention be also selectively chosen make electrochemistry region and substance A and Substance B alternately contacts or makes substance A and substance B alternately to contact with electrochemistry region, makes the substance A in the electrochemistry region Positive charged particle and electronics are generated, electronics is made to export importing between the electrochemistry region and region B.
As disposable embodiment, the embodiment of the present invention 2 and its disposable embodiment can be selected further It is correspondingly arranged the electrochemistry region with the region B to property;It also further can selectively select to make the electrochemistry Region and the region B have non-electronic conducting electrical relation, also further can selectively select to make the electrochemical school district Domain through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and At least one of electronic conduction area has non-electronic conducting electrical relation with the region B.
Embodiment 3
The electrochemical method for synthesizing disclosed in this invention, which is also selectively chosen, makes electrochemistry region and substance A phase The electrochemistry region and the mutual makes discontinuous contact of substance B are mutually contacted and made, generates the substance A just in the electrochemistry region Charged particle and electronics make electronics export importing between the electrochemistry region and region B.
As disposable embodiment, the embodiment of the present invention 3 and its disposable embodiment can be selected further It is correspondingly arranged the electrochemistry region with the region B to property;It also further can selectively select to make the electrochemistry Region and the region B have non-electronic conducting electrical relation, also further can selectively select to make the electrochemical school district Domain through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and At least one of electronic conduction area has non-electronic conducting electrical relation with the region B.
Embodiment 4
The electrochemical method for synthesizing disclosed in this invention, which is also selectively chosen, makes electrochemistry region and substance B phase The electrochemistry region and the mutual makes discontinuous contact of substance A are mutually contacted and made, generates the substance A just in the electrochemistry region Charged particle and electronics make electronics export importing between the electrochemistry region and region B.
As disposable embodiment, the embodiment of the present invention 4 and its disposable embodiment can be selected further It is correspondingly arranged the electrochemistry region with the region B to property;It also further can selectively select to make the electrochemistry Region and the region B have non-electronic conducting electrical relation, also further can selectively select to make the electrochemical school district Domain through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and At least one of electronic conduction area has non-electronic conducting electrical relation with the region B.
Embodiment 5
The electrochemical method for synthesizing disclosed in this invention, which is also selectively chosen, makes electrochemistry region A and substance A It alternately contacts or makes substance A and substance B alternately to contact with electrochemistry region A with substance B and make electrochemistry region B and the object Matter B and the substance A alternately contact or make substance B and substance A alternately to contact with electrochemistry region B, make the substance A described Electrochemistry region A generates positive charged particle and electronics, make the substance A the electrochemistry region B generate positive charged particle and Electronics makes electronics export importing between the electrochemistry region A and the electrochemistry region B.
As disposable embodiment, the embodiment of the present invention 5 and its disposable embodiment can also be selected further It selects to selecting property to be correspondingly arranged the electrochemistry region A with the electrochemistry region B;And it further can selectively select Make the electrochemistry region A and electrochemistry region B that there is non-electronic conducting electrical relation;And it can further selectively Selection make the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, At least one of ionized gas, solion and electronic conduction area have non-electronic conducting electricity with the electrochemistry region B Relationship.
Embodiment 6
The electrochemical method for synthesizing disclosed in this invention, which is also selectively chosen, makes electrochemistry region A and substance A It contacts with each other and makes the electrochemistry region A and the mutual makes discontinuous contact of substance B and make electrochemistry region B and substance A phase mutual connection The electrochemistry region B and the mutual makes discontinuous contact of substance B are touched and made, the substance A is made to generate positive band in the electrochemistry region A Charged particle and electronics make the substance A generate positive charged particle and electronics in the electrochemistry region B, make electronics in the electricity It exports and imports between chemical regions A and the electrochemistry region B.
As disposable embodiment, the embodiment of the present invention 6 and its disposable embodiment can also be selected further It selects to selecting property to be correspondingly arranged the electrochemistry region A with the electrochemistry region B;And it further can selectively select Make the electrochemistry region A and electrochemistry region B that there is non-electronic conducting electrical relation;And it can further selectively Selection make the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, At least one of ionized gas, solion and electronic conduction area have non-electronic conducting electricity with the electrochemistry region B Relationship.
Embodiment 7
The electrochemical method for synthesizing disclosed in this invention, which is also selectively chosen, makes electrochemistry region A and substance B It contacts with each other and makes the electrochemistry region A and the mutual makes discontinuous contact of substance A and make electrochemistry region B and substance B phase mutual connection The electrochemistry region B and the mutual makes discontinuous contact of substance A are touched and made, the substance A is made to generate positive band in the electrochemistry region A Charged particle and electronics make the substance A generate positive charged particle and electronics in the electrochemistry region B, make electronics in the electricity It exports and imports between chemical regions A and the electrochemistry region B.
As disposable embodiment, the embodiment of the present invention 7 and its disposable embodiment can also be selected further It selects to selecting property to be correspondingly arranged the electrochemistry region A with the electrochemistry region B;And it further can selectively select Make the electrochemistry region A and electrochemistry region B that there is non-electronic conducting electrical relation;And it can further selectively Selection make the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, At least one of ionized gas, solion and electronic conduction area have non-electronic conducting electricity with the electrochemistry region B Relationship.
Embodiment 8
The electrochemical method for synthesizing disclosed in this invention, which is also selectively chosen, makes electrochemistry region A and substance B It contacts with each other and makes the electrochemistry region A and the mutual makes discontinuous contact of substance A and make electrochemistry region B and substance A phase mutual connection The electrochemistry region B and the mutual makes discontinuous contact of substance B are touched and made, the substance A is made to generate positive band in the electrochemistry region A Charged particle and electronics make the substance A generate positive charged particle and electronics in the electrochemistry region B, make electronics in the electricity It exports and imports between chemical regions A and the electrochemistry region B.
As disposable embodiment, the embodiment of the present invention 8 and its disposable embodiment can also be selected further It selects to selecting property to be correspondingly arranged the electrochemistry region A with the electrochemistry region B;And it further can selectively select Make the electrochemistry region A and electrochemistry region B that there is non-electronic conducting electrical relation;And it can further selectively Selection make the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, At least one of ionized gas, solion and electronic conduction area have non-electronic conducting electricity with the electrochemistry region B Relationship.
Embodiment 9
The electrochemical method for synthesizing disclosed in this invention be also selectively chosen make electrochemistry region and substance A and The mixture of substance B contacts or contacts the mixture of substance A and substance B with electrochemistry region, makes the substance A in the electricity Chemical regions generate positive charged particle and electronics, export the electronics in the electrochemistry region and import.
Embodiment 10
The electrochemical method for synthesizing disclosed in this invention be also selectively chosen make electrochemistry region and substance A and The mixture makes discontinuous contact of substance B makes the mixture of substance A and substance B and electrochemistry region makes discontinuous contact, makes the substance A Positive charged particle and electronics are generated in the electrochemistry region, the electronics in the electrochemistry region is exported and imports.
Embodiment 11
The electrochemical method for synthesizing disclosed in this invention be also selectively chosen make electrochemistry region and substance A and The mixture of substance B contacts or contacts the mixture of substance A and substance B with electrochemistry region, makes the substance A in the electricity Chemical regions generate positive charged particle and electronics, and electronics is made to export importing between the electrochemistry region and region B.
As disposable embodiment, the embodiment of the present invention 11 and its disposable embodiment can be selected further It is correspondingly arranged the electrochemistry region and the region B to property;And it further can selectively select to make the electrochemical school district Domain and the region B have non-electronic conducting electrical relation;It further can also selectively select to make the electrochemical school district Domain through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and At least one of electronic conduction area has non-electronic conducting electrical relation with the region B.
Embodiment 12
The electrochemical method for synthesizing disclosed in this invention be also selectively chosen make electrochemistry region and substance A and The mixture makes discontinuous contact of substance B makes the mixture of substance A and substance B and electrochemistry region makes discontinuous contact, makes the substance A Positive charged particle and electronics are generated in the electrochemistry region, leads electronics between the electrochemistry region and region B Enter.
As disposable embodiment, the embodiment of the present invention 12 and its disposable embodiment can be selected further It is correspondingly arranged the electrochemistry region and the region B to property;And it further can selectively select to make the electrochemical school district Domain and the region B have non-electronic conducting electrical relation;It further can also selectively select to make the electrochemical school district Domain through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and At least one of electronic conduction area has non-electronic conducting electrical relation with the region B.
Embodiment 13
The electrochemical method for synthesizing disclosed in this invention, which is also selectively chosen, makes electrochemistry region A and substance A With the contact of the mixture of substance B or contact the mixture of substance A and substance B with electrochemistry region A, make electrochemistry region B and The mixture of substance A and substance B contacts or contacts the mixture of substance A and substance B with electrochemistry region B, makes the substance A Positive charged particle and electronics are generated in the electrochemistry region A, the substance A is made to generate positive electrification in the electrochemistry region B Particle and electronics make electronics export importing between the electrochemistry region A and the electrochemistry region B.
As disposable embodiment, the embodiment of the present invention 13 and its disposable embodiment can be selected further It is correspondingly arranged the electrochemistry region A with the electrochemistry region B to property;It also further can selectively select to make described The electrochemistry region A and electrochemistry region B has non-electronic conducting electrical relation;It also further can selectively select to make The electrochemistry region A is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion-gas At least one of body, solion and electronic conduction area have non-electronic conducting electrical relation with the electrochemistry region B.
Embodiment 14
The electrochemical method for synthesizing disclosed in this invention, which is also selectively chosen, makes electrochemistry region A and substance A With the mixture makes discontinuous contact of substance B or make the mixture of substance A and substance B and electrochemistry region A makes discontinuous contact, make electrochemistry The mixture makes discontinuous contact of region B and substance A and substance B keeps the mixture of substance A and substance B and electrochemistry region B interrupted Contact makes the substance A generate positive charged particle and electronics in the electrochemistry region A, makes the substance A in the electrochemistry Region B generates positive charged particle and electronics, leads electronics between the electrochemistry region A and the electrochemistry region B Enter.
As disposable embodiment, the embodiment of the present invention 14 and its disposable embodiment can be selected further It is correspondingly arranged the electrochemistry region A with the electrochemistry region B to property;It also further can selectively select to make described The electrochemistry region A and electrochemistry region B has non-electronic conducting electrical relation;It also further can selectively select to make The electrochemistry region A is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion-gas At least one of body, solion and electronic conduction area have non-electronic conducting electrical relation with the electrochemistry region B.
In the specific implementation, electrochemical method for synthesizing disclosed in this invention exports in the implementation process imported in electronics, Further can selectively it select using alternating source.
As disposable embodiment, the aforementioned all electrochemical method for synthesizing of the present invention in the specific implementation, The export for making electronics further can be selectively selected to import as work normality.
Electrochemical method for synthesizing disclosed in this invention only containing electrochemistry region in the specific implementation, makes itself and conduction Body is associated, and so that electronics is exported importing between the electrochemistry region and electric conductor is that work is normal State.
In the specific implementation, all electrochemical method for synthesizing containing electric conductor further can be selected selectively So that electric conductor is set as electrode, and further can selectively select that electric conductor is made to be set as three-diemsnional electrode.
Electrochemical method for synthesizing disclosed in this invention in the specific implementation, further can selectively select to make described Substance A is set as hydrogen, and the substance B is set as carbon;And it further can selectively select the production for making the electrochemical method for synthesizing Object is methane, ethane, propane or is octane.
Electrochemical method for synthesizing disclosed in this invention containing electrochemistry region in the specific implementation, can be selected further Selecting property it is arranged the electrochemistry area rotation.
Electrochemical method for synthesizing disclosed in this invention containing electrochemistry region A and electrochemistry region B is being embodied When, it further can selectively make the electrochemistry region A rotation setting, and make the electrochemistry region B rotation setting.
Electrochemical method for synthesizing disclosed in this invention containing the electrochemistry region A and the electrochemistry region B exists When it is implemented, further can selectively select to make electronics between the electrochemistry region A and the electrochemistry region B Export import be work normality.
Electrochemical method for synthesizing disclosed in this invention containing the electrochemistry region and the region B is being embodied When, it further can selectively select the export for making electronics between the electrochemistry region and the region B to import as work Make normality.
Electrochemical method for synthesizing disclosed in this invention containing the electrochemistry region and electric conductor in the specific implementation, The export for making electronics between the electrochemistry region and electric conductor further can be selectively selected to import as work normality.
In the specific implementation, disclosed method, which is selectively chosen, serves as half electrochemistry formated device of manufacture (i.e. Include the device region of an electrode in electrochemical method), it is also selectively chosen and serves as manufacture electrochemistry formated device.
In the specific implementation, the disclosed electrochemical method for synthesizing optionally makes the electrochemistry region and hands over Power transformation kinetic potential and the corresponding state of alternating current are to continue working process.
In the specific implementation, the disclosed electrochemical method for synthesizing optionally makes the region B and alternation electricity Kinetic potential and the corresponding state of alternating current are to continue working process.
In the specific implementation, the disclosed electrochemical method for synthesizing optionally make the electrochemistry region A with Alternating electromotive force and the corresponding state of alternating current are to continue working process.
In the specific implementation, the disclosed electrochemical method for synthesizing optionally make the electrochemistry region B with Alternating electromotive force and the corresponding state of alternating current are to continue working process.
In the specific implementation, the electrochemical method for synthesizing disclosed in this invention and alternating electromotive force and alternating current phase Corresponding, i.e., electrochemistry region is corresponding with alternating electromotive force and alternating current.
In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen through non-electronic Relationship is connected in the direct electricity that charged particle is formed, and relationship, warp is connected in the electricity formed through non-electronic charged particle reciprocating vibration One of electricity conducting relationship that capacitance relation is formed, secondly conjunction or thirdly conjunction.
The present invention in the specific implementation, further can selectively select to select the electrochemistry region optionally It selects and is set as three-diemsnional electrode.
The present invention in the specific implementation, further can selectively select to make the electrochemistry region A optionally Selection is set as three-diemsnional electrode.
The present invention in the specific implementation, further can selectively select to make the electrochemistry region B optionally Selection is set as three-diemsnional electrode.
In the specific implementation, further can selectively select is selectively chosen the region B sets the present invention For three-diemsnional electrode.
Electrochemical method for synthesizing disclosed in this invention only containing electrochemistry region in the specific implementation, can be selected further Make to selecting property the electrochemistry region and electric conductor includes the area alternating current Jie electricity, and makes described in the electrochemistry region process The area alternating current Jie electricity is associated with electric conductor.
Electrochemical method for synthesizing disclosed in this invention containing electrochemistry region and region B in the specific implementation, can be into One step selectively makes the electrochemistry region and the region B includes the area alternating current Jie electricity, and makes the electrochemical school district Domain is associated with the region B by the area the alternating current Jie electricity.
Electrochemical method for synthesizing disclosed in this invention containing electrochemistry region A and electrochemistry region B is being embodied When, it further can selectively make the electrochemistry region A and the electrochemistry region B includes the area alternating current Jie electricity, and Keep the electrochemistry region A associated with the electrochemistry region B by the area the alternating current Jie electricity.
In the present invention, the electrochemical method for synthesizing in disclosed only electrochemistry region is in the specific implementation, alternative Ground selects to make two electrode cooperating completionizations using electric conductor as another electrode using electrochemistry region as an electrode Learning can electric energy conversion;Also be selectively chosen using electrochemistry region as an electrode, using another electrochemistry region as Another electrode, two electrode cooperatings complete the conversion of chemical energy electric energy.
It is clear that the invention is not restricted to above embodiments, according to techniques known and technology disclosed in this invention Scheme, can derive or associate many variant schemes out, and all these variant schemes also are regarded as being protection model of the invention It encloses.

Claims (16)

1. a kind of electrochemical method for synthesizing, it is characterised in that: electrochemistry region is made alternately to contact or make object with substance A and substance B Matter A and substance B are alternately contacted with electrochemistry region, or so that electrochemistry region and substance A is contacted with each other and made the electrochemical school district Domain and the mutual makes discontinuous contact of substance B, or electrochemistry region and substance B is made to contact with each other and make the electrochemistry region and substance A Mutual makes discontinuous contact makes the substance A generate positive charged particle and electronics in the electrochemistry region, makes the electrochemistry region Electronics export import.
2. a kind of electrochemical method for synthesizing, it is characterised in that: electrochemistry region is made alternately to contact or make object with substance A and substance B Matter A and substance B are alternately contacted with electrochemistry region, or so that electrochemistry region and substance A is contacted with each other and made the electrochemical school district Domain and the mutual makes discontinuous contact of substance B, or electrochemistry region and substance B is made to contact with each other and make the electrochemistry region and substance A Mutual makes discontinuous contact makes the substance A generate positive charged particle and electronics in the electrochemistry region, makes electronics in the electrification It exports and imports between school district domain and region B;
It is connect or, electrochemistry region is made alternately to contact or make substance A and substance B to replace with electrochemistry region with substance A and substance B Touching, or so that electrochemistry region and substance A is contacted with each other and is made the electrochemistry region and the mutual makes discontinuous contact of substance B, or make electricity Chemical regions and substance B contact with each other and make the electrochemistry region and the mutual makes discontinuous contact of substance A, to make the substance A in institute It states electrochemistry region and generates positive charged particle and electronics, electronics is made to export importing, institute between the electrochemistry region and region B Electrochemistry region is stated to be correspondingly arranged with the region B;
It is connect or, electrochemistry region is made alternately to contact or make substance A and substance B to replace with electrochemistry region with substance A and substance B Touching, or so that electrochemistry region and substance A is contacted with each other and is made the electrochemistry region and the mutual makes discontinuous contact of substance B, or make electricity Chemical regions and substance B contact with each other and make the electrochemistry region and the mutual makes discontinuous contact of substance A, to make the substance A in institute It states electrochemistry region and generates positive charged particle and electronics, electronics is made to export importing between the electrochemistry region and region B;Institute Stating electrochemistry region and the region B has non-electronic conducting electrical relation, or, the electrochemistry region is through insulation, isolation In space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area extremely A kind of few and region B has non-electronic conducting electrical relation.
3. a kind of electrochemical method for synthesizing, it is characterised in that: electrochemistry region A is made alternately to contact or make object with substance A and substance B Matter A and substance B, which alternately contact with electrochemistry region A and replace electrochemistry region B with the substance B and the substance A, to be connect It touches or makes substance B and substance A alternately to contact with electrochemistry region B, or electrochemistry region A and substance A is made to contact with each other and make institute It states electrochemistry region A and the mutual makes discontinuous contact of substance B and electrochemistry region B and substance A is made to contact with each other and make the electrification School district domain B and the mutual makes discontinuous contact of substance B, or electrochemistry region A and substance B is made to contact with each other and make the electrochemistry region A With the mutual makes discontinuous contact of substance A and make electrochemistry region B and substance B contacts with each other and makes the electrochemistry region B and substance A Mutual makes discontinuous contact, or so that electrochemistry region A is contacted with each other with substance B and keep the electrochemistry region A and substance A mutually interrupted It contacts and makes electrochemistry region B and substance A to contact with each other and make the electrochemistry region B and the mutual makes discontinuous contact of substance B, make The substance A generates positive charged particle and electronics in the electrochemistry region A, produces the substance A in the electrochemistry region B Raw positive charged particle and electronics, make electronics export importing between the electrochemistry region A and the electrochemistry region B;
It is connect or, electrochemistry region A is made alternately to contact or make substance A and substance B to replace with electrochemistry region A with substance A and substance B It touches and electrochemistry region B is made alternately to contact or make substance B and substance A and electrochemistry region with the substance B and the substance A B is alternately contacted, or so that electrochemistry region A is contacted with each other with substance A and connect the electrochemistry region A mutually discontinuously with substance B It touches and makes electrochemistry region B and substance A to contact with each other and make the electrochemistry region B and the mutual makes discontinuous contact of substance B, or make Electrochemistry region A and substance B contact with each other and make the electrochemistry region A and the mutual makes discontinuous contact of substance A and make electrochemistry Region B and substance B contact with each other and make the electrochemistry region B and the mutual makes discontinuous contact of substance A, or make electrochemistry region A and Substance B contacts with each other and makes the electrochemistry region A and the mutual makes discontinuous contact of substance A and make electrochemistry region B and substance A phase The electrochemistry region B and the mutual makes discontinuous contact of substance B are mutually contacted and made, generates the substance A in the electrochemistry region A Positive charged particle and electronics, make the substance A generate positive charged particle and electronics in the electrochemistry region B, make electronics in institute It states to export between electrochemistry region A and the electrochemistry region B and import, the electrochemistry region A and B pairs of the electrochemistry region It should be arranged;
It is connect or, electrochemistry region A is made alternately to contact or make substance A and substance B to replace with electrochemistry region A with substance A and substance B It touches and electrochemistry region B is made alternately to contact or make substance B and substance A and electrochemistry region with the substance B and the substance A B is alternately contacted, or so that electrochemistry region A is contacted with each other with substance A and connect the electrochemistry region A mutually discontinuously with substance B It touches and makes electrochemistry region B and substance A to contact with each other and make the electrochemistry region B and the mutual makes discontinuous contact of substance B, or make Electrochemistry region A and substance B contact with each other and make the electrochemistry region A and the mutual makes discontinuous contact of substance A and make electrochemistry Region B and substance B contact with each other and make the electrochemistry region B and the mutual makes discontinuous contact of substance A, or make electrochemistry region A and Substance B contacts with each other and makes the electrochemistry region A and the mutual makes discontinuous contact of substance A and make electrochemistry region B and substance A phase The electrochemistry region B and the mutual makes discontinuous contact of substance B are mutually contacted and made, generates the substance A in the electrochemistry region A Positive charged particle and electronics, make the substance A generate positive charged particle and electronics in the electrochemistry region B, make electronics in institute It states to export between electrochemistry region A and the electrochemistry region B and import;The electrochemistry region A and electrochemistry region B has Have non-electronic conducting electrical relation, or, the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, At least one of plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemistry region B With non-electronic conducting electrical relation.
4. a kind of electrochemical method for synthesizing, it is characterised in that: make electrochemistry region contacted with the mixture of substance A and substance B or It contacts the mixture of substance A and substance B with electrochemistry region, the substance A is made to generate positive electrification in the electrochemistry region Particle and electronics export the electronics in the electrochemistry region and import;
Or, making the mixture makes discontinuous contact of electrochemistry region and substance A and substance B or making the mixture of substance A and substance B and electricity Chemical regions makes discontinuous contact makes the substance A generate positive charged particle and electronics in the electrochemistry region, makes the electrochemistry The electronics in region, which exports, to be imported.
5. a kind of electrochemical method for synthesizing, it is characterised in that: make electrochemistry region contacted with the mixture of substance A and substance B or It contacts the mixture of substance A and substance B with electrochemistry region, the substance A is made to generate positive electrification in the electrochemistry region Particle and electronics make electronics export importing between the electrochemistry region and region B;
Or, making the mixture makes discontinuous contact of electrochemistry region and substance A and substance B or making the mixture of substance A and substance B and electricity Chemical regions makes discontinuous contact makes the substance A generate positive charged particle and electronics in the electrochemistry region, makes electronics described It exports and imports between electrochemistry region and region B;
Or, making electrochemistry region that the mixture and electrochemistry of substance A and substance B are contacted or made with the mixture of substance A and substance B Region contact, makes the substance A generate positive charged particle and electronics in the electrochemistry region, makes electronics in the electrochemical school district It exports and imports between domain and region B, the electrochemistry region and the region B are correspondingly arranged;
Or, making the mixture makes discontinuous contact of electrochemistry region and substance A and substance B or making the mixture of substance A and substance B and electricity Chemical regions makes discontinuous contact makes the substance A generate positive charged particle and electronics in the electrochemistry region, makes electronics described It exports and imports between electrochemistry region and region B, the electrochemistry region and the region B are correspondingly arranged;
Or, making electrochemistry region that the mixture and electrochemistry of substance A and substance B are contacted or made with the mixture of substance A and substance B Region contact, makes the substance A generate positive charged particle and electronics in the electrochemistry region, makes electronics in the electrochemical school district It exports and imports between domain and region B;The electrochemistry region and the region B have non-electronic conducting electrical relation, or, described Electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, from At least one of sub- solution and electronic conduction area have non-electronic conducting electrical relation with the region B;
Or, making the mixture makes discontinuous contact of electrochemistry region and substance A and substance B or making the mixture of substance A and substance B and electricity Chemical regions makes discontinuous contact makes the substance A generate positive charged particle and electronics in the electrochemistry region, makes electronics described It exports and imports between electrochemistry region and region B;The electrochemistry region and the region B are closed with non-electronic conducting electricity System, or, the electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, from At least one of sub- gas, solion and electronic conduction area have non-electronic conducting electrical relation with the region B.
6. a kind of electrochemical method for synthesizing, it is characterised in that: make electrochemistry region A contacted with the mixture of substance A and substance B or It contacts the mixture of substance A and substance B with electrochemistry region A, meets electrochemistry region B and the mixture of substance A and substance B It touches or makes the mixture of substance A and substance B to contact with electrochemistry region B, generate the substance A in the electrochemistry region A Positive charged particle and electronics, make the substance A generate positive charged particle and electronics in the electrochemistry region B, make electronics in institute It states to export between electrochemistry region A and the electrochemistry region B and import;
Or, making electrochemistry region A that the mixture of substance A and substance B and electrification are contacted or made with the mixture of substance A and substance B School district domain A contact, make electrochemistry region B contact or make with the mixture of substance A and substance B the mixture of substance A and substance B and Electrochemistry region B contact, makes the substance A generate positive charged particle and electronics in the electrochemistry region A, makes the substance A Positive charged particle and electronics are generated in the electrochemistry region B, makes electronics in the electrochemistry region A and the electrochemistry region It exports and imports between B, the electrochemistry region A is correspondingly arranged with the electrochemistry region B;
Or, making electrochemistry region A that the mixture of substance A and substance B and electrification are contacted or made with the mixture of substance A and substance B School district domain A contact, make electrochemistry region B contact or make with the mixture of substance A and substance B the mixture of substance A and substance B and Electrochemistry region B contact, makes the substance A generate positive charged particle and electronics in the electrochemistry region A, makes the substance A Positive charged particle and electronics are generated in the electrochemistry region B, makes electronics in the electrochemistry region A and the electrochemistry region It exports and imports between B;The electrochemistry region A and electrochemistry region B has non-electronic conducting electrical relation, or, described Electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, from At least one of sub- solution and electronic conduction area have non-electronic conducting electrical relation with the electrochemistry region B;
Or, make the mixture makes discontinuous contact of electrochemistry region A and substance A and substance B or make the mixture of substance A and substance B with Electrochemistry region A makes discontinuous contact makes the mixture makes discontinuous contact of electrochemistry region B and substance A and substance B or makes substance A and object The mixture of matter B and electrochemistry region B makes discontinuous contact, make the substance A the electrochemistry region A generate positive charged particle and Electronics makes the substance A generate positive charged particle and electronics in the electrochemistry region B, makes electronics in the electrochemistry region A It exports and imports between the electrochemistry region B;
Or, make the mixture makes discontinuous contact of electrochemistry region A and substance A and substance B or make the mixture of substance A and substance B with Electrochemistry region A makes discontinuous contact makes the mixture makes discontinuous contact of electrochemistry region B and substance A and substance B or makes substance A and object The mixture of matter B and electrochemistry region B makes discontinuous contact, make the substance A the electrochemistry region A generate positive charged particle and Electronics makes the substance A generate positive charged particle and electronics in the electrochemistry region B, makes electronics in the electrochemistry region A It exports and imports between the electrochemistry region B, the electrochemistry region A is correspondingly arranged with the electrochemistry region B;
Or, make the mixture makes discontinuous contact of electrochemistry region A and substance A and substance B or make the mixture of substance A and substance B with Electrochemistry region A makes discontinuous contact makes the mixture makes discontinuous contact of electrochemistry region B and substance A and substance B or makes substance A and object The mixture and electrochemistry region B makes discontinuous contact of matter B;Make the substance A the electrochemistry region A generate positive charged particle and Electronics makes the substance A generate positive charged particle and electronics in the electrochemistry region B, makes electronics in the electrochemistry region A It exports and imports between the electrochemistry region B;The electrochemistry region A and electrochemistry region B has non-electronic conducting Electrical relation, or, the electrochemistry region A is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ion At least one of liquid, ionized gas, solion and electronic conduction area have non-electronic conducting with the electrochemistry region B Electrical relation.
7. the electrochemical method for synthesizing as described in any one of claims 1 to 6, it is characterised in that: in the mistake that electronics export imports Cheng Zhong uses alternating source.
8. the electrochemical method for synthesizing as described in any one of claims 1 to 6, it is characterised in that: it is work that the export of electronics, which imports, Make normality.
9. electrochemical method for synthesizing as claimed in claim 7, it is characterised in that: it is work normality that the export of electronics, which imports,.
10. the electrochemical method for synthesizing as described in any one of claim 1 to 6 and 9, it is characterised in that: the substance A is set as hydrogen Gas, the substance B are set as carbon;Or the substance A is set as hydrogen, the substance B is set as carbon, the production of the electrochemical method for synthesizing Object is methane, ethane, propane or is octane.
11. electrochemical method for synthesizing as claimed in claim 7, it is characterised in that: the substance A is set as hydrogen, and the substance B is set For carbon;Or the substance A is set as hydrogen, the substance B is set as carbon, the product of the electrochemical method for synthesizing be methane, ethane, Propane is octane.
12. electrochemical method for synthesizing as claimed in claim 8, it is characterised in that: the substance A is set as hydrogen, and the substance B is set For carbon;Or the substance A is set as hydrogen, the substance B is set as carbon, the product of the electrochemical method for synthesizing be methane, ethane, Propane is octane.
13. the electrochemical method for synthesizing as described in any one of claim 1 to 6 and 9 and 11 and 12, it is characterised in that: the electricity Chemical regions rotation setting;Or, in the method including the electrochemistry region A and electrochemistry region B, the electrochemistry Region A rotation setting, the electrochemistry region B rotation setting.
14. electrochemical method for synthesizing as claimed in claim 7, it is characterised in that: the electrochemistry area rotation setting;Or, In method including the electrochemistry region A and the electrochemistry region B, the electrochemistry region A rotation setting, the electrification School district domain B rotation setting.
15. electrochemical method for synthesizing as claimed in claim 8, it is characterised in that: the electrochemistry area rotation setting;Or, In method including the electrochemistry region A and the electrochemistry region B, the electrochemistry region A rotation setting, the electrification School district domain B rotation setting.
16. electrochemical method for synthesizing as claimed in claim 10, it is characterised in that: the electrochemistry area rotation setting;Or, In method including the electrochemistry region A and the electrochemistry region B, the electrochemistry region A rotation setting, the electrification School district domain B rotation setting.
CN201910107799.7A 2018-08-26 2019-02-02 A kind of electrochemical method for synthesizing Pending CN109536983A (en)

Applications Claiming Priority (16)

Application Number Priority Date Filing Date Title
CN2018109771224 2018-08-26
CN201810977122 2018-08-26
CN201810983639 2018-08-27
CN2018109819647 2018-08-27
CN201810983010 2018-08-27
CN2018109836394 2018-08-27
CN201810983010X 2018-08-27
CN201810981964 2018-08-27
CN201810981960 2018-08-27
CN2018109819609 2018-08-27
CN2018110530892 2018-09-10
CN201811051522 2018-09-10
CN2018110515229 2018-09-10
CN201811053089 2018-09-10
CN201910036854 2019-01-15
CN2019100368548 2019-01-15

Publications (1)

Publication Number Publication Date
CN109536983A true CN109536983A (en) 2019-03-29

Family

ID=65838940

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910107799.7A Pending CN109536983A (en) 2018-08-26 2019-02-02 A kind of electrochemical method for synthesizing

Country Status (1)

Country Link
CN (1) CN109536983A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007273190A (en) * 2006-03-30 2007-10-18 Shinshu Univ Method of manufacturing composite material, filter and diffusion layer for fuel cell
CN105637123A (en) * 2013-07-31 2016-06-01 奥克海德莱克斯控股有限公司 Electro-synthetic or electro-energy cell with gas diffusion electrode(s)

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007273190A (en) * 2006-03-30 2007-10-18 Shinshu Univ Method of manufacturing composite material, filter and diffusion layer for fuel cell
CN105637123A (en) * 2013-07-31 2016-06-01 奥克海德莱克斯控股有限公司 Electro-synthetic or electro-energy cell with gas diffusion electrode(s)

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
屠振密: "《现代合金电沉积理论与技术》", 31 May 2016, 北京:国防工业出版社 *

Similar Documents

Publication Publication Date Title
US9096939B2 (en) Electrolysis transistor
CN103732799A (en) Membrane/electrode assembly for an electrolysis device
US3138487A (en) Fuel cell
CN108807006A (en) A kind of preparation method of carbon-based flexible electrode
US20180163313A1 (en) Combined magnetohydrodynamic and electrochemical method and corresponding apparatus for producing hydrogen
Geng et al. Revealing the electrocatalytic mechanism of layered crystalline CoMoO4 for water splitting: a theoretical study from facet selecting to active site engineering
CN109536983A (en) A kind of electrochemical method for synthesizing
Garamoun et al. Thin‐Film Silicon for Flexible Metal–Air Batteries
CN109536989A (en) A kind of electrochemistry formated device
CN107665981B (en) It is a kind of using the ionic liquid containing chlorine as the battery of positive active material and its assemble method
CN109797401A (en) A kind of electrolytic method
CN211479869U (en) Capacitor
CN109735868A (en) A kind of electrolysis unit
CN211479874U (en) Capacitor
CN211479867U (en) Capacitor
KR840004616A (en) Improved dual layer energy storage
CN107666016B (en) It is a kind of using the ionic liquid containing iodine as the battery of positive active material and its assemble method
CN109786792A (en) A kind of chemical energy electric energy conversion method
CN109786802A (en) A kind of electrochemical reaction implementation method
CN109802203A (en) A kind of electrochemical appliance
Lehman-Chong et al. Improving the Selectivity of High Temperature Electrochemical Ammonia Synthesis Using Solid Oxide Proton Conducting Electrolytes
RU2277274C1 (en) Method for converting chemical material energy into ac current energy
Lu et al. A novel PdC monolayer with fully dispersed Pd atoms and a rigid carbon backbone: an intrinsic versatile electrocatalyst for overall water splitting and the corresponding reverse reaction
US20240014409A1 (en) Electrode For A Redox Flow Battery, Redox Flow Battery And Hydrogen Generation With A Redox Flow Battery
CN109802205A (en) A kind of electrochemical appliance

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20190329