CN110634674A - Capacitor - Google Patents

Capacitor Download PDF

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Publication number
CN110634674A
CN110634674A CN201910950495.7A CN201910950495A CN110634674A CN 110634674 A CN110634674 A CN 110634674A CN 201910950495 A CN201910950495 A CN 201910950495A CN 110634674 A CN110634674 A CN 110634674A
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CN
China
Prior art keywords
porous
conductive film
conductor
insulating medium
capacitor
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910950495.7A
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Chinese (zh)
Inventor
靳北彪
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Entropy Zero Technology Logic Engineering Group Co Ltd
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Entropy Zero Technology Logic Engineering Group Co Ltd
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Publication of CN110634674A publication Critical patent/CN110634674A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/005Electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/005Electrodes
    • H01G4/008Selection of materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/018Dielectrics
    • H01G4/06Solid dielectrics
    • H01G4/08Inorganic dielectrics
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/018Dielectrics
    • H01G4/06Solid dielectrics
    • H01G4/14Organic dielectrics
    • H01G4/18Organic dielectrics of synthetic material, e.g. derivatives of cellulose
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13Energy storage using capacitors

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)

Abstract

The invention discloses a capacitor, which comprises a porous electric conductor A and a porous electric conductor B, wherein an insulating medium is laid on one side of the porous electric conductor A, an insulating medium is laid on one side of the porous electric conductor B, and the porous electric conductor A, the insulating medium and the porous electric conductor B are sequentially and correspondingly arranged. The capacitor disclosed by the invention has the advantages of simple structure, small volume, large capacity and the like, and when the capacitor comprises at least one electrochemical region, the capacitor can also be used for generating power and applied to units or systems with related functional requirements.

Description

Capacitor
Technical Field
The invention relates to the field of electricity, in particular to a capacitor.
Background
Capacitors are widely used in the electronics industry, and capacitors are also widely used as power storage devices, such as supercapacitors, but the capacitors so far have either small capacity or include liquid electrolytes, which seriously hamper the wider development and application of capacitors (especially power capacitors). It would be of great significance if a large capacity, small volume capacitor could be created that did not require a liquid electrolyte. Therefore, a new capacitor needs to be invented.
Disclosure of Invention
In order to solve the above problems, the technical solution proposed by the present invention is as follows:
scheme 1: a capacitor comprises a porous conductor A and a porous conductor B, wherein an insulating medium is laid on one side of the porous conductor A, an insulating medium is laid on one side of the porous conductor B, and the porous conductor A, the insulating medium and the porous conductor B are sequentially arranged correspondingly.
Scheme 2: in addition to the embodiment 1, at least one of the porous electric conductor a and the porous electric conductor B is further selectively provided as an electrochemical region provided in communication with an oxidizing agent supply passage and/or a reducing agent supply passage.
Scheme 3: a capacitor comprises a porous electric conductor A and a porous electric conductor B, wherein an insulating medium is laid in a seeping hole on one side of the porous electric conductor A, an insulating medium is laid in a seeping hole on one side of the porous electric conductor B, and the porous electric conductor A, the insulating medium and the porous electric conductor B are sequentially and correspondingly arranged.
Scheme 4: in addition to the embodiment 3, at least one of the porous electric conductor a and the porous electric conductor B is further selectively provided as an electrochemical region provided in communication with the oxidizing agent supply passage and/or the reducing agent supply passage.
Scheme 5: in addition to any one of the embodiments 1 to 4, the porous conductor a and/or the porous conductor B is further selectively provided as graphene, a porous carbon material, a microporous conductive material, or a nanoporous conductive material.
Scheme 6: a capacitor comprises a porous conductive film A and a porous conductive film B, wherein an insulating medium is laid on one side of the porous conductive film A, an insulating medium is laid on one side of the porous conductive film B, and the porous conductive film A, the insulating medium and the porous conductive film B are sequentially and correspondingly arranged.
Scheme 7: on the basis of the embodiment 6, at least one of the porous conductive film a and the porous conductive film B is further selectively provided as an electrochemical region provided in communication with an oxidizing agent supply passage and/or a reducing agent supply passage.
Scheme 8: a capacitor comprises a porous conductive film A and a porous conductive film B, wherein an insulating medium is laid in a seeping hole on one side of the porous conductive film A, an insulating medium is laid in a seeping hole on one side of the porous conductive film B, and the porous conductive film A, the insulating medium and the porous conductive film B are sequentially and correspondingly arranged.
Scheme 9: on the basis of the embodiment 8, at least one of the porous conductive film a and the porous conductive film B is further selectively provided as an electrochemical region provided in communication with an oxidizing agent supply passage and/or a reducing agent supply passage.
Scheme 10: on the basis of any one of the schemes 6 to 9, it is further selectively selected that the porous conductive thin film a and/or the porous conductive thin film B is provided with graphene, a porous carbon material, a microporous conductive material, or a nanoporous conductive material.
In the foregoing aspect of the present invention, the insulating dielectric may be further selectively formed as an insulating dielectric film.
All of the foregoing aspects of the present invention may further optionally be selected such that the insulating medium comprises polyimide, or is provided as a nanodiamond material.
In the present invention, the term "electrochemical region" refers to any region in which an electrochemical reaction can occur, and includes, for example, a catalyst, an ultrastructure, and/or a region at a predetermined temperature (for example, an electrode in a fuel cell), and further, for example, a metal region at a predetermined temperature.
In the present invention, the so-called electrochemical region is selectively set to a region excluding the catalyst at a certain temperature and/or pressure, because high temperature and high pressure are also a catalytic process for promoting the reaction.
In the present invention, the term "porous" refers to a state in which a part of the insulating medium penetrates into the pores of the porous conductive material.
In the present invention, "plating" refers to a form of plating on a solid surface.
In the invention, the insulating medium can be arranged with holes or without holes.
In the present invention, the term "non-electron charged particles" refers to charged particles other than electrons, such as protons or ions.
In the invention, the reducing agent is a simple substance, a compound or a mixture, and ions or ionic solutions do not belong to the reducing agent.
In the invention, the oxidant is a simple substance, a compound or a mixture, and ions or ionic solutions do not belong to the oxidant.
In the present invention, the addition of letters such as "a" and "B" to a name of a certain component is merely to distinguish two or more components having the same name.
In the present invention, necessary components, units, systems, etc. should be provided where necessary according to a well-known technique in the electrical field.
The capacitor has the advantages of simple structure, small volume, large capacity and the like, and when the capacitor comprises at least one electrochemical region, the capacitor can also be used for generating power and applied to units or systems with related functional requirements.
Drawings
FIG. 1: the structure of embodiment 1 of the invention is schematically shown;
FIG. 2: the structure of embodiment 2 of the invention is schematically shown;
FIG. 3: the structure of embodiment 3 of the invention is schematically illustrated;
FIG. 4: the structure of embodiment 4 of the invention is schematically illustrated;
FIG. 5: the structure of embodiment 5 of the invention is schematically illustrated;
FIG. 6: the structure of embodiment 6 of the invention is schematically illustrated;
in the figure: 1 porous conductor a, 2 porous conductor B, 3 insulating medium, 4 porous conductive film a, 5 porous conductive film B, 6 current collector a, 7 current collector B.
Detailed Description
Example 1
The capacitor shown in fig. 1 comprises a porous conductor a1 and a porous conductor B2, wherein an insulating medium 3 is laid on one side of the porous conductor a1, an insulating medium 3 is laid on one side of the porous conductor B2, the porous conductor a1, the insulating medium 3 and the porous conductor B2 are arranged in sequence, and the porous conductor a1 and the porous conductor B2 are arranged in an insulating manner through the insulating medium 3.
As a changeable embodiment, in example 1 of the present invention, the application may be further selectively set to spray application, plating application, or sputtering application.
Example 2
The capacitor as shown in fig. 2 comprises a porous conductor A1 and a porous conductor B2, wherein an insulating medium 3 is arranged on one side of the porous conductor A1 in a porous mode, the insulating medium 3 is arranged on one side of the porous conductor B2 in a porous mode, the porous conductor A1, the insulating medium 3 and the porous conductor B2 are sequentially arranged in a corresponding mode, and the porous conductor A1 and the porous conductor B2 are arranged in an insulating mode through the insulating medium 3.
As a variable embodiment, in example 2 of the present invention, the porous coating may be further selectively applied by porous spraying, porous plating, or porous sputtering.
As a switchable embodiment, in each of examples 1 and 2 and the switchable embodiment thereof of the present invention, the porous conductor a1 and the porous conductor B2 may be made of the same material or different materials.
As a switchable embodiment, all the aforementioned embodiments of the present invention can be further selected to make the porous electric conductor a1 and/or the porous electric conductor B2 be graphene, a porous carbon material, a microporous electric conductive material or a nanoporous electric conductive material.
As a switchable embodiment, in each of examples 1 and 2 of the present invention, a current collector is selectively provided on one side of the porous conductor a1, a current collector is selectively provided on one side of the porous conductor B2, and the current collectors are provided as two electrodes of the capacitor.
Example 3
A capacitor as shown in fig. 3 includes a porous conductive film A4 and a porous conductive film B5, an insulating medium 3 is laid on one side of the porous conductive film A4, an insulating medium 3 is laid on one side of the porous conductive film B5, the porous conductive film A4, the insulating medium 3 and the porous conductive film B5 are sequentially disposed correspondingly, and the porous conductive film A4 and the porous conductive film B5 are disposed in an insulating manner through the insulating medium 3.
As a changeable embodiment, in example 3 of the present invention, the application may be further selectively set to spray application, plating application, or sputtering application.
Example 4
A capacitor as shown in fig. 4 includes a porous conductive film A4 and a porous conductive film B5, an insulating medium 3 is applied to one side of the porous conductive film A4, an insulating medium 3 is applied to one side of the porous conductive film B5, the porous conductive film A4, the insulating medium 3 and the porous conductive film B5 are sequentially disposed correspondingly, and the porous conductive film A4 and the porous conductive film B5 are disposed in an insulating manner through the insulating medium 3.
As a variable embodiment, in example 4 of the present invention, the porous coating may be further selectively applied by porous spraying, porous plating, or porous sputtering.
As a switchable embodiment mode, each of example 3 and example 4 of the present invention can be further selectively selected to set the porous conductive film A4 and the porous conductive film B5 to be the same material or to be different materials.
As a switchable embodiment, examples 3 and 4 of the present invention and the switchable embodiment thereof may be further selectively selected such that the porous conductive thin film A4 and/or the porous conductive thin film B5 is provided as graphene, a porous carbon material, a microporous conductive material, or as a nanoporous conductive material.
As a switchable embodiment, examples 3 and 4 of the present invention and the switchable embodiment thereof can be selected such that a current collector is provided on the porous conductive film A4, a current collector is provided on the porous conductive film B5, and the current collectors can be selected such that the two electrodes of the capacitor are provided.
Example 5
The capacitor shown in fig. 5 includes a porous conductor a1 and a porous conductor B2, an insulating medium 3 is laid on one side of the porous conductor a1, the insulating medium 3 is laid on one side of the porous conductor B2, the porous conductor a1, the insulating medium 3 and the porous conductor B2 are arranged in order, the porous conductor a1 and the porous conductor B2 are arranged in an insulating manner via the insulating medium 3, a current collector A6 is arranged on one side of the porous conductor a1, a current collector B7 is arranged on the porous conductor B2, and the current collector A6 and the current collector B7 are arranged as two electrodes of the capacitor.
Example 6
A capacitor as shown in fig. 6, comprising a porous conductive film A4 and a porous conductive film B5, wherein an insulating medium 3 is applied to a side of the porous conductive film A4, an insulating medium 3 is applied to a side of the porous conductive film B5, the porous conductive film A4, the insulating medium 3 and the porous conductive film B5 are sequentially disposed in correspondence, the porous conductive film A4 and the porous conductive film B5 are disposed in insulation via the insulating medium 3, a current collector A6 is disposed on a side of the porous conductive film A4, a current collector B7 is disposed on a side of the porous conductive film B5, and the current collector A6 and the current collector B7 are disposed as two electrodes of the capacitor.
As a changeable embodiment, in all the embodiments of the present invention including the porous electric conductor a1 and the porous electric conductor B2, at least one of the porous electric conductor a1 and the porous electric conductor B2 may be further selectively provided as an electrochemical region, and the electrochemical region may be provided so as to communicate with an oxidizing agent supply channel and/or a reducing agent supply channel.
As a changeable embodiment, all the aforementioned embodiments of the present invention including the porous conductive film A4 and the porous conductive film B5 may further selectively provide that at least one of the porous conductive film A4 and the porous conductive film B5 is provided as an electrochemical region, and the electrochemical region is provided in communication with an oxidant supply channel and/or a reducing agent supply channel.
As a changeable embodiment, all the aforementioned embodiments of the present invention may further selectively provide the insulating medium 3 as an insulating medium film.
As alternative embodiments, all the aforementioned embodiments of the present invention may further selectively choose to make the insulating medium 3 include polyimide, or to make the insulating medium 3 be a nanodiamond material.
As a changeable embodiment, the insulating medium 3 in the embodiment of the present invention may be provided with holes or may be provided without holes.
In the specific implementation of all the aforementioned embodiments of the present invention that include the electrochemical region (e.g., the porous conductor a1, the porous conductor B2, the porous conductive film A4, or the porous conductive film B5), the capacitor may selectively include one of the electrochemical regions, and specifically, the reducing agent decomposes electrons and non-electron charged particles in the electrochemical region, so that the process of extracting the electrons can realize external power supply. In specific implementation, the electrochemical region can be further selectively positioned in the space where the reducing agent is positioned or positioned in the cavity, and the reducing agent is supplied to the cavity through the reducing agent supply passage.
In the specific implementation of all the aforementioned embodiments of the present invention including the electrochemical region (for example, the porous conductor a1, the porous conductor B2, the porous conductive powder A6, or the porous conductive powder B7), the capacitor may be selectively made to include the electrochemical region a and the electrochemical region B, specifically, the reducing agent decomposes electrons and non-electron charged particles in the electrochemical region a, and the generated electrons are extracted, and the external power supply may be realized in the process of extracting electrons. And the generated electrons can be further selectively introduced into the electrochemical area B and participate in a reaction with an oxidizing agent introduced into the electrochemical area B, the oxidizing agent can be provided for the electrochemical area A after the electrons are extracted, a reducing agent is provided for the electrochemical area B, the reducing agent is decomposed to generate electrons and non-electron charged particles, the electrons in the electrochemical area B are extracted into the electrochemical area A, the extraction process of the electrons is externally supplied with electricity, the electrons are introduced into the electrochemical area A and then react with the oxidizing agent and the non-electron charged particles, and the products can be further selectively discharged through a physical method. The electrochemical region B may be further selectively supplied with an oxidant that reacts with the electrons supplied by the electrochemical region a and the non-electronically charged particles generated therefrom, and the resultant may be further selectively physically discharged.
The principle of the capacitor comprising the alternative action of the reducing agent and the oxidizing agent disclosed by the invention is as follows: alternately contacting an electrochemical region A with a reducing agent and an oxidizing agent or alternately contacting a reducing agent and an oxidizing agent with an electrochemical region A, alternately contacting an electrochemical region B with an oxidizing agent and a reducing agent or alternately contacting an oxidizing agent and a reducing agent with an electrochemical region B, generating positively charged particles and electrons in the electrochemical region A by the reducing agent, conducting electrons from the electrochemical region A to the electrochemical region B, allowing the oxidizing agent and electrons to coexist in the electrochemical region B, generating the positively charged particles and electrons in the electrochemical region B by the reducing agent, introducing electrons from the electrochemical region B to the electrochemical region A, reacting the positively charged particles, the oxidizing agent and the electrons in the electrochemical region A to generate a reaction product of the reducing agent and the oxidizing agent, and reacting the positively charged particles, the oxidizing agent and the electrons in the electrochemical region B to generate a reaction product of the reducing agent and the oxidizing agent, The oxidant reacts with the electrons to generate a reaction product of the reductant and the oxidant, and the output electric energy is realized by the lead-out and lead-in of the electrons between the electrochemical region a and the electrochemical region B, so that the continuous working process is realized (when the electrons are led from the electrochemical region a to the electrochemical region B, in some cases, the electrons react with the oxidant in the electrochemical region B to generate negatively charged particles C, the negatively charged particles C react with the positively charged particles in the electrochemical region B to generate a reaction product of the reductant and the oxidant, and the output electric energy is realized by the lead-out and lead-in of the electrons between the electrochemical region a and the electrochemical region B, so that the continuous working process is realized).
In the above embodiment, for example, in the same embodiment, the oxidizing agent may be air, and the reducing agent may be hydrogen gas or a gas containing hydrogen gas, and in this case, the non-electron charged particles may be protons. For example, in the same embodiment, the oxidizing agent may be air, and the reducing agent may be an alcohol (e.g., methanol, ethanol, etc.), and the non-electron charged particles may also be protons.
In the practice of all the above embodiments of the present invention using an oxidant, the oxidant can be selected from oxygen, compressed air, oxygen, liquid oxygen air, liquefied air, etc.
In the specific implementation of all the above embodiments of the present invention containing the reducing agent, the reducing agent can be selected from hydrogen, methane, methanol, ethanol, natural gas, coal gas, etc.
The attached drawings are only schematic, and any technical scheme meeting the written description of the application shall belong to the protection scope of the application.
Obviously, the present invention is not limited to the above embodiments, and many modifications can be derived or suggested according to the known technology in the field and the technical solutions disclosed in the present invention, and all of the modifications should be considered as the protection scope of the present invention.

Claims (10)

1. A capacitor comprising a porous conductor A (1) and a porous conductor B (2), characterized in that: laying an insulating medium (3) on one side of the porous conductor A (1), laying an insulating medium (3) on one side of the porous conductor B (2), and sequentially and correspondingly arranging the porous conductor A (1), the insulating medium (3) and the porous conductor B (2).
2. The capacitor of claim 1, wherein: at least one of the porous electric conductor A (1) and the porous electric conductor B (2) is provided as an electrochemical region, and the electrochemical region is provided in communication with an oxidizing agent supply passage and/or a reducing agent supply passage.
3. A capacitor comprising a porous conductor A (1) and a porous conductor B (2), characterized in that: and an insulating medium (3) is arranged on one side of the porous conductor A (1) in a porous way, an insulating medium (3) is arranged on one side of the porous conductor B (2) in a porous way, and the porous conductor A (1), the insulating medium (3) and the porous conductor B (2) are sequentially and correspondingly arranged.
4. A capacitor as claimed in claim 3, wherein: at least one of the porous electric conductor A (1) and the porous electric conductor B (2) is provided as an electrochemical region, and the electrochemical region is provided in communication with an oxidizing agent supply passage and/or a reducing agent supply passage.
5. The capacitor according to any one of claims 1 to 4, wherein: the porous conductor A (1) and/or the porous conductor B (2) are/is provided with graphene, a porous carbon material, a micro-porous conductive material or a nano-porous conductive material.
6. A capacitor comprising a porous conductive film A (4) and a porous conductive film B (5), characterized in that: laying an insulating medium (3) on one side of the porous conductive film A (4), laying an insulating medium (3) on one side of the porous conductive film B (5), and sequentially and correspondingly arranging the porous conductive film A (4), the insulating medium (3) and the porous conductive film B (5).
7. The capacitor of claim 6, wherein: at least one of the porous conductive film a (4) and the porous conductive film B (5) is provided as an electrochemical region provided in communication with an oxidant supply passage and/or a reducing agent supply passage.
8. A capacitor comprising a porous conductive film A (4) and a porous conductive film B (5), characterized in that: and an insulating medium (3) is laid in a porous hole on one side of the porous conductive film A (4), an insulating medium (3) is laid in a porous hole on one side of the porous conductive film B (5), and the porous conductive film A (4), the insulating medium (3) and the porous conductive film B (5) are sequentially and correspondingly arranged.
9. The capacitor of claim 8, wherein: at least one of the porous conductive film a (4) and the porous conductive film B (5) is provided as an electrochemical region provided in communication with an oxidant supply passage and/or a reducing agent supply passage.
10. A capacitor as claimed in any one of claims 6 to 9, wherein: the porous conductive film A (4) and/or the porous conductive film B (5) are provided with graphene, porous carbon materials, micro-porous conductive materials or nano-porous conductive materials.
CN201910950495.7A 2018-10-05 2019-10-08 Capacitor Pending CN110634674A (en)

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CN2018111644176 2018-10-05

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Publication number Priority date Publication date Assignee Title
CN211479869U (en) * 2018-10-05 2020-09-11 熵零技术逻辑工程院集团股份有限公司 Capacitor

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2352689A1 (en) * 2000-07-26 2002-01-26 Litton Systems, Inc. Thin film modular electrochemical apparatus and method of manufacture therefor
CN1685539A (en) * 2002-08-24 2005-10-19 德古萨公司 Separator-electrode unit for lithium-ion batteries, method for the production and use thereof in lithium batteries
CN102208671A (en) * 2011-05-13 2011-10-05 合肥学院 Microbiological fuel cell
CN107331527A (en) * 2017-08-30 2017-11-07 顾天罡 A kind of vast capacity ultracapacitor
CN211479869U (en) * 2018-10-05 2020-09-11 熵零技术逻辑工程院集团股份有限公司 Capacitor

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2352689A1 (en) * 2000-07-26 2002-01-26 Litton Systems, Inc. Thin film modular electrochemical apparatus and method of manufacture therefor
CN1685539A (en) * 2002-08-24 2005-10-19 德古萨公司 Separator-electrode unit for lithium-ion batteries, method for the production and use thereof in lithium batteries
CN102208671A (en) * 2011-05-13 2011-10-05 合肥学院 Microbiological fuel cell
CN107331527A (en) * 2017-08-30 2017-11-07 顾天罡 A kind of vast capacity ultracapacitor
CN211479869U (en) * 2018-10-05 2020-09-11 熵零技术逻辑工程院集团股份有限公司 Capacitor

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