CN109860679A - A kind of chemical energy device for converting electric energy - Google Patents
A kind of chemical energy device for converting electric energy Download PDFInfo
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- CN109860679A CN109860679A CN201910107998.8A CN201910107998A CN109860679A CN 109860679 A CN109860679 A CN 109860679A CN 201910107998 A CN201910107998 A CN 201910107998A CN 109860679 A CN109860679 A CN 109860679A
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- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 418
- 239000007800 oxidant agent Substances 0.000 claims abstract description 268
- 230000001590 oxidative effect Effects 0.000 claims abstract description 267
- 230000005611 electricity Effects 0.000 claims abstract description 206
- 239000000203 mixture Substances 0.000 claims abstract description 130
- 239000003792 electrolyte Substances 0.000 claims abstract description 75
- 239000007787 solid Substances 0.000 claims abstract description 51
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- 230000009467 reduction Effects 0.000 claims abstract description 16
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- 238000000108 ultra-filtration Methods 0.000 claims description 101
- -1 dielectric Substances 0.000 claims description 90
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- 229910052760 oxygen Inorganic materials 0.000 claims description 25
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- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 10
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- 229910052782 aluminium Inorganic materials 0.000 claims description 10
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- 229910052742 iron Inorganic materials 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 229910052744 lithium Inorganic materials 0.000 claims description 10
- 229910052725 zinc Inorganic materials 0.000 claims description 10
- 239000011701 zinc Substances 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 9
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- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 9
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 9
- 229910052791 calcium Inorganic materials 0.000 claims description 9
- 239000011575 calcium Substances 0.000 claims description 9
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
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- OMOVVBIIQSXZSZ-UHFFFAOYSA-N [6-(4-acetyloxy-5,9a-dimethyl-2,7-dioxo-4,5a,6,9-tetrahydro-3h-pyrano[3,4-b]oxepin-5-yl)-5-formyloxy-3-(furan-3-yl)-3a-methyl-7-methylidene-1a,2,3,4,5,6-hexahydroindeno[1,7a-b]oxiren-4-yl] 2-hydroxy-3-methylpentanoate Chemical compound CC12C(OC(=O)C(O)C(C)CC)C(OC=O)C(C3(C)C(CC(=O)OC4(C)COC(=O)CC43)OC(C)=O)C(=C)C32OC3CC1C=1C=COC=1 OMOVVBIIQSXZSZ-UHFFFAOYSA-N 0.000 description 190
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The invention discloses a kind of chemical energy device for converting electric energy, including region A, the region A is connected to setting with conductive reducing agent feed channel, and the region A is connected to setting with oxidant feed channel, and the region A includes the area alternating current Jie electricity.Chemical energy device for converting electric energy disclosed in this invention will terminate conventional electrochemical device (such as fuel cell etc.) with the history for existing for necessary condition of electrolyte (such as proton exchange membrane and solid oxide electrolyte etc.), the conventional electrochemical device that terminates also can not be used securely and reliably to the history of oxidant reduction agent composition, exploitation for efficient, long-life, Low-cost electric chemical devices provides new approach, and will redefine engine.
Description
Technical field
The present invention relates to electricity field, electrochemical field more particularly to a kind of chemical energy device for converting electric energy.
Background technique
Conventional electrochemical method is required to non-electronic charged particle (such as ion or proton) and transmits between two electrodes, that is, needs
Positive charged particle and negative charged particles that electrochemistry region (electrode) generates are removed, non-electronic charged particle is in two interpolars
Transmission not only consume electric energy, but also be required to conduct non-electronic charged particle non-conducting electronics and there are many particular/special requirements
Electrolyte (such as proton exchange membrane and solid oxide electrolyte etc. of hydrogen fuel cell), because of its complexity, this electrolysis
The manufacturing technology of matter is unqualified always, and has become and restrict electrochemical method and be efficiently widely applied and its electrochemical appliance (example
Such as fuel cell) improved efficiency, the basic reason of life-span upgrading and cost reduction, also have become and hinders electrochemical appliance (example
Such as fuel cell) efficiently industrialization problem the most serious.If can invent a kind of not non-to be removed from electrochemistry region
Electronics charged particle is the new chemical energy device for converting electric energy of necessary condition, and termination Conventional electrochemical method and electrochemistry are filled
(such as fuel cell etc.) is set to the history of electrolyte (such as proton exchange membrane and solid oxide electrolyte etc.) demand, also will
Exploitation for efficient, long-life, Low-cost electric chemical devices provides new approach.Therefore, it is necessary to invent a kind of new chemical energy
Device for converting electric energy.
Summary of the invention
To solve the above-mentioned problems, technical solution proposed by the present invention is as follows:
A kind of chemical energy device for converting electric energy of scheme 1., including region A, the region A and conductive reducing agent feed channel
Connection setting, the region A are connected to setting with oxidant feed channel, and the region A includes the area alternating current Jie electricity;
Or, the region A is connected to setting, the region A packet with the mixture feed channel of conductive reducing agent and oxidant
Include the area alternating current Jie electricity;
Or, the region A is connected to setting with conductive reducing agent feed channel, the region A and oxidant feed channel connect
Reducing agent control switch A is arranged on the conductive reducing agent feed channel in logical setting, and the reducing agent control switch A is controlled
Device control processed is discontinuously opened, and the region A includes the area alternating current Jie electricity;
Or, the region A is connected to setting with conductive reducing agent feed channel, the region A and oxidant feed channel connect
Logical setting, is arranged oxidant control switch A on oxidant feed channel, and the oxidant control switch A is filled by control
It sets control discontinuously to open, the region A includes the area alternating current Jie electricity.
Scheme 2. is further arranged the region A and electric conductor and closes with non-electronic conducting electricity on the basis of scheme 1
System, or, the region A and insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion-gas
At least one of body, solion and electronic conduction area have non-electronic conducting electrical relation, or, it is described conduction reducing agent with
Insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronics
At least one of area, which is connected, has non-electronic conducting electrical relation.
A kind of chemical energy device for converting electric energy of scheme 3., including region A and region B, the region A and conductive reducing agent supply
Channel connection setting is sent, the region A is connected to setting with oxidant feed channel, and the region A includes the area alternating current Jie electricity,
The region B includes the area alternating current Jie electricity;
Or, the region A is connected to setting, the region A packet with the mixture feed channel of conductive reducing agent and oxidant
The area alternating current Jie electricity is included, the region B includes the area alternating current Jie electricity;
Or, the region A is connected to setting with conductive reducing agent feed channel, the region A and oxidant feed channel connect
Reducing agent control switch A is arranged on the conductive reducing agent feed channel in logical setting, and the reducing agent control switch A is controlled
Device control processed is discontinuously opened, and the region A includes the area alternating current Jie electricity, and the region B includes the area alternating current Jie electricity;
Or, the region A is connected to setting with conductive reducing agent feed channel, the region A and oxidant feed channel connect
Logical setting, is arranged oxidant control switch A on oxidant feed channel, and the oxidant control switch A is filled by control
It sets control discontinuously to open, the region A includes the area alternating current Jie electricity, and the region B includes the area alternating current Jie electricity.
For scheme 4. on the basis of scheme 3, the region A and region B, which is further arranged, has non-electronic electric conduction
Relationship or the region B and the conductive reducing agent have non-electronic conducting electrical relation;
Or, the region A through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, from
At least one of sub- gas, solion and electronic conduction area have non-electronic conducting electrical relation with the region B, or,
The conduction reducing agent is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion-gas
At least one of body, solion and electronic conduction area have non-electronic conducting electrical relation with the region B.
A kind of chemical energy device for converting electric energy of scheme 5., including region A and region B, the region A and conductive reducing agent supply
Channel connection setting is sent, the region A is connected to setting with oxidant feed channel, and the region B and conductive reducing agent feed are logical
Road connection setting, the region B are connected to setting with oxidant feed channel, and the region A includes the area alternating current Jie electricity, described
Region B includes the area alternating current Jie electricity;
Or, the region A is connected to setting, the area with conductive reducing agent feed channel through conductive reducing agent feed switch A
Domain A is connected to setting with oxidant feed channel, and the region B is logical through conductive reducing agent feed switch B and conductive reducing agent feed
Road connection setting, the region B are connected to setting with oxidant feed channel, and the region A includes the area alternating current Jie electricity, described
Region B includes the area alternating current Jie electricity;
Or, the region A be connected to setting with conductive reducing agent feed channel, the region A through oxidant feed switch A and
The connection setting of oxidant feed channel, the region B are connected to setting with conductive reducing agent feed channel, and the region B is through aoxidizing
Agent feed switch B is connected to setting with oxidant feed channel, and the region A includes the area alternating current Jie electricity, the region B packet
Include the area alternating current Jie electricity;
Or, the region A is connected to setting, the area with conductive reducing agent feed channel through conductive reducing agent feed switch A
Domain A is connected to setting with oxidant feed channel through oxidant feed switch A, and the region B is through conductive reducing agent feed switch B
Setting is connected to conductive reducing agent feed channel, the region B is connected to oxidant feed channel through oxidant feed switch B and sets
It sets, the region A includes the area alternating current Jie electricity, and the region B includes the area alternating current Jie electricity;
Or, the region A is connected to setting, the area with conductive reducing agent feed channel through conductive reducing agent feed switch A
Domain A is connected to setting with oxidant feed channel through oxidant feed switch A, and the region B is through conductive reducing agent feed switch B
Setting is connected to conductive reducing agent feed channel, the region B is connected to oxidant feed channel through oxidant feed switch B and sets
It sets, the region A includes the area alternating current Jie electricity, and the region B includes the area alternating current Jie electricity, the conduction reducing agent feed
Switch A, the conductive reducing agent feed switch B, the oxidant feed switch A and the oxidant feed switch B are controlled
Device control;Realize the conduction reducing agent feed switch A and conduction reducing agent feed switch B unlatching and the oxidant
Feed switch A and the oxidant feed switch B are discontinuously opened, or are realized the conduction reducing agent feed switch A and described led
Electroreduction agent feed switch B is discontinuously opened and the oxidant feed switch A and oxidant feed switch B is opened, or real
The existing oxidant feed switch A and conduction reducing agent feed switch B is discontinuously opened and the conductive reducing agent feed is opened
The A and oxidant feed switch B is closed to open;
Or, the region A be connected to setting with the mixture feed channel of conductive reducing agent and oxidant, the region B and
Conductive reducing agent is connected to setting with the mixture feed channel of oxidant, and the region A includes the area alternating current Jie electricity, the area
Domain B includes the area alternating current Jie electricity;
Or, the region A is connected to through mixture control switch A with the mixture feed channel of conductive reducing agent and oxidant
Setting, the region B are connected to setting with the mixture feed channel of conductive reducing agent and oxidant through mixture control switch B,
The mixture control switch A and mixture control switch B is controlled interrupted unlatching by control device, and the region A includes
The area alternating current Jie electricity, the region B include the area alternating current Jie electricity.
For scheme 6. on the basis of scheme 5, the region A and region B, which is further arranged, has non-electronic electric conduction
The conductive reducing agent that relationship or the region A are contacted with the region B has non-electronic conducting electrical relation or the area
The conductive reducing agent that domain B is contacted with the region A has non-electronic conducting electrical relation, or the conduction contacted with the region A
Reducing agent and the conductive reducing agent contacted with the region B have non-electronic conducting electrical relation;
Or, the region A through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, from
At least one of sub- gas, solion and electronic conduction area have non-electronic conducting electrical relation with the region B, or,
The region A is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, ion
At least one of solution and electronic conduction area and the conductive reducing agent contacted with the region B are closed with non-electronic conducting electricity
System, or, the region B is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion-gas
At least one of body, solion and electronic conduction area and the conductive reducing agent contacted with the region A have non-electronic lead
Logical electrical relation, or, the conductive reducing agent contacted with the region A is through insulation, isolation space, electrolyte, dielectric, electricity
It at least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area and is connect with the region B
The conductive reducing agent of touching has non-electronic conducting electrical relation.
A kind of chemical energy device for converting electric energy of scheme 7., including conductive reducing agent, the conduction reducing agent and oxidant supply
Channel connection setting is sent, the conduction reducing agent includes the area alternating current Jie electricity;
Or, the conduction reducing agent is connected to setting with oxidant feed channel, the conduction reducing agent includes alternating current
The area Jie electricity, the conduction reducing agent and electric conductor have non-electronic conducting electrical relation, or, the conduction reducing agent is through completely cutting off
Body, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction
At least one of area has non-electronic conducting electrical relation with electric conductor, or, the conduction reducing agent and insulation, isolation sky
Between, in electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area at least
One kind having non-electronic conducting electrical relation.
A kind of chemical energy device for converting electric energy of scheme 8., including conductive reducing agent, the conduction reducing agent is through oxidant control
System switch A is connected to setting with oxidant feed channel, and the oxidant control switch A is controlled interrupted unlatching, institute by control device
Stating conductive reducing agent includes the area alternating current Jie electricity;
Or, the conduction reducing agent is connected to setting, the oxidant with oxidant feed channel through oxidant control switch A
Control switch A is controlled interrupted unlatching by control device, and the conduction reducing agent includes the area alternating current Jie electricity, the conductive reduction
Agent and electric conductor have non-electronic conducting electrical relation, or, the conduction reducing agent is through insulation, isolation space, electrolyte, electricity
At least one of medium, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area and electric conductor
With non-electronic conducting electrical relation, or, the conduction reducing agent and insulation, isolation space, electrolyte, dielectric, capacitor,
At least one of plasma, ionic liquid, ionized gas, solion and electronic conduction area have non-electronic conducting electricity
Relationship.
A kind of chemical energy device for converting electric energy of scheme 9., including conductive reducing agent and region B, the conduction reducing agent and oxygen
The connection setting of agent feed channel, the conduction reducing agent includes the area alternating current Jie electricity, and the region B includes that alternating current connects
Electric area;
Or, the conduction reducing agent is connected to setting with oxidant feed channel, the conduction reducing agent includes alternating current
The area Jie electricity, the region B include the area alternating current Jie electricity, and the conduction reducing agent and the region B have non-electronic electric conduction
Relationship, or, the conduction reducing agent is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid
At least one of body, ionized gas, solion and electronic conduction area are closed with the region B with non-electronic conducting electricity
System.
A kind of chemical energy device for converting electric energy of scheme 10., including conductive reducing agent and region B, the conduction reducing agent warp
Oxidant control switch A is connected to setting with oxidant feed channel, and the oxidant control switch A is controlled discontinuously by control device
It opens, the conduction reducing agent includes the area alternating current Jie electricity, and the region B includes the area alternating current Jie electricity;
Or, the conduction reducing agent is connected to setting, the oxidant with oxidant feed channel through oxidant control switch A
Control switch A is controlled interrupted unlatching by control device, and the conduction reducing agent includes the area alternating current Jie electricity, the region B packet
The area alternating current Jie electricity is included, the conduction reducing agent and the region B have non-electronic conducting electrical relation, or, the conduction
Reducing agent is molten through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, ion
At least one of liquid and electronic conduction area have non-electronic conducting electrical relation with the region B.
A kind of chemical energy device for converting electric energy of scheme 11., including conductive reducing agent, the conduction reducing agent include conductive go back
Former agent A and conductive reducing agent B, the conduction reducing agent A are connected to setting with oxidant feed channel, the conduction reducing agent B and
The connection setting of oxidant feed channel, the conduction reducing agent A includes the area alternating current Jie electricity, and the conduction reducing agent B includes
The area alternating current Jie electricity;
Or, conduction reducing agent A is connected to setting, conductive reducing agent B warp with oxidant feed channel through oxidant control switch A
Oxidant control switch B is connected to setting with oxidant feed channel, and the conduction reducing agent A includes the area alternating current Jie electricity, institute
Stating conductive reducing agent B includes the area alternating current Jie electricity;
Or, conduction reducing agent A is connected to setting, conductive reducing agent B warp with oxidant feed channel through oxidant control switch A
Oxidant control switch B is connected to setting with oxidant feed channel, and the oxidant control switch A and oxidant control are opened
It closes B and is controlled interrupted unlatching by control device, the conduction reducing agent A includes the area alternating current Jie electricity, the conduction reducing agent B packet
Include the area alternating current Jie electricity.
Scheme 12. has the conduction reducing agent A with the conduction reducing agent B on the basis of scheme 11
Non-electronic conducting electrical relation, or, the conduction reducing agent A through insulation, isolation space, electrolyte, dielectric, capacitor, etc.
At least one of gas ions, ionic liquid, ionized gas, solion and electronic conduction area have with the conduction reducing agent B
There is non-electronic conducting electrical relation.
Scheme 13. in scheme 1 to 12 on the basis of either a program, further by the conductive reducing agent be set as aluminium, zinc,
Iron, copper, tin, magnesium, sodium, potassium, calcium, carbon, lithium, mercury, lead, the solids including aluminium, the solids including zinc, the solid including iron
Object, the solids including copper, the solids including tin, the solids including magnesium, the solids including sodium, the solid including potassium
Object, the solids including calcium, the solids including lithium, the solids including mercury, the solids including lead, the solid including carbon
Object, fluidisation object, fluidisation object, fluidisation object, fluidisation object, the fluidisation including tin including copper including iron including zinc including aluminium
Object, fluidisation object, fluidisation object, fluidisation object, fluidisation object, the fluidisation including lithium including calcium including potassium including sodium including magnesium
Object, the fluidisation object including mercury, the fluidisation object including lead or be set as include carbon fluidisation object.
On the basis of either a program, the alternating current Jie electricity Qu Yu electricity is further arranged in scheme 1 to 13 in scheme 14.
Appearance, DC power supply, AC power source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, commutation are opened
Powered-down road, rectifier, electric field, oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction,
Its three conjunction, its four conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction,
Its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction tool
There is electrical relation.
Scheme 15. on the basis of either a program, further applies electricity to the conductive reducing agent and makees in scheme 1 to 14
With so that the conduction reducing agent is difficult to directly carry out redox reaction.
Scheme 16. on the basis of either a program, further hands over the output of the area the alternating current Jie electricity in scheme 1 to 15
Power transformation energy and/or absorption alternate electric energy are work normality.
Scheme 17. in scheme 1 to 16 on the basis of either a program, further by the oxidant be set as oxygen, air,
The mixture of air and oxygen has pressure air, compressed air or is set as hydrogen peroxide.
In the present invention, so-called " region " refers to the electrode of chemical energy device for converting electric energy.
In the present invention, so-called " conductive reducing agent " refers to the conductive reducing agent that can transmit electronics, alternative
Ground selection is set as the metals such as the i.e. conductive solid reductant, such as aluminium, magnesium, iron, zinc, lithium of conductive solids reducing agent.
In the present invention, the conduction reducing agent is optionally set as powder, fluidisation object.
In the present invention, when the conductive reducing agent is as electrode, the conduction reducing agent, which is selectively chosen, to be set as
Plate is set as fluidisation object.
In the present invention, so-called " inductor conductor " refers to all externally output magnetic force energy and leading from outer absorption magnetic force energy
Body.Such as transformer coil, electrical-coil, conductor bars for dynamoelectric machines etc..
In the present invention, so-called " phase converter " is the direction vector and its voltage for instigating electric current (or charged particle stream)
Angled device, the circuit for example including capacitor, the circuit including inductance and including capacitor also include inductance circuit
Deng.
Disclosed in this invention include that substance A, the principle of the scheme of substance B alternating action are as follows: make region A and substance
A and substance B alternately contact or make substance A and substance B alternately to contact with region A, and substance A is made to generate positive electrification in the region A
Particle and electronics export electronics from the region A, import electronics to the region A, are just charging described in the region A
Particle, the substance B and electron reaction generates the substance A and the substance B reacts product, utilize leading for electronics
It imports out and realizes output electric energy and/or absorb electric energy, so recycle, realization continues working process and (importing electricity to the region A
The period of the day from 11 p.m. to 1 a.m, in some cases, electronics, which is reacted in the region A with substance B, generates negative charged particles C, the negative charged particles C with
The product that the positive charged particle reaction generates the substance A and the substance B reacts is imported using the export of electronics
It realizes output electric energy and/or absorbs electric energy, so recycle, realization continues working process).In realizing this electrochemical process,
It is selectively chosen, the region A, external circuit, capacitor and reception and the region for electron constitute circuit and/or described
Region A, external circuit, non-electronic charged particle vibrate area and reception and constitute circuit for the region of electron.In this scheme,
Electro ultrafiltration can be implemented to the region A, electro ultrafiltration can control export and/or importing with strengthening electronic, thus can be with
It effectively avoids substance A and substance B from mixing and redox reaction directly occurs, improve safety, reliability and efficiency.In this side
In case, it can also first implement electro ultrafiltration to it before the region A and material effect, purpose is also to avoid substance A and object
Redox reaction directly occurs for matter B mixing, improves safety, reliability and efficiency.
Disclosed in this invention include substance A and substance B mixture effect scheme principle it is as follows: make region A
It contacts or makes the mixture of substance A and substance B to contact with region A with the mixture of substance A and substance B, make electricity using electro ultrafiltration
Son is exported from the region A, and then the substance A is made to form positive charged particle, and the region Xiang Suoshu A imports electronics, the positive band
Charged particle and the substance B and electron reaction generate the reaction product of the substance A and the substance B, next step, to institute
State region A import electronics, export electronics from the region A, under the action of electronics imports and exports, the substance A with it is described
Substance B reaction generates the reaction product of the substance A and the substance B, absorbs on the channel that electronics exports and/or imports
Electric energy and/or output electric energy, so recycle, and realization continues working process and (in some cases, importing electricity to the region A
The period of the day from 11 p.m. to 1 a.m, the substance B and electron reaction generate negative charged particles C, positive charged particle and the negative charging described in the region A
Particle C reaction generates the reaction product of the substance A and the substance B, absorbs on the channel that electronics exports and/or imports
Electric energy and/or output electric energy, so recycle, realization continues working process).It is alternative in realizing this electrochemical process
Ground selection, the region A, external circuit, capacitor and reception and the region for electron constitute circuit and/or the region A, outer
Circuit, non-electronic charged particle vibrate area and reception and constitute circuit for the region of electron.In this scheme, for effectively
Avoid the substance A and the substance B from mixing and redox reaction directly occur, can the region A and material effect it
Before, electro ultrafiltration first is implemented to it.
Disclosed in this invention include substance A and substance B the principle of scheme that discontinuously acts on of mixture it is as follows: except disconnected
Outside the influence of continuous effect, the complete phase of principle of the principle of this programme and the scheme for the mixture effect for including substance A and substance B
Together, interrupted function is that can be better protected from or eliminate substance A described in mixture and the substance B joins in electrode
The ability of redox reaction forfeiture output electric energy is directly carried out in the case where (the i.e. described region A participation), and then improves this
The efficiency of the disclosed scheme of invention is being mixed if following substance As and substance B mixture discontinuously act on shown in working principle diagram
Under the influence of object discontinuously acts on, a certain electrode may be implemented only exist substance A (except non-electronic charged particle) to function, and
Another electrode only exists the state that substance B (except non-electronic charged particle) functions, or realizes that a certain electrode only exists object
The high concentration object (except non-electronic charged particle) of matter A functions, and the high concentration object that another electrode only exists substance B is (non-
Except electronics charged particle) state that functions, any state either among these is all conducive to promote electrochemistry anti-
The efficiency answered.Certainly it is controlled as described above, being selectively chosen using external means (such as foreign current, external electrical field etc.)
The export of electronics imports step, promotes the efficiency of electrochemical reaction.Similarly, alternative in realizing this electrochemical process
Ground selection, the region A, external circuit, capacitor and reception and the region for electron constitute circuit and/or the region A, outer
Circuit, non-electronic charged particle vibrate area and reception and constitute circuit for the region of electron.
Disclosed in this invention include that substance A, the principle of the scheme of substance B alternating action are as follows: make region A and substance
A and substance B alternately contact or make substance A and substance B alternately to contact with region A, and substance A is made to generate positive electrification in the region A
Particle and electronics make electronics export to region B from the region A, import electronics from the region B to the region A, in institute
State that positive charged particle, the substance B and electron reaction described in the A of region generate the substance A and the substance B reacts
Product is imported using the export of the electronics between the region A and the region B and realizes output electric energy and/or absorb electric
Can, so recycle, realization continue working process (from the region B to the region A import electronics when, in some cases,
Electronics, which is reacted in the region A with substance B, generates negative charged particles C, the negative charged particles C and the positive charged particle reaction
It generates the substance A and product that the substance B reacts, utilizes the electronics between the region A and the region B
Export, which imports, to be realized output electric energy and/or absorbs electric energy, is so recycled, realization continues working process).Realizing this electrochemistry
In the process, it is selectively chosen, the region A, external circuit, capacitor and the region B constitute circuit and/or the region
A, external circuit, non-electronic charged particle oscillation area and the region B constitute circuit.It, can be to the region A in this scheme
Implement electro ultrafiltration, electro ultrafiltration can control export and/or importing with strengthening electronic, thus it is possible to prevente effectively from substance A and
Redox reaction directly occurs for substance B mixing, improves safety, reliability and efficiency.It, can also be in institute in this scheme
First implement electro ultrafiltration before stating region A and material effect to it, purpose is also to avoid substance A and substance B from mixing directly to occur
Redox reaction improves safety, reliability and efficiency.
Disclosed in this invention include substance A and substance B mixture effect scheme principle it is as follows: make region A
It contacts or makes the mixture of substance A and substance B to contact with region A with the mixture of substance A and substance B, make electricity using electro ultrafiltration
Son exports to region B from the region A, and then the substance A is made to form positive charged particle, from the region B to the region A
Electronics is imported, the positive charged particle generates the substance A with the substance B and electron reaction and reacting for the substance B is given birth to
At object, next step imports electronics from the region B to the region A, electronics is made to export to the region from the region A
B, under the action of the electronics between the region A and the region B imports and exports, the substance A reacts life with the substance B
At the reaction product of the substance A and the substance B, the export of electronics between the region A and the region B and/or
On the channel of importing absorb electric energy and/or output electric energy, so recycle, realization continue working process (in some cases, from
When the region B imports electronics to the region A, the substance B and electron reaction generate negative charged particles C, in the region A
The positive charged particle and negative charged particles C reaction generate the reaction product of the substance A and the substance B, in institute
It states and absorbs electric energy and/or output electric energy on the electronics export between region A and the region B and/or the channel imported, so follow
Ring, realization continue working process).In realizing this electrochemical process, be selectively chosen, the region A, external circuit,
Capacitor and the region B constitute circuit and/or the region A, external circuit, non-electronic charged particle oscillation area and the region B
Constitute circuit.It is anti-to be effectively prevented from the substance A and substance B mixing directly generation redox in this scheme
It answers, electro ultrafiltration first can be implemented to it before the region A and material effect.
Disclosed in this invention include substance A and substance B the principle of scheme that discontinuously acts on of mixture it is as follows: except disconnected
Outside the influence of continuous effect, the complete phase of principle of the principle of this programme and the scheme for the mixture effect for including substance A and substance B
Together, interrupted function is that can be better protected from or eliminate substance A described in mixture and the substance B joins in electrode
The ability of redox reaction forfeiture output electric energy is directly carried out in the case where (the i.e. described region A participation), and then improves this
The efficiency of the disclosed scheme of invention is being mixed if following substance As and substance B mixture discontinuously act on shown in working principle diagram
Under the influence of object discontinuously acts on, a certain electrode may be implemented only exist substance A (except non-electronic charged particle) to function, and
Another electrode only exists the state that substance B (except non-electronic charged particle) functions, or realizes that a certain electrode only exists object
The high concentration object (except non-electronic charged particle) of matter A functions, and the high concentration object that another electrode only exists substance B is (non-
Except electronics charged particle) state that functions, any state either among these is all conducive to promote electrochemistry anti-
The efficiency answered.Certainly it is controlled as described above, being selectively chosen using external means (such as foreign current, external electrical field etc.)
The export of electronics imports step, promotes the efficiency of electrochemical reaction.Similarly, alternative in realizing this electrochemical process
Ground selection, the region A, external circuit, capacitor and the region B constitute circuit and/or the region A, external circuit, non-electronic
Charged particle vibrates area and the region B constitutes circuit.
Disclosed in this invention include that substance A, the principle of the scheme of substance B alternating action are as follows: make region A and substance
A and substance B alternately contact or make substance A and substance B alternately to contact with region A, replace region B with substance B and substance A and connect
It touches or makes substance B and substance A alternately to contact with region B, so that substance A is generated positive charged particle and electronics in the region A, make electricity
Son exports to the region B from the region A, and the substance B described in the region B coexists with electronics, makes the substance A described
Region B generates the positive charged particle and electronics, so that electronics is imported into the region A from the region B, in the region A institute
The product that positive charged particle, the substance B and electron reaction generate the substance A and substance B reaction is stated, in the area
Positive charged particle, the substance B and electron reaction described in the B of domain generate the product of the substance A and substance B reaction, benefit
It is imported with the export of the electronics between the region A and the region B and realizes output electric energy and/or absorb electric energy, so recycled,
Realization continues working process, and (when importing electronics to the region B from the region A, in some cases, electronics is in the area
Domain B is reacted with substance B generates negative charged particles C, and the negative charged particles C is in the region B and the positive charged particle reaction
It generates the substance A and product that the substance B reacts, utilizes the electronics between the region A and the region B
Export, which imports, to be realized output electric energy and/or absorbs electric energy, is so recycled, realization continues working process).Realizing this electrochemistry
In the process, it is selectively chosen, the region A, external circuit, capacitor and the region B constitute circuit and/or the region
A, external circuit, non-electronic charged particle oscillation area and the region B constitute circuit.It, can be to the region in this scheme
The A and region B implements electro ultrafiltration, and electro ultrafiltration can control export and/or importing with strengthening electronic, thus can be effective
It avoids substance A and substance B from mixing and redox reaction directly occurs, improve safety, reliability and efficiency.In this scheme
In, it can also first implement electro ultrafiltration to it before the region A and region B and material effect, purpose is also to avoid
Redox reaction directly occurs for substance A and substance B mixing, improves safety, reliability and efficiency.
Disclosed in this invention include substance A and substance B mixture effect scheme principle it is as follows: make region A
It contacts or makes the mixture of substance A and substance B to contact with region A with the mixture of substance A and substance B, make region B and substance A
With the contact of the mixture of substance B or contact the mixture of substance A and substance B with region B, make electronics from described using electro ultrafiltration
Region A exports to the region B, and then the substance A is made to form positive charged particle in the region A, from the region B to institute
It states region A and imports electronics, the substance A generates the positive charged particle in the region B, is just charging described in the region A
Particle, the substance B and electron reaction generate the substance A and the substance B reaction product, described in the region B just
Charged particle, the substance B and electron reaction generate the substance A and the substance B reaction product, in the region A and
Electric energy and/or output electric energy are absorbed on the channel of electronics export and/or importing between the region B, are so recycled, realization is held
The continuous course of work (in some cases, the substance B and electron reaction when importing electronics to the region B from the region A
Negative charged particles C is generated, generates negative charged particles C from the region B to substance B described in the region A and electron reaction,
Positive charged particle described in the region A and negative charged particles C reaction generate the substance A and the reaction of the substance B is raw
At object, the positive charged particle described in the region B and negative charged particles C reaction generate the substance A and the substance B
Reaction product, between the region A and the region B electronics export and/or import channel on absorb electric energy and/
Or output electric energy, so recycle, realization continues working process).In realizing this electrochemical process, it is selectively chosen,
The region A, external circuit, capacitor and the region B constitute circuit and/or the region A, external circuit, non-electronic charged particle
It vibrates area and the region B constitutes circuit.It is straight to be effectively prevented from the substance A and substance B mixing in this scheme
Redox reaction is given birth in sending and receiving, first can implement electro ultrafiltration to it before the region A and region B and material effect.
Disclosed in this invention include substance A and substance B the principle of scheme that discontinuously acts on of mixture it is as follows: except disconnected
Outside the influence of continuous effect, the complete phase of principle of the principle of this programme and the scheme for the mixture effect for including substance A and substance B
Together, interrupted function is that can be better protected from or eliminate substance A described in mixture and the substance B joins in electrode
Output electric energy is lost with redox reaction is directly carried out in the case where (the i.e. described region A and/or the region B are participated in)
Ability, and then the efficiency of scheme disclosed in this invention is improved, such as following substance As and substance B mixture discontinuously act on work original
It manages shown in figure, under the influence of mixture discontinuously acts on, a certain electrode may be implemented and only exist substance A (non-electronic charged particle
Except) function, and another electrode only exists the state that substance B (except non-electronic charged particle) functions, or realizes
The high concentration object (except non-electronic charged particle) that a certain electrode only exists substance A functions, and another electrode only exists object
The state that the high concentration object (except non-electronic charged particle) of matter B functions, any state either among these have
Conducive to the efficiency for promoting electrochemical reaction.Certainly as described above, being selectively chosen using external means (such as external electrical
Stream, external electrical field etc.) control electronics export import step, promote the efficiency of electrochemical reaction.Similarly, this electrification is being realized
It during, is selectively chosen, the region A, external circuit, capacitor and the region B constitute circuit and/or the area
Domain A, external circuit, non-electronic charged particle oscillation area and the region B constitute circuit.
In the present invention, the partial circuit working principle of the electrical return of disclosed scheme is to utilize non-electronic band electrochondria
Sub reciprocating vibration in the electrolyte, which is realized alternation conducting and/or stood facing each other using non-electronic charged particle with electronics, realizes that alternation is led
It is logical, and then interior circuit and external circuit is made to form closed circuit, realize electrochemical process.
In the present invention, it is work normality that the area the alternating current Jie electricity, which exports alternate electric energy and/or absorbs alternate electric energy,.
In the scheme for including region A and electric conductor, the electrochemistry region stated below is equal with region A.
It is including the side of region A (electrochemical reaction occurs for the region) and region B (electrochemical reaction does not occur for the region)
In case, the electrochemistry region stated below is equal with region A.
It is including the scheme of region A (electrochemical reaction occurs for the region) and region B (electrochemical reaction occurs for the region)
In, the electrochemistry region stated below is equal with region A or with region B.
In the present invention, so-called " it is work that the area the alternating current Jie electricity, which exports alternate electric energy and/or absorbs alternate electric energy,
Normality " refers to that exporting electronics from the area the alternating current Jie electricity and import electronics to the area the alternating current Jie electricity is to continue working
Process exports electronics from the area the alternating current Jie electricity that is, using electrochemical appliance disclosed in this invention in working condition
It is a kind of lasting process with electronics is imported to the area the alternating current Jie electricity.In other words, the area the alternating current Jie electricity with
Alternating current is corresponding and the area the alternating current Jie electricity is opposite with alternating current should be the process of continuing working.
In the present invention, the device in only one disclosed region (conductive reducing agent), which is selectively chosen, serves as half
Electrochemical appliance (including the device region of an electrode i.e. in electrochemical appliance), is also selectively chosen for manufacturing electrification
Learn device.
In the present invention, according to scheme disclosed in this invention, the work of substance and electrode (such as region or conductive reducing agent)
With prior to electricity and the effect of electrode, this form may be implemented the due electrochemical process of the present invention completely, but substance A and
Substance B (such as reducing agent and oxidant) will appear in many cases to be existed simultaneously at same electrode (especially with object
When the mixture of matter A and substance B), if this state is precisely that startup stage or electrode did not had in the period of electro ultrafiltration, this
When substance A and substance B can directly occur redox reaction lose and electric energy between conversion process, in order to avoid this state
It generates it is necessary to implement electro ultrafiltration to electrode in advance, and it is so-called " to the conductive reducing agent application electro ultrafiltration, so that described lead
Electroreduction agent be difficult to directly carry out redox reaction " purpose be that this.
It in the present invention, is selectively chosen and electro ultrafiltration is applied to the conductive reducing agent, to realize to the conduction also
Substance A and object is reduced or avoided prior to the interaction between substance and the conductive reducing agent in the electro ultrafiltration of former agent
Matter B directly carries out the case where redox reaction loses output electric energy.
In the present invention, so that charged particle is stored in the means of a certain region (or conductive reducing agent) as realization, may be selected
Property select by make the region and participate in electrochemical reaction two kinds of metabolies contact and electric current alternating variation come in fact
Existing, being also selectively chosen makes that two kinds of substances for participating in electrochemical reaction are alternately contacted with the region and the alternating of electric current becomes
Change to realize, however two electrodes of electrochemical reaction (such as region A and electric conductor, region A and region B, conduction reducing agent A and
Conductive reducing agent B) between the conducting of non-electronic charged particle may or may not then exist.
In the present invention, so that charged particle is stored in the means of a certain region (or conductive reducing agent) as realization, may be selected
Property select to make the region and participate in the mixture contact of two kinds of substances of electrochemical reaction and the alternating variation of electric current come it is real
It is existing, it is selectively chosen the mixture makes discontinuous contact and electric current for making two kinds of substances in the region and participation electrochemical reaction
Alternating change to realize, however two electrodes of electrochemical reaction (such as region A and electric conductor, region A and region B, it is conductive also
Former agent A and conduction reducing agent B) between the conducting of non-electronic charged particle may or may not then exist.
In the present invention, it is that the Q generated at P is instigated to be stored in institute that the so-called Q for making the generation at P, which is stored at the P,
The electrode zone represented at P is stated, including the Q to be unnecessarily transmitted to the electrode zone polarity with representative at the P
The process of opposite electrode zone.
In the present invention, in realizing the chemical energy electric energy conversion plan, need for certain charged particle to be stored in a certain
It is waited in region and participates in reaction in the next step, it is to instigate to produce at P that the so-called Q for making the generation at P, which is stored at the P,
Raw Q is stored in the electrode zone represented at the P, including being unnecessarily transmitted to the Q and representative at the P
The process of the opposite polarity electrode zone of electrode zone.
In the present invention, the substance A used in the chemical energy device for converting electric energy and substance B are with the substance A and institute
In the presence of the form for stating the mixture of substance B, further can selectively it select with the substance A and the substance B
The form of molar mixture exist, or in the form of the mixture of the explosion limit substance A below and the substance B
In the presence of, or to exist in the form of the mixture of the local explosion limit substance A below and the substance B, or with pole of exploding
The form of the mixture of above substance A of limit and the substance B exists, or with the substance more than local explosion limit
The form of the mixture of A and the substance B exists.
In the present invention, the mixture of so-called substance A and substance B further can selectively select to be set as substance A and object
Molar mixture, the explosion limit substance A below of matter B and mixture, the local explosion limit substance A below of substance B
With the substance A more than mixture of more than mixture of substance B, explosion limit substance A and substance B or local explosion limit
With the mixture of substance B.
In the present invention, so-called molar mixture refers to that the molar concentration rate of mixture is positive and negative in chemical reaction molar ratio
Mixture within 10%.
In the present invention, the export importing of electronics of the region A, the region B, the conductive reducing agent refer to and do not include
The appearance and accumulation of electronics during being electrically separated.
In the present invention, the export of the electronics of the region A is imported to continue working process.
In the present invention, the export of the electronics of the region B is imported to continue working process.
In the present invention, corresponding with the alternating electromotive force and alternating current state of the conduction reducing agent is continued working
Journey.
The chemical energy device for converting electric energy disclosed in this invention is corresponding with alternating electromotive force and alternating current, that is, hands over
The area time-dependent current Jie electricity is corresponding with alternating electromotive force and alternating current.
In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen through non-electronic
Relationship is connected in the direct electricity that charged particle is formed, and relationship, warp is connected in the electricity formed through non-electronic charged particle reciprocating vibration
One of electricity conducting relationship that capacitance relation is formed, secondly conjunction or thirdly conjunction.
In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen including through exhausted
The electrical relation that alternating current can be made to be connected of edge body, dielectric and the conducting body isolation of non-electronic charged particle.
In the present invention, two electrodes (such as region A and electric conductor, region A and region B, conduction reducing agent A and it is conductive also
Former agent B) between there are in the scheme of electrolyte, non-electronic charged particle can both pass through electrolyte, reach another from an electrode
Electrode can also realize the effect that alternating current is connected by reciprocating vibration in the electrolyte.
In the present invention, the area alternating current Jie electricity corresponding with alternating electromotive force and alternating current is that essence of the invention is special
It levies, in the present invention, two kinds of substances due to participating in electrochemical reaction exist with conversion zone to be contacted, and the area alternating current Jie electricity
Corresponding with alternating electromotive force and alternating current, i.e., the electromotive force in the area alternating current Jie electricity in the present invention is alternating electromotive force,
It absorbs and/or the electric current of output electric energy is alternating current, and this is through the lasting sex work normality of whole work process, this
Kind continuing sex work normality eliminates the necessity of non-electronic charged particle transmission between two electrodes, therefore no matter makes between two electrodes
In electronics state of isolation, non-electronic charged particle state of isolation has the electrolyte that non-electronic charged particle is connected between two electrodes
State, be in other states, as long as can be realized the Oscillating flow of electronics, can work normally.It is deposited between two electrodes
In the scheme of electrolyte, non-electronic charged particle can both pass through electrolyte, reach another electrode from an electrode, can also be
Reciprocating vibration realizes the effect of alternating current conducting in electrolyte.This is the manufacture of electrochemical appliance especially fuel cell and makes
With providing brand-new method.
In the present invention, the alternation of electric current and substance replace and the effect of the alternation and mixture of substances of electric current is formed by
Alternation process is a kind of lasting course of work, is a kind of work normality, and its purpose is to eliminate non-electronic band
Charged particle two interelectrode transmitting necessity, to promote the science that chemical energy exchanges the electrochemical appliance of electric energy for, in turn
Promote service life, reliability, low cost and the efficiency of electrochemical appliance corresponding with scheme disclosed in this invention.This electricity
The purpose of principle and purpose of chemistry protocols and conventional fuel cell are catalyst regeneration is temporary to exchange Oxidizing and Reducing Agents
Feed channel, which forms the principle of temporary electrode change in polarity and purpose, has essential distinction, also and to prevent, weaken and remove
The principle and purpose of the frequently pole-reversing electroosmosis of electrode attachment have essential distinction.
In the present invention, from a certain region export electronic processes duration with to this region import electronic processes duration it
Than between 1/6 and 6, between 1/5 and 5, between 1/4 and 4, between 1/3 and 3, between 1/2.5 and 2.5,1/2
And between 2, between 1/1.5 and 1.5, between 1/1.3 and 1.3, between 1/1.2 and 1.2 or 1/1.1 and 1.1 it
Between, or it is equal with the duration of electronic processes is imported to this region from the duration of a certain region export electronic processes.
In the present invention, during the export of electronics imports, electro ultrafiltration can be used;Or, the export in electronics imports
During, it is selectively chosen using capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductor wire
Circle, motor, reversible electric machine, has charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit
The motor of additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its
Seven conjunctions, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13
Conjunction, its 14 conjunction, its 15 conjunction.
In the present invention, the purpose for applying electro ultrafiltration to the conductive reducing agent is that output electricity is controlled or strengthened using electro ultrafiltration
The process of energy and/or the process for absorbing electric energy, in this way can be with the efficiency and safety of lifting process, such as an electrochemical process
It may take a long time to complete, but if the procedure segment that electrochemical reaction rates can be made slower using electro ultrafiltration
Reaction rate promoted, and then improve efficiency.
In the present invention, so-called electro ultrafiltration, which refers to, brings it about displacement and/or stream to electronics application using electric field, electric current etc.
Dynamic effect.
In the present invention, it is formed by that the capacitance the big more to be conducive to electrochemical reaction close between the region A and the region B
The promotion of degree, therefore when being electrochemically reacted using scheme disclosed in this invention, the region A and the region should be made
Capacitance between B increases as much as possible.
It, can be in the region A and the area in order to increase the capacitance between the region A and the region B in the present invention
Plasma, ionic liquid, ionized gas or solion are set between the B of domain, and make ion in the region A and the region
Vibrated between B, and/or oscillate around in the region A and oscillated around in the region B, with realize increase the region A and
The purpose of capacitance between the region B.
In the present invention, it is more big more be conducive to electricity that the conduction reducing agent A and the conduction reducing agent B are formed by capacitance
The promotion of density is chemically reacted, therefore when being electrochemically reacted using scheme disclosed in this invention, the conduction should be made
Capacitance between reducing agent A and the conductive reducing agent B increases as much as possible.
It, can be described in order to increase the capacitance between the conduction reducing agent A and the conductive reducing agent B in the present invention
Plasma, ionic liquid, ionized gas or solion are set between conductive reducing agent A and the conductive reducing agent B, and made
Ion vibrates between the conduction reducing agent A and the conductive reducing agent B, and/or oscillates around in the conduction reducing agent A
And oscillated around in the conduction reducing agent B, to realize the electricity increased between the conduction reducing agent A and the conductive reducing agent B
The purpose of capacity.
In the present invention, to realize that specific charged particle is stored in electrochemistry region (such as region A, region B, conductive reduction
Agent), need to make the electrochemistry region alternate change physical environment or to make described between the different material for participating in electrochemical reaction
Electrochemistry region is contacted with the mixture for the different material for participating in electrochemical reaction, is just able to achieve.Fundamentally, as long as making institute
State electrochemistry region participate in electrochemical reaction different material between alternate change physical environment or make the electrochemistry region with
The mixture contact for participating in the different material of electrochemical reaction, can be achieved with the specific charged particle and is stored in electrochemistry region
Purpose, no matter electrochemistry region tool there are two types of the conductive channel of charged particle (such as it is one of for proton conductive it is logical
, i.e. there is the electrolyte that specific charged particle is connected between two electrodes in road, another kind is electronic conduction channel) or the electrification
School district domain only has electronic conduction channel, in other words, as long as making the electrochemistry region in the not jljl for participating in electrochemical reaction
Alternate change physical environment or make the electrochemistry region and participate in the mixture of different material of electrochemical reaction to contact between matter,
It can be achieved with the specific charged particle to be stored in electrochemistry region and participate in reaction realization electrochemical reaction in the next step
Purpose, no matter between two electrodes (such as region A and electric conductor, region A and region B, conduction reducing agent A and conduction reducing agent B)
With the presence or absence of electrolyte.The course of work for the scheme that the export of electrochemistry region imports charged particle is similar with this.
In the present invention, at electrochemistry region (such as region A, region B, conductive reducing agent), there are two types of charged particle to lead for tool
Circulation passage (such as one of is proton conductive channel, i.e. there is the electrolyte that specific charged particle is connected between two electrodes, it is another
Kind be electronic conduction channel) electrochemical regimes in, by make the electrochemistry region participate in electrochemical reaction not jljl
Alternate change physical environment or make the electrochemistry region and participate in the mixture of different material of electrochemical reaction to contact between matter,
It can be achieved to eliminate the necessity for removing the non-electronic charged particle generated in the electrochemistry region from the electrochemistry region,
It can also realize that non-electronic charged particle is stored in the electrochemistry region and participates in reaction in the next step and realize that electrochemistry is anti-
The purpose answered.The alternate change of physical environment makes the electrochemistry region and participates in the mixing of the different material of electrochemical reaction
Object contact, can make the non-electronic charged particle being stored in the electrochemistry region participate in reacting in the next step, realize
Electrochemical process, therefore the necessity for exporting from the electrochemistry region non-electronic charged particle completely disappears.Non-electronic
In the case that necessity derived from charged particle disappears, although some ought to be stored in the non-electrical in the electrochemistry region
Subband charged particle is exported, and is also had non-electronic charged particle and is stored in the next reaction step of the electrochemistry region waiting
Suddenly, in other words, if the electrochemistry region participate in electrochemical reaction different material between alternate change physical environment, or
It is contacted with the mixture of different material for participating in electrochemical reaction, although in two electrodes (such as region A and electric conductor, region A
And region B, conduction reducing agent A and conduction reducing agent B) between there are electrolyte, also have non-electronic charged particle and be stored in institute
Stating electrochemistry region waits participation reaction in the next step to realize electrochemical reaction process.
Chemical energy device for converting electric energy disclosed in this invention, there are can reduce in the case where electrolyte between two electrodes
Electrolyte load extends its service life and is conducive to the balance and stability operation of system.
In the present invention, in electrochemistry region, (such as region A, region B, conductive reducing agent) only has the side in electronic conduction channel
In case (for example, between the region A and the region B, between the conduction reducing agent A and the conductive reducing agent B, the region A
Interior circuit or external circuit between electric conductor are in electronics and non-electronic charged particle state of isolation), the electrochemistry region exists
Alternate change physical environment and the electrochemistry region and participation electrochemical reaction between the different material of participation electrochemical reaction
The mixture of different material contacts, and non-electronic charged particle can be made to be stored in the electrochemistry region, the change of physical environment
Or the electrochemistry region and the mixture for the different material for participating in electrochemical reaction is made to contact and can make to be stored in the electrochemistry
The non-electronic charged particle in region participates in reaction in the next step and realizes electrochemical process, that is, eliminates from electrochemistry region
Remove the necessity of non-electronic charged particle.Express herein, in Conventional electrochemical scheme, electrochemistry region (i.e. electrode) extremely
It less include two kinds of charged particle conductings, such as an electronic conduction channel, a proton conductive channel.
Chemical energy device for converting electric energy disclosed in this invention include exchanged for electric energy chemical energy electrochemical appliance (such as
Electrochemistry formated device etc.) and exchange with chemical energy the electrochemical appliance (such as fuel cell etc.) of electric energy for, it is closed as electrochemistry
At device in use, the different step that the export of electronics imports, which may exist, exports the case where electric energy is with electric energy is absorbed, but its
Summation is to absorb electric energy, as the device (such as fuel cell etc.) for exchanging electric energy for chemical energy in use, the export of electronics
The case where different step of importing may exist output electric energy and absorb electric energy, but its summation is output electric energy.
Chemical energy device for converting electric energy disclosed in this invention self-evidently includes the participation of substance.
In the present invention, the reducing agent is simple substance, compound or mixture, and ion or solion are not belonging to the reduction
Agent.
In the present invention, the oxidant is simple substance, compound or mixture, and ion or solion are not belonging to the oxidation
Agent.
In the present invention, it is so-called " area the alternating current Jie electricity and capacitor, DC power supply, AC power source, alternating source,
Inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit, electricity
Machine, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five it
Conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, its 12
The conjunction of item, its 13 conjunction, its 14 conjunction, its 15 conjunction have electrical relation " purpose be to pass through electro ultrafiltration
Control and/or the export of strengthening electronic import.
In the present invention, it is so-called " area the alternating current Jie electricity and capacitor, DC power supply, AC power source, alternating source,
Inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit, electricity
Machine, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five it
Conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, its 12
The conjunction of item, its 13 conjunction, its 14 conjunction, its 15 conjunction have electrical relation " purpose be to pass through electro ultrafiltration
Control and/or the export of strengthening electronic import, and control and/or the export of strengthening electronic importing can effectively avoid substance A and object
Redox reaction directly occurs for matter B mixing, improves safety, reliability and efficiency, and control and/or strengthening electronic are led
Safety, reliability and the efficiency that can be effectively promoted using substance A and substance B existing scheme as a mixture are imported out.
Using disclosed in this invention a kind of chemical energy device for converting electric energy as obtain electric energy scheme when, it is " described
The area alternating current Jie electricity and capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductance coil, charged particle pump,
Phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit, motor, reversible electric machine, with additional rotation inertia
Motor or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight
The conjunction of item, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14
Conjunction, its 15 conjunction have electrical relation " purpose be by electro ultrafiltration control and/or strengthening electronic export import.
A certain step in this control process is power consumption, but whole process is power supply.
Using disclosed in this invention a kind of chemical energy device for converting electric energy as obtain electric energy scheme and use object
When the mixture of matter A and substance B, " area the alternating current Jie electricity and capacitor, DC power supply, AC power source, alternating source, electricity
Feel conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit, motor,
Reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five conjunction,
Its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, its ten binomial
Conjunction, its 13 conjunction, its 14 conjunction, its 15 conjunction have electrical relation " purpose be not only by electricity make
It is imported with control and/or the export of strengthening electronic, and is to prevent substance A and substance B straight by the export importing of strengthening electronic
Tap into the effective means of row redox reaction.A certain step in this control process is power consumption, but whole process is to supply
Electricity.
Using disclosed in this invention a kind of chemical energy device for converting electric energy as obtain electric energy scheme when, it is " described
The area alternating current Jie electricity and capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductance coil, charged particle pump,
Phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit, motor, reversible electric machine, with additional rotation inertia
Motor or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight
The conjunction of item, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14
Conjunction, its 15 conjunction there is electrical relation " purpose be not only to control by electro ultrafiltration and/or the export of strengthening electronic is led
Enter, and is that the effective hand for preventing substance A and substance B from directly carrying out redox reaction is imported by the export of strengthening electronic
Section.A certain step in this control process is power consumption, but whole process is power supply.
It in the present invention, further can selectively select that catalyst corresponding with the substance A is made to be set as catalyst A, with
It is different that the corresponding catalyst of the substance B is set as catalyst B, the catalyst A and the catalyst B, in this case, institute
It states the catalyst in electrochemistry region and is selectively chosen the random mixing for being set as the catalyst A and the catalyst B
Select to catalyst choice in object or the electrochemistry region catalyst A for being set as contacting near catalytic domain and
The mixture of the catalyst B can increase the charged particle between the catalyst A and the catalyst B to improve efficiency
Mobility.
In the present invention, it can be selected according to the operating temperature of the property and the electrochemistry region of the substance A and the substance B
Select different catalyst.
In the present invention, concentration proportion is imported below local explosion limit to region (region A, region B, conductive reducing agent)
The substance A and the mixture of the substance B may include fire retardant, such as nitrogen, dioxy are added in the mixture of hydrogen and oxygen
Change carbon etc..
In the present invention, elimination means only to need to remove electronics from the necessity that region removes non-electronic charged particle,
Rather than electronics charged particle (such as proton) can store in the region that it is generated and the participation electrochemical reaction during next,
This means that It is not necessary to which the interior circuit or external circuit that centainly constitute with non-electronic charged particle channel, only need between two electrodes
Electronic conduction circuit is wanted, electrochemical process can be realized, in this scheme, the conducting for being selectively chosen its interior circuit is
It is realized, and utilized by the reciprocating vibration of charged particle in the capacitor and/or its internal part that are formed between its internal part
External circuit exports electric energy and/or absorbs electric energy.
In the present invention, eliminate means only to need to remove electronics from the necessity that region removes two kinds of charged particles, and another
A kind of charged particle (such as proton) can store in the region that it is generated and participate in during next electrochemical reaction, this meaning
Taste between two electrodes It is not necessary to the interior circuit or external circuit that are centainly constituted with non-electronic charged particle channel, it is only necessary to electricity
Sub- turning circuit, can be realized electrochemical process, and in this scheme, the conducting of interior circuit is by shape between its internal part
At capacitor and/or its internal part in charged particle reciprocating vibration realize, and using external circuit output electric energy and/or
Absorb electric energy.
In the present invention, the export importing of electronics is a kind of work normality, and the export importing of so-called electronics refers to through external circuit
The export of the electronics carried out imports.
In the present invention, so-called " electrolyte three-diemsnional electrode " refers to all three-diemsnional electrodes contacted with electrolyte.
In the present invention, so-called " non-electrolyte three-diemsnional electrode " refers to all three-diemsnional electrodes not contacted with electrolyte.
In the present invention, such as there is non-electronic conducting electrical relation using Y and X as synonym, Y and X, the electronics of the Y is led
The form of presentation imported out refers to that the Y, the X and electronics export import the composition that circuit three is same closed circuit
Part is selectively chosen electronics export importing circuit being set as external circuit, and non-electronic conducting electrical relation is formed
Circuit be set as interior circuit.
In the present invention, such as using U, W and V as synonym, U has non-electronic conducting electrical relation through W and V, and electronics is in institute
The form of presentation for exporting importing between U and the V is stated, refers to that the U, the W, the V and electronics export import circuit
It is the component part of same closed circuit, is selectively chosen and electronics export importing circuit is set as external circuit, and will be non-
Electronic conduction electrical relation is formed by circuit and is set as interior circuit.
In the present invention, so-called " alternating electromotive force " refers to that the changed electromotive force of electromotive force, such as direction become
The changed electromotive force of electromotive force or size of change.
In the present invention, so-called " alternating current " refers to the changed electric current of electric current, such as the changed electricity in direction
Stream, the changed electric current of size or alternating current.
In the present invention, so-called " alternating current " is selectively chosen the electric current for being set as the variation of electric current generating period,
Such as electric current or alternating current that electric current, the size generating period of direction generating period variation change.
In the present invention, so-called alternating current refers to the alternating current changed by sinusoidal rule.
In the present invention, so-called AC power source refers to the alternating source that electric current is changed by sinusoidal rule.
In the present invention, there is so-called A and B non-electronic conducting electrical relation to refer to having on interior circuit between A and B
Non-electronic conducting electrical relation, and its external circuit is selectively chosen electronic conduction relationship;Or, so-called A and B has non-electrical
Son conducting electrical relation, which refers to, has non-electronic conducting electrical relation on external circuit between A and B, and its interior circuit may be selected
Select electronic conduction relationship to property.
In the present invention, so-called " A is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid
At least one of body, ionized gas, solion and electronic conduction area have non-electronic conducting electrical relation with B " it include institute
State the two solion ponds that A and the B are isolated through electronic conduction area, insulator, dielectric and/or ion conducting body have it is non-
Electronic conduction electrical relation.In this scheme, being selectively chosen makes at least one in the A and the B and capacitor
Area and/or non-electronic charged particle transmitter form electrical relation.
In the present invention, it is so-called " A through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, from
At least one of sub- liquid, ionized gas, solion and electronic conduction area are closed with the B with non-electronic conducting electricity
System " includes two solions that the A is isolated with the B through electronic conduction area, insulator, dielectric and/or ion conducting body
The non-electronic conducting electrical relation that pond has.In this scheme, being selectively chosen makes in the A and B at least
One forms electrical relation with capacitive region and/or non-electronic charged particle transmitter.
In the present invention, so-called " non-electronic charged particle transmitter " refer to non-conducting electronics but proton conducting or it is specific from
The substance of son, i.e. electrolyte in conventional electrochemical device, can be according to the electrochemical properties of the reducing agent and the oxidant
Non-electronic charged particle transmitter is selected, such as when the reducing agent is H2, the oxidant is O2When, the non-electronic electrification
Particle conduction object alternative selects proton exchange membrane.
In the present invention, so-called " non-electronic conducting electrical relation " refers to the electricity formed through the charged particle other than electronics
Conducting relationship or the electricity to be formed conducting relationship of standing facing each other through electronics, for example, relationship, non-electronic electrification is connected in the electricity that capacitor is formed
The electricity conducting relationship etc. that particle reciprocating vibration is formed.
In the present invention, so-called " electronic conduction area " refers to that conduct electrons are not turned on the region of non-electronic charged particle, can
Selectively selection is set as metallic conductor area, carbon conductor region etc..
In the present invention, select electronic conduction area shape when, should for the purpose of increasing its capacitance with neighbors into
Row selection.
It is so-called region A, so-called electric conductor, so-called region B, so-called conductive reducing agent, so-called in the present invention
Conductive reducing agent A, so-called conduction reducing agent B are equal with electrode.
In the present invention, the region that electronics export imports is equal with electrode.
It in the present invention, is selectively chosen, there is dielectric capacitance relationship between electrode.
It in the present invention, is selectively chosen, the area A and electric conductor have a dielectric capacitance relationship, and dielectric can be with
It is gas, liquid, solid or vacuum.
It in the present invention, is selectively chosen, so-called conduction reducing agent A and so-called conduction reducing agent B have dielectric
Capacitance relation, dielectric can be gas, liquid, solid or vacuum.
It in the present invention, is selectively chosen, the area A and the region B have dielectric capacitance relationship, and dielectric can
To be gas, liquid, solid or vacuum.
In the present invention, so-called dielectric capacitance relationship refers to the capacitance relation through dielectric formation, and dielectric can be
Gas, liquid, solid or vacuum.
In the present invention, so-called " capacitor " be selectively chosen be set as electrolytic capacitor, super capacitor, electric double layer capacitance,
All capacitors such as pseudo capacitance, fake capacitance.
In the present invention, so-called " reversible electric machine " refers to the motor that can mutually convert between motor and generator,
For example, the motor that can be generated electricity when exportable rotary power, rotation when power supply.
In the present invention, it is selectively chosen and uses circumferential magnetic monopole direct current using DC reversible electromotor or selectivity selection
Reversible electric machine.
In the present invention, when the purpose using reversible electric machine is the power supply using reversible electric machine when exportable power reception power
The characteristics of can generating electricity, realizes the reinforcing and control imported to electronics export with electrode cooperating, and then realizes to electrochemistry mistake
The optimization of journey.
It in the present invention, is selectively chosen, so that reversible electric machine movement power generation is implemented electro ultrafiltration to electrode, when the electricity of electrode
When kinetic potential reaches setting degree, electrode, which powers to reversible electric machine, pushes reversible electric machine movement, sets when the electromotive force of electrode is reduced to
When determining degree, reversible electric machine implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, so again and again
Carry out cyclic process;In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy;
It is selectively chosen, control device is set between reversible electric machine and electrode;Be selectively chosen, load with reversible electric machine,
Electrode is arranged in series, or load is arranged in parallel with reversible electric machine.
It in the present invention, is selectively chosen, so that reversible electric machine movement power generation is implemented electro ultrafiltration to electrode, when electrode is in electricity
When electromotive force reaches setting degree under the action of chemical reaction and/or reversible electric machine, electrode is in electrochemical reaction and/or accumulation electricity
It powers under the action of lotus to reversible electric machine and pushes reversible electric machine movement, it is reversible when the electromotive force of electrode is reduced to setting degree
Motor implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, so carries out cyclic process again and again;
In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy;Optionally select
It selects, control device is set between reversible electric machine and electrode;It being selectively chosen, load is arranged in series with reversible electric machine, electrode,
Or load is arranged in parallel with reversible electric machine.
It in the present invention, is selectively chosen, makes electrode move reversible electric machine reversible electric machine power supply, when the electricity of electrode
When kinetic potential is reduced to setting degree, reversible electric machine implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, when
When the electromotive force of electrode reaches setting degree, electrode, which powers to reversible electric machine, pushes reversible electric machine movement, so again and again
Carry out cyclic process;In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy;
It is selectively chosen, control device is set between reversible electric machine and electrode;Be selectively chosen, load with reversible electric machine,
Electrode is arranged in series, or load is arranged in parallel with reversible electric machine.
It in the present invention, is selectively chosen, makes electrode under the action of electrochemical reaction and/or stored charge to reversible
Motor power supply moves reversible electric machine, and when the electromotive force of electrode is reduced to setting degree, reversible electric machine utilizes itself and its connection
The kinetic energy power generation of moving part to electrode implement electro ultrafiltration, when electrode under the action of electrochemical reaction and/or reversible electric machine electromotive force
When reaching setting degree, electrode pushes reversible electricity to reversible electric machine power supply under the action of electrochemical reaction and/or stored charge
Machine movement, so carries out cyclic process again and again;In circulation, there is the process for providing electric energy and absorbing electric energy in electrode, but
Circulation is whole to be to provide electric energy;It is selectively chosen, control device is set between reversible electric machine and electrode;Optionally
Selection, load are arranged in series with reversible electric machine, electrode, or load is arranged in parallel with reversible electric machine.
In the present invention, so-called " electrolyte " refer to all be arranged between two electrode of electrochemical appliance only allow it is specific
The substance that charged particle passes through but electronics is not allowed to pass through can be solid, liquid or membranous body etc., such as the proton of PEMFC
Film and solid oxide electrolyte etc..
In the present invention, so-called " local explosion limit " refers under conditions of electrochemistry region, the substance A and described
The concentration ratio that substance B cannot explode.
In the present invention, so-called interpolar spacer refers to make to have required for non-electronic conducting electrical relation between electrode
Substance (including vacuum), for example, electrolyte, dielectric etc..
In the present invention, the selection of interpolar spacer alternative is set as insulation, isolation space, electrolyte, dielectric, electricity
At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area.
In the present invention, so-called interpolar spacer, which is selectively chosen, is set as interior circuit, is also selectively chosen and sets
For external circuit.
In the present invention, so-called electro ultrafiltration is a kind of selectivity selection.
In the present invention, so-called " non-electronic charged particle " refers to the charged particle other than electronics, such as proton or ion.
In the present invention, after a certain component names plus the letter such as so-called " A ", " B " is merely to distinguish two or several
The identical component of title or substance.
In the present invention, necessary portion should be set in necessary place according to electricity field, the well-known technique of electrochemical field
Part, unit or system etc..
Beneficial effects of the present invention are as follows: chemical energy device for converting electric energy disclosed in this invention will terminate Conventional electrochemical
Device (such as fuel cell etc.) exists for necessity with electrolyte (such as proton exchange membrane and solid oxide electrolyte etc.)
The conventional electrochemical device that terminates also can not securely and reliably be used the history of oxidant reduction agent composition, be by the history of condition
Efficiently, the exploitation of long-life, Low-cost electric chemical devices provide new approach, and will redefine engine.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the embodiment of the present invention 1;
Fig. 2 is the structural schematic diagram of the embodiment of the present invention 2;
Fig. 3 is the structural schematic diagram of the embodiment of the present invention 3;
Fig. 4 is the structural schematic diagram of the embodiment of the present invention 4;
Fig. 5 is the structural schematic diagram of the embodiment of the present invention 5;
Fig. 6 is the structural schematic diagram of the embodiment of the present invention 6;
Fig. 7 is the structural schematic diagram of the embodiment of the present invention 7;
Fig. 8 is the structural schematic diagram of the embodiment of the present invention 8;
Fig. 9 is the structural schematic diagram of the embodiment of the present invention 9;
Figure 10 is the structural schematic diagram of the embodiment of the present invention 10;
Figure 11 is the structural schematic diagram of the embodiment of the present invention 11;
Figure 12 is the structural schematic diagram of the embodiment of the present invention 12;
Figure 13 is the structural schematic diagram of the embodiment of the present invention 13;
Figure 14 is the structural schematic diagram of the embodiment of the present invention 14;
Figure 15 is the structural schematic diagram of the embodiment of the present invention 15;
Figure 16 is the structural schematic diagram of the embodiment of the present invention 16;
Figure 17 is the structural schematic diagram of the embodiment of the present invention 17;
Figure 18 is the structural schematic diagram of the embodiment of the present invention 18;
Figure 19 is the structural schematic diagram of the embodiment of the present invention 19;
Figure 20 is the structural schematic diagram of the embodiment of the present invention 20;
Figure 21 is the structural schematic diagram of the embodiment of the present invention 21;
Figure 22 is the structural schematic diagram of the embodiment of the present invention 22;
Figure 23 is the structural schematic diagram of the embodiment of the present invention 23;
Figure 24-1 is the schematic diagram of the embodiment of the present invention 24;
Figure 24-2 is the schematic diagram of the embodiment of the present invention 25;
Figure 24-3 is the schematic diagram of the embodiment of the present invention 26;
Figure 25-1 is the schematic diagram of the embodiment of the present invention 27;
Figure 25-2 is the schematic diagram of the embodiment of the present invention 28;
Figure 25-3 is the schematic diagram of the embodiment of the present invention 29;
Figure 26-1 is the schematic diagram of the embodiment of the present invention 30;
Figure 26-2 is the schematic diagram of the embodiment of the present invention 31;
Figure 26-3 is the schematic diagram of the embodiment of the present invention 32;
Figure 26-4 is the schematic diagram of the embodiment of the present invention 33;
Figure 27-1 is the basic logic chart for exchanging electric energy for chemical energy;
Figure 27-2 is reducing agent oxidant electrochemical reaction controlled process figure;
Figure 27-3 is the schematic diagram of the embodiment of the present invention 34;
Figure 27-4 is the schematic diagram of the embodiment of the present invention 35.
In figure:
1 region A, 2 region B, 3 conductive reducing agent feed channels, 4 oxidant feed channels, 6 reducing agent control switch A,
61 conductive reducing agent feed switch A, 62 conductive reducing agent feed switch B, 7 oxidant control switch A, 71 oxidant feeds switch
A, 72 oxidant feed switch B, 8 mixture feed channels, 91 mixture control switch A, 92 mixture control switch B, 10 controls
Device processed, 20 electric conductors, 101 conductive reducing agents, 1011 conductive reducing agent A, 1012 conductive reducing agent B, the control of 711 oxidants
Switch B, 200 reversible electric machines.
Specific embodiment
Technical solution of the present invention is further illustrated in the following with reference to the drawings and specific embodiments.
Embodiment 1
Chemical energy device for converting electric energy as shown in Figure 1, including region A1, the region A1 and conductive reducing agent feed are logical
The connection setting of road 3, the region A1 are connected to setting with oxidant feed channel 4, and the region A1 includes the area alternating current Jie electricity.
Embodiment 2
Chemical energy device for converting electric energy as shown in Figure 2 cancels conductive reducing agent feed on the basis of embodiment 1
Channel 3 and oxidant feed channel 4 are changed to the mixture feed channel 8 of the region A1 and conductive reducing agent and oxidant
Connection setting.
Embodiment 3
Chemical energy device for converting electric energy as shown in Figure 3 is further gone back in the conduction on the basis of embodiment 1
Reducing agent control switch A6 is set on former agent feed channel 3, and the reducing agent control switch A6 is controlled discontinuously by control device 10
It opens.
Embodiment 4
Chemical energy device for converting electric energy as shown in Figure 4, on the basis of embodiment 1, further in the oxidant
Oxidant control switch A7 is set on feed channel 4, and the oxidant control switch A7 is controlled interrupted unlatching by control device 10.
Embodiment 5
Chemical energy device for converting electric energy as shown in Figure 5 further makes the region A1 on the basis of embodiment 1
There is non-electronic conducting electrical relation with electric conductor 20.
As can embodiment in conversion, further can also selectively be changed to make the region A1 and insulation,
Completely cut off in space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
At least one there is non-electronic conducting electrical relation, or be selectively changed to make, the conduction reducing agent is through insulation, isolation
In space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area extremely
A kind of few and electric conductor 20 has non-electronic conducting electrical relation.
Embodiment 6
Chemical energy device for converting electric energy as shown in FIG. 6, including region A1 and region B2, the region A1 and conductive reduction
The connection setting of agent feed channel 3, the region A1 are connected to setting with oxidant feed channel 4, and the region A1 includes alternation electricity
The area Liu Jie electricity, the region B2 include the area alternating current Jie electricity, and the region B2 is set as that the region of electrochemical reaction does not occur.
Embodiment 7
It is logical to cancel conductive reducing agent feed on the basis of embodiment 6 for chemical energy device for converting electric energy as shown in Figure 7
Road 3 and oxidant feed channel 4 are changed to connect in the mixture feed channel 8 of the region A1 and conductive reducing agent and oxidant
Logical setting.
Embodiment 8
Chemical energy device for converting electric energy as shown in Figure 8, further in the conductive reduction on the basis of embodiment 6
Reducing agent control switch A6 is set on agent feed channel 3, and the reducing agent control switch A6 is controlled by control device 10 discontinuously to be opened
It opens.
Embodiment 9
Chemical energy device for converting electric energy as shown in Figure 9 is further supplied in the oxidant on the basis of embodiment 6
Setting oxidant control switch A7, the oxidant control switch A7 on channel 4 is sent to be controlled interrupted unlatching by control device 10.
As can embodiment in conversion, make to the property of can choose the region A1 and the area in embodiment 6 to 9
Domain B2 has non-electronic conducting electrical relation, or the region B2 and the conductive reducing agent is made to have non-electronic conducting electricity
Relationship.
As can embodiment in conversion, make to the property of can choose the region A1 in embodiment 6 to 9 through completely cutting off
Body, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction
At least one of area and the region B2 have non-electronic conducting electrical relation, or make, the conduction reducing agent through insulation,
Completely cut off in space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
At least one with the region B2 have non-electronic conducting electrical relation.
Embodiment 10
Chemical energy device for converting electric energy as shown in Figure 10, including region A1 and region B2, the region A1 and conduction are also
The connection setting of former agent feed channel 3, the region A1 are connected to setting with oxidant feed channel 4, and the region B2 and conduction are also
The connection setting of former agent feed channel 3, the region B2 are connected to setting with oxidant feed channel 4, and the region A1 includes alternation
The area electric current Jie electricity, the region B2 include the area alternating current Jie electricity.
Embodiment 11
Chemical energy device for converting electric energy as shown in figure 11 further makes the region A1 on the basis of embodiment 10
It is connected to setting with conductive reducing agent feed channel 3 through conductive reducing agent feed switch A61, the region B2 is supplied through conductive reducing agent
Switch B62 is sent to be connected to setting with conductive reducing agent feed channel 3.
Embodiment 12
Chemical energy device for converting electric energy as shown in figure 12 further makes the region A1 on the basis of embodiment 10
Be connected to setting with oxidant feed channel 4 through oxidant feed switch A71, the region B2 through oxidant feed switch B72 with
The connection setting of oxidant feed channel 4.
Embodiment 13
Chemical energy device for converting electric energy as shown in fig. 13 that further makes the region A1 on the basis of embodiment 10
It is connected to setting with conductive reducing agent feed channel 3 through conductive reducing agent feed switch A61, the region A1 is opened through oxidant feed
It closes A71 and is connected to setting with oxidant feed channel 4, the region B2 is through conductive reducing agent feed switch B62 and conductive reducing agent
The connection setting of feed channel 3, the region B2 are connected to setting with oxidant feed channel 4 through oxidant feed switch B72.
Embodiment 14
Chemical energy device for converting electric energy as shown in figure 14 further makes the region A1 on the basis of embodiment 10
It is connected to setting with conductive reducing agent feed channel 3 through conductive reducing agent feed switch A61, the region A1 is opened through oxidant feed
It closes A71 and is connected to setting with oxidant feed channel 4, the region B2 is through conductive reducing agent feed switch B62 and conductive reducing agent
The connection setting of feed channel 3, the region B2 is connected to setting with oxidant feed channel 4 through oxidant feed switch B72, described
Conductive reducing agent feed switch A61, the conductive reducing agent feed switch B62, the oxidant feed switch A71 and the oxygen
Agent feed switch B72 is controlled by control device 10;Realize the conduction reducing agent feed switch A61 and the conductive reducing agent
Feed switch B62 is opened and the oxidant feed switch A71 and the oxidant feed switch B72 are discontinuously opened, or is realized
The conduction reducing agent feed switch A61 and conduction reducing agent feed switch B62 is discontinuously opened and the oxidant feed
The switch A71 and oxidant feed switch B72 is opened, or realizes the oxidant feed switch A71 and the conductive reduction
Agent feed switch B62 is discontinuously opened and the conduction reducing agent feed switch A61 and oxidant feed switch B72 is opened.
Embodiment 15
Chemical energy device for converting electric energy as shown in figure 15 eliminates conductive reducing agent on the basis of embodiment 10
Feed channel 3 and oxidant feed channel 4 are changed to keep the mixture feed of the region A1 and conductive reducing agent and oxidant logical
The connection setting of road 8, the region B2 are connected to setting with the mixture feed channel 8 of conductive reducing agent and oxidant.
Embodiment 16
Chemical energy device for converting electric energy as shown in figure 16 further makes the region on the basis of embodiment 15
A1 is connected to setting, the region with the mixture feed channel 8 of conductive reducing agent and oxidant through mixture control switch A91
B2 is connected to setting, the mixing with the mixture feed channel 8 of conductive reducing agent and oxidant through mixture control switch B92
The object control switch A91 and mixture control switch B92 is controlled interrupted unlatching by control device 10.
As can embodiment in conversion, above-described embodiment 10 to 16 and its convertible ground embodiment can in the present invention
Further selectively to make the region A1 and region B2 that there is non-electronic conducting electrical relation, or make the region A1
The conductive reducing agent contacted with the region B2 has non-electronic conducting electrical relation, or makes the region B2 and the region
A1 contact conductive reducing agent have non-electronic conducting electrical relation, or make with the region A1 conductive reducing agent contacted and with
The conductive reducing agent of the region B2 contact has non-electronic conducting electrical relation;
As can embodiment in conversion, above-described embodiment 10 to 16 and its convertible ground embodiment can in the present invention
With further selectively make the region A1 through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, from
At least one of sub- liquid, ionized gas, solion and electronic conduction area have non-electronic electric conduction with the region B2
Relationship, or make, the region A1 through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid,
At least one of ionized gas, solion and electronic conduction area and the conductive reducing agent contacted with the region B2 have non-
Electronic conduction electrical relation, or make, the region B2 is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma
At least one of body, ionic liquid, ionized gas, solion and electronic conduction area and the conduction contacted with the region A1
Reducing agent has non-electronic conducting electrical relation, or makes, and the conductive reducing agent contacted with the region A1 is empty through insulation, isolation
Between, in electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area at least
Conductive reducing agent that is a kind of and contacting with the region B2 has non-electronic conducting electrical relation.
Embodiment 17
Chemical energy device for converting electric energy as shown in figure 17, including conductive reducing agent 101, the conduction reducing agent 101 with
The connection setting of oxidant feed channel 4, the conduction reducing agent 101 includes the area alternating current Jie electricity.
As embodiment in conversion, there is the conductive reducing agent 101 with electric conductor
Non-electronic conducting electrical relation, or selectively make, the conduction reducing agent 101 is through insulation, isolation space, electrolyte, electricity
At least one of medium, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area and electric conductor
With non-electronic conducting electrical relation, or selectively make, the conduction reducing agent 101 and insulation, isolation space, electrolysis
At least one of matter, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area tool
There is non-electronic conducting electrical relation.
Embodiment 18
Chemical energy device for converting electric energy as shown in figure 18, including conductive reducing agent 101, the conduction reducing agent 101 pass through
Oxidant control switch A7 is connected to setting with oxidant feed channel 4, and the oxidant control switch A7 is controlled by control device 10
System is discontinuously opened, and the conduction reducing agent 101 includes the area alternating current Jie electricity.
As embodiment in conversion, there is the conductive reducing agent 101 with electric conductor
Non-electronic conducting electrical relation, or selectively further make, the conduction reducing agent 101 and insulation, isolation space, electrolysis
At least one of matter, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area tool
There is non-electronic conducting electrical relation, or selectively further make, the conduction reducing agent 101 is through insulation, isolation space, electricity
At least one of Xie Zhi, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
There is non-electronic conducting electrical relation with electric conductor.
Embodiment 19
Chemical energy device for converting electric energy as shown in figure 19, including conductive reducing agent 101 and region B2, the conductive reduction
Agent 101 is connected to setting with oxidant feed channel 4, and the conduction reducing agent 101 includes the area alternating current Jie electricity, the region
B2 includes the area alternating current Jie electricity.
As embodiment in conversion, further make to the property of can choose the conductive reducing agent 101 and region B2
Further make with non-electronic conducting electrical relation, or selectively, it is described conduction reducing agent 101 through insulation, isolation space,
At least one in electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
Kind has non-electronic conducting electrical relation with the region B2.
Embodiment 20
Chemical energy device for converting electric energy as shown in figure 20, including conductive reducing agent 101 and region B2, the conductive reduction
Agent 101 is connected to setting with oxidant feed channel 4 through oxidant control switch A7, and the oxidant control switch A7 is controlled
Device 10 controls interrupted unlatching, and the conduction reducing agent 101 includes the area alternating current Jie electricity, and the region B2 includes alternating current
The area Jie electricity.
As embodiment in conversion, further make to the property of can choose the conductive reducing agent 101 and region B2
Further make with non-electronic conducting electrical relation, or selectively, the conduction reducing agent 101 and insulation, isolation space,
At least one in electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
Kind has non-electronic conducting electrical relation with the region B2.
Embodiment 21
Chemical energy device for converting electric energy as shown in figure 21, including conductive reducing agent, the conduction reducing agent includes conduction
Reducing agent A1011 and conduction reducing agent B1012, the conduction reducing agent A1011 are connected to setting, institute with oxidant feed channel 4
It states conductive reducing agent B1012 and is connected to setting with oxidant feed channel 4, the conduction reducing agent A1011 includes that alternating current connects
Electric area, the conduction reducing agent B1012 includes the area alternating current Jie electricity.
Embodiment 22
Chemical energy device for converting electric energy as shown in figure 22 further makes conductive reduction on the basis of embodiment 21
Agent A1011 is connected to setting with oxidant feed channel 4 through oxidant control switch A7, and conductive reducing agent B1012 is through oxidant control
It makes switch B711 and is connected to setting with oxidant feed channel 4.
Embodiment 23
Chemical energy device for converting electric energy as shown in figure 23 further makes the oxidation on the basis of embodiment 22
The agent control switch A7 and oxidant control switch B711 is controlled interrupted unlatching by control device 10.
As can embodiment in conversion, the embodiment of the present invention 21 to 23 further can selectively make described lead
The electroreduction agent A1011 and conduction reducing agent B1012 has non-electronic conducting electrical relation, or further selectively makes,
The conduction reducing agent A1011 through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, from
At least one of sub- gas, solion and electronic conduction area have non-electronic electric conduction with the conduction reducing agent B1012
Relationship.
Embodiment 24
Figure 24-1 is under unitary electrode (such as the present invention in region A), and substance A and substance B replace with electrode to be contacted
Process chart, chemical energy device for converting electric energy disclosed in this invention are selectively chosen according to following course of work works
Make.
In Figure 24-1,1a is electrode, A representative species A (conductive reducing agent), B representative species B (oxidant).When substance A with
When electrode contacts (1. shown process in figure), the electronics of substance A is exported forming material A cation A under electro ultrafiltration+(i.e. also
Former agent cation A+), as the reducing agent cation A+(intensity of the amount of accumulation depending on electro ultrafiltration when running up to setting degree
With electrical relation possessed by electrode), substance A and substance B switching (as in figure 3. and 4. shown in process), and pass through electronics
Load 5a imported into electrode, substance B, substance A cation A at electrode+Substance A and substance B oxidation are generated also with electron reaction
The product C (5. shown in such as figure) of original reaction.Next two-way can be divided to continue, is as 5. passed through in figure all the wayExtremely
Shown in 1., apply the electro ultrafiltration in direction same as described above again, and switch substance A and substance B again, and then realizes Zhou Erfu
Beginning cycle operation;Another way is as 5. passed through in figureShown in 7., apply the electro ultrafiltration in direction contrary to the above, and continue to make
Substance B is contacted with electrode, so so that substance B and electronics is coexisted in electrode (substance B can receive and electronically form object in some cases
Matter B anion B—Or oxidant anion B—, do not show in figure), when electronics or oxidant anion B-run up to setting
When degree (in such as figure 9. shown in), switching substance A and substance B and make electronics through load 5a from electrode export (such as figure 10. andInstitute
Show), reducing agent cation, electronics and oxidant react herein generates C (in such as figureIt is shown), next electrode is implemented anti-
Electrotropic action and continuing make substance A contacted with electrode reach in figure 1. shown in state, and then realize cycle operation in cycles.
Principle shown in this figure and process are the course of work of unitary electrode.The purpose of electro ultrafiltration is to control and strengthen electrochemical reaction,
Electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from by storing process
Electric energy (for example, electric energy through capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration
It is not lost, and is stored at electrode, released together when electric current is reversed.
Embodiment 25
Figure 24-2 is mixture and the electrode phase of substance A and substance B under unitary electrode (such as region A in the present invention)
The process chart mutually contacted, chemical energy device for converting electric energy disclosed in this invention are selectively chosen according to following work
Process work.
In Figure 24-2,1a is electrode, A representative species A (conductive reducing agent), B representative species B (oxidant).When substance A and
(1. shown process in figure), the electronics quilt of the substance A under electro ultrafiltration in mixture when the mixture and electrode of substance B contact
Export forming material A cation A+(i.e. reducing agent cation A+), as the reducing agent cation A+When running up to setting degree
(electrical relation possessed by intensity and electrode of the amount of accumulation depending on electro ultrafiltration), makes electronics imported into electricity by loading 5a
Pole, substance B, substance A cation A at electrode+The product C of substance A and substance B redox reaction is generated with electron reaction
(4. shown in such as figure).Next two-way can be divided to continue, be all the way as in figure 5. to shown in 1., apply again with it is above-mentioned
The electro ultrafiltration of the same direction, that is, reach in figure 1. shown in state, and then realize cycle operation in cycles;Another way is as in figure
5. applying the electro ultrafiltration in direction contrary to the above, and then make substance B forming material B anion B shown in 6.—I.e. oxidant is negative
Ion B—(in some cases may forming material A, substance B and electronics coexist in the situation of electrode, do not shown in figure), when
Oxidant anion B—Or electron accumulation to setting degree when (in such as figure 8. shown in), export electronics from electrode through load 5a
(as figure is 9. shown) forms reducing agent cation A+, it is formed by reducing agent cation A+, oxidant (substance B) and electronics or also
Former agent cation A+With oxidant anion B—Reaction generates C (also as 9. shown in figure), next implements reversed electricity to electrode
Effect reach in figure 1. shown in state, and then realize cycle operation in cycles.Although during shown in Figure 24-2 at electrode
Always there is substance A and substance B have a reducing agent and oxidant always, but due to electro ultrafiltration there are reducing agents and oxidation
Agent can not directly carry out redox reaction, and then avoid or weaken mixture and directly carry out redox reaction at electrode
Lose the process of power supply capacity.Principle shown in this figure and process are the course of work of unitary electrode.The purpose of electro ultrafiltration is control
System with strengthen electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can also be with
From the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electro ultrafiltration consumes electric energy, but makees in electricity
It is not lost, and is stored at electrode with the electric energy consumed in the process, released together when electric current is reversed.
Embodiment 26
Figure 24-3 is mixture and the electrode phase of substance A and substance B under unitary electrode (such as region A in the present invention)
The process chart of mutual makes discontinuous contact, chemical energy device for converting electric energy disclosed in this invention are selectively chosen according to following
Course of work work.
In Figure 24-3,1a is electrode, A representative species A (conductive reducing agent), B representative species B (oxidant).Except substance A and
Outside the mixture of substance B and the influence of the mutual makes discontinuous contact of electrode, shown in principle shown in Figure 24-3 and process and Figure 24-2
It is identical, the purpose of mixture and electrode makes discontinuous contact be in order to reduce at electrode the mixture of substance A and substance B i.e. reducing agent and
Time existing for the mixture of oxidant, to realize the better control to electrochemical process.In such as figure 3., 4., 5. process
It is shown, it contacts with each other and is formed by circulation discontinuously, there is considerable time intervals to only exist a kind of substance i.e. at electrode
It only exists reducing agent or only exists oxidant (substance B and electronics are regarded as substance B anion B when coexisting—Rather than substance
B).Principle shown in this figure and process are the course of work of unitary electrode.The purpose of electro ultrafiltration is that control and reinforcing electrochemistry are anti-
It answers, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from by storing process
Electric energy (for example, electric energy through capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but the electricity consumed during electro ultrafiltration
It can not be lost, and be stored at electrode, be released together when electric current is reversed.
Embodiment 27
Figure 25-1 is shown including electrode (such as the present invention in region A) and electric conductor corresponding with this electrode,
The process chart that substance A and substance B are alternately contacted with electrode, chemical energy device for converting electric energy disclosed in this invention may be selected
Property select according to following courses of work work.
In Figure 25-1,1a is electrode, and 2a is electric conductor, and 6a is interpolar spacer, A representative species A (conductive reducing agent), B
Representative species B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.Work as object
When matter A and electrode 1a are contacted (1. shown process in figure), the electronics of substance A is exported to electric conductor 2a in turn under electro ultrafiltration
Make substance A forming material A cation A+(i.e. reducing agent cation A+), as the reducing agent cation A+Run up to setting degree
When (amount of accumulation depend on electro ultrafiltration intensity and electrode possessed by electrical relation), substance A and substance B switching (in such as figure
4. process shown in 3.), and electronics is made from electric conductor to imported into electrode by load 5a, substance B, substance A be just at electrode
Ion A+The product C (in such as figure 5. shown in) of substance A and substance B redox reaction is generated with electron reaction.Next may be used
It is as 5. passed through in figure all the way to divide two-way to continueShown in 1., apply the electro ultrafiltration in direction same as described above again,
And switch substance A and substance B again, and then realize cycle operation in cycles;Another way is as 5. passed through in figureTo 7. institute
Show, apply the electro ultrafiltration in direction contrary to the above, and continue to contact substance B with electrode, and then coexists in substance B and electronics
(substance B can receive in some cases electronically forms substance B anion B-or oxidant anion B to electrode—, in figure not
Display), as electronics or oxidant anion B—When running up to setting degree (in such as figure 9. shown in), switching substance A and substance B and
Make electronics through load 5a from electrode export to electric conductor (in such as figure 10. andIt is shown), reducing agent cation, electronics and oxidant
Reaction generates C (in such as figure at the electrode 1aIt is shown), reversed electro ultrafiltration next is implemented to electrode and continues to make substance
A contacted with electrode reach in figure 1. shown in state, and then realize cycle operation in cycles.Principle shown in this figure and process
It is the course of work for including the electrode and electric conductor that there is electrical relation through interpolar spacer.The purpose of electro ultrafiltration be control with it is strong
Change electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from through
Cross the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. of storing process.Electro ultrafiltration consumes electric energy, but in electro ultrafiltration process
The electric energy of middle consumption is not lost, and is stored at electrode, is released together when electric current is reversed.
Embodiment 28
Figure 25-2 is shown including electrode (such as the present invention in region A) and electric conductor corresponding with this electrode,
The process chart that the mixture of substance A and substance B and electrode contact with each other, chemical energy electric energy converting means disclosed in this invention
It sets to be selectively chosen and work according to following courses of work.
In Figure 25-2,1a is electrode, and 2a is electric conductor, and 6a is interpolar spacer, A representative species A (conductive reducing agent), B
Representative species B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.Work as object
(1. shown process in figure), the electricity of the substance A under electro ultrafiltration in mixture when the mixture of matter A and substance B and electrode contact
Son is exported to electric conductor 2a and then makes substance A forming material A cation A+(i.e. reducing agent cation A+), when the reducing agent
Cation A+When running up to setting degree (electrical relation possessed by intensity and electrode of the amount of accumulation depending on electro ultrafiltration), make
Electronics imported into electrode from electric conductor through load 5a, substance B, substance A cation A at electrode+Substance A is generated with electron reaction
With the product C of substance B redox reaction (in such as figure 4. shown in).Next two-way can be divided to continue, be all the way as
5. apply the electro ultrafiltration in direction same as described above again to shown in 1. in figure, that is, reach in figure 1. shown in state, and then realize week
And renew cycle operation;Another way is as, 5. to shown in 6., applied the electro ultrafiltration in direction contrary to the above, and then make substance in figure
B forming material B anion B — that is, oxidant anion B-(in some cases may forming material A, substance B and electronics
The situation of electrode is coexisted in, is not shown in figure), (in such as figure 8. when oxidant anion B-or electron accumulation are to setting degree
It is shown), so that electronics is exported to electric conductor (in such as figure 9. shown in) from electrode through load 5a and forms reducing agent cation A+, formed
Reducing agent cation A+, oxidant (substance B) and electronics or reducing agent cation A+C is generated with oxidant anion B-reaction
(also as in figure 9. shown in), next to electrode implement reversed electro ultrafiltration reach in figure 1. shown in state, and then realize week and
Renew cycle operation.Although there is substance A always at electrode during shown in Figure 25-2 and substance B have reducing agent always
And oxidant, but since the presence of electro ultrafiltration, reducing agent and oxidant can not directly carry out redox reaction, and then avoid
Or it weakens mixture and directly carries out the process that redox reaction loses power supply capacity at electrode.The purpose of electro ultrafiltration is control
System with strengthen electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can also be with
From the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electro ultrafiltration consumes electric energy, but makees in electricity
It is not lost, and is stored at electrode with the electric energy consumed in the process, released together when electric current is reversed.
Embodiment 29
Figure 25-3 is shown including electrode (such as the present invention in region A) and electric conductor corresponding with this electrode,
The process chart of the mixture of substance A and substance B and the mutual makes discontinuous contact of electrode, chemical energy electric energy disclosed in this invention turn
Changing device is selectively chosen to work according to following courses of work.
In Figure 25-3,1a is electrode, and 2a is electric conductor, and 6a is interpolar spacer, A representative species A (conductive reducing agent), B
Representative species B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.Except object
Outside the influence of the mixture of matter A and substance B and the mutual makes discontinuous contact of electrode, principle and the course of work shown in Figure 25-3 and figure
Principle shown in 25-2 is identical with process.The purpose of mixture and electrode makes discontinuous contact is to reduce reducing agent and oxidant mixture
Existing duration improves safety, controllability and reliability.The purpose of electro ultrafiltration is that control is made with electrochemical reaction, electricity is strengthened
With can come from external power supply, the chemical potential in electrochemical reaction can come from, can be from the electric energy by storing process
(for example, electric energy through capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not
Have and lost, and be stored at electrode, is released together when electric current is reversed.
Embodiment 30
Figure 26-1 show including electrode A (such as the present invention in region A) and electrode B (such as it is of the invention in region
B), substance A and the process chart that substance B is alternately contacted with electrode A and substance B and substance A are alternately contacted with electrode B, this
The disclosed chemical energy device for converting electric energy of invention is selectively chosen to work according to following courses of work.
In Figure 26-1,3a is electrode A, and 4a is electrode B, and 6a is interpolar spacer, A representative species A (conductive reducing agent), B
Representative species B (oxidant).(1. shown process in figure), substance when substance A is contacted with electrode A and substance B and electrode B contact
A is in electrode A forming material A cation A+(i.e. reducing agent cation A+) and electronics, substance B is in electrode B serious hope electronics (because electricity is negative
Property attract affine electronics), the electronics of electrode A is loaded 5a and exports to electrode B (substance B can receive electronics shape in some cases
At substance B anion B—Or oxidant anion B—, do not show in figure), as the A of electrode A+(or the electronics or electricity of electrode B
The B of pole B—) when running up to setting degree, substance A and substance B switch (in such as figure 4. shown in) and electronics through load 5a from electricity
Pole B imported into electrode A, occurs to generate substance A and substance B redox reaction product C at this time in electrode A and electrode B
Reaction (5. shown in such as figure).Because substance B has strong electronegativity, therefore works as and lead from the coexistence state of substance B, substance A and electronics
It will form substance B, substance A cation A when electronics out+With electronics coexistence state, and then three react generate C.Next can divide
Two-way continues, and is as 5. passed through in figure all the wayShown in 1., and in process1. locating to switch substance A and substance again
B, and then realize cycle operation in cycles;Another way is as 5. passed through in figureShown in 7., that is, carry out maintaining substance B and electricity
Pole A contact, substance A contacts with electrode B, when electrode A electronics (electronics and substance B electrode A coexist or electronics in electrode A and
Substance B forming material B anion or oxidant anion B-, do not show in figure) or when electrode B A+Run up to setting journey
When spending (8. shown in such as figure), switches substance A and substance B and electronics is made to export to electrode B (in such as figure from electrode A through load 5a
Shown in 9.), at this moment occurs to generate the reaction (in such as figure 10. shown) of C in electrode A and electrode B, continues to substance A and electrode
A contact and the state that is contacted with electrode B of substance B reach in figure 1. shown in process, and then realization cycle operation in cycles.
Embodiment 31
Figure 26-2 show including electrode A (such as the present invention in region A) and electrode B (such as it is of the invention in region
B), the mixture of substance A and substance B is contacted with electrode A and substance B and the mixture of substance A are contacted with electrode B and electricity is made
With the process chart of participation, chemical energy device for converting electric energy disclosed in this invention is selectively chosen according to following work
Process work.
In Figure 26-2,3a is electrode A, and 4a is electrode B, and 6a is interpolar spacer, A representative species A (conductive reducing agent), B
Representative species B (oxidant).When the mixture of substance A and substance B contacted with electrode A and the mixture of substance A and substance B and electricity
When pole B is contacted (1. shown process in figure), the substance A in mixture is in electrode A forming material A cation A+(i.e. reducing agent is being just
Ion A+) and electronics, the substance A in mixture is in electrode B also forming material A cation A+(i.e. reducing agent cation A+) and electricity
Son, the substance B in mixture are thirsted for electronics (because electronegativity attracts affine electronics) in electrode A, and the substance B in mixture is in electrode
B also thirsts for electronics (because electronegativity attracts affine electronics), and therefore, electrode A and electrode B are in symmetry status, do not have electric current stream
It is dynamic.However, the electronics of electrode A is exported to electrode B, and (substance B can receive electronics shape in some cases when applying electro ultrafiltration
At substance B anion B—Or oxidant anion B—, do not show in figure) and (in such as figure 1. and 2. shown in), as the A of electrode A+
(electrode B electronics or electrode B B—) when running up to setting degree (in such as figure 3. shown in), make electronics through load 5a from electrode
B imported into electrode A (4. shown in such as figure), occurs to generate substance A in electrode A and electrode B at this time and substance B redox is anti-
Answer the reaction (4. shown in such as figure) of product C.Because substance B has strong electronegativity, therefore works as from substance B, substance A and electronics
It will form substance B, substance A cation A when exporting electronics in coexistence state+With electronics coexistence state, and then three react generate C.It connects
Getting off can divide two-way to continue, and be as, 5. to shown in 1., and then realized cycle operation in cycles in figure all the way;Another way
Be as, 5. to shown in 6., applied the electro ultrafiltration of opposite direction in figure, when electrode A electronics (electronics and substance B coexist in electrode A,
Or electronics is in electrode A and substance B forming material B anion or oxidant anion B—, do not show in figure, in B—In the presence of,
Work as B—When running up to setting degree) when running up to setting degree or when electrode B A+(such as 8. institute in figure when running up to setting degree
Show), so that electronics is exported to electrode B (in such as figure 9. shown in) from electrode A through load 5a, is at this moment given birth in electrode A and electrode B
At the reaction (in such as figure 9. shown in) of C, apply opposite direction electro ultrafiltration reach in figure 1. shown in process, and then realize week and
Renew cycle operation.The purpose of electro ultrafiltration is that control can come from external power supply, can come with electrochemical reaction, electro ultrafiltration is strengthened
From the chemical potential in electrochemical reaction, the electric energy by storing process can be from (for example, the electricity through capacitor or oscillating circuit
Can) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored in electrode
Place, is released together when electric current is reversed.
Embodiment 32
Figure 26-3 show including electrode A (such as the present invention in region A) and electrode B (such as it is of the invention in region
B), the mixture of substance A and substance B discontinuously connects with electrode A makes discontinuous contact and substance B and the mixture of substance A with electrode B
Touching and electro ultrafiltration participate in process chart, chemical energy device for converting electric energy disclosed in this invention be selectively chosen by
It works according to following courses of work.
In Figure 26-3,3a is electrode A, and 4a is electrode B, and 6a is interpolar spacer, A representative species A (conductive reducing agent), B
Representative species B (oxidant).Other than the influence of electrode and mixture makes discontinuous contact, principle shown in Figure 26-3 and process and figure
Identical shown in 26-2, making the purpose of electrode and mixture makes discontinuous contact is to reduce duration existing for mixture, increases process
Safety, reliability and controllability.The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, and electro ultrafiltration can come from external electrical
Source can come from the chemical potential in electrochemical reaction, can be from the electric energy by storing process (for example, through capacitor or vibration
Swing the electric energy of circuit) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, but by
It is stored at electrode, is released together when electric current is reversed.
Embodiment 33
Figure 26-4 show including electrode A (such as the present invention in region A) and electrode B (such as it is of the invention in region
B), substance A and substance B alternately contacts with electrode A and substance B and substance A replace with electrode B and contact and electro ultrafiltration participation
Process chart, chemical energy device for converting electric energy disclosed in this invention are selectively chosen according to following course of work works
Make.
In Figure 26-4,3a is electrode A, and 4a is electrode B, and 6a is interpolar spacer, A representative species A (conductive reducing agent), B
Representative species B (oxidant).(1. shown process in figure), substance when substance A is contacted with electrode A and substance B and electrode B contact
A is in electrode A forming material A cation A+(i.e. reducing agent cation A+) and electronics, substance B is in electrode B serious hope electronics (because electricity is negative
Property attract affine electronics), the electronics of electrode A is exported to electrode B (in some cases under the action of the electro ultrafiltration of application
Substance B, which can receive, electronically forms substance B anion B—Or oxidant anion B—, do not show in figure), as the A of electrode A+
(electrode B electronics or electrode B B—) when running up to setting degree, substance A and substance B switch (in such as figure 3. and 4.
It is shown) and electronics through load 5a from electrode B imported into electrode A, generation substance A and object occurs in electrode A and electrode B at this time
The reaction (5. shown in such as figure) of matter B redox reaction product C.Because substance B have strong electronegativity, therefore when from substance B,
It will form substance B, substance A cation A when exporting electronics in the coexistence state of substance A and electronics+With electronics coexistence state, and then three
Reaction generates C.Next two-way can be divided to continue, is as 5. passed through in figure all the wayShown in 1., and in process1.
Place switches substance A and substance B again, and then realizes cycle operation in cycles;Another way is as 5. passed through in figureTo 7. institute
Show, that is, carry out that substance B is maintained to contact with electrode A, substance A is contacted with electrode B, and applies the electro ultrafiltration of opposite direction, works as electrode
Electronics (the electronics and substance B coexists in electrode A or electronics is in electrode A and substance B forming material B anion or oxidant of A
Anion B—, do not show in figure, in B—In the presence of, work as B—When running up to setting degree) when running up to setting degree or work as electrode B
A+When running up to setting degree (in such as figure 9. shown in), switching substance A and substance B and make electronics be loaded 5a to lead from electrode A
Arrive out electrode B (in such as figure 10. withIt is shown), the reaction of generation C at this moment occurs (in such as figure in electrode A and electrode BInstitute
Show), continue to the state that substance A is contacted with electrode A and substance B is contacted with electrode B reach in figure 1. shown in process, in turn
Realize cycle operation in cycles.The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, and electro ultrafiltration can come from external electrical
Source can come from the chemical potential in electrochemical reaction, can be from the electric energy by storing process (for example, through capacitor or vibration
Swing the electric energy of circuit) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, but by
It is stored at electrode, is released together when electric current is reversed.
Embodiment 34
The chemical energy device for converting electric energy as shown in Figure 27-3, including conductive reducing agent, the conduction reducing agent includes leading
Electroreduction agent A1011 and conduction reducing agent B1012, the conduction reducing agent A1011 are connected to setting with oxidant feed channel 4,
The conduction reducing agent B1012 is connected to setting with oxidant feed channel 4, and the conduction reducing agent A1011 includes alternating current
The area Jie electricity, the conduction reducing agent B1012 includes the area alternating current Jie electricity.In the present embodiment, it is selectively chosen two
Plasma is set between pole (the conduction reducing agent A1011 and the conduction reducing agent B1012).The oxygen in the present embodiment
Agent, which is selectively chosen, is set as oxygen.
Embodiment 35
The chemical energy device for converting electric energy as shown in Figure 27-4, including conductive reducing agent, the conduction reducing agent includes leading
Electroreduction agent A1011 and conduction reducing agent B1012, the conduction reducing agent A1011 are connected to setting with oxidant feed channel 4,
The conduction reducing agent B1012 is connected to setting with oxidant feed channel 4, and the conduction reducing agent A1011 includes alternating current
The area Jie electricity, the conduction reducing agent B1012 includes the area alternating current Jie electricity.In the present embodiment, it is selectively chosen two
Plasma is set between pole (the conduction reducing agent A1011 and the conduction reducing agent B1012).The present embodiment and embodiment 34
Technical solution difference be provided with reversible electric machine 200.The oxidant, which is selectively chosen, in embodiment is set as
Oxygen.
The aforementioned all embodiments of the present invention further can selectively select to select the oxidant optionally
It selects and is set as oxygen.
As can embodiment in conversion, above-mentioned all embodiments of the invention and its disposable embodiment
The conductive reducing agent is selectively further set as aluminium, zinc, iron, copper, tin, magnesium, sodium, potassium, calcium, carbon, lithium, mercury, lead, packet
Include the solids of aluminium, the solids including zinc, the solids including iron, the solids including copper, the solids including tin including
The solids of magnesium, the solids including sodium, the solids including potassium, the solids including calcium, solids including mercury including lithium
Solids, the solids including lead, the solids including carbon, fluidisation object, the fluidisation object including zinc including aluminium, including iron
Fluidize object, fluidisation object, fluidisation object, fluidisation object, fluidisation object, the stream including potassium including sodium including magnesium including tin including copper
Compound, the fluidisation object including calcium, the fluidisation object including lithium, the fluidisation object including mercury, the fluidisation object including lead are set as including carbon
Fluidisation object.
As can embodiment in conversion, above-mentioned all embodiments of the invention and its disposable embodiment
Further lead the area the alternating current Jie electricity with capacitor, DC power supply, AC power source, alternating source, inductance
It is body, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit, motor, reversible
Motor, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six
The conjunction of item, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial,
Its 13 conjunction, its 14 conjunction, its 15 conjunction have electrical relation.
As can embodiment in conversion, above-mentioned all embodiments of the invention and its disposable embodiment
Further selectively to apply electro ultrafiltration to the conductive reducing agent, so that the conduction reducing agent is difficult to directly be aoxidized
Reduction reaction.
As can embodiment in conversion, above-mentioned all embodiments of the invention and its disposable embodiment
The area the alternating current Jie electricity is selectively further exported alternate electric energy and/or absorbs alternate electric energy as work normality.
As can embodiment in conversion, above-mentioned all embodiments of the invention and its disposable embodiment
The oxidant is selectively further set as the mixture of oxygen, air, air and oxygen, has pressure air, compression empty
Gas is set as hydrogen peroxide.
The chemical energy electric energy of only region (such as region A, conductive reducing agent as electrode) disclosed in this invention turns
In the specific implementation, be selectively chosen makes using region as an electrode using electric conductor as another electrode changing device
Two electrode cooperatings complete the conversion of chemical energy electric energy;It is also selectively chosen using region as an electrode, by another
As another electrode, two electrode cooperatings complete the conversion of chemical energy electric energy in region.
The principle of the chemical energy device for converting electric energy of the invention is described as follows:
Figure 27-1 is the basic logic chart for exchanging electric energy for chemical energy.All are that with the process that chemical energy exchanges electric energy for
Electronics is exported from reducing agent, so that reducing agent is formed reducing agent cation, electronics is then imported into reducing agent cation and oxygen again
In the coexisting body of agent, and then realize that reducing agent cation, oxidant and electronics three react generation reducing agent and oxidant is anti-
The product that should be generated, the summation that the electronics export during this imports is to export the process of electric energy.Figure 27-1 be using hydrogen as
The diagram that the representative of reducing agent, the representative using oxygen as oxidant carry out this basic logic.
Figure 27-2 is reducing agent oxidant electrochemical reaction controlled process figure.Reducing agent and oxidant at electrode (such as
Region A, region B in the present invention) reaction that could occur, the electrochemical reaction of electric energy can be either exported, still cannot
The reducing agent of electric energy and the direct oxidation reduction reaction of oxidant are exported, essence is all reducing agent, oxidant and electrode effect
The indispensable reaction of three, and electrode to the effect of chemical reaction is realized by electro ultrafiltration.It means that passing through change
The electrical property (or electriferous state) of electrode can control this kind of reaction.For example, if making electrode that there is electronegativity (i.e.
The ability of affine electronics is reinforced, or the ability of the affine electronics electronically formed by export), so that it may so that reducing agent is formed reduction
Agent cation process occurs and can be with Accelerating reduction dosage form at the process of reducing agent cation, if electrode is made to have electropositivity
(i.e. the ability of release electronics is reinforced, or because what importing electronically formed provides the ability of electronics), so that it may make oxidant and go back
Former agent cation react and can reacting for accelerated oxidation agent and reducing agent cation (in other words, formed oxidant to aoxidize
Agent anion process occur and can accelerated oxidation dosage form at oxidant anion process).Electrode participate in (such as catalyst ginseng
With) reducing agent and oxidant directly carry out redox reaction during need electrode i.e. not positively charged without negative electricity
(do not have electropositivity and does not have electronegativity yet, it is not within the rule by the electropositivity of itself or electronegativity of electro ultrafiltration, in other words
Say, the electronegativity of electrode and electropositivity needed not to be changed), otherwise redox reaction can not be carried out directly.This means that
As long as we change the electrical property (changing its electropositivity, electronegativity, change its charging property) of electrode, so that it may avoid or weaken also
Former agent and oxidant directly carry out redox reaction heat release and lose the process for exporting electric energy, use reducing agent and oxygen to realize
The mixture of agent carries out the safety and controllability of chemical energy electric energy conversion process, also may be implemented to reducing agent and oxidant
Probabilistic control caused by the mixed process being difficult to avoid that in handoff procedure.Generation of the Figure 27-2 using hydrogen as reducing agent
Table, using oxygen as the representative of oxidant, using D as the representative of electrode (such as region A, region B in the present invention), for passing through
Implement the process that electro ultrafiltration changes it electrically and then control chemically reacts to electrode to be shown, in figure, D+Indicate that there is electricity
Electrode (the electrode that the ability of i.e. affine electronics is reinforced, i.e., because electronics is exported what its electron affinity energy power was reinforced of negativity
Electrode), D—Indicate that there is electropositive electrode (to discharge the electrode that the ability of electronics is reinforced, i.e., release because electronics is imported into it
The electrode that the ability of electric discharge is reinforced).
Attached drawing of the invention is only a kind of signal, and any technical solution for meeting the application literature record belongs to the application
Protection scope.
It is clear that the invention is not restricted to above embodiments, according to techniques known and technology disclosed in this invention
Scheme can be derived or associate many variant schemes out, and all these variant schemes also are regarded as being protection scope of the present invention.
Claims (27)
1. a kind of chemical energy device for converting electric energy, including region A (1), it is characterised in that: the region A (1) and conductive reducing agent
Feed channel (3) connection setting, the region A (1) are connected to setting with oxidant feed channel (4), and the region A (1) includes
The area alternating current Jie electricity;
Or, the region A (1) is connected to setting, the region A with the mixture feed channel (8) of conductive reducing agent and oxidant
It (1) include the area alternating current Jie electricity;
Or, the region A (1) is connected to setting with conductive reducing agent feed channel (3), the region A (1) and oxidant feed are logical
Reducing agent control switch A (6) are arranged on the conductive reducing agent feed channel (3), the reducing agent in road (4) connection setting
Control switch A (6) is controlled by control device (10) and is discontinuously opened, and the region A (1) includes the area alternating current Jie electricity;
Or, the region A (1) is connected to setting with conductive reducing agent feed channel (3), the region A (1) and oxidant feed are logical
Road (4) connection setting, is arranged oxidant control switch A (7) on oxidant feed channel (4), the oxidant control
Switch A (7) is controlled by control device (10) and is discontinuously opened, and the region A (1) includes the area alternating current Jie electricity.
2. chemical energy device for converting electric energy as described in claim 1, it is characterised in that: the region A (1) has non-with electric conductor
Electronic conduction electrical relation, or, the region A (1) and insulation, isolation space, electrolyte, dielectric, capacitor, plasma
At least one of body, ionic liquid, ionized gas, solion and electronic conduction area have non-electronic conducting electrical relation,
Or, the conduction reducing agent and insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion
At least one of gas, solion and electronic conduction area have non-electronic conducting electrical relation.
3. a kind of chemical energy device for converting electric energy, including region A (1) and region B (2), it is characterised in that: the region A (1) with
Conductive reducing agent feed channel (3) connection setting, the region A (1) are connected to setting, the area with oxidant feed channel (4)
Domain A (1) includes the area alternating current Jie electricity, and the region B (2) includes the area alternating current Jie electricity;
Or, the region A (1) is connected to setting, the region A with the mixture feed channel (8) of conductive reducing agent and oxidant
It (1) include the area alternating current Jie electricity, the region B (2) includes the area alternating current Jie electricity;
Or, the region A (1) is connected to setting with conductive reducing agent feed channel (3), the region A (1) and oxidant feed are logical
Reducing agent control switch A (6) are arranged on the conductive reducing agent feed channel (3), the reducing agent in road (4) connection setting
Control switch A (6) is controlled by control device (10) and is discontinuously opened, and the region A (1) includes the area alternating current Jie electricity, the area
Domain B (2) includes the area alternating current Jie electricity;
Or, the region A (1) is connected to setting with conductive reducing agent feed channel (3), the region A (1) and oxidant feed are logical
Road (4) connection setting, is arranged oxidant control switch A (7) on oxidant feed channel (4), the oxidant control
Switch A (7) is controlled by control device (10) and is discontinuously opened, and the region A (1) includes the area alternating current Jie electricity, the region B
It (2) include the area alternating current Jie electricity.
4. chemical energy device for converting electric energy as claimed in claim 3, it is characterised in that: the region A (1) and the region B (2)
There is non-electronic conducting electrical relation with non-electronic conducting electrical relation or the region B (2) and the conductive reducing agent;
Or, the region A (1) is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion-gas
At least one of body, solion and electronic conduction area have non-electronic conducting electrical relation with the region B (2), or, institute
State conductive reducing agent through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas,
At least one of solion and electronic conduction area have non-electronic conducting electrical relation with the region B (2).
5. a kind of chemical energy device for converting electric energy, including region A (1) and region B (2), it is characterised in that: the region A (1) with
Conductive reducing agent feed channel (3) connection setting, the region A (1) are connected to setting, the area with oxidant feed channel (4)
Domain B (2) is connected to setting with conductive reducing agent feed channel (3), and the region B (2) is connected to oxidant feed channel (4) to be set
It sets, the region A (1) includes the area alternating current Jie electricity, and the region B (2) includes the area alternating current Jie electricity;
Or, the region A (1) is connected to setting with conductive reducing agent feed channel (3) through conductive reducing agent feed switch A (61),
The region A (1) is connected to setting with oxidant feed channel (4), and the region B (2) is through conductive reducing agent feed switch B (62)
Setting is connected to conductive reducing agent feed channel (3), the region B (2) is connected to setting with oxidant feed channel (4), described
Region A (1) includes the area alternating current Jie electricity, and the region B (2) includes the area alternating current Jie electricity;
Or, the region A (1) is connected to setting with conductive reducing agent feed channel (3), the region A (1) is opened through oxidant feed
It closes A (71) and is connected to setting with oxidant feed channel (4), the region B (2) is connected to conductive reducing agent feed channel (3) and sets
It sets, the region B (2) is connected to setting, the region A (1) with oxidant feed channel (4) through oxidant feed switch B (72)
Including the area alternating current Jie electricity, the region B (2) includes the area alternating current Jie electricity;
Or, the region A (1) is connected to setting with conductive reducing agent feed channel (3) through conductive reducing agent feed switch A (61),
The region A (1) is connected to setting with oxidant feed channel (4) through oxidant feed switch A (71), and the region B (2) is through leading
Electroreduction agent feed switch B (62) is connected to setting with conductive reducing agent feed channel (3), and the region B (2) is through oxidant feed
Switch B (72) is connected to setting with oxidant feed channel (4), and the region A (1) includes the area alternating current Jie electricity, the region B
It (2) include the area alternating current Jie electricity;
Or, the region A (1) is connected to setting with conductive reducing agent feed channel (3) through conductive reducing agent feed switch A (61),
The region A (1) is connected to setting with oxidant feed channel (4) through oxidant feed switch A (71), and the region B (2) is through leading
Electroreduction agent feed switch B (62) is connected to setting with conductive reducing agent feed channel (3), and the region B (2) is through oxidant feed
Switch B (72) is connected to setting with oxidant feed channel (4), and the region A (1) includes the area alternating current Jie electricity, the region B
It (2) include the area alternating current Jie electricity, the conduction reducing agent feed switch A (61), the conductive reducing agent feed switch B
(62), the oxidant feed switch A (71) and the oxidant feed switch B (72) are controlled by control device (10);It realizes
The conduction reducing agent feed switch A (61) and the conduction reducing agent feed switch B (62) unlatching and the oxidant feed
Switch A (71) and the oxidant feed switch B (72) are discontinuously opened, or realize the conduction reducing agent feed switch A (61)
It is discontinuously opened with the conduction reducing agent feed switch B (62) and the oxidant feed switch A (71) and the oxidant supplies
It send switch B (72) to open, or realizes that the oxidant feed switch A (71) and the conduction reducing agent feed switch B (62) are disconnected
Continuous unlatching and the unlatching of the conduction reducing agent feed switch A (61) and the oxidant feed switch B (72);
Or, the region A (1) is connected to setting, the region B with the mixture feed channel (8) of conductive reducing agent and oxidant
(2) it is connected to setting with the mixture feed channel (8) of conductive reducing agent and oxidant, the region A (1) includes that alternating current connects
Electric area, the region B (2) include the area alternating current Jie electricity;
Or, mixture feed channel (8) of the region A (1) through mixture control switch A and conductive reducing agent and oxidant is even
Logical setting, mixture feed channel (8) of the region B (2) through mixture control switch B and conductive reducing agent and oxidant is even
Logical setting, the mixture control switch A and the mixture control switch B are controlled interrupted unlatching, the area by control device
Domain A (1) includes the area alternating current Jie electricity, and the region B (2) includes the area alternating current Jie electricity.
6. chemical energy device for converting electric energy as claimed in claim 5, it is characterised in that: the region A (1) and the region B (2)
Have with the conductive reducing agent that non-electronic conducting electrical relation or the region A (1) are contacted with the region B (2) non-electronic
The conductive reducing agent that conducting electrical relation or the region B (2) are contacted with the region A (1) is closed with non-electronic conducting electricity
System, or the conductive reducing agent contacted with the region A (1) and the conductive reducing agent contacted with the region B (2) are with non-electronic
Electrical relation is connected;
Or, the region A (1) through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, from
At least one of sub- gas, solion and electronic conduction area have non-electronic conducting electrical relation with the region B (2),
Or, the region A (1) is through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ion-gas
At least one of body, solion and electronic conduction area and the conductive reducing agent contacted with the region B (2) have non-electronic
Be connected electrical relation, or, the region B (2) through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, from
At least one of sub- liquid, ionized gas, solion and electronic conduction area and the conduction contacted with the region A (1) are also
Former agent has non-electronic conducting electrical relation, or, the conductive reducing agent contacted with the region A (1) is empty through insulation, isolation
Between, in electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area at least
Conductive reducing agent that is a kind of and contacting with the region B (2) has non-electronic conducting electrical relation.
7. a kind of chemical energy device for converting electric energy, including conductive reducing agent (101), it is characterised in that: the conduction reducing agent
(101) setting is connected to oxidant feed channel (4), the conduction reducing agent (101) includes the area alternating current Jie electricity;
Or, the conduction reducing agent (101) is connected to setting with oxidant feed channel (4), the conduction reducing agent (101) includes
The area alternating current Jie electricity, the conduction reducing agent (101) and electric conductor have non-electronic conducting electrical relation, or, the conduction
Reducing agent (101) through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, from
At least one of sub- solution and electronic conduction area have non-electronic conducting electrical relation with electric conductor, or, the conductive reduction
Agent (101) and insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, ion are molten
At least one of liquid and electronic conduction area have non-electronic conducting electrical relation.
8. a kind of chemical energy device for converting electric energy, including conductive reducing agent (101), it is characterised in that: the conduction reducing agent
(101) be connected to setting with oxidant feed channel (4) through oxidant control switch A (7), the oxidant control switch A (7) by
Control device (10) control is discontinuously opened, and the conduction reducing agent (101) includes the area alternating current Jie electricity;
Or, the conduction reducing agent (101) is connected to setting, institute with oxidant feed channel (4) through oxidant control switch A (7)
It states oxidant control switch A (7) and is controlled discontinuously unlatching by control device (10), the conduction reducing agent (101) includes alternation electricity
The area Liu Jie electricity, the conduction reducing agent (101) and electric conductor have non-electronic conducting electrical relation, or, the conduction reducing agent
(101) through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion
There is non-electronic conducting electrical relation at least one of electronic conduction area and electric conductor, or, the conduction reducing agent (101)
With insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electricity
At least one of son conducting area has non-electronic conducting electrical relation.
9. a kind of chemical energy device for converting electric energy, including conductive reducing agent (101) and region B (2), it is characterised in that: described to lead
Electroreduction agent (101) is connected to setting with oxidant feed channel (4), and the conduction reducing agent (101) includes that alternating current connects electricity
Area, the region B (2) include the area alternating current Jie electricity;
Or, the conduction reducing agent (101) is connected to setting with oxidant feed channel (4), the conduction reducing agent (101) includes
The area alternating current Jie electricity, the region B (2) include the area alternating current Jie electricity, the conduction reducing agent (101) and the region B
(2) there is non-electronic conducting electrical relation, or, the conduction reducing agent (101) is situated between through insulation, isolation space, electrolyte, electricity
At least one of matter, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area and the region
B (2) has non-electronic conducting electrical relation.
10. a kind of chemical energy device for converting electric energy, including conductive reducing agent (101) and region B (2), it is characterised in that: described to lead
Electroreduction agent (101) is connected to setting with oxidant feed channel (4) through oxidant control switch A (7), and the oxidant control is opened
It closes A (7) and is controlled discontinuously unlatching by control device (10), the conduction reducing agent (101) includes the area alternating current Jie electricity, the area
Domain B (2) includes the area alternating current Jie electricity;
Or, the conduction reducing agent (101) is connected to setting, institute with oxidant feed channel (4) through oxidant control switch A (7)
It states oxidant control switch A (7) and is controlled discontinuously unlatching by control device (10), the conduction reducing agent (101) includes alternation electricity
The area Liu Jie electricity, the region B (2) include the area alternating current Jie electricity, and the conduction reducing agent (101) has with the region B (2)
Non-electronic conducting electrical relation, or, the conduction reducing agent (101) is through insulation, isolation space, electrolyte, dielectric, electricity
At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area and the region B (2)
With non-electronic conducting electrical relation.
11. a kind of chemical energy device for converting electric energy, including conductive reducing agent, it is characterised in that: the conduction reducing agent includes leading
Electroreduction agent A (1011) and conduction reducing agent B (1012), the conduction reducing agent A (1011) and oxidant feed channel (4) are even
Logical setting, the conduction reducing agent B (1012) are connected to setting, the conduction reducing agent A (1011) with oxidant feed channel (4)
Including the area alternating current Jie electricity, the conduction reducing agent B (1012) includes the area alternating current Jie electricity;
Or, conduction reducing agent A (1011) is connected to setting with oxidant feed channel (4) through oxidant control switch A (7), it is conductive
Reducing agent B (1012) is connected to setting, the conduction reducing agent with oxidant feed channel (4) through oxidant control switch B (711)
A (1011) includes the area alternating current Jie electricity, and the conduction reducing agent B (1012) includes the area alternating current Jie electricity;
Or, conduction reducing agent A (1011) is connected to setting with oxidant feed channel (4) through oxidant control switch A (7), it is conductive
Reducing agent B (1012) is connected to setting, the oxidant control with oxidant feed channel (4) through oxidant control switch B (711)
Switch A (7) and the oxidant control switch B (711) are controlled by control device (10) discontinuously opens, the conduction reducing agent A
It (1011) include the area alternating current Jie electricity, the conduction reducing agent B (1012) includes the area alternating current Jie electricity.
12. chemical energy device for converting electric energy as claimed in claim 11, it is characterised in that: the conduction reducing agent A (1011) with
The conduction reducing agent B (1012) have non-electronic conducting electrical relation, or, the conduction reducing agent A (1011) through insulation,
Completely cut off in space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area
At least one with the conduction reducing agent B (1012) with non-electronic conducting electrical relation.
13. the chemical energy device for converting electric energy as described in any one of claims 1 to 12, it is characterised in that: the conductive reduction
Agent is set as aluminium, zinc, iron, copper, tin, magnesium, sodium, potassium, calcium, carbon, lithium, mercury, lead, the solids including aluminium, the solids including zinc, packet
Include the solids of iron, the solids including copper, the solids including tin, the solids including magnesium, the solids including sodium including
The solids of potassium, the solids including calcium, the solids including lithium, the solids including mercury, solids including carbon including lead
Solids, fluidisation object, fluidisation object, fluidisation object, the fluidisation object including copper including iron including zinc including aluminium, including tin
Fluidize object, fluidisation object, fluidisation object, fluidisation object, fluidisation object, the stream including lithium including calcium including potassium including sodium including magnesium
Compound, the fluidisation object including mercury, the fluidisation object including lead or be set as include carbon fluidisation object.
14. the chemical energy device for converting electric energy as described in any one of claims 1 to 12, it is characterised in that: the alternating current
The area Jie electricity and capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductance coil, charged particle pump, phase transition
Device, reversing switch circuit, rectifier, electric field, oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its
Two conjunctions, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its
Nine conjunctions, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its ten
Five conjunctions have electrical relation.
15. chemical energy device for converting electric energy as claimed in claim 13, it is characterised in that: the alternating current Jie electricity Qu Yu electricity
Appearance, DC power supply, AC power source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, commutation are opened
Powered-down road, rectifier, electric field, oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction,
Its three conjunction, its four conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction,
Its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction tool
There is electrical relation.
16. the chemical energy device for converting electric energy as described in any one of claim 1 to 12 and 15, it is characterised in that: led to described
Electroreduction agent applies electro ultrafiltration, so that the conduction reducing agent is difficult to directly carry out redox reaction.
17. chemical energy device for converting electric energy as claimed in claim 13, it is characterised in that: apply electricity to the conductive reducing agent and make
With so that the conduction reducing agent is difficult to directly carry out redox reaction.
18. chemical energy device for converting electric energy as claimed in claim 14, it is characterised in that: apply electricity to the conductive reducing agent and make
With so that the conduction reducing agent is difficult to directly carry out redox reaction.
19. the chemical energy device for converting electric energy as described in any one of claim 1 to 12 and 15 and 17 and 18, it is characterised in that:
It is work normality that the area the alternating current Jie electricity, which exports alternate electric energy and/or absorbs alternate electric energy,.
20. chemical energy device for converting electric energy as claimed in claim 13, it is characterised in that: the output of the area the alternating current Jie electricity is handed over
Power transformation energy and/or absorption alternate electric energy are work normality.
21. chemical energy device for converting electric energy as claimed in claim 14, it is characterised in that: the output of the area the alternating current Jie electricity is handed over
Power transformation energy and/or absorption alternate electric energy are work normality.
22. chemical energy device for converting electric energy as claimed in claim 16, it is characterised in that: the output of the area the alternating current Jie electricity is handed over
Power transformation energy and/or absorption alternate electric energy are work normality.
23. the chemical energy device for converting electric energy as described in any one of claim 1 to 12 and 15 and 17 and 18 and 20 to 22, special
Sign is: the oxidant is set as the mixture of oxygen, air, air and oxygen, there is pressure air, compressed air or is set as peroxide
Change hydrogen.
24. chemical energy device for converting electric energy as claimed in claim 13, it is characterised in that: the oxidant be set as oxygen, air,
The mixture of air and oxygen has pressure air, compressed air or is set as hydrogen peroxide.
25. chemical energy device for converting electric energy as claimed in claim 14, it is characterised in that: the oxidant be set as oxygen, air,
The mixture of air and oxygen has pressure air, compressed air or is set as hydrogen peroxide.
26. chemical energy device for converting electric energy as claimed in claim 16, it is characterised in that: the oxidant be set as oxygen, air,
The mixture of air and oxygen has pressure air, compressed air or is set as hydrogen peroxide.
27. chemical energy device for converting electric energy as claimed in claim 19, it is characterised in that: the oxidant be set as oxygen, air,
The mixture of air and oxygen has pressure air, compressed air or is set as hydrogen peroxide.
Applications Claiming Priority (28)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810977121X | 2018-08-26 | ||
CN201810977121 | 2018-08-26 | ||
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