CN109860678A

CN109860678A - A kind of electrochemical reaction implementation method

Info

Publication number: CN109860678A
Application number: CN201910107795.9A
Authority: CN
Inventors: 靳北彪
Original assignee: Entropy Zero Technology Logic Engineering Group Co Ltd
Current assignee: Entropy Zero Technology Logic Engineering Group Co Ltd
Priority date: 2018-08-26
Filing date: 2019-02-02
Publication date: 2019-06-07
Also published as: CN109802200A

Abstract

The invention discloses a kind of electrochemical reaction implementation methods, making electrochemistry region alternately contact or make reducing agent and oxidant alternately to contact with electrochemistry region with reducing agent and oxidant makes electronics export and/or import between the electrochemistry region and region B, the normality for so persistently realizing work, externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.Electrochemical reaction implementation method disclosed in this invention is by termination Conventional electrochemical method and electrochemical appliance (such as fuel cell etc.) with the history for existing for necessary condition of electrolyte (such as proton exchange membrane and solid oxide electrolyte etc.), the Conventional electrochemical method and device that terminates also can not be used securely and reliably to the history of oxidant reduction agent composition, exploitation for efficient, long-life, Low-cost electric chemical devices provides new approach, and will redefine engine.

Description

A kind of electrochemical reaction implementation method

Technical field

The present invention relates to electricity field, electrochemical field more particularly to a kind of electrochemical reaction implementation methods.

Background technique

Conventional electrochemical method is required to non-electronic charged particle (such as ion or proton) and transmits between two electrodes, that is, needs Positive charged particle and negative charged particles that electrochemistry region (electrode) generates are removed, non-electronic charged particle is in two interpolars Transmission not only consume electric energy, but also be required to conduct non-electronic charged particle non-conducting electronics and there are many particular/special requirements Electrolyte (such as proton exchange membrane and solid oxide electrolyte etc. of hydrogen fuel cell), because of its complexity, this electrolysis The manufacturing technology of matter is unqualified always, and has become and restrict electrochemical method and be efficiently widely applied and its electrochemical appliance (example Such as fuel cell) improved efficiency, the basic reason of life-span upgrading and cost reduction, also have become and hinders electrochemical appliance (example Such as fuel cell) efficiently industrialization problem the most serious.If can invent a kind of not non-to be removed from electrochemistry region Electronics charged particle is that the model electrochemical of necessary condition reacts implementation method, and termination Conventional electrochemical method and electrochemistry are filled It sets (such as fuel cell etc.) and necessary item is existed for electrolyte (such as proton exchange membrane and solid oxide electrolyte etc.) The history of part, also will termination Conventional electrochemical method and device can not safe and reliable going through using oxidant reduction agent composition History provides new approach for efficient, long-life, Low-cost electric chemical devices exploitation, and will redefine engine.Therefore, Need to invent a kind of model electrochemical reaction implementation method.

Summary of the invention

To solve the above-mentioned problems, technical solution proposed by the present invention is as follows:

Scheme 1: a kind of electrochemical reaction implementation method makes electrochemistry region alternately contact or make with reducing agent and oxidant Reducing agent and oxidant are alternately contacted with electrochemistry region, or electrochemistry region and reducing agent is made to contact with each other and make the electrification School district domain and the mutual makes discontinuous contact of oxidant, or so that electrochemistry region and oxidant is contacted with each other and make the electrochemistry region with The mutual makes discontinuous contact of reducing agent makes electronics export and/or import between the electrochemistry region and region B, so continues reality The normality now to work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics；

Or, electrochemistry region is made alternately to contact or make reducing agent and oxidant and electrochemistry region with reducing agent and oxidant It alternately contacts, or so that electrochemistry region is contacted with each other with reducing agent and connect the electrochemistry region mutually discontinuously with oxidant Touching, or electrochemistry region and oxidant is made to contact with each other and make the electrochemistry region and the mutual makes discontinuous contact of reducing agent, to make institute It states reducing agent and is separated into positive particles A and electronics at electrochemistry region, electronics is made to export to region from the electrochemistry region B makes electronics return to the electrochemistry region from region B importing, the normality of work is so persistently realized, in the export of electronics And/or electric energy is externally provided on the channel imported or from outer absorption electric energy；

Or, reducing agent is made to be separated into positive particles A and electronics at electrochemistry region, make electronics from the electrochemistry region Region B is exported to, electronics is made to return to the electrochemistry region from region B importing, oxidant is present in the electrochemical school district The normality of work is so persistently realized in domain, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption Electric energy；

Or, reducing agent is made to be separated into positive particles A and electronics at electrochemistry region, make electronics from the electrochemistry region Region B is exported to, so that electronics is returned to the electrochemistry region from region B importing and reacts with oxidant, so continue The normality for realizing work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

Scheme 2: a kind of electrochemical reaction implementation method, to electrochemistry region alternating importing reducing agent and oxidant, or to Electrochemistry region imports reducing agent and discontinuously imports oxidant to the electrochemistry region, or imports oxidant to electrochemistry region And reducing agent is discontinuously imported to the electrochemistry region, so that the reducing agent is separated into positive particles at the electrochemistry region A and electronics make electronics export to region B from the electrochemistry region, and electronics is made to return to the electrochemistry from region B importing The normality of work is so persistently realized in region, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer suction Receive electric energy.

Scheme 3: a kind of electrochemical reaction implementation method is in electrochemistry region alternately in reducing agent and oxidant, or It is in electrochemistry region in reducing agent and is in the electrochemistry region discontinuously in oxidant, or be in electrochemistry region It in oxidant and is in the electrochemistry region discontinuously in reducing agent, separates the reducing agent at the electrochemistry region At positive particles A and electronics, electronics is made to export to region B from the electrochemistry region, returns to electronics from region B importing The electrochemistry region is so persistently realized the normality of work, is externally mentioned on the channel of export and/or the importing of the electronics For electric energy or from outer absorption electric energy.

Scheme 4: a kind of electrochemical reaction implementation method alternately imports reducing agent and oxidant to electrochemistry region, makes institute It states reducing agent and is separated into positive particles A and electronics at the electrochemistry region, export to electronics from the electrochemistry region Region B makes electronics return to the electrochemistry region from region B importing, the step that electronics imports and exports and the reducing agent The step alternately imported with the oxidant matches, and the normality of work is so persistently realized, in the export and/or importing of electronics Channel on externally provide electric energy or from outer absorption electric energy；

Or, importing reducing agent to electrochemistry region and discontinuously importing oxidant to the electrochemistry region, make the reduction Agent is separated into positive particles A and electronics at the electrochemistry region, and electronics is made to export to region B from the electrochemistry region, Electronics is set to return to the electrochemistry region from region B importing, the step that electronics imports and exports discontinuously is led with the oxidant The step entered matches, and so persistently realizes the normality of work, and electricity is externally provided on the channel of export and/or the importing of electronics Can or from outer absorption electric energy；

Or, importing oxidant to electrochemistry region and discontinuously importing reducing agent to the electrochemistry region, make the reduction Agent is separated into positive particles A and electronics at the electrochemistry region, and electronics is made to export to region B from the electrochemistry region, Electronics is set to return to the electrochemistry region from region B importing, the step that electronics imports and exports discontinuously is led with the reducing agent The step entered matches, and so persistently realizes the normality of work, and electricity is externally provided on the channel of export and/or the importing of electronics Can or from outer absorption electric energy.

Scheme 5: a kind of electrochemical reaction implementation method is in electrochemistry region alternately in reducing agent and oxidant, makes The reducing agent is separated into positive particles A and electronics at the electrochemistry region, exports electronics from the electrochemistry region To region B, electronics is set to return to the electrochemistry region from region B importing, the step that electronics imports and exports and the electrification The step that school district domain is alternately in the reducing agent and the oxidant matches, and so persistently realizes the normality of work, Electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy；

Or, being in electrochemistry region in reducing agent and being in the electrochemistry region discontinuously in oxidant, make described Reducing agent is separated into positive particles A and electronics at the electrochemistry region, and electronics is made to export to area from the electrochemistry region Domain B makes electronics return to the electrochemistry region from region B importing, the step that electronics imports and exports and the electrochemical school district The step that domain is discontinuously in the oxidant matches, so persistently realize work normality, electronics export and/or lead Electric energy is externally provided on the channel entered or from outer absorption electric energy；

Or, being in electrochemistry region in oxidant and being in the electrochemistry region discontinuously in reducing agent, make described Reducing agent is separated into positive particles A and electronics at the electrochemistry region, and electronics is made to export to area from the electrochemistry region Domain B makes electronics return to the electrochemistry region from region B importing, the step that electronics imports and exports and the electrochemical school district The step that domain is discontinuously in the reducing agent matches, so persistently realize work normality, electronics export and/or lead Electric energy is externally provided on the channel entered or from outer absorption electric energy.

Scheme 6: a kind of electrochemical reaction implementation method keeps electrochemistry region and the mixture of reducing agent and oxidant mutual Contact or mutual makes discontinuous contact, make the reducing agent be separated into positive particles A and electronics at the electrochemistry region, make electronics It exports and/or imports between the electrochemistry region and region B, the normality of work is so persistently realized, in the export of electronics And/or electric energy is externally provided on the channel imported or from outer absorption electric energy；

Or, the mixture of electrochemistry region and reducing agent and oxidant is made to contact with each other or mutual makes discontinuous contact, make described Reducing agent is separated into positive particles A and electronics at the electrochemistry region, and electronics is made to export to area from the electrochemistry region Domain B makes electronics return to the electrochemistry region from region B importing, the normality of work is so persistently realized, in leading for electronics Externally provide electric energy out and/or on the channel that imports or from outer absorption electric energy；

Or, importing the mixture of reducing agent and oxidant to electrochemistry region, make the reducing agent in the electrochemical school district It is separated into positive particles A and electronics at domain, electronics is made to export to region B from the electrochemistry region, makes electronics from the region B Importing returns to the electrochemistry region, so persistently realizes the normality of work, right on the channel of export and/or the importing of electronics Outer offer electric energy or from outer absorption electric energy；

Or, importing the mixture of reducing agent and oxidant to electrochemistry region, make the reducing agent in the electrochemical school district It is separated into positive particles A and electronics at domain, electronics is made to export to region B from the electrochemistry region, makes electronics from the region B Importing returns to the electrochemistry region, and the step that control electronics imports and exports realizes steady operation, so persistently realizes work Normality externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

Scheme 7: a kind of electrochemical reaction implementation method discontinuously imports the mixing of reducing agent and oxidant to electrochemistry region Object makes the reducing agent be separated into positive particles A and electronics at the electrochemistry region, makes electronics from the electrochemistry region Region B is exported to, so that electronics is returned to the electrochemistry region from region B importing, so persistently realizes the normality of work, Electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy；

Or, discontinuously importing the mixture of reducing agent and oxidant to electrochemistry region, make the reducing agent in the electrification It is separated into positive particles A and electronics at the domain of school district, electronics is made to export to region B from the electrochemistry region, makes electronics from described B importing in region returns to the electrochemistry region, and the step that control electronics imports and exports realizes steady operation, so lasting to realize The normality of work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

Scheme 8: a kind of electrochemical reaction implementation method makes electrochemistry region be in the mixture of reducing agent and oxidant In, so that the reducing agent is separated into positive particles A and electronics at the electrochemistry region, makes electronics from the electrochemistry region Region B is exported to, so that electronics is returned to the electrochemistry region from region B importing, so persistently realizes the normality of work, Electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy；

Or, being in electrochemistry region in the mixture of reducing agent and oxidant, make the reducing agent in the electrochemistry It is separated into positive particles A and electronics at region, so that electronics is exported to region B from the electrochemistry region, makes electronics from the area B importing in domain returns to the electrochemistry region, and the step that control electronics imports and exports realizes steady operation, so persistently realizes work The normality of work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

Scheme 9: a kind of electrochemical reaction implementation method makes electrochemistry region discontinuously be in the mixing of reducing agent and oxidant In object, the reducing agent is made to be separated into positive particles A and electronics at the electrochemistry region, makes electronics from the electrochemical school district Domain exports to region B, so that electronics is returned to the electrochemistry region from region B importing, so persistently realizes the normality of work, Electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy；

Or, being in electrochemistry region discontinuously in the mixture of reducing agent and oxidant, make the reducing agent in the electricity It is separated into positive particles A and electronics at chemical regions, so that electronics is exported to region B from the electrochemistry region, makes electronics from institute It states region B importing and returns to the electrochemistry region, the step that control electronics imports and exports realizes steady operation, so lasting to realize The normality of work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

Scheme 10: a kind of electrochemical reaction implementation method alternately imports reducing agent and oxidant to electrochemistry region, makes institute It states the electronics that reducing agent is separated at the electrochemistry region and exports to region B from the electrochemistry region, make electronics from institute It states region B importing and returns to the electrochemistry region, the step that electronics imports and exports replaces with the reducing agent and the oxidant The step of importing matches, and so persistently realizes the normality of work, externally provides on the channel of export and/or the importing of electronics Electric energy or from outer absorption electric energy；

Or, importing reducing agent to electrochemistry region and discontinuously importing oxidant to the electrochemistry region, make the reduction The electronics that agent is separated at the electrochemistry region exports to region B from the electrochemistry region, makes electronics from the region B Importing returns to the electrochemistry region, and the step that the step that electronics imports and exports discontinuously is imported with the oxidant matches, such as This persistently realizes the normality of work, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy；

Or, importing oxidant to electrochemistry region and discontinuously importing reducing agent to the electrochemistry region, make the reduction The electronics that agent is separated at the electrochemistry region exports to region B from the electrochemistry region, makes electronics from the region B Importing returns to the electrochemistry region, and the step that the step that electronics imports and exports discontinuously is imported with the reducing agent matches, such as This persistently realizes the normality of work, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy.

Scheme 11: a kind of electrochemical reaction implementation method is in electrochemistry region alternately in reducing agent and oxidant, makes The electronics that the reducing agent is separated at the electrochemistry region exports to region B from the electrochemistry region, make electronics from The region B importing returns to the electrochemistry region, and the step that electronics imports and exports replaces with the electrochemistry region is in institute The step stated in reducing agent and the oxidant matches, so persistently realize work normality, electronics export and/or lead Electric energy is externally provided on the channel entered or from outer absorption electric energy；

Or, being in electrochemistry region in reducing agent and being in the electrochemistry region discontinuously in oxidant, make described The electronics that reducing agent is separated at the electrochemistry region exports to region B from the electrochemistry region, makes electronics from described B importing in region returns to the electrochemistry region, and the step that electronics imports and exports and the electrochemistry region are discontinuously in the oxygen Step in agent matches, and so persistently realizes the normality of work, externally mentions on the channel of export and/or the importing of electronics For electric energy or from outer absorption electric energy；

Or, being in electrochemistry region in oxidant and being in the electrochemistry region discontinuously in reducing agent, make described The electronics that reducing agent is separated at the electrochemistry region exports to region B from the electrochemistry region, makes electronics from described B importing in region returns to the electrochemistry region, and the step that electronics imports and exports and the electrochemistry region are discontinuously in described and go back Step in former agent matches, and so persistently realizes the normality of work, externally mentions on the channel of export and/or the importing of electronics For electric energy or from outer absorption electric energy.

Scheme 12: a kind of electrochemical reaction implementation method imports the mixture of reducing agent and oxidant to electrochemistry region, The electronics for being separated into the reducing agent at the electrochemistry region exports to region B from the electrochemistry region, makes electronics The electrochemistry region is returned to from region B importing, the step that control electronics imports and exports is realized steady operation, so continued The normality for realizing work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

Scheme 13: a kind of electrochemical reaction implementation method makes electrochemistry region be in the mixture of reducing agent and oxidant In, the electronics for being separated into the reducing agent at the electrochemistry region exports to region B from the electrochemistry region, makes electricity Son returns to the electrochemistry region from region B importing, and the step that control electronics imports and exports is realized steady operation, so held The continuous normality for realizing work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

Scheme 14: a kind of electrochemical reaction implementation method, to electrochemistry region alternating importing reducing agent and oxidant, or to Electrochemistry region imports reducing agent and discontinuously imports oxidant to the electrochemistry region, or imports oxidant to electrochemistry region And discontinuously import reducing agent to the electrochemistry region, the electronics for being separated into the reducing agent at the electrochemistry region from The electrochemistry region exports to region B, so that electronics is returned to the electrochemistry region from region B importing, so continues reality The normality now to work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

Scheme 15: a kind of electrochemical reaction implementation method is in electrochemistry region alternately in reducing agent and oxidant, or It is in electrochemistry region in reducing agent and is in the electrochemistry region discontinuously in oxidant, or be in electrochemistry region It in oxidant and is in the electrochemistry region discontinuously in reducing agent, separates the reducing agent at the electrochemistry region At electronics export to region B from the electrochemistry region, make electronics from the region B importing return to the electrochemistry region, The normality for so persistently realizing work externally provides electric energy or electric from outer absorption on the channel of export and/or the importing of electronics Energy.

Scheme 16: a kind of electrochemical reaction implementation method imports the mixture of reducing agent and oxidant to electrochemistry region, The electronics for being separated into the reducing agent at the electrochemistry region exports to region B from the electrochemistry region, makes electronics Return to the electrochemistry region from region B importing, so persistently realize the normality of work, electronics export and/or lead Electric energy is externally provided on the channel entered or from outer absorption electric energy.

Scheme 17: a kind of electrochemical reaction implementation method makes electrochemistry region be in the mixture of reducing agent and oxidant In, the electronics for being separated into the reducing agent at the electrochemistry region exports to region B from the electrochemistry region, makes electricity Son returns to the electrochemistry region from region B importing, so persistently realizes the normality of work, electronics export and/or Electric energy is externally provided on the channel of importing or from outer absorption electric energy.

Scheme 18: it in scheme 1 to 5 and 10 and 11 and 14 and 15 on the basis of either a program, further selectively selects It selects and is inserted into inert substance and/or dead band duration between the reducing agent and the oxidant.

During electronics exports and/or imports, the aforementioned all schemes of the present invention optionally use electro ultrafiltration.

During electronics exports and/or imports, the aforementioned all schemes of the present invention are selectively chosen using electricity Appearance, DC power supply, AC power source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, commutation are opened Powered-down road, rectifier, electric field, oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, Its three conjunction, its four conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, Its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction.

The aforementioned all schemes of the present invention further can selectively select to make the electrochemistry region and the region B it Between there is no electrolyte to be connected to, or there are electrolyte connections, or there are dielectric relationships, or there are dielectric capacitance relationships or described The local of electrochemistry region is connected between the part of the region B there are electrolyte or the electrochemistry region and the region B Between there are there are ionic liquid or the electrochemistry regions between plasma or the electrochemistry region and the region B There are ionized gas between the region B.

The aforementioned all schemes of the present invention further can selectively select to make the electrochemistry region through insulation, isolation In space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area extremely A kind of few and region B has non-electronic conducting electrical relation.

The aforementioned all schemes of the present invention further can selectively select to make to apply the region for participating in electrochemical reaction Electro ultrafiltration, so that the substance for participating in electrochemical reaction is difficult to directly carry out redox reaction.

The aforementioned all schemes of the present invention further can selectively select to make electronics in the electrochemistry region and described It is work normality that export between the B of region, which imports,.

In the present invention, the region that electronics export imports is equal with electrode.

In the present invention, so-called electrochemistry region, so-called region B are equal with electrode.

In the present invention, " importing returns to " is equal with " importing " in " export imports ".

The present invention include AC power source and including further can selectively make in interrupted or alternate method it is described The frequency and phase of AC power source and the change frequency and phase of material stream match.

The present invention include alternating source and including further can selectively make in interrupted or alternate method it is described The frequency and phase of alternating source and the change frequency and phase of material stream match.

In the present invention, it is selectively chosen and electro ultrafiltration is applied to the electrochemistry region to realize electricity to the electrochemistry The effect in region is prior to the interaction between substance and the electrochemistry region, reducing agent and oxidant is reduced or avoided The case where redox reaction is directly carried out without electrochemical reaction.

In the present invention, so-called " dielectric relationship " refers to the relationship of both no power or obstructed ion.

In the present invention, so-called " there are electrolyte companies between the part of the local and described region B in the electrochemistry region It is logical " refer to be less than the electrochemistry region unidirectionally the electrochemistry region of macroscopical area 50% with to be less than the region B mono- To there are electrolyte connections between the region B of macroscopical area 50%.

In the present invention, the reducing agent includes methanol, ethyl alcohol, dimethyl ether, methane, natural gas, hydrogen, carbon monoxide, hydrogen Gas and carbon monoxide mixtures, gasoline, diesel oil, kerosene, carbon dust or coal dust end etc..

In the present invention, one of the reducing agent and the oxidant substance can be sensu lato oxidant, described Another substance in reducing agent and the oxidant can be the reducing agent of broad sense.Such as the reducing agent can be methanol, second Alcohol, natural gas, coal gas, hydrogen, methane, coal etc., the oxidant can be oxygen, liquid oxygen, air, compressed air, liquefied air, mistake Hydrogen oxide etc..

In the present invention, in certain circumstances, it may be necessary to start, because starting needs, make DC power supply, AC power source or electricity Hold with the electrochemistry regional connectivity or make the electrochemistry region be in electric field with realize start purpose principle be: utilization External means are implemented export to the electronics for needing derived or needs to import or are imported to create electrochemical reaction condition.

In the present invention, so-called " external means " refer to that all can have effective external means to electronics, such as outer Portion's electric hand section, external magnetic means, external electromagnetic means and external electrical field means etc..

In the present invention, so-called " inductor conductor " refers to all externally output magnetic force energy and leading from outer absorption magnetic force energy Body.Such as transformer coil, electrical-coil, conductor bars for dynamoelectric machines etc..

In the present invention, so-called " phase converter " is the direction vector and its voltage for instigating electric current (or charged particle stream) Angled device, the circuit for example including capacitor, the circuit including inductance and including capacitor also include inductance circuit Deng.

In the present invention, the principle of electrochemical method disclosed in this invention is carried out as described below:

Through detailed analysis, it can be found that there is the basic logic of universality using the process of redox reaction power generation, specifically Be analyzed as follows: the process to be generated electricity using redox reaction, is exported from reducing agent by electronics, forms reducing agent cation, then By electronics derived from institute imported into reducing agent cation and oxidant coexistence make three react generate the reducing agent and The product of the oxidizing reduction reaction externally exports electric energy on the path that electronics export and electronics import.In tradition In hydrogen-oxygen fuel cell, such as PEMFC, under the effect of the catalyst, hydrogen molecule is separated into proton and electronics, and proton is made to pass through matter Proton exchange enters the oxygen side with catalyst, and electronics is loaded from hydrogen side and imported into proton and what oxygen coexisted has catalyst Oxygen side, proton (H⁺), oxygen (O₂) and electronics (e^-) reaction generation water.This means that the process to be generated electricity using redox reaction With following basic logic: electronics is made into reducing agent positively ionized from reducing agent export, then by electronics imported into reducing agent just from The coexistence of son and oxidant makes reducing agent cation, oxidant and electronics three react the generation reducing agent and the oxidation The product of agent redox reaction, this overall process is external output electric energy, and the output of electric energy is leading by electronics Realization is imported out.This basic logic is it is meant that we can not be by the constraint of conventional fuel cell concrete form, as long as full The requirement of this basic logic of foot, so that it may externally export electric energy using the redox reaction of Oxidizing and Reducing Agents.And this The basic process of the disclosed method of invention is exactly to electronically form reducing agent cation from reducing agent export in electrochemistry region, is made Electronics exports to region B, then electronics is made to imported into the electrochemistry region from the region B, and makes electronics, oxidant and described Reducing agent cation three coexists, so that so that electronics and Oxidizing and Reducing Agents cation three is reacted generates the oxidation The product of agent and the reducing agent redox reaction, and then real there are no by necessity derived from the reducing agent cation Property under the premise of, also there is no by necessity derived from other non-electronic charged particles under the premise of, externally export electric energy.

Disclosed in this invention include reducing agent, oxidant alternating action method principle it is as follows: make electrochemical school district Domain alternately contacts or makes reducing agent and oxidant alternately to contact with electrochemistry region with reducing agent and oxidant, makes reducing agent in institute It states electrochemistry region and generates positive charged particle and electronics, so that electronics is exported to region B from the electrochemistry region, make electronics from institute It states region B to import to the electrochemistry region, positive charged particle, the oxidant and electron back described in the electrochemistry region The product that the reducing agent and the oxidant react should be generated, using the electrochemistry region and the region B it Between the export of electronics import and realize output electric energy and/or absorb electric energy, so recycle, realization continues working process (from institute State region B to the electrochemistry region import electronics when, in some cases, electronics is anti-in the electrochemistry region and oxidant Negative charged particles C should be generated, the negative charged particles C and the positive charged particle reaction generate the reducing agent and the oxidation The product that agent reacts is imported using the export of the electronics between the electrochemistry region and the region B and realizes output Electric energy and/or absorption electric energy, so recycle, realization continues working process).It is alternative in realizing this electrochemical process Ground selection makes the electrochemistry region, external circuit, capacitor and the region B constitute circuit, and/or make the electrochemistry region, External circuit, non-electronic charged particle oscillation area and the region B constitute circuit.It in this approach, can be to the electrochemistry Electro ultrafiltration is implemented in region, and electro ultrafiltration can control export and/or importing with strengthening electronic, thus it is possible to prevente effectively from reduction Redox reaction directly occurs for agent and oxidant mixing, improves safety, reliability and efficiency.In this approach, may be used First to implement electro ultrafiltration to it before the electrochemistry region and material effect, purpose is also to avoid reducing agent and oxidant Redox reaction directly occurs for mixing, improves safety, reliability and efficiency.

Disclosed in this invention include reducing agent and oxidant mixture effect method principle it is as follows: make electrification School district domain contacts with the mixture of reducing agent and oxidant or makes the mixture of reducing agent and oxidant to contact with electrochemistry region, So that electronics is exported to region B from the electrochemistry region using electro ultrafiltration, and then the reducing agent is made to form positive charged particle, from The region B imports electronics, the positive charged particle and the oxidant to the electrochemistry region and electron reaction generates institute The reaction product of reducing agent and the oxidant is stated, next step imports electricity from the region B to the electrochemistry region Son makes electronics export to the region B from the electrochemistry region, the electricity between the electrochemistry region and the region B Under the action of son imports and exports, the reducing agent and the oxidant reaction generate reacting for the reducing agent and the oxidant Product, between the electrochemistry region and the region B electronics export and/or import channel on absorb electric energy and/ Or output electric energy, it so recycles, realization continues working process (in some cases, from the region B to the electrochemical school district When domain imports electronics, the oxidant and electron reaction generate negative charged particles C, the positive band electrochondria described in the electrochemistry region The sub and described negative charged particles C reaction generates the reaction product of the reducing agent and the oxidant, in the electrochemical school district Electric energy and/or output electric energy are absorbed on the channel of electronics export and/or importing between domain and the region B, are so recycled, in fact Now continue working process).In realizing this electrochemical process, be selectively chosen make the electrochemistry region, external circuit, Capacitor and the region B constitute circuit, and/or make the electrochemistry region, external circuit, non-electronic charged particle oscillation Qu Hesuo It states region B and constitutes circuit.In this approach, oxygen directly occurs to be effectively prevented from the reducing agent and oxidant mixing Change reduction reaction, electro ultrafiltration first can be implemented to it before the electrochemistry region and material effect.

Disclosed in this invention include reducing agent and oxidant the principle of method that discontinuously acts on of mixture it is as follows: remove Outside the influence discontinuously acted on, the principle of this method and the principle of the method for the mixture effect for including reducing agent and oxidant are complete It is identical, and interrupted function is that can be better protected from or eliminate reducing agent described in mixture and the oxidant in electricity Pole participates in directly carrying out the ability that redox reaction loses output electric energy in the case where (the i.e. described electrochemistry region participates in), And then the efficiency of the method disclosed in the present is improved, under the influence of mixture discontinuously acts on, a certain electrode may be implemented only There are reducing agents (except non-electronic charged particle) to function, and another electrode only exists oxidant (non-electronic charged particle Except) state that functions, or realize that a certain electrode only exists the high concentration object of reducing agent (except non-electronic charged particle) It functions, and another electrode only exists the state that the high concentration object (except non-electronic charged particle) of oxidant functions, Any state either among these is all conducive to the efficiency for promoting electrochemical reaction.Certainly as described above, optionally Selection imports step using the export of external means (such as foreign current, external electrical field etc.) control electronics, and it is anti-to promote electrochemistry The efficiency answered.Similarly, in realizing this electrochemical process, being selectively chosen makes the electrochemistry region, external circuit, electricity Hold and the region B constitutes circuit, and/or makes the electrochemistry region, external circuit, non-electronic charged particle oscillation area and described Region B constitutes circuit.

In the present invention, the working principle of the partial circuit of the electrical return of disclosed method is to utilize non-electronic electrification Particle in the electrolyte realized alternation conducting and/or stood facing each other using non-electronic charged particle with electronics and realize that alternation is led by reciprocating vibration It is logical, and then interior circuit and external circuit is made to form closed circuit, realize electrochemical process.

In the present invention, it is work normality that the export of the electronics between the electrochemistry region and the region B, which imports,.

In the present invention, so-called " it is that work is normal that the export of the electronics between the electrochemistry region and the region B, which imports, State " refers to export of the electronics from the electrochemistry region to the region B and electronics from the region B to the electrochemistry region It imports to continue working process, i.e., using the electrochemical appliance of electrochemical method disclosed in this invention in working condition, from Electrochemistry region export electronics, the region Xiang Suoshu B import electronics, electronics is exported from the region B and to the electrochemistry It is a kind of lasting process that region, which imports electronics,.In other words, the electrochemistry region and the region B are opposite with alternating current It answers and the electrochemistry region and region B is opposite with alternating current should be the process of continuing working.

In the present invention, when the reducing agent and the oxidant are certain two kinds of predetermined substance, electrochemical reaction is being realized In the process, having the reaction of the third substance participation cyclicity, (so-called cyclicity reaction, which refers to, generates certain at an electrode Substance, and the reaction that this substance is consumed at another electrode), such as the reducing agent is methanol, the oxidant is When oxygen, in acid condition, water is had as the third substance and participates in cyclicity reaction, is i.e. water produces at the electrode for absorbing electronics It is raw, and be consumed at the electrode of output electronics, and under alkaline condition, hydroxyl, which is had, as the third substance participates in recycling Property reaction, hydroxyl absorb electronics electrode at generate, output electronics electrode at be consumed.For example, methanol fuel is electric The electrochemical reaction process concrete condition in pond is as follows:

Overall reaction under alkaline condition: 2CH₃OH+3O₂+4OH^-=2CO₃ ^2-+6H₂O

Anode reaction: O₂+4e^-+2H₂O=4OH^-

Negative reaction: CH₃OH-6e^-+8OH^-=CO₃ ^2-+6H₂O

Overall reaction in acid condition: 2CH₃OH+3O₂=2CO₂+4H₂O

Anode reaction: O₂+4e^-+4H⁺=2H₂O

Negative reaction: CH₃OH-6e^-+H₂O=6H⁺+CO₂

For another example the electrochemical reaction process concrete condition of methane fuel cell is as follows:

Overall reaction under alkaline condition: CH₄+2O₂+2OH^-=CO₃ ^2-+3H₂O

Anode reaction: 2O₂+8e^-+4H₂O=8OH^-

Negative reaction: CH₄-8e^-+10OH^-=CO₃ ^2-+7H₂O

Overall reaction in acid condition: CH₄+2O₂=CO₂+2H₂O

Anode reaction: 2O₂+8e^-+8H⁺=4H₂O

Negative reaction: CH₄-8e^-+2H₂O=8H⁺+CO₂

In the present invention, according to the method disclosed in the present, substance and the effect in electrode (such as electrochemistry region) are preferential In electricity and the effect of electrode, this form may be implemented the due electrochemical process of the present invention completely, but reducing agent and oxidation Agent will appear in many cases to be existed simultaneously at same electrode (when especially with the mixture of reducing agent and oxidant), If this state is precisely that startup stage or electrode did not had in the period of electro ultrafiltration, at this moment reducing agent and oxidant can be direct The conversion process between redox reaction forfeiture and electric energy occurs, in order to avoid this state generates it is necessary in advance to electrode Implement electro ultrafiltration, and it is so-called " to the region application electro ultrafiltration for participating in electrochemical reaction, so as to participate in the substance of electrochemical reaction Be difficult to directly carry out redox reaction " purpose be that this.

In the present invention, under certain temperature and/or pressure, so-called electrochemistry region, which is selectively chosen, to be set as not wrapping The conductive region of catalyst is included, because it is anti-can still to carry out electrochemistry without using catalyst under certain temperature and/or pressure It answers.

It in the present invention, is selectively chosen and electro ultrafiltration is applied to the electrochemistry region, to realize to the electrochemistry Reducing agent and oxygen is reduced or avoided prior to the interaction between substance and the electrochemistry region in the electro ultrafiltration in region Agent directly carries out the case where redox reaction loses output electric energy.

In the present invention, so that charged particle is stored in the means in electrochemistry region as realizing, be selectively chosen and pass through The alternating of the contact of two kinds of metabolies and electric current that make electrochemistry region and participation electrochemical reaction changes to realize, also optional Select to selecting property to make that two kinds of substances for participating in electrochemical reaction alternately contacts with electrochemistry region and the alternating of electric current changes It realizes, however the conducting of the non-electronic charged particle between two electrodes of electrochemical reaction (such as electrochemistry region and region B) May or may not then exist.

In the present invention, charged particle is set to be stored in the means in electrochemistry region as realizing, being selectively chosen makes electricity The mixture contact of two kinds of substances of chemical regions and participation electrochemical reaction and the alternating of electric current change to realize, may be selected Property select to make electrochemistry region and participate in the mixture makes discontinuous contact of two kinds of substances of electrochemical reaction and the alternating of electric current Variation is to realize, however the non-electronic charged particle between two electrodes of electrochemical reaction (such as electrochemistry region and region B) Conducting may or may not then exist.

In the present invention, it is that the Q generated at P is instigated to be stored in institute that the so-called Q for making the generation at P, which is stored at the P, The electrode zone represented at P is stated, including the Q to be unnecessarily transmitted to the electrode zone polarity with representative at the P The process of opposite electrode zone.

Reaction is participated in the next step in present invention, it is desirable to certain charged particle is stored in a certain region and is waited, It is that the Q generated at P is instigated to be stored in the electrode represented at the P that the so-called Q for making the generation at P, which is stored at the P, Region, including the Q to be unnecessarily transmitted to the mistake with the opposite polarity electrode zone of electrode zone represented at the P Journey.

In the present invention, the reducing agent used in the electrochemical reaction implementation method and oxidant with the reducing agent and In the presence of the form of the mixture of the oxidant, further can selectively it select with the reducing agent and the oxygen The form of the molar mixture of agent exists, or with the mixture of the explosion limit reducing agent and the oxidant below Form exist, or by the form of the mixture of the local explosion limit reducing agent below and the oxidant exist, or In the form of the mixture of more than the explosion limit reducing agent and the oxidant exist, or with local explosion limit more than The reducing agent and the oxidant mixture form exist.

In the present invention, the mixture of so-called reducing agent and oxidant further can selectively select to be set as reducing agent and Molar mixture, the explosion limit reducing agent below and the mixture of oxidant, local explosion limit of oxidant are below It is more than the mixture of more than mixture of reducing agent and oxidant, explosion limit reducing agent and oxidant or local explosion limit Reducing agent and oxidant mixture.

In the present invention, so-called molar mixture refers to that the molar concentration rate of mixture is positive and negative in chemical reaction molar ratio Mixture within 10%.

In the present invention, the export of the electronics in the electrochemistry region imports the electronics referred to do not include during being electrically separated Appearance and accumulation.

In the present invention, the export of the electronics in the electrochemistry region is imported to continue working process.

In the present invention, electrochemistry region state corresponding with alternating electromotive force and alternating current is to continue working Journey.

The electrochemical reaction implementation method disclosed in this invention is corresponding with alternating electromotive force and alternating current, i.e., electric Chemical regions are corresponding with alternating electromotive force and alternating current.

In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen through non-electronic Relationship is connected in the direct electricity that charged particle is formed, and relationship, warp is connected in the electricity formed through non-electronic charged particle reciprocating vibration One of electricity conducting relationship that capacitance relation is formed, secondly conjunction or thirdly conjunction.

In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen including through exhausted The electrical relation that alternating current can be made to be connected of edge body, dielectric and the conducting body isolation of non-electronic charged particle.

In the present invention, in the method between two electrodes (such as electrochemistry region and region B) there are electrolyte, non-electronic band Charged particle can both pass through electrolyte, reach another electrode from an electrode, can also realize alternation by reciprocating vibration in the electrolyte The effect of current lead-through.

In the present invention, electrochemistry region corresponding with alternating electromotive force and alternating current is essence feature of the invention, In the present invention, two kinds of substances due to participating in electrochemical reaction exist with electrochemistry region to be contacted, and electrochemistry region and friendship Power transformation kinetic potential and alternating current are corresponding, i.e., the electromotive force in electrochemistry region in the present invention is alternating electromotive force, absorb and/or The electric current for exporting electric energy is alternating current, and this is through the lasting sex work normality of whole work process, this duration Work normality eliminates the necessity of non-electronic charged particle transmission between two electrodes, thus no matter make between two electrodes in electronics every Exhausted state, non-electronic charged particle state of isolation have the state for the electrolyte that non-electronic charged particle is connected between two electrodes, also It is that can be worked normally in other states as long as can be realized the Oscillating flow of electronics.There are electrolyte between two electrodes In method, non-electronic charged particle can both pass through electrolyte, reach another electrode from an electrode, can also be past in the electrolyte Complex oscillation realizes the effect of alternating current conducting.This provides fine for the manufacture and use of electrochemical appliance especially fuel cell New method.

In the present invention, the alternation of electric current and substance replace and the effect of the alternation and mixture of substances of electric current is formed by Alternation process is a kind of lasting course of work, is a kind of work normality, and its purpose is to eliminate non-electronic band Charged particle two interelectrode transmitting necessity, to promote the science that chemical energy exchanges the electrochemical method of electric energy for, in turn Promote service life, reliability, low cost and the efficiency of electrochemical appliance corresponding with the method disclosed in the present.This electricity The purpose of principle and purpose of chemical method and conventional fuel cell are catalyst regeneration is temporary to exchange Oxidizing and Reducing Agents Feed channel, which forms the principle of temporary electrode change in polarity and purpose, has essential distinction, also and to prevent, weaken and remove The principle and purpose of the frequently pole-reversing electroosmosis of electrode attachment have essential distinction.

In the present invention, from a certain region export electronic processes duration with to this region import electronic processes duration it Than between 1/6 and 6, between 1/5 and 5, between 1/4 and 4, between 1/3 and 3, between 1/2.5 and 2.5,1/2 And between 2, between 1/1.5 and 1.5, between 1/1.3 and 1.3, between 1/1.2 and 1.2 or 1/1.1 and 1.1 it Between, or it is equal with the duration of electronic processes is imported to this region from the duration of a certain region export electronic processes.

In the present invention, during exporting electric energy and/or absorbing electric energy, selectively selection uses electro ultrafiltration；Or, During exporting electric energy and/or absorbing electric energy, selectively selection uses capacitor, DC power supply, AC power source, alternation electricity Source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit, Motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five Conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, its ten The conjunction of binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction.

In the present invention, the purpose of so-called " during exporting electric energy and/or absorbing electric energy, using electro ultrafiltration " is benefit The process of output electric energy is controlled or strengthened with electro ultrafiltration and/or absorbs the process of electric energy, in this way can with the efficiency of lifting process and Safety, such as an electrochemical process may take a long time to complete, but if can be made using electro ultrafiltration The reaction rate of the slower procedure segment of electrochemical reaction rates is promoted, and then is improved efficiency.

In the present invention, so-called electro ultrafiltration, which refers to, brings it about displacement and/or stream to electronics application using electric field, electric current etc. Dynamic effect.

In the present invention, it is more big more be conducive to electrochemistry that capacitance is formed by between the electrochemistry region and the region B The promotion of reaction density, therefore when being electrochemically reacted using the method disclosed in the present, the electrochemical school district should be made Capacitance between domain and the region B increases as much as possible.

It, can be in the electrochemical school district in order to increase the capacitance between the electrochemistry region and the region B in the present invention Plasma, ionic liquid, ionized gas or solion are set between domain and the region B, and make ion in the electrification It is vibrated between school district domain and the region B, and/or vibrates in the electrochemistry areas adjacent and oscillated around in the region B, To realize the purpose for increasing the capacitance between the electrochemistry region and the region B.

In the present invention, it is more big more be conducive to electrification that capacitance is formed by between the electrochemistry region and the region B The promotion of reaction density is learned, therefore when being electrochemically reacted using the method disclosed in the present, the electrochemistry should be made Capacitance between region and the region B increases as much as possible.

In the present invention, to realize that specific charged particle is stored in electrochemistry region, need to join the electrochemistry region Alternate change physical environment or make the electrochemistry region between the different material of electrochemical reaction and participate in electrochemical reaction The mixture of different material contacts, and is just able to achieve.Fundamentally, as long as the electrochemistry region is made to participate in electrochemical reaction Different material between alternate change physical environment or make the electrochemistry region and participate in the mixed of the different material of electrochemical reaction Object contact is closed, can be achieved with the purpose that the specific charged particle is stored in electrochemistry region, no matter the electrochemistry region has There are two types of the conductive channel of charged particle, (such as one of is proton conductive channel, i.e. there is conducting certain band between two electrodes The electrolyte of charged particle, another kind be electronic conduction channel) or the electrochemistry region there was only electronic conduction channel, change sentence It talks about, as long as making the electrochemistry region alternate change physical environment or described between the different material for participating in electrochemical reaction Electrochemistry region is contacted with the mixture for the different material for participating in electrochemical reaction, can be achieved with the specific charged particle storage Participate in the purpose that electrochemical reaction is realized in reaction in electrochemistry region and in the next step, no matter two electrodes (such as the electricity Chemical regions and the region B) between whether there is electrolyte.The export of electrochemistry region imports the worked of the method for charged particle Journey is similar with this.

In the present invention, in electrochemistry region, tool there are two types of the conductive channel of charged particle, (such as lead for proton by one of which , i.e. there is the electrolyte that specific charged particle is connected between two electrodes in circulation passage, another kind is electronic conduction channel) electrochemistry side In method, alternate change physical environment or made described between the different material for participating in electrochemical reaction by making the electrochemistry region Electrochemistry region is contacted with the mixture for the different material for participating in electrochemical reaction, can be achieved to eliminate from the electrochemistry region The necessity for removing the non-electronic charged particle generated in the electrochemistry region, can also realize that non-electronic charged particle is stored in The electrochemistry region and the purpose for participating in reaction realization electrochemical reaction in the next step.The alternate change of physical environment or The electrochemistry region and the mixture for the different material for participating in electrochemical reaction are contacted, can make to be stored in the electrochemical school district Non-electronic charged particle in domain participates in reacting in the next step, realizes electrochemical process, therefore from the electrochemical school district The necessity that non-electronic charged particle is exported in domain completely disappears.The case where necessity derived from non-electronic charged particle disappears Under, although some non-electronic charged particle that ought to be stored in the electrochemistry region is exported, also have non-electronic Charged particle is stored in the electrochemistry region and waits next reaction step, in other words, if the electrochemistry region The alternate change physical environment between the different material for participating in electrochemical reaction, or it is mixed with the different material of participation electrochemical reaction Object contact is closed, although there are electrolyte between two electrodes (such as the electrochemistry region and described region B), is also had non-electronic Charged particle is stored in the electrochemistry region and participation reaction in the next step is waited to realize electrochemical reaction process.

Electrochemical reaction implementation method disclosed in this invention, there are can reduce in the case where electrolyte between two electrodes Electrolyte load extends its service life and is conducive to the balance and stability operation of system.

In the present invention, in the method that electrochemistry region only has electronic conduction channel (the i.e. described electrochemistry region with it is described Interior circuit or external circuit between the B of region are in electronics and non-electronic charged particle state of isolation), the electrochemistry region is being joined Alternate change physical environment and the electrochemistry region and electrochemical reaction is participated in not between the different material of electrochemical reaction The mixture of commaterial contacts, and non-electronic charged particle can be made to be stored in the electrochemistry region, the change of physical environment or Contacting the electrochemistry region with the mixture for the different material for participating in electrochemical reaction can make to be stored in the electrochemical school district The non-electronic charged particle in domain participates in reaction in the next step and realizes electrochemical process, that is, eliminates and move from electrochemistry region The necessity of non-electronic charged particle out.Express herein, in Conventional electrochemical method, electrochemistry region (i.e. electrode) is at least wrapped Include two kinds of charged particle conductings, such as an electronic conduction channel, a proton conductive channel.

Electrochemical reaction implementation method disclosed in this invention include exchanged for electric energy chemical energy electrochemical method (such as Electrochemical method for synthesizing etc.) and exchange with chemical energy the electrochemical method (such as fuel cell etc.) of electric energy for, it is closed as electrochemistry At method in use, the different step that the export of electronics imports, which may exist, exports the case where electric energy is with electric energy is absorbed, but its Summation is to absorb electric energy, as the method (such as fuel cell etc.) for exchanging electric energy for chemical energy in use, the export of electronics The case where different step of importing may exist output electric energy and absorb electric energy, but its summation is output electric energy.

Electrochemical reaction implementation method disclosed in this invention self-evidently includes the participation of substance.

Electrochemical reaction implementation method disclosed in this invention is as the method for exchanging electric energy for chemical energy in use, participating in Electrochemical reaction the oxidant alternative selection be set as: oxygen, compressed air, oxygen, liquid oxygen, air, liquefied air, Fluorine, chlorine, bromine, iodine, ozone, nitric acid, the concentrated sulfuric acid, hypochlorous acid, chromic acid, Peracetic acid, perchloric acid, chlorate, nitrate, permanganic acid Salt, perchlorate, bichromate, Calcium perchlorate, ammonium perchlorate, sodium perchlorate, potassium hyperchlorate, lithium perchlorate, magnesium perchlorate, height Barium chlorate, perchloric acid strontium, silver perchlorate, ammonium chlorate, sodium chlorate, potassium chlorate, magron, calcium chlorate, copper chlorate, zinc chlorate, chlorine Sour thallium, silver chlorate, potassium permanganate, acerdol, barium permanganate, lithium nitrate, sodium nitrate, potassium nitrate, calcium nitrate, cesium nitrate, nitre Sour beryllium, potassium bromate, zinc bromate, ammonium periodate, calcium iodate, iron iodate, sodium dichromate, potassium bichromate, iron chloride, ammonium ceric nitrate, Sodium hypochlorite, SODIUM PERCARBONATE, sodium perborate, calcium hypochlorite, sodium dichloro cyanurate, copper oxide, di-iron trioxide, peroxidating Sodium, manganese dioxide, nitrogen dioxide, potassium peroxide, magnesium dioxide, calcium dioxide, hydrogen peroxide, chromium trioxide, strontium dioxide, two Sodium oxide molybdena, silver oxide, acetone, acrylonitrile, benzaldehyde, dibenzoyl peroxide, benzoquinones, carbon tetrabromide are set as chloramines etc. It is one or more kinds of；The reducing agent alternative selection is set as: hydrogen, alkane, alkene, alkynes, aromatic hydrocarbon, halogenated hydrocarbons, alcohol Class compound, phenolic compound, aldehyde compound, ketone compounds, hydroxyl acid compounds, ester type compound, sodium, aluminium, zinc, Lithium, potassium, magnesium, manganese, carbon, calcium, barium, vanadium, chromium, iron, cobalt, copper, boron, silicon, phosphorus, tin, mercury, lead, carbon dust, coal dust end, sulphur, aluminum hydride Lithium, diethyl aluminium hydride sodium, sodium borohydride, potassium borohydride, carbon monoxide, hydrogen sulfide, hydrazine, ammonia, hydrogen chloride, hydrogen iodide, two Sulfur oxide, hydrogen peroxide, vulcanized sodium, stannous chloride, formaldehyde, sulfurous acid, sulfuric acid, oxalic acid, ethyl alcohol, sodium sulfite, bisulfite Sodium, ferrous sulfate, methanol, natural gas, coal gas, methane, coke, diesel oil, dimethyl ether, kerosene, gasoline, hydrogen carbon monoxide mixtures One or more of or be set as heavy oil etc..

In the present invention, electrochemical action may be present between the reducing agent and the oxidant.

In the present invention, the item of the reducing agent and the oxidant in electrochemical reaction implementation method disclosed in this invention Under part, electrochemical reaction can occur.

In the present invention, the reducing agent is simple substance, compound or mixture, and ion or solion are not belonging to the reduction Agent.

In the present invention, the oxidant is simple substance, compound or mixture, and ion or solion are not belonging to the oxidation Agent.

Electrochemical reaction implementation method disclosed in this invention is in the nature chemical energy electric energy conversion method.

Electrochemical method disclosed in this invention is in the nature chemical energy electric energy conversion method.

It is so-called " during electronics exports and/or imports, to use capacitor, DC power supply, alternating current in the present invention Source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, Oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four it Conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 Conjunction, its ten binomial conjunction, its 13 conjunction, its 14 conjunction, its 15 conjunction " purpose be by electro ultrafiltration control The export of system and/or strengthening electronic imports.

It is so-called " during electronics exports and/or imports, to use capacitor, DC power supply, alternating current in the present invention Source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, Oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four it Conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 Conjunction, its ten binomial conjunction, its 13 conjunction, its 14 conjunction, its 15 conjunction " purpose be by electro ultrafiltration control The export of system and/or strengthening electronic imports, and control and/or the export of strengthening electronic importing can effectively avoid reducing agent and oxidation Redox reaction directly occurs for agent mixing, improves safety, reliability and efficiency, and control and/or strengthening electronic are led Safety, reliability and the effect that can be effectively promoted using reducing agent and oxidant existing method as a mixture are imported out Rate.

Using disclosed in this invention electrochemical reaction implementation method as obtain electric energy method when, " led in electronics Out and/or during importing, capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductance coil, band are used Charged particle pump, reversing switch circuit, rectifier, electric field, oscillating circuit, motor, reversible electric machine, has and adds phase converter The motor of rotary inertia or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its seven Conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, The purpose of its 14 conjunction, its 15 conjunction " is imported by electro ultrafiltration control and/or the export of strengthening electronic.This A certain step in control process is power consumption, but whole process is power supply.

Using disclosed in this invention electrochemical reaction implementation method as obtain electric energy method and use reducing agent When with the mixture of oxidant, " during electronics exports and/or imports, capacitor, DC power supply, AC power source, friendship are used Variable power source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillation Circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, Its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 it The purpose of conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction " is not only to pass through electro ultrafiltration Control and/or the export of strengthening electronic import, and are to prevent reducing agent and oxidant straight by the export importing of strengthening electronic Tap into the effective means of row redox reaction.A certain step in this control process is power consumption, but whole process is to supply Electricity.

Using disclosed in this invention electrochemical reaction implementation method as obtain electric energy method when, " led in electronics Out and/or during importing, capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductance coil, band are used Charged particle pump, reversing switch circuit, rectifier, electric field, oscillating circuit, motor, reversible electric machine, has and adds phase converter The motor of rotary inertia or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its seven Conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, The purpose of its 14 conjunction, its 15 conjunction " is not only to control by electro ultrafiltration and/or the export of strengthening electronic imports, It and is that the effective means for preventing reducing agent and oxidant from directly carrying out redox reaction is imported by the export of strengthening electronic. A certain step in this control process is power consumption, but whole process is power supply.

It in the present invention, further can selectively select that catalyst corresponding with the reducing agent is made to be set as catalyst A, with It is different that the corresponding catalyst of the oxidant is set as catalyst B, the catalyst A and the catalyst B, in this case, Catalyst in the electrochemistry region, which is selectively chosen, is set as the random mixed of the catalyst A and catalyst B Select the catalyst A for being set as contacting near catalytic domain with closing the catalyst choice in object or the electrochemistry region The band electrochondria between the catalyst A and the catalyst B can be increased with the mixture of the catalyst B in order to improve efficiency The mobility of son.

In the present invention, the purpose for being inserted into the inert substance is to evade the reducing agent and the oxidant described Exist while at electrochemistry region, or the reduction reducing agent and the oxidant exist simultaneously at the electrochemistry region Chance.

In the present invention, disclosed electrochemical reaction implementation method can be used for converting electric energy for chemical energy, it can also be used to Chemical energy is converted electrical energy into, the method that can be used to fuel cell and electrochemistry formated.

In the present invention, electrochemistry region alternative selects one of the electrode for being set as electrochemical reaction or electrode Point, the region B alternative selection is set as the electrode of electrochemical reaction or a part of electrode.

In the present invention, disclosed method can not only make the reducing agent and the oxidant externally discharge electric energy to be formed The reaction product of energy the rank low reducing agent and the oxidant, also can use the reducing agent and the oxidation Agent absorbs the reaction product of electric energy synthesis energy the rank higher reducing agent and the oxidant.

It, can be according to the operating temperature of the property and the electrochemistry region of the reducing agent and the oxidant in the present invention Select different catalyst.

In the present invention, Xiang Suoshu electrochemistry region import concentration proportion in the local explosion limit reducing agent below and The mixture of the oxidant may include fire retardant, such as nitrogen, carbon dioxide etc. are added in the mixture of hydrogen and oxygen.

In the present invention, in the method that the electrochemistry region is under set temperature, the set temperature can be set as high In equal to 100 DEG C.

In the present invention, in the method that the electrochemistry region is under set temperature, the set temperature can be set as low In equal to 90 DEG C.

In the present invention, the reducing agent and the oxidant are to refer to that electrochemical reaction occurs in the electrochemistry region Substance.

In the present invention, it can react after the reducing agent and oxidant absorption electric energy and generate compound, or right It can react after outer feed electric energy and generate compound.

In the present invention, in the method for including AC power source, the reaction of the reducing agent and the oxidant can be suction The reaction for receiving electric energy is also possible to export the reaction of electric energy.

In the present invention, in the method for including alternating source, the reaction of the reducing agent and the oxidant can be suction The reaction for receiving electric energy is also possible to export the reaction of electric energy.

In the present invention, eliminating from the necessity that electrochemistry region removes non-electronic charged particle means only to need to remove electricity Son, rather than electronics charged particle (such as proton) can store in the electrochemistry region that it is generated and the participation electricity during next Chemical reaction, it means that It is not necessary to the interior circuit or outer that centainly there is non-electronic charged particle channel to constitute between two electrodes Circuit, it is only necessary to which electrochemical process can be realized in electronic conduction circuit, in this approach, is selectively chosen electricity in it The conducting on road is that the reciprocating vibration of charged particle in capacitor and/or its internal part by being formed between its internal part is realized , and using external circuit output electric energy and/or absorb electric energy.

In the present invention, eliminating from the necessity that electrochemistry region removes two kinds of charged particles means only to need to remove electricity Son, and another charged particle (such as proton) can store in the electrochemistry region that it is generated and the participation electricity during next Chemical reaction, it means that It is not necessary to the interior circuit or outer that centainly there is non-electronic charged particle channel to constitute between two electrodes Circuit, it is only necessary to which electrochemical process can be realized in electronic conduction circuit, and in this approach, the conducting of interior circuit is to pass through The reciprocating vibration of charged particle is realized in the capacitor and/or its internal part formed between its internal part, and utilizes dispatch from foreign news agency Road exports electric energy and/or absorbs electric energy.

In the present invention, the export importing of electronics is a kind of work normality, and the export importing of so-called electronics refers to through external circuit The export of the electronics carried out imports.

In the present invention, the electrochemistry region, which is selectively chosen, is set as three-diemsnional electrode.

In the present invention, the region B is set as electrode, and further can selectively select that the region B is made to be set as three-dimensional Electrode.

In the present invention, such as there is non-electronic conducting electrical relation using Y and X as synonym, Y and X, the electronics of the Y is led The form of presentation imported out refers to that the Y, the X and electronics export import the composition that circuit three is same closed circuit Part is selectively chosen electronics export importing circuit being set as external circuit, and non-electronic conducting electrical relation is formed Circuit be set as interior circuit.

In the present invention, such as using U, W and V as synonym, U has non-electronic conducting electrical relation through W and V, and electronics is in institute The form of presentation for exporting importing between U and the V is stated, refers to that the U, the W, the V and electronics export import circuit It is the component part of same closed circuit, is selectively chosen and electronics export importing circuit is set as external circuit, and will be non- Electronic conduction electrical relation is formed by circuit and is set as interior circuit.

In the present invention, so-called " alternating electromotive force " refers to that the changed electromotive force of electromotive force, such as direction become The changed electromotive force of electromotive force or size of change.

In the present invention, so-called " alternating current " refers to the changed electric current of electric current, such as the changed electricity in direction Stream, the changed electric current of size or alternating current.

In the present invention, so-called " alternating current " is selectively chosen the electric current for being set as the variation of electric current generating period, Such as electric current or alternating current that electric current, the size generating period of direction generating period variation change.

In the present invention, so-called alternating current refers to the alternating current changed by sinusoidal rule.

In the present invention, so-called AC power source refers to the alternating source that electric current is changed by sinusoidal rule.

In the present invention, there is so-called A and B non-electronic conducting electrical relation to refer to having on interior circuit between A and B Non-electronic conducting electrical relation, and its external circuit is selectively chosen electronic conduction relationship；Or, so-called A and B has non-electrical Son conducting electrical relation, which refers to, has non-electronic conducting electrical relation on external circuit between A and B, and its interior circuit may be selected Select electronic conduction relationship to property.

In the present invention, it is so-called " the electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, etc. At least one of gas ions, ionic liquid, ionized gas, solion and electronic conduction area have non-electrical with the region B Son conducting electrical relation " include the electrochemistry region with the region B through insulator, dielectric and/or ion be connected body every From the non-electronic conducting electrical relation that has of two solion ponds.In this approach, being selectively chosen makes the electricity At least one in chemical regions and the region B forms electrical relation with capacitive region and/or non-electronic charged particle transmitter.

In the present invention, so-called " non-electronic charged particle transmitter " refer to non-conducting electronics but proton conducting or it is specific from The substance of son, i.e. electrolyte in conventional electrochemical device, can be according to the electrochemical properties of the reducing agent and the oxidant Non-electronic charged particle transmitter is selected, such as when the reducing agent is H₂, the oxidant is O₂When, the non-electronic electrification Particle conduction object alternative selects proton exchange membrane.

In the present invention, so-called " non-electronic conducting electrical relation " refers to the electricity formed through the charged particle other than electronics Conducting relationship or the electricity to be formed conducting relationship of standing facing each other through electronics, for example, relationship, non-electronic electrification is connected in the electricity that capacitor is formed The electricity conducting relationship etc. that particle reciprocating vibration is formed.

In the present invention, so-called " capacitor " be selectively chosen be set as electrolytic capacitor, super capacitor, electric double layer capacitance, All capacitors such as pseudo capacitance, fake capacitance.

In the present invention, so-called " reversible electric machine " refers to the motor that can mutually convert between motor and generator, For example, the motor that can be generated electricity when exportable rotary power, rotation when power supply.

In the present invention, it is selectively chosen and uses circumferential magnetic monopole direct current using DC reversible electromotor or selectivity selection Reversible electric machine.

In the present invention, when the purpose using reversible electric machine is the power supply using reversible electric machine when exportable power reception power The characteristics of can generating electricity, realizes the reinforcing and control imported to electronics export with electrode cooperating, and then realizes to electrochemistry mistake The optimization of journey.

It in the present invention, is selectively chosen, so that reversible electric machine movement power generation is implemented electro ultrafiltration to electrode, when the electricity of electrode When kinetic potential reaches setting degree, electrode, which powers to reversible electric machine, pushes reversible electric machine movement, sets when the electromotive force of electrode is reduced to When determining degree, reversible electric machine implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, so again and again Carry out cyclic process；In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy； It is selectively chosen, control device is set between reversible electric machine and electrode；Be selectively chosen, load with reversible electric machine, Electrode is arranged in series, or load is arranged in parallel with reversible electric machine.

It in the present invention, is selectively chosen, so that reversible electric machine movement power generation is implemented electro ultrafiltration to electrode, when electrode is in electricity When electromotive force reaches setting degree under the action of chemical reaction and/or reversible electric machine, electrode is in electrochemical reaction and/or accumulation electricity It powers under the action of lotus to reversible electric machine and pushes reversible electric machine movement, it is reversible when the electromotive force of electrode is reduced to setting degree Motor implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, so carries out cyclic process again and again； In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy；Optionally select It selects, control device is set between reversible electric machine and electrode；It being selectively chosen, load is arranged in series with reversible electric machine, electrode, Or load is arranged in parallel with reversible electric machine.

It in the present invention, is selectively chosen, makes electrode move reversible electric machine reversible electric machine power supply, when the electricity of electrode When kinetic potential is reduced to setting degree, reversible electric machine implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, when When the electromotive force of electrode reaches setting degree, electrode, which powers to reversible electric machine, pushes reversible electric machine movement, so again and again Carry out cyclic process；In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy； It is selectively chosen, control device is set between reversible electric machine and electrode；Be selectively chosen, load with reversible electric machine, Electrode is arranged in series, or load is arranged in parallel with reversible electric machine.

It in the present invention, is selectively chosen, makes electrode under the action of electrochemical reaction and/or stored charge to reversible Motor power supply moves reversible electric machine, and when the electromotive force of electrode is reduced to setting degree, reversible electric machine utilizes itself and its connection The kinetic energy power generation of moving part to electrode implement electro ultrafiltration, when electrode under the action of electrochemical reaction and/or reversible electric machine electromotive force When reaching setting degree, electrode pushes reversible electricity to reversible electric machine power supply under the action of electrochemical reaction and/or stored charge Machine movement, so carries out cyclic process again and again；In circulation, there is the process for providing electric energy and absorbing electric energy in electrode, but Circulation is whole to be to provide electric energy；It is selectively chosen, control device is set between reversible electric machine and electrode；Optionally Selection, load are arranged in series with reversible electric machine, electrode, or load is arranged in parallel with reversible electric machine.

In the present invention, so-called " electrolyte " refer to all be arranged between two electrode of electrochemical appliance only allow it is specific The substance that charged particle passes through but electronics is not allowed to pass through can be solid, liquid or membranous body etc., such as the proton of PEMFC Film and solid oxide electrolyte etc..

In the present invention, so-called " being inserted into inert substance between the reducing agent and the oxidant " refers to goes back described Former agent is contacted with electrochemistry region and the oxidant contacted with this electrochemistry region between make inert substance and this electrochemical school district Domain contact, the purpose is to keep the boundary between the electrochemical reaction of the reducing agent and the electrochemical reaction of the oxidant more clear It is clear.

In the present invention, so-called " dead band duration is inserted between the reducing agent and the oxidant " refers to goes back described Former agent is contacted with electrochemistry region and the oxidant contacted with this electrochemistry region between be arranged dead band duration, the purpose is to keep away Exempt from the reducing agent and oxidant mixing, makes the electrochemical process of the reducing agent and the electrochemical process of the oxidant Between boundary it is apparent, so-called dead band duration refers to the time interval of setting, and specific duration is according to the reducing agent and institute State the property of oxidant, the temperature in electrochemistry region and catalyst whether there is or not and stopping of needing of the reducing agent and the oxidant Time etc. is stayed to determine.

In the present invention, so-called " inert substance " refers to the object not reacted with the reducing agent and the oxidant Matter.

In the present invention, so-called " electrochemistry region " refers to that the region of electrochemical reaction can occurs in all, for example including Catalyst, ultra microstructure and/or region (such as electrode in fuel cell etc.) at a set temperature, then for example in setting temperature Metallic region under degree.

It is so-called to refer to " including catalyst, ultra microstructure and/or electrochemistry region at a set temperature " in the present invention The electrochemistry region or including catalyst or including ultra microstructure or under the set temperature or the electrification School district domain includes two or three in these three conditions.

In the present invention, so-called " ultra microstructure " refers to the microcosmic knot that can cause electrochemical reaction under setting condition Structure.

In the present invention, so-called " local explosion limit " refers under conditions of the electrochemistry region, the reducing agent The concentration ratio that cannot be exploded with the oxidant.

In the present invention, include the catalyst method in, the catalyst be set as include noble metal catalyst, or The catalyst be set as include rare earth element catalyst.

In the present invention, so-called " electronic conduction area " refers to that conduct electrons are not turned on the region of non-electronic charged particle, can Selectively selection is set as metallic conductor area, carbon conductor region etc..

In the present invention, select electronic conduction area shape when, should for the purpose of increasing its capacitance with neighbors into Row selection.

In the present invention, so-called electrochemistry region and region B have dielectric capacitance relationship.

In the present invention, so-called " dielectric capacitance relationship " refers to the capacitance relation by dielectric formation, such as the electrification Capacitance relation through dielectric formation between school district domain and the region B, dielectric can be gas, liquid, solid or true It is empty.

In the present invention, so-called interpolar spacer refers to make to have required for non-electronic conducting electrical relation between electrode Substance (including vacuum), for example, electrolyte, dielectric etc..

In the present invention, the selection of interpolar spacer alternative is set as insulation, isolation space, electrolyte, dielectric, electricity At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area.

In the present invention, so-called interpolar spacer, which is selectively chosen, is set as interior circuit, is also selectively chosen and sets For external circuit.

In the present invention, so-called electro ultrafiltration is a kind of selectivity selection.

In the present invention, so-called " non-electronic charged particle " refers to the charged particle other than electronics, such as proton or ion.

In the present invention, so-called " motor with additional rotation inertia " refers to the requirement with basis to rotary inertia, The motor of additional setting rotary inertia.

In the present invention, after a certain component names plus the letter such as so-called " A ", " B " is merely to distinguish two or several The identical component of title or substance.

In the present invention, necessary portion should be set in necessary place according to electricity field, the well-known technique of electrochemical field Part, unit or system etc..

Beneficial effects of the present invention are as follows: electrochemical reaction implementation method disclosed in this invention will terminate Conventional electrochemical Method and electrochemical appliance (such as fuel cell etc.) are with electrolyte (such as proton exchange membrane and solid oxide electrolyte etc.) The history for existing for necessary condition, also will termination Conventional electrochemical method and device can not securely and reliably use oxidant reduction The history of agent composition provides new approach for efficient, long-life, Low-cost electric chemical devices exploitation, and will determine again Adopted engine.

Detailed description of the invention

Fig. 1-1 is the schematic diagram of the embodiment of the present invention 27；

Fig. 1-2 is the schematic diagram of the embodiment of the present invention 28；

Fig. 1-3 is the schematic diagram of the embodiment of the present invention 29；

Fig. 1-4 is the schematic diagram of the embodiment of the present invention 30；

Fig. 1-5 is the schematic diagram of the embodiment of the present invention 31；

Fig. 1-6 is the schematic diagram of the embodiment of the present invention 32；

Fig. 1-7 is the schematic diagram of the embodiment of the present invention 33；

Fig. 2-1 is the basic logic chart for exchanging electric energy for chemical energy；

Fig. 2-2 is reducing agent oxidant electrochemical reaction controlled process figure.

Specific embodiment

Technical solution of the present invention is further illustrated in the following with reference to the drawings and specific embodiments.

Embodiment 1

The invention discloses a kind of electrochemical reaction implementation methods, can specifically make electrochemistry region and reducing agent and oxidant Alternating contacts or makes reducing agent and oxidant alternately to contact with electrochemistry region, makes electronics in the electrochemistry region and region B Between export and/or import, so persistently realize work normality, externally mentioned on the channel of export and/or the importing of electronics For electric energy or from outer absorption electric energy.

As disposable embodiment, the embodiment of the present invention 1, which is also selectively chosen, makes electrochemistry region and reduction Agent contacts with each other and makes the electrochemistry region and the mutual makes discontinuous contact of oxidant, or makes electrochemistry region and oxidant phase mutual connection It touches and makes the electrochemistry region and the mutual makes discontinuous contact of reducing agent.

Embodiment 2

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, makes electrochemistry region and reducing agent It alternately contacts or makes reducing agent and oxidant alternately to contact with electrochemistry region with oxidant, make the reducing agent in electrochemical school district It is separated into positive particles A and electronics at domain, electronics is made to export to region B from the electrochemistry region, makes electronics from the region B Importing returns to the electrochemistry region, so persistently realizes the normality of work, right on the channel of export and/or the importing of electronics Outer offer electric energy or from outer absorption electric energy.

As disposable embodiment, the embodiment of the present invention 2, which is also selectively chosen, makes electrochemistry region and reduction Agent contacts with each other and makes the electrochemistry region and the mutual makes discontinuous contact of oxidant, or makes electrochemistry region and oxidant phase mutual connection It touches and makes the electrochemistry region and the mutual makes discontinuous contact of reducing agent.

Embodiment 3

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, makes reducing agent in electrochemistry region Place is separated into positive particles A and electronics, and electronics is made to export to region B from the electrochemistry region, leads electronics from the region B Enter to return to the electrochemistry region, oxidant is present in the electrochemistry region, the normality of work is so persistently realized, in electronics Export and/or importing channel on externally provide electric energy or from outer absorption electric energy.

Embodiment 4

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, makes reducing agent in electrochemistry region Place is separated into positive particles A and electronics, and electronics is made to export to region B from the electrochemistry region, leads electronics from the region B Enter to return to the electrochemistry region to react with oxidant, so persistently realize work normality, electronics export and/or Electric energy is externally provided on the channel of importing or from outer absorption electric energy.

Embodiment 5

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to electrochemistry region and alternately imports Reducing agent and oxidant, or import reducing agent to electrochemistry region and discontinuously import oxidant to the electrochemistry region, or to Electrochemistry region imports oxidant and discontinuously imports reducing agent to the electrochemistry region, makes the reducing agent in the electrochemistry It is separated into positive particles A and electronics at region, so that electronics is exported to region B from the electrochemistry region, makes electronics from the area B importing in domain returns to the electrochemistry region, the normality of work is so persistently realized, in the channel of export and/or the importing of electronics It is upper externally to provide electric energy or from outer absorption electric energy.

Embodiment 6

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, is in electrochemistry region alternately In reducing agent and oxidant, or it is in electrochemistry region in reducing agent and the electrochemistry region is made discontinuously to be in oxidant In, or be in electrochemistry region in oxidant and be in the electrochemistry region discontinuously in reducing agent, make the reducing agent It is separated into positive particles A and electronics at the electrochemistry region, so that electronics is exported to region B from the electrochemistry region, makes Electronics returns to the electrochemistry region from region B importing, the normality of work is so persistently realized, in the export of the electronics And/or electric energy is externally provided on the channel imported or from outer absorption electric energy.

Embodiment 7

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to electrochemistry region and alternately imports Reducing agent and oxidant make the reducing agent be separated into positive particles A and electronics at the electrochemistry region, make electronics from institute It states electrochemistry region and exports to region B, so that electronics is returned to the electrochemistry region from region B importing, electronics imports and exports Step replace with the reducing agent and the oxidant import step match, so persistently realize work normality, Electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy.

As disposable embodiment, the embodiment of the present invention 7 is also selectively chosen to electrochemistry region and imports also Former agent and oxidant is discontinuously imported to the electrochemistry region, and the step that electronics imports and exports discontinuously is imported with the oxidant Step match.

As disposable embodiment, the embodiment of the present invention 7 is also selectively chosen to electrochemistry region and imports oxygen Agent and reducing agent is discontinuously imported to the electrochemistry region, and the step that electronics imports and exports discontinuously is imported with the reducing agent Step match.

Embodiment 8

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, is in electrochemistry region alternately In reducing agent and oxidant, the reducing agent is made to be separated into positive particles A and electronics at the electrochemistry region, make electronics from The electrochemistry region exports to region B, so that electronics is returned to the electrochemistry region from region B importing, electronics is led Step out replaces the step being in the reducing agent and the oxidant with the electrochemistry region and matches, and so continues The normality for realizing work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

As disposable embodiment, the embodiment of the present invention 8, which is also selectively chosen, is in electrochemistry region also In the former agent and step that makes the electrochemistry region discontinuously be in oxidant, and import and export electronics and the electrochemical school district The step that domain is discontinuously in the oxidant matches.

As disposable embodiment, the embodiment of the present invention 8, which is also selectively chosen, makes electrochemistry region be in oxygen In the agent and step that makes the electrochemistry region discontinuously be in reducing agent, and import and export electronics and the electrochemical school district The step that domain is discontinuously in the reducing agent matches.

Embodiment 9

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, makes electrochemistry region and reducing agent It contacts with each other with the mixture of oxidant or mutual makes discontinuous contact, is separated into the reducing agent just at the electrochemistry region Charged particle A and electronics make electronics export and/or import between the electrochemistry region and region B, so persistently realize work The normality of work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

Embodiment 10

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, makes electrochemistry region and reducing agent It contacts with each other with the mixture of oxidant or mutual makes discontinuous contact, is separated into the reducing agent just at the electrochemistry region Charged particle A and electronics make electronics export to region B from the electrochemistry region, and electronics is made to return to institute from region B importing Electrochemistry region is stated, the normality of work is so persistently realized, externally provides electric energy on the channel of export and/or the importing of electronics Or from outer absorption electric energy.

Embodiment 11

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to import to electrochemistry region and restore The mixture of agent and oxidant makes the reducing agent be separated into positive particles A and electronics at the electrochemistry region, makes electronics Region B is exported to from the electrochemistry region, so that electronics is returned to the electrochemistry region from region B importing, so continues The normality for realizing work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

Embodiment 12

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to import to electrochemistry region and restore The mixture of agent and oxidant makes the reducing agent be separated into positive particles A and electronics at the electrochemistry region, makes electronics Region B is exported to from the electrochemistry region, so that electronics is returned to the electrochemistry region from region B importing, controls electronics The step imported and exported realizes steady operation, the normality of work is so persistently realized, in the channel of export and/or the importing of electronics It is upper externally to provide electric energy or from outer absorption electric energy.

Embodiment 13

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen to electrochemistry region, discontinuously to be imported The mixture of reducing agent and oxidant makes the reducing agent be separated into positive particles A and electronics at the electrochemistry region, makes Electronics exports to region B from the electrochemistry region, so that electronics is returned to the electrochemistry region from region B importing, so The normality for persistently realizing work, externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

Embodiment 14

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen to electrochemistry region, discontinuously to be imported The mixture of reducing agent and oxidant makes the reducing agent be separated into positive particles A and electronics at the electrochemistry region, makes Electronics exports to region B from the electrochemistry region, so that electronics is returned to the electrochemistry region from region B importing, controls Step that electronics imports and exports realizes steady operation, so persistently realize the normality of work, in the export and/or importing of electronics Electric energy is externally provided on channel or from outer absorption electric energy.

Embodiment 15

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, makes electrochemistry region be in reduction In the mixture of agent and oxidant, so that the reducing agent is separated into positive particles A and electronics at the electrochemistry region, make electricity Son exports to region B from the electrochemistry region, so that electronics is returned to the electrochemistry region from region B importing, so holds The continuous normality for realizing work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

Embodiment 16

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, makes electrochemistry region be in reduction In the mixture of agent and oxidant, so that the reducing agent is separated into positive particles A and electronics at the electrochemistry region, make electricity Son exports to region B from the electrochemistry region, and electronics is made to return to the electrochemistry region, control electricity from region B importing The step that son imports and exports realizes steady operation, so persistently realizes the normality of work, in the export of electronics and/or leading to for importing Electric energy is externally provided on road or from outer absorption electric energy.

Embodiment 17

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, is in electrochemistry region discontinuously In the mixture of reducing agent and oxidant, the reducing agent is made to be separated into positive particles A and electronics at the electrochemistry region, So that electronics is exported to region B from the electrochemistry region, so that electronics is returned to the electrochemistry region from region B importing, such as This persistently realizes the normality of work, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy.

Embodiment 18

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, is in electrochemistry region discontinuously In the mixture of reducing agent and oxidant, the reducing agent is made to be separated into positive particles A and electronics at the electrochemistry region, So that electronics is exported to region B from the electrochemistry region, so that electronics is returned to the electrochemistry region from region B importing, control The step that electronics processed imports and exports realizes steady operation, the normality of work is so persistently realized, in the export and/or importing of electronics Channel on externally provide electric energy or from outer absorption electric energy.

Embodiment 19

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to electrochemistry region and alternately imports Reducing agent and oxidant, the electronics for being separated into the reducing agent at the electrochemistry region are exported from the electrochemistry region To region B, electronics is set to return to the electrochemistry region from region B importing, the step that electronics imports and exports and the reduction The step that agent and the oxidant alternately import matches, and so persistently realizes the normality of work, electronics export and/or lead Electric energy is externally provided on the channel entered or from outer absorption electric energy.

As disposable embodiment, the embodiment of the present invention 19 is also selectively chosen to electrochemistry region and imports also The former agent and step for discontinuously importing oxidant to the electrochemistry region, and importing and exporting electronics is discontinuously led with the oxidant The step entered matches.

As disposable embodiment, the embodiment of the present invention 19 is also selectively chosen to electrochemistry region and imports oxygen The agent and step for discontinuously importing reducing agent to the electrochemistry region, and importing and exporting electronics is discontinuously led with the reducing agent The step entered matches.

Embodiment 20

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, is in electrochemistry region alternately In reducing agent and oxidant, the electronics for being separated into the reducing agent at the electrochemistry region is led from the electrochemistry region Region B is arrived out, so that electronics is returned to the electrochemistry region from region B importing, the step that electronics imports and exports and the electricity The step that chemical regions are alternately in the reducing agent and the oxidant matches, and so persistently realizes the normality of work, Electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy.

As disposable embodiment, the embodiment of the present invention 20, which is also selectively chosen, is in electrochemistry region also In the former agent and step that makes the electrochemistry region discontinuously be in oxidant, and import and export electronics and the electrochemical school district The step that domain is discontinuously in the oxidant matches.

As disposable embodiment, the embodiment of the present invention 20, which is also selectively chosen, makes electrochemistry region be in oxygen In the agent and step that makes the electrochemistry region discontinuously be in reducing agent, and import and export electronics and the electrochemical school district The step that domain is discontinuously in the reducing agent matches.

Embodiment 21

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to import to electrochemistry region and restore The mixture of agent and oxidant, the electronics for being separated into the reducing agent at the electrochemistry region is from the electrochemistry region Region B is exported to, electronics is made to return to the electrochemistry region from region B importing, the step that control electronics imports and exports is real Existing steady operation so persistently realizes the normality of work, externally provided on the channel of export and/or the importing of electronics electric energy or From outer absorption electric energy.

Embodiment 22

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, makes electrochemistry region be in reduction In the mixture of agent and oxidant, the electronics that is separated into the reducing agent at the electrochemistry region is from the electrochemical school district Domain exports to region B, and electronics is made to return to the electrochemistry region, the step that control electronics imports and exports from region B importing It realizes steady operation, so persistently realizes the normality of work, externally provide electric energy on the channel of export and/or the importing of electronics Or from outer absorption electric energy.

Embodiment 23

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to electrochemistry region and alternately imports Reducing agent and oxidant, or import reducing agent to electrochemistry region and discontinuously import oxidant to the electrochemistry region, or to Electrochemistry region imports oxidant and discontinuously imports reducing agent to the electrochemistry region, makes the reducing agent in the electrochemistry The electronics being separated at region exports to region B from the electrochemistry region, and electronics is made to return to the electricity from region B importing Chemical regions, so persistently realize work normality, externally provided on the channel of export and/or the importing of electronics electric energy or from Outer absorption electric energy.

Embodiment 24

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, is in electrochemistry region alternately In reducing agent and oxidant, or it is in electrochemistry region in reducing agent and the electrochemistry region is made discontinuously to be in oxidant In, or be in electrochemistry region in oxidant and be in the electrochemistry region discontinuously in reducing agent, make the reducing agent The electronics being separated at the electrochemistry region exports to region B from the electrochemistry region, leads electronics from the region B Enter to return to the electrochemistry region, so persistently realize the normality of work, on the channel of export and/or the importing of electronics externally There is provided electric energy or from outer absorption electric energy.

Embodiment 25

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to import to electrochemistry region and restore The mixture of agent and oxidant, the electronics for being separated into the reducing agent at the electrochemistry region is from the electrochemistry region Region B is exported to, so that electronics is returned to the electrochemistry region from region B importing, so persistently realizes the normality of work, Electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy.

Embodiment 26

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, makes electrochemistry region be in reduction In the mixture of agent and oxidant, the electronics that is separated into the reducing agent at the electrochemistry region is from the electrochemical school district Domain exports to region B, so that electronics is returned to the electrochemistry region from region B importing, so persistently realizes the normality of work, Electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy.

Embodiment 27

Fig. 1-1 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , the process chart that substance A and substance B alternately contacts with electrode, electrochemical reaction implementation method of the present invention is optional Property select according to following courses of work work.

In Fig. 1-1,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, A representative species A (reducing agent), B representative species B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.When substance A and electricity When pole 1 contacts (1. shown process in figure), the electronics of substance A is exported to electric conductor 2 and then forms substance A under electro ultrafiltration Substance A cation A⁺(i.e. reducing agent cation A⁺), as the reducing agent cation A⁺(the amount of accumulation when running up to setting degree Electrical relation possessed by intensity and electrode depending on electro ultrafiltration), 3. and 4. substance A and substance B switching are (as shown in figure Process), and electronics is made to imported into electrode from electric conductor by load 5, substance B, substance A cation A at electrode⁺And electron back The product C (5. shown in such as figure) of substance A and substance B redox reaction should be generated.Next can divide two-way continue into Row, is as 5. passed through in figure all the wayShown in 1., apply the electro ultrafiltration in direction same as described above again, and switch substance A again With substance B, and then cycle operation in cycles is realized；Another way is as 5. passed through in figureShown in 7., apply contrary to the above The electro ultrafiltration in direction, and continue to contact substance B with electrode, and then substance B and electronics is made to coexist in electrode (in some cases Substance B, which can receive, electronically forms substance B anion B^—Or oxidant anion B^—, do not show in figure), when electronics or oxidation Agent anion B^—When running up to setting degree (9. shown in such as figure), switches substance A and substance B and electronics is made to be loaded 5 from electricity Pole exports to electric conductor (in such as figureWithIt is shown), reducing agent cation, electronics and oxidant react at the electrode C is generated (in such as figureIt is shown), reversed electro ultrafiltration next is implemented to electrode and continues to contact substance A with electrode to reach figure In 1. shown in state, and then realize cycle operation in cycles.Principle shown in this figure and process be include being isolated through interpolar Object has the electrode of electrical relation and the course of work of electric conductor.The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, electricity Effect can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from the electricity by storing process Energy (for example, electric energy through capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is simultaneously It is not lost, and is stored at electrode, released together when electric current is reversed.

Embodiment 28

Fig. 1-2 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , H₂And O₂The process chart of contact is alternateed with electrode, electrochemical reaction implementation method of the present invention is alternative Ground selection works according to following courses of work.

In Fig. 1-2,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, and wherein electric conductor is exported in electrodic electron and imported Play the role of another electrode in the process.Except the substance A (reducing agent) in Fig. 1-1 is with H₂To represent, substance B (oxidant) With O₂Outer to represent, principle and the course of work shown in Fig. 1-2 are identical as principle shown in Fig. 1-1 and process.The mesh of electro ultrafiltration Be control and strengthen electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, It can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electro ultrafiltration consumes electric energy, but The electric energy consumed during electro ultrafiltration is not lost, and is stored at electrode, is released together when electric current is reversed.

Embodiment 29

Fig. 1-3 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , CH₃OH and O₂The process chart of contact is alternateed with electrode, electrochemical reaction implementation method of the present invention may be selected Property select according to following courses of work work.

In Fig. 1-3,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, and wherein electric conductor is exported in electrodic electron and imported Play the role of another electrode in the process.Except the substance A (reducing agent) in Fig. 1-1 is with CH₃OH is representative, substance B (oxidation Agent) with O₂To represent, H₂It is outer that O as recycled material participates in reaction, shown in principle and the course of work shown in Fig. 1-3 and Fig. 1-1 Principle it is identical with process.The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, and electro ultrafiltration can come from external power supply, can With the chemical potential in electrochemical reaction, the electric energy by storing process can be from (for example, through capacitor or oscillating circuit Electric energy) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored in At electrode, released together when electric current is reversed.

Embodiment 30

Fig. 1-4 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , the process chart that the mixture and electrode of substance A and substance B contact with each other, electrochemical reaction realization side of the present invention Method is selectively chosen to work according to following courses of work.

In Fig. 1-4,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, A representative species A (reducing agent), B representative species B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.When substance A and object When the mixture and electrode of matter B contact (1. shown process in figure), the electronics of the substance A under electro ultrafiltration in mixture is exported To electric conductor 2 and then make substance A forming material A cation A⁺(i.e. reducing agent cation A⁺), as the reducing agent cation A⁺Product When tiring out setting degree (electrical relation possessed by intensity and electrode of the amount of accumulation depending on electro ultrafiltration), make electronics through loading 5 imported into electrode from electric conductor, substance B, substance A cation A at electrode⁺Substance A and substance B oxidation are generated with electron reaction The product C (4. shown in such as figure) of reduction reaction.Next two-way can be divided to continue, be all the way as in figure 5. to 1. institute Show, apply the electro ultrafiltration in direction same as described above again, that is, reach in figure 1. shown in state, and then realize circulation industrial in cycles Make；Another way is and then to keep substance B forming material B negative as, 5. to shown in 6., applied the electro ultrafiltration in direction contrary to the above in figure Ion B^—That is oxidant anion B^—(in some cases may forming material A, substance B and electronics coexist in the shape of electrode Condition is not shown in figure), as oxidant anion B^—Or electron accumulation to setting degree when (in such as figure 8. shown in), pass through electronics Load 5 exports to electric conductor (in such as figure 9. shown in) from electrode and forms reducing agent cation A⁺, it is formed by reducing agent cation A⁺, oxidant (substance B) and electronics or reducing agent cation A⁺With oxidant anion B^—Reaction generates C (also such as 9. institute in figure Show), next to electrode implement reversed electro ultrafiltration reach in figure 1. shown in state, and then realize cycle operation in cycles. Although there is substance A always at electrode during shown in Fig. 1-4 and substance B have reducing agent and oxidant always, Due to the presence of electro ultrafiltration, reducing agent and oxidant can not directly carry out redox reaction, and then avoid or weaken mixing Object directly carries out the process that redox reaction loses power supply capacity at electrode.The purpose of electro ultrafiltration is control and reinforcing electrification Reaction is learned, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from by storage Electric energy (for example, electric energy through capacitor or oscillating circuit) of process etc..Electro ultrafiltration consumes electric energy, but consumes during electro ultrafiltration Electric energy not lost, and be stored at electrode, released together when electric current is reversed.

Embodiment 31

Fig. 1-5 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , the mixture of substance A and substance B and the process chart of the mutual makes discontinuous contact of electrode, electrochemical reaction reality of the present invention Existing method is selectively chosen to work according to following courses of work.

In Fig. 1-5,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, A representative species A (reducing agent), B representative species B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.Except substance A and object Outside the mixture of matter B and the influence of the mutual makes discontinuous contact of electrode, shown in principle and the course of work shown in Fig. 1-5 and Fig. 1-4 Principle is identical with process.The purpose of mixture and electrode makes discontinuous contact is when reducing existing for reducing agent and oxidant mixture It is long, improve safety, controllability and reliability.The purpose of electro ultrafiltration is that control can come with electrochemical reaction, electro ultrafiltration is strengthened From external power supply, can come from the chemical potential in electrochemical reaction, can be from by storing process electric energy (for example, through The electric energy of capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but there is no damaged the electric energy consumed during electro ultrafiltration It loses, and is stored at electrode, released together when electric current is reversed.

Embodiment 32

Fig. 1-6 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , H₂And O₂Mixture and the process chart that contacts with each other of electrode, electrochemical reaction implementation method of the present invention it is optional It selects to selecting property to work according to following courses of work.

In Fig. 1-6,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, and wherein electric conductor is exported in electrodic electron and imported Play the role of another electrode in the process.Except substance A (reducing agent) is with H₂To represent, substance B (oxidant) is with O₂To represent Outside, principle and the course of work shown in Fig. 1-6 are identical as principle shown in Fig. 1-4 and process.Electro ultrafiltration can come from external electrical Source can come from the chemical potential in electrochemical reaction, can be from the electric energy by storing process (for example, through capacitor or vibration Swing the electric energy of circuit) etc..The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, and electro ultrafiltration consumes electric energy, but in electro ultrafiltration The electric energy consumed in the process is not lost, and is stored at electrode, is released together when electric current is reversed.

Embodiment 33

Fig. 1-7 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , CH₃OH and O₂Mixture and the process chart that contacts with each other of electrode, electrochemical reaction implementation method of the present invention can It selectively selects to work according to following courses of work.

In Fig. 1-7,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, and wherein electric conductor is exported in electrodic electron and imported Play the role of another electrode in the process.Except substance A (reducing agent) is with CH₃OH is representative, and substance B (oxidant) is with O₂For generation Off-balancesheet, H₂O is participated in outside reaction as recycled material, principle and the course of work shown in Fig. 1-7 and principle and mistake shown in Fig. 1-4 Cheng Xiangtong.The purpose of electro ultrafiltration is that control can come from external power supply, can come from electrification with electrochemical reaction, electro ultrafiltration is strengthened The chemical potential in reaction is learned, can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process. Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored at electrode, to electricity It is released together when flowing reversed.

As disposable embodiment, the aforementioned all electrochemistry without using Oxidizing and Reducing Agents mixture of the present invention It reacts implementation method in the specific implementation, further can selectively select interleaving in the reducing agent and the oxidant Enter inert substance and/or dead band duration.

As disposable embodiment, during electronics exports and/or imports, the aforementioned all electricity of the present invention It chemically reacts implementation method in the specific implementation, is selectively chosen using electro ultrafiltration.

As disposable embodiment, during electronics exports and/or imports, the aforementioned all electricity of the present invention It chemically reacts implementation method in the specific implementation, further can selectively select using capacitor, DC power supply, alternating current Source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, Oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four it Conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 Conjunction, its ten binomial conjunction, its 13 conjunction, its 14 conjunction, its 15 conjunction.

As disposable embodiment, the aforementioned all electrochemical reaction implementation methods of the present invention are being embodied When, it further can selectively select to make that electrolyte connection is not present between the electrochemistry region and the region B, or deposit It is connected in electrolyte, or there are dielectric relationships, or there are dielectric capacitance relationship or the parts and the area in the electrochemistry region There are there are plasmas or described between electrolyte connection or the electrochemistry region and the region B between the part of domain B There are there are ions between ionic liquid or the electrochemistry region and the region B between electrochemistry region and the region B Gas.

As disposable embodiment, the aforementioned all electrochemical reaction implementation methods of the present invention are being embodied When, it further can selectively select to make the electrochemistry region through insulation, isolation space, electrolyte, dielectric, electricity At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area have with the region B Non-electronic conducting electrical relation.

As disposable embodiment, the aforementioned all electrochemical reaction implementation methods of the present invention are being embodied When, it further can selectively select to make to apply electro ultrafiltration to the region for participating in electrochemical reaction, so that it is anti-to participate in electrochemistry The substance answered is difficult to directly carry out redox reaction.

As disposable embodiment, the aforementioned all electrochemical reaction implementation methods of the present invention are being embodied When, it further can selectively select the export for making electronics between the electrochemistry region and the region B to import as work Make normality.

The present invention in the specific implementation, further can selectively select to make to export electronic processes from the electrochemistry region Duration and to the electrochemistry region import the ratio between durations of electronic processes between 1/6 and 6, between 1/5 and 5,1/4 And between 4, between 1/3 and 3, between 1/2.5 and 2.5, between 1/2 and 2, between 1/1.5 and 1.5, in 1/1.3 and Between 1.3, between 1/1.2 and 1.2 or between 1/1.1 and 1.1, or from the electrochemistry region export electronic processes when It is long equal with the duration of electronic processes is imported to the electrochemistry region.

In the specific implementation, be selectively chosen leads electronics between the electrochemistry region and region B to the present invention Import out is work normality.Wherein the region B, which is selectively chosen, is set as electrode corresponding with the electrochemistry region.

Electrochemical reaction implementation method disclosed in this invention in the specific implementation, makes the electrochemistry region and alternation electricity Kinetic potential and the corresponding state of alternating current are to continue working process.

In the specific implementation, the electrochemical reaction implementation method disclosed in this invention and alternating electromotive force and alternation electricity Flow corresponding, i.e., electrochemistry region is corresponding with alternating electromotive force and alternating current.

As disposable embodiment, the electrochemical reaction implementation method disclosed in this invention is used as with chemical energy When exchanging the method for electric energy for, the reactant for participating in electrochemical reaction can be selected from substance documented in Summary, The substance A is preferably set to be set as hydrogen, methanol, ethyl alcohol, methane etc..

The principle of the electrochemical reaction implementation method of the invention is described as follows:

Fig. 2-1 is the basic logic chart for exchanging electric energy for chemical energy.All are that with the process that chemical energy exchanges electric energy for Electronics is exported from reducing agent, so that reducing agent is formed reducing agent cation, electronics is then imported into reducing agent cation and oxygen again In the coexisting body of agent, and then realize that reducing agent cation, oxidant and electronics three react generation reducing agent and oxidant is anti- The product that should be generated, the summation that the electronics export during this imports is to export the process of electric energy.Fig. 2-1 is using hydrogen as also The diagram that the representative of former agent, the representative using oxygen as oxidant carry out this basic logic.

Fig. 2-2 is reducing agent oxidant electrochemical reaction controlled process figure.Reducing agent and oxidant at electrode (such as this Electrochemistry region in invention) reaction that could occur, the electrochemical reaction of electric energy can be either exported, still cannot be exported The reducing agent of electric energy and the direct oxidation reduction reaction of oxidant, essence are all reducing agent, oxidant and electrode effect three Indispensable reaction, and electrode to the effect of chemical reaction is realized by electro ultrafiltration.It means that by changing electrode Electrical property (or electriferous state) this kind of reaction can be controlled.For example, if making electrode that there is electronegativity (i.e. affine electricity The ability of son is reinforced, or the ability of the affine electronics electronically formed by export), so that it may make reducing agent formed reducing agent just from Subprocess occurs and can be with Accelerating reduction dosage form at the process of reducing agent cation, if making electrode that there is electropositivity (to discharge The ability of electronics is reinforced, or the ability of the offer electronics electronically formed by importing), so that it may make oxidant and reducing agent just from Son react and can reacting for accelerated oxidation agent and reducing agent cation (oxidant in other words, is made to form oxidant anion Process occur and can accelerated oxidation dosage form at oxidant anion process).Going back for (such as catalyst participation) is participated in electrode Former agent and oxidant directly carry out needing electrode is not i.e. positively charged (not have electricity without negative electricity during redox reaction Positivity does not also have electronegativity, not within the rule by the electropositivity of itself or electronegativity of electro ultrafiltration, in other words, needs electrode Electronegativity and electropositivity be not changed), otherwise redox reaction can not be carried out directly.This means that as long as we change The electrical property (changing its electropositivity, electronegativity, change its charging property) of electrode, so that it may avoid or weaken reducing agent and oxidant It directly carries out redox reaction heat release and loses the process for exporting electric energy, to realize the mixture for using reducing agent and oxidant The safety and controllability for carrying out chemical energy electric energy conversion process also may be implemented to difficult in reducing agent and oxidant handoff procedure To avoid mixed process caused by probabilistic control.Representative of the Fig. 2-2 using hydrogen as reducing agent, using oxygen as oxidation The representative of agent, using D as the representative in electrode (such as electrochemistry region in the present invention), for by implementing electro ultrafiltration to electrode Change it electrically and then the process for controlling chemical reaction is shown, in figure, D⁺Indicate have the electrode of electronegativity (i.e. affine The electrode that the ability of electronics is reinforced, i.e., because electronics is exported the electrode that its electron affinity energy power is reinforced), D^—Expression has Electropositive electrode (i.e. electrode that the ability of release electronics is reinforced, i.e., because ability that electronics is imported into its release electronics is strong The electrode of change).

Attached drawing of the invention is only a kind of signal, and any technical solution for meeting the application literature record belongs to the application Protection scope.

It is clear that the invention is not restricted to above embodiments, according to techniques known and technology disclosed in this invention Scheme, can derive or associate many variant schemes out, and all these variant schemes also are regarded as being protection model of the invention It encloses.

Claims

1. a kind of electrochemical reaction implementation method, it is characterised in that: contact electrochemistry region alternately with reducing agent and oxidant Or contact reducing agent and oxidant alternately with electrochemistry region, or so that electrochemistry region and reducing agent is contacted with each other and make described Electrochemistry region and the mutual makes discontinuous contact of oxidant, or so that electrochemistry region and oxidant is contacted with each other and make the electrochemical school district Domain and the mutual makes discontinuous contact of reducing agent, make electronics export and/or import between the electrochemistry region and region B, so hold The continuous normality for realizing work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics；

Or, electrochemistry region is made alternately to contact or make reducing agent and oxidant to replace with electrochemistry region with reducing agent and oxidant Contact, or electrochemistry region and reducing agent is made to contact with each other and make the electrochemistry region and the mutual makes discontinuous contact of oxidant, or Electrochemistry region and oxidant is set to contact with each other and make the electrochemistry region and the mutual makes discontinuous contact of reducing agent, to make the reduction Agent is separated into positive particles A and electronics at electrochemistry region, so that electronics is exported to region B from the electrochemistry region, makes electricity Son returns to the electrochemistry region from region B importing, so persistently realizes the normality of work, electronics export and/or Electric energy is externally provided on the channel of importing or from outer absorption electric energy；

Or, reducing agent is made to be separated into positive particles A and electronics at electrochemistry region, export electronics from the electrochemistry region To region B, electronics is set to return to the electrochemistry region from region B importing, oxidant is present in the electrochemistry region, such as This persistently realizes the normality of work, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy；

Or, reducing agent is made to be separated into positive particles A and electronics at electrochemistry region, export electronics from the electrochemistry region To region B, so that electronics is returned to the electrochemistry region from region B importing and react with oxidant, it is so lasting to realize The normality of work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

2. a kind of electrochemical reaction implementation method, it is characterised in that: reducing agent and oxidant are alternately imported to electrochemistry region, or Reducing agent is imported to electrochemistry region and discontinuously imports oxidant to the electrochemistry region, or is imported and aoxidized to electrochemistry region Agent and reducing agent is discontinuously imported to the electrochemistry region, the reducing agent is made to be separated into positive electrochondria at the electrochemistry region Sub- A and electronics make electronics export to region B from the electrochemistry region, and electronics is made to return to the electrification from region B importing The normality of work is so persistently realized in school district domain, electric energy is externally provided on the channel of export and/or the importing of electronics or outside Absorb electric energy.

3. a kind of electrochemical reaction implementation method, it is characterised in that: it is in electrochemistry region alternately in reducing agent and oxidant, Or it is in electrochemistry region in reducing agent and is in the electrochemistry region discontinuously in oxidant, or make at electrochemistry region It in oxidant and is in the electrochemistry region discontinuously in reducing agent, punishes the reducing agent in the electrochemistry region From at positive particles A and electronics, so that electronics is exported to region B from the electrochemistry region, import back electronics from the region B To the electrochemistry region, the normality of work is so persistently realized, on the channel of export and/or the importing of the electronics externally There is provided electric energy or from outer absorption electric energy.

4. a kind of electrochemical reaction implementation method, it is characterised in that: alternately import reducing agent and oxidant to electrochemistry region, make The reducing agent is separated into positive particles A and electronics at the electrochemistry region, exports electronics from the electrochemistry region To region B, electronics is set to return to the electrochemistry region from region B importing, the step that electronics imports and exports and the reduction The step that agent and the oxidant alternately import matches, and so persistently realizes the normality of work, electronics export and/or lead Electric energy is externally provided on the channel entered or from outer absorption electric energy；

Or, importing reducing agent to electrochemistry region and discontinuously importing oxidant to the electrochemistry region, the reducing agent is made to exist It is separated into positive particles A and electronics at the electrochemistry region, so that electronics is exported to region B from the electrochemistry region, makes electricity Son returns to the electrochemistry region from region B importing, what the step that electronics imports and exports discontinuously was imported with the oxidant Step matches, so persistently realize work normality, externally provided on the channel of export and/or the importing of electronics electric energy or From outer absorption electric energy；

Or, importing oxidant to electrochemistry region and discontinuously importing reducing agent to the electrochemistry region, the reducing agent is made to exist It is separated into positive particles A and electronics at the electrochemistry region, so that electronics is exported to region B from the electrochemistry region, makes electricity Son returns to the electrochemistry region from region B importing, what the step that electronics imports and exports discontinuously was imported with the reducing agent Step matches, so persistently realize work normality, externally provided on the channel of export and/or the importing of electronics electric energy or From outer absorption electric energy.

5. a kind of electrochemical reaction implementation method, it is characterised in that: it is in electrochemistry region alternately in reducing agent and oxidant, So that the reducing agent is separated into positive particles A and electronics at the electrochemistry region, leads electronics from the electrochemistry region Region B is arrived out, so that electronics is returned to the electrochemistry region from region B importing, the step that electronics imports and exports and the electricity The step that chemical regions are alternately in the reducing agent and the oxidant matches, and so persistently realizes the normality of work, Electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy；

Or, being in electrochemistry region in reducing agent and being in the electrochemistry region discontinuously in oxidant, make the reduction Agent is separated into positive particles A and electronics at the electrochemistry region, and electronics is made to export to region B from the electrochemistry region, Electronics is set to return to the electrochemistry region from region B importing, the step that electronics imports and exports and the electrochemistry region are disconnected The continuous step in the oxidant matches, so persistently realize the normality of work, in the export and/or importing of electronics Electric energy is externally provided on channel or from outer absorption electric energy；

Or, being in electrochemistry region in oxidant and being in the electrochemistry region discontinuously in reducing agent, make the reduction Agent is separated into positive particles A and electronics at the electrochemistry region, and electronics is made to export to region B from the electrochemistry region, Electronics is set to return to the electrochemistry region from region B importing, the step that electronics imports and exports and the electrochemistry region are disconnected The continuous step in the reducing agent matches, so persistently realize the normality of work, in the export and/or importing of electronics Electric energy is externally provided on channel or from outer absorption electric energy.

6. a kind of electrochemical reaction implementation method, it is characterised in that: make the mixture in electrochemistry region Yu reducing agent and oxidant It contacts with each other or mutual makes discontinuous contact, so that the reducing agent is separated into positive particles A and electronics at the electrochemistry region, make Electronics is exported and/or is imported between the electrochemistry region and region B, the normality of work is so persistently realized, in electronics Electric energy is externally provided in export and/or the channel imported or from outer absorption electric energy；

Or, the mixture of electrochemistry region and reducing agent and oxidant is made to contact with each other or mutual makes discontinuous contact, make the reduction Agent is separated into positive particles A and electronics at the electrochemistry region, and electronics is made to export to region B from the electrochemistry region, So that electronics is returned to the electrochemistry region from region B importing, the normality of work is so persistently realized, in the export of electronics And/or electric energy is externally provided on the channel imported or from outer absorption electric energy；

Or, importing the mixture of reducing agent and oxidant to electrochemistry region, make the reducing agent at the electrochemistry region It is separated into positive particles A and electronics, electronics is made to export to region B from the electrochemistry region, imports electronics from the region B The electrochemistry region is returned to, the normality of work is so persistently realized, is externally mentioned on the channel of export and/or the importing of electronics For electric energy or from outer absorption electric energy；

Or, importing the mixture of reducing agent and oxidant to electrochemistry region, make the reducing agent at the electrochemistry region It is separated into positive particles A and electronics, electronics is made to export to region B from the electrochemistry region, imports electronics from the region B The electrochemistry region is returned to, the step that control electronics imports and exports realizes steady operation, so persistently realizes the normality of work, Electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy.

7. a kind of electrochemical reaction implementation method, it is characterised in that: discontinuously import reducing agent and oxidant to electrochemistry region Mixture makes the reducing agent be separated into positive particles A and electronics at the electrochemistry region, makes electronics from the electrochemistry Region exports to region B, so that electronics is returned to the electrochemistry region from region B importing, so persistently realizes the normal of work State externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics；

Or, discontinuously importing the mixture of reducing agent and oxidant to electrochemistry region, make the reducing agent in the electrochemical school district It is separated into positive particles A and electronics at domain, electronics is made to export to region B from the electrochemistry region, makes electronics from the region B Importing returns to the electrochemistry region, and the step that control electronics imports and exports realizes steady operation, so persistently realizes work Normality externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

8. a kind of electrochemical reaction implementation method, it is characterised in that: electrochemistry region is made to be in the mixing of reducing agent and oxidant In object, the reducing agent is made to be separated into positive particles A and electronics at the electrochemistry region, makes electronics from the electrochemical school district Domain exports to region B, so that electronics is returned to the electrochemistry region from region B importing, so persistently realizes the normality of work, Electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy；

Or, being in electrochemistry region in the mixture of reducing agent and oxidant, make the reducing agent in the electrochemistry region Place is separated into positive particles A and electronics, and electronics is made to export to region B from the electrochemistry region, leads electronics from the region B Enter to return to the electrochemistry region, the step that control electronics imports and exports realizes steady operation, so persistently realizes the normal of work State externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

9. a kind of electrochemical reaction implementation method, it is characterised in that: electrochemistry region is made discontinuously to be in reducing agent and oxidant In mixture, so that the reducing agent is separated into positive particles A and electronics at the electrochemistry region, make electronics from the electrification School district domain exports to region B, so that electronics is returned to the electrochemistry region from region B importing, so persistently realizes work Normality externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics；

Or, being in electrochemistry region discontinuously in the mixture of reducing agent and oxidant, make the reducing agent in the electrochemistry It is separated into positive particles A and electronics at region, so that electronics is exported to region B from the electrochemistry region, makes electronics from the area B importing in domain returns to the electrochemistry region, and the step that control electronics imports and exports realizes steady operation, so persistently realizes work Normality, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy.

10. a kind of electrochemical reaction implementation method, it is characterised in that: reducing agent and oxidant are alternately imported to electrochemistry region, The electronics for being separated into the reducing agent at the electrochemistry region exports to region B from the electrochemistry region, makes electronics The electrochemistry region is returned to from region B importing, the step that electronics imports and exports and the reducing agent and the oxidant The step alternately imported matches, and so persistently realizes the normality of work, on the channel of export and/or the importing of electronics externally There is provided electric energy or from outer absorption electric energy；

Or, importing reducing agent to electrochemistry region and discontinuously importing oxidant to the electrochemistry region, the reducing agent is made to exist The electronics being separated at the electrochemistry region exports to region B from the electrochemistry region, imports electronics from the region B The electrochemistry region is returned to, the step that the step that electronics imports and exports discontinuously is imported with the oxidant matches, so holds The continuous normality for realizing work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics；

Or, importing oxidant to electrochemistry region and discontinuously importing reducing agent to the electrochemistry region, the reducing agent is made to exist The electronics being separated at the electrochemistry region exports to region B from the electrochemistry region, imports electronics from the region B The electrochemistry region is returned to, the step that the step that electronics imports and exports discontinuously is imported with the reducing agent matches, so holds The continuous normality for realizing work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

11. a kind of electrochemical reaction implementation method, it is characterised in that: electrochemistry region is made alternately to be in reducing agent and oxidant In, the electronics for being separated into the reducing agent at the electrochemistry region exports to region B from the electrochemistry region, makes electricity Son returns to the electrochemistry region from region B importing, and the step that electronics imports and exports replaces place with the electrochemistry region Step in the reducing agent and the oxidant matches, so persistently realize work normality, electronics export and/ Or electric energy is externally provided on the channel imported or from outer absorption electric energy；

Or, being in electrochemistry region in reducing agent and being in the electrochemistry region discontinuously in oxidant, make the reduction The electronics that agent is separated at the electrochemistry region exports to region B from the electrochemistry region, makes electronics from the region B Importing returns to the electrochemistry region, and the step that electronics imports and exports and the electrochemistry region are discontinuously in the oxidant Step match, so persistently realize work normality, externally provide electric energy on the channel of export and/or the importing of electronics Or from outer absorption electric energy；

Or, being in electrochemistry region in oxidant and being in the electrochemistry region discontinuously in reducing agent, make the reduction The electronics that agent is separated at the electrochemistry region exports to region B from the electrochemistry region, makes electronics from the region B Importing returns to the electrochemistry region, and the step that electronics imports and exports and the electrochemistry region are discontinuously in the reducing agent Step match, so persistently realize work normality, externally provide electric energy on the channel of export and/or the importing of electronics Or from outer absorption electric energy.

12. a kind of electrochemical reaction implementation method, it is characterised in that: import the mixing of reducing agent and oxidant to electrochemistry region Object, the electronics for being separated into the reducing agent at the electrochemistry region export to region B from the electrochemistry region, make electricity Son returns to the electrochemistry region from region B importing, and the step that control electronics imports and exports is realized steady operation, so held The continuous normality for realizing work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

13. a kind of electrochemical reaction implementation method, it is characterised in that: electrochemistry region is made to be in the mixing of reducing agent and oxidant In object, the electronics for being separated into the reducing agent at the electrochemistry region exports to region B from the electrochemistry region, makes Electronics returns to the electrochemistry region from region B importing, and the step that control electronics imports and exports realizes steady operation, so The normality for persistently realizing work, externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

14. a kind of electrochemical reaction implementation method, it is characterised in that: reducing agent and oxidant are alternately imported to electrochemistry region, Or reducing agent is imported to electrochemistry region and discontinuously imports oxidant to the electrochemistry region, or imports oxygen to electrochemistry region Agent and reducing agent is discontinuously imported to the electrochemistry region, the electricity for being separated into the reducing agent at the electrochemistry region Son exports to region B from the electrochemistry region, so that electronics is returned to the electrochemistry region from region B importing, so holds The continuous normality for realizing work externally provides electric energy or from outer absorption electric energy on the channel of export and/or the importing of electronics.

15. a kind of electrochemical reaction implementation method, it is characterised in that: electrochemistry region is made alternately to be in reducing agent and oxidant In, or be in electrochemistry region in reducing agent and be in the electrochemistry region discontinuously in oxidant, or make electrochemical school district Domain is in oxidant and is in the electrochemistry region discontinuously in reducing agent, makes the reducing agent in the electrochemistry region The electronics that place is separated into exports to region B from the electrochemistry region, and electronics is made to return to the electrochemistry from region B importing The normality of work is so persistently realized in region, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer suction Receive electric energy.

16. a kind of electrochemical reaction implementation method, it is characterised in that: import the mixing of reducing agent and oxidant to electrochemistry region Object, the electronics for being separated into the reducing agent at the electrochemistry region export to region B from the electrochemistry region, make electricity Son returns to the electrochemistry region from region B importing, so persistently realizes the normality of work, electronics export and/or Electric energy is externally provided on the channel of importing or from outer absorption electric energy.

17. a kind of electrochemical reaction implementation method, it is characterised in that: electrochemistry region is made to be in the mixing of reducing agent and oxidant In object, the electronics for being separated into the reducing agent at the electrochemistry region exports to region B from the electrochemistry region, makes Electronics returns to the electrochemistry region from region B importing, so persistently realizes the normality of work, electronics export and/ Or electric energy is externally provided on the channel imported or from outer absorption electric energy.

18. the electrochemical reaction implementation method as described in any one of claim 1 to 5 and 10 and 11 and 14 and 15, feature exist In: inert substance and/or dead band duration are inserted between the reducing agent and the oxidant.

19. the electrochemical reaction implementation method as described in any one of claims 1 to 17, it is characterised in that: electronics export and/ Or during importing, use electro ultrafiltration；Or, using capacitor, DC power supply, friendship during electronics exports and/or imports Galvanic electricity source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, Electric field, oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its Four conjunctions, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunctions, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction.

20. electrochemical reaction implementation method as claimed in claim 18, it is characterised in that: in the mistake that electronics is exported and/or imported Cheng Zhong uses electro ultrafiltration；Or, using capacitor, DC power supply, AC power source, friendship during electronics exports and/or imports Variable power source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillation Circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, Its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 it Conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction.

21. the electrochemical reaction implementation method as described in any one of claim 1 to 17 and 20, it is characterised in that: the electrification There is no electrolyte to be connected between school district domain and the region B, or there are electrolyte connections, or there are dielectric relationships, or exists The local of dielectric capacitance relationship or the electrochemistry region is connected between the part of the region B there are electrolyte or the electricity There are there are ionic liquids between plasma or the electrochemistry region and the region B between chemical regions and the region B There are ionized gas between body or the electrochemistry region and the region B；

Or, the electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, At least one of ionized gas, solion and electronic conduction area have non-electronic conducting electrical relation with the region B.

22. electrochemical reaction implementation method as claimed in claim 18, it is characterised in that: the electrochemistry region and the region There is no electrolyte to be connected between B, or there are electrolyte connections, or there are dielectric relationships, or there are dielectric capacitance relationship or institutes The local of electrochemistry region is stated to be connected between the part of the region B there are electrolyte or the electrochemistry region and the area There are there are ionic liquid or the electrochemistry between plasma or the electrochemistry region and the region B between the B of domain There are ionized gas between region and the region B；

23. electrochemical reaction implementation method as claimed in claim 19, it is characterised in that: the electrochemistry region and the region There is no electrolyte to be connected between B, or there are electrolyte connections, or there are dielectric relationships, or there are dielectric capacitance relationship or institutes The local of electrochemistry region is stated to be connected between the part of the region B there are electrolyte or the electrochemistry region and the area There are there are ionic liquid or the electrochemistry between plasma or the electrochemistry region and the region B between the B of domain There are ionized gas between region and the region B；

24. the electrochemical reaction implementation method as described in any one of claim 1 to 17 and 20 and 22 and 23, it is characterised in that: Electro ultrafiltration is applied to the region for participating in electrochemical reaction, so that the substance for participating in electrochemical reaction is difficult to directly carry out redox Reaction.

25. electrochemical reaction implementation method as claimed in claim 18, it is characterised in that: applied to the region for participating in electrochemical reaction Power-up effect, so that the substance for participating in electrochemical reaction is difficult to directly carry out redox reaction.

26. electrochemical reaction implementation method as claimed in claim 19, it is characterised in that: applied to the region for participating in electrochemical reaction Power-up effect, so that the substance for participating in electrochemical reaction is difficult to directly carry out redox reaction.

27. electrochemical reaction implementation method as claimed in claim 21, it is characterised in that: applied to the region for participating in electrochemical reaction Power-up effect, so that the substance for participating in electrochemical reaction is difficult to directly carry out redox reaction.

28. the electrochemical reaction implementation method as described in any one of claim 1 to 17 and 20 and 22 and 23 and 25 to 27, special Sign is: it is work normality that export of the electronics between the electrochemistry region and the region B, which imports,.

29. electrochemical reaction implementation method as claimed in claim 18, it is characterised in that: electronics is in the electrochemistry region and institute Stating the export between the B of region and importing is work normality.

30. electrochemical reaction implementation method as claimed in claim 19, it is characterised in that: electronics is in the electrochemistry region and institute Stating the export between the B of region and importing is work normality.

31. electrochemical reaction implementation method as claimed in claim 21, it is characterised in that: electronics is in the electrochemistry region and institute Stating the export between the B of region and importing is work normality.

32. electrochemical reaction implementation method as claimed in claim 24, it is characterised in that: electronics is in the electrochemistry region and institute Stating the export between the B of region and importing is work normality.