CN109860960A

CN109860960A - A kind of electrochemical reaction implementation method

Info

Publication number: CN109860960A
Application number: CN201910107790.6A
Authority: CN
Inventors: 靳北彪
Original assignee: Entropy Zero Technology Logic Engineering Group Co Ltd
Current assignee: Entropy Zero Technology Logic Engineering Group Co Ltd
Priority date: 2018-08-26
Filing date: 2019-02-02
Publication date: 2019-06-07
Also published as: CN109786802A; CN109802201A; CN109860680A; CN109786793A; CN109786801A

Abstract

The invention discloses a kind of electrochemical reaction implementation methods, electrochemistry region is set alternately to contact or make substance A and substance B alternately to contact with electrochemistry region with substance A and substance B, the substance A is set to be separated into positive charged particle and electronics at the electrochemistry region, the electronics in the electrochemistry region is exported to import, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy, so persistently realizes the normality of work.Electrochemical reaction implementation method disclosed in this invention is by termination Conventional electrochemical method and electrochemical appliance (such as fuel cell etc.) with the history for existing for necessary condition of electrolyte (such as proton exchange membrane, solid oxide electrolyte etc.), also the Conventional electrochemical method and device that will terminate can not be securely and reliably using the history using Material A Material B mixture, exploitation for efficient, long-life, Low-cost electric chemical devices provides new approach, and will redefine engine.

Description

A kind of electrochemical reaction implementation method

Technical field

The present invention relates to electricity field, electrochemical field more particularly to a kind of electrochemical reaction implementation methods.

Background technique

Conventional electrochemical method is required to non-electronic charged particle (such as ion or proton) and transmits between two electrodes, that is, needs Positive charged particle and negative charged particles that electrochemistry region (electrode) generates are removed, non-electronic charged particle is in two interpolars Transmission not only consume electric energy, but also be required to conduct non-electronic charged particle non-conducting electronics and there are many particular/special requirements Electrolyte (such as proton exchange membrane, solid oxide electrolyte of hydrogen fuel cell etc.), because of its complexity, this electrolyte Manufacturing technology it is unqualified always, and have become restrict electrochemical method be efficiently widely applied and its electrochemical appliance (such as Fuel cell) basic reason that reduces of improved efficiency, life-span upgrading and cost, also have become hinder electrochemical appliance (such as Fuel cell) efficiently industrialization problem the most serious.If can invent a kind of not to remove non-electrical from electrochemistry region Subband charged particle is that the model electrochemical of necessary condition reacts implementation method, by termination Conventional electrochemical method and electrochemical appliance (such as fuel cell etc.) is with the necessary condition that exists for of electrolyte (such as proton exchange membrane, solid oxide electrolyte etc.) History, the Conventional electrochemical method and device that will also terminate can not securely and reliably use the history using Material A Material B mixture, Exploitation for efficient, long-life, Low-cost electric chemical devices provides new approach, and will redefine engine.Therefore, it is necessary to Invent a kind of model electrochemical reaction implementation method.

Summary of the invention

To solve the above-mentioned problems, technical solution proposed by the present invention is as follows:

Scheme 1: a kind of electrochemical reaction implementation method makes electrochemistry region alternately contact or make object with substance A and substance B Matter A and substance B are alternately contacted with electrochemistry region, or so that electrochemistry region and substance A is contacted with each other and made the electrochemical school district Domain and the mutual makes discontinuous contact of substance B, or electrochemistry region and substance B is made to contact with each other and make the electrochemistry region and substance A Mutual makes discontinuous contact makes the substance A be separated into positive charged particle and electronics at the electrochemistry region, makes the electrochemistry The electronics in region, which exports, to be imported, and electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy, such as This persistently realizes the normality of work；

Or, replace introduction of substances A and substance B to electrochemistry region, or to electrochemistry region introduction of substances A and discontinuously import Substance B, or to electrochemistry region introduction of substances B and interrupted introduction of substances A, punish the substance A in the electrochemistry region From at electronics exported from the electrochemistry region, make electronics importing return to the electrochemistry region, electronics export and/or Electric energy is externally provided on the channel of importing or from outer absorption electric energy, so persistently realizes the normality of work；

Or, electrochemistry region is made alternately to contact or make substance A and substance B to replace with electrochemistry region with substance A and substance B Contact, the electronics for being separated into the substance A at the electrochemistry region are exported from the electrochemistry region, import electronics The electrochemistry region is returned to, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy, electricity The step that son imports and exports matches with the electrochemistry region with the step that the substance A and the substance B alternately contact, such as This persistently realizes the normality of work；

Or, so that electrochemistry region and substance A is contacted with each other and make the electrochemistry region and the mutual makes discontinuous contact of substance B, The electronics for being separated into the substance A at the electrochemistry region is exported from the electrochemistry region, returns to electronics importing The electrochemistry region, externally provides electric energy on the channel of export and/or the importing of electronics or from outer absorption electric energy, electronics is led Enter derived step and the step in the electrochemistry region and the substance B makes discontinuous contact matches, so persistently realizes work Normality；

Or, so that electrochemistry region and substance B is contacted with each other and make the electrochemistry region and the mutual makes discontinuous contact of substance A, The electronics for being separated into the substance A at the electrochemistry region is exported from the electrochemistry region, returns to electronics importing The electrochemistry region, externally provides electric energy on the channel of export and/or the importing of electronics or from outer absorption electric energy, electronics is led Enter derived step and the step in the electrochemistry region and the substance A makes discontinuous contact matches, so persistently realizes work Normality.

Scheme 2: a kind of electrochemical reaction implementation method replaces introduction of substances A and substance B to electrochemistry region, or to electricity Chemical regions introduction of substances A and interrupted introduction of substances B, or to electrochemistry region introduction of substances B and interrupted introduction of substances A, make institute It states substance A and is separated into electronics at the electrochemistry region, export electronics from the electrochemistry region, return to electronics importing The electrochemistry region externally provides electric energy on the channel of export and/or the importing of electronics or from outer absorption electric energy, so holds The continuous normality for realizing work；

Or, replacing introduction of substances A and substance B to electrochemistry region, separate the substance A at the electrochemistry region It at electronics, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in the export of electronics And/or externally provide electric energy or from outer absorption electric energy on the channel imported, step and the substance A that electronics imports and exports and The step that the substance B alternately imports matches, and so persistently realizes the normality of work；

Or, making the substance A at the electrochemistry region to electrochemistry region introduction of substances A and interrupted introduction of substances B It is separated into electronics, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in leading for electronics It externally provides electric energy out and/or on the channel of importing or from outer absorption electric energy, the step and the substance B that electronics imports and exports is disconnected The continuous step imported matches, and so persistently realizes the normality of work；

Or, making the substance A at the electrochemistry region to electrochemistry region introduction of substances B and interrupted introduction of substances A It is separated into electronics, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in leading for electronics It externally provides electric energy out and/or on the channel of importing or from outer absorption electric energy, the step and the substance A that electronics imports and exports is disconnected The continuous step imported matches, and so persistently realizes the normality of work.

Scheme 3: a kind of electrochemical reaction implementation method is in electrochemistry region alternately in substance A and substance B, or makes Electrochemistry region is in substance A and is discontinuously in substance B, or is in electrochemistry region in substance B and is discontinuously in object In matter A, the electronics for being separated into the substance A at the electrochemistry region is exported from the electrochemistry region, leads electronics Enter to return to the electrochemistry region, electric energy externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy, So persistently realize the normality of work；

Or, being in electrochemistry region alternately in substance A and substance B, punish the substance A in the electrochemistry region From at electronics exported from the electrochemistry region, make electronics importing return to the electrochemistry region, electronics export and/or Electric energy is externally provided on the channel of importing or from outer absorption electric energy, the step that electronics imports and exports replaces with the electrochemistry region Step in the substance A and the substance B matches, and so persistently realizes the normality of work；

Or, electrochemistry region is made to be in substance A and discontinuously be in substance B, make the substance A in the electrochemical school district The electronics being separated at domain is exported from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in leading for electronics Externally provide electric energy or from outer absorption electric energy out and/or on the channel that imports, the step and the electrochemistry that electronics imports and exports The step that region is discontinuously in the substance B matches, and so persistently realizes the normality of work；

Or, electrochemistry region is made to be in substance B and discontinuously be in substance A, make the substance A in the electrochemical school district The electronics being separated at domain is exported from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in leading for electronics Externally provide electric energy or from outer absorption electric energy out and/or on the channel that imports, the step and the electrochemistry that electronics imports and exports The step that region is discontinuously in the substance A matches, and so persistently realizes the normality of work.

Scheme 4: a kind of electrochemical reaction implementation method is in electrochemistry region alternately in substance A and substance B, or makes Electrochemistry region is in substance A and is discontinuously in substance B, or is in electrochemistry region in substance B and is discontinuously in object In matter A, the substance A is made to be separated into electronics at the electrochemistry region, exports electronics from the electrochemistry region, make electricity Son imports and returns to the electrochemistry region, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption Electric energy so persistently realizes the normality of work；

Or, being in electrochemistry region alternately in substance A and substance B, punish the substance A in the electrochemistry region It from electronics, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in the export of electronics And/or electric energy is externally provided or from outer absorption electric energy on the channel imported, the step and the electrochemical school district that electronics imports and exports The step that domain is alternately in the substance A and the substance B matches, and so persistently realizes the normality of work；

Or, electrochemistry region is made to be in substance A and discontinuously be in substance B, make the substance A in the electrochemical school district It is separated into electronics at domain, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in electronics Export and/or importing channel on externally provide electric energy or from outer absorption electric energy, the step and the electricity that electronics imports and exports The step that chemical regions are discontinuously in the substance B matches, and so persistently realizes the normality of work；

Or, electrochemistry region is made to be in substance B and discontinuously be in substance A, make the substance A in the electrochemical school district It is separated into electronics at domain, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in electronics Export and/or importing channel on externally provide electric energy or from outer absorption electric energy, the step and the electricity that electronics imports and exports The step that chemical regions are discontinuously in the substance A matches, and so persistently realizes the normality of work.

Scheme 5: a kind of electrochemical reaction implementation method makes the mixture phase mutual connection in electrochemistry region with substance A and substance B Touching or mutual makes discontinuous contact, make the substance A be separated into positive charged particle and electronics at the electrochemistry region, make the electricity The electronics of chemical regions, which exports, to be imported, and electric energy or electric from outer absorption is externally provided on the channel of export and/or the importing of electronics Can, so persistently realize the normality of work；

Or, the mixture of electrochemistry region and substance A and substance B is made to contact with each other or mutual makes discontinuous contact, make the object Matter A is separated into positive particles and electronics at the electrochemistry region, exports the electronics in the electrochemistry region and imports, Electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy, controls the step that electronics imports and exports It realizes steady operation, so persistently realizes the normality of work；

Or, to the mixture of electrochemistry region introduction of substances A and substance B or to the interrupted introduction of substances A in electrochemistry region and The mixture of substance B, the electronics for being separated into the substance A at the electrochemistry region are exported from the electrochemistry region, So that electronics importing is returned to the electrochemistry region, electric energy is externally provided on the channel of export and/or the importing of electronics or outside Electric energy is absorbed, so persistently realizes the normality of work；

Or, making the substance A at the electrochemistry region to the mixture of electrochemistry region introduction of substances A and substance B The electronics being separated into is exported from the electrochemistry region, make electronics importing return to the electrochemistry region, electronics export and/ Or electric energy is externally provided on the channel imported or from outer absorption electric energy, controls the step that electronics imports and exports and realizes steady operation, So persistently realize the normality of work.

Scheme 6: a kind of electrochemical reaction implementation method, to electrochemistry region introduction of substances A and substance B mixture or to The mixture of electrochemistry region interrupted introduction of substances A and substance B, make the substance A be separated into electricity at the electrochemistry region Son exports electronics from the electrochemistry region, make electronics importing return to the electrochemistry region, electronics export and/or Electric energy is externally provided on the channel of importing or from outer absorption electric energy, so persistently realizes the normality of work；

Or, making the substance A at the electrochemistry region to the mixture of electrochemistry region introduction of substances A and substance B It is separated into electronics, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in leading for electronics Electric energy is externally provided out and/or on the channel of importing or from outer absorption electric energy, controls the step that electronics imports and exports and realizes and stablize The normality of work is so persistently realized in work.

Scheme 7: a kind of electrochemical reaction implementation method is in electrochemistry region in the mixture of substance A and substance B, The electronics for being separated into the substance A at the electrochemistry region is exported from the electrochemistry region, returns to electronics importing The electrochemistry region externally provides electric energy on the channel of export and/or the importing of electronics or from outer absorption electric energy, so holds The continuous normality for realizing work；

Or, being in electrochemistry region in the mixture of substance A and substance B, make the substance A in the electrochemistry region The electronics that place is separated into is exported from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in the export of electronics And/or electric energy is externally provided on the channel imported or from outer absorption electric energy, controls the step that electronics imports and exports and realizes and stablize work Make, so persistently realizes the normality of work.

Scheme 8: a kind of electrochemical reaction implementation method is in electrochemistry region in the mixture of substance A and substance B, So that the substance A is separated into electronics at the electrochemistry region, exports electronics from the electrochemistry region, import electronics The electrochemistry region is returned to, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy, such as This persistently realizes the normality of work；

Or, being in electrochemistry region in the mixture of substance A and substance B, make the substance A in the electrochemistry region Place is separated into electronics, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in electronics Electric energy is externally provided in export and/or the channel imported or from outer absorption electric energy, controls the step that electronics imports and exports and realizes surely Fixed work, so persistently realizes the normality of work.

Scheme 9: a kind of electrochemical reaction implementation method makes electrochemistry region discontinuously be in the mixture of substance A and substance B In, the electronics for being separated into the substance A at the electrochemistry region is exported from the electrochemistry region, imports back electronics To the electrochemistry region, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy, so Persistently realize the normality of work；

Or, being in electrochemistry region discontinuously in the mixture of substance A and substance B, make the substance A in the electrochemistry The electronics being separated at region is exported from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in electronics Electric energy is externally provided in export and/or the channel imported or from outer absorption electric energy, controls the step that electronics imports and exports and realizes surely Fixed work, so persistently realizes the normality of work.

Scheme 10: a kind of electrochemical reaction implementation method makes electrochemistry region discontinuously be in the mixing of substance A and substance B In object, the substance A is made to be separated into electronics at the electrochemistry region, exports electronics from the electrochemistry region, make electricity Son imports and returns to the electrochemistry region, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption Electric energy so persistently realizes the normality of work；

Or, being in electrochemistry region discontinuously in the mixture of substance A and substance B, make the substance A in the electrochemistry It is separated into electronics at region, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in electricity Electric energy is externally provided on the channel of export and/or the importing of son or from outer absorption electric energy, it is real to control the step that electronics imports and exports Existing steady operation, so persistently realizes the normality of work.

Scheme 11: it in scheme 1 to 4 on the basis of either a program, further selectively selects in the substance A and institute It states and is inserted into inert substance and/or dead band duration between substance B.

The aforementioned all schemes of the present invention optionally use electro ultrafiltration during electronics exports and/or imports.

The aforementioned all schemes of the present invention further can selectively select to make during electronics exports and/or imports With capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, change To switching circuit, rectifier, electric field, oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two Conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine Conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 Conjunction.

The aforementioned all schemes of the present invention further can selectively select to apply electricity to the region for participating in electrochemical reaction Effect, so that the substance for participating in electrochemical reaction is difficult to directly carry out redox reaction.

The aforementioned all schemes of the present invention further can selectively select the export for making electronics to import as work normality.

In the present invention, aforementioned all schemes further can selectively select to make the electrochemistry region through insulation, Completely cut off in space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area At least one with electric conductor have non-electronic conducting electrical relation.

In the present invention, aforementioned all schemes further can selectively select to make the electrochemistry region and insulation, Completely cut off in space, electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area At least one have non-electronic conducting electrical relation.

The aforementioned all schemes of the present invention further can selectively select to make electronics in the electrochemistry region and conduction It is work normality that export between body, which imports,.

In the present invention, so-called electrochemistry region, electric conductor are equal with electrode.

In the present invention, the region of electronics export importing, electric conductor are equal with electrode.

In the present invention, " importing returns to " is equal with " importing " in " export imports ".

In the present invention, disclosed method is the electrochemical reaction implementation method at single electrode, in specific implementation, optional It selects to selecting property using the electrochemistry region as an electrode, using electric conductor as another electrode, two electrode cooperatings, The conversion of chemical energy electric energy is completed, is selectively chosen using an electrochemistry region as an electrode, by another institute Electrochemistry region is stated as another electrode, two electrode cooperatings complete the conversion of chemical energy electric energy.

In the present invention, disclosed method, which is selectively chosen, serves as half electrochemical appliance of manufacture (i.e. electrochemistry dress Include the device region of an electrode in setting), it is also selectively chosen and serves as manufacture electrochemical appliance.

In the present invention, during electronics exports and/or imports, it is selectively chosen using AC power source, it is described The frequency and phase of AC power source match with the switching frequency and phase of the substance A and the substance B；Or it is exported in electronics And/or during importing, using alternating source, the frequency and phase and the substance A and the substance of the alternating source The switching frequency and phase of B matches.

In the present invention, during electronics exports and/or imports, it is selectively chosen using oscillating circuit, it is described The frequency and phase of oscillating circuit match with the switching frequency and phase of the substance A and the substance B.

In the present invention, makes DC power supply, AC power source, alternating source or capacitor and the electrochemistry regional connectivity or make institute It states for the purpose of electrochemistry region is in electric field starting purpose can be achieved or can maintain normal work.

In the present invention, so-called " step " includes frequency and phase.

In the present invention, so-called switching (alternating) refers to including described the electrochemistry region introduction of substances A and substance B The mutual switching of switching and/or the electrochemistry region between two kinds of material streams of substance A and the substance B.

In the present invention, so-called " inductor conductor " refers to all externally output magnetic force energy and leading from outer absorption magnetic force energy Body.Such as transformer coil, electrical-coil, conductor bars for dynamoelectric machines etc..

In the present invention, so-called " phase converter " is the direction vector and its voltage for instigating electric current (or charged particle stream) Angled device, the circuit for example including capacitor, the circuit including inductance and including capacitor also include inductance circuit Deng.

In the present invention, the principle of electrochemical reaction implementation method disclosed in this invention is carried out as described below:

Through detailed analysis, it can be found that there is the basic logic of universality using the process of redox reaction power generation, specifically Be analyzed as follows: the process to be generated electricity using redox reaction, is exported from reducing agent by electronics, forms reducing agent cation, then By electronics derived from institute imported into reducing agent cation and oxidant coexistence make three react generate the reducing agent and The product of the oxidizing reduction reaction externally exports electric energy on the path that electronics export and electronics import.In tradition In hydrogen-oxygen fuel cell, such as PEMFC, under the effect of the catalyst, hydrogen molecule is separated into proton and electronics, and proton is made to pass through matter Proton exchange enters the oxygen side with catalyst, and electronics is loaded from hydrogen side and imported into proton and what oxygen coexisted has catalyst Oxygen side, proton (H⁺), oxygen (O₂) and electronics (e^-) reaction generation water.This means that the process to be generated electricity using redox reaction With following basic logic: electronics is made into reducing agent positively ionized from reducing agent export, then by electronics imported into reducing agent just from The coexistence of son and oxidant makes reducing agent cation, oxidant and electronics three react the generation reducing agent and the oxidation The product of agent redox reaction, this overall process is external output electric energy, and the output of electric energy is leading by electronics Realization is imported out.This basic logic is it is meant that we can not be by the constraint of conventional fuel cell concrete form, as long as full The requirement of this basic logic of foot, so that it may externally export electric energy using the redox reaction of Oxidizing and Reducing Agents.And this Exactly from electrochemistry region, export electronics makes reducing agent form reducing agent cation to the basic process of the disclosed method of invention, then Make electronics imported into the electrochemistry region to coexist with oxidant and the reducing agent cation, thus make electronics and oxidant and Reducing agent cation three, which reacts, generates the product of the oxidant and the reducing agent redox reaction, and then realizes Under the premise of there is no by necessity derived from the reducing agent cation, also it is being not present other non-electronic charged particles Under the premise of derived necessity, electric energy is externally exported.

Disclosed in this invention include that substance A, the principle of the method for substance B alternating action are as follows: make electrochemistry region It alternately contacts or makes substance A and substance B alternately to contact with electrochemistry region with substance A and substance B, make substance A in the electrification School district domain generates positive charged particle and electronics, exports electronics from the electrochemistry region, makes electronics to the electrochemistry region It imports, positive charged particle, the substance B described in the electrochemistry region and electron reaction generate the substance A and the object The product that matter B reacts is imported using the export of electronics and realizes output electric energy and/or absorb electric energy, so recycled, realize Continue working process (to the electrochemistry region import electronics when, in some cases, electronics the electrochemistry region with Substance B reaction generates negative charged particles C, and the negative charged particles C and the positive charged particle reaction generate the substance A and institute The product that substance B reacts is stated, is imported using the export of electronics and realizes output electric energy and/or absorb electric energy, so recycled, Realization continues working process).In realizing this electrochemical process, being selectively chosen makes the electrochemistry region, dispatch from foreign news agency Road, capacitor and reception and circuit is constituted for the region of electron, and/or makes the electrochemistry region, external circuit, non-electronic electrification Particle oscillation area constitutes circuit with reception and for the region of electron.It in this approach, can be real to the electrochemistry region Electro ultrafiltration is applied, electro ultrafiltration can control export and/or importing with strengthening electronic, thus it is possible to prevente effectively from substance A and object Redox reaction directly occurs for matter B mixing, improves safety, reliability and efficiency.It in this approach, can also be described First implement electro ultrafiltration before electrochemistry region and material effect to it, purpose is also that substance A and substance B is avoided to mix directly hair Raw redox reaction, improves safety, reliability and efficiency.

Disclosed in this invention include substance A and substance B mixture effect method principle it is as follows: make electrochemistry Region contacts with the mixture of substance A and substance B or makes the mixture of substance A and substance B to contact with electrochemistry region, utilizes electricity Effect exports electronics from the electrochemistry region, and then the substance A is made to form positive charged particle, Xiang Suoshu electrochemistry region Electronics is imported, the positive charged particle generates the substance A with the substance B and electron reaction and reacting for the substance B is given birth to At object, next step, Xiang Suoshu electrochemistry region imports electronics, exports electronics from the electrochemistry region, imports in electronics Under the action of export, the substance A reacts the reaction product for generating the substance A and the substance B with the substance B, Electric energy and/or output electric energy are absorbed in electronics export and/or the channel imported, are so recycled, realization continues working process (at certain In a little situations, when importing electronics to the electrochemistry region, the substance B and electron reaction generate negative charged particles C, in institute It states positive charged particle described in electrochemistry region and negative charged particles C reaction generates the anti-of the substance A and the substance B Product is answered, electric energy and/or output electric energy are absorbed on the channel that electronics exports and/or imports, is so recycled, is realized and continue work Make process).In realizing this electrochemical process, being selectively chosen makes the electrochemistry region, external circuit, capacitor and connects It receives and constitutes circuit for the region of electron, and/or make the electrochemistry region, external circuit, non-electronic charged particle oscillation area Circuit is constituted with reception and for the region of electron.In this approach, to be effectively prevented from the substance A and the substance B Redox reaction directly occurs for mixing, first can implement electro ultrafiltration to it before the electrochemistry region and material effect.

Disclosed in this invention include substance A and substance B the principle of method that discontinuously acts on of mixture it is as follows: except disconnected Outside the influence of continuous effect, the complete phase of principle of the principle of this method and the method for the mixture effect for including substance A and substance B Together, interrupted function is that can be better protected from or eliminate substance A described in mixture and the substance B joins in electrode With the ability for directly carrying out redox reaction in the case where (i.e. the electrochemistry region participate in) and losing output electric energy, in turn The efficiency for improving the method disclosed in the present may be implemented a certain electrode and only exist under the influence of mixture discontinuously acts on Substance A (except non-electronic charged particle) functions, and another electrode only exists substance B (except non-electronic charged particle) The state functioned, or the high concentration object (except non-electronic charged particle) for realizing that a certain electrode only exists substance A are made with it With, and another electrode only exists the state that the high concentration object (except non-electronic charged particle) of substance B functions, either this Any state therein is all conducive to the efficiency for promoting electrochemical reaction.Certainly as described above, being selectively chosen use The export that external means (such as foreign current, external electrical field etc.) control electronics imports step, promotes the efficiency of electrochemical reaction. Similarly, in realizing this electrochemical process, being selectively chosen makes the electrochemistry region, external circuit, capacitor and reception With for electron region constitute circuit, and/or make the electrochemistry region, external circuit, non-electronic charged particle oscillation area and It receives and constitutes circuit for the region of electron.

In the present invention, the partial circuit working principle of the electrical return of disclosed method is to utilize non-electronic band electrochondria Sub reciprocating vibration in the electrolyte, which is realized alternation conducting and/or stood facing each other using non-electronic charged particle with electronics, realizes that alternation is led It is logical, and then interior circuit and external circuit is made to form closed circuit, realize electrochemical process.

In the present invention, it is work normality that the export of the electronics in electrochemistry region, which imports,.

In the present invention, so-called " it is work normality that the export of the electronics in electrochemistry region, which imports, " refers to from the electrochemistry It is to continue working process that region, which exports electronics and imports electronics to the electrochemistry region, that is, applies electrification disclosed in this invention The electrochemical appliance of method exports electronics from the electrochemistry region and imports to the electrochemistry region in working condition Electronics is a kind of lasting process.In other words, the electrochemistry region with alternating current corresponding and described electrochemistry region It is opposite with alternating current to should be the process of continuing working.

In the present invention, when the substance A and the substance B are certain two kinds of predetermined substance, electrochemical reaction mistake is being realized Cheng Zhong, having the reaction of the third substance participation cyclicity, (so-called cyclicity reaction, which refers to, generates certain object at an electrode Matter, and the reaction that this substance is consumed at another electrode), such as the substance A is methanol, when the substance B is oxygen, In acid condition, it having water as the third substance and participates in cyclicity reaction, i.e. water generates at the electrode for absorbing electronics, and It is consumed at the electrode of output electronics, and under alkaline condition, it is anti-as the third substance participation cyclicity to have hydroxyl It answers, hydroxyl generates at the electrode for absorbing electronics, is consumed at the electrode of output electronics.For example, methanol fuel cell Electrochemical reaction process concrete condition is as follows:

Overall reaction under alkaline condition: 2CH₃OH+3O₂+4OH^-=2CO₃ ^2-+6H₂O

Anode reaction: O₂+4e^-+2H₂O=4OH^-

Negative reaction: CH₃OH-6e^-+8OH^-=CO₃ ^2-+6H₂O

Overall reaction in acid condition: 2CH₃OH+3O₂=2CO₂+4H₂O

Anode reaction: O₂+4e^-+4H⁺=2H₂O

Negative reaction: CH₃OH-6e^-+H₂O=6H⁺+CO₂

For another example the electrochemical reaction process concrete condition of methane fuel cell is as follows:

Overall reaction under alkaline condition: CH₄+2O₂+2OH^-=CO₃ ^2-+3H₂O

Anode reaction: 2O₂+8e^-+4H₂O=8OH^-

Negative reaction: CH₄-8e^-+10OH^-=CO₃ ^2-+7H₂O

Overall reaction in acid condition: CH₄+2O₂=CO₂+2H₂O

Anode reaction: 2O₂+8e^-+8H⁺=4H₂O

Negative reaction: CH₄-8e^-+2H₂O=8H⁺+CO₂

In the present invention, according to the method disclosed in the present, substance and the effect in electrode (such as electrochemistry region) are preferential In electricity and the effect of electrode, this form may be implemented the due electrochemical process of the present invention completely, but substance A and substance B (such as reducing agent and oxidant) will appear exist simultaneously at same electrode in many cases (especially with substance A and When the mixture of substance B), if this state is precisely that startup stage or electrode did not had in the period of electro ultrafiltration, at this moment object Conversion process between redox reaction forfeiture and electric energy can directly occur for matter A and substance B, in order to avoid the production of this state It is raw it is necessary to implement electro ultrafiltration to electrode in advance, and so-called " electro ultrafiltration is applied to the region for participating in electrochemical reaction, so that ginseng With the substance of electrochemical reaction be difficult to directly carry out redox reaction " purpose be that this.

In the present invention, under certain temperature and/or pressure, so-called electrochemistry region, which is selectively chosen, to be set as not wrapping The conductive region of catalyst is included, because it is anti-can still to carry out electrochemistry without using catalyst under certain temperature and/or pressure It answers.

It in the present invention, is selectively chosen and electro ultrafiltration is applied to the region for participating in electrochemical reaction, to realize to described Prior to the interaction between substance and the region substance A is reduced or avoided and substance B is direct in the electro ultrafiltration in region Carry out the case where redox reaction loses output electric energy.

In the present invention, so that charged particle is stored in the means in electrochemistry region as realizing, be selectively chosen and pass through The alternating of the contact of two kinds of metabolies and electric current that make electrochemistry region and participation electrochemical reaction changes to realize, also optional Select to selecting property to make that two kinds of substances for participating in electrochemical reaction alternately contacts with electrochemistry region and the alternating of electric current changes It realizes, however the conducting of the non-electronic charged particle between two electrodes of electrochemical reaction (such as electrochemistry region and electric conductor) May or may not then exist.

In the present invention, charged particle is set to be stored in the means in electrochemistry region as realizing, being selectively chosen makes electricity The mixture contact of two kinds of substances of chemical regions and participation electrochemical reaction and the alternating of electric current change to realize, may be selected Property select to make electrochemistry region and participate in the mixture makes discontinuous contact of two kinds of substances of electrochemical reaction and the alternating of electric current Variation is to realize, however the non-electronic band electrochondria between two electrodes of electrochemical reaction (for example, electrochemistry region and electric conductor) The conducting of son may or may not then exist.

In the present invention, it is that the Q generated at P is instigated to be stored in institute that the so-called Q for making the generation at P, which is stored at the P, The electrode zone represented at P is stated, including the Q to be unnecessarily transmitted to the electrode zone polarity with representative at the P The process of opposite electrode zone.

In the present invention, in realizing the electrochemical reaction implementation method, need for certain charged particle to be stored in a certain It is waited in region and participates in reaction in the next step, it is to instigate to produce at P that the so-called Q for making the generation at P, which is stored at the P, Raw Q is stored in the electrode zone represented at the P, including being unnecessarily transmitted to the Q and representative at the P The process of the opposite polarity electrode zone of electrode zone.

In the present invention, the substance A used in the electrochemical reaction implementation method and substance B are with the substance A and institute In the presence of the form for stating the mixture of substance B, further can selectively it select with the substance A and the substance B The form of molar mixture exist, or in the form of the mixture of the explosion limit substance A below and the substance B In the presence of, or to exist in the form of the mixture of the local explosion limit substance A below and the substance B, or with pole of exploding The form of the mixture of above substance A of limit and the substance B exists, or with the substance more than local explosion limit The form of the mixture of A and the substance B exists.

In the present invention, the mixture of so-called substance A and substance B further can selectively select to be set as substance A and object Molar mixture, the explosion limit substance A below of matter B and mixture, the local explosion limit substance A below of substance B With the substance A more than mixture of more than mixture of substance B, explosion limit substance A and substance B or local explosion limit With the mixture of substance B.

In the present invention, so-called molar mixture refers to that the molar concentration rate of mixture is positive and negative in chemical reaction molar ratio Mixture within 10%.

In the present invention, the export of the electronics in the electrochemistry region imports the electronics referred to do not include during being electrically separated Appearance and accumulation.

In the present invention, the export of the electronics in the electrochemistry region is imported to continue working process.

In the present invention, electrochemistry region state corresponding with alternating electromotive force and alternating current is to continue working Journey.

The electrochemical reaction implementation method disclosed in this invention is corresponding with alternating electromotive force and alternating current, i.e., electric Chemical regions are corresponding with alternating electromotive force and alternating current.

In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen through non-electronic Relationship is connected in the direct electricity that charged particle is formed, and relationship, warp is connected in the electricity formed through non-electronic charged particle reciprocating vibration One of electricity conducting relationship that capacitance relation is formed, secondly conjunction or thirdly conjunction.

In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen including through exhausted The electrical relation that alternating current can be made to be connected of edge body, dielectric and the conducting body isolation of non-electronic charged particle.

In the present invention, there are in the method for electrolyte between electrochemistry region and electric conductor, non-electronic charged particle both may be used Electrolyte is passed through, reaches another electrode from an electrode, can also realize alternating current conducting by reciprocating vibration in the electrolyte Effect.

In the present invention, electrochemistry region corresponding with alternating electromotive force and alternating current is essence feature of the invention, In the present invention, two kinds of substances due to participating in electrochemical reaction exist with electrochemistry region to be contacted, and electrochemistry region and friendship Power transformation kinetic potential and alternating current are corresponding, i.e., the electromotive force in electrochemistry region in the present invention is alternating electromotive force, absorb and/or The electric current for exporting electric energy is alternating current, and this is through the lasting sex work normality of whole work process, this duration Work normality eliminates the necessity of non-electronic charged particle transmission between two electrodes, thus no matter make between two electrodes in electronics every Exhausted state, non-electronic charged particle state of isolation have the state for the electrolyte that non-electronic charged particle is connected between two electrodes, also It is that can be worked normally in other states as long as can be realized the Oscillating flow of electronics.There are electrolyte between two electrodes In method, non-electronic charged particle can both pass through electrolyte, reach another electrode from an electrode, can also be past in the electrolyte Complex oscillation realizes the effect of alternating current conducting.This provides fine for the manufacture and use of electrochemical appliance especially fuel cell New method.

In the present invention, the alternation of electric current and substance replace and the effect of the alternation and mixture of substances of electric current is formed by Alternation process is a kind of lasting course of work, is a kind of work normality, and its purpose is to eliminate non-electronic band Charged particle two interelectrode transmitting necessity, to promote the science that chemical energy exchanges the electrochemical method of electric energy for, in turn Promote service life, reliability, low cost and the efficiency of electrochemical appliance corresponding with the method disclosed in the present.This electricity The purpose of principle and purpose of chemical method and conventional fuel cell are catalyst regeneration is temporary to exchange Oxidizing and Reducing Agents Feed channel, which forms the principle of temporary electrode change in polarity and purpose, has essential distinction, also and to prevent, weaken and remove The principle and purpose of the frequently pole-reversing electroosmosis of electrode attachment have essential distinction.

In the present invention, from a certain region export electronic processes duration with to this region import electronic processes duration it Than between 1/6 and 6, between 1/5 and 5, between 1/4 and 4, between 1/3 and 3, between 1/2.5 and 2.5,1/2 And between 2, between 1/1.5 and 1.5, between 1/1.3 and 1.3, between 1/1.2 and 1.2 or 1/1.1 and 1.1 it Between, or it is equal with the duration of electronic processes is imported to this region from the duration of a certain region export electronic processes.

In the present invention, during exporting electric energy and/or absorbing electric energy, selectively selection uses electro ultrafiltration；Or, During exporting electric energy and/or absorbing electric energy, selectively selection uses capacitor, DC power supply, AC power source, alternation electricity Source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit, Motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five Conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, its ten The conjunction of binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction.

In the present invention, the purpose of so-called " during exporting electric energy and/or absorbing electric energy, using electro ultrafiltration " is benefit The process of output electric energy is controlled or strengthened with electro ultrafiltration and/or absorbs the process of electric energy, in this way can with the efficiency of lifting process and Safety, such as an electrochemical process may take a long time to complete, but if can be made using electro ultrafiltration The reaction rate of the slower procedure segment of electrochemical reaction rates is promoted, and then is improved efficiency.

In the present invention, so-called electro ultrafiltration, which refers to, brings it about displacement and/or stream to electronics application using electric field, electric current etc. Dynamic effect.

In the present invention, it is more big more be conducive to electrochemical reaction that capacitance is formed by between the electrochemistry region and electric conductor The promotion of density, therefore when being electrochemically reacted using the method disclosed in the present, should make the electrochemistry region and Capacitance between the electric conductor increases as much as possible.

It, can be in the electrochemistry in order to increase the capacitance between the electrochemistry region and the electric conductor in the present invention Plasma, ionic liquid, ionized gas or solion are set between region and the electric conductor, and make ion in the electricity It is vibrated between chemical regions and the electric conductor, and/or in electrochemistry areas adjacent oscillation and near the electric conductor Oscillation, to realize the purpose for increasing the capacitance between the electrochemistry region and the electric conductor.

In the present invention, to realize that specific charged particle is stored in electrochemistry region, need to join the electrochemistry region Alternate change physical environment or make the electrochemistry region between the different material of electrochemical reaction and participate in electrochemical reaction The mixture of different material contacts, and is just able to achieve.Fundamentally, as long as the electrochemistry region is made to participate in electrochemical reaction Different material between alternate change physical environment or make the electrochemistry region and participate in the mixed of the different material of electrochemical reaction Object contact is closed, can be achieved with the purpose that the specific charged particle is stored in electrochemistry region, no matter the electrochemistry region has There are two types of the conductive channel of charged particle, (such as one of is proton conductive channel, i.e. there is conducting certain band between two electrodes The electrolyte of charged particle, another kind be electronic conduction channel) or the electrochemistry region there was only electronic conduction channel, change sentence It talks about, as long as making the electrochemistry region alternate change physical environment or described between the different material for participating in electrochemical reaction Electrochemistry region is contacted with the mixture for the different material for participating in electrochemical reaction, can be achieved with the specific charged particle storage It participates in electrochemistry region and in the next step reacting the purpose for realizing electrochemical reaction, no matter two electrodes are (for example, electrochemistry Region and electric conductor) between whether there is electrolyte.Electrochemistry region export import charged particle method the course of work and this It is similar.

In the present invention, in electrochemistry region, tool there are two types of the conductive channel of charged particle, (such as lead for proton by one of which , i.e. there is the electrolyte that specific charged particle is connected between two electrodes in circulation passage, another kind is electronic conduction channel) electrochemistry side In method, alternate change physical environment or made described between the different material for participating in electrochemical reaction by making the electrochemistry region Electrochemistry region is contacted with the mixture for the different material for participating in electrochemical reaction, can be achieved to eliminate from the electrochemistry region The necessity for removing the non-electronic charged particle generated in the electrochemistry region, can also realize that non-electronic charged particle is stored in The electrochemistry region and the purpose for participating in reaction realization electrochemical reaction in the next step.The alternate change of physical environment or The electrochemistry region and the mixture for the different material for participating in electrochemical reaction are contacted, can make to be stored in the electrochemical school district Non-electronic charged particle in domain participates in reacting in the next step, realizes electrochemical process, therefore from the electrochemical school district The necessity that non-electronic charged particle is exported in domain completely disappears.The case where necessity derived from non-electronic charged particle disappears Under, although some non-electronic charged particle that ought to be stored in the electrochemistry region is exported, also have non-electronic Charged particle is stored in the electrochemistry region and waits next reaction step, in other words, if the electrochemistry region The alternate change physical environment between the different material for participating in electrochemical reaction, or it is mixed with the different material of participation electrochemical reaction Object contact is closed, although there are electrolyte between two electrodes (for example, electrochemistry region and electric conductor), also has non-electronic band electrochondria Son is stored in the electrochemistry region and participation reaction in the next step is waited to realize electrochemical reaction process.

Electrochemical reaction implementation method disclosed in this invention, there are can reduce in the case where electrolyte between two electrodes Electrolyte load extends its service life and is conducive to the balance and stability operation of system.

In the present invention, (for example, the electrochemistry region and institute in the method that electrochemistry region only has electronic conduction channel The interior circuit or external circuit stated between electric conductor are in electronics and non-electronic charged particle state of isolation), the electrochemistry region exists Alternate change physical environment and the electrochemistry region and participation electrochemical reaction between the different material of participation electrochemical reaction The mixture of different material contacts, and non-electronic charged particle can be made to be stored in the electrochemistry region, the change of physical environment Or the electrochemistry region and the mixture for the different material for participating in electrochemical reaction is made to contact and can make to be stored in the electrochemistry The non-electronic charged particle in region participates in reaction in the next step and realizes electrochemical process, that is, eliminates from electrochemistry region Remove the necessity of non-electronic charged particle.Express herein, in Conventional electrochemical method, electrochemistry region (i.e. electrode) at least It is connected including two kinds of charged particles, such as an electronic conduction channel, a proton conductive channel.

Electrochemical reaction implementation method disclosed in this invention include exchanged for electric energy chemical energy electrochemical method (such as Electrochemical method for synthesizing etc.) and exchange with chemical energy the electrochemical method (such as fuel cell etc.) of electric energy for, it is closed as electrochemistry At method in use, the different step that the export of electronics imports, which may exist, exports the case where electric energy is with electric energy is absorbed, but its Summation is to absorb electric energy；As the method (such as fuel cell etc.) for exchanging electric energy for chemical energy in use, the export of electronics The case where different step of importing may exist output electric energy and absorb electric energy, but its summation is output electric energy.

Electrochemical reaction implementation method disclosed in this invention self-evidently includes the participation of substance.

Electrochemical reaction implementation method disclosed in this invention is as the method for exchanging electric energy for chemical energy in use, participating in The substance of electrochemical reaction, i.e., the described substance A and the substance B, one of which are oxidant, and another kind is reducing agent, such as The substance A is set as reducing agent, and the substance B is set as oxidant, and the oxidant alternative selection is set as: oxygen, compression are empty Gas, oxygen, liquid oxygen, air, liquefied air, fluorine, chlorine, bromine, iodine, ozone, nitric acid, the concentrated sulfuric acid, hypochlorous acid, chromic acid, Peracetic acid, Perchloric acid, chlorate, nitrate, permanganate, perchlorate, bichromate, Calcium perchlorate, ammonium perchlorate, sodium perchlorate, height Potassium chlorate, lithium perchlorate, magnesium perchlorate, barium perchlorate, perchloric acid strontium, silver perchlorate, ammonium chlorate, sodium chlorate, potassium chlorate, chloric acid Magnesium, calcium chlorate, copper chlorate, zinc chlorate, chloric acid thallium, silver chlorate, potassium permanganate, acerdol, barium permanganate, lithium nitrate, nitric acid Sodium, potassium nitrate, calcium nitrate, cesium nitrate, beryllium nitrate, potassium bromate, zinc bromate, ammonium periodate, calcium iodate, iron iodate, sodium dichromate, Potassium bichromate, iron chloride, ammonium ceric nitrate, sodium hypochlorite, SODIUM PERCARBONATE, sodium perborate, calcium hypochlorite, sodium dichloro cyanurate, Copper oxide, di-iron trioxide, sodium peroxide, manganese dioxide, nitrogen dioxide, potassium peroxide, magnesium dioxide, calcium dioxide, peroxide Change hydrogen, chromium trioxide, strontium dioxide, sodium dioxide, silver oxide, acetone, acrylonitrile, benzaldehyde, dibenzoyl peroxide, benzene Quinone, carbon tetrabromide one or more of are set as chloramines etc.；Reducing agent alternative selection is set as: hydrogen, alkane, Alkene, alkynes, aromatic hydrocarbon, halogenated hydrocarbons, alcohol compound, phenolic compound, aldehyde compound, ketone compounds, hydroxy acid class Close object, ester type compound, sodium, aluminium, zinc, lithium, potassium, magnesium, manganese, carbon, calcium, barium, vanadium, chromium, iron, cobalt, copper, boron, silicon, phosphorus, tin, mercury, Lead, carbon dust, coal dust end, sulphur, lithium aluminium hydride reduction, diethyl aluminium hydride sodium, sodium borohydride, potassium borohydride, carbon monoxide, vulcanization Hydrogen, hydrazine, ammonia, hydrogen chloride, hydrogen iodide, sulfur dioxide, hydrogen peroxide, vulcanized sodium, stannous chloride, formaldehyde, sulfurous acid, sulfuric acid, Oxalic acid, ethyl alcohol, sodium sulfite, sodium hydrogensulfite, ferrous sulfate, methanol, natural gas, coal gas, methane, coke, diesel oil, diformazan Ether, kerosene, gasoline, hydrogen carbon monoxide mixtures one or more of are set as heavy oil etc..

In the present invention, electrochemical action may be present between the substance A and the substance B.

In the present invention, the condition of the substance A and the substance B in electrochemical reaction implementation method disclosed in this invention Under, electrochemical reaction can occur.

In the present invention, the substance A is simple substance, compound or mixture, and ion or solion are not belonging to the substance A。

In the present invention, the substance B is simple substance, compound or mixture, and ion or solion are not belonging to the substance B。

The essence of electrochemical reaction implementation method disclosed in this invention is selectively chosen to be turned as chemical energy electric energy Change method.

It is so-called " during electronics exports and/or imports, to use capacitor, DC power supply, alternating current in the present invention Source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, Oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four it Conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 Conjunction, its ten binomial conjunction, its 13 conjunction, its 14 conjunction, its 15 conjunction " purpose be by electro ultrafiltration control The export of system and/or strengthening electronic imports.

It is so-called " during electronics exports and/or imports, to use capacitor, DC power supply, alternating current in the present invention Source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, Oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four it Conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 Conjunction, its ten binomial conjunction, its 13 conjunction, its 14 conjunction, its 15 conjunction " purpose be by electro ultrafiltration control The export of system and/or strengthening electronic imports, and control and/or the export of strengthening electronic importing can effectively avoid substance A and substance B Redox reaction directly occurs for mixing, improves safety, reliability and efficiency, and control and/or the export of strengthening electronic Import safety, reliability and the efficiency that can be effectively promoted using substance A and substance B existing method as a mixture.

Using disclosed in this invention electrochemical reaction implementation method as obtain electric energy method when, " led in electronics Out and/or during importing, capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductance coil, band are used Charged particle pump, reversing switch circuit, rectifier, electric field, oscillating circuit, motor, reversible electric machine, has and adds phase converter The motor of rotary inertia or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its seven Conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, The purpose of its 14 conjunction, its 15 conjunction " is imported by electro ultrafiltration control and/or the export of strengthening electronic.This A certain step in control process is power consumption, but whole process is power supply.

Using disclosed in this invention electrochemical reaction implementation method as the method for obtaining electric energy and using substance A and When the mixture of substance B, " during electronics exports and/or imports, capacitor, DC power supply, AC power source, alternation are used Power supply, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillation electricity Road, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its Five conjunctions, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, The purpose of the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction " is not only through electro ultrafiltration control The export of system and/or strengthening electronic imports, and be prevented by the export of strengthening electronic importing substance A and substance B directly into The effective means of row redox reaction.A certain step in this control process is power consumption, but whole process is power supply.

Using disclosed in this invention electrochemical reaction implementation method as obtain electric energy method when, " led in electronics Out and/or during importing, capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductance coil, band are used Charged particle pump, reversing switch circuit, rectifier, electric field, oscillating circuit, motor, reversible electric machine, has and adds phase converter The motor of rotary inertia or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its seven Conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, The purpose of its 14 conjunction, its 15 conjunction " is not only to control by electro ultrafiltration and/or the export of strengthening electronic imports, It and is that the effective means for preventing substance A and substance B from directly carrying out redox reaction is imported by the export of strengthening electronic.This A certain step in one control process is power consumption, but whole process is power supply.

It in the present invention, further can selectively select that catalyst corresponding with the substance A is made to be set as catalyst A, with It is different that the corresponding catalyst of the substance B is set as catalyst B, the catalyst A and the catalyst B, in this case, institute It states the catalyst in electrochemistry region and is selectively chosen the random mixing for being set as the catalyst A and the catalyst B Select to catalyst choice in object or the electrochemistry region catalyst A for being set as contacting near catalytic domain and The mixture of the catalyst B can increase the charged particle between the catalyst A and the catalyst B to improve efficiency Mobility.

In the present invention, the purpose for being inserted into the inert substance is to evade the substance A and the substance B in the electricity Exist while at chemical regions, or reduces the substance A and the substance B simultaneous machine at the electrochemistry region Meeting.

In the present invention, so-called electrochemistry region and electric conductor have dielectric capacitance relationship.

In the present invention, so-called " dielectric capacitance relationship " refers to the capacitance relation by dielectric formation, such as the electrification Through the capacitance relation of dielectric formation between school district domain and electric conductor, dielectric can be gas, liquid, solid or vacuum.

In the present invention, disclosed electrochemical reaction implementation method can be used for converting electric energy for chemical energy, it can also be used to Chemical energy is converted electrical energy into, the method that can be used to fuel cell and electrochemistry formated.

In the present invention, electrochemistry region alternative selects one of the electrode for being set as electrochemical reaction or electrode Point.

In the present invention, disclosed method can not only make the substance A and the substance B externally discharge electric energy formation energy The reaction product of the magnitude not low substance A and the substance B, also can use the substance A and the substance B absorbs The reaction product of electric energy synthesis energy the rank higher substance A and the substance B.

In the present invention, it can be selected according to the operating temperature of the property and the electrochemistry region of the substance A and the substance B Select different catalyst.

In the present invention, Xiang Suoshu electrochemistry region import concentration proportion in the local explosion limit substance A below and The mixture of the substance B may include fire retardant, such as nitrogen, carbon dioxide etc. are added in the mixture of hydrogen and oxygen.

In the present invention, in the method that the electrochemistry region is under set temperature, the set temperature can be set as high In equal to 100 DEG C.

In the present invention, in the method that the electrochemistry region is under set temperature, the set temperature can be set as low In equal to 90 DEG C.

In the present invention, the substance A and the substance B refer to that electrochemical reaction occurs in the electrochemistry region Substance.

In the present invention, it can react after the substance A and substance B absorption electric energy and generate compound, or external It can react after feed electric energy and generate compound.

In the present invention, in the method for including AC power source, the reaction of the substance A and the substance B can be absorption The reaction of electric energy is also possible to export the reaction of electric energy.

In the present invention, in the method for including alternating source, the reaction of the substance A and the substance B can be absorption The reaction of electric energy is also possible to export the reaction of electric energy.

In the present invention, eliminating from the necessity that electrochemistry region removes non-electronic charged particle means only to need to remove electricity Son, rather than electronics charged particle (such as proton) can store in the electrochemistry region that it is generated and the participation electricity during next Chemical reaction, it means that It is not necessary to the interior circuit or outer that centainly there is non-electronic charged particle channel to constitute between two electrodes Circuit, it is only necessary to which electrochemical process can be realized in electronic conduction circuit, in this approach, is selectively chosen electricity in it The conducting on road is that the reciprocating vibration of charged particle in capacitor and/or its internal part by being formed between its internal part is realized , and using external circuit output electric energy and/or absorb electric energy.

In the present invention, eliminating from the necessity that electrochemistry region removes two kinds of charged particles means only to need to remove electricity Son, and another charged particle (such as proton) can store in the electrochemistry region that it is generated and the participation electricity during next Chemical reaction, it means that It is not necessary to the interior circuit or outer that centainly there is non-electronic charged particle channel to constitute between two electrodes Circuit, it is only necessary to which electrochemical process can be realized in electronic conduction circuit, and in this approach, the conducting of interior circuit is to pass through The reciprocating vibration of charged particle is realized in the capacitor and/or its internal part formed between its internal part, and utilizes dispatch from foreign news agency Road exports electric energy and/or absorbs electric energy.

In the present invention, the export importing of electronics is a kind of work normality, and the export importing of so-called electronics refers to through external circuit The export of the electronics carried out imports.

In the present invention, the electrochemistry region is optionally set as electrode.

In the present invention, the electric conductor, which is selectively chosen, is set as electrode corresponding with the electrochemistry region.

In the present invention, such as there is non-electronic conducting electrical relation using Y and X as synonym, Y and X, the electronics of the Y is led The form of presentation imported out refers to that the Y, the X and electronics export import the composition that circuit three is same closed circuit Part is selectively chosen electronics export importing circuit being set as external circuit, and non-electronic conducting electrical relation is formed Circuit be set as interior circuit.

In the present invention, such as using U, W and V as synonym, U has non-electronic conducting electrical relation through W and V, and electronics is in institute The form of presentation for exporting importing between U and the V is stated, refers to that the U, the W, the V and electronics export import circuit It is the component part of same closed circuit, is selectively chosen and electronics export importing circuit is set as external circuit, and will be non- Electronic conduction electrical relation is formed by circuit and is set as interior circuit.

In the present invention, so-called " alternating electromotive force " refers to that the changed electromotive force of electromotive force, such as direction become The changed electromotive force of electromotive force or size of change.

In the present invention, so-called " alternating current " refers to the changed electric current of electric current, such as the changed electricity in direction Stream, the changed electric current of size or alternating current.

In the present invention, so-called " alternating current " is selectively chosen the electric current for being set as the variation of electric current generating period, Such as electric current or alternating current that electric current, the size generating period of direction generating period variation change.

In the present invention, so-called alternating current refers to the alternating current changed by sinusoidal rule.

In the present invention, so-called AC power source refers to the alternating source that electric current is changed by sinusoidal rule.

In the present invention, there is so-called A and B non-electronic conducting electrical relation to refer to having on interior circuit between A and B Non-electronic conducting electrical relation, and its external circuit is selectively chosen electronic conduction relationship；Or, so-called A and B has non-electrical Son conducting electrical relation, which refers to, has non-electronic conducting electrical relation on external circuit between A and B, and its interior circuit may be selected Select electronic conduction relationship to property.

In the present invention, it is so-called " the electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, etc. At least one of gas ions, ionic liquid, ionized gas and solion have non-electronic conducting electrical relation with electric conductor " Two solions being isolated with the electric conductor through insulator, dielectric and/or ion conducting body including the electrochemistry region The non-electronic conducting electrical relation that pond has.In this approach, being selectively chosen makes the electrochemistry region and described At least one in electric conductor forms electrical relation with capacitive region and/or non-electronic charged particle transmitter.

In the present invention, so-called " non-electronic charged particle transmitter " refer to non-conducting electronics but proton conducting or it is specific from The substance of son, i.e. electrolyte in conventional electrochemical device, can be according to the electrochemical properties of the reducing agent and the oxidant Non-electronic charged particle transmitter is selected, such as when the reducing agent is H₂, the oxidant is O₂When, the non-electronic electrification Particle conduction object alternative selects proton exchange membrane.

In the present invention, so-called " non-electronic conducting electrical relation " refers to the electricity formed through the charged particle other than electronics Conducting relationship or the electricity to be formed conducting relationship of standing facing each other through electronics, for example, relationship, non-electronic electrification is connected in the electricity that capacitor is formed The electricity conducting relationship etc. that particle reciprocating vibration is formed.

In the present invention, so-called " capacitor " be selectively chosen be set as electrolytic capacitor, super capacitor, electric double layer capacitance, All capacitors such as pseudo capacitance, fake capacitance.

In the present invention, so-called " reversible electric machine " refers to the motor that can mutually convert between motor and generator, For example, the motor that can be generated electricity when exportable rotary power, rotation when power supply.

In the present invention, it is selectively chosen and uses circumferential magnetic monopole direct current using DC reversible electromotor or selectivity selection Reversible electric machine.

In the present invention, when the purpose using reversible electric machine is the power supply using reversible electric machine when exportable power reception power The characteristics of can generating electricity, realizes the reinforcing and control imported to electronics export with electrode cooperating, and then realizes to electrochemistry mistake The optimization of journey.

It in the present invention, is selectively chosen, so that reversible electric machine movement power generation is implemented electro ultrafiltration to electrode, when the electricity of electrode When kinetic potential reaches setting degree, electrode, which powers to reversible electric machine, pushes reversible electric machine movement, sets when the electromotive force of electrode is reduced to When determining degree, reversible electric machine implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, so again and again Carry out cyclic process；In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy； It is selectively chosen, control device is set between reversible electric machine and electrode；Be selectively chosen, load with reversible electric machine, Electrode is arranged in series, or load is arranged in parallel with reversible electric machine.

It in the present invention, is selectively chosen, so that reversible electric machine movement power generation is implemented electro ultrafiltration to electrode, when electrode is in electricity When electromotive force reaches setting degree under the action of chemical reaction and/or reversible electric machine, electrode is in electrochemical reaction and/or accumulation electricity It powers under the action of lotus to reversible electric machine and pushes reversible electric machine movement, it is reversible when the electromotive force of electrode is reduced to setting degree Motor implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, so carries out cyclic process again and again； In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy；Optionally select It selects, control device is set between reversible electric machine and electrode；It being selectively chosen, load is arranged in series with reversible electric machine, electrode, Or load is arranged in parallel with reversible electric machine.

It in the present invention, is selectively chosen, makes electrode move reversible electric machine reversible electric machine power supply, when the electricity of electrode When kinetic potential is reduced to setting degree, reversible electric machine implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, when When the electromotive force of electrode reaches setting degree, electrode, which powers to reversible electric machine, pushes reversible electric machine movement, so again and again Carry out cyclic process；In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy； It is selectively chosen, control device is set between reversible electric machine and electrode；Be selectively chosen, load with reversible electric machine, Electrode is arranged in series, or load is arranged in parallel with reversible electric machine.

It in the present invention, is selectively chosen, makes electrode under the action of electrochemical reaction and/or stored charge to reversible Motor power supply moves reversible electric machine, and when the electromotive force of electrode is reduced to setting degree, reversible electric machine utilizes itself and its connection The kinetic energy power generation of moving part to electrode implement electro ultrafiltration, when electrode under the action of electrochemical reaction and/or reversible electric machine electromotive force When reaching setting degree, electrode pushes reversible electricity to reversible electric machine power supply under the action of electrochemical reaction and/or stored charge Machine movement, so carries out cyclic process again and again；In circulation, there is the process for providing electric energy and absorbing electric energy in electrode, but Circulation is whole to be to provide electric energy；It is selectively chosen, control device is set between reversible electric machine and electrode；Optionally Selection, load are arranged in series with reversible electric machine, electrode, or load is arranged in parallel with reversible electric machine.

In the present invention, so-called " electrolyte " refer to all be arranged between two electrode of electrochemical appliance only allow it is specific The substance that charged particle passes through but electronics is not allowed to pass through can be solid, liquid or membranous body etc., such as the proton of PEMFC Film, solid oxide electrolyte etc..

In the present invention, so-called " being inserted into inert substance between the substance A and the substance B " refers in the substance A is contacted with electrochemistry region and the substance B contacted with this electrochemistry region between connect inert substance with this electrochemistry region Touching, the purpose is to keep the boundary between the electrochemical reaction of the substance A and the electrochemical reaction of the substance B apparent.

In the present invention, so-called " dead band duration is inserted between the substance A and the substance B " refers in the substance A is contacted with electrochemistry region and the substance B contacted with this electrochemistry region between be arranged dead band duration, the purpose is to avoid The substance A and substance B mixing, make between the electrochemical process of the substance A and the electrochemical process of the substance B Boundary is apparent, and so-called dead band duration refers to the time interval of setting, and specific duration is according to the substance A and the substance B Property, the temperature in electrochemistry region and catalyst whether there is or not and residence time etc. for needing of the substance A and the substance B come It determines.

In the present invention, so-called " inert substance " refers to the substance not reacted with the substance A and the substance B.

In the present invention, so-called " electrochemistry region " refers to that the region of electrochemical reaction can occurs in all, for example including Catalyst, ultra microstructure and/or region (such as electrode in fuel cell etc.) at a set temperature, then for example in setting temperature Metallic region under degree.

It is so-called to refer to " including catalyst, ultra microstructure and/or electrochemistry region at a set temperature " in the present invention The electrochemistry region or including catalyst or including ultra microstructure or under the set temperature or the electrification School district domain includes two or three in these three conditions.

In the present invention, so-called " ultra microstructure " refers to the microcosmic knot that can cause electrochemical reaction under setting condition Structure.

In the present invention, so-called " local explosion limit " refers under conditions of the electrochemistry region, the substance A and The concentration ratio that the substance B cannot explode.

In the present invention, include the catalyst method in, the catalyst be set as include noble metal catalyst, or The catalyst be set as include rare earth element catalyst.

In the present invention, so-called interpolar spacer refers to make to have required for non-electronic conducting electrical relation between electrode Substance (including vacuum), for example, electrolyte, dielectric etc..

In the present invention, the selection of interpolar spacer alternative is set as insulation, isolation space, electrolyte, dielectric, electricity At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area.

In the present invention, so-called interpolar spacer, which is selectively chosen, is set as interior circuit, is also selectively chosen and sets For external circuit.

In the present invention, so-called " electronic conduction area " refers to that conduct electrons are not turned on the region of non-electronic charged particle, can Selectively selection is set as metallic conductor area, carbon conductor region etc..

In the present invention, select electronic conduction area shape when, should for the purpose of increasing its capacitance with neighbors into Row selection.

In the present invention, so-called electro ultrafiltration is a kind of selectivity selection.

In the present invention, so-called " non-electronic charged particle " refers to the charged particle other than electronics, such as proton or ion.

In the present invention, so-called " motor with additional rotation inertia " refers to the requirement with basis to rotary inertia, The motor of additional setting rotary inertia.

It more than some numerical value include this number, such as two or more includes two kinds in the present invention.

In the present invention, after a certain component names plus the letter such as so-called " A ", " B " is merely to distinguish two or several The identical component of title or substance.

In the present invention, necessary portion should be set in necessary place according to electricity field, the well-known technique of electrochemical field Part, unit or system etc..

Beneficial effects of the present invention are as follows: electrochemical reaction implementation method disclosed in this invention will terminate Conventional electrochemical Method and electrochemical appliance (such as fuel cell etc.) are with electrolyte (such as proton exchange membrane, solid oxide electrolyte etc.) The history of necessary condition is existed for, termination Conventional electrochemical method and device can not securely and reliably also be used into substance A object The history of matter B mixture provides new approach for efficient, long-life, Low-cost electric chemical devices exploitation, and will determine again Adopted engine.

Detailed description of the invention

Fig. 1-1 is the schematic diagram of the embodiment of the present invention 24；

Fig. 1-2 is the schematic diagram of the embodiment of the present invention 25；

Fig. 1-3 is the schematic diagram of the embodiment of the present invention 26；

Fig. 1-4 is the schematic diagram of the embodiment of the present invention 27；

Fig. 1-5 is the schematic diagram of the embodiment of the present invention 28；

Fig. 1-6 is the schematic diagram of the embodiment of the present invention 29；

Fig. 1-7 is the schematic diagram of the embodiment of the present invention 30；

Fig. 2-1 is the schematic diagram of the embodiment of the present invention 31；

Fig. 2-2 is the schematic diagram of the embodiment of the present invention 32；

Fig. 2-3 is the schematic diagram of the embodiment of the present invention 33；

Fig. 2-4 is the schematic diagram of the embodiment of the present invention 34；

Fig. 2-5 is the schematic diagram of the embodiment of the present invention 35；

Fig. 2-6 is the schematic diagram of the embodiment of the present invention 36；

Fig. 2-7 is the schematic diagram of the embodiment of the present invention 37；

Fig. 3-1 is the basic logic chart for exchanging electric energy for chemical energy；

Fig. 3-2 is reducing agent oxidant electrochemical reaction controlled process figure.

Specific embodiment

Technical solution of the present invention is further illustrated in the following with reference to the drawings and specific embodiments.

Embodiment 1

The invention discloses a kind of electrochemical reaction implementation methods, and electrochemistry region and substance A and substance B can specifically handed over For contacting or making substance A and substance B alternately to contact with electrochemistry region, separate the substance A at the electrochemistry region At positive charged particle and electronics, exports the electronics in the electrochemistry region and import, in the channel of export and/or the importing of electronics It is upper that electric energy is externally provided or from outer absorption electric energy, so persistently realizes the normality of work.

As disposable embodiment, the embodiment of the present invention 1, which is also selectively chosen, makes electrochemistry region and substance A Contact with each other and make the electrochemistry region and the mutual makes discontinuous contact of substance B, or make electrochemistry region and substance B contact with each other and Make the electrochemistry region and the mutual makes discontinuous contact of substance A.

Embodiment 2

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to electrochemistry region and alternately imports Substance A and substance B, the electronics for being separated into the substance A at the electrochemistry region are exported from the electrochemistry region, So that electronics importing is returned to the electrochemistry region, electric energy is externally provided on the channel of export and/or the importing of electronics or outside Electric energy is absorbed, so persistently realizes the normality of work.

As disposable embodiment, the embodiment of the present invention 2 is also selectively chosen to electrochemistry region and imports object Matter A and interrupted introduction of substances B, or to electrochemistry region introduction of substances B and interrupted introduction of substances A.

Embodiment 3

Electrochemical reaction implementation method disclosed in this invention be also selectively chosen make electrochemistry region and substance A and Substance B alternately contacts or makes substance A and substance B alternately to contact with electrochemistry region, makes the substance A in the electrochemical school district The electronics being separated at domain is exported from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in leading for electronics Externally provide electric energy or from outer absorption electric energy out and/or on the channel that imports, the step and the electrochemistry that electronics imports and exports Region matches with the step that the substance A and the substance B alternately contact, and so persistently realizes the normality of work.

As disposable embodiment, the embodiment of the present invention 3, which is also selectively chosen, makes electrochemistry region and substance A It contacts with each other and makes the electrochemistry region and the mutual makes discontinuous contact of substance B, and the step and the electrification that electronics imports and exports The step of school district domain and the substance B makes discontinuous contact matches.

As disposable embodiment, the embodiment of the present invention 3, which is also selectively chosen, makes electrochemistry region and substance B It contacts with each other and makes the electrochemistry region and the mutual makes discontinuous contact of substance A, and the step and the electrification that electronics imports and exports The step of school district domain and the substance A makes discontinuous contact matches.

Embodiment 4

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to electrochemistry region and alternately imports Substance A and substance B make the substance A be separated into electronics at the electrochemistry region, make electronics from the electrochemistry region Export, make electronics importing return to the electrochemistry region, externally provided on the channel of export and/or the importing of electronics electric energy or From outer absorption electric energy, the normality of work is so persistently realized.

As disposable embodiment, the embodiment of the present invention 4 is also selectively chosen to electrochemistry region and imports object Matter A and interrupted introduction of substances B, or to electrochemistry region introduction of substances B and interrupted introduction of substances A.

Embodiment 5

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to electrochemistry region and alternately imports Substance A and substance B make the substance A be separated into electronics at the electrochemistry region, make electronics from the electrochemistry region Export, make electronics importing return to the electrochemistry region, externally provided on the channel of export and/or the importing of electronics electric energy or From outer absorption electric energy, the step that electronics imports and exports replaces the step imported with the substance A and the substance B and matches, such as This persistently realizes the normality of work.

As disposable embodiment, the embodiment of the present invention 5 is also selectively chosen to electrochemistry region and imports object Matter A and interrupted introduction of substances B, and the step that the step that imports and exports of electronics is discontinuously imported with the substance B matches.

As disposable embodiment, the embodiment of the present invention 5 is also selectively chosen to electrochemistry region and imports object Matter B and interrupted introduction of substances A, and the step that the step that imports and exports of electronics is discontinuously imported with the substance A matches.

Embodiment 6

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, is in electrochemistry region alternately In substance A and substance B, the electronics for being separated into the substance A at the electrochemistry region is led from the electrochemistry region Out, make electronics importing return to the electrochemistry region, externally provided on the channel of export and/or the importing of electronics electric energy or from Outer absorption electric energy so persistently realizes the normality of work.

As disposable embodiment, the embodiment of the present invention 6, which is also selectively chosen, makes electrochemistry region be in object It is in matter A and interrupted in substance B, or electrochemistry region is made to be in substance B and discontinuously be in substance A.

Embodiment 7

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, is in electrochemistry region alternately In substance A and substance B, the electronics for being separated into the substance A at the electrochemistry region is led from the electrochemistry region Out, make electronics importing return to the electrochemistry region, externally provided on the channel of export and/or the importing of electronics electric energy or from Outer absorption electric energy, the step that electronics imports and exports replaces with the electrochemistry region to be in the substance A and the substance B Step matches, and so persistently realizes the normality of work.

As disposable embodiment, the embodiment of the present invention 7, which is also selectively chosen, makes electrochemistry region be in object It is in matter A and interrupted in substance B, and the step that electronics imports and exports discontinuously is in the substance B with the electrochemistry region In step match.

As disposable embodiment, the embodiment of the present invention 7, which is also selectively chosen, makes electrochemistry region be in object It is in matter B and interrupted in substance A, and the step that electronics imports and exports discontinuously is in the substance A with the electrochemistry region In step match.

Embodiment 8

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, is in electrochemistry region alternately In substance A and substance B, the substance A is made to be separated into electronics at the electrochemistry region, makes electronics from the electrochemical school district Domain export makes electronics importing return to the electrochemistry region, externally provides electric energy on the channel of export and/or the importing of electronics Or from outer absorption electric energy, the normality of work is so persistently realized.

As disposable embodiment, the embodiment of the present invention 8, which is also selectively chosen, makes electrochemistry region be in object It is in matter A and interrupted in substance B, or electrochemistry region is made to be in substance B and discontinuously be in substance A.

Embodiment 9

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, is in electrochemistry region alternately In substance A and substance B, the substance A is made to be separated into electronics at the electrochemistry region, makes electronics from the electrochemical school district Domain export makes electronics importing return to the electrochemistry region, externally provides electric energy on the channel of export and/or the importing of electronics Or from outer absorption electric energy, the step that electronics imports and exports replaces with the electrochemistry region is in the substance A and the substance B In step match, so persistently realize work normality.

As disposable embodiment, the embodiment of the present invention 9, which is also selectively chosen, makes electrochemistry region be in object It is in matter A and interrupted in substance B, and the step that electronics imports and exports discontinuously is in the substance B with the electrochemistry region In step match.

As disposable embodiment, the embodiment of the present invention 9, which is also selectively chosen, makes electrochemistry region be in object It is in matter B and interrupted in substance A, and the step that electronics imports and exports discontinuously is in the substance A with the electrochemistry region In step match.

Embodiment 10

Electrochemical reaction implementation method disclosed in this invention be also selectively chosen make electrochemistry region and substance A and The mixture of substance B contacts with each other or mutual makes discontinuous contact, and the substance A is made to be separated into positive band at the electrochemistry region Charged particle and electronics export the electronics in the electrochemistry region and import, on the channel of export and/or the importing of electronics externally Electric energy is provided or from outer absorption electric energy, so persistently realizes the normality of work.

Embodiment 11

Electrochemical reaction implementation method disclosed in this invention be also selectively chosen make electrochemistry region and substance A and The mixture of substance B contacts with each other or mutual makes discontinuous contact, and the substance A is made to be separated into positive electricity at the electrochemistry region Particle and electronics export the electronics in the electrochemistry region and import, externally mention on the channel of export and/or the importing of electronics For electric energy or from outer absorption electric energy, controls the step that electronics imports and exports and realize steady operation, so persistently realize the normal of work State.

Embodiment 12

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to electrochemistry region introduction of substances A With the mixture of substance B or to the mixture of electrochemistry region interrupted introduction of substances A and substance B, make the substance A in the electricity The electronics being separated at chemical regions is exported from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in electricity Electric energy is externally provided on the channel of export and/or the importing of son or from outer absorption electric energy, so persistently realizes the normality of work.

Embodiment 13

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to electrochemistry region introduction of substances A With the mixture of substance B, the electronics for being separated into the substance A at the electrochemistry region is led from the electrochemistry region Out, make electronics importing return to the electrochemistry region, externally provided on the channel of export and/or the importing of electronics electric energy or from Outer absorption electric energy, the step that control electronics imports and exports realize steady operation, so persistently realize the normality of work.

Embodiment 14

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to electrochemistry region introduction of substances A With the mixture of substance B or to the mixture of electrochemistry region interrupted introduction of substances A and substance B, make the substance A in the electricity It is separated into electronics at chemical regions, exports electronics from the electrochemistry region, electronics importing is made to return to the electrochemistry region, Electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy, so persistently realizes the normal of work State.

Embodiment 15

Electrochemical reaction implementation method disclosed in this invention is also selectively chosen to electrochemistry region introduction of substances A With the mixture of substance B, the substance A is made to be separated into electronics at the electrochemistry region, makes electronics from the electrochemical school district Domain export makes electronics importing return to the electrochemistry region, externally provides electric energy on the channel of export and/or the importing of electronics Or from outer absorption electric energy, controls the step that electronics imports and exports and realize steady operation, so persistently realize the normality of work.

Embodiment 16

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, makes electrochemistry region be in substance A In the mixture of substance B, the electronics for being separated into the substance A at the electrochemistry region is led from the electrochemistry region Out, make electronics importing return to the electrochemistry region, externally provided on the channel of export and/or the importing of electronics electric energy or from Outer absorption electric energy so persistently realizes the normality of work.

Embodiment 17

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, makes electrochemistry region be in substance A In the mixture of substance B, the electronics for being separated into the substance A at the electrochemistry region is led from the electrochemistry region Out, make electronics importing return to the electrochemistry region, externally provided on the channel of export and/or the importing of electronics electric energy or from Outer absorption electric energy, the step that control electronics imports and exports realize steady operation, so persistently realize the normality of work.

Embodiment 18

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, makes electrochemistry region be in substance A In the mixture of substance B, so that the substance A is separated into electronics at the electrochemistry region, make electronics from the electrochemistry Region export makes electronics importing return to the electrochemistry region, electricity is externally provided on the channel of export and/or the importing of electronics Can or from outer absorption electric energy, so persistently realize work normality.

Embodiment 19

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, makes electrochemistry region be in substance A In the mixture of substance B, so that the substance A is separated into electronics at the electrochemistry region, make electronics from the electrochemistry Region export makes electronics importing return to the electrochemistry region, electricity is externally provided on the channel of export and/or the importing of electronics Can or from outer absorption electric energy, control the step that electronics imports and exports and realize steady operation, so persistently realize the normality of work.

Embodiment 20

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, is in electrochemistry region discontinuously In the mixture of substance A and substance B, the electronics that is separated into the substance A at the electrochemistry region is from the electrochemistry Region export makes electronics importing return to the electrochemistry region, electricity is externally provided on the channel of export and/or the importing of electronics Can or from outer absorption electric energy, so persistently realize work normality.

Embodiment 21

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, is in electrochemistry region discontinuously In the mixture of substance A and substance B, the electronics that is separated into the substance A at the electrochemistry region is from the electrochemistry Region export makes electronics importing return to the electrochemistry region, electricity is externally provided on the channel of export and/or the importing of electronics Can or from outer absorption electric energy, control the step that electronics imports and exports and realize steady operation, so persistently realize the normality of work.

Embodiment 22

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, is in electrochemistry region discontinuously In the mixture of substance A and substance B, the substance A is made to be separated into electronics at the electrochemistry region, makes electronics from described The export of electrochemistry region makes electronics importing return to the electrochemistry region, on the channel of export and/or the importing of electronics externally Electric energy is provided or from outer absorption electric energy, so persistently realizes the normality of work.

Embodiment 23

Electrochemical reaction implementation method disclosed in this invention, which is also selectively chosen, is in electrochemistry region discontinuously In the mixture of substance A and substance B, the substance A is made to be separated into electronics at the electrochemistry region, makes electronics from described The export of electrochemistry region makes electronics importing return to the electrochemistry region, on the channel of export and/or the importing of electronics externally Electric energy is provided or from outer absorption electric energy, controls the step that electronics imports and exports and realizes steady operation, so persistently realize work Normality.

Embodiment 24

Fig. 1-1 is under unitary electrode (such as the present invention in electrochemistry region), and substance A and substance B replace with electrode to be connect The process chart of touching, electrochemical reaction implementation method of the present invention are selectively chosen according to following course of work works Make.

In Fig. 1-1,1 is electrode, A representative species A (reducing agent), B representative species B (oxidant).When substance A and electrode connect When touching (1. shown process in figure), the electronics of substance A is exported forming material A cation A under electro ultrafiltration⁺(i.e. reducing agent is being just Ion A⁺), as the reducing agent cation A⁺(intensity and electrode of the amount of accumulation depending on electro ultrafiltration when running up to setting degree Possessed electrical relation), substance A and substance B switching (as in figure 3. and 4. shown in process), and electronics is made to pass through load 5 It is imported into electrode, substance B, substance A cation A at electrode⁺Substance A and substance B redox reaction are generated with electron reaction Product C (in such as figure 5. shown in).Next two-way can be divided to continue, is as 5. passed through in figure all the wayShown in 1., Apply the electro ultrafiltration in direction same as described above again, and switch substance A and substance B again, and then realizes circulation industrial in cycles Make；Another way is as 5. passed through in figureShown in 7., apply the electro ultrafiltration in direction contrary to the above, and continues to make substance B and electricity Pole contact, and then make substance B and electronics coexist in electrode (in some cases substance B can receive electronically form substance B bear from Sub- B^—Or oxidant anion B^—, do not show in figure), as electronics or oxidant anion B^—When running up to setting degree (such as In figure 9. shown in), switching substance A and substance B and make electronics through load 5 from electrode export (as figure 10. andIt is shown), reducing agent Cation, electronics and oxidant react herein generates C (in such as figureIt is shown), next to electrode implement reversed electro ultrafiltration and Continue to make substance A contacted with electrode reach in figure 1. shown in state, and then realize cycle operation in cycles.Shown in this figure Principle and process are the course of work of unitary electrode.The purpose of electro ultrafiltration be control with strengthen electrochemical reaction, electro ultrafiltration can be with From external power supply, can come from the chemical potential in electrochemical reaction, can be from by storing process electric energy (for example, Electric energy through capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but there is no damaged the electric energy consumed during electro ultrafiltration It loses, and is stored at electrode, released together when electric current is reversed.

Embodiment 25

Fig. 1-2 is H under unitary electrode (such as electrochemistry region in the present invention)₂And O₂Contact is alternateed with electrode Process chart, electrochemical reaction implementation method of the present invention is selectively chosen to work according to following courses of work.

In Fig. 1-2,1 is electrode.The principle and process that this figure illustrates are identical as Fig. 1-1, only the reducing agent object in Fig. 1-1 Matter A is with H₂To represent, oxidant species B is with O₂To represent, reducing agent cation A⁺It is then H⁺.Principle shown in this figure and process For the course of work of unitary electrode.The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, and electro ultrafiltration can come from external electrical Source can come from the chemical potential in electrochemical reaction, can be from the electric energy by storing process (for example, through capacitor or vibration Swing the electric energy of circuit) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, but by It is stored at electrode, is released together when electric current is reversed.

Embodiment 26

Fig. 1-3 is CH under unitary electrode (such as electrochemistry region in the present invention)₃OH and O₂It alternates and contacts with electrode Process chart, electrochemical reaction implementation method of the present invention be selectively chosen according to following courses of work work.

In Fig. 1-3,1 is electrode.The principle and process that this figure illustrates are identical as Fig. 1-1, only the reducing agent object in Fig. 1-1 Matter A is with CH₃OH is representative, and oxidant species B is with O₂To represent.Furthermore compared with Fig. 1-1, the principle shown in Fig. 1-3 and process Middle H₂O takes part in electrochemical reaction process as recycled material.Principle shown in this figure and process are the worked of unitary electrode Journey.The purpose of electro ultrafiltration is that control can come from external power supply, it is anti-to can come from electrochemistry with electrochemical reaction, electro ultrafiltration is strengthened Chemical potential in answering can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electricity is made With consumption electric energy, but the electric energy consumed during electro ultrafiltration is being lost, and is stored at electrode, anti-to electric current To when release together.

Embodiment 27

Fig. 1-4 is the mixture and electricity of substance A and substance B under unitary electrode (such as electrochemistry region in the present invention) The process chart that pole contacts with each other, electrochemical reaction implementation method of the present invention are selectively chosen according to following work Process work.

In Fig. 1-4,1 is electrode, A representative species A (reducing agent), B representative species B (oxidant).When substance A and substance B Mixture and electrode when contacting (in figure 1. shown in process), the electronics of the substance A under electro ultrafiltration in mixture is exported shape At substance A cation A⁺(i.e. reducing agent cation A⁺), as the reducing agent cation A⁺When running up to setting degree (accumulation Electrical relation possessed by intensity and electrode of the amount depending on electro ultrafiltration), so that electronics is imported into electrode by load 5, in electrode Locate substance B, substance A cation A⁺With the product C of electron reaction generation substance A and substance B redox reaction (in such as figure Shown in 4.).Next two-way can be divided to continue, is as, 5. to shown in 1., applied side same as described above again in figure all the way To electro ultrafiltration, that is, reach in figure 1. shown in state, and then realize cycle operation in cycles；Another way be as in figure 5. to 6. It is shown, apply the electro ultrafiltration in direction contrary to the above, and then make substance B forming material B anion B^—That is oxidant anion B^— (in some cases may forming material A, substance B and electronics coexist in the situation of electrode, do not shown in figure), work as oxidant Anion B^—Or electron accumulation to setting degree when (in such as figure 8. shown in), make electronics through load 5 from electrode export (such as figure 9. institute Show) form reducing agent cation A⁺, it is formed by reducing agent cation A⁺, oxidant (substance B) and electronics or reducing agent just from Sub- A⁺With oxidant anion B^—Reaction generates C (also as 9. shown in figure), next implements reversed electro ultrafiltration to electrode and reaches In figure 1. shown in state, and then realize cycle operation in cycles.Although existing always at electrode during shown in Fig. 1-4 There is reducing agent and oxidant always in substance A and substance B, but due to electro ultrafiltration there are reducing agents and oxidant can not be straight Row redox reaction is tapped into, and then avoids or weakens mixture and directly carry out redox reaction forfeiture power supply at electrode The process of ability.Principle shown in this figure and process are the course of work of unitary electrode.The purpose of electro ultrafiltration is control and strengthens Electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from by Electric energy (for example, electric energy through capacitor or oscillating circuit) of storing process etc..Electro ultrafiltration consumes electric energy, but in electro ultrafiltration process The electric energy of middle consumption is not lost, and is stored at electrode, is released together when electric current is reversed.

Embodiment 28

Fig. 1-5 is the mixture and electricity of substance A and substance B under unitary electrode (such as electrochemistry region in the present invention) The process chart of extremely mutual makes discontinuous contact, electrochemical reaction implementation method of the present invention are selectively chosen according to following Course of work work.

In Fig. 1-5,1 is electrode, A representative species A (reducing agent), B representative species B (oxidant).Except substance A and substance B Mixture and the mutual makes discontinuous contact of electrode influence outside, principle shown in Fig. 1-5 is identical as shown in Fig. 1-4 with process, mixed The purpose for closing object and electrode makes discontinuous contact is to reduce the mixture of substance A and substance B i.e. reducing agent and oxidant at electrode Mixture existing for the time, to realize better control to electrochemical process.As in figure 3., 4., shown in the processes such as 5., Discontinuously contact with each other and be formed by circulation, have at electrode considerable time intervals only exist a kind of substance only exist and also Former agent only exists oxidant (substance B and electronics is regarded as substance B anion B when coexisting^—Rather than substance B).This figure institute The principle and process shown are the course of work of unitary electrode.The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, electro ultrafiltration It can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from the electric energy (example by storing process Such as, the electric energy through capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not It is lost, and is stored at electrode, released together when electric current is reversed.

Embodiment 29

Fig. 1-6 is H under unitary electrode (such as electrochemistry region in the present invention)₂And O₂Mixture and electrode phase mutual connection The process chart of touching, electrochemical reaction implementation method of the present invention are selectively chosen according to following course of work works Make.

In Fig. 1-6,1 is electrode.Principle and process shown in Fig. 1-6 are identical as Fig. 1-4, only the substance A in Fig. 1-4 With H₂To represent, substance B is with O₂To represent.Principle shown in this figure and process are the course of work of unitary electrode.The mesh of electro ultrafiltration Be control and strengthen electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, It can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electro ultrafiltration consumes electric energy, but The electric energy consumed during electro ultrafiltration is not lost, and is stored at electrode, is released together when electric current is reversed.

Embodiment 30

Fig. 1-7 is CH under unitary electrode (such as electrochemistry region in the present invention)₃OH and O₂Mixture and electrode phase The process chart mutually contacted, electrochemical reaction implementation method of the present invention are selectively chosen according to following courses of work Work.

In Fig. 1-7,1 is electrode.Principle and process shown in Fig. 1-7 are identical as Fig. 1-4, only the substance A in Fig. 1-4 With CH₃OH is representative, and substance B is with O₂To represent.In addition to this, compared with principle and process shown in Fig. 1-4, water as shown in the figure Electrochemical reaction is taken part in as recycled material.Principle shown in this figure and process are the course of work of unitary electrode.Electro ultrafiltration Purpose be control and strengthen electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the change in electrochemical reaction Gesture is learned, can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electro ultrafiltration consumption electricity Can, but the electric energy consumed during electro ultrafiltration is not lost, and be stored at electrode, when electric current is reversed together It releases.

Embodiment 31

Fig. 2-1 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , the process chart that substance A and substance B alternately contacts with electrode, electrochemical reaction implementation method of the present invention is optional Property select according to following courses of work work.

In Fig. 2-1,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, A representative species A (reducing agent), B representative species B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.When substance A and electricity When pole 1 contacts (1. shown process in figure), the electronics of substance A is exported to electric conductor (2) and then makes substance A shape under electro ultrafiltration At substance A cation A⁺(i.e. reducing agent cation A⁺), as the reducing agent cation A⁺When running up to setting degree (accumulation Electrical relation possessed by intensity and electrode of the amount depending on electro ultrafiltration), substance A and substance B switching are (3. and 4. shown in such as figure Process), and electronics is made 5 to imported into electrode from electric conductor by load, substance B, substance A cation A at electrode⁺And electricity The product C (5. shown in such as figure) of sub- reaction product matter A and substance B redox reaction.Next can divide two-way after It is continuous to carry out, it is as 5. passed through in figure all the wayShown in 1., apply the electro ultrafiltration in direction same as described above again, and switch again Substance A and substance B, and then realize cycle operation in cycles；Another way is as 5. passed through in figureTo shown in 7., apply with it is upper The electro ultrafiltration of opposite direction is stated, and continues to contact substance B with electrode, and then substance B and electronics is made to coexist in electrode (certain In the case of substance B can receive and electronically form substance B anion B^—Or oxidant anion B^—, do not show in figure), work as electronics Or oxidant anion B^—When running up to setting degree (in such as figure 9. shown in), switching substance A and substance B and make electronics through loading 5 from electrode export to electric conductor (in such as figure 10. andIt is shown), reducing agent cation, electronics and oxidant are at the electrode Reaction generates C (in such as figureIt is shown), reversed electro ultrafiltration next is implemented to electrode and continues to contact substance A with electrode to reach Into figure 1. shown in state, and then realize cycle operation in cycles.Principle shown in this figure and process are to include through interpolar Spacer has the electrode of electrical relation and the course of work of electric conductor.The purpose of electro ultrafiltration is that control and reinforcing electrochemistry are anti- It answers, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from by storing process Electric energy (for example, electric energy through capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but the electricity consumed during electro ultrafiltration It can not be lost, and be stored at electrode, be released together when electric current is reversed.

Embodiment 32

Fig. 2-2 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , H₂And O₂The process chart of contact is alternateed with electrode, electrochemical reaction implementation method of the present invention is alternative Ground selection works according to following courses of work.

In Fig. 2-2,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, and wherein electric conductor is exported in electrodic electron and imported Play the role of another electrode in the process.Except the substance A (reducing agent) in Fig. 2-1 is with H₂To represent, substance B (oxidant) With O₂Outer to represent, principle and the course of work shown in Fig. 2-2 are identical as principle shown in Fig. 2-1 and process.The mesh of electro ultrafiltration Be control and strengthen electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, It can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electro ultrafiltration consumes electric energy, but The electric energy consumed during electro ultrafiltration is not lost, and is stored at electrode, is released together when electric current is reversed.

Embodiment 33

Fig. 2-3 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , CH₃OH and O₂The process chart of contact is alternateed with electrode, electrochemical reaction implementation method of the present invention may be selected Property select according to following courses of work work.

In Fig. 2-3,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, and wherein electric conductor is exported in electrodic electron and imported Play the role of another electrode in the process.Except the substance A (reducing agent) in Fig. 2-1 is with CH₃OH is representative, substance B (oxidation Agent) with O₂To represent, H₂It is outer that O as recycled material participates in reaction, shown in principle and the course of work shown in Fig. 2-3 and Fig. 2-1 Principle it is identical with process.The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, and electro ultrafiltration can come from external power supply, can With the chemical potential in electrochemical reaction, the electric energy by storing process can be from (for example, through capacitor or oscillating circuit Electric energy) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored in At electrode, released together when electric current is reversed.

Embodiment 34

Fig. 2-4 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , the process chart that the mixture and electrode of substance A and substance B contact with each other, electrochemical reaction realization side of the present invention Method is selectively chosen to work according to following courses of work.

In Fig. 2-4,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, A representative species A (reducing agent), B representative species B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.When substance A and object When the mixture and electrode of matter B contact (1. shown process in figure), the electronics of the substance A under electro ultrafiltration in mixture is exported To electric conductor 2 and then make substance A forming material A cation A⁺(i.e. reducing agent cation A⁺), as the reducing agent cation A⁺Product When tiring out setting degree (electrical relation possessed by intensity and electrode of the amount of accumulation depending on electro ultrafiltration), make electronics through loading 5 imported into electrode from electric conductor, substance B, substance A cation A at electrode⁺Substance A and substance B oxidation are generated with electron reaction The product C (4. shown in such as figure) of reduction reaction.Next two-way can be divided to continue, be all the way as in figure 5. to 1. institute Show, apply the electro ultrafiltration in direction same as described above again, that is, reach in figure 1. shown in state, and then realize circulation industrial in cycles Make；Another way is and then to keep substance B forming material B negative as, 5. to shown in 6., applied the electro ultrafiltration in direction contrary to the above in figure Ion B^—That is oxidant anion B^—(in some cases may forming material A, substance B and electronics coexist in the shape of electrode Condition is not shown in figure), as oxidant anion B^—Or electron accumulation to setting degree when (in such as figure 8. shown in), pass through electronics Load 5 exports to electric conductor (in such as figure 9. shown in) from electrode and forms reducing agent cation A⁺, it is formed by reducing agent cation A⁺, oxidant (substance B) and electronics or reducing agent cation A⁺With oxidant anion B^—Reaction generates C (also such as 9. institute in figure Show), next to electrode implement reversed electro ultrafiltration reach in figure 1. shown in state, and then realize cycle operation in cycles. Although there is substance A always at electrode during shown in Fig. 2-4 and substance B have reducing agent and oxidant always, Due to the presence of electro ultrafiltration, reducing agent and oxidant can not directly carry out redox reaction, and then avoid or weaken mixing Object directly carries out the process that redox reaction loses power supply capacity at electrode.The purpose of electro ultrafiltration is control and reinforcing electrification Reaction is learned, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from by storage Electric energy (for example, electric energy through capacitor or oscillating circuit) of process etc..Electro ultrafiltration consumes electric energy, but consumes during electro ultrafiltration Electric energy not lost, and be stored at electrode, released together when electric current is reversed.

Embodiment 35

Fig. 2-5 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , the mixture of substance A and substance B and the process chart of the mutual makes discontinuous contact of electrode, electrochemical reaction reality of the present invention Existing method is selectively chosen to work according to following courses of work.

In Fig. 2-5,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, A representative species A (reducing agent), B representative species B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.Except substance A and object Outside the mixture of matter B and the influence of the mutual makes discontinuous contact of electrode, shown in principle and the course of work shown in Fig. 2-5 and Fig. 2-4 Principle is identical with process.The purpose of mixture and electrode makes discontinuous contact is when reducing existing for reducing agent and oxidant mixture It is long, improve safety, controllability and reliability.The purpose of electro ultrafiltration is that control can come with electrochemical reaction, electro ultrafiltration is strengthened From external power supply, can come from the chemical potential in electrochemical reaction, can be from by storing process electric energy (for example, through The electric energy of capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but there is no damaged the electric energy consumed during electro ultrafiltration It loses, and is stored at electrode, released together when electric current is reversed.

Embodiment 36

Fig. 2-6 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , H₂And O₂Mixture and the process chart that contacts with each other of electrode, electrochemical reaction implementation method of the present invention it is optional It selects to selecting property to work according to following courses of work.

In Fig. 2-6,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, and wherein electric conductor is exported in electrodic electron and imported Play the role of another electrode in the process.Except substance A (reducing agent) is with H₂To represent, substance B (oxidant) is with O₂To represent Outside, principle and the course of work shown in Fig. 2-6 are identical as principle shown in Fig. 2-4 and process.Electro ultrafiltration can come from external electrical Source can come from the chemical potential in electrochemical reaction, can be from the electric energy by storing process (for example, through capacitor or vibration Swing the electric energy of circuit) etc..The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, and electro ultrafiltration consumes electric energy, but in electro ultrafiltration The electric energy consumed in the process is not lost, and is stored at electrode, is released together when electric current is reversed.

Embodiment 37

Fig. 2-7 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , CH₃OH and O₂Mixture and the process chart that contacts with each other of electrode, electrochemical reaction implementation method of the present invention can It selectively selects to work according to following courses of work.

In Fig. 2-7,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, and wherein electric conductor is exported in electrodic electron and imported Play the role of another electrode in the process.Except substance A (reducing agent) is with CH₃OH is representative, and substance B (oxidant) is with O₂For generation Off-balancesheet, H₂O is participated in outside reaction as recycled material, principle and the course of work shown in Fig. 2-7 and principle and mistake shown in Fig. 2-4 Cheng Xiangtong.The purpose of electro ultrafiltration is that control can come from external power supply, can come from electrification with electrochemical reaction, electro ultrafiltration is strengthened The chemical potential in reaction is learned, can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process. Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored at electrode, to electricity It is released together when flowing reversed.

As disposable embodiment, the aforementioned electrochemical reaction implementation method without using mixture of the present invention can be into One step selectively selects to be inserted into inert substance and/or dead band duration between the substance A and the substance B.

Electrochemical reaction implementation method of the present invention in the specific implementation, electronics export and/or import during, Optionally use electro ultrafiltration；And it further can selectively select using capacitor, DC power supply, AC power source, alternation electricity Source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit, Motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five Conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, its ten The conjunction of binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction.

Electrochemical reaction implementation method of the present invention in the specific implementation, can be further selectively electrochemical to participating in The region for learning reaction applies electro ultrafiltration, so that the substance for participating in electrochemical reaction is difficult to directly carry out redox reaction.

Electrochemical reaction implementation method of the present invention in the specific implementation, further can selectively select to make electronics Export import be work normality.

Electrochemical reaction implementation method of the present invention in the specific implementation, further can selectively select to make electronics It is work normality that export between the electrochemistry region and the electric conductor, which imports,.

The present invention in the specific implementation, from the durations of electrochemistry region export electronic processes with to the electrochemical school district Domain import the ratio between durations of electronic processes between 1/6 and 6, between 1/5 and 5, between 1/4 and 4, between 1/3 and 3, Between 1/2.5 and 2.5, between 1/2 and 2, between 1/1.5 and 1.5, between 1/1.3 and 1.3, in 1/1.2 and 1.2 Between or between 1/1.1 and 1.1, or from the durations of electrochemistry region export electronic processes with to the electrochemistry region The duration for importing electronic processes is equal.

The present invention in the specific implementation, be selectively chosen make electronics the electrochemistry region and the electric conductor it Between export import be work normality.Wherein the electric conductor optionally selects to be set as corresponding with the electrochemistry region Electrode.

Electrochemical reaction implementation method disclosed in this invention, which is selectively chosen, serves as half electrochemical appliance of manufacture (including the device region of an electrode i.e. in electrochemical appliance), is also selectively chosen and serves as manufacture electrochemical appliance. Two and half electrochemical appliances can construct an electrochemical appliance.

Electrochemical reaction implementation method disclosed in this invention in the specific implementation, makes the electrochemistry region and alternation electricity Kinetic potential and the corresponding state of alternating current are to continue working process.

In the specific implementation, the electrochemical reaction implementation method disclosed in this invention and alternating electromotive force and alternation electricity Flow corresponding, i.e., electrochemistry region is corresponding with alternating electromotive force and alternating current.

As disposable embodiment, the electrochemical reaction implementation method disclosed in this invention is used as with chemical energy When exchanging the method for electric energy for, the reactant for participating in electrochemical reaction can be selected from substance documented in Summary, The substance A is preferably set to be set as hydrogen, methanol, ethyl alcohol, methane etc..

As disposable embodiment, electrochemical reaction implementation method disclosed in this invention in the specific implementation, It is selectively chosen using the electrochemistry region as an electrode, and using electric conductor as another electrode, and makes two electricity Pole cooperating is to complete the conversion of chemical energy electric energy.It is also selectively chosen using an electrochemistry region as an electrode, Using another electrochemistry region as another electrode, and make two electrode cooperatings to complete the conversion of chemical energy electric energy.

The principle of the electrochemical reaction implementation method of the invention is described as follows:

Fig. 3-1 is the basic logic chart for exchanging electric energy for chemical energy.All are that with the process that chemical energy exchanges electric energy for Electronics is exported from reducing agent, so that reducing agent is formed reducing agent cation, electronics is then imported into reducing agent cation and oxygen again In the coexisting body of agent, and then realize that reducing agent cation, oxidant and electronics three react generation reducing agent and oxidant is anti- The product that should be generated, the summation that the electronics export during this imports is to export the process of electric energy.Fig. 3-1 is using hydrogen as also The diagram that the representative of former agent, the representative using oxygen as oxidant carry out this basic logic.

Fig. 3-2 is reducing agent oxidant electrochemical reaction controlled process figure.Reducing agent and oxidant at electrode (such as this Electrochemistry region in invention) reaction that could occur, the electrochemical reaction of electric energy can be either exported, still cannot be exported The reducing agent of electric energy and the direct oxidation reduction reaction of oxidant, essence are all reducing agent, oxidant and electrode effect three Indispensable reaction, and electrode to the effect of chemical reaction is realized by electro ultrafiltration.It means that by changing electrode Electrical property (or electriferous state) this kind of reaction can be controlled.For example, if making electrode that there is electronegativity (i.e. affine electricity The ability of son is reinforced, or the ability of the affine electronics electronically formed by export), so that it may make reducing agent formed reducing agent just from Subprocess occurs and can be with Accelerating reduction dosage form at the process of reducing agent cation, if making electrode that there is electropositivity (to discharge The ability of electronics is reinforced, or the ability of the offer electronics electronically formed by importing), so that it may make oxidant and reducing agent just from Son react and can reacting for accelerated oxidation agent and reducing agent cation (oxidant in other words, is made to form oxidant anion Process occur and can accelerated oxidation dosage form at oxidant anion process).Going back for (such as catalyst participation) is participated in electrode Former agent and oxidant directly carry out needing electrode is not i.e. positively charged (not have electricity without negative electricity during redox reaction Positivity does not also have electronegativity, not within the rule by the electropositivity of itself or electronegativity of electro ultrafiltration, in other words, needs electrode Electronegativity and electropositivity be not changed), otherwise redox reaction can not be carried out directly.This means that as long as we change The electrical property (changing its electropositivity, electronegativity, change its charging property) of electrode, so that it may avoid or weaken reducing agent and oxidant It directly carries out redox reaction heat release and loses the process for exporting electric energy, to realize the mixture for using reducing agent and oxidant The safety and controllability for carrying out chemical energy electric energy conversion process also may be implemented to difficult in reducing agent and oxidant handoff procedure To avoid mixed process caused by probabilistic control.Representative of the Fig. 3-2 using hydrogen as reducing agent, using oxygen as oxidation The representative of agent, using D as the representative in electrode (such as electrochemistry region in the present invention), for by implementing electro ultrafiltration to electrode Change it electrically and then the process for controlling chemical reaction is shown, in figure, D⁺Indicate have the electrode of electronegativity (i.e. affine The electrode that the ability of electronics is reinforced, i.e., because electronics is exported the electrode that its electron affinity energy power is reinforced), D^—Expression has Electropositive electrode (i.e. electrode that the ability of release electronics is reinforced, i.e., because ability that electronics is imported into its release electronics is strong The electrode of change).

Attached drawing of the invention is only a kind of signal, and any technical solution for meeting the application literature record belongs to the application Protection scope.

It is clear that the invention is not restricted to above embodiments, according to techniques known and technology disclosed in this invention Scheme, can derive or associate many variant schemes out, and all these variant schemes also are regarded as being protection model of the invention It encloses.

Claims

1. a kind of electrochemical reaction implementation method, it is characterised in that: make electrochemistry region and substance A and substance B alternately contact or It contacts substance A and substance B alternately with electrochemistry region, or electrochemistry region and substance A is made to contact with each other and make the electrification School district domain and the mutual makes discontinuous contact of substance B, or electrochemistry region and substance B is made to contact with each other and make the electrochemistry region and object The mutual makes discontinuous contact of matter A makes the substance A be separated into positive charged particle and electronics at the electrochemistry region, makes the electricity The electronics of chemical regions, which exports, to be imported, and electric energy or electric from outer absorption is externally provided on the channel of export and/or the importing of electronics Can, so persistently realize the normality of work；

Or, replace introduction of substances A and substance B to electrochemistry region, or to electrochemistry region introduction of substances A and interrupted introduction of substances B, or to electrochemistry region introduction of substances B and interrupted introduction of substances A, it is separated into the substance A at the electrochemistry region Electronics exported from the electrochemistry region, make electronics importing return to the electrochemistry region, in the export and/or importing of electronics Channel on externally provide electric energy or from outer absorption electric energy, so persistently realize the normality of work；

It is connect or, electrochemistry region is made alternately to contact or make substance A and substance B to replace with electrochemistry region with substance A and substance B Touching, the electronics for being separated into the substance A at the electrochemistry region are exported from the electrochemistry region, import back electronics To the electrochemistry region, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy, electronics The step imported and exported matches with the electrochemistry region with the step that the substance A and the substance B alternately contact, so Persistently realize the normality of work；

Or, electrochemistry region and substance A is made to contact with each other and make the electrochemistry region and the mutual makes discontinuous contact of substance B, to make institute It states the electronics that substance A is separated at the electrochemistry region to export from the electrochemistry region, returns to electronics importing described Electrochemistry region, externally provides electric energy on the channel of export and/or the importing of electronics or from outer absorption electric energy, electronics is led Step out and the step in the electrochemistry region and the substance B makes discontinuous contact match, and so persistently realize the normal of work State；

Or, electrochemistry region and substance B is made to contact with each other and make the electrochemistry region and the mutual makes discontinuous contact of substance A, to make institute It states the electronics that substance A is separated at the electrochemistry region to export from the electrochemistry region, returns to electronics importing described Electrochemistry region, externally provides electric energy on the channel of export and/or the importing of electronics or from outer absorption electric energy, electronics is led Step out and the step in the electrochemistry region and the substance A makes discontinuous contact match, and so persistently realize the normal of work State.

2. a kind of electrochemical reaction implementation method, it is characterised in that: to electrochemistry region alternating introduction of substances A and substance B, or to Electrochemistry region introduction of substances A and interrupted introduction of substances B, or to electrochemistry region introduction of substances B and interrupted introduction of substances A, make The substance A is separated into electronics at the electrochemistry region, exports electronics from the electrochemistry region, imports back electronics To the electrochemistry region, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy, so Persistently realize the normality of work；

Or, replacing introduction of substances A and substance B to electrochemistry region, the substance A is made to be separated into electricity at the electrochemistry region Son exports electronics from the electrochemistry region, make electronics importing return to the electrochemistry region, electronics export and/or Electric energy is externally provided on the channel of importing or from outer absorption electric energy, the step and the substance A and the object that electronics imports and exports The step that matter B is alternately imported matches, and so persistently realizes the normality of work；

Or, separating the substance A at the electrochemistry region to electrochemistry region introduction of substances A and interrupted introduction of substances B It at electronics, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in the export of electronics And/or electric energy is externally provided or from outer absorption electric energy, the step that electronics imports and exports and the substance B are interrupted on the channel imported The step of importing matches, and so persistently realizes the normality of work；

Or, separating the substance A at the electrochemistry region to electrochemistry region introduction of substances B and interrupted introduction of substances A It at electronics, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in the export of electronics And/or electric energy is externally provided or from outer absorption electric energy, the step that electronics imports and exports and the substance A are interrupted on the channel imported The step of importing matches, and so persistently realizes the normality of work.

3. a kind of electrochemical reaction implementation method, it is characterised in that: it is in electrochemistry region alternately in substance A and substance B, or So that electrochemistry region is in substance A and is discontinuously in substance B, or electrochemistry region is made to be in substance B and discontinuously be in In substance A, the electronics for being separated into the substance A at the electrochemistry region is exported from the electrochemistry region, makes electronics Importing returns to the electrochemistry region, and electric energy or electric from outer absorption is externally provided on the channel of export and/or the importing of electronics Can, so persistently realize the normality of work；

Or, being in electrochemistry region alternately in substance A and substance B, it is separated into the substance A at the electrochemistry region Electronics exported from the electrochemistry region, make electronics importing return to the electrochemistry region, in the export and/or importing of electronics Channel on externally provide electric energy or from outer absorption electric energy, the step that electronics imports and exports replaces with the electrochemistry region to be in Step in the substance A and the substance B matches, and so persistently realizes the normality of work；

Or, electrochemistry region is made to be in substance A and discontinuously be in substance B, make the substance A at the electrochemistry region The electronics being separated into is exported from the electrochemistry region, make electronics importing return to the electrochemistry region, electronics export and/ Or electric energy is externally provided or from outer absorption electric energy on the channel imported, the step and the electrochemistry region that electronics imports and exports are disconnected The continuous step in the substance B matches, and so persistently realizes the normality of work；

Or, electrochemistry region is made to be in substance B and discontinuously be in substance A, make the substance A at the electrochemistry region The electronics being separated into is exported from the electrochemistry region, make electronics importing return to the electrochemistry region, electronics export and/ Or electric energy is externally provided or from outer absorption electric energy on the channel imported, the step and the electrochemistry region that electronics imports and exports are disconnected The continuous step in the substance A matches, and so persistently realizes the normality of work.

4. a kind of electrochemical reaction implementation method, it is characterised in that: it is in electrochemistry region alternately in substance A and substance B, or So that electrochemistry region is in substance A and is discontinuously in substance B, or electrochemistry region is made to be in substance B and discontinuously be in In substance A, the substance A is made to be separated into electronics at the electrochemistry region, exports electronics from the electrochemistry region, make Electronics importing returns to the electrochemistry region, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer suction Electric energy is received, so persistently realizes the normality of work；

Or, being in electrochemistry region alternately in substance A and substance B, it is separated into the substance A at the electrochemistry region Electronics exports electronics from the electrochemistry region, make electronics importing return to the electrochemistry region, electronics export and/ Or electric energy is externally provided or from outer absorption electric energy on the channel imported, the step and the electrochemistry region that electronics imports and exports are handed over Match for the step in the substance A and the substance B, so persistently realizes the normality of work；

Or, electrochemistry region is made to be in substance A and discontinuously be in substance B, make the substance A at the electrochemistry region It is separated into electronics, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in leading for electronics Externally provide electric energy or from outer absorption electric energy out and/or on the channel that imports, the step and the electrochemistry that electronics imports and exports The step that region is discontinuously in the substance B matches, and so persistently realizes the normality of work；

Or, electrochemistry region is made to be in substance B and discontinuously be in substance A, make the substance A at the electrochemistry region It is separated into electronics, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in leading for electronics Externally provide electric energy or from outer absorption electric energy out and/or on the channel that imports, the step and the electrochemistry that electronics imports and exports The step that region is discontinuously in the substance A matches, and so persistently realizes the normality of work.

5. a kind of electrochemical reaction implementation method, it is characterised in that: make the mixture phase in electrochemistry region with substance A and substance B Mutually contact or mutual makes discontinuous contact, make the substance A be separated into positive charged particle and electronics at the electrochemistry region, make institute The electronics export for stating electrochemistry region imports, and electric energy is externally provided on the channel of export and/or the importing of electronics or from outer suction Electric energy is received, so persistently realizes the normality of work；

Or, the mixture of electrochemistry region and substance A and substance B is made to contact with each other or mutual makes discontinuous contact, the substance A is made to exist Positive particles and electronics are separated at the electrochemistry region, the electronics in the electrochemistry region is exported and imports, in electronics Electric energy is externally provided in export and/or the channel imported or from outer absorption electric energy, controls the step that electronics imports and exports and realizes surely Fixed work, so persistently realizes the normality of work；

Or, to the mixture of electrochemistry region introduction of substances A and substance B or to the interrupted introduction of substances A in electrochemistry region and substance B Mixture, the electronics for being separated into the substance A at the electrochemistry region exports from the electrochemistry region, makes electronics Importing returns to the electrochemistry region, and electric energy or electric from outer absorption is externally provided on the channel of export and/or the importing of electronics Can, so persistently realize the normality of work；

Or, separating the substance A at the electrochemistry region to the mixture of electrochemistry region introduction of substances A and substance B At electronics exported from the electrochemistry region, make electronics importing return to the electrochemistry region, electronics export and/or lead Electric energy is externally provided on the channel entered or from outer absorption electric energy, controls the step that electronics imports and exports and realizes steady operation, so Persistently realize the normality of work.

6. a kind of electrochemical reaction implementation method, it is characterised in that: to the mixture of electrochemistry region introduction of substances A and substance B Or the mixture to electrochemistry region interrupted introduction of substances A and substance B, separate the substance A at the electrochemistry region It at electronics, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in the export of electronics And/or electric energy is externally provided on the channel imported or from outer absorption electric energy, so persistently realizes the normality of work；

Or, separating the substance A at the electrochemistry region to the mixture of electrochemistry region introduction of substances A and substance B It at electronics, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in the export of electronics And/or electric energy is externally provided on the channel imported or from outer absorption electric energy, controls the step that electronics imports and exports and realizes and stablize work Make, so persistently realizes the normality of work.

7. a kind of electrochemical reaction implementation method, it is characterised in that: electrochemistry region is made to be in the mixture of substance A and substance B In, the electronics for being separated into the substance A at the electrochemistry region is exported from the electrochemistry region, imports back electronics To the electrochemistry region, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy, so Persistently realize the normality of work；

Or, being in electrochemistry region in the mixture of substance A and substance B, punish the substance A in the electrochemistry region From at electronics exported from the electrochemistry region, make electronics importing return to the electrochemistry region, electronics export and/or Electric energy is externally provided on the channel of importing or from outer absorption electric energy, controls the step that electronics imports and exports and realizes steady operation, such as This persistently realizes the normality of work.

8. a kind of electrochemical reaction implementation method, it is characterised in that: electrochemistry region is made to be in the mixture of substance A and substance B In, so that the substance A is separated into electronics at the electrochemistry region, exports electronics from the electrochemistry region, make electronics Importing returns to the electrochemistry region, and electric energy or electric from outer absorption is externally provided on the channel of export and/or the importing of electronics Can, so persistently realize the normality of work；

Or, being in electrochemistry region in the mixture of substance A and substance B, punish the substance A in the electrochemistry region It from electronics, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in the export of electronics And/or electric energy is externally provided on the channel imported or from outer absorption electric energy, controls the step that electronics imports and exports and realizes and stablize work Make, so persistently realizes the normality of work.

9. a kind of electrochemical reaction implementation method, it is characterised in that: electrochemistry region is made discontinuously to be in the mixed of substance A and substance B It closes in object, the electronics for being separated into the substance A at the electrochemistry region is exported from the electrochemistry region, leads electronics Enter to return to the electrochemistry region, electric energy externally provided on the channel of export and/or the importing of electronics or from outer absorption electric energy, So persistently realize the normality of work；

Or, being in electrochemistry region discontinuously in the mixture of substance A and substance B, make the substance A in the electrochemistry region The electronics that place is separated into is exported from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in the export of electronics And/or electric energy is externally provided on the channel imported or from outer absorption electric energy, controls the step that electronics imports and exports and realizes and stablize work Make, so persistently realizes the normality of work.

10. a kind of electrochemical reaction implementation method, it is characterised in that: electrochemistry region is made discontinuously to be in the mixed of substance A and substance B It closes in object, so that the substance A is separated into electronics at the electrochemistry region, export electronics from the electrochemistry region, make Electronics importing returns to the electrochemistry region, electric energy is externally provided on the channel of export and/or the importing of electronics or from outer suction Electric energy is received, so persistently realizes the normality of work；

Or, being in electrochemistry region discontinuously in the mixture of substance A and substance B, make the substance A in the electrochemistry region Place is separated into electronics, exports electronics from the electrochemistry region, so that electronics importing is returned to the electrochemistry region, in electronics Electric energy is externally provided in export and/or the channel imported or from outer absorption electric energy, controls the step that electronics imports and exports and realizes surely Fixed work, so persistently realizes the normality of work.

11. the electrochemical reaction implementation method as described in any one of claims 1 to 4, it is characterised in that: in the substance A and Inert substance and/or dead band duration are inserted between the substance B.

12. the electrochemical reaction implementation method as described in any one of claims 1 to 10, it is characterised in that: electronics export and/ Or during importing, use electro ultrafiltration；Or, using capacitor, DC power supply, friendship during electronics exports and/or imports Galvanic electricity source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, Electric field, oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its Four conjunctions, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunctions, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction.

13. electrochemical reaction implementation method as claimed in claim 11, it is characterised in that: in the mistake that electronics is exported and/or imported Cheng Zhong uses electro ultrafiltration；Or, using capacitor, DC power supply, AC power source, friendship during electronics exports and/or imports Variable power source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillation Circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, Its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 it Conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction.

14. the electrochemical reaction implementation method as described in any one of claims 1 to 10 and 13, it is characterised in that: electric to participating in The region of chemical reaction applies electro ultrafiltration, so that the substance for participating in electrochemical reaction is difficult to directly carry out redox reaction.

15. electrochemical reaction implementation method as claimed in claim 11, it is characterised in that: applied to the region for participating in electrochemical reaction Power-up effect, so that the substance for participating in electrochemical reaction is difficult to directly carry out redox reaction.

16. electrochemical reaction implementation method as claimed in claim 12, it is characterised in that: applied to the region for participating in electrochemical reaction Power-up effect, so that the substance for participating in electrochemical reaction is difficult to directly carry out redox reaction.

17. the electrochemical reaction implementation method as described in any one of claims 1 to 10 and 13 and 15 and 16, it is characterised in that: It is work normality that export of the electronics between the electrochemistry region and electric conductor, which imports,.

18. electrochemical reaction implementation method as claimed in claim 11, it is characterised in that: electronics is in the electrochemistry region and leads It is work normality that export between electric body, which imports,.

19. electrochemical reaction implementation method as claimed in claim 12, it is characterised in that: electronics is in the electrochemistry region and leads It is work normality that export between electric body, which imports,.

20. electrochemical reaction implementation method as claimed in claim 14, it is characterised in that: electronics is in the electrochemistry region and leads It is work normality that export between electric body, which imports,.