CN109616407A - The preparation method of the SiC-TVS device of high-power electromagnetic pulse protection - Google Patents

The preparation method of the SiC-TVS device of high-power electromagnetic pulse protection Download PDF

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Publication number
CN109616407A
CN109616407A CN201811515536.1A CN201811515536A CN109616407A CN 109616407 A CN109616407 A CN 109616407A CN 201811515536 A CN201811515536 A CN 201811515536A CN 109616407 A CN109616407 A CN 109616407A
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sic
tvs
preparation
tvs device
electromagnetic pulse
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Inventor
张耀辉
李跃波
杨杰
黄刘宏
何为
熊久良
潘征
闫民华
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National Academy of Defense Engineering of PLA Academy of Military Science
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National Academy of Defense Engineering of PLA Academy of Military Science
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/0445Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising crystalline silicon carbide
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
    • H01L29/0603Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by particular constructional design considerations, e.g. for preventing surface leakage, for controlling electric field concentration or for internal isolations regions
    • H01L29/0607Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by particular constructional design considerations, e.g. for preventing surface leakage, for controlling electric field concentration or for internal isolations regions for preventing surface leakage or controlling electric field concentration
    • H01L29/0611Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by particular constructional design considerations, e.g. for preventing surface leakage, for controlling electric field concentration or for internal isolations regions for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse biased devices
    • H01L29/0615Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by particular constructional design considerations, e.g. for preventing surface leakage, for controlling electric field concentration or for internal isolations regions for preventing surface leakage or controlling electric field concentration for increasing or controlling the breakdown voltage of reverse biased devices by the doping profile or the shape or the arrangement of the PN junction, or with supplementary regions, e.g. junction termination extension [JTE]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
    • H01L29/0684Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape, relative sizes or dispositions of the semiconductor regions or junctions between the regions
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66053Multistep manufacturing processes of devices having a semiconductor body comprising crystalline silicon carbide
    • H01L29/6606Multistep manufacturing processes of devices having a semiconductor body comprising crystalline silicon carbide the devices being controllable only by variation of the electric current supplied or the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched, e.g. two-terminal devices

Abstract

The preparation method of the SiC-TVS device of high-power electromagnetic pulse protection, the present invention uses wide bandgap semiconductor SiC material, it is designed using NPN structure, the SiC-TVS device is prepared using both-end NPN structure, the doping concentration and thickness parameter in the area middle layer P are determined by the method for DC characteristic emulation and fast rise time impulse response emulation, for the electric field concentration effect for alleviating N+ anode area edge, achieve the purpose that extend main knot depletion region using knot terminal extension JTE technology, after the preparation of SiC device processing step, after tested, the device is in response speed, through-current capability, Si-TVS device similar in specification is significantly better than in hot operation characteristic, it is with a wide range of applications in high-temperature work environment and high-power electromagnetic pulse protection field.

Description

The preparation method of the SiC-TVS device of high-power electromagnetic pulse protection
Technical field
The present invention relates to high-power electromagnetic pulse devices to protect field, and in particular to a kind of high-power electromagnetic pulse protection The preparation method of SiC-TVS device.
Background technique
Known, with the development of Pulse Power Techniques, the safety of high-power electromagnetic pulse pair electronic information equipment is constituted It seriously threatens.Surge impact is one of the important model of high-power electromagnetic impulse impairments electronic information equipment, and electromagnetic pulse can It is coupled on the power supply line and communication line of electronic equipment and generates surge energy, first device can be caused by entering electronic equipment internal through conduction Part and circuit damage, the danger for making important electronic information equipment face interference, even damage.For the conduction of electronic information equipment Harassing and wrecking protection causes more and more attention.
Surge protective device is the important method for inhibiting equipment conduction interference, and TVS device is most fast temporary as responding at present State protective device has many advantages, such as that fast response time, clamp voltage are accurate.Current TVS device is mostly Si sill, in lightning protection There is relatively broad application in field.Compared with thunder and lightning, the harassing and wrecking waveform that high-power electromagnetic pulse couples on cable, radio-frequency component More, there is faster rising edge, wherein nuclear electromagnetic pulse is several nanoseconds, and ultra wide band is magnitude of subnanosecond in time domain.Si-TVS Device is limited to own material properties, will appear voltage overshoot phenomenon in fast rise time pulse protection, has seriously affected to rear end The protection effect of equipment.
In addition, Si-TVS device mostly uses multiple low-voltages small for the device of high voltage grade and big through-current capability The mode of through-flow grade devices in series is designed, and the junction capacity and knot inductance that will result in device itself in this way increase, to device Part response speed affects greatly.For some special high temperature application environments, such as in the enging cabin of automobile, aircraft, Higher leakage current also limits its normal use etc. to Si-TVS at high temperature.
Summary of the invention
To overcome deficiency present in background technique, the present invention provides a kind of SiC- of high-power electromagnetic pulse protection The preparation method of TVS device, the present invention prepare SiC-TVS device using SiC material, and effective solution Si-TVS device is in height Response speed is slower in power electromagnetic pulse protection, and through-current capability is poor, and the larger problem of leakage current under high temperature, is high power Electromagnetic conductive harassing and wrecking protection provides new device selection scheme.
To realize that goal of the invention as described above, the present invention use technical solution as described below:
A kind of preparation method of the SiC-TVS device of high-power electromagnetic pulse protection, the preparation method use broad stopband first Semiconductor SiC material makes SiC-TVS device, and SiC-TVS device is prepared using both-end NPN structure, emulated by DC characteristic Determine the doping concentration and thickness parameter in the area middle layer P, with the method for fast rise time impulse response emulation to alleviate the anode region N+ side The electric field concentration effect of edge uses knot terminal extension JTE technology to extend main knot depletion region, walks by SiC-TVS device technology After rapid preparation, it is packaged using SMB form and contrast test.
The preparation method of the SiC-TVS device of the high-power electromagnetic pulse protection, the SiC-TVS device are both-end NPN structure, design cathodic region N+ are SiC material conductive substrates, and with a thickness of 350 μm, anode region N+ is surface epitaxial layer, thickness It is 0.5 μm, the doping concentration value of cathodic region N+ and anode region N+ are 1 × 1019 cm-3, exhausting when TVS break-through is guaranteed with this Occur mainly in the low-doped area P.
The preparation method of the SiC-TVS device of the high-power electromagnetic pulse protection, extends JTE technology by knot terminal The electric field concentration effect of N+ anode area edge is effectively relieved, by way of ion implanting, in the highly doped main knot side N+ Introduce that a coupled doping type is identical but the lower area N- of doping concentration, to reach the mesh for extending main knot depletion region , so as to improve the breakdown voltage of device, improve the influence of the electric leakage of the device surface as caused by extension tablet quality.
The preparation method of the SiC-TVS device of the high-power electromagnetic pulse protection, the SiC-TVS device preparation Processing step successively include epitaxial material preparation, SiC wafer RCA cleaning, shallow slot mesa mesa etch, JTE terminal structure formed, End ring structure formed, ion implanting activation annealing, sacrifice oxidation and thermal oxide passivation, cathode and an anode Ohmic contact preparation, Second level passivation, electrode thickeies and polyimide passivation.
Using technical solution as described above, the present invention has superiority as described below:
The present invention has given full play to that SiC material forbidden bandwidth is wide, electronics saturation drift velocity is high, critical breakdown strength is high, thermal conductivity The high advantage of rate, under sub- ns impulses injection, the response speed and residual voltage level of SiC-TVS device will be considerably better than Si- TVS device, under the injection of typical 10/1000 μ s surge pulse of thunder and lightning, SiC-TVS device shows more stronger than Si-TVS Through-current capability, when device is close to when burning, the through-flow multiple of shallow-trench isolation JTE type SiC-TVS has reached the several times of Si-TVS, together When, SiC-TVS device has preferable high temperature operation capability, and under 150 DEG C of high temperature, SiC-TVS ratio Si-TVS electric leakage is low multiple The order of magnitude, SiC-TVS device have lower junction capacity, the about a quarter of same package area Si-TVS device, determine SiC-TVS can preferably be applied in the higher surge protection circuit design of working frequency.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention;
Fig. 2 is the SiC-TVS device dynamic emulation that fast pulse injects lower different parameters;
Fig. 3 is the device architecture with terminal structure and exhausts signal;
Fig. 4 is the processing step of shallow-trench isolation JTE type SiC-TVS;
Fig. 5 is the shallow-trench isolation JTE type SiC-TVS device forward mode I-V test result that preparation finishes;
Fig. 6 is the test of shallow-trench isolation JTE type SiC-TVS ultra-wide degree impulses injection;
Fig. 7 is the contrast test that shallow-trench isolation JTE type SiC-TVS and Si-TVS is injected in 10/1000 μ s lightening pulse;
Fig. 8 is shallow-trench isolation JTE type SiC-TVS and Si-TVS I-V characteristic contrast test under high temperature environment.
Specific embodiment
The present invention can be explained in more detail by the following examples, the invention is not limited to the following examples;
A kind of preparation method of the SiC-TVS device of high-power electromagnetic pulse protection, the preparation in conjunction with described in attached drawing 1~8 Method uses wide bandgap semiconductor SiC material to make SiC-TVS device first, and SiC-TVS device uses both-end NPN structure system It is standby, determine that the doping concentration in the area middle layer P and thickness are joined by the method for DC characteristic emulation and fast rise time impulse response emulation Number uses knot terminal extension JTE technology to extend main knot depletion region, warp for the electric field concentration effect for alleviating N+ anode area edge After crossing the preparation of SiC-TVS device process steps, it is packaged using SMB form and contrast test;The SiC-TVS device is double NPN structure is held, design cathodic region N+ is SiC material conductive substrates, and with a thickness of 350 μm, anode region N+ is surface epitaxial layer, thick Degree is 0.5 μm, and the doping concentration value of cathodic region N+ and anode region N+ are 1 × 1019 cm-3, consumption when guaranteeing TVS break-through with this The low-doped area P is occurred mainly in the greatest extent;Further, JTE technology is extended by knot terminal N+ anode area edge is effectively relieved Electric field concentration effect introduces a coupled doping in the highly doped main knot side N+ by way of ion implanting Type is identical but the lower area N- of doping concentration, to achieve the purpose that extend main knot depletion region, so as to improve the breakdown potential of device Pressure improves the influence of the electric leakage of the device surface as caused by extension tablet quality.
Further, the processing step of SiC-TVS device preparation successively include epitaxial material prepare, SiC wafer RCA it is clear It washes, shallow slot mesa mesa etch, JTE terminal structure are formed, cut-off ring structure is formed, ion implanting activation annealing, sacrifice oxidation And thermal oxide passivation, the preparation of cathode and an anode Ohmic contact, second level passivation, electrode thickening and polyimide passivation, it needs to illustrate The processing step for being the preparation of SiC-TVS device and SMB form to be packaged with contrast test be the prior art, simultaneously because It is not the emphasis that the present invention protects, therefore does not do tired in detail state to its particular content.
Further, using the preparation of NPN structure, working principle is not simple by the two-way SiC-TVS as shown in Figure 1: The avalanche breakdown of PN junction, but with the increase of reverse bias, the area middle layer P constantly exhausts, and when the area P fully- depleted, device, which reaches, wears Logical state, can make high current pass through at this time.Pass-through state is relatively stable compared to avalanche condition.The punch through voltage of device is big The small doping and thickness depending on the area P.Therefore, intend being required according to direct current target voltage and dynamic nanosecond and subnanosecond pulse response Obtain the structural parameters in the area middle layer P.
Design cathodic region N+ is SiC material conductive substrates, and thickness is thicker (350 μm of representative value);Anode region N+ is outside surface Prolong layer, thinner thickness (0.5 μm of representative value).The area Liang Ge N+ be it is highly doped (typical concentration value be 1 × 1019 cm-3), it is protected with this Exhausting when demonstrate,proving TVS break-through occurs mainly in the low-doped area P.
Consider the design of P plot structure parameter.Since identical target can be achieved in different doping concentrations and thickness combination Punch through voltage, and different doping concentrations and thickness combination influence the RC parameter of device, and then the TVS dynamic for influencing device is rung Answer characteristic.Therefore, other than in addition to the DC voltage the considerations of, it is also necessary to which be closely connected TVS dynamic response characteristic, finally to determine the area P Structural parameters.
It is illustrated in figure 2 the SiC-TVS device dynamic simulation result that fast pulse injects lower different parameters, specific method is to adopt With TCAD software, dynamic simulation research is carried out to several groups of typical area P parameters.Test circuit is that surge pulse is injected into protector Part end, protective device rear end are grounded by series resistance, and series impedance is 50 Ω.
By test result it is found that the response characteristic of device is this it appears that device for given fast pulse pumping signal The influence of part parasitic capacitance.Device area is the key factor for influencing parasitic capacitance;When extension layer parameter is mixed towards big thickness, gently When miscellaneous direction changes, the response signal amplitude of same area device increases;When thickness is very big, doping is very low, device is to excitation Signal cannot make the response of clamper clipping.Simulation result more than comprehensive comparison, number 1 the area P parameter (i.e. 3.2 μm of thickness, Doping concentration 5 × 1016 cm-3) response signal is optimal from clamper Limiting effect.It is also used in the development of practical devices The area the P parameter of number 3 is used for the Experimental comparison of structure design.
As shown in figure 3, extending JTE technology using knot terminal the electric field concentration effect of N+ anode area edge is effectively relieved. JTE technology introduces a coupled doping in the highly doped main knot side N+ generally by the mode of ion implanting Type is identical but the lower area N- of doping concentration, to achieve the purpose that extend main knot depletion region.One suitable JTE N- of doping Area will gradually be exhausted with the increase of device reverse bias, and the ionized donor impurity in the area N- becomes effective additional charge, be made Winner ties intensive equipotential lines that edge is formed due to curvature effect surface extension outward, alleviates the electric field at this and concentrates and imitates It answers, therefore the breakdown voltage of device is improved.
It is as described in Figure 4 the processing step of SiC-TVS device preparation, device preparation technology includes standard RCA clean, shallow slot Mesa mesa etch, JTE terminal structure are formed, cut-off ring structure is formed, ion implanting activation annealing, sacrifice oxidation and thermal oxide Passivation, the preparation of cathode and an anode Ohmic contact, second level passivation, electrode thicken, polyimide passivation.
The shallow-trench isolation JTE type SiC-TVS device sample and device forward direction Working mould finished as described in Figure 5 for preparation The basic I-V electrology characteristic of formula, is sampled as a test cell.As can be seen that under the conditions of the electric current instrument maximum current limliting of 8 mA, Device has very low leakage current under off-state, and sharp keen snowslide break-through trend is presented in I-V characteristic, and in unit device one Cause property is preferable, which reflects preparing by device structure design and process optimization, realizes good SiC TVS diode basis Electrology characteristic, the punch through voltage of the device concentrate between 140~190 V.
Test result for the device under ultra-wideband pulse injection as described in Figure 6, which can inject It rises along being 180 ps or so, pulse halfwidth is the pulse signal of 220 ps, and pulse voltage amplitude is adjustable less than 3 kV.It is right SiC-TVS device carries out the encapsulation of SMB form, randomly selects three groups of devices and is designated as #1-1, #1-9, #1-14, the input of registering device Voltage and residual voltage, as shown in table 1.
1 shallow-trench isolation JTE type SiC-TVS device ultra-wideband pulse protection effect of table
As shown in table 1, which can play protective action to the protective device that rising edge is 180 ps, show the sound of the device Answer speed advantage.The reason is that compared with Si, the critical breakdown strength of SiC material is higher caused by the material advantage of SiC, Drift layer thickness and active region area are significantly less than corresponding Si device, while the electronics saturation drift velocity of SiC is higher, reflection There is faster response speed on device.
It is as described in Figure 7 test result of the device under 10/1000 μ s lightning surge impulses injection, selects close PN junction Junction area and the Si-TVS device (SMA6J130CA) of voltage class compare.Wherein the junction area of SiC-TVS device is 1.1 ×1.1mm2, the junction area of Si-TVS device (SMA6J130CA) is 1.3 × 1.3mm2
It is gradually increased input voltage, the residual voltage of registering device and passes through electric current.For Si-TVS device, device handbook In for IppNumerical value carried out test, it is right for convenience of comparing since device handbook test number is there are certain allowance Si-TVS device takes the I of standardppMultiple test its can by maximum tolerance electric current.SMA6J130CA device is 10/1000 I under μ s waveformPP For 2.9A.Shallow-trench isolation JTE type SiC-TVS device lightning surge test result is as shown in table 2, Si-TVS device Part (SMA6J130CA) test result is as shown in table 3.
2 shallow-trench isolation JTE type SiC-TVS device of table, 10/1000 μ s protection against lightning surge characteristic test
The test of 3 SMA6J130CA device of table, 10/1000 μ s maximum surge tolerance
It can be seen from contrast test data under the injection of 10/1000 μ s surge pulse, SiC-TVS device has preferable electricity Pressing tongs position and protection effect.Importantly, SiC-TVS device, which is shown, compares Si-TVS in global input voltage range Stronger through-current capability: when device is close to when burning, the through-flow multiple of shallow-trench isolation JTE type SiC-TVS has reached the 4 of Si-TVS Times.This test result reflected SiC-TVS have the advantages that rigidity high current density characteristic this.
It is as described in Figure 8 comparison I-V test result of the SiC-TVS and Si-TVS in high temperature DC test system.In order to With test macro requirement, extra soldered draws long pin at SMB encapsulation SiC-TVS external electrode pin.From contrast test result As can be seen that the high temperatures typical electric leakage of SiC-TVS is about hundred pico-ampere levels (~10 under 150 DEG C of high temperature-10A), Si-TVS production The high temperatures typical electric leakage of product is microampere order (~10-6A), low 4 orders of magnitude of SiC-TVS ratio Si-TVS electric leakage.Low drain under high temperature Electricity is the reason is that, broad stopband SiC material has extremely low intrinsic carrier concentration (19 orders of magnitude lower than Si material), this is significantly The intrinsic excitation temperature threshold of SiC device is reduced, so that device still is able to keep the blocking characteristics of Low dark curient at high temperature, this The high-temperature stable ability to work of SiC-TVS will be greatly improved.
Part not in the detailed description of the invention is the prior art.
The embodiment selected herein to disclose goal of the invention of the invention, is presently considered to be suitable, still, It is to be understood that the present invention is intended to include all changes and improvement that all belong to the embodiment in this design and invention scope.

Claims (4)

1. a kind of preparation method of the SiC-TVS device of high-power electromagnetic pulse protection, it is characterized in that: the preparation method is first SiC-TVS device is made using wide bandgap semiconductor SiC material, SiC-TVS device is prepared using both-end NPN structure, by straight The method of properties of flow emulation and fast rise time impulse response emulation determines the doping concentration and thickness parameter in the area middle layer P, to alleviate N The electric field concentration effect of+anode area edge uses knot terminal extension JTE technology to extend main knot depletion region, by SiC-TVS device After the preparation of part processing step, it is packaged using SMB form and contrast test.
2. the preparation method of the SiC-TVS device of high-power electromagnetic pulse protection according to claim 1, it is characterized in that: The SiC-TVS device is both-end NPN structure, and design cathodic region N+ is SiC material conductive substrates, with a thickness of 350 μm, anode Area N+ is surface epitaxial layer, and with a thickness of 0.5 μm, the doping concentration value of cathodic region N+ and anode region N+ are 1 × 1019 cm-3, with This guarantees that exhausting when TVS break-through occurs mainly in the low-doped area P.
3. the preparation method of the SiC-TVS device of high-power electromagnetic pulse protection according to claim 1, it is characterized in that: The electric field concentration effect of N+ anode area edge is effectively relieved by knot terminal extension JTE technology, by way of ion implanting, The identical but lower area N- of doping concentration in highly doped N+ one coupled doping type of main knot side introducing, to reach Improve the device table as caused by extension tablet quality to the purpose for extending main knot depletion region so as to improve the breakdown voltage of device The influence of face electric leakage.
4. the preparation method of the SiC-TVS device of high-power electromagnetic pulse protection according to claim 1, it is characterized in that: The processing step of the SiC-TVS device preparation successively includes that epitaxial material prepares, SiC wafer RCA is cleaned, shallow slot mesa table top Etching, JTE terminal structure are formed, cut-off ring structure is formed, ion implanting activation annealing, sacrifice oxidation and thermal oxide passivation, yin Pole and anode ohmic contact preparation, second level passivation, electrode thickeies and polyimide passivation.
CN201811515536.1A 2018-12-12 2018-12-12 The preparation method of the SiC-TVS device of high-power electromagnetic pulse protection Pending CN109616407A (en)

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