CN109593319B - 用于abs塑料的阻燃剂、阻燃abs塑料及其制备方法 - Google Patents
用于abs塑料的阻燃剂、阻燃abs塑料及其制备方法 Download PDFInfo
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- CN109593319B CN109593319B CN201811518143.6A CN201811518143A CN109593319B CN 109593319 B CN109593319 B CN 109593319B CN 201811518143 A CN201811518143 A CN 201811518143A CN 109593319 B CN109593319 B CN 109593319B
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- abs plastic
- flame retardant
- lignin
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- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title claims abstract description 140
- 239000003063 flame retardant Substances 0.000 title claims abstract description 109
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 105
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 title description 8
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 title description 5
- 229920003023 plastic Polymers 0.000 title description 2
- 239000004033 plastic Substances 0.000 title description 2
- 229920005610 lignin Polymers 0.000 claims abstract description 106
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000002253 acid Substances 0.000 claims abstract description 51
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 48
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 34
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 34
- 238000010438 heat treatment Methods 0.000 claims abstract description 32
- 238000002156 mixing Methods 0.000 claims abstract description 26
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 24
- 239000004202 carbamide Substances 0.000 claims abstract description 20
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000001816 cooling Methods 0.000 claims abstract description 16
- 238000001035 drying Methods 0.000 claims abstract description 16
- 238000001914 filtration Methods 0.000 claims abstract description 16
- 150000000703 Cerium Chemical class 0.000 claims abstract description 13
- 239000000376 reactant Substances 0.000 claims abstract description 11
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 7
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 7
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 claims description 12
- OZECDDHOAMNMQI-UHFFFAOYSA-H cerium(3+);trisulfate Chemical compound [Ce+3].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OZECDDHOAMNMQI-UHFFFAOYSA-H 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims 3
- PGJHGXFYDZHMAV-UHFFFAOYSA-K azanium;cerium(3+);disulfate Chemical compound [NH4+].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O PGJHGXFYDZHMAV-UHFFFAOYSA-K 0.000 claims 1
- HKVFISRIUUGTIB-UHFFFAOYSA-O azanium;cerium;nitrate Chemical compound [NH4+].[Ce].[O-][N+]([O-])=O HKVFISRIUUGTIB-UHFFFAOYSA-O 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 abstract description 3
- 229920002223 polystyrene Polymers 0.000 abstract description 3
- 238000003756 stirring Methods 0.000 description 40
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 30
- 238000001125 extrusion Methods 0.000 description 30
- VZDYWEUILIUIDF-UHFFFAOYSA-J cerium(4+);disulfate Chemical compound [Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O VZDYWEUILIUIDF-UHFFFAOYSA-J 0.000 description 27
- 229910000355 cerium(IV) sulfate Inorganic materials 0.000 description 27
- 230000003179 granulation Effects 0.000 description 16
- 238000005469 granulation Methods 0.000 description 16
- 239000000919 ceramic Substances 0.000 description 11
- 229910052573 porcelain Inorganic materials 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- XMPZTFVPEKAKFH-UHFFFAOYSA-P ceric ammonium nitrate Chemical compound [NH4+].[NH4+].[Ce+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O XMPZTFVPEKAKFH-UHFFFAOYSA-P 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- OKJMLYFJRFYBPS-UHFFFAOYSA-J tetraazanium;cerium(4+);tetrasulfate Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OKJMLYFJRFYBPS-UHFFFAOYSA-J 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 229920001276 ammonium polyphosphate Polymers 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F289/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/40—Introducing phosphorus atoms or phosphorus-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H6/00—Macromolecular compounds derived from lignin, e.g. tannins, humic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
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CN201811518143.6A CN109593319B (zh) | 2018-12-12 | 2018-12-12 | 用于abs塑料的阻燃剂、阻燃abs塑料及其制备方法 |
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CN201811518143.6A CN109593319B (zh) | 2018-12-12 | 2018-12-12 | 用于abs塑料的阻燃剂、阻燃abs塑料及其制备方法 |
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CN109593319A CN109593319A (zh) | 2019-04-09 |
CN109593319B true CN109593319B (zh) | 2021-06-29 |
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CN112175404B (zh) * | 2020-10-29 | 2022-05-24 | 浙江农林大学 | 一种竹炭基高阻燃膨胀型协效体系的制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1824683A (zh) * | 2006-02-05 | 2006-08-30 | 福州大学 | 反应性挤出法制备高沸醇木质素接枝共聚物的方法 |
JP2010254754A (ja) * | 2009-04-22 | 2010-11-11 | Shin-Etsu Chemical Co Ltd | 有機樹脂難燃化用添加剤、難燃性樹脂組成物及びその成形品 |
CN104371116A (zh) * | 2014-11-04 | 2015-02-25 | 南京林业大学 | 一种木质素基膨胀型阻燃剂的制备方法和应用 |
CN106543634A (zh) * | 2016-11-25 | 2017-03-29 | 西华大学 | 一种阻燃abs复合材料及其制备方法 |
CN108003640A (zh) * | 2017-12-01 | 2018-05-08 | 浙江农林大学 | 木质素为炭源的膨胀型阻燃剂生产方法 |
CN108659228A (zh) * | 2018-04-25 | 2018-10-16 | 中南林业科技大学 | 一种改性木质素阻燃剂及其制备方法 |
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2018
- 2018-12-12 CN CN201811518143.6A patent/CN109593319B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1824683A (zh) * | 2006-02-05 | 2006-08-30 | 福州大学 | 反应性挤出法制备高沸醇木质素接枝共聚物的方法 |
JP2010254754A (ja) * | 2009-04-22 | 2010-11-11 | Shin-Etsu Chemical Co Ltd | 有機樹脂難燃化用添加剤、難燃性樹脂組成物及びその成形品 |
CN104371116A (zh) * | 2014-11-04 | 2015-02-25 | 南京林业大学 | 一种木质素基膨胀型阻燃剂的制备方法和应用 |
CN106543634A (zh) * | 2016-11-25 | 2017-03-29 | 西华大学 | 一种阻燃abs复合材料及其制备方法 |
CN108003640A (zh) * | 2017-12-01 | 2018-05-08 | 浙江农林大学 | 木质素为炭源的膨胀型阻燃剂生产方法 |
CN108659228A (zh) * | 2018-04-25 | 2018-10-16 | 中南林业科技大学 | 一种改性木质素阻燃剂及其制备方法 |
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Inventor after: Chen Weicheng Inventor after: Shu You Inventor after: Huang Rong Inventor before: Shu You Inventor before: Huang Rong |
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Effective date of registration: 20210615 Address after: 313000 No.166, Chenda village, Xichuan village, Meishan Town, Changxing County, Huzhou City, Zhejiang Province Applicant after: Chen Weicheng Address before: No.138 Jinhai Road, Hecheng District, Huaihua City, Hunan Province Applicant before: HUNAN LYUSHEN ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20210831 Address after: 313100 No. 50, Daxiang Road, Meishan Town Industrial Park, Changxing County, Huzhou City, Zhejiang Province Patentee after: Huzhou Weiyue polymer material Co.,Ltd. Address before: 313000 No.166, Chenda village, Xichuan village, Meishan Town, Changxing County, Huzhou City, Zhejiang Province Patentee before: Chen Weicheng |