CN109566620A - A kind of bactericidal composition and its application and fungicide - Google Patents
A kind of bactericidal composition and its application and fungicide Download PDFInfo
- Publication number
- CN109566620A CN109566620A CN201811641119.1A CN201811641119A CN109566620A CN 109566620 A CN109566620 A CN 109566620A CN 201811641119 A CN201811641119 A CN 201811641119A CN 109566620 A CN109566620 A CN 109566620A
- Authority
- CN
- China
- Prior art keywords
- fungicide
- bactericidal composition
- copper complex
- oligosaccharides
- leaf spot
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 29
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 28
- 230000000855 fungicidal effect Effects 0.000 title claims abstract description 22
- 239000000417 fungicide Substances 0.000 title claims abstract description 22
- 230000001580 bacterial effect Effects 0.000 claims abstract description 29
- OICGFSUWXCJLCO-UHFFFAOYSA-N 1-ethylsulfonylsulfanylethane Chemical compound CCSS(=O)(=O)CC OICGFSUWXCJLCO-UHFFFAOYSA-N 0.000 claims abstract description 25
- 241000894006 Bacteria Species 0.000 claims abstract description 22
- 235000004936 Bromus mango Nutrition 0.000 claims abstract description 13
- 235000014826 Mangifera indica Nutrition 0.000 claims abstract description 13
- 235000009184 Spondias indica Nutrition 0.000 claims abstract description 13
- 229920001661 Chitosan Polymers 0.000 claims description 8
- 239000000470 constituent Substances 0.000 claims description 8
- 239000002552 dosage form Substances 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 230000002265 prevention Effects 0.000 claims description 3
- 239000000375 suspending agent Substances 0.000 claims description 3
- 239000004562 water dispersible granule Substances 0.000 claims description 2
- 240000007228 Mangifera indica Species 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 241001093152 Mangifera Species 0.000 abstract description 12
- 238000013329 compounding Methods 0.000 abstract description 6
- 230000001408 fungistatic effect Effects 0.000 abstract description 5
- 239000002131 composite material Substances 0.000 abstract description 2
- 239000000575 pesticide Substances 0.000 abstract description 2
- 239000000523 sample Substances 0.000 description 10
- 239000003814 drug Substances 0.000 description 6
- 239000001963 growth medium Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000001018 virulence Effects 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 3
- 230000005764 inhibitory process Effects 0.000 description 3
- 206010027146 Melanoderma Diseases 0.000 description 2
- 206010039509 Scab Diseases 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 208000025865 Ulcer Diseases 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 210000001367 artery Anatomy 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000000443 biocontrol Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 235000010603 pastilles Nutrition 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000010076 replication Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000036269 ulceration Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/08—Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to pesticide field more particularly to a kind of bactericidal composition and its application and fungicide.Bactericidal composite provided by the invention includes oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate.The present invention regard oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate compounding as bactericidal composition, has fabulous control efficiency to bacterial angular leaf spot, especially mango bacterial angular leaf spot.The fungistatic effect test of mango bacterial angular leaf spot bacterium is carried out to bactericidal composition provided by the invention, as the result is shown: median effective concentration (EC50) minimum up to 1.38, coefficient of synergism (SR) reaches as high as 2.48.
Description
Technical field
The invention belongs to pesticide field more particularly to a kind of bactericidal composition and its application and fungicide.
Background technique
Bacterial angular leaf spot, also known as bacterial black rot or burst swing disease, the tip of mainly causing harm, leaf and fruit.Do not turn green shoot
Blade of catching an illness shows pinhead-sized pore, after be extended to the small blackspot of protrusion, surrounding has yellow dizzy, and scab is in polygonal, later period
Scab is fused into irregular big blackspot, the raw lobe streak of leaf middle arteries petiole.Raw syringe needle shape black dot on pericarp at the beginning of fruit is caught an illness,
After be extended to crateriform dark brown ulceration, easily induction anthrax-bacilus, the base of a fruit corruption bacterium intrusion.
The regions following the line of the sea such as China Guangdong, Guangxi, Hainan, Fujian mango fruiting later period to autumn growth growth period meets Heavy Rain of Typhoon
It frequently attacks, causes a large amount of machinery wounds, bacterial angular leaf spot pathogenetic bacteria, which often seizes the opportunity to worm one's way into, to cause to fall ill, and it is improper such as to prevent and treat, just
Serious economic loss can be caused to orchard worker.
Summary of the invention
In view of this, the purpose of the present invention is to provide a kind of bactericidal composition and its application and fungicide, the present invention is mentioned
The bactericidal composition of confession has preferable control efficiency for bacterial angular leaf spot.
The present invention provides a kind of bactericidal compositions, including oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate.
Preferably, the oligosaccharides-copper complex is chitosan oligosaccharide-copper complex.
Preferably, the mass ratio of the oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate is (0.1~10): 1.
Preferably, the mass ratio of the oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate is (0.5~7): 1.
Preferably, the mass ratio of the oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate is 0.6:1.
The present invention provides application of the bactericidal composition described in above-mentioned technical proposal in prevention and treatment bacterial angular leaf spot.
Preferably, the bacterial angular leaf spot is mango bacterial angular leaf spot.
The present invention provides a kind of fungicide, the active constituent of the fungicide is that Claims 1 to 5 is described in any item
Bactericidal composition.
Preferably, mass content of the active constituent in fungicide is 1~20ppm.
Preferably, the dosage form of the fungicide is suspending agent, aqueous emulsion or water dispersible granules.
Compared with prior art, the present invention provides a kind of bactericidal composition and its application and fungicide.The present invention provides
Bactericidal composite include oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate.The present invention is by oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate compounding as sterilization
Composition has fabulous control efficiency to bacterial angular leaf spot, especially mango bacterial angular leaf spot.To provided by the invention
Bactericidal composition carries out the fungistatic effect test of mango bacterial angular leaf spot bacterium, as the result is shown: median effective concentration (EC50) it is minimum can
Up to 1.38, coefficient of synergism (SR) reaches as high as 2.48.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below
There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this
The embodiment of invention for those of ordinary skill in the art without creative efforts, can also basis
The attached drawing of offer obtains other attached drawings.
Fig. 1 is the digital photograph figure of bacterial clump growing state provided in an embodiment of the present invention.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
The present invention provides a kind of bactericidal compositions, including oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate.Wherein, the oligosaccharides-copper
Complex compound is preferably chitosan oligosaccharide-copper complex；The mass ratio of the oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate is preferably (0.1~10):
1, more preferably (0.5~7): 1, concretely 0.5:1,0.6:1,0.8:1,1:1,1.2:1,1.5:1,1.7:1,2:1,2.3:
1、2.5:1、2.8:1、3:1、3.2:1、3.5:1、3.7:1、4:1、4.2:1、4.5:1、4.7:1、5:1、5.2:1、5.5:1、
5.7:1、6:1、6.2:1、6.5:1、6.7:1、7:1。
The source of the oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate is not particularly limited in the present invention, can use commercial goods
Or it is prepared according to method well known to those skilled in the art.
The preparation method of the bactericidal composition is also not particularly limited in the present invention, directly mixes each raw material in proportion
Uniformly.
The present invention regard oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate compounding as bactericidal composition, to bacterial angular leaf spot, especially
Mango bacterial angular leaf spot has fabulous control efficiency.The bacillary angle spot of mango is carried out to bactericidal composition provided by the invention
The fungistatic effect of germ is tested, as the result is shown: median effective concentration (EC50) minimum up to 1.38, coefficient of synergism (SR) reaches as high as
2.48。
The present invention also provides a kind of the answering in prevention and treatment bacterial angular leaf spot of bactericidal composition described in above-mentioned technical proposal
With the especially application in biocontrol of mango bacterial angular leaf spot.Application provided by the invention is anti-using the bactericidal composition
Bacterial angular leaf spot is controlled, there is preferable control efficiency.
The present invention also provides a kind of fungicide, the active constituent of the fungicide is sterilization described in above-mentioned technical proposal
Composition.Wherein, mass content of the active constituent in fungicide is preferably 1~20ppm, concretely 1ppm,
1.25ppm、1.5ppm、2ppm、2.25ppm、2.5ppm、3ppm、4ppm、5ppm、6ppm、7ppm、8ppm、9ppm、10ppm、
12ppm, 15ppm, 18ppm or 20ppm；The dosage form of the fungicide includes but is not limited to suspending agent, aqueous emulsion or water-dispersible grain
Agent.In the present invention, other auxiliary agents or auxiliary material contained in the fungicide are not particularly limited, those skilled in the art's root
It is reasonably selected according to actual conditions.
Fungicide provided by the invention is using the bactericidal composition as active constituent, special therefore to bacterial angular leaf spot
It is not that mango bacterial angular leaf spot has fabulous control efficiency.
For the sake of becoming apparent from, it is described in detail below by following embodiment.
Embodiment
1. test strain
Mango bacterial angular leaf spot bacterium (commercially available)；
2. test medicine
20wt% chitosan oligosaccharide-copper complex raw medicine, 5wt% S-Ethyl ethylthio sulfonate raw medicine；
3. measuring fungistatic effect
3.1 plan design
Using the fungistatic effect of plate dilution assay method sample；Altogether be arranged 5 different proportions chitosan oligosaccharide-copper complex with
S-Ethyl ethylthio sulfonate compounds sample, and each sample is arranged the mass concentration gradient of 5 active constituents, respectively 20ppm, 10ppm, 5ppm,
In addition 2.5ppm, 1.25ppm are arranged single dose chitosan oligosaccharide-copper complex, single dose S-Ethyl ethylthio sulfonate, control sample clear water, amount to 36 tests
Sample, each test sample replication 3 times, the details of test sample (chitosan oligosaccharide-copper complex in table 1 as shown in table 1
Ratio with S-Ethyl ethylthio sulfonate is pure medicine ratio):
1 test sample information of table
3.2. the preparation of each test sample
Take test sample to be dissolved in aqua sterilisa in super-clean bench, be configured to concentration be 1wt% female medical fluid, constant volume 10mL,
It shakes up spare.
3.3. the preparation of drug containing tablet
The NA culture medium just to have sterilized (50mL/ bottles) is cooled to 45 DEG C or so, mother's 0.5mL medical fluid is drawn with liquid-transfering gun, adds
Enter into culture medium, after mixing inverted plate, is configured to the medicament of 20ppm, 10ppm, 5ppm, 2.5ppm, 1.25ppm concentration
Plate, every bottle of culture medium fall 3 wares.
3.4. bacterium is connect
The preparation of bacterium solution: by sterile working, the big thallus of the grain of rice is chosen in the bacterium of new culture scribing line and is dissolved in 1mL aqua sterilisa
In, it shakes up, dilution 3 × 106Times, for use, goes that the bacterium solution 30uL diluted is taken to be added in pastille culture medium to be coagulated, shake up, most
It is placed on the bacterial clump growing state cultivated in incubator and investigate plate afterwards for 24 hours.As a result as shown in Figure 1, Fig. 1 is of the invention real
The digital photograph figure of the bacterial clump growing state of example offer is provided.
3.5. DATA REASONING
After cultivating 48h.It is classified using ocular estimate by the growing state of bacterium on plate:
: without growth；
+: the growth of bacterium accounts for 1~10% on plate；
++: the growth of bacterium accounts for 11~25% on plate；
+++: the growth of bacterium accounts for 26~50% on plate；
The growth of bacterium accounts for 51% or more on ++++: plate.
3.6. test result analysis (being shown in Table 2~4)
Table 2 is using ocular estimate by the growing state statistical result of bacterium on plate
Table 3 is using ocular estimate by the statistical result of bacteria colony count (unit: a) on plate
4 regression equation of table, EC50With SR result
| Regression equation | r | EC50 | x1 | x2 | SR (synergy) | |
| A | Y=4.1292+0.8086x | 0.8738 | 11.94 | 3.47 | 11.93 | 0.29 |
| B | Y=4.8603+0.3814x | 0.9960 | 2.32 | 3.43 | 2.3243 | 1.48 |
| C | Y=4.4142+1.2546x | 0.9942 | 2.93 | 3.36 | 2.9303 | 1.15 |
| D | Y=4.6349+0.4346x | 1 | 6.92 | 3.3 | 6.9196 | 0.48 |
| E | Y=4.6274+2.6436x | 0.9468 | 1.38 | 3.22 | 1.3 | 2.48 |
| F | Y=4.5380+0.8446x | 0.7543 | 3.52 | |||
| G | Y=4.4979+1.1251x | 1.0000 | 2.79 |
By table 2 and table 3 it can be seen that high concentration 20ppm is grown almost without bacterium colony, and A and its F have a small amount of bacterium colony raw
It is long, it can be seen that E and D is stronger to the inhibition virulence of mango bacterial angular leaf spot bacterium, in relatively high concentration in compounded combination
Almost without bacterial growth, E is preferable to the inhibition of the bacterium for the sterile length of being born of 20ppm, 10ppm, 5ppm, especially compounded combination D, E,
Preferable than single dose S-Ethyl ethylthio sulfonate, from the point of view of compounded combination, S-Ethyl ethylthio sulfonate content is higher, inhibits virulence stronger, from range estimation bacterium colony growth
Situation is it is not difficult to find that D, E inhibit virulence stronger, and clump count is less, and especially the clump count of compounding E significantly lacks and compares single dose
S-Ethyl ethylthio sulfonate.
It can be seen from Table 4 that: the toxicity for compounding E is very strong, and there are SP > 1.5 to have synergistic effect, other compoundings are without synergy
Effect.Inhibition virulence sequence between each sample is successively are as follows: E > B > G > C > F > D > A.This test discovery E is optimal compounded combination
That is: chitosan oligosaccharide-copper complex: S-Ethyl ethylthio sulfonate=3:5 (mass ratio), EC50It is 1.38, effect is stronger than single dose S-Ethyl ethylthio sulfonate.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of bactericidal composition, including oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate.
2. bactericidal composition according to claim 1, which is characterized in that the oligosaccharides-copper complex is chitosan oligosaccharide-copper network
Close object.
3. bactericidal composition according to claim 1, which is characterized in that the matter of the oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate
Amount is than being (0.1~10): 1.
4. bactericidal composition according to claim 3, which is characterized in that the matter of the oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate
Amount is than being (0.5~7): 1.
5. bactericidal composition according to claim 4, which is characterized in that the matter of the oligosaccharides-copper complex and S-Ethyl ethylthio sulfonate
Amount is than being 0.6:1.
6. application of the described in any item bactericidal compositions of Claims 1 to 5 in prevention and treatment bacterial angular leaf spot.
7. application according to claim 6, which is characterized in that the bacterial angular leaf spot is mango bacterial angular leaf spot.
8. a kind of fungicide, which is characterized in that the active constituent of the fungicide, which is that Claims 1 to 5 is described in any item, to kill
Bacteria composition.
9. fungicide according to claim 8, which is characterized in that mass content of the active constituent in fungicide be
1~20ppm.
10. fungicide according to claim 8, which is characterized in that the dosage form of the fungicide be suspending agent, aqueous emulsion or
Water dispersible granules.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811641119.1A CN109566620B (en) | 2018-12-29 | 2018-12-29 | Bactericidal composition, application thereof and bactericide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811641119.1A CN109566620B (en) | 2018-12-29 | 2018-12-29 | Bactericidal composition, application thereof and bactericide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109566620A true CN109566620A (en) | 2019-04-05 |
| CN109566620B CN109566620B (en) | 2021-06-22 |
Family
ID=65932750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811641119.1A Active CN109566620B (en) | 2018-12-29 | 2018-12-29 | Bactericidal composition, application thereof and bactericide |
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| Country | Link |
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| CN (1) | CN109566620B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111084188A (en) * | 2019-12-30 | 2020-05-01 | 海南正业中农高科股份有限公司 | Composition containing amino oligosaccharide, hymexazol and ethylicin and application thereof |
| CN112655711A (en) * | 2020-12-30 | 2021-04-16 | 江苏生久农化有限公司 | Mixed pesticide for preventing and controlling sanitary pests such as mosquitoes, flies and the like and use method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101816305A (en) * | 2010-05-09 | 2010-09-01 | 海南正业中农高科股份有限公司 | Bactericide pesticide composite containing oligochitosan |
| EP2692232A1 (en) * | 2011-03-28 | 2014-02-05 | Bodegas Vega Sicilia, S.A. | Use of natural antifungal agents in order to prevent the infection of pruning wounds, grafts and lesions in woody plants by phytopathogenic fungi |
| CN103947671A (en) * | 2014-04-28 | 2014-07-30 | 牛赡光 | Chitosan oligosaccharide copper complex fungicide and application of chitosan oligosaccharide copper complex fungicide |
-
2018
- 2018-12-29 CN CN201811641119.1A patent/CN109566620B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101816305A (en) * | 2010-05-09 | 2010-09-01 | 海南正业中农高科股份有限公司 | Bactericide pesticide composite containing oligochitosan |
| EP2692232A1 (en) * | 2011-03-28 | 2014-02-05 | Bodegas Vega Sicilia, S.A. | Use of natural antifungal agents in order to prevent the infection of pruning wounds, grafts and lesions in woody plants by phytopathogenic fungi |
| CN103947671A (en) * | 2014-04-28 | 2014-07-30 | 牛赡光 | Chitosan oligosaccharide copper complex fungicide and application of chitosan oligosaccharide copper complex fungicide |
Non-Patent Citations (1)
| Title |
|---|
| 农业部农药检定所: "寡糖乙蒜素", 《农药登记公告》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111084188A (en) * | 2019-12-30 | 2020-05-01 | 海南正业中农高科股份有限公司 | Composition containing amino oligosaccharide, hymexazol and ethylicin and application thereof |
| CN112655711A (en) * | 2020-12-30 | 2021-04-16 | 江苏生久农化有限公司 | Mixed pesticide for preventing and controlling sanitary pests such as mosquitoes, flies and the like and use method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109566620B (en) | 2021-06-22 |
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