CN109548785A - Grape flower wing steinernema lure composition and its application and lure - Google Patents

Grape flower wing steinernema lure composition and its application and lure Download PDF

Info

Publication number
CN109548785A
CN109548785A CN201811413549.8A CN201811413549A CN109548785A CN 109548785 A CN109548785 A CN 109548785A CN 201811413549 A CN201811413549 A CN 201811413549A CN 109548785 A CN109548785 A CN 109548785A
Authority
CN
China
Prior art keywords
grape flower
flower wing
lure
parts
wing steinernema
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811413549.8A
Other languages
Chinese (zh)
Inventor
梅向东
王忠跃
刘永强
蔡欢欢
张开心
胡西旦·买买提
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institute of Plant Protection of Chinese Academy of Agricultural Sciences
Original Assignee
Institute of Plant Protection of Chinese Academy of Agricultural Sciences
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institute of Plant Protection of Chinese Academy of Agricultural Sciences filed Critical Institute of Plant Protection of Chinese Academy of Agricultural Sciences
Priority to CN201811413549.8A priority Critical patent/CN109548785A/en
Publication of CN109548785A publication Critical patent/CN109548785A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/02Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00Protecting plants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00Stationary means for catching or killing insects
    • A01M1/02Stationary means for catching or killing insects with devices or substances, e.g. food, pheronones attracting the insects
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N27/00Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02Acyclic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/06Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Insects & Arthropods (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of grape flower wing steinernemas for belonging to insect sex pheromone preparation technical field to trap composition and its application.The grape flower wing steinernema lure composition includes grape flower wing steinernema sex pheromone and synergist, the weight ratio of the grape flower wing steinernema and synergist is 1: (0.5-100), wherein the main component of the grape flower wing steinernema sex pheromone is (E, Z) -7, 12 carbon diene -1- alcohol acetic ester (E7 of 9-, ) and (Z) -9- dodecylene acetic acid esters (Z9-12:Ac) Z9-12:Ac, the synergist group is divided into 1-POL, hexanal, amphene, australene, nopinene, ocimenum, methyl n-heptyl ketone, ethyl palmitate, limonene, cineole, 1, 8- Cineole, ethyl butyrate, Bronyl acetate, 1, 3, 5, one or more of 7- cyclo-octatetraene.Grape flower wing steinernema lure composition provided by the invention can accurately be applied to grape flower wing steinernema detecting and reporting pest information, mass trapping, Insect pest suppression, be of great significance for comprehensive treatment grape flower wing steinernema.

Description

Grape flower wing steinernema lure composition and its application and lure
Technical field
The present invention relates to insect sex pheromone preparation technical fields, more particularly to grape flower wing steinernema lure composition And its application and lure.
Background technique
Grape flower wing steinernema Lobesia botrana (Denis et Schiffermuller), belongs to Lepidoptera (Lepidoptera), Tortricidae (Tortricidae), flower wing steinernema category (Lobesia) are a kind of a variety of warps of serious harm The worldwide pest for the plant flowers and fruit of helping, includes that our country is listed as important inward plant quarantine to have in world many countries Evil insect.Grape flower wing rouleau moth larvae can cause harm the grape fruit of grape flower, berry and maturation, the normal initiation of causing harm to fruit The generation of grape fruit disease.In addition to grape, host further includes olive, blackberry, blueberry, cherry, nectarine, persimmon and pomegranate etc..Grape The flower wing steinernema source place of production is Italy, reached all Europe, Africa northern and the western, Middle East in Asia and the Far East Area with And Some Areas of USA.2009 to 2014 grape flower wing steinernemas cause local value about 5,700,000,000 in wreaking havoc for California, USA The grape and drupe crop of dollar are on the hazard, and the grape in the U.S. is almost made to export therefore and interrupt.With international fruit trade Easy increase, the risk that grape flower wing steinernema invades China further increase, therefore in the quarantine dynamics for reinforcing inward grape While, reinforce the basic research to it, to cope with challenge of the grape flower wing steinernema to China's grape industry.
Skill is controlled as a kind of harmful organism environmentally friendly, that specificity is strong using insect pheromone prevention and treatment harmful organism Art, fast-developing at home and abroad in recent years, there are many pheromone products of pest to be widely applied at home.But it uses Grape flower wing Cydia spp. gyplure is only capable of trapping to male worm, and female adult can also continue to lay eggs, cause damages to crops such as grapes, influences The field using effect of grape flower wing Cydia spp. gyplure.Filtering out has attractive activity to the female male worm of grape flower wing steinernema Plant volatile, especially have the plant volatile of attractive activity to grape flower wing steinernema female adult, then with grape flower wing Cydia spp. gyplure carries out rational mixture and produces the lure composition for having attractive activity to the female male worm of grape flower wing steinernema, The field control effect of grape flower wing steinernema can be improved, moreover it is possible to reduce the dosage of grape flower wing steinernema sex pheromone, save About field control cost, to establish more perfect grape flower wing steinernema countermeasure system.
Summary of the invention
In view of this, it is an object of the present invention to provide a kind of grape flower wing steinernema lure composition, to reduce The dosage of pheromones, the effect for improving comprehensive treatment grape flower wing steinernema, to reduce control cost.
The object of the invention is also to provide a kind of application methods of grape flower wing steinernema lure composition, including by institute Synergist is stated to be applied in the lure containing grape flower wing steinernema sex pheromone;Or it is the synergist and grape flower wing is small It is applied in the lure of blank after volume moth sex pheromone mixing;Or the synergist is applied in the lure of blank, then will Lure containing the synergist and the collocation of grape flower wing steinernema sex pheromone use.
The object of the invention is also to provide a kind of for traping the lure of grape flower wing steinernema, and the lure contains State grape flower wing steinernema lure composition.
The object of the invention is also to provide a kind of prevention and treatment and/or the methods of monitoring grape flower wing steinernema.
Grape flower wing steinernema lure composition provided by the invention includes grape flower wing steinernema sex pheromone and collaboration The weight ratio of agent, the grape flower wing steinernema sex pheromone and synergist is 1: (0.5-100), wherein the grape flower wing is small The main component for rolling up moth sex pheromone is (E, Z) -7,9- 12 carbon diene -1- alcohol acetic ester (E7, Z9-12:Ac) and (Z) -9- Dodecylene acetic acid esters (Z9-12:Ac), the synergist group be divided into 1-POL, hexanal, amphene, australene, nopinene, Ocimenum, methyl n-heptyl ketone, ethyl palmitate, limonene, cineole, 1, 8-Cineole, ethyl butyrate, Bronyl acetate, 1,3,5, One or more of 7- cyclo-octatetraene.
Technical characterstic and advantage of the invention:
1, usage mode is flexible, and the present invention provides grape flower wing steinernema lure composition, including grape flower wing steinernema Sex pheromone and its synergist can be made synergist lure and be used cooperatively with grape flower wing steinernema sex pheromone lure core, Grape flower wing steinernema sex pheromone solution conjunction with which agent solution can be mixed, the use of lure composition lure is made;It is more Kind ingredient can be used alone with unrestricted choice, or be used in conjunction with according to the proportion, and independence is stronger;2) and only contain grape flower wing Steinernema sex pheromone and compared without the lure of its synergist, using containing grape flower wing steinernema sex pheromone and its collaboration The lure of agent ingredient shows stronger trapping activity in the grape flower wing steinernema trapping experiments in field;3) present invention provides Synergist ingredient it is cheap, can reduce production lure cost, be suitable for popularize.
Specific embodiment
To make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, to this hair Bright further description.
The requirement of reinforcement and Agricul tural Sustain able Development recently as people's environmental consciousness,
Synergist component in 1 grape flower wing steinernema lure composition of table
Synergist No. CAS Molecular formula Molecular weight
1-POL 616-25-1 C5H10O 86.13
Hexanal 66-25-1 C6H12O 100.16
Amphene 79-92-5 C10H16 136.23
Australene 80-56-8 C10H16 136.23
Nopinene 19902-08-0 C10H16 136.23
Ocimenum 13877-91-3 C10H16 136.23
Methyl n-heptyl ketone 821-55-6 C9H18O 142.24
Ethyl palmitate 628-97-7 C18H36O2 284.48
Limonene 138-86-3 C10H16 136.23
Cineole 172617-99-1 C28H38O7 486.60
1, 8-Cineole 470-82-6 C10H18O 154.25
Ethyl butyrate 203-306-4 C6H12O2 116.16
Bronyl acetate 20347-65-3 C12H20O2 196.29
1,3,5,7- cyclo-octatetraene 629-20-9 C8H8 104.14
1 synergist of embodiment is to grape flower wing steinernema sex pheromone synergistic effect
The vineyard in flakes for selecting grape variety, growing way, fertilizer and water management consistent carries out synergist pair as experimental plot The synergism test of grape flower wing steinernema sex pheromone lure core.
By 1-POL, hexanal, amphene, australene, nopinene, ocimenum, methyl n-heptyl ketone, ethyl palmitate, lemon Alkene, cineole, 1, 8-Cineole, ethyl butyrate, Bronyl acetate, 1,3,5,7- cyclo-octatetraene and grape flower wing steinernema letter Breath element is configured to the hexane solution of 500 μ g/ μ L respectively.Wherein grape flower wing steinernema sex pheromone is 99 parts (E, Z) -7,9- 12 carbon diene -1- alcohol acetic esters (E7, Z9-12:Ac) and 1 part of (Z) -9- dodecylene acetic acid esters (Z9-12:Ac) uniformly mix Gained.
A certain amount of each synergist component solution and grape flower wing steinernema sex pheromone solution are drawn with 200 μ L liquid-transfering guns It is uniformly mixed and obtains grape flower wing steinernema lure composition.The lure composition components are shown in Table 2.Lure is polyethylene material.
When field carries out trapping experiments, with thin wire by grape flower wing steinernema lure composition lure or grape flower wing Steinernema sex pheromone lure core is fixed on grape flower wing steinernema trapper, and (grape flower wing steinernema trapper is purchased from Beijing prompt Cubic Biotechnology Co., Ltd).CK1For without grape flower wing steinernema lure composition lure or grape flower wing steinernema The blank control of pheromones lure;CK2The only control of grape flower wing steinernema sex pheromone lure core;01 group to 42 groups is containing single group Divide the processing of the grape flower wing steinernema lure composition lure of synergist.Three repetitions, random alignment, phase is arranged in each processing Two trapper interval 10m of neighbour.After setting from second day, every morning records the grape flower wing steinernema quantity traped, Persistently investigate 30 days.
Test result is as shown in table 2.It is using containing grape flower wing steinernema sex pheromone synergist of the invention After lure, the trapping efficiency of sex pheromone lure core is remarkably reinforced, and the dosage of sex pheromone greatly reduces.
Field synergistic effect of 2 synergist of table to grape flower wing steinernema sex pheromone
Grape flower wing steinernema lure composition provided by the invention, which can accurately be applied to grape flower wing steinernema, supervises Survey, detecting and reporting pest information, mass trapping, Insect pest suppression are of great significance for comprehensive treatment grape flower wing steinernema.And the Portugal The preparation of grape wing steinernema lure composition, using simple, trapping capability is strong, and stability is good;Meanwhile the grape flower wing steinernema Lure composition specificity is strong, does not generate resistance, nontoxic to people and animals, environmental-friendly;Resistance is strong, is not afraid of wind, rainforest and day It shines;Lasting period is long, and control efficiency can maintain 30 days or more.
It should be understood by those ordinary skilled in the art that: the above is only a specific embodiment of the present invention, and It is not used in the limitation present invention, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done, It should be included within protection scope of the present invention.

Claims (5)

1. a kind of grape flower wing steinernema lure composition, which is characterized in that including grape flower wing steinernema sex pheromone and association The weight ratio of same agent, the grape flower wing steinernema sex pheromone and synergist is 1: (0.5-100), wherein the grape flower Wing steinernema sex pheromone is made of following components according to respective parts by weight: 12 carbon diene -1- alcohol acetic ester of (E, Z) -7,9- 95-99 parts of (E7, Z9-12:Ac), 1-5 parts of (Z) -9- dodecylene acetic acid esters (Z9-12:Ac), the synergist is by following components It is formed according to respective parts by weight: 0-9 parts of 1-POL, 0-9 parts of hexanal, 0-9 parts of amphene, 0-9 parts of australene, nopinene 0-9 Part, 0-9 parts of ocimenum, 0-9 parts of methyl n-heptyl ketone, 0-9 parts of ethyl palmitate, 0-9 parts of limonene, 0-9 parts of cineole, 1, 8-Cineole 0-9 parts, 0-9 parts of ethyl butyrate, 0-9 parts of Bronyl acetate, 0-9 parts of 1,3,5,7- cyclo-octatetraene.
2. a kind of for traping the lure of grape flower wing steinernema, which is characterized in that contain grape flower wing described in claim 1 Steinernema lure composition.
3. the application method of grape flower wing steinernema lure composition described in claim 1, which is characterized in that including will be described Synergist is applied in the lure containing grape flower wing steinernema sex pheromone;Or by the synergist and grape flower wing rouleau It is applied in the lure of blank after the mixing of moth sex pheromone;Or the synergist is applied in the lure of blank, then will be contained The lure and the collocation of grape flower wing steinernema sex pheromone for having the synergist use.
4. a kind of method of prevention and treatment and/or monitoring grape flower wing steinernema, which is characterized in that including will be described in claim 1 Grape flower wing steinernema lure composition is applied to the generating region and potential generating region of grape flower wing steinernema.
5. the method for preventing and treating according to claim 4 and/or monitoring grape flower wing steinernema, which is characterized in that the Portugal The dosage of grape wing steinernema composition is 0.1-10 milli gram/m.
CN201811413549.8A 2018-11-26 2018-11-26 Grape flower wing steinernema lure composition and its application and lure Pending CN109548785A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811413549.8A CN109548785A (en) 2018-11-26 2018-11-26 Grape flower wing steinernema lure composition and its application and lure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811413549.8A CN109548785A (en) 2018-11-26 2018-11-26 Grape flower wing steinernema lure composition and its application and lure

Publications (1)

Publication Number Publication Date
CN109548785A true CN109548785A (en) 2019-04-02

Family

ID=65867395

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811413549.8A Pending CN109548785A (en) 2018-11-26 2018-11-26 Grape flower wing steinernema lure composition and its application and lure

Country Status (1)

Country Link
CN (1) CN109548785A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114732012A (en) * 2022-04-11 2022-07-12 河南爱树科技发展有限公司 Long-acting compound attractant for grape flower-fin diamond back moth and grape penetrating fin moth and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108024529A (en) * 2015-06-11 2018-05-11 新西兰植物与食品研究所 Lure the composition and system of lepidopterous insects
CN108124866A (en) * 2016-11-30 2018-06-08 中国农业科学院植物保护研究所 Grape flower wing steinernema sex attractant and its preparation method and application

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108024529A (en) * 2015-06-11 2018-05-11 新西兰植物与食品研究所 Lure the composition and system of lepidopterous insects
CN108124866A (en) * 2016-11-30 2018-06-08 中国农业科学院植物保护研究所 Grape flower wing steinernema sex attractant and its preparation method and application

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
GIAN FRANCO ANFORA•MARCO TASIN•: "Synthetic Grape Volatiles Attr act Mated Lobesia botrana Females in Laboratory and Field Bioassays", 《J CHEM ECOL 》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114732012A (en) * 2022-04-11 2022-07-12 河南爱树科技发展有限公司 Long-acting compound attractant for grape flower-fin diamond back moth and grape penetrating fin moth and preparation method thereof

Similar Documents

Publication Publication Date Title
CN106818905A (en) A kind of cultivation Chinese herbal disinfectant and preparation method thereof
CN103271410A (en) Preparation method for all natural plant type insect prevention preservative
CN106386886A (en) Environment-friendly pesticide for vegetables, melons and fruits and preparation method thereof
CN107969443A (en) A kind of preparation method for preventing Citrus Huanglongbing pathogen medicament
CN101637172B (en) Insecticidal/acaricidal composition having lufenuron and tebufenozide
CN104273138A (en) Fruit fly trapping and killing agent and preparation method thereof
CN105494341A (en) Compound bird repelling agent containing cinnamonitrile and methyl anthranilate
CN101869108A (en) Pesticide combination containing pyriproxyfen
CN109548785A (en) Grape flower wing steinernema lure composition and its application and lure
CN109287631A (en) Soy sauce residues glyceride prevents and treats the application in miniature pest or leaf surface fungi bacteriosis preparation in preparation
CN103355326A (en) High-efficiency pesticide composition
CN104146009A (en) Composite insecticide special for fruit trees and preparation method for composite insecticide
CN108719345B (en) Origanum vulgaris essential oil preparation, preparation method and application thereof
CN103141505A (en) Film diffusing oil agent combined reagent for preventing and treating rice planthopper
CN103300074B (en) Stellera chamaejasmine compounded pesticide as well as preparation method and applications thereof
WO2011092721A9 (en) A botanical pesticide for agriculture/horticulture crops
CN104351283A (en) Pesticide for preventing and treating rice planthoppers
CN108684733A (en) A kind of plant pesticide formula
Swaminathan et al. Anti-feedant activity of some biopesticides on Henosepilachna vigintioctopunctata (F.)(Coleoptera: Coccinellidae)
CN109452278A (en) It is a kind of for preventing and treating the sex pheromone analog of grape flower wing steinernema
CN103283787A (en) Pesticide composition for farmland weed diseases and preparation method of pesticide composition
CN102217596B (en) Blended pesticide preparation of TDS and tebufenozide
CN105685115A (en) Compound disinfectant containing toona sinensis ingredients
CN105532736B (en) A kind of composition pesticide and its application
CN112640899B (en) Microsphere-containing pesticide synergist, preparation and application thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20190402

WD01 Invention patent application deemed withdrawn after publication