CN109287631A - Soy sauce residues glyceride prevents and treats the application in miniature pest or leaf surface fungi bacteriosis preparation in preparation - Google Patents
Soy sauce residues glyceride prevents and treats the application in miniature pest or leaf surface fungi bacteriosis preparation in preparation Download PDFInfo
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- CN109287631A CN109287631A CN201810995471.9A CN201810995471A CN109287631A CN 109287631 A CN109287631 A CN 109287631A CN 201810995471 A CN201810995471 A CN 201810995471A CN 109287631 A CN109287631 A CN 109287631A
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- glyceride
- soy sauce
- sauce residues
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
- C12P7/6436—Fatty acid esters
- C12P7/6445—Glycerides
- C12P7/6454—Glycerides by esterification
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- Agronomy & Crop Science (AREA)
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Abstract
The invention discloses soy sauce residues glyceride to prevent and treat the application in miniature pest or leaf surface fungi bacteriosis pesticidal preparations in preparation, and the soy sauce residues glyceride is to contain C16‑C22The glyceride of fatty acid.The present invention is using soy sauce residues glyceride as main component, add pesticidal preparations made of effective auxiliary agent, it is found through test process,, to the miniature insect such as Tetranychus urticae, diaphorina citri, panonychus citri, aedes albopictus, the control efficiency of the diseases such as Sooty mould is suitable with current mineral oil emulsion for it, and does not show phytotoxicity after multiple applications in a short time on crops, it is simple with ingredient, stable, highly-safe, insect prevention protection effect is good, the advantages of to crop without phytotoxicity.And the main component and additive of the pesticidal preparations are food-grade, and it is degradable in the environment, it is easy to the production of industrialized standard metaplasia, compared with mineral oil emulsion, there is the stronger market competitiveness.
Description
Technical field
The present invention relates to technical field of pesticide, and in particular to soy sauce residues glyceride prevents and treats miniature pest in preparation or blade face is true
Application in bacterium bacteriosis preparation.
Background technique
Environment amenable oil base pesticide belongs to physical control effect, and disease pest is low to its drug resistance, has preferable application
Prospect.But really to have the market competitiveness, it is desirable that the good drug efficacy and stabilization of pesticide, to crop without phytotoxicity, using it is simple and at
This is cheap.The mineral oil emulsion of high-quality, it is small to crop damage to the good drug efficacy and stabilization of disease pest because of processing technology level height,
It occupies a tiny space on high-end pesticide market, but since it belongs to non-renewable raw material, with high costs, application amount is limited.And
Current biological source oil, although (such as gutter oil, vegetable oil, animal oil) from a wealth of sources, its complicated component, drug effect shakiness
It is fixed, and the harmful components in oil are too many, are difficult to solve to the phytotoxicity of crop, and fine processing is at high cost, therefore, it is difficult to large area
It promotes and applies.
Soy sauce is the traditional condiment in China, and output is huge, and soy sauce residues are the wastes that sauce fermentation brewing generates,
Moisture is big, quantity is more, easy mouldy fouling, it is difficult to save, deal with improperly and will cause environmental pollution.
Summary of the invention
The object of the present invention is to provide soy sauce residues glyceride to prevent and treat miniature pest or leaf surface fungi bacteriosis agriculture in preparation
Application in medicine preparation.
The soy sauce residues glyceride main component is containing C16-C22The glyceride that fatty acid and glycerol generate.
The soy sauce residues glyceride preparation the following steps are included: the grease that will be extracted in soy sauce residues temperature be 115
~118 DEG C, vacuum degree be 0.13kPa/1mmHg under conditions of continue 40min remove volatility distill ingredient after, be down to temperature
At 50~70 DEG C, after the amounts of glycerol of the specific lipase Novozym 40086 and 2~10% (m/m) of 1~2% (m/m) is added
Sustained response is isolated when soy sauce residues acid value of lipids drops to 4mgKOH/g or less with the strainer that pore size is 100-200 mesh
Soy sauce residues glyceride.
The miniature pest includes Tetranychus urticae, panonychus citri, diaphorina citri or aedes albopictus.
The leaf surface fungi bacteriosis includes Sooty mould.
Another object of the present invention is to provide a kind of pesticidal preparations of glyceride containing soy sauce residues, as mass fraction,
Including soy sauce residues glyceride 94~95%, polyoxyethylene sorbitan monooleate 1.5~2%, polyoxyethylene sorbitol acid anhydride
Monostearate 0.5%, dehydrated alcohol 1~2%, polyvinylpyrrolidone 0.5%, xanthan gum or sodium alginate 1%.
Soy sauce residues glyceride of the invention, main component are containing C16-C22The glyceride that fatty acid and glycerol generate, to work
The harmful ingredient of object substantially reduces, and good to the control efficiency of some disease pests, and soy sauce residues glyceride is applied to Pesticidal products
Preparation, have good prospect.
Compared with prior art, the invention has the following advantages:
(1) present invention adds pesticidal preparations made of effective auxiliary agent, at test using soy sauce residues glyceride as main component
Haircut is existing, and to the miniature insect such as Tetranychus urticae, diaphorina citri, aedes albopictus and panonychus citri, the diseases such as Sooty mould are prevented
It is suitable with current mineral oil emulsion to control effect, and does not show phytotoxicity after multiple applications in a short time on crops.
(2) soy sauce residues glyceride provided by the invention is from a wealth of sources, cheap, belongs to waste recovery, is conducive to environmental protection, will
Pesticidal preparations are made in it, have ingredient simple, stable, highly-safe, insect prevention protection effect is good, the advantage small to chemical injury of crops.
And its main component and additive are food-grade, and it is degradable in the environment, it is easy to the production of industrialized standard metaplasia, with mineral oil cream
Agent is compared, low in cost, has the stronger market competitiveness.
Detailed description of the invention
Fig. 1 is the pesticidal preparations of the glyceride of the invention containing soy sauce residues and the Contrast on effect of clear water processing prevention and treatment Tetranychus urticae.
Wherein, A is clear water treated blade, and the Tetranychus urticae on blade is always in rapid activity；B is glycerol containing soy sauce residues of the invention
The pesticidal preparations of ester treated blade, the Tetranychus urticae on blade are substantially dead.
Fig. 2 is the pesticidal preparations of the glyceride of the invention containing soy sauce residues and the effect pair of clear water processing prevention and treatment diaphorina citri nymph
Than.Wherein, A is the wood louse nymph on clear water processing seedling, and B is the death of the pesticidal preparations processing of the glyceride of the invention containing soy sauce residues
Nymph.
Fig. 3 is the pesticidal preparations of the glyceride of the invention containing soy sauce residues and the effect pair of clear water processing prevention and treatment diaphorina citri adult
Than.Wherein, A is the wood louse adult on clear water processing seedling, and B is the death of the pesticidal preparations processing of the glyceride of the invention containing soy sauce residues
Adult.
Fig. 4 is the pesticidal preparations of the glyceride of the invention containing soy sauce residues and clear water handles the Contrast on effect that dark mildew morbidity is set.
Wherein, A is to spray the effect of the pesticidal preparations processing of the glyceride containing soy sauce residues of the invention after a week；B is to spray clear water processing one
Effect after week.
Specific embodiment
The following examples are further illustrations of the invention, rather than limiting the invention.
Embodiment 1
The preparation of soy sauce residues glyceride, comprising the following steps:
The grease extracted in soy sauce residues is continued under conditions of temperature is 115 DEG C, vacuum degree is 0.13kPa/1mmHg
After 40min removes volatility distillation ingredient, when temperature is down to 50 DEG C, the specific lipase of 1% (m/m) is added
Sustained response after the amounts of glycerol of Novozym40086 and 5% (m/m), when soy sauce residues acid value of lipids drops to 4mgKOH/g or less,
Soy sauce residues glyceride is isolated with the strainer that pore size is 100 mesh.
The preparation of the pesticidal preparations of the glyceride containing soy sauce residues:
(1) be formulated: by mass percentage, the pesticidal preparations of the glyceride containing soy sauce residues contain soy sauce residues glyceride 94%,
Polyoxyethylene sorbitan monooleate 2%, dehydrated alcohol 1%, is gathered polyoxyethylene sorbitan monostearate 0.5%
Vinylpyrrolidone 0.5%, xanthan gum 1%.
(2) it prepares: after sufficiently mixing with above-mentioned each components in certain proportion, obtaining the pesticidal preparations of the glyceride containing soy sauce residues.It can
To be watered 60 times (volume ratios), stir evenly spare.
Embodiment 2
The grease extracted in soy sauce residues, comprising the following steps:
The grease extracted in soy sauce residues is continued under conditions of temperature is 118 DEG C, vacuum degree is 0.13kPa/1mmHg
After 40min removes volatility distillation ingredient, when temperature is down to 70 DEG C, the specific lipase of 2% (m/m) is added
Sustained response after the amounts of glycerol of Novozym40086 and 10% (m/m), when soy sauce residues acid value of lipids drops to 4mgKOH/g or less,
Soy sauce residues glyceride is isolated with the strainer that pore size is 200 mesh.
The preparation of the pesticidal preparations of the glyceride containing soy sauce residues:
(1) be formulated: by mass percentage, the pesticidal preparations of the glyceride containing soy sauce residues contain soy sauce residues glyceride 95%,
Polyoxyethylene sorbitan monooleate 1.5%, polyoxyethylene sorbitan monostearate 0.5%, dehydrated alcohol 1%,
Polyvinylpyrrolidone 0.5%, sodium alginate 1%.
(2) it prepares: after sufficiently mixing with above-mentioned each components in certain proportion, obtaining the pesticidal preparations of the glyceride containing soy sauce residues.It can
To be watered 60 times (volume ratios), stir evenly spare.
Embodiment 3
The preparation of soy sauce residues glyceride, comprising the following steps:
The grease extracted in soy sauce residues is continued under conditions of temperature is 116 DEG C, vacuum degree is 0.13kPa/1mmHg
After 40min removes volatility distillation ingredient, when temperature is down to 60 DEG C, the specific lipase of 1.5% (m/m) is added
Sustained response after the amounts of glycerol of Novozym40086 and 2% (m/m), when soy sauce residues acid value of lipids drops to 4mgKOH/g or less,
Soy sauce residues glyceride is isolated with the strainer that pore size is 150 mesh.
The preparation of the pesticidal preparations of the glyceride containing soy sauce residues:
(1) be formulated: by mass percentage, the pesticidal preparations of the glyceride containing soy sauce residues contain soy sauce residues glyceride 94%,
Polyoxyethylene sorbitan monooleate 1.5%, polyoxyethylene sorbitan monostearate 0.5%, dehydrated alcohol 2%,
Polyvinylpyrrolidone 0.5%, sodium alginate 1%.
(2) it prepares: after sufficiently mixing with above-mentioned each components in certain proportion, obtaining the pesticidal preparations of the glyceride containing soy sauce residues.It can
To be watered 60 times (volume ratios), stir evenly spare.
Test example one, the glyceride containing soy sauce residues pesticidal preparations to the control efficiency of miniature pest
1, test material: the pesticidal preparations of the glyceride containing soy sauce residues made from embodiment 1 (are watered 60 times (volume ratios), stir
It mixes uniformly spare)；Mineral oil emulsion (mineral oil is watered 60 times (volume ratios), stir evenly to get；Its mineral oil in fluid is by method
Total SA of state provides, name of product are as follows: uncommon kingfisher)；Tetranychus urticae, panonychus citri, aedes albopictus and diaphorina citri are room
Interior propagating population, has raised 3 generations or more, does not apply any pesticide.
2, test method
(1) to the prevention and treatment of Tetranychus urticae: choosing the black nightshade that 3 Tetranychus urticaes occur, spray be watered diluted implementation respectively
The pesticidal preparations of the glyceride containing soy sauce residues made from example 1 are watered diluted mineral oil emulsion and clear water as control.Each
Handle 5 repetitions.A situation arises for the phytotoxicity of the observation Tetranychus urticae death rate and black nightshade blade for 24 hours.
(2) to the prevention and treatment of panonychus citri: choosing 3 plants of panonychus citris and serious citrus seedling occurs, investigation is complete before being administered
The initial population quantity of pawl mite, every young plant are investigated by four orientation, and 2-3 piece blade is investigated in each orientation, add up to 8-12 piece
Blade records investigation result.3 young plants spray the agriculture for being watered diluted embodiment 1 glyceride obtained containing soy sauce residues respectively later
Medicine preparation is watered diluted mineral oil emulsion and clear water as control.Same procedure investigation population quantity after a week, and with
Data are recalled before spray to compare and analyze.5 repetitions of each processing.
(3) to the prevention and treatment of diaphorina citri: choose 2 plants of citrus seedlings for having a diaphorina citri nymph, be inserted in 35cm in cylinder mould ×
35cm × 55cm, sprays the pesticidal preparations for being watered diluted embodiment 1 glyceride obtained containing soy sauce residues respectively and clear water is (right
According to), the death condition of wood louse nymph in cylinder mould is observed in 5 repetitions of each processing for 24 hours.
(4) to the prevention and treatment of aedes albopictus: selecting a cylinder mould 45cm × 45cm × 45cm, be put into aedes albopictus adult mosquito 50, hand
Sprayer is held to uniformly spraying the pesticidal preparations for being watered the glyceride containing soy sauce residues made from diluted embodiment 1, clear water in cylinder mould
For control, adult mosquito survival condition is observed afterwards for 24 hours.4 repetitions of each processing.
3, test result
(1) to the control efficiency of Tetranychus urticae: the pesticidal preparations of the glyceride provided by the invention containing soy sauce residues are to two variegated leafs
The control efficiency of mite is shown in Table 1 and Fig. 1.As can be seen from Table 1, the pesticidal preparations and mine of the glyceride provided by the invention containing soy sauce residues
Object oil emu compares, and the two, without significant difference, reaches 95% or more to the median lethal rate of Tetranychus urticae；Ratio is handled with clear water
Compared with the pesticidal preparations or mineral oil emulsion of the glyceride provided by the invention containing soy sauce residues have the median lethal rate of Tetranychus urticae
There is extremely significant difference (P < 0.01).As shown in Figure 1, the Tetranychus urticae on clear water processing rear blade is always in rapid activity, and makes
It is substantially dead with the Tetranychus urticae on the pesticidal preparations of the glyceride provided by the invention containing soy sauce residues treated blade, thus may be used
Know, the pesticidal preparations of the glyceride provided by the invention containing soy sauce residues have preferable control efficiency to Tetranychus urticae.
Control efficiency of each medicament of table 1 to Tetranychus urticae
Note: same column same letter indicates that difference is not significant (P > 0.05).
(2) to the control efficiency of panonychus citri: the pesticidal preparations of the glyceride provided by the invention containing soy sauce residues are to citrus
The control efficiency of Panonychus citri is shown in Table 2.As shown in Table 2, the pesticidal preparations of the glyceride provided by the invention containing soy sauce residues are complete to citrus
Pawl mite adult mite has extraordinary control efficiency, and lethality is up to 97.50%, suitable with the control efficiency of mineral oil, no significance difference
It is different, but compared with clear water processing, difference is extremely significant.
Control efficiency of each medicament of table 2 to panonychus citri adult mite
Note: same column same letter indicates that difference is not significant (P > 0.05).
(3) to the control efficiency of diaphorina citri: the pesticidal preparations of the glyceride provided by the invention containing soy sauce residues are to citrus wood
The control efficiency of lice is shown in Table 3, Fig. 2 and Fig. 3.As shown in Table 3, the pesticidal preparations of the glyceride provided by the invention containing soy sauce residues are to mandarin orange
Tangerine wood louse nymph has extraordinary control efficiency, and lethality is up to 99.47%, compared with clear water processing, has extremely significant difference
(P < 0.01).In addition, from figure 2 it may also be seen that the wood louse nymph through chemicals treatment, lethal effect is very good, and (Fig. 2A is at clear water
The wood louse nymph on seedling is managed, B is the dead nymph that the pesticidal preparations of the glyceride containing soy sauce residues are handled).During spray, it can fly
Adult is easy to hide tagging for medicament, but the adult sprayed application to by medicament, also can be dead immediately, see Fig. 3 (after A is clear water processing,
Wood louse adult on seedling, B are the dead adult that the pesticidal preparations of the glyceride containing soy sauce residues spray application to).
By Fig. 2 and Fig. 3 can be seen that wood louse adult after clear water processing on citrus seedling and nymph always in rapid activity, and
Using on pesticidal preparations treated the citrus seedling of the glyceride provided by the invention containing soy sauce residues wood louse adult and the big portion of nymph
Divide death, it follows that the pesticidal preparations of the glyceride provided by the invention containing soy sauce residues have preferably prevention and treatment to diaphorina citri
Effect.
Control efficiency of each medicament of table 3 to diaphorina citri nymph
(4) to the control efficiency of aedes albopictus: the pesticidal preparations of the glyceride provided by the invention containing soy sauce residues to lineae ablicantes she
The control efficiency of mosquito is shown in Table 4.As can be seen from Table 4, the pesticidal preparations of the glyceride provided by the invention containing soy sauce residues to lineae ablicantes she
Mosquito has preferable control efficiency, and lethality is up to 98%, compared with clear water processing, has extremely significant difference (P < 0.01).
Control efficiency of each medicament of table 4 to aedes albopictus
Note: P is that average value examines saliency value (double tail detections) in paired sample T test.
Test example two, the glyceride containing soy sauce residues pesticidal preparations to the control efficiency of leaf surface fungi bacteriosis
1, test material: the glyceride containing soy sauce residues made from embodiment 1 pesticidal preparations (be watered 60 times (volume ratio) it is dilute
It releases)；Mineral oil emulsion (mineral oil is watered 60 times (volume ratios), stir evenly to get；Its mineral oil in fluid is by Total France
Company provides, name of product are as follows: uncommon kingfisher)；Dark mildew is Citrus fuliginous.
2, test method
The pathogenetic mandarin tree of coal smoke is chosen, sprays be watered diluted embodiment 1 glyceride containing soy sauce residues obtained respectively
Pesticidal preparations, be watered diluted mineral oil emulsion and clear water as control.5 repetitions of each processing.Continuous observation citrus
A situation arises for the symptom of blade and phytotoxicity.
3, test result
The pesticidal preparations of the glyceride provided by the invention containing soy sauce residues are shown in Fig. 4 to the control efficiency of Citrus fuliginous.By Fig. 4
As can be seen that the pesticidal preparations of present invention glyceride containing soy sauce residues, which are sprayed dark mildew, occurs serious citrus seedling, after a week, leaf
On piece is generated without obvious coal smoke disease symptoms, and without phytotoxicity, and after using fresh water spraying, coal smoke disease symptoms are unchanged on blade, table
The pesticidal preparations of bright present invention glyceride containing soy sauce residues have preferable control efficiency to Citrus fuliginous.
The above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred embodiment is not construed as pair
Limitation of the invention, protection scope of the present invention should be defined by the scope defined by the claims..For the art
For those of ordinary skill, without departing from the spirit and scope of the present invention, several improvements and modifications can also be made, these change
It also should be regarded as protection scope of the present invention into retouching.
Claims (6)
1. soy sauce residues glyceride prevents and treats the application in miniature pest or leaf surface fungi bacteriosis pesticidal preparations in preparation.
2. application according to claim 1, which is characterized in that the main component of the soy sauce residues glyceride is containing C16-
C22The glyceride that fatty acid and glycerol generate.
3. application according to claim 2, which is characterized in that the preparation of the soy sauce residues glyceride includes following step
Rapid: the grease that will be extracted in soy sauce residues is 115~118 DEG C in temperature, and vacuum degree continues under conditions of being 0.13kPa/1mmHg
After 40min removes volatility distillation ingredient, when temperature is down to 50~70 DEG C, the specific lipase of 1~2% (m/m) is added
The amounts of glycerol sustained response of Novozym 40086 and 2~10% (m/m) drops to 4mgKOH/g or less to soy sauce residues acid value of lipids
When, soy sauce residues glyceride is isolated with the strainer that pore size is 100~200 mesh.
4. application according to claim 1 to 3, which is characterized in that the miniature pest includes Tetranychus urticae, mandarin orange
Citrus red mite, diaphorina citri or aedes albopictus.
5. application according to claim 1 to 3, which is characterized in that the leaf surface fungi bacteriosis includes bituminous coal
Disease.
6. a kind of pesticidal preparations of glyceride containing soy sauce residues, which is characterized in that as mass fraction, including soy sauce residues glyceride 94
~95%, polyoxyethylene sorbitan monooleate 1.5~2%, polyoxyethylene sorbitan monostearate 0.5%, nothing
Water-ethanol 1~2%, polyvinylpyrrolidone 0.5%, xanthan gum or sodium alginate 1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810995471.9A CN109287631B (en) | 2018-08-29 | 2018-08-29 | Application of soy sauce residue glyceride in preparation of preparation for preventing and treating micro-pests or foliar fungal and bacterial diseases |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810995471.9A CN109287631B (en) | 2018-08-29 | 2018-08-29 | Application of soy sauce residue glyceride in preparation of preparation for preventing and treating micro-pests or foliar fungal and bacterial diseases |
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| Publication Number | Publication Date |
|---|---|
| CN109287631A true CN109287631A (en) | 2019-02-01 |
| CN109287631B CN109287631B (en) | 2021-01-29 |
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|---|---|---|---|
| CN201810995471.9A Active CN109287631B (en) | 2018-08-29 | 2018-08-29 | Application of soy sauce residue glyceride in preparation of preparation for preventing and treating micro-pests or foliar fungal and bacterial diseases |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113475503A (en) * | 2021-07-28 | 2021-10-08 | 广东省科学院动物研究所 | Triolein emulsion for pesticide and application thereof |
| CN113667703A (en) * | 2021-08-05 | 2021-11-19 | 湖南省农业科学院 | Soy sauce residue glyceride, agricultural vegetable oil emulsion and preparation method and application thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113498793B (en) * | 2021-07-08 | 2022-12-09 | 广东省科学院动物研究所 | Vegetable oil and metarhizium anisopliae insecticidal composition with synergistic effect and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113475503A (en) * | 2021-07-28 | 2021-10-08 | 广东省科学院动物研究所 | Triolein emulsion for pesticide and application thereof |
| CN113475503B (en) * | 2021-07-28 | 2022-12-02 | 广东省科学院动物研究所 | Glycerol trioleate emulsion for pesticide and application thereof |
| CN113667703A (en) * | 2021-08-05 | 2021-11-19 | 湖南省农业科学院 | Soy sauce residue glyceride, agricultural vegetable oil emulsion and preparation method and application thereof |
| CN113667703B (en) * | 2021-08-05 | 2023-07-25 | 湖南省农业科学院 | Soybean sauce residue glyceride, agricultural vegetable oil emulsion, and preparation methods and applications thereof |
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| Publication number | Publication date |
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| CN109287631B (en) | 2021-01-29 |
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