CN109498484A - A kind of permanent bubble and its hair colouring methods of having hair dyed - Google Patents

A kind of permanent bubble and its hair colouring methods of having hair dyed Download PDF

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Publication number
CN109498484A
CN109498484A CN201811597943.1A CN201811597943A CN109498484A CN 109498484 A CN109498484 A CN 109498484A CN 201811597943 A CN201811597943 A CN 201811597943A CN 109498484 A CN109498484 A CN 109498484A
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dose
composition
alcohol
hair
hydrochloride
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Inventor
赵文忠
洪盛杰
林学镁
胡卫华
李洪波
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LAF INTERNATIONAL GROUP Ltd
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LAF INTERNATIONAL GROUP Ltd
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Priority to CN201811597943.1A priority Critical patent/CN109498484A/en
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783—Angiosperms [Magnoliophyta]
    • A61K8/9789—Magnoliopsida [dicotyledons]
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88—Two- or multipart kits
    • A61K2800/882—Mixing prior to application

Abstract

The invention belongs to daily chemicals fields, and in particular to a kind of permanent bubble and its hair colouring methods of having hair dyed.The present invention permanently has hair dyed bubble, includes first dose of composition for hair dying and second dose of oxidizing agent composition, furthermore between weight ratio be 20 to 60:40 to 80.First dose of composition for hair dying includes: (1) accounting for the low-carbon alcohols of first dose of composition for hair dying weight percent (similarly hereinafter) 1.05-27%, (2) anionic surfactant of 0.5-20%, (3) 1-10% nonionic surfactant, (4) antioxidant of 0.05-3%, the oxidative dyestuff of (5) 1.25-9%；(6) C of first dose of composition for hair dying weight 1-5% is accounted for14‑22Fatty alcohol；(7) chelating agent of 0.05-0.4%；(8) alkaline reagent of 1-10%.The present invention uses natural, can cooperate with the uniformity for increasing and dyeing, increase reaction time of more active matters on hair, the uniformity for color of having hair dyed is promoted.

Description

A kind of permanent bubble and its hair colouring methods of having hair dyed
Technical field
The invention belongs to daily chemicals fields, and in particular to a kind of permanent bubble product and its hair colouring methods of having hair dyed.
Technical background
Hair dyeing product is generally divided into three types, provisional hair dyeing product, semipermanent hair dyeing product and permanent dye Send out product.
Permanent hair dyeing product is a kind of oxidative coloration of hair product, comprising first dose of composition by dyes and is contained Second dose of composition of oxidant.The dyeing of permanent hair dyeing product is more lasting, therefore frequency of use also highest.Existing market The dosage form of upper permanent hair dyeing product includes pulvis, lotion, liquid, the dosage forms such as gel.
The hair dyeing product of early stage is mostly the oxidative coloration of hair product of powdery, including contain oxidized form dyes and tool There is first dose of composition of the water-soluble polymer (such as sodium carboxymethylcellulose and hydroxyethyl cellulose) of thickening power and contains There is second dose of composition of 6% or so oxidant, mixes first dose of composition and second dose of composition before hair dyeing.In short, powder The oxidized form hair dyeing product of shape needs to stir at least 3-5 minutes time before use to guarantee thickener hydration dissolution therein And it obtains certain viscosity and has hair dyed.
The oxidative coloration of hair product of liquid equally includes first dose and second dose of mixing and does not need oxidation as powdery Type hair dyeing product, which equally needs to stir the long time, to be used, but the disadvantage is that the hair dyeing product of liquid is stagnant on hair The property stayed is poor, accidentally will touch skin and clothes and affect the uniformity of dyeing.
It is respectively to contain dyes emulsifying that the characteristics of oxidative coloration of hair product of cream shape, which is first dose and second dose, The sticky lotion of state and emulsification lotion containing oxidant, are sufficiently mixed and then are applied to hair for first dose and second dose using preceding On, it increases anelasticity of the hair dye on hair and does not have to worry to flow and make skin or clothes dirty, be currently on the market The hair dyeing product of mainstream dosage form.
Although the oxidized form hair dyeing product of cream shape is the mainstream of market comsupton, the cream rinse of lotion state still has perhaps It is more it is insufficient such as, using preceding that first dose and second dose of mixing time is longer, cream rinse is coated with using comb or brush Mode of operation method on hair is controlled for applying the crucial of dye speed, dyeability and the uniformity in long hair hair dye Deng the effect that can all influence to have hair dyed.
To overcome the above deficiency, the present invention has found better solution by experiment repeatedly.Therefore mesh of the invention One of be to provide a kind of permanent hair dyeing product for being more easier hair dyeing, the characteristics of hair dyeing product is, using first dose with The stable foam that second dose of mixing generates is had hair dyed, this in paste body shape hair dyeing product by first and second doses after mixing again It is compared with comb or brush come the process of brush head hair hair dyeing, shortens the time of stirring, shorten painting of the hair dye on hair It smears the time, easy to use and high-efficient, even dyeing of having hair dyed, because hair dyeing product of the present invention is produced by first dose and second dose mixing The foaminess fast and easy that raw foam and shampoo hair washing generate, and the foam that two dosage form mixing generate makes coloring agent The uniform state of molecule is presented with oxidant, does not have to worry hair dye trickling or contamination skin or clothes during use.
Summary of the invention
The object of the present invention is to provide a kind of permanent hair dyeing bubble products.
It is a further object of the present invention to provide the methods of the product.
Of the invention is achieved in that a kind of permanent hair dyeing bubble, includes first dose of composition for hair dying and second dose Oxidizing agent composition, first dose of composition for hair dying includes:
(1) low-carbon alcohols of first dose of composition for hair dying weight percent 1.05-27% are accounted for, which is ethyl alcohol, the third two Alcohol, isopropanol and n-butanol at least one therein；
(2) anionic surfactant of first dose of composition for hair dying weight 0.5-20%, the anion surface active are accounted for Agent is selected from laruyl alcohol sodium sulfovinate, lauric alcohol sodium sulfovinate, laurel alcohol sulfuric ester potassium, laurel alcohol sulfuric ester ammonium, myristyl alcohol Sodium sulfovinate, Cetyl Alcohol sodium sulfovinate, sodium cocoyl glutamate, lauryl alcohol sodium sulfovinate, lauryl alcohol sulfuric ester ammonium are wherein At least one；
(3) first dose of composition for hair dying weight 1-10% nonionic surfactant, nonionic surfactant choosing are accounted for Lanonol, lauric alcohol polyoxyethylene ether, ethoxylated dodecyl alcohol, Cetyl Alcohol are etherified from Cocoalkyl glucosides, polyoxyethylene Polyoxyethylene ether, Brij-721, Brij, docosyl alcohol polyoxyethylene ether at least one therein；
(4) antioxidant of first dose of composition for hair dying weight 0.05-3% is accounted for, the antioxidant is sodium sulfite and South Africa Askew beans leaf extract；
(5) oxidative dyestuff of first dose of composition for hair dying weight 1.25-9% is accounted for；
(6) C of first dose of composition for hair dying weight 1-5% is accounted for14-22Fatty alcohol；
(7) chelating agent of first dose of composition for hair dying weight 0.05-0.4% is accounted for；
(8) alkaline reagent of first dose of composition for hair dying weight 1-10% is accounted for；
(9) pure water of first dose of composition for hair dying weight 12.6-87.15% is accounted for；
Second dose of oxidizing agent composition is by oxidant, stabilizer, anionic surfactant, pH adjusting agent and C14-22 Fatty alcohol；
The weight ratio of first dose of composition and second dose of composition is 20 to 60:80 to 40.
In technical solution of the present invention: oxidative dyestuff is selected from o-phenylenediamine sulfate or hydrochloride, isophthalic diammonium sulfate Or hydrochloride, to benzene diammonium sulfate or hydrochloride, N, N- bis- (2- ethoxys) is to benzene diammonium sulfate or hydrochloride, 2,4- bis- Amino-benzene oxygen alcohol sulfate salt or hydrochloride, 2- nitro-p- p-phenylenediamine sulfate or hydrochloride, Toluene-2,4-diisocyanate, 5- diamines sulphur Hydrochlorate or hydrochloride, 2,6-diaminopyridine sulfate or hydrochloride, o-aminophenol sulfate or hydrochloride, m-aminophenol Sulfate or hydrochloride, p-aminophenol sulfate or hydrochloride, -5 nitrophenol of 2- amino, 4 amino -2- hydroxy-methylbenzene sulfuric acid Salt or hydrochloride, 1- naphthols, resorcinol, Phenyl Methyl Pyrazolone 98Min, picramic acid at least one therein.
In technical solution of the present invention: the C14-22Fatty alcohol is selected from C14Alcohol, C16Alcohol, C18Alcohol, oleyl alcohol, C22Alcohol is therein extremely Few one kind.
In technical solution of the present invention: the chelating agent is selected from disodium ethylene diamine tetraacetate or tetrasodium ethylenediamine tetraacetate.
In technical solution of the present invention: the alkalizing agent is selected from ammonium hydroxide, ammonium carbonate, ammonium hydrogen carbonate, monoethanolamine, diethanol Amine, triethanolamine at least one therein.
In technical solution of the present invention: second dose of oxidizing agent composition includes to account for second dose of oxidizing agent composition weight 5- 30% oxidant, the stabilizer of 0.01-1%, the anionic surfactant of 1-20%, 0.01-1% pH adjusting agent, The C of 0.1-5%14-22The deionized water of fatty alcohol and surplus.
In technical solution of the present invention: oxidant described in second dose of oxidizing agent composition of the hair dyeing is that hydrogen peroxide is molten Liquid, SODIUM PERCARBONATE and sodium perborate at least one therein；The stabilizer is sodium stannate, antifebrin therein at least one Kind；The anionic surfactant is laruyl alcohol sodium sulfovinate and lauric alcohol sodium sulfovinate；The pH adjusting agent be phosphoric acid and Pyrophosphate at least one therein；The C14-C22Fatty alcohol is C16Alcohol.
The action method of skill of the present invention hair dyeing bubble product: first dose of composition and second dose of composition and each are prepared respectively Self-sealing saves, using it is preceding by first dose of composition and second dose of composition according to weight ratio 20 to 60:80 to 40 ratio into Row mixing is placed into the molten tank of gas or the molten filling of non-gas, is generated uniform mousse by gas punching press or air foam pump head and is steeped Foam is uniformly sprawled on hair and is stopped 5-30 minutes time, finally cleaned up with clear water by foam.
Beneficial effects of the present invention
Foam caused by foam-like hair dyeing product of the present invention can be detained 30 minutes not with when dyeing on hair It can trickle, be infected with skin and clothing.Further, since foam, which does not trickle, reduces the loss of active matter, more active matters are increased Reaction time on hair, the uniformity for color of having hair dyed can also be promoted.The present invention uses natural, not only subtracts Hair dyeing allergic phenomena can also cooperate with the uniformity for increasing and dyeing less.
A kind of permanent hair dyeing bubble product of the invention, by first dose of composition containing oxidative dyestuff and contains oxidation Second dose of composition of agent forms, by first dose and second dose of composition mixed merga pass aerosol according to a certain percentage when use Or the container with artificial air's foam pump head generates foam to have hair dyed, durable lather will not collapse and dye in use process Uniformly.
Specific embodiment
First dose of composition
Low-carbon alcohols
Low-carbon alcohols of the present invention account for first dose of composition for hair dying weight 1.05-27% of the present invention, advanced optimize as 3.1- 23%.
Low-carbon alcohols typically refer to carbon atom number and are located at the alcohol of C1-4 such as, ethyl alcohol, isopropanol, n-butanol, propylene glycol, and the third three Alcohol, low-carbon alcohols of the present invention are ethyl alcohol and propylene glycol, wherein propylene glycol accounts for first dose of composition weight 0.05-2% of the present invention, into One-step optimization is 0.1-1%, and ethyl alcohol accounts for first dose of composition weight 1-25% of the present invention, advanced optimizes as 3-22%.
Low-carbon alcohols described in first dose of composition of the invention, can reduce aqueous solution and anion table under the conditions of appropriate dosage The surface tension of face activating agent simultaneously promotes foaming capacity, prevents foam from trickling and obtains ideal foam.
Anionic surfactant
Anionic surfactant described in first dose of composition of the invention is selected from laruyl alcohol sodium sulfovinate, laruyl alcohol sulfuric acid Ester potassium, laurel alcohol sulfuric ester ammonium, myristyl alcohol sodium sulfovinate, Cetyl Alcohol sodium sulfovinate, sodium cocoyl glutamate, lauryl alcohol sulphur Acid esters sodium and lauryl alcohol sulfuric ester ammonium at least one therein.
Anionic surfactant described in first dose of composition of the invention accounts for the 0.5-20% of first dose of composition weight.
Anionic surfactant described in first dose of composition of the invention is lauryl alcohol sodium sulfovinate and cocounut oil acyl paddy Propylhomoserin sodium, wherein lauryl alcohol sodium sulfovinate accounts for first dose of composition weight 8% of the invention, and sodium cocoyl glutamate accounts for the present invention Weight 4%.
The effect of anionic surfactant described in first dose of composition of the invention is that collaboration generates good foam.
Nonionic surfactant
Nonionic surfactant described in first dose of composition of the invention accounts for first dose of composition weight 1-10%.
Nonionic surfactant described in first dose of composition of the invention is selected from Cocoalkyl glucosides, polyoxyethylene etherificate Lanonol, ethoxylated dodecyl alcohol, fatty alcohol polyoxyethylene ether for example cetanol polyoxyethylene ether, Brij-721, Brij, ethoxylated dodecyl alcohol, docosyl alcohol polyoxyethylene ether at least one therein.
The preferred Brij30 of nonionic surfactant described in first dose of composition of the invention, the polyoxy second Alkene lauryl alcohol is the composition of polyoxyethylene (12) lauryl alcohol and polyoxyethylene (21) lauryl alcohol.
Composed of Non-ionic Surfactant described in first dose of composition of the invention states polyoxyethylene (12) lauryl alcohol and polyoxy The weight ratio 1:2 to 2:1 of ethylene (21) lauryl alcohol.
The effect of nonionic surfactant of the present invention is that system emulsification is played in first dose of composition of the invention The evenly dispersed effect with coloring agent.
Nonionic surfactant described in first dose of composition of the invention accounts for first dose of composition weight 2-8%.
Oxidative dyestuff (coloring agent)
Oxidative coloration agent described in first dose of composition of the invention is dyestuff intermediate and coupling agent, have hair dyed intermediate and idol Mixture occurs oxidation reaction, coupling and condensation reaction after penetrating into scalp cortical layer under alkaline condition and forms different color Dyeing effect.The oxidative staining agent includes phenylenediamine, pyridine diammonium class, phenol, aphthols, amino phenols, hydroxyl Base phenol, benzyl pyridinone, pyruvic acid and its salt etc..
Oxidized form coloring agent described in first dose of composition of the invention is selected from o-phenylenediamine or its sulfate or its hydrochloride, Benzene diammonium or its sulfate or its hydrochloride, to benzene diammonium or its sulfate or its hydrochloride, N, N- bis- (2- ethoxys) are to benzene Diammonium or its sulfate or its hydrochloride, 2,4- diamino phenoxy ethyl alcohol or its sulfate or its hydrochloride ,-p- pairs of 2- nitro Phenylenediamine or its sulfate or its hydrochloride, Toluene-2,4-diisocyanate, 5- diamines or its sulfate or its hydrochloride, 2,6-diaminopyridine or Its sulfate or its hydrochloride, o-aminophenol or its sulfate or hydrochloride, m-aminophenol or its sulfate or hydrochloride, Para-aminophenol or its sulfate or hydrochloride, -5 nitrophenol of 2- amino, 4 amino -2- hydroxy-methylbenzenes or its sulfate or its Hydrochloride, 1- naphthols, resorcinol, Phenyl Methyl Pyrazolone 98Min, picramic acid at least one therein.
Oxidized form coloring agent described in first dose of composition of the invention is preferably to benzene diammonium, m-aminophenol, 4 amino -2- hydroxyls Base toluene, 1- naphthols and resorcinol；Wherein, first dose of composition weight 0.1-3% of the present invention is accounted for benzene diammonium, it is further excellent Turn to 0.3-2%；M-aminophenol accounts for first dose of composition weight 0.05-2% of the present invention, advanced optimizes as 0.1-1.6%； 4 amino -2- hydroxy-methylbenzenes account for first dose of composition weight 0.1-1% of the present invention, advanced optimize as 0.2-0.9%；1- naphthols First dose of composition weight 0.05-2% of the present invention is accounted for, is advanced optimized as 0.1-1%；Resorcinol accounts for first dose of group of the invention Polymer weight 1%, advanced optimizing is 0.5%.
Coloring agent described in first dose of composition of the invention accounts for composition weight 1.25-9%, advanced optimizes as 1.2- 6.2%.
Antioxidant
Antioxidant described in first dose of composition of the invention accounts for the 0.05-3% of first dose of composition weight of the invention.
When Hair grooming contains first dose of coloring agent and contains second dose of processing hair of oxidant (hydrogen peroxide), hair Start to expand and be formed simultaneously the dye molecule of macromolecular, these dye molecules, which are relatively large in diameter, to be difficult to penetrate into hair and shown Color, only dye coupling agent and intermediate are just aoxidized after penetrating into hair inside, and are formed inside hair shaft biggish Dye molecule, these dye molecules, which are closed in hair shaft, can just make hair-dyeing.So if oxidation is too fast, without foot Enough dyestuff intermediates and coupling agent penetrate into inside hair, then the color generated is shallower, and unevenly, color is not full.Cause This needs antioxidant.
In addition, to guarantee that the Material in packing container used in first dose of composition keeps foot under container opening status Enough the long time is not oxidized, keeps 1 week or more time, at least in order to the reuse of remaining lotion.Therefore antioxidant Selection and using extremely important.
Antioxidant described in first dose of composition of the invention can be selected from chemical antioxidants such as, sodium sulfite, ascorbic acid Sodium, thioacetic acid, ammonium mercaptoacetate, ascorbic acid and arabo-ascorbic acid at least one therein；Natural antioxygen can also be selected from Agent such as, Bitter Melon P.E, grape seed extract, oil tea extract, apple bank up the roots of seedlings extract, Ramulus et Folium Mussaendae Pubescentis extract, the askew beans leaf in South Africa Extract, maypop berry extract at least one therein.
The askew beans leaf extract of the preferred sodium sulfite of antioxidant and South Africa described in first dose of composition of the invention.
The askew beans leaf extract in South Africa described in first dose of composition of the invention, for mesquite, possesses dense branches and leaves and opens The acid-resisting plant of yellow flower is grown on to the north of 200 kilometers of the earth of the Cape Town, RSA north on the mountain Cedarberg, is autochthonal soil Long primordial plant, locals are known as " Louis boss " (Rooibos) i.e. meaning (the also known as Aspalathus of " red shrub " Linearis).The plant growing condition of this fragrance is more harsh, can be in barren acid sand ground, the drying high temperature in summer Or grown under the precipitation breeding condition in winter, anti-oxidant flavones (flavonols) rich in, there is very strong antioxidant activity, Being applied with has anti-allergic effects.The effect of the askew beans leaf extract in South Africa in the present invention be increase hair dyeing product storage time simultaneously And collaboration increases the hair-dyeing uniformity, prevents the generation of scalp allergic phenomena in hair dye.
The askew beans leaf extract in South Africa described in first dose of composition of the invention, using leaf as raw material, using the side of non-fermented Method is extracted that is, being extracted and being obtained using conventional plant leach extraction method.
Sodium sulfite described in first dose of composition of the invention accounts for the 0.05-1% of first dose of composition weight of the invention, excellent It is selected as 0.1-0.5%
The askew beans leaf extract in South Africa described in first dose of composition of the invention accounts for first dose of composition weight of the present invention 0.05-2%, preferably 0.1-1.5%
C14-22Fatty alcohol
C containing 1-5% in first dose of composition of the invention14-22Fatty alcohol, the fatty alcohol is in first dose of group of the invention It closes in object and plays thickening power, contribute to form the lotion of certain viscosity to stablize lotion.
C described in first dose of composition of the invention14-22Fatty alcohol is selected from C14Alcohol, C16Alcohol, C18Alcohol, oleyl alcohol, C22Alcohol is wherein At least one, the preferred C of the present invention14Alcohol.
C described in first dose of composition of the invention14Alcohol accounts for the 3% of first dose of composition weight.
Chelating agent
Often contain heavy metal in raw material and production process, heavy metal ion plays the autoxidation of dyestuff intermediate and urges Change effect, is unfavorable for the stabilization of coloring agent in first dose of composition, it is therefore desirable to introduce chelating agent.Chelating agent is selected from the present invention Disodium ethylene diamine tetraacetate or tetrasodium ethylenediamine tetraacetate, preferably tetrasodium ethylenediamine tetraacetate.In first dose of composition of the invention Chelating agent accounts for composition weight 0.05-0.4%, and advanced optimizing is 0.2%.
Alkaline reagent
Most of oxidative hair dyes have many pungent tastes, are because most of alkali agent uses ammonium hydroxide, oxygen The pH value of change type hair dyeing product is 8.5-10.5, needs higher alkalinity, the oxidation reaction of main cause (1) intermediate is necessary It is carried out compared under strong alkaline condition, (2) hair ability expansion and softening under alkaline condition, hair scale piece is opened, then in dyestuff The cortical layer of mesosome and the better scattering and permeating of coupling agent ability.
Alkalizing agent described in first dose of composition of the invention is selected from ammonium hydroxide, ammonium carbonate, ammonium hydrogen carbonate, monoethanolamine, diethyl Hydramine, triethanolamine at least one therein,
Alkaline reagent described in first dose of composition of the invention accounts for first dose of composition weight 1-10%, advanced optimizes as 2- 6%.
Alkaline reagent described in first dose of composition of the invention is ammonium hydroxide and monoethanolamine.
Ammonium hydroxide described in first chamber of the present invention accounts for first chamber weight 4%.
Monoethanolamine described in first chamber of the present invention accounts for first chamber weight 2%.
Remaining is deionized water.
A kind of foam-like oxidized form hair dyeing product of the present invention includes first dose of composition containing oxidized form coloring agent and contains There is second dose of composition of oxidant, the weight ratio using preceding first dose of composition and second dose of composition is first dose of combination Object: second dose of composition is 20 to 60:80 to 40, and advanced optimizing is 10 to 50:20 to 60
Second dose of composition
Second dose of composition described in a kind of foam-like oxidized form hair dyeing product of the present invention be by oxidant, stabilizer, yin from Sub- surfactant, pH adjusting agent, C14-C22Fatty alcohol and deionized water composition.
Oxidant
Oxidant described in second dose of composition of the invention is selected from hydrogenperoxide steam generator (commercially available 30% content of hydrogen peroxide), mistake Sodium carbonate and sodium perborate at least one therein, the preferred hydrogenperoxide steam generator of the present invention.Described in second dose of composition of the invention Oxidant accounts for second dose of composition weight 5-30%.
Hydrogenperoxide steam generator described in second dose of composition of the invention accounts for second dose of composition weight 20%.
Stabilizer
Stabilizer described in second dose of composition of the invention is sodium stannate, and antifebrin at least one therein is of the invention excellent Select sodium stannate.Sodium stannate accounts for second dose of composition weight 0.01-1% in the present invention.
Sodium stannate described in second dose of composition of the invention accounts for second dose of composition weight 0.1%.
Anionic surfactant
Anionic surfactant described in second dose of composition of the invention is selected from laruyl alcohol sodium sulfovinate, cocounut oil alcohol sulfuric ester Sodium, laurel alcohol sulfuric ester potassium, laurel alcohol sulfuric ester ammonium, myristyl alcohol sodium sulfovinate, Cetyl Alcohol sodium sulfovinate, cocounut oil acyl glutamic acid Sodium, lauryl alcohol sodium sulfovinate and lauryl alcohol sulfuric ester ammonium at least one therein.
Anionic surfactant described in second dose of composition of the invention accounts for the 1-20% of second dose of composition weight.
The preferred lauryl alcohol sodium sulfovinate of anionic surfactant and lauric alcohol described in second dose of composition of the invention Sodium sulfovinate.
It invents lauryl alcohol sodium sulfovinate in anionic surfactant described in second dose of composition and accounts for second dose of composition The 8% of weight.
Lauric alcohol sodium sulfovinate accounts for second dose of composition in anionic surfactant described in second dose of composition of the invention The 0.5% of weight.
PH adjusting agent
PH adjusting agent described in second dose of composition of the invention is selected from phosphoric acid and sodium pyrophosphate,
PH adjusting agent described in second dose of composition of the invention accounts for composition weight 0.01-1%,
Phosphoric acid described in second dose of composition of the invention accounts for second dose of composition weight 0.1%,
Sodium pyrophosphate described in second dose of composition of the invention accounts for second dose of composition weight 0.05%,
PH≤4 of second dose of composition of the invention.
C14-C22 fatty alcohol
C described in second dose of composition of the invention14-C22Fatty alcohol includes C14Alcohol, C16Alcohol, C18Alcohol and C22Alcohol is therein It is at least one.Fatty alcohol is C in second dose of composition of the invention16Alcohol, C described in second dose of composition of the invention16Alcohol accounts for composition Weight 0.1-5%.C described in second dose of composition of the invention16Alcohol is 1.5%, and surplus is deionized water.
Foam-like oxidized form hair dyeing product application method:
According to the present invention, the use of hair dyeing product of the present invention is by preparing first dose of composition and second dose of composition simultaneously It is sealed, later mixes first dose of composition and second dose of composition according to the ratio of weight ratio 10 to 50:20 to 60 Merging is put into the molten tank of gas or the molten filling of non-gas, generates uniform mousse foam by gas punching press or foam pump head, and will bubble Foam is uniformly sprawled on hair and is stopped the time of 5-30 minutes or 5-20 minutes, is finally cleaned up with clear water.
Embodiment
Here is the non-limiting example of hair dyeing bubble product of the invention.These embodiments are only given to say Improving eyesight, limitation of the invention can not be interpreted as.Because without departing from the spirit and scope of the present invention, can be with The present invention is changed.In this these embodiment, unless stated otherwise, all concentration is all weight percent.
Prepare embodiment (1)-(10)
The preparation method is as follows:
First dose of composition
It (1) include to benzene diammonium, m-aminophenol, 4 amino -2- hydroxy-methylbenzenes, 1- naphthols and isophthalic by oxidative dyestuff Diphenol, which is added together, is put into propylene glycol and deionized water is heated to 70 DEG C of dissolutions, spare.
(2) by deionized water, sodium sulfite, tetrasodium ethylenediamine tetraacetate, lauryl alcohol sodium sulfovinate, cocounut oil acyl glutamic acid Sodium, polyoxyethylene (12) lauryl alcohol, polyoxyethylene (21) lauryl alcohol, C14Alcohol is added together, and is heated to 75 DEG C, is stirred molten Uniformly, ammonium hydroxide and monoethanolamine is then added, and kept for 70 DEG C in solution, spare.
(3) (1) is added to (2), stirs and cooled down simultaneously, remaining ethyl alcohol is added when temperature drops to 45 degrees Celsius, The askew beans leaf extract in South Africa and essence, stir and continue to cool down.
(4) it is sealed when temperature drops to 25 degrees Celsius filling.
Second dose of composition
(1) by laruyl alcohol sodium sulfovinate, lauric alcohol sodium sulfovinate, C16Alcohol, sodium stannate, phosphoric acid, sodium pyrophosphate are added to In ionized water, it is stirred and heated to 75 DEG C；
(2) hydrogenperoxide steam generator is added and continues to stir, the pH value of second dose of composition is transferred to pH≤4；
(3) it is sealed when cooling to 25 DEG C filling.
Embodiment (1)-(5)
First dose of composition embodiment (1)-(5) table 1
Second dose of composition embodiment (1)-(5) table 2
Embodiment (6)-(10)
First dose of composition embodiment (6)-(10) table 3
Second dose of composition embodiment (6)-(10) table 4
Most preferred embodiment
First dose of composition-table 5
Most preferred embodiment
Second dose of composition-table 6
Laruyl alcohol sodium sulfovinate 0.5
Lauric alcohol sodium sulfovinate 1.5
C16Alcohol 0.1
Sodium stannate 0.1
Phosphoric acid 0.05
Sodium pyrophosphate 20
Hydrogenperoxide steam generator (30%) 0.5
Deionized water Add to 100
First dose of composition for hair dying antioxidant compliance test result (the results are shown in Table 7)
Table 7
First dose of composition is fabricated to A composition, composition B, C in combination object and D composition respectively in table 7, and close respectively Envelope saves one month, and the color of Kaifeng observation A, B, C and D sample is substantially unchanged.Sample A, B after container is broken a seal later, C, D places (camera bellows) and naturally respectively at the 3rd day, the 7th day, the 10th day, the 15th day, observes within the 20th day, the results are shown in Table 8
Table 8
Note: base colors indicate that+number the colors that represent deeper more with "+", change colour also more serious, illustrate that antioxidant capacity is got over Difference, on the contrary antioxidant capacity is better.Table 8 is as the result is shown: the overall antioxidant capacity of sample A and sample C is suitable, sample B and sample D's Overall antioxidant capacity is suitable, and the overall antioxidant capacity of sample B and sample D is better than sample A and sample C. and wherein puts in the Kaifeng sample B Less, antioxidant capacity is best for variation before and after setting 7 days observation colors.Illustrate that the askew beans leaf extract in natural South Africa has more Good antioxygen cooperative ability.
Head retention compliance test result
Embodiment (1)-head retention of (10) is verified-is shown in Table 9
Test method: embodiment (1)-(10) are mixed for respective first dose and second dose, and merging has air bubble The container of foam pump head, with thumb Pressing pump go out foam on glass dish (with thumb pressing pump head the 5th time formation foam To observe object), the persistence of foam is divided into difference, medium, good, very four ranks, with the plus sige "+" table of different number Show, and be explained as follows:
Poor (+): slightly foam or foam completely disappears
Medium (++): comparison reduces half before and after foam height or foam richness
Good (+++): almost do not change before and after foam height or foam richness or variation is little
Very good (++++): froth texture is strong, careful, and foam height or richness are self-consistent
Table 9
1 2 3 4 5 6 7 8 9 10
F10Min ++ ++ +++ +++ +++ +++ +++ ++++ ++ ++
F20Min ++ ++ ++ ++ +++ +++ +++ +++ ++ ++
F30Min ++ ++ ++ ++ ++ ++ +++ +++ ++ +
F40Min + + ++ + ++ ++ ++ +++ + +
F50Min + + + + ++ ++ ++ +++ + +
F60Min + + + + ++ ++ ++ ++ + +
In table 9, F represents foam, in terms of foam test result: the foam quality and persistence of embodiment 8 are best, and foam is held Long property characteristic can prevent hair dyeing bubble collapsing pollution skin and clothes, it is often more important that due to reducing foam solution fluidized flow It loses, so that the performance coloration that the reactive dye substance in bubble can be more permanent on hair, ensure that hair dyeing Color uniformity.In addition, gradient decaying is presented as time went on for foam quality and decaying is serious, explanation since embodiment 9 As low-carbon alcohols dosage is increased to constant weight percentage, such as when more than weight percent described in embodiment 8, low-carbon alcohols and table There is critical point in the foam quality that face activating agent is presented.

Claims (7)

  1. It include first dose of composition for hair dying and second dose of oxidizing agent composition 1. a kind of permanent hair dyeing bubble, described first dose Composition for hair dying includes:
    (1) low-carbon alcohols of first dose of composition for hair dying weight percent 1.05-27% are accounted for, which is ethyl alcohol, propylene glycol, different Propyl alcohol or n-butanol at least one therein；
    (2) anionic surfactant of first dose of composition for hair dying weight 0.5-20%, anionic surfactant choosing are accounted for From in laruyl alcohol sodium sulfovinate, lauric alcohol sodium sulfovinate, laurel alcohol sulfuric ester potassium, laurel alcohol sulfuric ester ammonium, myristyl alcohol sulfuric acid Ester sodium, Cetyl Alcohol sodium sulfovinate, sodium cocoyl glutamate, lauryl alcohol sodium sulfovinate, lauryl alcohol sulfuric ester ammonium are therein extremely Few one kind；
    (3) first dose of composition for hair dying weight 1-10% nonionic surfactant is accounted for, which is selected from Cocoalkyl glucosides, polyoxyethylene are etherified lanonol, lauric alcohol polyoxyethylene ether, ethoxylated dodecyl alcohol, Cetyl Alcohol polyoxy Vinethene, Brij-721, Brij, docosyl alcohol polyoxyethylene ether at least one therein；
    (4) antioxidant of first dose of composition for hair dying weight 0.05-3% is accounted for, the antioxidant is the askew beans of sodium sulfite and South Africa Leaf extract；
    (5) oxidative dyestuff of first dose of composition for hair dying weight 1.25-9% is accounted for；
    (6) C of first dose of composition for hair dying weight 1-5% is accounted for14-22Fatty alcohol；
    (7) chelating agent of first dose of composition for hair dying weight 0.05-0.4% is accounted for；
    (8) alkaline reagent of first dose of composition for hair dying weight 1-10% is accounted for；
    (9) pure water of first dose of composition for hair dying weight 12.6-87.15% is accounted for；
    Second dose of oxidizing agent composition includes the oxidant for accounting for second dose of oxidizing agent composition weight 5-30%, 0.01-1% Stabilizer, the anionic surfactant of 1-20%, the pH adjusting agent of 0.01-1%, the C of 0.1-5%14-22Fatty alcohol and remaining The deionized water of amount；
    The weight ratio of first dose of composition and second dose of composition is 20 to 60:80 to 40.
  2. 2. hair dyeing bubble according to claim 1, wherein oxidative dyestuff be selected from o-phenylenediamine sulfate or hydrochloride, Benzene diammonium sulfate or hydrochloride, to benzene diammonium sulfate or hydrochloride, N, N- bis- (2- ethoxys) to benzene diammonium sulfate or Hydrochloride, 2,4- diamino phenoxy alcohol sulfate salt or hydrochloride, 2- nitro-p- p-phenylenediamine sulfate or hydrochloride, first Benzene -2,5- diamines sulfate or hydrochloride, 2,6-diaminopyridine sulfate or hydrochloride, o-aminophenol sulfate or hydrochloric acid Salt, m-aminophenol sulfate or hydrochloride, p-aminophenol sulfate or hydrochloride, -5 nitrophenol of 2- amino, 4 amino - 2- hydroxy-methylbenzene sulfate or hydrochloride, 1- naphthols, resorcinol, Phenyl Methyl Pyrazolone 98Min, picramic acid therein at least one Kind.
  3. 3. hair dyeing bubble according to claim 1, the C14-22Fatty alcohol is selected from C14Alcohol, C16Alcohol, C18Alcohol, oleyl alcohol, C22Alcohol At least one therein.
  4. 4. hair dyeing bubble according to claim 1, the chelating agent is selected from disodium ethylene diamine tetraacetate or ethylenediamine tetrem Sour four sodium.
  5. 5. hair dyeing bubble according to claim 1, the alkalizing agent is selected from ammonium hydroxide, ammonium carbonate, ammonium hydrogen carbonate, monoethanol Amine, diethanol amine, triethanolamine at least one therein.
  6. 6. hair dyeing bubble according to claim 1, oxidant described in second dose of oxidizing agent composition of the hair dyeing were Hydrogen peroxide solution, SODIUM PERCARBONATE and sodium perborate at least one therein；The stabilizer is sodium stannate, antifebrin is therein It is at least one；The anionic surfactant is laruyl alcohol sodium sulfovinate and lauric alcohol sodium sulfovinate；The pH adjusting agent is Phosphoric acid or pyrophosphate at least one therein；The C14-C22Fatty alcohol is C16Alcohol.
  7. 7. the hair colouring methods of hair dyeing bubble described in claim 1: preparing first dose of composition and second dose of composition respectively simultaneously Respectively be sealed, using it is preceding by first dose of composition and second dose of composition according to the ratio of weight ratio 20 to 60:80 to 40 It carries out mixing to be placed into the molten tank of gas or the molten filling of non-gas, uniform mousse is generated by gas punching press or air foam pump head and is steeped Foam is uniformly sprawled on hair and is stopped 5-30 minutes time, finally cleaned up with clear water by foam.
CN201811597943.1A 2018-12-26 2018-12-26 A kind of permanent bubble and its hair colouring methods of having hair dyed Pending CN109498484A (en)

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CN112999097A (en) * 2019-12-20 2021-06-22 朋友株式会社 Aerosol composition for dyeing and decolorizing/depigmenting hair comprising an oxidizing agent
CN113827489A (en) * 2021-11-11 2021-12-24 广州温雅日用化妆品有限公司 Bubble-formulation hair dye and hair dyeing method
CN114010511A (en) * 2021-11-08 2022-02-08 章华化妆品科技有限公司 Hair dye, color developing agent and using method of double-agent oxidation type hair dye

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Publication number Priority date Publication date Assignee Title
CN112999097A (en) * 2019-12-20 2021-06-22 朋友株式会社 Aerosol composition for dyeing and decolorizing/depigmenting hair comprising an oxidizing agent
CN114010511A (en) * 2021-11-08 2022-02-08 章华化妆品科技有限公司 Hair dye, color developing agent and using method of double-agent oxidation type hair dye
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