CN113827489A - Bubble-formulation hair dye and hair dyeing method - Google Patents
Bubble-formulation hair dye and hair dyeing method Download PDFInfo
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- CN113827489A CN113827489A CN202111331163.4A CN202111331163A CN113827489A CN 113827489 A CN113827489 A CN 113827489A CN 202111331163 A CN202111331163 A CN 202111331163A CN 113827489 A CN113827489 A CN 113827489A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Abstract
The invention provides a bubble formulation hair dye, which comprises a hair dyeing agent No. 1 and a hair dyeing agent No. 2; the pH value of the hair dyeing agent No. 1 is 9.0-10.5; the hair dyeing agent No. 1 comprises: the foam-generating and foam-stabilizing agent comprises a foam-generating and foam-stabilizing agent, a coloring agent, an antioxidant, a chelating agent, a pH regulator, glycerol, propylene glycol, ethanol and essence; the foam generating and stabilizing agent consists of tetradecanol, sodium lauroyl sarcosinate and decyl glucoside, wherein the mass ratio of the tetradecanol to the sodium lauroyl sarcosinate to the decyl glucoside is 0.1-10: 2-15: 0.5-10; the hair dyeing agent No. 2 comprises: ceteareth-30, sodium lauroyl sarcosinate, tetradecanol, glycerol, ethanol, 50% hydrogen peroxide and etidronic acid. The hair dye is coated on the hair in a bubble formulation for dyeing, and the selection of each component and the component combination effect of the hair dye are further deeply researched, so that the bubble formulation hair dye with rich and fine foam, high bubble stability, long hair dyeing effective time and good hair dyeing effect is obtained.
Description
Technical Field
The invention belongs to the technical field of hair dyes, and particularly relates to a bubble formulation hair dye and a hair dyeing method.
Background
In order to enable hair dyeing components in the existing market to stay on hair for a longer time, increase hair dyeing treatment time and prevent the hair dyeing components from dripping, the hair dyeing components are usually arranged in a paste shape with higher viscosity, but the hair dyeing components are difficult to brush uniformly when being combed by a hair dyeing comb, so that the hair dyeing components are unevenly distributed on the whole hair, and particularly the covering effect of the hair dyeing components at the root of the hair is poor. Therefore, the existing hair dye has poor hair dyeing effect, obvious hair dyeing traces and poor user experience.
CN201811597943.1 discloses that the hair is dyed by using foam generated by mixing the first agent and the second agent, which shortens the stirring time and shortens the painting time of the hair dye on the hair, compared with the process of uniformly mixing the first agent and the second agent in a paste-shaped hair dyeing product and then brushing the hair by using a comb or a brush, the method is convenient to use, has high hair dyeing efficiency and uniform dyeing, and does not worry about the hair dye flowing or staining skin or clothes during the use. However, the foam generated by mixing the first agent and the second agent increases the raw material selection cost of the first agent and the second agent, and the foam is unstable, so that the hair dyeing quality is difficult to control.
CN201811181728.3 discloses a method for shampooing hair in bubble formulation shampoo, which uses a mousse pump head to squeeze the shampoo into foam; the mousse pump head is used for extruding the foam, so that the shampoo does not need to be concentrated on the top of the head and spread to other parts, the contact between chemical substances and the scalp can be reduced, and the shampoo is economical, environment-friendly, healthy and free of toxic and side effects. Under the thought of the technical scheme, the inventor thinks that the hair dye can also be coated on the hair in a bubble formulation for dyeing, and further deeply studies the selection of each component and the combination effect of the components of the hair dye, aiming at obtaining the bubble formulation hair dye with high bubble stability and long hair dyeing effective time.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide the bubble type hair dye which is rich and fine in foam, high in bubble stability, long in hair dyeing effective time and good in hair dyeing effect.
In order to achieve the purpose, the invention adopts the following technical scheme:
a bubble formulation hair dye comprises a hair dyeing agent No. 1 and a hair dyeing agent No. 2, wherein the weight ratio of the hair dyeing agent No. 1 to the hair dyeing agent No. 2 is 1: 1-3; the pH value of the hair dyeing agent No. 1 is 9.0-10.5;
the hair dyeing agent No. 1 comprises the following raw materials in parts by weight:
3-30 parts of foam generating and stabilizing agent
0.5-7 parts of coloring agent
0.5-2 parts of antioxidant
0.1 to 0.5 portion of chelating agent
0-18 parts of pH regulator
0-20 parts of glycerol
0-20 parts of propylene glycol
0-30 parts of ethanol
0-2.0 parts of essence
The foam generating and stabilizing agent consists of tetradecanol, sodium lauroyl sarcosinate and decyl glucoside, wherein the mass ratio of the tetradecanol to the sodium lauroyl sarcosinate to the decyl glucoside is 0.1-10: 2-20: 0.5-10;
the hair dyeing agent No. 2 comprises the following raw materials in parts by weight:
ceteareth-300.1-2.0 parts
2-15 parts of sodium lauroyl sarcosinate
0.1 to 10 portions of tetradecanol
0-10 parts of glycerol
0-20 parts of ethanol
4.0 to 18.0 portions of 50 percent hydrogen peroxide
0.1 to 0.5 portion of hydroxyethyl diphosphonic acid.
In the development of the bubble formulation hair dye, the inventor is continuously dedicated to the research of foam generation, foam stabilization and fine and rich foam. Specifically, in the formula of the hair dyeing agent No. 1, different surfactants are continuously selected from a large amount of surfactants to be compounded for experiments, and the foaming foam stabilizer consisting of tetradecanol, sodium lauroyl sarcosinate and decyl glucoside is finally obtained by continuously adjusting the foaming foam stabilizer mechanism and the experimental phenomenon. In the hair dyeing agent No. 2, through long-term experimental study, three raw materials, namely ceteareth-30, sodium lauroyl sarcosinate and tetradecanol, are selected and matched to prepare stable emulsion. In addition, the invention also adjusts the selection and content proportion of other components in the hair dyeing agents No. 1 and No. 2 and the setting of pH value, so that the overall formula of the hair dye is reasonable and the using effect is good.
In the invention, preferably, the hair dyeing agent No. 1 comprises the following raw materials in parts by weight:
7-22 parts of foam generating and stabilizing agent
0.5-5 parts of coloring agent
0.6 to 1 portion of antioxidant
0.3 to 0.4 portion of chelating agent
4-16 parts of pH regulator
0.5-3 parts of glycerol
2-7 parts of propylene glycol
5-10 parts of ethanol
0.3-0.5 part of essence
The bubble-generating foam stabilizer consists of tetradecanol, sodium lauroyl sarcosinate and decyl glucoside, wherein the mass ratio of the tetradecanol to the sodium lauroyl sarcosinate to the decyl glucoside is 2-7: 4-10: 1-5;
the hair dyeing agent No. 2 comprises the following raw materials in parts by weight:
ceteareth-300.5-1.5 parts
4-10 parts of sodium lauroyl sarcosinate
0.5 to 1.0 portion of tetradecanol
5-10 parts of glycerol
7-13 parts of ethanol
4.0 to 18.0 portions of 50 percent hydrogen peroxide
0.1 to 0.3 portion of hydroxyethyl diphosphonic acid.
The above formula content is the preferred amount range selected by the inventor, and in the present invention, the sum of the weight parts of all the formulas is 100 parts.
Preferably, the pH regulator consists of 25 wt% of ammonia water and monoethanolamine, and the mass ratio of the 25 wt% of ammonia water to the monoethanolamine is 0.5-2: 1. The selection of the components of the pH regulator has little influence on the performance of other components in the formula and has little irritation to the skin.
Further preferably, the hair dyeing agent No. 1 comprises the following raw materials in parts by weight:
16 parts of foam generating and stabilizing agent (the mass ratio of tetradecanol, sodium lauroyl sarcosinate and decyl glucoside is 1: 2: 1)
4 portions of coloring agent
0.8 portion of antioxidant
0.3 portion of chelating agent
3 portions of 25 percent ammonia water
4 portions of monoethanolamine
2 portions of glycerol
4 parts of propylene glycol
8 portions of ethanol
0.5 part of essence
The hair dyeing agent No. 2 comprises the following raw materials in parts by weight:
ceteareth-300.5 parts
Sodium lauroyl sarcosinate 8 parts
Tetradecanol 0.5 part
8 portions of glycerol
7 portions of ethanol
9 portions of 50 percent hydrogen peroxide
0.2 part of hydroxyethyldiphosphonic acid.
The amount of each component of the formula is the optimal amount selected by the inventor, and the optimal amount is obtained through a large amount of experimental research and screening, and the components can be matched with each other, so that the foam stabilizing effect is better, the hair dyeing is uniform, and the hair dyeing effect is good.
Further preferably, the coloring agent comprises the following raw materials in parts by weight: 0.5-3 parts of p-phenylenediamine, 0.3-2 parts of resorcinol, 0.2-2 parts of m-aminophenol and 0.1-1.2 parts of 2, 4-aminophenoxyethanol-2 HCl. Still more preferably, the coloring agent comprises the following raw materials in parts by weight: 2.5 parts of p-phenylenediamine, 1.2 parts of resorcinol, 1 part of m-aminophenol and 0.8 part of 2, 4-aminophenoxyethanol-2 HCl. The component selection of the coloring agent comprehensively considers the combination effect of the coloring components and the irritation of the coloring components to the scalp, and the combination of the four components is selected through multiple experimental adjustments, so that the coloring effect is good, and the irritation to the scalp and the hair is not large.
Further preferably, the antioxidant consists of sodium erythorbate and sodium sulfite, and the mass ratio of the sodium erythorbate to the sodium sulfite is 3: 5. Sodium erythorbate and sodium sulfite have strong reducibility, and have good use effect when being used as an antioxidant in hair dye.
Preferably, the chelating agent is disodium EDTA.
In the invention, the foam-generating foam stabilizer can also comprise the following components in parts by weight: 1.0-20 parts of sodium laureth sulfate, 0.1-5 parts of stearic acid and 0.1-8 parts of dodecanoic acid. Preferably, the foam generating and stabilizing agent consists of the following components in parts by weight: 3 parts of sodium laureth sulfate, 3 parts of stearic acid and 4 parts of dodecanoic acid. The three raw materials are matched to pump fine foam, and are stable and not easy to defoam.
In the invention, the hair dyeing agent No. 2 can also comprise the following raw materials in parts by weight:
50.1-1 parts of oleyl alcohol ether
0.1-4 parts of PEG-40 stearate
0.1-5 parts of hexadecanol or octadecanol
0-10 parts of glycerol
0-20 parts of ethanol
4.0 to 18.0 portions of 50 percent hydrogen peroxide
0.1 to 0.5 portion of hydroxyethyl diphosphonic acid.
Preferably, the feed comprises the following raw materials in parts by weight:
oleyl alcohol ether-50.4 parts
1.5 portions of PEG-40 stearate
Cetyl alcohol or stearyl alcohol 1.5 parts
8 portions of glycerol
7 portions of ethanol
9 portions of 50 percent hydrogen peroxide
0.2 part of hydroxyethyldiphosphonic acid.
The stable emulsion can be prepared by matching the three raw materials of the oleyl alcohol ether-5, the PEG-40 stearate, the cetyl alcohol or the stearyl alcohol, and is a better scheme obtained by screening of the inventor.
In the invention, 50% hydrogen peroxide is used as an oxidant in the hair dyeing agent No. 2, so that the addition amount of black dyeing series products is less, and the addition amount of color dyeing series products is large. The skilled person can select it as desired.
Preferably, the preparation method of the hair dyeing agent No. 1 and the hair dyeing agent No. 2 comprises the steps of weighing the raw materials according to the formula weight, uniformly mixing, adding the solvent, and uniformly mixing.
The invention also provides a using method of the bubble-type hair dye, which comprises the steps of uniformly mixing the hair dye No. 1 agent and the hair dye No. 2 agent according to the weight ratio of 1:2, pumping bubbles out by using a mousse pump, uniformly coating the bubbles on hair, and washing after the hair is dyed. Because the foam is uniform, fine and smooth and is uniformly attached, the specific hair dyeing time is shorter than that of the hair dye combed by the hair dyeing comb.
Compared with the prior art, the invention has the beneficial effects that: the inventor of the invention thinks that the hair dye is coated on the hair in a bubble formulation for dyeing, and further deeply studies the selection of each component and the component combination effect of the hair dye, thereby obtaining the bubble formulation hair dye with rich and fine foam, high bubble stability, long hair dyeing effective time and good hair dyeing effect. The hair dyeing time is shorter than that of hair dye combed by a hair dyeing comb. The inventor continuously selects different surfactants from a large amount of surfactants to compound and carry out experiments, and finally obtains the foam generation and stabilization agent consisting of tetradecanol, sodium lauroyl sarcosinate and decyl glucoside by continuously adjusting foaming and stabilization mechanisms and experimental phenomena, and the three raw materials can pump fine foam and are stable and difficult to defoam. Similarly, in hair dye No. 2, a stable emulsion can be prepared by mixing ceteareth-30, sodium lauroyl sarcosinate and tetradecanol. The bubble formulation hair dye has the advantages of simple hair dyeing operation, high hair dyeing efficiency and uniform dyeing, and the hair dye does not need to worry about flowing or staining skin or clothes during the use.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments, but the scope of the present invention is not limited to the embodiments.
The starting materials used in the following examples are all commercially available unless otherwise specified.
Example 1:
a bubble formulation hair dye comprises a hair dyeing agent No. 1 and a hair dyeing agent No. 2, wherein the weight ratio of the hair dyeing agent No. 1 to the hair dyeing agent No. 2 is 1:1.
The formula of the hair dyeing agent No. 1 is as follows:
foam-generating foam stabilizer 3Kg
Dyeing agent 3Kg
Antioxidant 0.5Kg
Chelating agent 0.1Kg
pH regulator (regulating pH of agent No. 1 to 9.0)
Glycerol 1Kg
Propylene glycol 1Kg
Ethanol 1Kg
Deionized water to 100 Kg.
The bubble-generating foam stabilizer consists of tetradecanol, sodium lauroyl sarcosinate and decyl glucoside, wherein the mass ratio of the tetradecanol to the sodium lauroyl sarcosinate to the decyl glucoside is 1: 2: 1; the pH regulator consists of 25 wt% of ammonia water and monoethanolamine, and the mass ratio of the 25 wt% of ammonia water to the monoethanolamine is 0.5: 1.
The formula of the coloring agent is as follows: 2.5Kg of p-phenylenediamine, 1.2Kg of resorcinol, 1Kg of m-aminophenol, and 0.8Kg of 2, 4-aminophenoxyethanol-2 HCl. The antioxidant consists of sodium erythorbate and sodium sulfite, wherein the mass ratio of the sodium erythorbate to the sodium sulfite is 3: 5. The chelating agent is disodium EDTA.
The formula of the hair dyeing agent No. 2 is as follows:
ceteareth-300.1 Kg
Sodium lauroyl sarcosinate 2Kg
Tetradecanol 0.1Kg
Glycerol 1Kg
Ethanol 1Kg
4.0Kg of 50% hydrogen peroxide
0.1Kg of hydroxyethylidene diphosphate
Deionized water to 100 Kg.
Example 2:
a bubble formulation hair dye comprises a hair dyeing agent No. 1 and a hair dyeing agent No. 2, wherein the weight ratio of the hair dyeing agent No. 1 to the hair dyeing agent No. 2 is 1: 3.
The formula of the hair dyeing agent No. 1 is as follows:
30Kg of foam generating and stabilizing agent
Dyeing agent 4Kg
Antioxidant 2Kg
Chelating agent 0.5Kg
pH regulator (regulating pH of agent No. 1 to 10.5)
Glycerol 5Kg
Propylene glycol 5Kg
Ethanol 5Kg
0.5Kg of essence
Deionized water to 100 Kg.
The foam generating and stabilizing agent consists of 17Kg of sodium laureth sulfate, 5Kg of stearic acid and 8Kg of lauric acid; the pH regulator consists of 25 wt% of ammonia water and monoethanolamine, and the mass ratio of the 25 wt% of ammonia water to the monoethanolamine is 2: 1.
The formula of the coloring agent is as follows: 2.5Kg of p-phenylenediamine, 1.2Kg of resorcinol, 1Kg of m-aminophenol, and 0.8Kg of 2, 4-aminophenoxyethanol-2 HCl. The antioxidant consists of sodium erythorbate and sodium sulfite, wherein the mass ratio of the sodium erythorbate to the sodium sulfite is 3: 5. The chelating agent is disodium EDTA.
The formula of the hair dyeing agent No. 2 is as follows:
ceteareth-302.0 Kg
15Kg of sodium lauroyl sarcosinate
Tetradecanol 0.5Kg
Glycerol 10Kg
20Kg of ethanol
18.0Kg of 50% hydrogen peroxide
0.5Kg of hydroxyethylidene diphosphate
Deionized water to 100 Kg.
Example 3:
a bubble formulation hair dye comprises a hair dyeing agent No. 1 and a hair dyeing agent No. 2, wherein the weight ratio of the hair dyeing agent No. 1 to the hair dyeing agent No. 2 is 1: 2;
the formula of the hair dyeing agent No. 1 is as follows:
foam-generating foam stabilizer 16Kg
Dyeing agent 4Kg
Antioxidant 0.8Kg
Chelating agent 0.3Kg
pH regulator (regulating pH of agent No. 1 to 10)
Glycerol 2Kg
Propylene glycol 4Kg
Ethanol 8Kg
0.5Kg of essence
Deionized water to 100 Kg.
The bubble-generating foam stabilizer consists of tetradecanol, sodium lauroyl sarcosinate and decyl glucoside, wherein the mass ratio of the tetradecanol to the sodium lauroyl sarcosinate to the decyl glucoside is 1: 2: 1; the pH regulator consists of 25 wt% of ammonia water and monoethanolamine, and the mass ratio of the 25 wt% of ammonia water to the monoethanolamine is 3: 4.
The formula of the coloring agent is as follows: 2.5Kg of p-phenylenediamine, 1.2Kg of resorcinol, 1Kg of m-aminophenol, and 0.8Kg of 2, 4-aminophenoxyethanol-2 HCl. The antioxidant consists of sodium erythorbate and sodium sulfite, wherein the mass ratio of the sodium erythorbate to the sodium sulfite is 3: 5. The chelating agent is disodium EDTA.
The formula of the hair dyeing agent No. 2 is as follows:
ceteareth-300.5 Kg
Sodium lauroyl sarcosinate 8Kg
Tetradecanol 0.4Kg
Glycerol 8Kg
Ethanol 7Kg
9Kg of 50% hydrogen peroxide
0.2Kg of hydroxyethylidene diphosphate
Deionized water to 100 Kg.
Example 4:
a bubble formulation hair dye comprises a hair dyeing agent No. 1 and a hair dyeing agent No. 2, wherein the weight ratio of the hair dyeing agent No. 1 to the hair dyeing agent No. 2 is 1: 2.
The formula of the hair dyeing agent No. 1 is as follows:
10Kg of foam generating and stabilizing agent
Dyeing agent 3Kg
Antioxidant 1.6Kg
Chelating agent 0.2Kg
pH regulator (regulating pH of agent No. 1 to 10)
Glycerol 10Kg
Propylene glycol 10Kg
Ethanol 8Kg
0.3Kg of essence
Deionized water to 100 Kg.
The foam generating and stabilizing agent consists of 3Kg of sodium laureth sulfate, 3Kg of stearic acid and 4Kg of lauric acid; the pH regulator consists of 25 wt% of ammonia water and monoethanolamine, and the mass ratio of the 25 wt% of ammonia water to the monoethanolamine is 1:1.
The formula of the coloring agent is as follows: 2.5Kg of p-phenylenediamine, 1.2Kg of resorcinol, 1Kg of m-aminophenol, and 0.8Kg of 2, 4-aminophenoxyethanol-2 HCl. The antioxidant consists of sodium erythorbate and sodium sulfite, wherein the mass ratio of the sodium erythorbate to the sodium sulfite is 3: 5. The chelating agent is disodium EDTA.
The formula of the hair dyeing agent No. 2 is as follows:
oleyl alcohol ether-50.4 Kg
PEG-40 stearate 1.5Kg
Cetyl alcohol or stearyl alcohol 1.5Kg
Glycerol 7Kg
Ethanol 8Kg
9Kg of 50% hydrogen peroxide
0.3Kg of hydroxyethylidene diphosphate
Deionized water to 100 Kg.
Example 5:
a bubble formulation hair dye comprises a hair dyeing agent No. 1 and a hair dyeing agent No. 2, wherein the weight ratio of the hair dyeing agent No. 1 to the hair dyeing agent No. 2 is 1: 2.
The formula of the hair dyeing agent No. 1 is as follows:
10Kg of foam generating and stabilizing agent
Dyeing agent 3Kg
Antioxidant 0.8Kg
Chelating agent 0.3Kg
pH regulator (regulating pH of agent No. 1 to 10)
Glycerol 12Kg
Propylene glycol 12Kg
12Kg of ethanol
0.5Kg of essence
Deionized water to 100 Kg.
The foam generating and stabilizing agent consists of 3Kg of sodium laureth sulfate, 3Kg of stearic acid and 4Kg of lauric acid; the pH regulator consists of 25 wt% of ammonia water and monoethanolamine, and the mass ratio of the 25 wt% of ammonia water to the monoethanolamine is 5: 3.
The formula of the coloring agent is as follows: 2.5Kg of p-phenylenediamine, 1.2Kg of resorcinol, 1Kg of m-aminophenol, and 0.8Kg of 2, 4-aminophenoxyethanol-2 HCl. The antioxidant consists of sodium erythorbate and sodium sulfite, wherein the mass ratio of the sodium erythorbate to the sodium sulfite is 3: 5. The chelating agent is disodium EDTA.
The formula of the hair dyeing agent No. 2 is as follows:
oleyl alcohol ether-50.4 Kg
PEG-40 stearate 1.5Kg
Cetyl alcohol or stearyl alcohol 1.5Kg
Glycerol 8Kg
Ethanol 7Kg
9Kg of 50% hydrogen peroxide
0.2Kg of hydroxyethylidene diphosphate
Deionized water to 100 Kg.
Example 6:
a bubble formulation hair dye comprises a hair dyeing agent No. 1 and a hair dyeing agent No. 2, wherein the weight ratio of the hair dyeing agent No. 1 to the hair dyeing agent No. 2 is 1: 1.5.
The formula of the hair dyeing agent No. 1 is as follows:
foam-generating foam stabilizer 16Kg
Dyeing agent 4Kg
Antioxidant 0.8Kg
Chelating agent 0.3Kg
pH regulator (regulating pH of agent No. 1 to 10)
Glycerol 2Kg
Propylene glycol 4Kg
Ethanol 8Kg
0.5Kg of essence
Deionized water to 100 Kg.
The bubble-generating foam stabilizer consists of tetradecanol, sodium lauroyl sarcosinate and decyl glucoside, wherein the mass ratio of the tetradecanol to the sodium lauroyl sarcosinate to the decyl glucoside is 1: 2: 1; the pH regulator consists of 25 wt% of ammonia water and monoethanolamine, and the mass ratio of the 25 wt% of ammonia water to the monoethanolamine is 3: 4.
The formula of the coloring agent is as follows: 2Kg of p-phenylenediamine, 0.8Kg of resorcinol, 0.8Kg of m-aminophenol and 0.4Kg of 2, 4-aminophenoxyethanol-2 HCl. The antioxidant consists of sodium erythorbate and sodium sulfite, wherein the mass ratio of the sodium erythorbate to the sodium sulfite is 3: 5. The chelating agent is disodium EDTA.
The formula of the hair dyeing agent No. 2 is as follows:
oleyl alcohol ether-50.4 Kg
PEG-40 stearate 1.5Kg
Cetyl alcohol or stearyl alcohol 1.5Kg
Glycerol 8Kg
Ethanol 7Kg
9Kg of 50% hydrogen peroxide
0.2Kg of hydroxyethylidene diphosphate
Deionized water to 100 Kg.
Comparative example 1:
in comparison with example 3, the same procedure as in example 3 was repeated except that the foam stabilizer was not used and an equivalent amount of a foaming agent commonly used in the art (sodium laureth sulfate, cocamidopropyl betaine, cocamide DEA in a mixed composition of 1:1: 1) was used instead.
Comparative example 2:
compared with the embodiment 3, the foam generating and stabilizing agent is characterized by consisting of tetradecanol and sodium lauroyl sarcosinate, wherein the mass ratio of the tetradecanol to the sodium lauroyl sarcosinate is 1:3, the other operations were the same as in example 3.
Comparative example 3:
compared with example 3, the bubble type hair dye has the same components, but the content of each component is different from that of example 3, and the other operations are the same as example 3. The comparative examples had the following composition contents:
the formula of the hair dyeing agent No. 1 is as follows:
foam-generating foam stabilizer 4Kg
Dyeing agent 4Kg
Antioxidant 2.5Kg
Chelating agent 0.6Kg
pH regulator (regulating pH of agent No. 1 to 10.5)
Glycerol 12Kg
Propylene glycol 12Kg
12Kg of ethanol
0.5Kg of essence
Deionized water to 100 Kg.
The formula of the hair dyeing agent No. 2 is as follows:
ceteareth-302.5 Kg
12Kg of sodium lauroyl sarcosinate
Tetradecanol 11Kg
Glycerol 8Kg
Ethanol 7Kg
9Kg of 50% hydrogen peroxide
0.2Kg of hydroxyethylidene diphosphate
Deionized water to 100 Kg.
Performance testing
After the agents for dyeing hair No. 1 and No. 2 of examples 1 to 6 and comparative examples 1 to 3 were mixed uniformly, the same amount of bubbles was pumped by a mousse pump of the same specification to compare the foaming effect and the foam durability. The results are shown in Table 1.
TABLE 1
| Item | Foaming effect | Durability of foam |
| Example 1 | Can pump out fine and thick foam | Water started after 32 minutes of foam duration |
| Example 2 | Can pump out fine and thick foam | Water dissolution started after the foam lasted for 37 minutes |
| Example 3 | Can pump out fine and thick foam | Water started after 42 minutes of foam duration |
| Example 4 | Can pump out fine and thick foam | Water dissolution started after foam lasted for 40 minutes |
| Example 5 | Can pump out fine and thick foam | Water dissolution started after the foam lasted for 35 minutes |
| Example 6 | Can pump out fine and thick foam | The foam began to hydrate after 38 minutes |
| Comparative example 1 | Can pump out fine and thick foam | Water started after foam lasted for 8 minutes |
| Comparative example 2 | Can pump out fine and thick foam | Water starts to melt after the foam lasts for 15 minutes |
| Comparative example 3 | Can pump out fine and thick foam | After the foam lasted for 20 minutes, the water started to melt |
Hair dyeing and evaluation
Dyeing the hair: the hair dyeing agents No. 1 and No. 2 of examples 1 to 6 and comparative examples 1 to 3 were mixed uniformly, bubbles were pumped out by a mousse pump, and the mixture was uniformly applied to commercially available hair strands, left at room temperature for 30 minutes, and then washed with commercially available 2 in 1 shampoo and dried naturally to obtain 9 kinds of "just dyed" hair strands; further, a commercially available hair dye combed with a hair comb was uniformly applied to commercially available hair strands through the hair comb, left to stand at room temperature for 30 minutes, and then washed with the above 2 in 1 shampoo and dried naturally to obtain 1 type of control hair strands. 30 professional hairdressers evaluate and score the hair bundles just dyed (full score is 10, the dyeing effect is bright and bright in color, uniform and free of chromatic aberration, 0 score is dark and lusterless, layering is obvious, depth is different, and the like), and the average number of each group of scores is used as a final score value.
Cleaning: observing the color of the dyed hair bundle, cleaning the hair bundle, respectively taking the same amount of shampoo and pure water, placing the hair bundle in a beaker, soaking for 30min with the pure water added with the shampoo while stirring, taking out the hair bundle, and measuring the ultraviolet absorbance of the liquid in the beaker. After 1 hour, washing the hair bundle again by the method, and measuring the ultraviolet absorbance value of the washed liquid; the measurement was repeated 7 times and the color of the hair strand was observed again.
The results are shown in Table 2.
TABLE 2
As can be seen from the results in Table 2, the hair dye of the bubble formulation of the present invention has good dyeing effect, good washing fastness and is not easy to fall off. The coloring agents of examples 1 to 6 had good color development, no fading after several washes, and good color fastness.
Variations and modifications to the above-described embodiments may occur to those skilled in the art, which fall within the scope and spirit of the above description. Therefore, the present invention is not limited to the specific embodiments disclosed and described above, and some modifications and variations of the present invention should fall within the scope of the claims of the present invention. Furthermore, although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.
Claims (10)
1. The bubble formulation hair dye is characterized by comprising a hair dyeing agent No. 1 and a hair dyeing agent No. 2, wherein the weight ratio of the hair dyeing agent No. 1 to the hair dyeing agent No. 2 is 1: 1-3; the pH value of the hair dyeing agent No. 1 is 9.0-10.5;
the hair dyeing agent No. 1 comprises the following raw materials in parts by weight:
3-30 parts of foam generating and stabilizing agent
0.5-7 parts of coloring agent
0.5-2 parts of antioxidant
0.1 to 0.5 portion of chelating agent
0-18 parts of pH regulator
0-20 parts of glycerol
0-20 parts of propylene glycol
0-30 parts of ethanol
0-2.0 parts of essence
The foam generating and stabilizing agent consists of tetradecanol, sodium lauroyl sarcosinate and decyl glucoside, wherein the mass ratio of the tetradecanol to the sodium lauroyl sarcosinate to the decyl glucoside is 0.1-10: 2-20: 0.5-10;
the hair dyeing agent No. 2 comprises the following raw materials in parts by weight:
ceteareth-300.1-2.0 parts
2-15 parts of sodium lauroyl sarcosinate
0.1 to 10 portions of tetradecanol
0-10 parts of glycerol
0-20 parts of ethanol
4.0 to 18.0 portions of 50 percent hydrogen peroxide
0.1 to 0.5 portion of hydroxyethyl diphosphonic acid.
2. The bubble formulation hair dye of claim 1, wherein the pH regulator comprises 25 wt% of ammonia water and monoethanolamine, and the mass ratio of the 25 wt% of ammonia water to the monoethanolamine is 0.5-2: 1.
3. The bubble formulation hair dye of claim 1, wherein the hair dye comprises the following raw materials in parts by weight:
0.5-3 parts of p-phenylenediamine
Resorcinol 0.3-2 parts
0.2-2 parts of m-aminophenol
0.1-1.2 parts of 2, 4-amino phenoxyethanol-2 HCl.
4. The bubble formulation hair dye of claim 3, wherein the hair dye comprises the following raw materials in parts by weight:
2.5 parts of p-phenylenediamine
Resorcinol 1.2 parts
1 part of m-aminophenol
0.8 part of 2, 4-amino phenoxyethanol-2 HCl.
5. The bubble formulation hair dye of claim 1, wherein the foam generating and stabilizing agent comprises the following components in parts by weight:
sodium laureth sulfate 1.0-20 parts
0.1-5 parts of stearic acid
0.1-8 parts of dodecanoic acid.
6. The bubble formulation hair dye of claim 5, wherein the foam generating and stabilizing agent comprises the following components in parts by weight:
sodium laureth sulfate 3 parts
Stearic acid 3 parts
4 parts of dodecanoic acid.
7. The bubble formulation hair dye of claim 1, wherein the hair dyeing agent No. 2 comprises the following raw materials in parts by weight:
50.1-1 parts of oleyl alcohol ether
0.1-4 parts of PEG-40 stearate
0.1-5 parts of hexadecanol or octadecanol
0-10 parts of glycerol
0-20 parts of ethanol
4.0 to 18.0 portions of 50 percent hydrogen peroxide
0.1 to 0.5 portion of hydroxyethyl diphosphonic acid.
8. The bubble formulation hair dye of claim 7, wherein the hair dyeing agent No. 2 comprises the following raw materials in parts by weight:
oleyl alcohol ether-50.4 parts
1.5 portions of PEG-40 stearate
Cetyl alcohol or stearyl alcohol 1.5 parts
8 portions of glycerol
7 portions of ethanol
9 portions of 50 percent hydrogen peroxide
0.2 part of hydroxyethyldiphosphonic acid.
9. The bubble formulation hair dye of claim 2, wherein the hair dye No. 1 agent comprises the following raw materials in parts by weight:
foam generating and stabilizing agent 16 parts
4 portions of coloring agent
0.8 portion of antioxidant
0.3 portion of chelating agent
3 portions of 25 percent ammonia water
4 portions of monoethanolamine
2 portions of glycerol
4 parts of propylene glycol
8 portions of ethanol
0.5 part of essence
The hair dyeing agent No. 2 comprises the following raw materials in parts by weight:
ceteareth-300.5 parts
Sodium lauroyl sarcosinate 8 parts
Tetradecanol 0.5 part
8 portions of glycerol
7 portions of ethanol
9 portions of 50 percent hydrogen peroxide
0.2 part of hydroxyethyldiphosphonic acid.
10. A using method of a bubble-type hair dye is characterized in that a hair dye No. 1 agent and a hair dye No. 2 agent are uniformly mixed according to a weight ratio of 1:2, bubbles are pumped out by a mousse pump and uniformly coated on hair, and the hair is washed off after the hair is dyed.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115350112A (en) * | 2022-04-18 | 2022-11-18 | 广州艾柔生物科技有限公司 | Hair dyeing composition, preparation method and application thereof, and hair dyeing mousse |
| CN115350112B (en) * | 2022-04-18 | 2024-04-19 | 广州艾柔生物科技有限公司 | Hair dyeing composition, preparation method and application thereof and hair dyeing mousse |
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| CN101835457A (en) * | 2007-10-24 | 2010-09-15 | 花王株式会社 | Two-part hair dye |
| CN109498484A (en) * | 2018-12-26 | 2019-03-22 | 拉芳家化股份有限公司 | A kind of permanent bubble and its hair colouring methods of having hair dyed |
| CN113350240A (en) * | 2021-06-25 | 2021-09-07 | 张勇 | Planting extract hair dyeing cream and preparation method thereof |
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| CN101835457A (en) * | 2007-10-24 | 2010-09-15 | 花王株式会社 | Two-part hair dye |
| CN101816622A (en) * | 2010-05-17 | 2010-09-01 | 广州温雅日用化妆品有限公司 | Bubble-formulation hair dye and preparation method thereof |
| CN109498484A (en) * | 2018-12-26 | 2019-03-22 | 拉芳家化股份有限公司 | A kind of permanent bubble and its hair colouring methods of having hair dyed |
| CN113350240A (en) * | 2021-06-25 | 2021-09-07 | 张勇 | Planting extract hair dyeing cream and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115350112A (en) * | 2022-04-18 | 2022-11-18 | 广州艾柔生物科技有限公司 | Hair dyeing composition, preparation method and application thereof, and hair dyeing mousse |
| CN115350112B (en) * | 2022-04-18 | 2024-04-19 | 广州艾柔生物科技有限公司 | Hair dyeing composition, preparation method and application thereof and hair dyeing mousse |
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