JPH06271435A - Hair dye - Google Patents
Hair dyeInfo
- Publication number
- JPH06271435A JPH06271435A JP6030093A JP6030093A JPH06271435A JP H06271435 A JPH06271435 A JP H06271435A JP 6030093 A JP6030093 A JP 6030093A JP 6030093 A JP6030093 A JP 6030093A JP H06271435 A JPH06271435 A JP H06271435A
- Authority
- JP
- Japan
- Prior art keywords
- agent
- hair
- foamy
- dye
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、専用ブラシを用いるか
又は毛髪に直接塗布してコーミングすることにより毛髪
の上で第１剤と第２剤とを混合することができ、簡便な
使用方法で短時間に毛髪を種々の色調に染色する染着効
果と、同時に毛髪の明度を部分的又は全体的に任意に調
整することを可能にするライトニング（ブリーチ作用）
効果とを兼ね備え、かつ優れたコンディショニング効果
が長期にわたり持続する泡状の毛髪染色剤に関する。INDUSTRIAL APPLICABILITY The present invention allows a first agent and a second agent to be mixed on the hair by using a dedicated brush or by directly applying the hair onto the hair and combing the hair. A dyeing effect that dyes hair in various color tones in a short time, and at the same time, a lightening (bleaching effect) that allows the brightness of the hair to be adjusted partially or wholly at the same time.
The present invention relates to a foamy hair dye that has both effects and an excellent conditioning effect that lasts for a long period of time.
【０００２】[0002]
【従来の技術】従来より広く使用されている毛髪染色剤
は、酸化染料中間体を主成分とする粉末状、液状、又は
クリーム状の第１剤と、過酸化水素等の酸化剤を主成分
とする粉末状、液状、又はクリーム状の第２剤とを混合
する２剤型の染色剤であった。しかしこれらは、混合時
に第１剤と第２剤とを均一に分散させることが難しく、
更に混合液を毛髪に塗布する際に時間を要し塗布しにく
いという欠点があり、理美容室での大きな課題である時
間短縮につながらなかった。2. Description of the Related Art Hair dyes that have been widely used hitherto include a powdery, liquid or creamy first agent containing an oxidative dye intermediate as a main component, and an oxidant such as hydrogen peroxide as a main component. It was a two-component type dyeing agent which was mixed with a powdery, liquid or creamy second agent. However, it is difficult to uniformly disperse the first agent and the second agent during mixing,
Further, there is a drawback that it takes time to apply the mixed solution to hair and it is difficult to apply it, and it has not been possible to shorten the time, which is a major problem in a hairdressing and beauty salon.
【０００３】又、従来の毛髪染色剤では基本的にはジア
ミン系の酸化染料中間体が使用されていたため、その扱
い方によっては毛髪の損傷や頭皮に対する一次皮膚刺激
を生ずる危険があり、更に地肌や頭皮への染着が見られ
るなどの問題があった。更に従来の毛髪用脱色剤には過
酸化水素が使用されていることが多く、過酸化水素の脱
色力を高めるためにアンモニア水等のアルカリ剤を加え
て毛髪に塗布するようにしており、これにより毛髪中の
メラニン色素の酸化漂白を行い黒髪を茶色〜褐色系にす
ることが可能となっていた。しかしこのような脱色剤
は、酸性領域（ｐＨが６．０以下）では脱色力が不十分
であって求められる明度が得られず、実用に値しないこ
とは公知であった。そのため一般には毛髪施術時の脱色
剤のｐＨは１０．０〜１２．０と高く調整されており、
毛髪が損傷を受けやすいうえに臭気も強く、皮膚や眼に
対する刺激が大きいと言う問題もあって、改良が望まれ
ている。Further, since the conventional hair dyeing agent basically uses a diamine type oxidative dye intermediate, there is a risk of causing hair damage or primary skin irritation to the scalp depending on how to handle the same, and further, the bare skin. There was a problem such as dyeing on the scalp. Further, hydrogen peroxide is often used in the conventional hair decolorizing agent, and in order to enhance the decolorizing power of hydrogen peroxide, an alkaline agent such as ammonia water is added and applied to the hair. By this, it was possible to oxidize and bleach the melanin pigment in the hair to make the black hair brown to brownish. However, it has been known that such a decolorizing agent is not practically applicable because the decolorizing power is insufficient in the acidic region (pH of 6.0 or less) and the required brightness cannot be obtained. Therefore, the pH of the decolorizing agent during hair treatment is generally adjusted to a high value of 10.0 to 12.0,
There is a problem that the hair is easily damaged and also has a strong odor and irritation to the skin and eyes is large, and therefore improvement is desired.
【０００４】[0004]
【発明が解決しようとする課題】そこで本発明は、簡便
な使用方法で短時間に毛髪への塗布が可能であり、種々
の色調に毛髪を染色することができると共に毛髪の明度
を部分的又は全体的に任意に調整でき、更に仕上がりに
良好な感触が得られるうえに優れたコンディショニング
効果が長期にわたり持続するような毛髪染色剤を提供す
ることを目的とした。Therefore, according to the present invention, the hair can be applied to the hair in a short time by a simple use method, the hair can be dyed in various color tones, and the lightness of the hair is partially or An object of the present invention is to provide a hair dyeing agent which can be adjusted as desired on the whole, and which has a good feeling of finishing and an excellent conditioning effect which is maintained for a long period of time.
【０００５】[0005]
【課題を解決するための手段】上記実情に鑑み、本発明
者らは鋭意研究を重ねた結果、カチオン性直接染料を主
成分とする第１剤と過酸化水素等の酸化剤を主成分とす
る第２剤とを、いずれも泡状として混合使用することに
より、本発明の目的を達成することができることを見出
した。In view of the above-mentioned circumstances, the inventors of the present invention have conducted extensive studies, and as a result, have found that a first agent containing a cationic direct dye as a main component and an oxidizing agent such as hydrogen peroxide as a main component. It was found that the object of the present invention can be achieved by mixing and using the second agent to be used in the form of foam.
【０００６】すなわち本発明は、カチオン性直接染料を
主成分とする泡状第１剤と過酸化水素等の酸化剤を主成
分とする泡状第２剤とからなる泡状の毛髪染色剤であ
り、更に第１剤のカチオン性直接染料として赤色系又は
黄色系の染料を用い、泡状第１剤と泡状第２剤とを混合
してｐＨを６．０〜１０．０の範囲内とした泡状毛髪染
色剤を用いて毛髪施術を実施すれば、毛髪の明度を好み
のように調整することが可能となるものである。That is, the present invention is a foam hair dye comprising a foam first agent containing a cationic direct dye as a main component and a foam second agent containing an oxidizing agent such as hydrogen peroxide as a main component. In addition, a red or yellow dye is used as the cationic direct dye of the first agent, and the foamy first agent and the foamy second agent are mixed to adjust the pH within the range of 6.0 to 10.0. When the hair treatment is performed using the foamy hair dye, the lightness of the hair can be adjusted as desired.
【０００７】本発明の第１剤に配合されるカチオン性直
接染料としては、例えば３−アミノ−４−ヒドロキシニ
トロベンゼン、２−アミノ−５−ヒドロキシニトロベン
ゼン、２−アミノ−３−ヒドロキシニトロベンゼン、２
−アミノ−４−ヒドロキシニトロベンゼン、２−アミノ
−５−Ｎ，Ｎ−ビス−（β−ヒドロキシエチル）アミノ
ニトロベンゼン、２−アミノ−４−クロロ−５−Ｎ−
（β−ヒドロキシエチル）アミノニトロベンゼン、３，
４−ビス−（Ｎ−β−ヒドロキシエチルアミノ）ニトロ
ベンゼン、２−アミノ−４−メチル−５−Ｎ−（β，γ
−ジヒドロキシプロピルアミノ）ニトロベンゼン、２−
アミノ−４−メチル−５−（β−アミノエチル）アミノ
ニトロベンゼン、３，４−ジアミノニトロベンゼン、
２，５−ジアミノニトロベンゼン、２−アミノ−５−Ｎ
−（β−ヒドロキシエチル）アミノニトロベンゼン、２
−Ｎ−（β−ヒドロキシエチル）アミノ−５−Ｎ，Ｎ−
ビス−（β−ヒドロキシエチル）アミノニトロベンゼ
ン、２−Ｎ−メチルアミノ−５−Ｎ，Ｎ−ビス−（β−
ヒドロキシエチル）アミノニトロベンゼン、２−Ｎ−メ
チルアミノ−５−Ｎ−メチル−Ｎ−（β−ヒドロキシエ
チル）アミノニトロベンゼン、２−Ｎ−（β−ヒドロキ
シエチル）アミノ−５−ヒドロキシニトロベンゼン、３
−メトキシ−４−Ｎ−（β−ヒドロキシエチル）アミノ
ニトロベンゼン、４−ニトロ−３−メチルアミノフェノ
キシエタノール、２−Ｎ−（β−ヒドロキシエチル）ア
ミノ−５−アミノニトロベンゼン、２−Ｎ−（β−ヒド
ロキシエチル）アミノニトロベンゼン、３−アミノ−４
−Ｎ−（β−ヒドロキシエチル）アミノニトロベンゼ
ン、３−β−ヒドロキシエチロキシ−４−Ｎ−（β−ヒ
ドロキシエチル）アミノニトロベンゼン、２−アミノ−
５−Ｎ−メチルアミノニトロベンゼン、２−アミノ−３
−メチルニトロベンゼン、２−Ｎ−（β−ヒドロキシエ
チル）アミノ−５−β，γ−ジヒドロキシプロピロキシ
ニトロベンゼン、３−ヒドロキシ−４−Ｎ−（β−ヒド
ロキシエチル）アミノニトロベンゼン、３−ヒドロキシ
−４−アミノニトロベンゼン、２，５−Ｎ，Ｎ′−β−
ヒドロキシエチルアミノニトロベンゼン、２−Ｎ−（β
−アミノエチル）アミノ−５−Ｎ，Ｎ−ビス−（β−ヒ
ドロキシエチル）アミノニトロベンゼン、２−Ｎ−（β
−アミノエチル）アミノ−４−メトキシニトロベンゼ
ン、２−Ｎ−（β−アミノエチル）アミノ−５−（β−
ヒドロキシエチル）アミノニトロベンゼンなど、及び特
に有用なものとしては、１−アミノ−４−メチルアミノ
アントラキノン、１，４−ジアミノアントラキノン、２
−アミノ−４−ニトロフェノール、２−アミノ−５−ニ
トロフェノール、２−ニトロパラフェニレンジアミン、
４−ニトロオルトフェニレンジアミン、塩酸２−ニトロ
パラフェニレンジアミン、２−アミノ−４，６−ジニト
ロフェノール、２−アミノ−４，６−ジニトロフェノー
ルナトリウム、２，４，６−トリニトロフェノール、硫
酸２−アミノ−５−ニトロフェノール、硫酸ニトロパラ
フェニレンジアミン、硫酸４−ニトロオルトフェニレン
ジアミン、硫酸４−ニトロメタフェニレンジアミン、２
−ヒドロキシ−５−ニトロ−２′−４′−ジアミノアゾ
ベンゼン−５′−スルホン酸ナトリウム、パラアミノフ
ェニルスルファミン酸が挙げられる。Examples of the cationic direct dye compounded in the first agent of the present invention include 3-amino-4-hydroxynitrobenzene, 2-amino-5-hydroxynitrobenzene, 2-amino-3-hydroxynitrobenzene and 2
-Amino-4-hydroxynitrobenzene, 2-amino-5-N, N-bis- (β-hydroxyethyl) aminonitrobenzene, 2-amino-4-chloro-5-N-
(Β-hydroxyethyl) aminonitrobenzene, 3,
4-bis- (N-β-hydroxyethylamino) nitrobenzene, 2-amino-4-methyl-5-N- (β, γ
-Dihydroxypropylamino) nitrobenzene, 2-
Amino-4-methyl-5- (β-aminoethyl) aminonitrobenzene, 3,4-diaminonitrobenzene,
2,5-diaminonitrobenzene, 2-amino-5-N
-(Β-hydroxyethyl) aminonitrobenzene, 2
-N- (β-hydroxyethyl) amino-5-N, N-
Bis- (β-hydroxyethyl) aminonitrobenzene, 2-N-methylamino-5-N, N-bis- (β-
Hydroxyethyl) aminonitrobenzene, 2-N-methylamino-5-N-methyl-N- (β-hydroxyethyl) aminonitrobenzene, 2-N- (β-hydroxyethyl) amino-5-hydroxynitrobenzene, 3
-Methoxy-4-N- (β-hydroxyethyl) aminonitrobenzene, 4-nitro-3-methylaminophenoxyethanol, 2-N- (β-hydroxyethyl) amino-5-aminonitrobenzene, 2-N- (β- Hydroxyethyl) aminonitrobenzene, 3-amino-4
-N- (β-hydroxyethyl) aminonitrobenzene, 3-β-hydroxyethyloxy-4-N- (β-hydroxyethyl) aminonitrobenzene, 2-amino-
5-N-methylaminonitrobenzene, 2-amino-3
-Methylnitrobenzene, 2-N- (β-hydroxyethyl) amino-5-β, γ-dihydroxyproproxynitrobenzene, 3-hydroxy-4-N- (β-hydroxyethyl) aminonitrobenzene, 3-hydroxy-4- Aminonitrobenzene, 2,5-N, N'-β-
Hydroxyethylaminonitrobenzene, 2-N- (β
-Aminoethyl) amino-5-N, N-bis- (β-hydroxyethyl) aminonitrobenzene, 2-N- (β
-Aminoethyl) amino-4-methoxynitrobenzene, 2-N- (β-aminoethyl) amino-5- (β-
Hydroxyethyl) aminonitrobenzene and the like, and particularly useful ones are 1-amino-4-methylaminoanthraquinone, 1,4-diaminoanthraquinone, 2
-Amino-4-nitrophenol, 2-amino-5-nitrophenol, 2-nitroparaphenylenediamine,
4-nitroorthophenylenediamine, 2-nitroparaphenylenediamine hydrochloride, 2-amino-4,6-dinitrophenol, 2-amino-4,6-dinitrophenol sodium, 2,4,6-trinitrophenol, sulfuric acid 2 -Amino-5-nitrophenol, nitroparaphenylenediamine sulfate, 4-nitroorthophenylenediamine sulfate, 4-nitrometaphenylenediamine sulfate, 2
-Hydroxy-5-nitro-2'-4'-diaminoazobenzene-5'-sodium sulfonate, para-aminophenylsulfamic acid are mentioned.
【０００８】これらのカチオン性直接染料は、単独で又
は２種以上を混合して用いることができ、色調にもよる
が０．１％〜５．０％重量配合することが好ましく、特
には、０．１５％〜２．０％配合することが好ましい。These cationic direct dyes may be used alone or in admixture of two or more, and depending on the color tone, it is preferable to add 0.1% to 5.0% by weight, and particularly, It is preferable to add 0.15% to 2.0%.
【０００９】このような第１剤中には、例えばＬＰＧな
どの易揮発性の液化ガスや炭酸ガスなどの発泡剤や発泡
助剤を予め配合しておいて泡状化することが望ましい
が、別途に用意した発泡剤や発泡手段を併用して泡状化
するようにしてもよい。またポリペプチド、カチオン性
ポリペプチド、カチオン化セルロース等の高分子類など
のコンディショニング剤、金属封鎖剤、増粘剤、ｐＨ調
整剤、安定剤、香料等などの公知配合剤を必要に応じて
配合することができる。It is desirable that a foaming agent such as LPG or a volatile gas such as LPG or a foaming auxiliary agent such as carbon dioxide gas is previously mixed in the first agent to form a foam. A foaming agent or foaming means prepared separately may be used together to form a foam. In addition, known additives such as conditioning agents for polymers such as polypeptides, cationic polypeptides and cationized celluloses, sequestering agents, thickeners, pH adjusters, stabilizers, fragrances, etc. may be added as necessary. can do.
【００１０】本発明の第２剤に配合される酸化剤として
は、過酸化水素、過ほう酸ナトリウム、過炭酸ナトリウ
ム、過酸化尿素、硫酸ナトリウム−過酸化水素付加物、
第２燐酸ナトリウム−過酸化水素付加物、ピロ燐酸ナト
リウム−過酸化水素付加物等が挙げられる。As the oxidizer to be added to the second agent of the present invention, hydrogen peroxide, sodium perborate, sodium percarbonate, urea peroxide, sodium sulfate-hydrogen peroxide adduct,
Examples thereof include secondary sodium phosphate-hydrogen peroxide adducts, sodium pyrophosphate-hydrogen peroxide adducts, and the like.
【００１１】このような第２剤中にも、第１剤と同様に
発泡剤や発泡助剤を予め配合しておいて泡状化するよう
にしても、或いは別途に用意した発泡剤や発泡手段を併
用して泡状化するようにしてもよい。また安定剤、増粘
剤、金属封鎖剤、ｐＨ調整剤等の公知配合剤を必要に応
じて配合することができる。Like the first agent, a foaming agent or a foaming auxiliary agent may be pre-blended into the second agent to form a foam, or a separately prepared foaming agent or a foaming agent. You may make it foam by using a means together. In addition, known compounding agents such as a stabilizer, a thickener, a sequestering agent, and a pH adjusting agent can be added as necessary.
【００１２】本発明の剤型は上記の２剤型のものであっ
て、使用する際に泡状としてから混合してｐＨが６．０
乃至１０．０の範囲に調整されていればよい。The dosage form of the present invention is the above-mentioned two-part dosage form, and when used, it is foamed and mixed to have a pH of 6.0.
It suffices if it is adjusted within the range of 1 to 10.0.
【００１３】[0013]
【作用】本発明の毛髪染色剤は、泡状とした第１剤と泡
状とした第２剤とを所望のｐＨとなるように混合して毛
髪に塗布したのち、スチーマーや赤外線加温器等を用い
て塗布部分を加温すると短時間で毛髪に染色と明度の調
整を行うことができ、毛髪の損傷や仕上がり感の低下等
を生ずることはない。The hair dye of the present invention is prepared by mixing the foam-like first agent and the foam-like second agent so as to have a desired pH and applying the mixture to the hair, and then a steamer or an infrared warmer. When the applied portion is heated by using, for example, the hair can be dyed and the lightness can be adjusted in a short time, and the hair is not damaged and the finished feeling is not deteriorated.
【００１４】[0014]
【実施例】以下実施例によって本発明を更に詳細に説明
するが、本発明は実施例の記載によって何等限定される
ものではない。 （実施例１）以下の処方により第１剤及び第２剤を用意
した。The present invention will be described in more detail with reference to the following examples, but the present invention is not limited to the description of the examples. (Example 1) The 1st agent and the 2nd agent were prepared by the following prescription.
【表１】第１剤 ： ステアリルアルコール ２．０重量％ ポリオキシエチレン（25）ラウリルエーテル １．０重量％ ラウリルジメチルアミンオキサイド １．０重量％ ジプロピレングリコール ５．０重量％ ４−ニトロオルトフェニレンジアミン ０．５重量％ 炭酸水素アンモニウム ３．０重量％ ２５％アンモニア水 ｐＨ９．０とする量 液化石油ガス(5.0kg/cm3・ at25℃） ８．０重量％ 精製水 残量[Table 1] First agent : stearyl alcohol 2.0% by weight polyoxyethylene (25) lauryl ether 1.0% by weight lauryl dimethylamine oxide 1.0% by weight dipropylene glycol 5.0% by weight 4-nitroorthophenylene Diamine 0.5% by weight Ammonium hydrogen carbonate 3.0% by weight 25% Ammonia water pH 9.0 amount Liquefied petroleum gas (5.0 kg / cm 3 · at 25 ° C) 8.0% by weight Purified water balance
【表２】第２剤 ： ステアリルアルコール ２．０重量％ ポリオキシエチレン（25）ラウリルエーテル １．０重量％ ラウリルジメチルアミンオキサイド １．０重量％ ３５％過酸化水素水 １５．６重量％ 液化石油ガス(5.0kg/cm3・ at25℃） ８．０重量％ 精製水 残量[Table 2] Second agent : stearyl alcohol 2.0% by weight polyoxyethylene (25) lauryl ether 1.0% by weight lauryldimethylamine oxide 1.0% by weight 35% hydrogen peroxide solution 15.6% by weight Liquefied petroleum Gas (5.0kg / cm 3 at 25 ℃) 8.0wt% Purified water Remaining amount
【００１５】第１剤と第２剤をそれぞれ６０ｇずつ発泡
させながら採って十分に混合し、ｐＨ調整剤を加えてｐ
Ｈが８．８となるよう調整したのち、この毛髪染色剤を
刷毛で毛束に塗布し、５０℃の恒温槽に入れて１５分間
放置した後よく洗浄し、乾かした。染色処理した毛束に
ついては、下記の試験方法によって染色力、明度調整
（ブリーチ力）及び、毛髪損傷を調べ、その結果を表３
に示した。60 g of each of the first agent and the second agent were taken while being foamed and mixed thoroughly, and a pH adjusting agent was added to add p.
After adjusting the H to 8.8, the hair dye was applied to the hair bundle with a brush, placed in a constant temperature bath at 50 ° C., left for 15 minutes, washed well, and dried. For the dyed hair bundle, the dyeing power, lightness adjustment (bleaching power) and hair damage were examined by the following test methods, and the results are shown in Table 3.
It was shown to.
【００１６】染色力（色調）：ミルタ色彩色差計ＣＲ−
２００を用いて処理毛を測定し、ａ値及びｂ値で評価し
た。（ａ値の数値が大きい程赤色が強く、ｂ値の数値が
大きい程黄色が強い。）明度調整 ：ミルタ色彩色差計ＣＲ−２００を用いて処理
毛を測定し、Ｌ（ブリーチ力）値で評価した。（Ｌ値の
数値が大きい程明度が明るくブリーチ力が大である。）毛髪損傷 ：顕微鏡で毛髪の表面の状態を調べた。 Dyeing power (color tone) : Mirta color difference meter CR-
The treated hair was measured using 200 and evaluated by a value and b value. (The larger the value of the a value, the stronger the red color, and the larger the value of the b value, the stronger the yellow color.) Lightness adjustment : The treated hair is measured by using a Milta color difference meter CR-200, and the L (bleaching force) value is used. evaluated. (The larger the L value, the brighter the lightness and the larger the bleaching power.) Hair damage : The surface condition of the hair was examined with a microscope.
【００１７】（比較例１）４−ニトロオルトフェニレン
ジアミンを加えないほかは実施例１の第１剤と同様な配
合の第１剤６０ｇと実施例１の第２剤６０ｇを発泡させ
ながら採って十分に混合し、ｐＨ調整剤を加えてｐＨが
８．８となるよう調整し、この毛髪染色剤を刷毛で毛束
に塗布し、５０℃の恒温槽に入れて１５分間放置した後
よく洗浄し、乾かした。染色処理した毛束については、
実施例１と同様に染色力、ブリーチ力、毛髪損傷を調べ
て、その結果を表３に併せて示した。(Comparative Example 1) 60 g of a first agent and 60 g of a second agent of Example 1 having the same composition as the first agent of Example 1 except that 4-nitroorthophenylenediamine was not added were taken while foaming. Mix thoroughly, adjust the pH to 8.8 by adding a pH adjuster, apply this hair dye to the hair bundle with a brush, put it in a constant temperature bath at 50 ° C and leave it for 15 minutes, then wash it well. And dried. For dyed hair bundles,
The dyeing power, bleaching power and hair damage were examined in the same manner as in Example 1, and the results are also shown in Table 3.
【００１８】（比較例２）比較例１の第１剤６０ｇと実
施例１の第２剤６０ｇとを発泡させながら採って、ｐＨ
が１０．５となるよう調整したほかは比較例１と全く同
様にして染色力、ブリーチ力、毛髪損傷を調べて、その
結果を表３に併せて示した。表３から明らかなように、
本発明の毛髪染色剤は色調及び明度の調整が容易であ
り、しかも毛髪の損傷がないという優れた性能を有して
いる。(Comparative Example 2) 60 g of the first agent of Comparative Example 1 and 60 g of the second agent of Example 1 were taken while foaming, and the pH was adjusted.
The dyeing power, bleaching power and hair damage were examined in the same manner as in Comparative Example 1 except that the result was adjusted to be 10.5. The results are also shown in Table 3. As is clear from Table 3,
The hair dye of the present invention has an excellent performance that the color tone and the lightness can be easily adjusted and the hair is not damaged.
【００１９】[0019]
【表３】 [Table 3]
【００２０】（実施例２）以下の処方により第１剤及び
第２剤を用意した。Example 2 A first agent and a second agent were prepared according to the following formulations.
【表４】第１剤 ： ステアリルアルコール ２．０重量％ ポリオキシエチレン（25）ラウリルエーテル １．０重量％ ラウリルジメチルアミンオキサイド １．０重量％ ジプロピレングリコール ５．０重量％ ２−ニトロパラフェニレンジアミン １．０重量％ 炭酸水素アンモニウム ３．０重量％ ２５％アンモニア水 ｐＨ９．０とする量 液化石油ガス(5.0kg/cm3・ at25℃） ８．０重量％ 精製水 残量[Table 4] First agent : stearyl alcohol 2.0% by weight polyoxyethylene (25) lauryl ether 1.0% by weight lauryldimethylamine oxide 1.0% by weight dipropylene glycol 5.0% by weight 2-nitroparaphenylene Diamine 1.0% by weight Ammonium hydrogen carbonate 3.0% by weight 25% Ammonia water pH 9.0 quantity Liquefied petroleum gas (5.0 kg / cm 3 at 25 ° C) 8.0% by weight Purified water remaining amount
【表５】第２剤 ： ステアリルアルコール ２．０重量％ ポリオキシエチレン（25）ラウリルエーテル １．０重量％ ラウリルジメチルアミンオキサイド １．０重量％ ３５％過酸化水素水 １５．６重量％ 液化石油ガス(5.0kg/cm3・ at25℃） ８．０重量％ 精製水 残量[Table 5] Second agent : Stearyl alcohol 2.0% by weight Polyoxyethylene (25) lauryl ether 1.0% by weight Lauryl dimethylamine oxide 1.0% by weight 35% Hydrogen peroxide water 15.6% by weight Liquefied petroleum Gas (5.0kg / cm 3 at 25 ℃) 8.0wt% Purified water Remaining amount
【００２１】泡状第１剤と泡状第２剤をそれぞれ６０ｇ
ずつ採って十分混合し、ｐＨ調整剤を加えてｐＨが８．
８となるよう調整し、この毛髪染色剤をそれぞれ６名の
モニター（Ａ〜Ｅ）の頭髪の右半分に塗布した。なお比
較の為に、２−ニトロパラフェニレンジアミンを加えな
いほかは上記の第１剤と全く同様の配合の第１剤を用い
て、上記と同様にしてｐＨが８．８となるよう調整した
毛髪染色剤を３名のモニター（Ａ〜Ｃ）の頭髪の左半分
に塗布した。又同様にｐＨが１０．５となるよう調整し
た毛髪染色剤を３名のモニター（Ｄ〜Ｆ）の頭髪の左半
分に塗布した。その後室温で３０分間放置したのち、十
分に洗浄し乾かした。処理後の毛髪の染色力、明度及び
仕上がり感について美容師の評価を受け、その結果を表
６にまとめた。表６から明らかなように、本発明の毛髪
染色剤は染色と明度調整を行うにあたって毛髪の損傷な
く、良好な仕上がり感を得ることができる優れた性能を
有している。60 g of each of the foamy first agent and the foamy second agent
Each of them is mixed well and a pH adjuster is added to adjust the pH to 8.
The hair dye was adjusted to 8 and this hair dye was applied to the right half of the hair of each of 6 monitors (AE). For comparison, the pH was adjusted to 8.8 in the same manner as above using the first agent having the same formulation as the first agent except that 2-nitroparaphenylenediamine was not added. The hair dye was applied to the left half of the hair of three monitors (AC). Similarly, a hair dyeing agent adjusted to have a pH of 10.5 was applied to the left half of the hairs of three monitors (DF). Then, after leaving it at room temperature for 30 minutes, it was thoroughly washed and dried. A hairdresser evaluated the dyeing power, lightness and finish of the treated hair, and the results are summarized in Table 6. As is clear from Table 6, the hair dyeing agent of the present invention has an excellent ability to obtain a good feeling of finish without damaging the hair when dyeing and adjusting the lightness.
【００２２】[0022]
【表６】 [Table 6]
【００２３】（実施例３）以下の処方により第１剤及び
第２剤を用意した。Example 3 A first agent and a second agent were prepared by the following prescription.
【表７】第１剤 ： ステアリルアルコール ２．０重量％ ポリオキシエチレン（25）ラウリルエーテル １．０重量％ ラウリルジメチルアミンオキサイド １．０重量％ ジプロピレングリコール ５．０重量％ ２−アミノ−５−ニトロフェノール １．０重量％ 炭酸水素アンモニウム ３．０重量％ ２５％アンモニア水 ｐＨ９．０とする量 液化石油ガス(5.0kg/cm3・ at25℃） ８．０重量％ 精製水 残量[Table 7] First agent : stearyl alcohol 2.0% by weight polyoxyethylene (25) lauryl ether 1.0% by weight lauryldimethylamine oxide 1.0% by weight dipropylene glycol 5.0% by weight 2-amino-5 - nitrophenol 1.0 wt% amount liquefied petroleum gas and ammonium hydrogen carbonate 3.0% by weight of 25% aqueous ammonia pH9.0 (5.0kg / cm 3 · at25 ℃) 8.0 wt% purified water Balance
【表８】第２剤 ： ステアリルアルコール ２．０重量％ ポリオキシエチレン（25）ラウリルエーテル １．０重量％ ラウリルジメチルアミンオキサイド １．０重量％ ３５％過酸化水素水 １５．６重量％ 液化石油ガス(5.0kg/cm3・ at25℃） ８．０重量％ 精製水 残量[Table 8] Second agent : stearyl alcohol 2.0% by weight polyoxyethylene (25) lauryl ether 1.0% by weight lauryldimethylamine oxide 1.0% by weight 35% hydrogen peroxide solution 15.6% by weight Liquefied petroleum Gas (5.0kg / cm 3 at 25 ℃) 8.0wt% Purified water Remaining amount
【００２４】泡状第１剤と泡状第２剤をそれぞれ６０ｇ
ずつ採って十分混合し、ｐＨ調整剤を加えてｐＨが８．
８となるように調整し、この毛髪染色剤をそれぞれ６名
のモニター（Ｇ〜Ｌ）の頭髪の右半分に塗布した。なお
比較の為に２−アミノ−５−ニトロフェノールを加えな
いほかは全く同様にしてｐＨが８．８となるよう調整し
た毛髪染色剤を３名のモニター（Ｇ〜Ｉ）の頭髪の左半
分に塗布した。又同様にｐＨが１０．５となるよう調整
した毛髪染色剤を３名のモニター（Ｊ〜Ｌ）の頭髪の左
半分に塗布した。その後室温で３０分間放置したのち、
十分に洗浄し乾かした。処理後の毛髪の染色力、明度及
び仕上がり感について美容師の評価を受け、その結果を
表９にまとめた。表９から明らかなように、本発明の毛
髪染色剤は染色と明度調整を行うにあたって毛髪の損傷
なく、良好な仕上がり感を得ることができる優れた性能
を有している。60 g of each of the foamy first agent and the foamy second agent
Each of them is mixed well and a pH adjuster is added to adjust the pH to 8.
The hair dye was adjusted to be 8, and the hair dye was applied to the right half of the hair of each of 6 monitors (G to L). For comparison, a hair dye adjusted to pH 8.8 in exactly the same manner except that 2-amino-5-nitrophenol was not added, and the left half of the hair of three monitors (GI). Was applied to. Similarly, a hair dyeing agent adjusted to have a pH of 10.5 was applied to the left half of the hair of three monitors (JL). After leaving it for 30 minutes at room temperature,
Thoroughly washed and dried. A hairdresser evaluated the dyeing power, lightness and finish of the treated hair, and the results are summarized in Table 9. As is clear from Table 9, the hair dyeing agent of the present invention has an excellent ability to obtain a good feeling of finish without damaging the hair when dyeing and adjusting the lightness.
【００２５】[0025]
【表９】 [Table 9]
【００２６】（実施例４）以下の処方により第１剤及び
第２剤を用意した。Example 4 A first agent and a second agent were prepared according to the following formulations.
【表１０】第１剤 ： ステアリルアルコール ２．０重量％ ポリオキシエチレン（25）ラウリルエーテル １．０重量％ ラウリルジメチルアミンオキサイド １．０重量％ カチオン化セルロース １．０重量％ ジプロピレングリコール ５．０重量％ １，４−ジアミノアントラキノン １．０重量％ 炭酸水素アンモニウム ３．０重量％ ２５％アンモニア水 ｐＨ９．０とする量 液化石油ガス(5.0kg/cm3・ at25℃） ８．０重量％ 精製水 残量[Table 10] First agent : stearyl alcohol 2.0% by weight polyoxyethylene (25) lauryl ether 1.0% by weight lauryldimethylamine oxide 1.0% by weight cationized cellulose 1.0% by weight dipropylene glycol 5. 0% by weight 1,4-diaminoanthraquinone 1.0% by weight Ammonium hydrogen carbonate 3.0% by weight 25% Aqueous ammonia pH 9.0 liquefied petroleum gas (5.0 kg / cm 3 at 25 ° C) 8.0% by weight Purified water Remaining amount
【表１１】第２剤 ： ステアリルアルコール ２．０重量％ ポリオキシエチレン（25）ラウリルエーテル １．０重量％ ラウリルジメチルアミンオキサイド １．０重量％ ３５％過酸化水素水 １５．６重量％ 液化石油ガス(5.0kg/cm3・ at25℃） ８．０重量％ 精製水 残量[Table 11] Second agent : stearyl alcohol 2.0% by weight polyoxyethylene (25) lauryl ether 1.0% by weight lauryldimethylamine oxide 1.0% by weight 35% hydrogen peroxide water 15.6% by weight Liquefied petroleum Gas (5.0kg / cm 3 at 25 ℃) 8.0wt% Purified water Remaining amount
【００２７】本例の第２剤は、第１剤と第２剤を混合し
たときのｐＨが８．８となるようあらかじめ調整したも
のである。このような泡状第１剤と泡状第２剤を用いて
３名のモニターの頭髪の右半分に塗布し施術時間の計測
を行った。なお比較のために一般に使用されているクリ
ームタイプの染色剤をモニターの頭髪の左半分に塗布し
同様に施術時間の計測を行いその結果を表１２にまとめ
た。なお、モニターの毛髪量により施術時間のバラツキ
を少なくするため、採用した３名のモニターはすべてミ
ディアムヘアーとした。表１２から明らかなように、本
発明の毛髪染色剤は第１剤及び第２剤の計量並びにそれ
らの混合等の作業工程が不要であり、専用ブラシ又は毛
髪へ直接塗布したのちコーミングすることにより第１剤
と第２剤とを毛髪の上で混合することができ、短時間で
の塗布が可能となるばかりでなく、全作業時間も短縮さ
れていることがわかる。The second agent of this example was previously adjusted so that the pH when the first agent and the second agent were mixed was 8.8. The foamy first agent and the foamy second agent were applied to the right half of the hair of three monitors, and the treatment time was measured. For comparison, a commonly used cream type dye was applied to the left half of the hair of the monitor, and the treatment time was measured in the same manner, and the results are summarized in Table 12. In addition, in order to reduce the variation in the treatment time depending on the amount of hair on the monitor, all three monitors employed were medium hair. As is clear from Table 12, the hair dye of the present invention does not require work steps such as weighing of the first agent and the second agent and mixing thereof, and is applied directly to a dedicated brush or hair and then combed. It can be seen that the first agent and the second agent can be mixed on the hair and not only the application in a short time is possible, but also the total working time is shortened.
【００２８】[0028]
【表１２】 [Table 12]
【００２９】[0029]
【発明の効果】本発明の毛髪染色剤は第１剤及び第２剤
がいずれも泡状であり、専用ブラシを使用することによ
って、簡便な使用方法で短時間に施術することが可能と
なり、ｐＨ６．０〜１０．０の領域で毛髪を種々の色調
に染色すると同時に明度調整を行うにあたり、毛髪に損
傷を与えず良好な仕上がり感を得ることができ、優れた
コンディショニング効果を長期にわたり持続できる効果
を有している。EFFECT OF THE INVENTION In the hair dyeing agent of the present invention, both the first agent and the second agent are foamy, and by using a dedicated brush, it becomes possible to perform the treatment in a short time by a simple use method, When dyeing hair in various color tones and adjusting lightness in the range of pH 6.0 to 10.0, a good finish feeling can be obtained without damaging the hair, and an excellent conditioning effect can be maintained for a long period of time. Have an effect.
Claims (3)
第１剤と過酸化水素等の酸化剤を主成分とする泡状第２
剤とからなる泡状の毛髪染色剤。1. A foamy first agent containing a cationic direct dye as a main component and a foamy second agent containing an oxidizing agent such as hydrogen peroxide as a main component.
A foamy hair dye consisting of an agent.
系又は黄色系の染料を用いた請求項１に記載の毛髪染色
剤。2. The hair dye according to claim 1, wherein a red or yellow dye is used as the cationic direct dye of the first agent.
り、ｐＨが６．０〜１０．０の範囲内にある請求項１又
は２に記載の毛髪染色剤。3. The hair dyeing agent according to claim 1, which is formed by mixing a foamy first agent and a foamy second agent and has a pH in the range of 6.0 to 10.0.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6030093A JPH06271435A (en) | 1993-03-19 | 1993-03-19 | Hair dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6030093A JPH06271435A (en) | 1993-03-19 | 1993-03-19 | Hair dye |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH06271435A true JPH06271435A (en) | 1994-09-27 |
Family
ID=13138188
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6030093A Pending JPH06271435A (en) | 1993-03-19 | 1993-03-19 | Hair dye |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH06271435A (en) |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4868750A (en) * | 1971-12-21 | 1973-09-19 |
-
1993
- 1993-03-19 JP JP6030093A patent/JPH06271435A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4868750A (en) * | 1971-12-21 | 1973-09-19 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5980587A (en) * | 1995-12-01 | 1999-11-09 | L'oreal | Method for dyeing keratin fibers with a dye compositions containing at least one direct dye and at least one basifying agent |
| US6368360B2 (en) | 1995-12-01 | 2002-04-09 | L'oreal S.A. | Method for dyeing keratin fibres with a dye composition containing at least one direct dye and a least one basifying agent |
| US6592630B2 (en) | 2000-03-17 | 2003-07-15 | Kao Corporation | Hair dye composition |
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| US6547834B1 (en) | 2000-03-17 | 2003-04-15 | Kao Corporation | Hair dye composition |
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| US6746493B2 (en) | 2000-04-07 | 2004-06-08 | Kao Corporation | Hair dye composition |
| EP1170000A1 (en) * | 2000-06-27 | 2002-01-09 | Kao Corporation | Hair dye composition |
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| EP2168634A2 (en) | 2002-09-13 | 2010-03-31 | Kao Corporation | Hair dye composition comprising methine dye |
| US7056355B2 (en) | 2002-09-16 | 2006-06-06 | Kao Corporation | Hair dye composition and dyeing method |
| US7169194B2 (en) | 2002-12-23 | 2007-01-30 | L'oreal S.A. | Dye composition comprising at least one particular tricationic direct dye, dyeing process, use and multi-compartment devices |
| US8153108B2 (en) | 2003-04-25 | 2012-04-10 | Kao Corporation | Hair cosmetic product |
| US8158112B2 (en) | 2003-04-25 | 2012-04-17 | Kao Corporation | Hair cosmetic product |
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| US8277784B2 (en) | 2003-04-25 | 2012-10-02 | Kao Corporation | Hair cosmetic product |
| EP1535599A1 (en) | 2003-11-28 | 2005-06-01 | Kao Corporation | Method effecting a reversible colour change of dyed hair |
| US7766976B2 (en) | 2004-12-02 | 2010-08-03 | The Procter & Gamble Company | Polymer thickened hair colouring and bleaching compositions |
| US7875269B2 (en) | 2004-12-02 | 2011-01-25 | The Procter & Gamble Company | Thickened hair colourant and bleaching compositions |
| JP2008521833A (en) * | 2004-12-02 | 2008-06-26 | ザ プロクター アンド ギャンブル カンパニー | Hair dyeing composition |
| JP2007314524A (en) * | 2006-04-25 | 2007-12-06 | Kao Corp | Hair cosmetic |
| US7887600B2 (en) | 2006-07-12 | 2011-02-15 | The Procter & Gamble Company | Gel network surfactant based thickening systems for hair colourant and bleaching compositions |
| US7824449B2 (en) | 2007-04-26 | 2010-11-02 | Kao Corporation | Hair dye composition |
| US10226649B2 (en) | 2007-04-27 | 2019-03-12 | Kao Corporation | Hair dyeing or bleaching method |
| US8388696B2 (en) | 2007-04-27 | 2013-03-05 | Kao Corporation | Two-part hair dye or bleach composition |
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| US8152858B2 (en) | 2007-10-24 | 2012-04-10 | Kao Corporation | Head hair dyeing method |
| US8349022B2 (en) | 2009-03-11 | 2013-01-08 | Kao Corporation | Two-part hair dye |
| US8449627B2 (en) | 2009-03-11 | 2013-05-28 | Kao Corporation | Two-part hair dye |
| WO2011065550A1 (en) * | 2009-11-30 | 2011-06-03 | 花王株式会社 | Two-part hair dye |
| CN102647976A (en) * | 2009-11-30 | 2012-08-22 | 花王株式会社 | Two-part hair dye |
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