CN103140210A - Hair cosmetic composition, method for using same, and hair-cosmetic-related product - Google Patents

Abstract

Disclosed is a hair cosmetic composition that is made into a foam by a non-aerosol foamer container and applied to hair. Said composition produces a good foam, coats well, and does not drip off during application. Said hair cosmetic composition contains: (A) at least 10% by mass of a non-ionic surfactant; (B) a cationic surfactant; and (C) at least one surfactant selected from among anionic surfactants and ampholytic surfactants.

Description

Cosmetic hair composition, its using method and hair cosmetic product

Technical field

The present invention relates to cosmetic hair composition, its using method and hair cosmetic product.More specifically, the present invention relates to form cosmetic hair composition, its using method that the blister dosage form uses and contain this cosmetic hair composition and hair cosmetic product that non-aerosol foam container consists of by non-aerosol foam container (ノ Application エ ア ゾ ー Le フ ォ ー マ ー container).

Background technology

The known hair cosmetic composition such as stain that in use decolouring of hair dye or hair taken off forms the blister dosage form and uses.If use these hair cosmetic compositions with the blister dosage form, can expect following advantage: be easy to immaculate and coat equably on hair; Even do not make hair cosmetic composition be high viscosity, also can prevent drippage in the time of on coating hair; Can save the worry of widely used gel or the hair adhesion in use of emulsifiable paste shape hair cosmetic composition etc.

The hair cosmetic composition that uses with the blister dosage form can roughly be divided into aerosol-type and non-aerosol-type.Aerosol-type uses the such propellant of liquefied gas, forms bubble so that dosage form is formed blister by utilizing aerosol.Non-aerosol-type does not use propellant, and the bubble of use pump foamite system or crushed foam device, other non-aerosol foam container (being designated hereinafter simply as " Foam Container ") formation parcel air forms blister with dosage form.

Technical literature formerly

Patent documentation

Patent documentation 1: Japanese kokai publication hei 09-136818 communique

Patent documentation 2: Japanese kokai publication hei 10-287534 communique

Patent documentation 3: TOHKEMY 2007-291015 communique

Patent documentation 4: TOHKEMY 2008-291020 communique.

Disclose by aerosol in above-mentioned patent documentation 1, patent documentation 2 dosage form has been formed oxide hair dye composition or the hair coloring preparation composition that blister uses.In addition, disclose in above-mentioned patent documentation 3, patent documentation 4 and by non-aerosol foam container, dosage form has been formed hair dye that blister uses etc.

Summary of the invention

Invent problem to be solved

, in non-aerosol-type blister hair cosmetic composition, although easily obtain with the affinity of hair or the relative good foam of ductility when coating hair, have form be easy to through the time the tendency of foam of froth breaking.

For eliminating the above-mentioned deficiency to non-aerosol-type blister hair cosmetic composition, for example consider that improvement is as the blending of the surfactant of foaming agent.

In patent documentation 1, patent documentation 2 in disclosed aerosol-type blister hair dye blending many surfactants.But, there are differences because the gentle bubble of the foaming of aerosol-type and non-aerosol-type mechanism consists of, so think that the action effect of the surfactant relevant with foaming characteristic and foam characteristic also differs widely.Therefore, directly with the blending of disclosed surfactant in these documents not as a reference.

In patent documentation 3 in 2 doses of formula hair depigmenting agent/hair dyes of disclosed non-aerosol-type blister, by the blending higher alcohol, in the preparation drippage, blending reaches the surfactant of 2 ~ 10 % by weight when mixing for 1 dose/2 doses when preventing from coating hair, the improvement foaming characteristic.But the effect of invention is special, is " foaming characteristic when guaranteeing the low temperature relevant with the blending higher alcohol ".As surfactant, preferred compositions is used anion surfactant and non-ionic surface active agent, and non-ionic surface active agent wherein uses in the scope of less than 10% weight when mixing for 1 dose/2 doses.

In patent documentation 4 in 2 doses of formula hair dye/hair depigmenting agents of disclosed non-aerosol-type blister, preferably use surfactant as foaming agent, but the main points of invention are the optimization of preparation viscosity, although relate to kind and the blending amount of the surfactant of blending, do not find how much to have disclosing of essential meaning.

For in above-mentioned formerly technical literature about the open situation of blending surfactant in the blister hair cosmetic composition, the application applicant has proposed in Japanese Patent Application No. 2009-247089 (TOHKEMY 2011-093820) by being blended into respectively as the ionic different surfactant of anionic surfactant and cationic surface active agent 1 dose and 2 doses to keep the cosmetic hair composition of blister dosage form.But, find when further furtheing investigate, in this cosmetic hair composition, with 1 dose when 2 doses are mixed, formed the insoluble matter of thinking the anionic-cationic complex, so when wishing to bubble by non-aerosol foam container, because such complex causes that discharge is poor, can't obtain the foam of high-quality.Therefore, the present invention with following problem as the technical task that should solve: the cosmetic hair composition that foam, the coating on hair that can obtain high-quality are excellent, do not drip when coating on hair is provided, and described compositions is for forming the blister dosage form to be applicable to the cosmetic hair composition of hair by non-aerosol foam container.

Solve the means of problem

(formation of the 1st invention)

Solve the constituting for forming the blister dosage form being applicable to the cosmetic hair composition of hair by non-aerosol foam container in use of the application the 1st invention of above-mentioned problem, described cosmetic hair composition contains the composition of following (A) composition ~ (C).

(A) the above nonionic surfactant of 10 quality %.

(B) cationic surface active agent.

(C) be selected from anionic surfactant and amphoteric surfactant more than a kind.

In above-mentioned the 1st invention, " more than 10 quality % " mean in 2 doses of formula cosmetic hair compositions, " being more than 10 quality % when the 2nd dose is mixed at the 1st dose ".Similarly, in present specification, as long as without particular provisions, stipulate that the numerical value of the content of certain composition all means in 2 doses of formula cosmetic hair compositions, " content at the 1st dose when the 2nd dose is mixed ".

(formation of the 2nd invention)

The cosmetic hair composition that constitutes above-mentioned the 1st invention for the application's the 2nd invention that solves above-mentioned problem, described cosmetic hair composition when using with the mixed liquor formation blister dosage form of the 1st dose and the 2nd dose to be applicable to 2 doses of formula compositionss of hair, it is blending (B) composition in described the 1st dose, blending (C) composition in described the 2nd dose.

(formation of the 3rd invention)

Hair composition for above-mentioned the 1st invention of constituting of the application's the 3rd invention that solves above-mentioned problem or the 2nd invention is cosmetic hair composition, and described cosmetic hair composition is that hair dye, hair depigmenting agent or hair take off stain.

(formation of the 4th invention)

Be used for solving the using method that constitutes cosmetic hair composition of the application's the 4th invention of above-mentioned problem, described using method forms the blister dosage form to be applicable to hair for the cosmetic hair composition with any one in the 1st invention the ~ the 3 invention by non-aerosol foam container.

(formation of the 5th invention)

Be used for solving above-mentioned problem the application's the 5th invention constitute the hair cosmetic product, described hair cosmetic product contains the cosmetic hair composition of any one in the 1st invention the ~ the 3 invention and is used for this cosmetic hair composition is formed the non-aerosol foam container of blister dosage form and consists of.

The effect of invention

According to the 1st invention, cosmetic hair composition can be provided, it can obtain the foam of high-quality when forming the blister dosage form by non-aerosol foam container, and meanwhile the coating on hair is excellent, does not drip when coating hair.

That is, as basic effect, contain the cationic surface active agent of (B) composition and (C) cosmetic hair composition of the anionic surfactant of composition can obtain the foam of thickness (モ チ モ チ) when forming the blister dosage form.But then, form the viewpoint of complex from the interaction due to these surfactants, if for non-aerosol foam container, cause its discharge poor.In addition, coat hair if cause discharging poor foam, the problem such as drippage when produce placing, steep aspect durability also unsatisfactory.

But, in the 1st invention, by further adding nonionic surfactant conduct (A) composition more than 10 quality %, the above-mentioned discharge that can eliminate non-aerosol foam container is poor, and then the film-strength of raising bubble, make bubble be difficult to disappear, obtain the foam of the aspect high-qualitys such as hardness of quality, bubble at foaming characteristic, bubble.The coating of this foam on hair (with the affinity of hair, coating time ductility) might as well, keep firm blister when coating hair, be difficult to froth breaking, so do not drip when placing.If not the blending quantity not sufficient 10 quality % of ionic surfactant can't fully obtain above-mentioned effect.

Need to prove, as (C) composition, also can use simultaneously amphoteric surfactant or replace anionic surfactant to use amphoteric surfactant with anionic surfactant.As everyone knows, amphoteric surfactant exists with anionic form in the pH zone of an alkaline side, exists with cationic form in the pH zone of an acid side.Oxide hair dye or hair take off stain and are alkalescence at the 1st dose when the 2nd dose is mixed.Therefore, in the situation that above-mentioned cosmetic hair composition, amphoteric surfactant shows in fact the behavior of anionic surfactant, demonstrates equally the above-mentioned action effect for the anionic surfactant narration.

According to the 2nd invention, by the cationic surface active agent of (B) composition of blending in the 1st dose is mixed with anionic surfactant or the amphoteric surfactant of (C) composition of blending in the 2nd dose, the foam of the thickness that generation forms because of both interaction, but due to both all contact till when the 2nd dose mix to bubble to the 1st dose, so the stability of each agent keeps well.

According to the 3rd invention, the hair dye, hair depigmenting agent or the hair that are provided as the particularly preferred embodiment of cosmetic hair composition take off stain.

According to the 4th invention, be provided for cosmetic hair composition is made good non-spray-type blister dosage form to be applicable to the effective ways of hair.

According to the 5th invention, provide and contain cosmetic hair composition and be used for this cosmetic hair composition is mixed the non-aerosol foam container that forms the blister dosage form and the easy hair cosmetic product that consists of.

The best mode that carries out an invention

Then, the enforcement that comprises best mode mode of the present invention is described.

[cosmetic hair composition]

Cosmetic hair composition of the present invention forms the blister dosage form to be applicable to the compositions of hair by non-aerosol foam container in use for being used for, as essential composition, contain respectively the surfactant more than a kind in anionic surfactant and amphoteric surfactant of being selected from of cationic surface active agent as the above nonionic surfactant of the 10 quality % of (A) composition, conduct (B) composition, conduct (C) composition.

Satisfying under the prerequisite of above condition, the kind indefinite of cosmetic hair composition, preferred hair dye, hair depigmenting agent or hair take off stain.As hair dye, but example goes out oxide hair dye or acidic hair coloring preparation, but particularly preferably example goes out oxide hair dye.

As cosmetic hair composition, also comprise 1 dose of formula compositions, but 2 doses of formula cosmetic hair compositions particularly preferably.In 2 doses of formula cosmetic hair compositions, also comprise the 1st dose or the 2nd dose of compositions that further is divided into a plurality of preparations and consists of.For example but example goes out in 2 doses of formula oxide hair dyes, replacement in the 1st dose in blending (B) composition in the 2nd dose the formation of blending (C) composition, the 1st dose of preparation that is divided into the preparation and the blending that contain the 1st dose of composition of common oxide hair dye and has (B) composition consisted of the situation of hair dye, or the 2nd dose of preparation that is divided into the preparation and the blending that contain the 2nd dose of composition of common oxide hair dye and has (C) composition consisted of the situation etc. of hair dye.

[the essential blending form of composition in the 1st dose and the 2nd dose]

When cosmetic hair composition is 2 doses of formulas, (A) the blending form basic indefinite of composition in the 1st dose and the 2nd dose of composition ~ (C), can select arbitrarily, but preferably will (B) composition be blended in mutually different preparation with (C) composition, particularly preferably respectively (B) composition is blended in the 1st dose, and (C) composition is blended in the 2nd dose.

When with (B) composition with (C) when composition is blended in mutually different preparation, be in by the mass ratio (C)/(B) that makes both blending amounts in 0.01 ~ 5 scope, be easier to keep the blister dosage form.By being in 0.05 ~ 2 scope, mass ratio (C)/(B) can make this effect more remarkable.

In above situation, (A) composition also can be blended in either party in the 1st dose and the 2nd dose, reaches under the prerequisite of 10 quality % in total blending amount, also can disperse to be blended in the both sides of the 1st dose and the 2nd dose.

In addition, in the 1st dose is in 2 doses of formula cosmetic hair compositions such as alkaline zone, the 2nd dose of 2 doses of formula oxide hair dyes that are in acidic region, when share anionic surfactant and amphoteric surfactant as (C) composition, as mentioned above, because amphoteric surfactant exists with anionic form in the 1st dose, exist with cationic form in the 2nd dose, so from preventing from forming the viewpoint of equilibrium ion, preferably with the identical mode blending amphoteric surfactant of the surfactant polarity in each agent.In addition, also each composition of composition of (A) composition ~ (C) only can be blended in either party in the 1st dose and the 2nd dose.When cosmetic hair composition was 1 dose of formula acidic hair coloring preparation etc., (A) composition ~ (C) each composition of composition was blended in same preparation.

[dosage form of cosmetic hair composition etc.]

The 1st dose and the 2nd dose of dosage form before foaming in dosage form as 1 dose of formula cosmetic hair composition before foaming or 2 doses of formula cosmetic hair compositions, for example can list solid, shaped, water-soluble aqueous, disperse aqueous, emulsion shape, gel, cystose and emulsifiable paste shape.As solid shaped dosage forms, for example can list Powdered and tablet.When making solid shaped dosage forms, the viewpoint of excellent dispersion, be preferably Powdered when mixing the 1st dose and the 2nd dose.Need to prove, for example when making solid shaped dosage forms with the 1st dose, make with the 2nd dose the preparation that contains water.In a word, in 1 dose of formula cosmetic hair composition, to the dosage form of its preparation without particular determination; In 2 doses of formula cosmetic hair compositions, if can guarantee the dosage form of each auto-flowability when the 2nd dose is mixed at its 1st dose, dosage form is without particular determination.

In addition, with regard to cosmetic hair composition, in the situation that 1 dose of formula, contain water in its preparation as the base material that is used for bubbling, in the situation that 2 doses of formulas, contain water as the base material that is used for foaming at least one party in the 1st dose and the 2nd dose.More than the content of water is preferably 40 quality %, more preferably more than 60 quality %.

[(A) composition]

(A) of the present invention composition is that in cosmetic hair composition, blending has the above nonionic surfactant of 10 quality %.Although (A) upper limit indefinite of composition blending amount for example can be limited in below 40 quality %.

As nonionic surfactant, but example goes out following material, but is not limited to this.Nonionic surfactant can use separately wherein a kind also can be with share more than 2 kinds wherein.If be particularly that hydrophilic nonionic agent more than 15 and HLB are, the lipophile nonionic agent of less than 15 share with HLB more than 9, the good stability of preparation.HLB (hydrophile-lipophile balance value: Hydrophile-Lipophile Balance) can calculate according to known Griffin formula.

1. POE alkyl ethers such as polyoxyethylene (being designated hereinafter simply as POE) cetyl ether, POE octadecyl ether, POE docosyl ether, POE oleyl ether, POE lauryl ether, POE tridecyl ether, POE octyl group lauryl ether, POE hexyl decyl ethers, POE isooctadecane base ether, POE decyl pentadecyl ether, POE decyl myristyl ether, POE alkyl (C12 ~ 14) ether.

2. the POE alkyl phenyl ether such as POE nonylplenyl ether, POE octyl phenyl ether.

3. POE sorbitan fatty esters such as POE dehydrating sorbitol monooleate, POE anhydrosorbitol monostearate, POE anhydrosorbitol list palmitate, POE sorbitan monolaurate, POE anhydrosorbitol trioleate.

4. the POE fatty acid monoglyceride such as POE glyceryl monostearate, POE monomyristin.

5. POE Spans such as POE sorbitol four oleates, POE sorbitol six stearates, POE sorbitan monolaurate, POE sorbitol Cera Flava.

6. POE castor oil hydrogenated, POE Oleum Ricini.

7. polyethylene glycol monooleate, polyethylene glycol mono stearate, polyethylene glycol monolaurate.

8. glycerol high-grade aliphatic esters such as lipophilic glycerin mono-fatty acid ester, lipophilic glyceryl monostearate, self-emulsifying type glyceryl monostearate.

9. sorbitan fatty esters such as dehydrating sorbitol monooleate, sorbitan sesquioleate, anhydrosorbitol trioleate, anhydrosorbitol monostearate, anhydrosorbitol list palmitate, sorbitan monolaurate.

10. lanolin derivatives such as POE lanoline, POE lanolin alcohol, POE sorbitol lanoline.

11. the alkanolamide such as lauric acid diethyl amide, cocoanut fatty acid diethanolamide.

12. the POE fatty acid amides such as POE stearmide.

13. sucrose fatty acid ester.

14. the alkyl amine oxides such as dimethyl dodecyl amine oxide.

15. the alkyl androstanediol such as lauryl glucoside, alkyl (8 ~ 16) glucoside.

16. lecithin derivant hydrogenated soy phosphatidyl choline, hydrogenated yolk lecithin etc.

[(B) composition]

(B) of the present invention composition is the cationic surface active agent of blending in cosmetic hair composition.Although (B) the blending amount indefinite of composition preferably sets in the scope of 0.1 ~ 10 quality %, particularly preferably is set in the scope of 0.5 ~ 5 quality %.

as cationic surface active agent, for example but example goes out Dodecyl trimethyl ammonium chloride, hexadecyltrimethylammonium chloride (cetrimonium chloride), octadecyl trimethyl ammonium chloride (octadecyl trimethyl ammonium chloride ス テ ア リ Le ト リ モ ニ ウ system Network ロ リ De), alkyl trimethyl ammonium chloride, docosyl trimethyl aluminum chloride (INCROQUAT TMC-80 ECONOL TM22 ベ ヘ ニ Le ト リ モ ニ ウ system Network ロ リ De), two (octadecyl) alkyl dimethyl ammonium chloride (two (octadecyl) alkyl dimethyl ammonium chloride), cetyl trimethyl ammonium bromide, Cetyltrimethylammonium bromide, lanolin fatty acid aminopropyl ethyl Dimethyl Ammonium sulfovinate (エ チ Le sulphuric acid ラ ノ リ Application fatty acid ア ミ ノ プ ロ ピ Le エ チ Le ジ メ チ Le ア Application モ ニ ウ system), octadecyl trimethyl Saccharin Ammonium salt, the cetyl trimethyl Saccharin Ammonium salt, docosyl trimethyl methylsulfuric acid ammonium and Quaternium-91 (Network オ タ ニ ウ system-91) etc., but be not limited to this.Cationic surface active agent can use separately a kind, but from foaming characteristic and thoughts and feelings aspect, preferably share more than 2 kinds.

[(C) composition]

(C) of the present invention composition is anionic surfactant and/or the amphoteric surfactant of blending in cosmetic hair composition.(C) the blending amount indefinite of composition, but be preferably set in 0.05 ~ 10 quality % scope, particularly preferably be set as in 0.1 ~ 3 quality % scope.

As (C) composition, but example goes out following material, but is not limited to this.(C) composition can use separately wherein a kind or share wherein more than 2 kinds.

in (C) composition, as anionic surfactant, but go out the alkyl ether sulfates such as POE sodium lauryl tri(oxyethyl) sulfate such as example, sodium lauryl sulphate, sodium cetostearylsulphate, the alkyl sulfates such as sodium hexadecyl sulfate, alkene ether sulfate, alkenyl sulfate, olefine sulfonate, alkane sulfonate, saturated or unsaturated fatty acid salt, the alkyl or alkenyl ether carboxylate, α-alpha-sulfonated fatty hydrochlorate, the N-acyl amino acid type surfactants such as cocos nucifera oil acyl glutamic acid triethanolamine (cocos nucifera oil acyl glutamic acid TEA), mono phosphoric acid ester or diester type surfactant, with esters of sulfosuccinic acids etc.As the anionic group of these surfactants to ion, for example can list sodium ion, potassium ion and triethanolamine.

In (C) composition, as amphoteric surfactant, but example goes out following material.

1. fatty amide propyl dimethylaminoethyl acid betanin and sodium salt, potassium salt or the triethanolamine salts such as coconut oil fat amido propyl dimethylaminoethyl acid betanin (ヤ シ fatty acid oil ア ミ De プ ロ ピ Le ジ メ チ Le ア ミ ノ jealous woman acid ベ タ イ Application), Petiolus Trachycarpi oil fat amido propyl dimethylaminoethyl acid betanin, dodecanamide propyl dimethylaminoethyl acid betanin (lauroylamidopropyl betaine), Oleum Ricini amido propyl dimethylaminoethyl acid betanin.

2. alkyl dimethyl oxyneurine and sodium salt, potassium salt or the triethanolamine salts such as decyl dimethylaminoethyl acid betanin, dodecyl dimethyl oxyneurine, myristyl dimethylaminoethyl acid betanin, hexadecyldimethyl benzyl ammonium oxyneurine, octadecyl dimethylaminoethyl acid betanin, oleyl dimethylaminoethyl acid betanin, docosyl dimethylaminoethyl acid betanin, cocos nucifera oil alkyl dimethyl oxyneurine.

3. cocos nucifera oil acyl both sexes guanidine-acetic acid Na (N-cocos nucifera oil acyl (ヤ シ fatty acid oil ア シ Le)-N '-carboxymethyl-N '-hydroxyethylethylene diamine), cocos nucifera oil acyl both sexes base propanoic acid Na (N-cocos nucifera oil acyl-N '-carboxyethyl-N '-hydroxyethylethylene diamine), lauroyl both sexes guanidine-acetic acid Na (N-lauroyl-N '-carboxymethyl-N '-hydroxyethylethylene diamine), Fructus Canarii albi oleoyl both sexes guanidine-acetic acid Na, cocoa acyl both sexes guanidine-acetic acid Na, Semen Sesami oleoyl both sexes guanidine-acetic acid Na, Prunus dulcis oleoyl both sexes guanidine-acetic acid Na (ス イ ー ト ア ー モ Application De ア Application ホ jealous woman acid Na), stearoyl both sexes guanidine-acetic acid salt, palmitoleoyl both sexes guanidine-acetic acid Na, Semen arachidis hypogaeae oleoyl both sexes guanidine-acetic acid Na, sunflower seed oleoyl both sexes guanidine-acetic acid Na, the N-acyl amino ethyl-N-2-hydroxyethylamino carboxylates such as Semen Gossypii oleoyl both sexes guanidine-acetic acid Na.

4. the N-acyl amino ethyl-N-carboxyl methoxy ethyl aminocarboxylate such as cocos nucifera oil acyl both sexes base oxalic acid Na, cocos nucifera oil acyl both sexes base dipropionic acid Na and lauroyl both sexes base oxalic acid Na.

5. hydroxy alkyl (C12-14) hydroxyethyl sarcosine.

[classification of cosmetic hair composition]

Cosmetic hair composition indefinite of the present invention is for example taken off stain as oxide hair dye, acidic hair coloring preparation, hair depigmenting agent or hair and is consisted of.Particularly preferably consist of as oxide hair dye or hair depigmenting agent.

(oxide hair dye)

Oxide hair dye comprises the 1st dose of containing alkaline agent and oxidation dye and contains the 2nd dose of oxidant, decomposes the melanin of hair, by the oxidation polymerization of oxidant initiated oxidation dyestuff, has hair dyed.Oxidation dye can be divided into dyestuff intermediate and colour former.Also but the direct dyess such as blending basic stain, nitro dye, natural dye, disperse dyes replace acid stain.

As dyestuff intermediate, for example can list phenylenediamine, aminophenols, toluylenediamine class, diphenylamine, diaminobenzene amine, N-phenyl phenylenediamine, diamino-pyridine class and its esters.As salt, such as listing hydrochlorate, sulfate and acetate etc.

Colour former can be contained in the 1st dose as required for by be combined the compound of color development with dyestuff intermediate.As colour former, for example can list resorcinol, 1,2,3,-thrihydroxy-benzene, catechol, m-aminophenol, m-diaminobenzene., 2,4-diaminophenol, 1,2,4-benzenetriol, Toluene-3,4-dithiol, 4-diamidogen, Toluene-2,4-diisocyanate, 4-diamidogen, hydroquinone, alpha-Naphthol, 2,6-diamino-pyridine, 1,5-dihydroxy naphthlene, the amino orthoresol of 5-, p-methylaminophenol, 2,4-diamino phenoxy ethanol, gallic acid, tannin, progallin A, gallicin, propyl gallate, Galla Chinensis, 5-(the 2-hydroxyethyl is amino)-2-methylphenol and salt thereof.

In oxide hair dye, the content of dyestuff intermediate is preferably 0.01 ~ 10 quality %, more preferably 0.1 ~ 5 quality %.When dyestuff intermediate contain quantity not sufficient 0.01 quality % the time, the anxiety that can not get sufficient dyeability is arranged.Even because the content of dyestuff intermediate surpasses 10 quality %, dyeability does not further improve yet, so the anxiety of the economy reduction of hair dyeing is arranged.

As the dyestuff beyond above-mentioned oxidation dye, the 1st dose also can suitably contain and for example be selected from least a in the oxidation dye that records in " fiducial mark quasi drug raw material specification (medicine part outer article raw material Regulations lattice) " (in June, 2006 distribution, medicine thing day newspaper office) and direct dyes.

Alkaline agent is when promoting the 2nd dose of oxidant effect that contains, and the swelling hair improves dyestuff to the permeability of hair, improves thus dyeability.As alkaline agent, for example can list ammonia, alkanolamine, organic amine, inorganic base, basic amino acid and sulfate.As organic amine, for example can list AMPD and guanidine.As inorganic base, for example can list sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, ammonium carbonate, sodium bicarbonate and ammonium bicarbonate.As basic amino acid, for example can list arginine and lysine and alkaline amino acid salt.As the salt of basic amino acid, for example can list ammonium salt.As sulfate, can list ammonium sulfate.

The content of alkaline agent is preferably the amount that in mixing the oxide hair dye of the 1st dose and the 2nd dose pH reaches 7 ~ 12 scopes.If pH less than 7 when the hydrogen peroxide that contains as oxidant, has the anxiety that can't fully promote the effect of hydrogen peroxide in the 2nd dose.If the pH when using surpasses 12, when oxide hair dye is coated hair, the anxiety of the defectives such as easy generation damage hair is arranged.

The 2nd dose contains oxidant at least.Oxidant makes oxidation dye generation oxidation polymerization and color development.As oxidant, for example can list hydrogen peroxide, perhydrit, tripolycyanamide peroxide (Over acidify メ ラ ミ Application), the hydrogen peroxide adduct of SODIUM PERCARBONATE, potassium percarbonate, Dexol, potassium perborate, sodium peroxide, potassium peroxide, Magnesium dioxide, Barium dioxide, calper calcium peroxide, strontium peroxide, the hydrogen peroxide adduct of sulfate, phosphatic hydrogen peroxide adduct and pyrophosphate.

In the 2nd dose, the content of oxidant is preferably 0.1 ~ 10.0 quality %, and more preferably 0.5 ~ 8.0%.When oxidant contain quantity not sufficient 0.1 quality % the time, in distress so that the anxiety of the abundant oxidation polymerization of oxidation dye.When the content of oxidant surpasses 10.0 quality %, the anxiety of easy damaged hair is arranged.

(acidic hair coloring preparation)

Acidic hair coloring preparation is generally 1 dose of formula, and fluidity is the acidity of pH2.5 ~ 4.0 left and right, makes acid stain and forms ionic bond with the hair of cationic.As acid stain, such as listing nitro dye, azo dye, nitroso-dyes, triphenhlmethane dye, xanthene dye, quinoline dye, anthraquinone dye, bipseudoindoxyl dye etc.

As acid stain, more specifically, but example goes out Amaranth, red No. 3, red No. 102, red No. 104, red No. 105, red No. 106, red No. 227, red No. 230, yellow No. 4, Sunset Yellow FCF, yellow No. 202, yellow No. 203, orange No. 205, orange No. 207, orange No. 402, green No. 3, green No. 204, green No. 401, No. 401, purple, blue No. 1, blue No. 2, blue No. 202, No. 201, brown, No. 401, black etc.

In acidic hair coloring preparation, the content of acid stain is 0.005 ~ 5 quality %, more preferably 0.01 ~ 3 quality %.

(hair depigmenting agent)

The hair depigmenting agent comprises the 1st dose of containing alkaline agent and contains the 2nd dose of oxidant, decomposes the melanin of hair, makes the hair decolouring.Do not contain outside the oxidation dye this point if remove, the hair depigmenting agent similarly consists of with oxide hair dye basically.

(hair takes off stain)

Hair takes off stain and is generally 2 doses of formulas, main purpose is that taking off of hair dye (decomposition of dying the dyestuff that has in hair), with the hair depigmenting agent relatively in, in the 1st dose in the blending alkaline agent, further blending there are differences as a kind of persulfate of alkaline agent aspect as the aided bleaching agent.The 1st dose is Powdered or graininess, lamellar etc., and the 2nd dose is aqueous.

As persulfate, preferred exemplary goes out the alkali metal salt of persulfuric acid, and particularly preferably example goes out potassium peroxydisulfate or sodium peroxydisulfate.The blending amount indefinite of persulfate, but be preferably in the scope of 2.0 ~ 25 quality %, more preferably in the scope of 3.5 ~ 18 quality %.

[other composition in cosmetic hair composition]

In 1 dose of formula cosmetic hair composition or 2 doses of formula cosmetic hair compositions the 1st dose and the 2nd dose, can suitably select as required to contain such as oiliness composition, water-soluble high-molecular compound, chelating agen, inorganic salt, dispersant etc.

As the oiliness composition, for example can list higher alcohol, oils and fats, wax, hydrocarbon, higher fatty acids, alkyl glycerylether, ester, silicone, polyhydric alcohol.

As higher alcohol, for example can list hexadecanol (spermol), 2-hexyldecanol, stearyl alcohol, isooctadecanol, cetostearyl alcohol, oleyl alcohol, arachidic alcohol, behenyl alcohol, 2-octyl dodecanol, lauryl alcohol, myristyl alcohol, decyl tetradecyl alchohol and lanolin alcohol.Higher alcohol has when the blister dosage form of cosmetic hair composition being made non-aerosol-type is coated on hair promotes the effect that prevents preparation drippage effect.

As oils and fats, for example can list lanoline, olive oil, Camellia oil, Butyrospermum oils and fats, almond oil, safflower oil, Oleum helianthi, soybean oil, Oleum Gossypii semen, Oleum sesami, oleum maydis, Oleum Brassicae campestris, Testa oryzae oil, rice germ oil, Oleum Vitis viniferae, American Avocado Tree oil, macadimia nut oil, Oleum Ricini, Oleum Cocois and Radix Oenotherae erythrosepalae oil.

As wax, for example can list Cera Flava, candelilla wax, Brazil wax, Simmondsia chinensis oil and lanoline.

As hydrocarbon, for example can list paraffin, olefine oligomer, polyisobutylene, Parleam, mineral oil, Squalene, polybutene, polyethylene, microwax and vaseline.

As higher fatty acids, for example can list lauric acid, myristic acid, Palmic acid, stearic acid, behenic acid, isostearic acid, 12-hydroxy stearic acid, oleic acid and lanolin fatty acid.

As alkyl glycerylether, for example can list batilol .alpha.-hexadecylglyceryl ether, selachyl alcohol and isooctadecane base glycerol ether.

as ester, for example can list diisopropyl adipate, isopropyl myristate, sad hexadecane ester, isononyl isononanoate, myristic acid octyl group dodecane ester, isopropyl palmitate, stearic stearolactone, myristic acid tetradecane ester, the different tridecane ester of myristic acid, Palmic acid 2-Octyl Nitrite, castor oil acid octyl group dodecane ester, has the fatty acid cholesterol ester of 10 ~ 30 carbon numbers/lanosterol ester, cetyl lactate, the acetic acid lanoline, two-2 ethyl hexanoic acid glycol ester, pentaerythritol fatty ester, the dipentaerythritol fatty acid ester, capric acid hexadecane ester, decanoin, malic acid two isooctadecane esters, dioctyl succinate and 2 ethyl hexanoic acid hexadecane ester.

As silicone, for example can list dimethyl polysiloxane (simethicone), methyl phenyl silicone, decamethylcyclopentaandoxane, ten diformazan basic ring six siloxanes, terminal hydroxyl modification dimethyl polysiloxane, have high polymerizing silicone, polyether modified silicone, amino modified silicone, betanin modified silicone, alkyl-modified silicone, alkoxy-modified silicone, carboxy-modified silicone and the fluorine modified silicone of 650 ~ 10,000 average degree of polymerization.

As polyhydric alcohol, for example can list dihydroxylic alcohols and glycerol.As dihydroxylic alcohols, for example can list ethylene glycol, diethylene glycol, 2,2'-ethylenedioxybis(ethanol)., Polyethylene Glycol, propylene glycol, dipropylene glycol, Isopropanediol and 1,3 butylene glycol.As glycerol, for example can list glycerol, diglycerol and polyglycereol.

As water-soluble high-molecular compound, for example can list carboxymethyl cellulose, hydroxyethyl-cellulose, starch and cyclodextrin.As chelating agen, for example can list ethylenediaminetetraacetic acid (EDTA, edetic acid), hydroxyethylethylene diamine tri-acetic acid (HEDTA) and salt, diethylene triamine pentacetic acid (DTPA) and its esters and Etidronic Acid (HEDP, etidronic acid) and its esters.As inorganic salt, for example can list sodium chloride, sodium sulfate.As dispersant, for example can list magnesium stearate.

In addition, also can contain in the 1st dose and the 2nd dose of 1 dose of formula cosmetic hair composition or 2 doses of formula cosmetic hair compositions and for example be selected from least a in the material that records in saccharide, antiseptic, stabilizing agent, pH adjusting agent, plant extract, extracts from crude drugs, vitamins, spice and UV absorbent and " fiducial mark quasi drug raw material specification " (in June, 2006 distribution, medicine thing day newspaper office).

[using method of cosmetic hair composition]

The using method of cosmetic hair composition of the present invention is for forming the blister dosage form to be applicable to the method for hair with above-mentioned cosmetic hair composition by non-aerosol foam container.

As non-aerosol foam container, as long as have under the prerequisite that to carry out non-aerosol-type foaming and discharge function to cosmetic hair composition, with regard to indefinite.Preferably can using hereinafter described, non-aerosol foam container bubbles.

[hair cosmetic product]

Hair cosmetic product of the present invention contains to be useful on to be made in use non-aerosol-type blister dosage form with the above-mentioned cosmetic hair composition that is applicable to hair and is used for this cosmetic hair composition is formed the non-aerosol foam container of blister dosage form and consists of.

As the typical example of non-aerosol foam container, can list pump foamite system and crushed foam device.The pump foamite system will be taken in liquid (for example the 1st of hair cosmetic composition the dose/the 2nd dose mixed liquor) by pressing operation pump pressure head and form the blister discharge, mix with taking in liquid the mouth neck portion that the bubble displacer that is the blister discharge is installed on vessel with air.Disclosing the pump foamite system in TOHKEMY 2007-275777 communiques etc., is known.The crushed foam device is pointed extruding soft synthetic resin container made body (repeating squeeze operation and releasing squeeze operation to container) by use, take in liquid and air imports foam with the gas-liquid mixed chamber of discharging head with above-mentioned, by the bubble displacer, the foam that forms is discharged from nozzle.Recording the crushed foam device in the document " new trend of hair dyeing technology (exploitation of blister hair dyeing technology-) " of interim publication in June, 2009 of TOHKEMY 2008-291024 communique and magazine " Fragrance Journal (Off レ グ ラ Application ス ジ ャ ー Na Le) " etc., is known.

The bubble displacer of non-aerosol foam container has one or more multiple aperture plasma membranes that forms foam.As the material of multiple aperture plasma membrane, can list nylon, polyester, polyethylene, polypropylene etc.As the order number of multiple aperture plasma membrane, preference is as 50 ~ 300 orders.

Embodiment

Below embodiments of the invention are described.Technical scope of the present invention is not limited because of following examples.

(formations of 2 doses of formula hair dyes)

Prepare in table 1 " the 1st dose " hurdle as in the 1st dose of the hair dye of the composition shown in routine 1-1 ~ routine 1-5 and table 2 " the 2nd dose " hurdle as the 2nd dose of the hair dye of the composition shown in routine 2-1 ~ routine 2-6, optionally make up above-mentioned the 1st dose and the 2nd dose according to shown in table 3 " combination " hurdle, consist of 2 doses of formula hair dyes of embodiment 1 ~ embodiment 8, comparative example 1 ~ comparative example 5.

In table 1 and table 2, represent the content of the quality % unit in the 1st dose or the 2nd dose of the numeric representation of component content of the 1st dose or the 2nd dose, and do not represent the 1st dose of content when the 2nd dose is mixed.In addition, for the composition that belongs to the arbitrary class in the composition of (A) of the present invention composition ~ (C), the marge in the table left side marks its classification.Belonging to shown in table 1 and table 2, " POE (7) alkyl (C12 ~ 14) ether " and " POE (5) alkyl (C12 ~ 14) ether " of (A) composition was 12 ~ 14 POE alkyl ether mixed material for the alkyl chain carbon atomic number, and " alkyl (8 ~ 16) glucoside " of the conduct shown in table 1 (A) composition is 8 ~ 16 alkyl androstanediol mixed material for the alkyl chain carbon atomic number.In addition, the composition of mark " ※ " labelling is Dow Corning Toray Co. after the composition title in table 2, Ltd. (East レ ダ ウ コ ー ニ Application グ society) FZ-4671 (aminoethyl aminopropyl methylsiloxane-dimethylsiloxane copolymer (20%)) of system.

(evaluations of 2 doses of formula hair dyes)

The ratio of 1:1 is received into above-mentioned non-aerosol foam container (pump foamite system) with the various embodiments described above, each comparative example the 1st dose and the 2nd dose and makes mixed liquor in mass ratio, by this pump pressure head of pressing operation, above-mentioned mixed liquor is blister and discharges, alveolar substance, coating and the drippage of each embodiment, each comparative example are estimated.Here, as the pump foamite system, use (strain) lucky wild industrial made trade name W-5721, WP foam pump L nozzle type (the gas/liquid mixing ratio: 13/1, output: 0.9g (pressing 1 time), multiple aperture plasma membrane: 90 2, purpose polyethylene systems sieve rings).

Particularly, for " alveolar substance ", the quality of overall merit foaming characteristic, bubble, the hardness of bubble.For " coating ", estimate to form and steep the complexity of extension and the complexity of coating when the blister hair dye is coated on wig.For " drippage ", through the time observe to estimate form the blister hair dye and coat on wig after the complexity of drippage in 30 minutes.

When the assessment items such as above-mentioned " alveolar substance ", " coating ", " drippage " were estimated, the comparative example 1 take the content of (A) composition under the state of the 1st dose and the 2nd dose mixing as 9.25% is (standard of evaluation) in contrast.For each assessment item, as shown in following evaluation criterion, compare by the evaluation result with contrast the relative evaluation that obtains, estimate according to 6 grades.In addition, for all assessment items of all embodiment, comparative example, estimated simultaneously by 10 group members that belong to a small group, adopt to obtain maximum evaluation results in the evaluation result that these group members obtain.These evaluation results are recorded in the value column of each assessment item of table 3.

＜evaluation criterion 〉

+++: is very excellent compared with the control

++: very excellent compared with the control

+: excellent compared with the control

-: poor compared with the control

--: very poor compared with the control

---: non-constant compared with the control.

[table 1]

。

[table 2]

。

[table 3]

。

Utilizability on industry

According to the present invention, the cosmetic hair composition that foam, the coating on hair that can obtain high-quality are excellent, do not drip when coating on hair can be provided, and described compositions is for forming non-aerosol-type blister dosage form to be applicable to the cosmetic hair composition of hair.

Claims (5)

1. cosmetic hair composition, described compositions forms the blister dosage form to be applicable to the cosmetic hair composition of hair by non-aerosol foam container in use for being used for, and it is characterized in that, contains the composition of following (A) composition ~ (C):

(A) the above nonionic surfactant of 10 quality %,

(B) cationic surface active agent,

(C) be selected from anionic surfactant and amphoteric surfactant more than a kind.

2. the cosmetic hair composition of claim 1, it is characterized in that, above-mentioned cosmetic hair composition when using with the mixed liquor formation blister dosage form of the 1st dose and the 2nd dose to be applicable to 2 doses of formula compositionss of hair, blending (B) composition in the 1st dose, blending (C) composition in the 2nd dose.

3. claim 1 or 2 cosmetic hair composition, is characterized in that, above-mentioned cosmetic hair composition is that hair dye, hair depigmenting agent or hair take off stain.

4. the using method of cosmetic hair composition, is characterized in that, the cosmetic hair composition of any one in claim 1 ~ claim 3 is formed the blister dosage form to be applicable to hair by non-aerosol foam container.

5. the hair cosmetic product, is characterized in that, contains the cosmetic hair composition of any one in claim 1 ~ claim 3 and be used for described cosmetic hair composition being formed the non-aerosol foam container of blister dosage form and consisting of.