CN103298450A - Hair cosmetic composition, method for using same, and hair cosmetic product - Google Patents
Hair cosmetic composition, method for using same, and hair cosmetic product Download PDFInfo
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- CN103298450A CN103298450A CN2011800525339A CN201180052533A CN103298450A CN 103298450 A CN103298450 A CN 103298450A CN 2011800525339 A CN2011800525339 A CN 2011800525339A CN 201180052533 A CN201180052533 A CN 201180052533A CN 103298450 A CN103298450 A CN 103298450A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Abstract
Provided is a hair cosmetic that discharges in a foam dosage form from a non-aerosol foamer container, is capable of imparting a favorable feeling to hair, does not drip during application to hair, and does not produce flaws in the quality of discharged foam. A hair cosmetic composition configured as a hair dye or a hair-bleaching agent, and at time of use entailing the discharge of a liquid mixture of a first agent and a second agent as foam from a non-aerosol foamer container and subsequent application to hair, the hair cosmetic composition containing a non-ionic surfactant component (A) in the amount of 10 mass% or more, and a silicone component (B).
Description
Technical field
The present invention relates to cosmetic hair composition, its using method and hair cosmetic product.And then at length, the present invention relates to and to discharge with blister and to be applied to cosmetic hair composition, its using method of hair and to contain this cosmetic hair composition and non-aerosol foaming vessel and the hair cosmetic product that constitutes from the non-aerosol foaming vessel.
Background technology
The hair cosmetic composition of known hair dye or hair depigmenting agent etc. uses with the dosage form of blister in use.In general, when using these hair cosmetic compositions with the dosage form of blister, can expect following advantage: the evenly coating on the no spot of hair ground easily, can eliminate the such trouble of the hair caking that when the hair cosmetic composition of the gel that uses extensive use or paste, produces etc.
The hair cosmetic composition that uses with the dosage form of blister is broadly divided into aerosol type and non-aerosol type.For aerosol type, use the such propellant of liquid gas, make dosage form be blister by having utilized aerocolloidal bubble formation.For the non-aerosol type, do not use propellant, and use pump foam maker (
) or other non-aerosol foaming vessel (following also abbreviate as " foaming vessel ") of crushed foam generator form the bubble of having taken in air, making dosage form is blister.Preferred non-aerosol foaming vessel is considered in aspect simple from the formation of the container that is used for carrying out the blister dosage formization, favourable on cost and when not preserving or the aspect of the danger during operation.
In following patent documentation 1, the patent documentation 2, the oxide hair dye composition or the hair coloring preparation composition that utilize aerosol and dosage form is used for blister are disclosed.In addition, in following patent documentation 3, patent documentation 4, disclose and utilized the non-aerosol foaming vessel and make hair dye that dosage form uses for blister etc.
[patent documentation 1] Japanese kokai publication hei 09-136818 communique
[patent documentation 2] Japanese kokai publication hei 10-287534 communique
[patent documentation 3] TOHKEMY 2007-291015 communique
[patent documentation 4] TOHKEMY 2008-291020 communique
[patent documentation 5] TOHKEMY 2006-124279 communique
[patent documentation 6] TOHKEMY 2004-339216 communique
[patent documentation 7] TOHKEMY 2010-006803 communique.
Summary of the invention
Hair cosmetic composition for the blister dosage form that can discharge from the non-aerosol foaming vessel has above-mentioned various advantages, but then, also has the problem of the good sense of touch (feel) that is difficult to obtain hair.Therefore, as the disclosed pair of preparation formula in the above-mentioned patent documentation 5 (
) hair cosmetic composition is such, as the composition that improves sense of touch, attempt having cooperated present known silicone, perhaps as two preparation formula blister hair dyes of record in the above-mentioned patent documentation 6,7, as the composition that improves sense of touch, attempt having cooperated present known cationization polymer.
But silicone has the froth breaking effect, therefore when it being engaged in the hair cosmetic composition of blister dosage form, exist be easy to when being applied to hair drippage (
) problem of such discharge alveolar substance.In addition, when cooperating the cationization polymer, the viscosity of hair cosmetic composition raises, therefore exist (1) hair cosmetic composition to be difficult to sieve aperture by the net of non-aerosol foaming vessel, can not generate the bubble of the high-quality of texture exquisiteness, (2) also grow too of alveolar substance is poor to the affinity of hair, forms the problem that is difficult to be coated on the discharge alveolar substance on the hair.
Therefore, the problem that desire of the present invention solves provides the hair cosmetic composition of discharging with the blister dosage form from the non-aerosol foaming vessel, and it can give hair good sense of touch, and does not have the shortcoming of discharging alveolar substance, does not drip when being applied to hair.
(formation of the 1st invention)
In order to solve above-mentioned problem, the formation of the application's the 1st invention is cosmetic hair composition, it constitutes as hair dye or hair depigmenting agent, during use the mixed liquor of the 1st preparation and the 2nd preparation is discharged with blister from the non-aerosol foaming vessel, and be applied to hair, wherein, contain above (A) composition of 10 quality %: nonionic surfactant, and contain (B) composition: silicone.
In the 1st above-mentioned invention, " more than the 10 quality % " refer to " the 1st preparation and the 2nd preparation are more than the 10 quality % when mixing ".Similarly, in present specification, limit the short of special explanation of numerical value of the content of certain composition, all refer to " content when the 1st preparation and the 2nd preparation mix ".
(formation of the 2nd invention)
In order to solve above-mentioned problem, the formation of the application's the 2nd invention is cosmetic hair composition, it constitutes as hair dye or hair depigmenting agent, during use the mixed liquor of the 1st preparation and the 2nd preparation is discharged with blister from the non-aerosol foaming vessel, and be applied to hair, wherein, contain following (A) composition that surpasses 10 quality %, and contain following (B1) composition.
(A) nonionic surfactant.
(B1) polyoxyethylene modified silicone.
(formation of the 3rd invention)
In order to solve above-mentioned problem, the formation of the application's the 3rd invention is the cosmetic hair composition of above-mentioned the 2nd invention, and wherein, (A) content of composition is in the scope of 11 quality %～25 quality %.
(formation of the 4th invention)
In order to solve above-mentioned problem, the formation of the application's the 4th invention is the cosmetic hair composition of above-mentioned the 2nd invention or the 3rd invention, and it is that oxide hair dye, acid hair dye, hair depigmenting agent or hair take off stain.
(formation of the 5th invention)
In order to solve above-mentioned problem, the formation of the application's the 5th invention is the using method of cosmetic hair composition, and it is discharged from the non-aerosol foaming vessel each described cosmetic hair composition in the 2nd invention～the 4 invention with blister, and is applied to hair.
(formation of the 6th invention)
In order to solve above-mentioned problem, the formation of the application the 6th invention is the hair cosmetic product, and it contains each described cosmetic hair composition in the 2nd invention～the 4 invention and is used for the non-aerosol foaming vessel that this cosmetic hair composition is discharged with blister and constitutes.
(formation of the 7th invention)
In order to solve above-mentioned problem, the formation of the application's the 7th invention is cosmetic hair composition, it constitutes as hair dye or hair depigmenting agent, during use the mixed liquor of the 1st preparation and the 2nd preparation is discharged with blister from the non-aerosol foaming vessel, and be applied to hair, wherein, contain above following (A) composition of 10 quality %, and contain following (B) composition and (C) composition.
(A) nonionic surfactant.
(B) silicone.
(C) be selected from cationization polymer and contain the diallyl quaternary ammonium salt and at least a as in the copolymer that constitutes the unit of acrylic acid.
(formation of the 8th invention)
In order to solve above-mentioned problem, the formation of the application's the 8th invention is the cosmetic hair composition of above-mentioned the 7th invention, and wherein, (A) content of composition is in 10～1000 the scope with respect to the mass ratio A/C of the content of (C) composition.
(formation of the 9th invention)
In order to solve above-mentioned problem, the formation of the application's the 9th invention is the cosmetic hair composition of above-mentioned the 7th invention or the 8th invention, and wherein, (B) content of composition is in 0.01～50 the scope with respect to the mass ratio B/C of the content of (C) composition.
(formation of the 10th invention)
In order to solve above-mentioned problem, the formation of the application's the 10th invention is each described cosmetic hair composition in above-mentioned the 7th invention～the 9 invention, wherein, (C) composition is to be selected from the cationization polysaccharide and to contain at least a as in the polymer that constitutes the unit and the copolymer of diallyl quaternary ammonium salt.
(formation of the 11st invention)
In order to solve above-mentioned problem, the formation of the application's the 11st invention is each described cosmetic hair composition in above-mentioned the 7th invention～the 10 invention, and it is that oxide hair dye, acid hair dye, hair depigmenting agent or hair take off stain.
(formation of the 12nd invention)
In order to solve above-mentioned problem, the formation of the application's the 12nd invention is the using method of cosmetic hair composition, it is discharged from the non-aerosol foaming vessel each described cosmetic hair composition in the 7th invention～the 11 invention with blister, and is applied to hair.
(formation of the 13rd invention)
In order to solve above-mentioned problem, the formation of the application the 13rd invention is the hair cosmetic product, and it contains each described cosmetic hair composition in the 7th invention～the 11 invention and is used for the non-aerosol foaming vessel that this cosmetic hair composition is discharged with blister and constitutes.
According to the 1st invention, can expect following effect.That is, the hair cosmetic composition of discharging with the blister dosage form from the non-aerosol foaming vessel contains the silicone as (B) composition, and the nonionic surfactant that contains conduct (A) composition more than the 10 quality % simultaneously is used as foaming agent.Be somebody's turn to do (A) even composition also generates the bubble that is difficult to froth breaking especially, therefore the froth breaking effect that can resist silicone in various surfactants.Consequently the 1st the invention hair cosmetic composition can not cause by silicone cause be applied to hair the time drippage.In addition, even (A) composition has at various surfactant moderate stimulations also especially little feature.
On the other hand, silicone (1) has the viscosity that suppresses hair cosmetic composition and raises, the character that improves liquidity, and (2) have the effect of the arrangement that upsets the surfactant in the bubble.Therefore, though hypothesis for the hair cosmetic composition of the 1st invention and then cooperate the cationization polymer, the viscosity of the hair cosmetic composition that is caused by this cooperation raises also and can be suppressed owing to the character of above-mentioned (1) of silicone.In addition, the such problem of " because the viscosity of hair cosmetic composition raises, can not generate the bubble of the high-quality of texture exquisiteness " that is caused by the cooperation of cationization polymer, " alveolar substance also become too strong and be difficult to be coated on the hair " is also owing to the character of above-mentioned (2) of silicone is suppressed.
Therefore, according to the 1st invention, can provide the hair cosmetic composition of discharging with the blister dosage form from the non-aerosol foaming vessel, it can give hair good sense of touch, and when being applied to hair, does not produce the problem of above-mentioned various discharge alveolar substance.
And, when the content of (A) composition is less than 10 quality % in the cosmetic hair composition, when using the hair cosmetic composition of blister dosage form, be easy to produce the problem of various discharge alveolar substances.
According to the 2nd invention, the hair cosmetic composition of discharging with the blister dosage form from the non-aerosol foaming vessel can be provided, it can give hair good sense of touch, and when being applied to hair, prevents that the effect of dripping is excellent especially.
In the 2nd invention, the 1st reason that obtains above-mentioned effect is to contain the nonionic surfactant that surpasses 10 quality %.Nonionic surfactant has the speciality that generates the bubble that is difficult to froth breaking, and in addition, it is surfactant, stimulates simultaneously and lacks, by cooperate, can fully generate the bubble that is difficult to froth breaking, does not have drippage with the amount that surpasses 10 quality %.
In view of the remarkable result of the 2nd invention, preferred especially " nonionic surfactant that surpasses 10 quality % " for example is more than the 10.1 quality %, more than the 10.5 quality % or more than the 11 quality %.The content of especially preferred nonionic surfactant is shown in the 3rd invention.
In the 2nd invention, the 2nd reason that obtains above-mentioned effect is to contain the polyoxyethylene modified silicone as silicone.The polyoxyethylene modified silicone is compared with other silicone, has water solublity to a certain degree, and shows a part of surface activity effect.Consequently not only only give hair good sense of touch, also by with the synergism of above-mentioned nonionic surfactant, the drippage in the time of can effectively preventing from being applied to hair.
According to the 3rd invention, be in the scope of 11 quality %～25 quality % by making the content as the nonionic surfactant of (A) composition, can and then significantly improve the effect of above-mentioned the 1st invention.If (A) content of composition surpasses 25 quality %, then Fa Ming effect is saturated.
According to the 4th invention, can be provided as the particularly preferred embodiment of cosmetic hair composition, oxide hair dye, acid hair dye, hair depigmenting agent or hair take off stain.
According to the 5th invention, can provide the effective ways of cosmetic hair composition being discharged and is applied to hair from the non-aerosol foaming vessel with good blister.
According to the 6th invention, easy hair cosmetic product can be provided, it contains cosmetic hair composition and is used for making this cosmetic hair composition to constitute with the non-aerosol foaming vessel of blister discharge.
According to the 7th invention, the hair cosmetic composition of discharging with the blister dosage form from the non-aerosol foaming vessel can be provided, it can give hair good sense of touch, and " generation of the bubble of the high-quality of texture exquisiteness " or " being easy to be coated on the discharge alveolar substance on the hair " such effect is excellent especially.Can obtain reason also narration to some extent in the 1st invention of this effect, and then at length, can infer as follows.
When in containing the hair cosmetic composition that nonionic surfactant as (A) composition is used as foaming agent, cooperating (C) composition, usually can produce the shortcoming of discharging alveolar substance, this shortcoming has (a) hair cosmetic composition to be difficult to sieve aperture by the net of non-aerosol foaming vessel, can not generate fine bubble, (b) also grow too of alveolar substance, to hair affinity poor, form the bubble be difficult to be coated on the hair etc.
But, and then when cooperating silicone as (B) composition, the viscosity that can suppress hair cosmetic composition raises, and flowability improves, and the result has eliminated the shortcoming of above-mentioned (a), can generate fine bubble.In addition, (B) composition is based on the effect of the arrangement that upsets surfactant and show certain froth breaking effect, thereby eliminated the shortcoming of above-mentioned (b), and too strong alveolar substance moderately dies down.And (B) composition is that sense of touch improves composition originally, so the sense of touch of hair further improves.
On the other hand, (B) also there is the problem that is easy to cause drippage in composition based on above-mentioned froth breaking effect when being applied to the hair cosmetic composition of blister dosage form.But from the angle consideration that makes the alveolar substance grow by (C) composition and contain the nonionic surfactant of conduct (A) composition more than the 10 quality %, this problem balance is eliminated well.This is because (A) composition generates the bubble be difficult to froth breaking, and stimulates fewly, and therefore above (A) composition of 10 quality % is on the basis with few stimulation, and also the froth breaking effect with (B) composition is suppressed at suitable level.
As the 8th the invention limit, (A) content of composition with respect to the mass ratio A/C of the content of (C) composition preferably in 10～1000 scope.When A/C less than 10 the time, the negative effect of above-mentioned (C) composition is come to the surface, have to discharge the alveolar substance grow to possibility that needs above degree, if A/C surpasses 1000, the possible variation of the sense of touch of hair then.
As the 9th the invention limit, (B) content of composition with respect to the mass ratio B/C of the content of (C) composition preferably in 0.01～50 scope.When B/C less than 0.01 the time, the negative effect of above-mentioned (C) composition is come to the surface, and has to discharge the alveolar substance grow to possibility that needs above degree, if B/C surpasses 50, then (C) composition might destroy with (B) balance of composition, becoming is easy to froth breaking.
Limit like that as the 10th invention, as (C) composition, preferably be selected from the cationization polysaccharide of water solublity excellence and contain at least a as in the polymer of formation unit and the copolymer of diallyl quaternary ammonium salt.
According to the 11st invention, can be provided as the particularly preferred embodiment of cosmetic hair composition, oxide hair dye, acid hair dye, hair depigmenting agent or hair take off stain.
According to the 12nd invention, can provide the effective ways of cosmetic hair composition being discharged and is applied to hair from the non-aerosol foaming vessel with good blister.
According to the 13rd invention, easy hair cosmetic product can be provided, it contains cosmetic hair composition and is used for making this cosmetic hair composition to constitute with the non-aerosol foaming vessel of blister discharge.
The specific embodiment
Then, implement mode of the present invention for being used for, describe in the mode that comprises its preferred forms.
In the following description, the 2nd invention～the 6 invention is referred to as " the 2nd invention group ", the 7th invention～the 13 invention is referred to as " the 7th invention group ".When being called " the present invention " simply, refer to whole the 1st invention～the 13 inventions.
(cosmetic hair composition)
When cosmetic hair composition of the present invention is to use the mixed liquor of the 1st preparation and the 2nd preparation is discharged with blister from the non-aerosol foaming vessel, and be applied to the compositions of hair.
In the cosmetic hair composition of the 1st invention group, as essential composition, contain the above nonionic surfactant as the 10 quality % of (A) composition, and contain the silicone as (B) composition.For the cosmetic hair composition of the 2nd invention group, as essential composition, contain the nonionic surfactant of conduct (A) composition that surpasses 10 quality %, and contain the polyoxyethylene modified silicone as (B1) composition.Cosmetic hair composition for the 7th invention group, as essential composition, the nonionic surfactant that contains above conduct (A) composition of 10 quality %, and contain the silicone as (B) composition, further, (C) composition is to be selected from the cationization polymer and to contain the diallyl quaternary ammonium salt and at least a as in the copolymer that constitutes the unit of acrylic acid.
Cosmetic hair composition of the present invention is two preparation formulas, also comprises the 1st preparation and/or the 2nd preparation further are divided into the mode that many group preparations constitute.
When the cosmetic hair composition of the 1st invention be two preparation formula, (A) composition can at random be selected with (B) composition is unqualified basically to the fit system in the 1st preparation and the 2nd preparation.For example (A) composition can be engaged in any one of the 1st preparation and the 2nd preparation, also can disperse to be engaged in the 1st preparation and the 2nd preparation in the two, so that the 1st preparation and the 2nd preparation use level when mixing is more than the 10 quality %.In addition, (B) composition can be engaged in any one of the 1st preparation and the 2nd preparation, also can disperse to be engaged in the 1st preparation and the 2nd preparation in the two.
When the cosmetic hair composition of the 2nd invention group was two preparation formula, (A) composition and (B1) composition is unqualified basically to the fit system in the 1st preparation and the 2nd preparation can at random be selected.For example (A) composition can be engaged in any one of the 1st preparation and the 2nd preparation, also can disperse to be engaged in the 1st preparation and the 2nd preparation in the two, so that the 1st preparation and the 2nd preparation use level when mixing surpasses 10 quality %.In addition, (B1) composition can be engaged in any one of the 1st preparation and the 2nd preparation, also can disperse to be engaged in the 1st preparation and the 2nd preparation in the two.
When the cosmetic hair composition of the 7th invention group was two preparation formula, (A) composition～(C) composition was unqualified basically to the fit system in the 1st preparation and the 2nd preparation, can at random select.For example (A) composition can be engaged in any one of the 1st preparation and the 2nd preparation, also can disperse to be engaged in the 1st preparation and the 2nd preparation in the two, so that the 1st preparation and the 2nd preparation use level when mixing is more than the 10 quality %.In addition, (B) composition and (C) composition can be engaged in any one of the 1st preparation and the 2nd preparation, also can disperse to be engaged in the 1st preparation and the 2nd preparation in the two.
(dosage form of cosmetic hair composition etc.)
When cosmetic hair composition of the present invention is two preparation formula, the dosage form before foaming as the 1st preparation and the 2nd preparation, for example can exemplify solid, shaped, water-soluble aqueous, disperse aqueous, emulsion shape, gel, cystose and paste.The dosage form of solid, shaped can be enumerated for example Powdered and tablet.When being the dosage form of solid, shaped, consider from the angle of excellent dispersion when mixing the 1st preparation and the 2nd preparation, be preferably Powdered.And when for example making the 1st preparation be the dosage form of solid, shaped, the 2nd preparation is the preparation that contains water.In a word, for cosmetic hair composition, need only the flowability that can guarantee separately with its 1st preparation and the mixing of the 2nd preparation the time, there is no particular limitation to dosage form.
In addition, for cosmetic hair composition, at least one of the 1st preparation and the 2nd preparation, contain water and be used as for the substrate of bubbling.The content of water is preferably more than the 40 quality %, more preferably more than the 50 quality %.
((A) composition)
(A) of the present invention composition is with more than the 10 quality % or surpass the nonionic surfactant that the amount of 10 quality % cooperates in cosmetic hair composition.(A) in the scope of the use level of composition particularly preferably in 11 quality %～25 quality %.Wherein, in the cosmetic hair composition of the 7th invention group, for the use level of (A) composition, can consider following mass ratio A/C and set preferred use level.(A) upper limit of the use level of composition is unqualified, can be limited to below the 50 quality %.If surpass 50 quality %, then be unsuitable for the non-aerosol foaming vessel.
Nonionic surfactant can be enumerated following material, but is not limited thereto.Nonionic surfactant can use a kind separately, also can will also use more than 2 kinds.Especially, and if be that nonionic activating agent more than 14 and HLB are more than 5 and less than 14 nonionic activating agent, then stability of formulation is good with HLB.HLB(hydrophile-lipophile balance: Hydrophile-Lipophile Balance) can be calculated by known formula Griffin.
1. the POE alkyl ether of polyoxyethylene (being designated hereinafter simply as POE) cetyl ether, POE stearyl ether, POE mountain Yu base ether, POE oleyl ether, POE lauryl ether, POE tridecyl ether, POE octyl group lauryl ether, POE hexyl decyl ethers, POE iso stearyl ether, POE decyl pentadecyl ether, POE decyl myristyl ether, POE alkyl (C12～14) ether etc.
2.POE the POE alkyl phenyl ether of nonylplenyl ether, POE octyl phenyl ether etc.
3. the POE sorbitan fatty acid esters of single oleic acid POE sorbitan ester, monostearate POE sorbitan ester, single Palmic acid POE sorbitan, mono laurate POE sorbitan ester, three oleic acid POE sorbitan esters etc.
4. the POE fatty acid monoglyceride of monostearate POE glyceride, single myristic acid POE glyceride etc.
5. the POE Sorbitol fatty acid ester of four oleic acid POE sorbitol esters, six stearic acid POE sorbitol esters, mono laurate POE sorbitol ester, POE Sorbitol Cera Flava etc.
6.POE hardened castor oil, POE Oleum Ricini.
7. single oleic acid macrogol ester, monostearate macrogol ester, mono laurate macrogol ester.
8. the higher fatty acids glyceride of lipophilic glyceryl monooleate, lipophilic glyceryl monostearate, self-emulsifying type glyceryl monostearate etc.
9. the sorbitan fatty acid esters of single oleic acid sorbitan ester, sesquialter oleic acid sorbitan ester, three oleic acid sorbitan esters, monostearate sorbitan ester, single Palmic acid sorbitan ester, mono laurate sorbitan ester etc.
10.POE the lanolin derivative of lanoline, POE lanolin alcohol, POE Sorbitol lanoline etc.
11. the alkanolamide of lauric acid diethyl amide, fatty acid distribution of coconut oil diglycollic amide etc.
12.POE the POE fatty acid amide of stearmide etc.
13. sucrose fatty acid ester.
14. the alkyl amine oxide of dimethyllaurylamine oxide etc.
15. the alkyl androstanediol of lauryl glucoside, alkyl (8～16) glucoside etc.
16. lecithin derivant hydrogenated soy phosphatidyl choline, hydrogenated yolk lecithin etc.
17.POE the POE POP alkyl ether of polyoxypropylene (being designated hereinafter simply as POP) cetyl ether etc.
((A) surfactant beyond the composition)
And, under the scope that does not hinder the invention effect, in cosmetic hair composition of the present invention, except cooperating nonionic surfactant, can also cooperate the surfactant of other kind arbitrarily.As the surfactant of these other kinds, can enumerate cationic surfactant, anionic surfactant, amphoteric surfactant.
Cationic surfactant can be enumerated for example lauryl trimethyl ammonium chloride; cetyl trimethyl ammonium chloride (Cetrimonium Chloride); stearyl trimethyl ammonium chloride (Stearyl trimonium Chloride); alkyl trimethyl ammonium chloride; mountain Yu base trimethyl ammonium chloride (Behentrimonium Chloride); VARISOFT TA100 (Distearyldimonium Chloride); two cocoyl alkyl dimethyl ammonium chlorides; the cetyl trimethylammonium bromide; the stearyl trimethylammonium bromide; ethyl sulfuric acid lanoceric acid aminopropyl ethyl Dimethyl Ammonium; stearyl trimethyl ammonium glucide hydrochlorate; cetyl trimethyl ammonium glucide hydrochlorate; mountain Yu base trimethyl ammonium Methylsulfate and quaternary ammonium salt-91 etc., but be not limited thereto.Cationic surfactant can use a kind separately, but considers from the aspect of foaming characteristic and sense of touch, preferably will also use more than 2 kinds.The use level of cationic surfactant is preferably 0.1～10 quality %.
The anionic surfactant can enumerate for example alkyl ether sulfate of POE sodium laureth sulfate etc.; sodium lauryl sulphate; sodium cetostearylsulphate; the alkyl sulfate of sodium hexadecyl sulfate etc.; alkene ether sulfate; alkenyl sulfate; alkene sulfonate; alkane sulfonate; saturated or unsaturated fatty acid salt; the alkyl or alkenyl ether carboxylate; α-alpha-sulfonated fatty hydrochlorate; the N-acyl amino acid type surfactant of cocoyl glutamic acid triethanolamine (cocoyl glutamic acid TEA) etc.; mono phosphoric acid ester or diester type surfactant; with sulfosuccinate etc.As the equilibrium ion of the anion base of these surfactants, can enumerate for example sodium ion, potassium ion and triethanolamine.Anionic surfactant's use level is preferably 0.05～10 quality %.
Amphoteric surfactant can be enumerated following material.
1. fatty acid amide propyl-dimethyl glycine betanin and their sodium salt, potassium salt or the triethanolamine salt of fatty acid distribution of coconut oil amido propyl dimethylaminoethyl acid betanin, palm oil fatty acid amido propyl dimethylaminoethyl acid betanin, dodecanamide propyl dimethylaminoethyl acid betanin (dodecanamide propyl betanin), ricinoleic acid amide propyl-dimethyl glycine betanin etc.
2. alkyl dimethyl glycine betanin and their sodium salt, potassium salt or the triethanolamine salt of decyl dimethylaminoethyl acid betanin, lauryl dimethyl glycine betanin, myristyl dimethylaminoethyl acid betanin, cetyl dimethylaminoethyl acid betanin, stearyl dimethylaminoethyl acid betanin, oil base dimethylaminoethyl acid betanin, mountain Yu base dimethylaminoethyl acid betanin, cocos nucifera oil alkyl dimethyl glycine betanin etc.
3. cocos nucifera oil acyl both sexes guanidine-acetic acid sodium (N-fatty acid distribution of coconut oil acyl group-N '-carboxymethyl-N '-hydroxyethylethylene diamine); cocos nucifera oil acyl both sexes base sodium propionate (N-fatty acid distribution of coconut oil acyl group-N '-carboxyethyl-N '-hydroxyethylethylene diamine); lauroyl both sexes guanidine-acetic acid sodium (N-lauroyl-N '-carboxymethyl-N '-hydroxyethylethylene diamine); Fructus Canarii albi oleoyl both sexes guanidine-acetic acid sodium; cocoa acyl both sexes guanidine-acetic acid sodium; Semen Sesami oleoyl both sexes guanidine-acetic acid sodium; Prunus dulcis oleoyl both sexes guanidine-acetic acid sodium; stearoyl both sexes guanidine-acetic acid salt; palmitoleoyl both sexes guanidine-acetic acid sodium; Semen arachidis hypogaeae oleoyl both sexes guanidine-acetic acid sodium; heronsbill seed oleoyl both sexes guanidine-acetic acid sodium; the N-acyl amino ethyl-N-2-hydroxyethyl aminocarboxylate of Semen Gossypii oleoyl both sexes guanidine-acetic acid sodium etc.
4. the N-acyl amino ethyl-N-carboxymethoxyl ethylamino carboxylate of cocos nucifera oil acyl both sexes base sodium diacelate, cocos nucifera oil acyl both sexes base dipropionic acid and lauroyl both sexes base sodium diacelate etc.
5. hydroxy alkyl (C12-14) hydroxyethyl sarcosine.
The use level of amphoteric surfactant is preferably 0.05～10 quality %.
((B) composition and (B1) composition)
((B) composition)
(B) composition is silicone.(B) use level of composition is unqualified, can consider following mass ratio B/C and sets preferred use level.In general, above-mentioned use level preferably is in the scope about 0.01～3 quality % in cosmetic hair composition.
Dimethicone), have a dimethyl polysiloxane (INCI name: dimethiconol), methyl phenyl silicone, decamethylcyclopentaandoxane, ten diformazan basic rings, six siloxanes, polyether modified silicone, amino modified silicone, betanin modified silicone, alkyl-modified silicone, alkoxy-modified silicone, sulfhydryl modified silicone, carboxy-modified silicone, fluorine modified silicone etc. of C-terminal base as the object lesson of silicone, can enumerate (the INCI name: of dimethyl polysiloxane for example.Amino modified silicone is preferably enumerated aminoethylamino propyl group methylsiloxane dimethylsiloxane copolymer.Polyether modified silicone can be enumerated PEG-10 dimethyl polysiloxane (PEG-10 dimethicone), PEG-11 dimethyl polysiloxane (PEG-11 dimethicone).
((B1) composition)
(B1) composition is the polyoxyethylene modified silicone.It is a kind of of silicone.(B1) use level of composition is unqualified, preferably in the scope of 0.01～5 quality %, in the scope particularly preferably in 0.05～2 quality %.
As the polyoxyethylene modified silicone, except PEG-10 dimethyl polysiloxane (the INCI name: the average addition molal quantity of ethylene oxide is 10 material) or PEG-11 dimethyl polysiloxane as polyoxyethylene methyl polysiloxane polymer, other also especially preferably enumerates the PEG-3 dimethyl polysiloxane, the PEG-7 dimethyl polysiloxane, the PEG-8 dimethyl polysiloxane, the PEG-9 dimethyl polysiloxane, the PEG-12 dimethyl polysiloxane, the PEG-14 dimethyl polysiloxane, the PEG-17 dimethyl polysiloxane, PEG-6 methyl ether dimethyl polysiloxane, PEG-7 methyl ether dimethyl polysiloxane, PEG-8 methyl ether dimethyl polysiloxane, PEG-9 methyl ether dimethyl polysiloxane, PEG-10 methyl ether dimethyl polysiloxane, PEG-11 methyl ether dimethyl polysiloxane, PEG-32 methyl ether dimethyl polysiloxane, PEG-9 polydimethylsiloxane base ethyl dimethyl polysiloxane, lauryl PEG-9 polydimethylsiloxane base ethyl dimethyl polysiloxane etc.
And under the scope that does not hinder the invention effect, for the cosmetic hair composition of the 2nd invention group, the polyoxyethylene modified silicone except as (B1) composition can also cooperate the silicone of other kinds arbitrarily.
As these silicones, can enumerate for example dimethyl polysiloxane (dimethicone), methyl phenyl silicone, decamethylcyclopentaandoxane, ten diformazan basic rings, six siloxanes, amino modified silicone, betanin modified silicone, alkyl-modified silicone, alkoxy-modified silicone, carboxy-modified silicone, fluorine modified silicone.
((C) composition)
(C) composition is to be selected from the cationization polymer and to contain the diallyl quaternary ammonium salt and at least a as in the copolymer that constitutes the unit of acrylic acid.(C) there is no particular limitation for the use level of composition, preferably in the scope of 0.01～2 quality %.On the other hand, (A) content of composition is unqualified with respect to the mass ratio A/C of the content of (C) composition, preferably in 10～1000 scope, in preferred especially 50～500 the scope.(B) content of composition is also unqualified with respect to the mass ratio B/C of the content of (C) composition, preferably in 0.01～50 scope, in preferred especially 0.1～20 the scope.
The cationization polymer is water miscible cationization polymer preferably.Water miscible cationization polymer can be enumerated Poise C-80M as the cationization polysaccharide, cationic starch, JR-125 etc., can also enumerate dimethyl diallyl ammonium chloride polymer (polyquaternary ammonium salt-6 (POLYQUATERNIUM-6), for example マ ー コ ー ト 100 (MERQUAT 100) in addition; Nalco company), dimethyl diallyl ammonium chloride/acrylamide copolymer (polyquaternary ammonium salt-7 (POLYQUATERNIUM-7), for example マ ー コ ー ト 550 (MERQUAT 550); Nalco company), quaternized polyvinyl pyrrolidone etc.
As the object lesson of Poise C-80M, can enumerate chlorination O-[2-hydroxyl-3-(trimethyl ammonium) propyl group] hydroxyethyl-cellulose, addition glycidyl trimethyl ammonium chloride and polymer (polyquaternary ammonium salt-10 (POLYQUATERNIUM-10), for example レ オ ガ ー De G (LEOGARD G), the レ オ ガ ー De GP of the quaternary ammonium salt that obtains on hydroxyethyl-cellulose; ラ イ オ Application company, Port リ マ ー JR-125, Port リ マ ー JR-400, Port リ マ ー JR-30M, Port リ マ ー LR-400, Port リ マ ー LR-30M; Amerchol company), hydroxyethyl-cellulose/dimethyl diallyl ammonium chloride copolymer (polyquaternary ammonium salt-4 (POLYQUATERNIUM-4), for example セ ル コ ー ト HC-100 (CELQUAT HC-100), セ ル コ ー ト HC-200, セ ル コ ー ト LC-100, セ ル コ ー ト L-200; Na シ ョ Na Le ス タ ー チ ア Application De ケ ミ カ Le company) etc.
The object lesson of JR-125 can be enumerated chlorination O-[2-hydroxyl-3-(trimethyl ammonium) propyl group] guar gum etc.
The object lesson of quaternized polyvinyl pyrrolidone can be enumerated by vinyl pyrrolidone (VP) and the copolymer of dimethylaminoethyl methacrylate and quaternary ammonium salt (polyquaternary ammonium salt-11 (POLYQUATERNIUM-11), for example ガ フ コ ー ト 734 (GAFQUAT 734), ガ フ コ ー ト 755, the ガ フ コ ー ト 755N that dithyl sulfate obtains; ア イ エ ス ピ ー ジ ャ パ Application company) etc.
As containing diallyl quaternary ammonium salt and the acrylic acid object lesson as the copolymer that constitutes the unit, can enumerate dimethyl diallyl ammonium chloride/acrylic copolymer (polyquaternary ammonium salt-22 (POLYQUATERNIUM-22), for example マ ー コ ー ト 280 (MERQUAT 280), マ ー コ ー ト 295; Nalco company), acrylic acid/dimethyl diallyl ammonium chloride/acrylamide copolymer (polyquaternary ammonium salt-39 (POLYQUATERNIUM-39), マ ー コ ー ト プ ラ ス 3330 (MERQUAT PLUS3330) for example, 3331; Nalco company) etc.
Wherein, raise if consider the viscosity of cosmetic hair composition, then be preferably selected from the cationization polysaccharide especially and contain at least a as in the polymer that constitutes the unit and the copolymer of diallyl quaternary ammonium salt.
((C) polymer beyond the composition)
And under the scope that does not hinder the invention effect, for the cosmetic hair composition of the 7th invention group, the above-mentioned cationization polymer except as (C) composition can also cooperate the polymer of other kinds arbitrarily.
As these polymer, can enumerate for example anionic property polymer of CVP Carbopol ETD2050 etc., the amphiphilic polymers of having removed the composition that is equivalent to (C) composition of acrylic acid acrylic acid methyl ester. Methacrylamide oxypropyl trimethyl ammonium chloride copolymer etc., arabic gum, the vegetalitas polymer of carrageenan etc., dextran, the department of microbiology polymer of pulullan polysaccharide etc., collagen, casein, the animality polymer of gelatin etc., the starch based polymer of carboxymethyl starch etc., methylcellulose, carboxymethyl cellulose, the cellulose-based polymer of hydroxyethyl-cellulose etc., the ethylene base system macromolecule of CVP Carbopol ETD2050 etc. etc.
(kind of cosmetic hair composition)
Cosmetic hair composition of the present invention is unqualified, for example can be used as oxide hair dye, acid hair dye, hair depigmenting agent or hair and takes off stain and constitute.Especially preferably constitute as oxide hair dye or hair depigmenting agent.
(oxide hair dye)
Oxide hair dye comprises the 1st preparation that contains basic species and oxidation dye and the 2nd preparation that contains oxidant, and its melanin with hair decomposes, owing to the oxidation polymerization of the oxidation dye that utilizes oxidant to produce is had hair dyed.Oxidation dye is categorized as dyestuff intermediate and coupling agent.Also can cooperate the direct dyes of basic stain, nitro dye, natural dye, disperse dyes etc. to replace oxidation dye.
Dyestuff intermediate can be enumerated for example phenylenediamine, aminophenols, diaminotoluene class, diphenyl amine, diamino-phenyl amine, N-phenyl phenylenediamine, diamino-pyridine class and their salt.Salt can be enumerated hydrochlorate, sulfate and acetate etc.
Coupling agent is that the chemical compound of color development can be contained in the 1st preparation as required by the combination dye intermediate.Coupling agent can be enumerated for example resorcinol, pyrogallol, catechol, m-aminophenol, m-diaminobenzene., 2,4-diaminophenol, 1,2,4-benzene triol, Toluene-3,4-dithiol, 4-diamidogen, Toluene-2,4-diisocyanate, 4-diamidogen, hydroquinone, α-naphthalene alcohol, 2,6-diamino-pyridine, 1,5-dihydroxy naphthlene, the amino orthoresol of 5-, p-methylaminophenol, 2,4-diamino phenoxy ethanol, gallic acid, tannic acid, progallin A, gallicin, propyl gallate, Galla Chinensis, 5-(2-hydroxyethyl amino)-2-methylphenol and their salt.
The content of the dyestuff intermediate in the oxide hair dye is preferably 0.01～10 quality %, more preferably 0.1～5 quality %.The content of dyestuff intermediate might can not obtain sufficient dyeability during less than 0.01 quality %.Even the content of dyestuff intermediate surpasses 10 quality %, dyeability does not have bigger raising yet, thereby the economy of hair dyeing might reduce.
The 1st preparation can suitably contain at least a of the oxidation dye of record in " the medicine part outer article raw material Regulations lattice " that for example are selected from Japan (in June, 2006 distribution, medicine thing day newspaper office) and direct dyes, is used as the dyestuff beyond the above-mentioned oxidation dye.
Basic species makes the hair swelling simultaneously by promoting to be contained in the effect of the oxidant in the 2nd preparation, increases dyestuff for the impregnability of hair, and dyeability is improved.Basic species can be enumerated for example ammonia, alkanolamine, organic amine, inorganic base, basic amino acid and sulfate.Organic amine can be enumerated for example 2-amino-2-methyl-1, ammediol and guanidine.Inorganic base can be enumerated for example sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, ammonium carbonate, sodium bicarbonate and ammonium bicarbonate.Basic amino acid can be enumerated for example arginine and lysine and alkaline amino acid salt.The salt of basic amino acid can be enumerated for example ammonium salt.Sulfate can be enumerated ammonium sulfate.
The content of basic species is that to make pH be the amount of 7～12 scopes preferably in the oxide hair dye that has mixed the 1st preparation and the 2nd preparation.If when pH less than 7, then contains as the hydrogen peroxide of oxidant, can not fully promote the effect of hydrogen peroxide in the 2nd preparation.If the pH when using surpasses 12, when then being coated on oxide hair dye on the hair, the shortcoming that might take place that hair sustains damage easily etc.
The 2nd preparation contains oxidant at least.Oxidant makes oxidation dye carry out oxidation polymerization and color development.Oxidant can be enumerated for example hydrogen peroxide adduct of hydrogen peroxide adduct, phosphatic hydrogen peroxide adduct and the pyrophosphate of hydrogen peroxide, urea peroxide, peroxidating tripolycyanamide, SODIUM PERCARBONATE, potassium percarbonate, Dexol, potassium perborate, sodium peroxide, potassium peroxide, Magnesium dioxide, Barium dioxide, calper calcium peroxide, strontium peroxide, sulfate.
The content of oxidant is preferably 0.1～10.0 quality % in the 2nd preparation, more preferably 0.5～8.0 quality %.The content of oxidant might be difficult to make oxidation dye fully to carry out oxidation polymerization during less than 0.1 quality %.When the content of oxidant surpasses 10.0 quality %, might damage hair easily.
(acid hair dye)
Acid hair dye be generally single preparation formula (
), fluidity is the acidity about pH2.5～4.0, it is for the hair that has cationic, can make acid stain carry out the material of ions binding.Acid stain can be enumerated for example nitro dye, azo dye, nitroso-dyes, triphenhlmethane dye, ton dyestuff, quinoline dye, anthraquinone dye, indigoid dye etc.
As acid stain, more specifically, can enumerate red No. 2, red No. 3, red No. 102, red No. 104, red No. 105, red No. 106, red No. 227, red No. 230, yellow No. 4, yellow No. 5, yellow No. 202, yellow No. 203, orange No. 205, orange No. 207, orange No. 402, green No. 3, green No. 204, green No. 401, No. 401, purple, blue No. 1, blue No. 2, blue No. 202, No. 201, brown, No. 401, black etc.
The content of the acid stain in the acid hair dye is 0.005～5 quality %, more preferably 0.01～3 quality %.
(hair depigmenting agent)
The hair depigmenting agent comprises the 1st preparation that contains basic species and the 2nd preparation that contains oxidant, and its melanin with hair decomposes, and hair is decoloured.The hair depigmenting agent is not except containing oxidation dye, and other has same formation with oxide hair dye basically.
(hair takes off stain)
Hair take off stain be generally the above many preparations formula of two preparations (
), its main purpose is to carry out taking off of hair to dye (decomposition of dying the dyestuff on hair), compare with the hair depigmenting agent, difference is to cooperate in the basic species in the 1st preparation, and then cooperates a kind of persulfate as basic species to be used as decoloring assistant.The 1st preparation is Powdered or graininess, lamellar etc., and the 2nd preparation is aqueous.
Persulfate is preferably enumerated the alkali metal salt of persulfuric acid, especially preferred potassium peroxydisulfate or sodium peroxydisulfate.The use level of persulfate is unqualified, preferably in the scope of 2.0～25 quality %, more preferably in the scope of 3.5～18 quality %.
(other composition in the cosmetic hair composition)
In the 1st preparation or the 2nd preparation of cosmetic hair composition, except mentioned component, can also suitably select and contain for example oiliness composition, water-soluble high-molecular compound, chelating agen, inorganic salt, dispersant etc. as required.
As the oiliness composition, except above-mentioned silicone, can enumerate for example higher alcohol, oils and fats, wax, hydrocarbon, higher fatty acids, alkyl glycerylether, ester, polyhydric alcohol.
As higher alcohol, can enumerate for example spermol (hexadecanol), 2-hexyldecanol, stearyl alcohol, isooctadecanol, 16 octadecanol, oleyl alcohol, arachidic alcohol, behenyl alcohol, 2-octyl dodecanol, lauryl alcohol, myristyl alcohol, decyl tetradecyl alchohol and lanolin alcohol.Higher alcohol has following effects: in the blister dosage form that cosmetic hair composition is formed the non-aerosol type and when being coated on the hair, can promote the effect of dripping of preventing of preparation.
Oils and fats can be enumerated for example lanoline, olive oil, Chinese toon oil, shea butter, almond oil, safflower oil, Oleum helianthi, soybean oil, Oleum Gossypii semen, Oleum sesami, Semen Maydis oil, Oleum Brassicae campestris, Testa oryzae oil, rice germ oil, seed of Fructus Vitis viniferae oil, American Avocado Tree oil, macadimia nut oil, Oleum Ricini, cocos nucifera oil and Radix Oenotherae erythrosepalae oil.
Wax can be enumerated for example Cera Flava, candelilla wax, Brazil wax, Jojoba oil and lanoline.
Hydrocarbon can be enumerated for example paraffin, olefin oligomer, polyisobutylene, Parleam, mineral oil, squalane, polybutene, polyethylene, microwax and vaseline.
Higher fatty acids can be enumerated for example lauric acid, myristic acid, Palmic acid, stearic acid, mountain Yu acid, isostearic acid, 12-hydroxy stearic acid, oleic acid and lanoceric acid.
Alkyl glycerylether can be enumerated for example batilol .alpha.-hexadecylglyceryl ether, selachyl alcohol and iso stearyl glycerin ether.
Ester can be enumerated for example diisopropyl adipate, isopropyl myristate, Octanoic acid, hexadecyl ester, the different nonyl ester of different n-nonanoic acid, myristic acid octyl group dodecyl ester, isopropyl palmitate, the stearic acid stearyl, myristyl myristate, myristic acid isotridecyl ester, Palmic acid 2-Octyl Nitrite, castor oil acid octyl group dodecyl ester, carbon number is fatty acid cholesterol ester/lanosterol ester of 10～30, the lactic acid cetyl, the acetoxylation lanoline, two-2 ethyl hexanoic acid glycol ester, pentaerythritol fatty ester, the dipentaerythritol fatty acid ester, the capric acid cetyl, tricaprin, malic acid two different stearyl esters, dioctyl succinate and 2 ethyl hexanoic acid cetyl.
Polyhydric alcohol can be enumerated for example dihydroxylic alcohols and glycerol.Dihydroxylic alcohols can be enumerated for example ethylene glycol, diethylene glycol, triethylene glycol, Polyethylene Glycol, propylene glycol, dipropylene glycol, isoamyl two pure and mild 1,3 butylene glycols.Glycerol can be enumerated for example glycerol, two glycerol and polyglycereol.
Water-soluble high-molecular compound for example can enumerate the natural series macromolecule, semi-synthetic be macromolecule, synthetic be macromolecule.
The high molecular object lesson of natural series can be enumerated arabic gum, carrageenan, galactan, guar gum, Semen Fructus Chaenomelis glue, locust bean gum, Tragacanth, pectin, mannan, starch, xanthan gum, glucosan, curdlan, succinoglycan, gelatin, collagen protein, casein, albumin, tamarind gum etc.
As semi-synthetic be high molecular object lesson, can enumerate the cellulose-based macromolecule of methylcellulose, ethyl cellulose, hydroxyethyl-cellulose, carboxymethyl cellulose, hydroxypropyl emthylcellulose etc.; The starch of carboxymethyl starch, methyl starch, soluble starch etc. is macromolecule; The alginic acid of alginate, propylene glycol alginate etc. is macromolecule; Guar gum is macromolecule etc.
As synthetic be high molecular object lesson, can enumerate the ethylene base system macromolecule of CVP Carbopol ETD2050, polyacrylamide, acrylic acid alkyl methacrylate copolymer, polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl methyl ether, sodium polyacrylate etc.; Polyethylene glycol oxide; The ethylene oxide oxypropylene block copolymer; The cationization thing of vinyl pyrrolidone dimethylaminoethyl methacrylic acid copolymer; The homopolymer of dimethyl diallyl ammonium chloride, the dimethyl diallyl ammonium chloride acrylamide copolymer, the QAS polymer derivant of dimethyl diallyl ammonium chloride acrylic copolymer etc., the alkyl acrylate copolymer emulsion, alkyl acrylate styrol copolymer emulsion, the acrylic acid series aqueous dispersed polymer of the polyxyethylated monoester copolymer emulsion of alkyl acrylate alkyl methacrylate polyoxyethylene (20) stearyl ether copolymer emulsion and alkyl acrylate itaconic acid etc. etc.
Chelating agen can be enumerated for example ethylenediaminetetraacetic acid (EDTA, edetic acid), hydroxyethylethylene diamine tri-acetic acid (HEDTA) and its salt, diethylenetriamine pentaacetic acid and its esters and hydroxyl ethane di 2 ethylhexyl phosphonic acid (HEDP, etidronic acid) and its esters.Inorganic salt can be enumerated for example sodium chloride, sodium sulfate.Dispersant can be enumerated for example magnesium stearate.
In the 1st preparation or the 2nd preparation of the cosmetic hair composition of the cosmetic hair composition of single preparation formula or two preparation formulas, other also can contain at least a in the material of record in " the medicine part outer article raw material Regulations lattice " that for example are selected from saccharide, antiseptic, stabilizing agent, pH regulator agent, plant extract, extracts from crude drugs, vitamins, spice and UV absorbent and Japan (in June, 2006 distribution, medicine thing day newspaper office).
(using method of cosmetic hair composition)
The using method of cosmetic hair composition of the present invention is that above-mentioned cosmetic hair composition is discharged with blister from the non-aerosol foaming vessel, and is applied to the method for hair.
As the non-aerosol foaming vessel, as long as for cosmetic hair composition, the container with function of the foaming that can carry out the non-aerosol type and discharge gets final product, and is unqualified.The following non-aerosol foaming vessel of preferred use bubbles.
(hair cosmetic product)
Hair cosmetic product of the present invention contains and forms the blister dosage form of non-aerosol type when using and be applied to the above-mentioned cosmetic hair composition of hair and be used for the non-aerosol foaming vessel that this cosmetic hair composition is discharged with blister and constitute.
As the representative example of non-aerosol foaming vessel, can enumerate pump foam maker or crushed foam generator.The pump foam maker is to carry out extrusion operation by the head to pump, accommodate the container that liquid (for example the 1st preparation of hair cosmetic composition/the 2nd preparation mixed liquor) is discharged with blister and make, wherein, accommodate the peristome that liquid mixes with air, is assemblied in container body with the bubble displacer of blister discharge with making.The pump foam maker is open in TOHKEMY 2007-275777 communique etc., is known.The crushed foam generator refers to following equipment, namely, by using finger the container body of soft synthetic resin system to be pushed (repeating to remove operation for squeeze operation and the compression of container), the same liquid and the air of accommodating imported foam maker with in the gas-liquid mixed chamber of discharging head and mix, and the bubble that utilizes the bubble displacer to form is discharged from nozzle.The crushed foam generator is recorded in the document " the new い of ヘ ア カ ラ ー skill Intraoperative Move is to (blister ヘ ア カ ラ ー skill Intraoperative Open send out-) " of TOHKEMY 2008-291024 communique or number publication magazine " Off レ グ ラ Application ス ジ ャ ー Na Le (Fragrance Journal) " in June, 2009 etc., is known.
The bubble displacer of non-aerosol foaming vessel has 1 or many perforated membrane that is used to form bubble.The material of perforated membrane can be enumerated nylon, polyester, polyethylene, polypropylene etc.The sieve mesh preference of perforated membrane is as being 50～300 sieve meshes.In addition, the mixing ratio of gas and liquid (gas-liquid mixed than) scope of gas/liquid=5/1～20/1 preferably.
Embodiment
Embodiment and the comparative example of the 2nd invention group and the 7th invention group below are described.Technical scope of the present invention is not limited to these embodiment and comparative example.
The embodiment of the 2nd invention group
(formations of two preparation formula hair dyes)
Prepare shown in the following table 1 the example 1～example 9 of hair dye the 2nd preparation formed shown in the example 1～example 7 of hair dye the 1st preparation formed and the table 2, as as shown in " combination " hurdle of table 3, with these the 1st preparations and the combination of the 2nd preparation selectivity, constitute the two preparation formula hair dyes that relate in embodiment 1～embodiment 9, the comparative example 1～comparative example 5.
In table 1 and table 2, the numerical value of representing the component content of the 1st preparation or the 2nd preparation is not the content statement when the 1st preparation and the 2nd preparation are mixed, but is the content statement of unit with quality % in the 1st preparation or the 2nd preparation.(A) composition of the present invention for being equivalent to or (B1) composition of composition, the marge in the left side of table is expressed as " A " or " B1 ".The composition that the marge in left side at table is expressed as " B1 than " is represented the composition with respect to the relatively usefulness of (B1) composition.Use the FZ-4671 as aminoethylamino propyl group methylsiloxane dimethylsiloxane copolymer (20%) of eastern レ ダ ウ コ ー ニ Application グ corporate system as " B1 ratio " the aminoethylamino propyl group methylsiloxane dimethylsiloxane copolymer of composition shown in the table 2.
In the table 3, the numeral that shows in the item of " the 1st preparation " in " combination " hurdle and " the 2nd preparation " is the example numbering of the 1st preparation shown in table 1 or the table 2 or the 2nd preparation.
(evaluations of two preparation formula hair dyes)
Be that 1: 1 ratio is accommodated in the above-mentioned non-aerosol foaming vessel (pump foam maker) with the 1st preparation of the various embodiments described above, each comparative example and the 2nd preparation with mass ratio, form mixed liquor, carry out extrusion operation by the head with this pump, above-mentioned mixed liquor is discharged with the infusion type.The pump foam maker uses made trade name W-5721, WP foam maker pump L bleed type (the gas/liquid mixing ratio: 13/1 of (strain) lucky wild industry, output: 0.9g(1 extruding), perforated membrane: 2 of the polyethylene of 90 sieve meshes メ ッ processed シ ュ リ Application グ).
(evaluation of sense of touch)
After the hair dye of the above-mentioned blister that each embodiment, each comparative example are related to is discharged, utilize conventional method to coat with on the long hair bundle that judges with the 30cm of hair immediately respectively.Evaluation hair after the after washing coating in 30 minutes is had one's hair wash 2 times, after then handling, comes to estimate with the sense of touch of hair estimating by 10 experimenters.
Estimate according to carrying out based on 8 stages of following metewand, in 10 experimenters' evaluation result, adopt maximum evaluation results.Evaluation result is shown in table 3.
◎: hair does not harden, and is very smooth, and smoothness is good
◎～zero: hair does not harden, and is smooth, and smoothness is good
Zero: hair hardens hardly, and is smooth
Zero～△: hardening of hair is few, smooth
△: feel that a little hair hardens, hair surface is smooth inadequately
△～*: feel that hair hardens, hair surface is smooth inadequately
*: hair hardens, and hair surface is rough
* *: hair is stone, and hair surface is rough.
(evaluation of drippage)
The hair dye of the above-mentioned blister that each embodiment, each comparative example are related to is coated on the wig after discharging immediately, then carry out under 40 ℃ the condition 30 minutes through the time observe, the drippage complexity of blister hair dye is observed, is estimated.Estimate basis and carry out based on 8 stages of following metewand, evaluation result is shown in table 3.
◎: the liquefaction, the drippage that do not have bubble fully
◎～zero: bubble is not liquefaction almost, not drippage
Zero: bubble has liquefaction slightly, but does not drip
Zero～△: in 30 minutes, steep raising is given birth to liquefaction, drippage
△: in 15 minutes, steep raising is given birth to liquefaction, drippage
△～*: in 10 minutes, steep raising is given birth to liquefaction, drippage
*: in 5 minutes, steep raising is given birth to liquefaction, drippage
In * *: 5 minutes, steep raising is given birth to liquefaction, is dripped in large quantities.
[table 1]
[table 2]
[table 3]
The embodiment of the 7th invention group
(formations of two preparation formula hair dyes)
Prepare shown in the following table 4 the example 1～example 13 of hair dye the 2nd preparation formed shown in the example 1～example 6 of hair dye the 1st preparation formed and the table 5, as as shown in " combination " hurdle of table 6, with these the 1st preparations and the combination of the 2nd preparation selectivity, constitute the two preparation formula hair dyes that relate in embodiment 1～embodiment 14, the comparative example 1～comparative example 4.
In table 4 and table 5, the numerical value of representing the component content of the 1st preparation or the 2nd preparation is not the content statement when the 1st preparation and the 2nd preparation are mixed, but is the content statement of unit with quality % in the 1st preparation or the 2nd preparation.(A) of the present invention for being equivalent to composition, (B) composition or (C) composition of composition, the marge in the left side of table is expressed as " A ", " B " or " C " respectively.Used the FZ-4671 as aminoethylamino propyl group methylsiloxane dimethylsiloxane copolymer (20%) of eastern レ ダ ウ コ ー ニ Application グ corporate system as the aminoethylamino propyl group methylsiloxane dimethylsiloxane copolymer of " B " composition shown in the table 5.
In the table 6, the numeral that shows in the item of " the 1st preparation " in " combination " hurdle and " the 2nd preparation " is the example numbering of the 1st preparation shown in table 4 or the table 5 or the 2nd preparation.The mass ratio A/C and the mass ratio B/C that have represented each embodiment, comparative example in the table 6 in the lump.
(evaluations of two preparation formula hair dyes)
Be that 1: 1 ratio is accommodated in the made pump foam maker of above-mentioned (strain) lucky wild industry with the 1st preparation of the various embodiments described above, each comparative example and the 2nd preparation with mass ratio, form mixed liquor, carry out extrusion operation by the head with this pump, discharge above-mentioned mixed liquor with the infusion type.
(evaluation of alveolar substance)
For the hair dye of the blister of each embodiment that discharges from the non-aerosol foaming vessel, each comparative example, utilize the texture exquisiteness (
) the observation evaluation of volume big (the high さ of か さ) estimates " alveolar substance ".
Estimate basis and carry out based on 8 stages of following metewand, evaluation result is shown in table 6.
◎: the texture exquisiteness of bubble, in good order, the very large bubble of volume
◎～zero: the texture of bubble is neat, the very large bubble of volume
Zero: the texture of bubble is neat, bulky bubble
Zero～△: the texture of bubble is neat, the bubble of a bit deficient on the volume
△: have slightly foaming (
), the bubble that is weak on the volume
△～*: foaming is many, the bubble that is weak on the volume
*: foaming is many, washiness and the bubble that spreads
* *: bubbled many and the big bubble of interlock, a lot of and bubble of diffusion of moisture
Wherein, bubble (bubble か body) do not refer to the neat state of uniform, so-called texture that steeps, and refers to contain big bubble and the situation of discharging from pump foam maker container.
(evaluation of sense of touch)
After the hair dye of the above-mentioned blister that each embodiment, each comparative example are related to is discharged, utilize conventional method to coat with on the long hair bundle that judges with the 30cm of hair immediately respectively.Evaluation hair after the after washing coating in 30 minutes is had one's hair wash 2 times, after then handling, comes to estimate with the sense of touch of hair estimating by 10 experimenters.
Estimate according to carrying out based on 8 stages of following metewand, in 10 experimenters' evaluation result, adopt maximum evaluation results.Evaluation result is shown in table 6.
◎: hair does not harden, and is very smooth, and smoothness is good
◎～zero: hair does not harden, and is smooth, and smoothness is good
Zero: hair hardens hardly, and is smooth
Zero～△: hardening of hair is few, smooth
△: feel that a little hair hardens, hair surface is smooth inadequately
△～*: feel that hair hardens, hair surface is smooth inadequately
*: hair hardens, and hair surface is rough
* *: hair is stone, and hair surface is rough.
[table 4]
[table 5]
[table 6]
The industry utilizability
According to the present invention, the hair cosmetic composition of discharging with the blister dosage form from the non-aerosol foaming vessel can be provided, it can give hair good sense of touch, and does not have the shortcoming of discharging alveolar substance, does not drip when being applied to hair.
Claims (13)
1. cosmetic hair composition, it is as hair dye or hair depigmenting agent and constitute, during use the mixed liquor of the 1st preparation and the 2nd preparation is discharged with blister from the non-aerosol foaming vessel, and be applied to hair, it is characterized in that, contain above (A) composition of 10 quality %: nonionic surfactant, and contain (B) composition: silicone.
2. cosmetic hair composition, it is as hair dye or hair depigmenting agent and constitute, during use the mixed liquor of the 1st preparation and the 2nd preparation is discharged with blister from the non-aerosol foaming vessel, and be applied to hair, it is characterized in that, contain following (A) composition that surpasses 10 quality %, and contain following (B1) composition
(A) nonionic surfactant,
(B1) polyoxyethylene modified silicone.
3. the described cosmetic hair composition of claim 2 is characterized in that, the content of above-mentioned (A) composition is in the scope of 11 quality %～25 quality %.
4. claim 2 or 3 described cosmetic hair compositions is characterized in that, above-mentioned cosmetic hair composition is that oxide hair dye, acid hair dye, hair depigmenting agent or hair take off stain.
5. the using method of cosmetic hair composition, it is discharged each described cosmetic hair composition in the claim 2～4 from the non-aerosol foaming vessel with blister, and is applied to hair.
6. hair cosmetic product, it contains each described cosmetic hair composition in the claim 2～4 and is used for the non-aerosol foaming vessel that this cosmetic hair composition is discharged with blister and constitutes.
7. cosmetic hair composition, it is as hair dye or hair depigmenting agent and constitute, during use the mixed liquor of the 1st preparation and the 2nd preparation is discharged with blister from the non-aerosol foaming vessel, and be applied to hair, wherein, contain above following (A) composition of 10 quality %, and contain following (B) composition and (C) composition
(A) nonionic surfactant,
(B) silicone,
(C) be selected from cationization polymer and contain the diallyl quaternary ammonium salt and at least a as in the copolymer that constitutes the unit of acrylic acid.
8. the described cosmetic hair composition of claim 7 is characterized in that, (A) content of composition is in 10～1000 the scope with respect to the mass ratio A/C of the content of above-mentioned (C) composition.
9. claim 7 or 8 described cosmetic hair compositions is characterized in that, (B) content of composition is in 0.01～50 the scope with respect to the mass ratio B/C of the content of above-mentioned (C) composition.
10. each described cosmetic hair composition in the claim 7～9 is characterized in that, above-mentioned (C) composition is to be selected from the cationization polysaccharide and to contain at least a as in the polymer that constitutes the unit and the copolymer of diallyl quaternary ammonium salt.
11. each described cosmetic hair composition is characterized in that in the claim 7～10, above-mentioned cosmetic hair composition is that oxide hair dye, acid hair dye, hair depigmenting agent or hair take off stain.
12. the using method of cosmetic hair composition is characterized in that, each described cosmetic hair composition in the claim 7～11 is discharged with blister from the non-aerosol foaming vessel, and be applied to hair.
13. the hair cosmetic product, it contains each described cosmetic hair composition in the claim 7～11 and is used for the non-aerosol foaming vessel that this cosmetic hair composition is discharged with blister and constitutes.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010-245196 | 2010-11-01 | ||
| JP2010-245607 | 2010-11-01 | ||
| JP2010245607A JP5687030B2 (en) | 2010-11-01 | 2010-11-01 | Hair cosmetic composition, method of use thereof and hair cosmetic product |
| JP2010245196A JP5687029B2 (en) | 2010-11-01 | 2010-11-01 | Hair cosmetic composition, method of use thereof and hair cosmetic product |
| PCT/JP2011/074460 WO2012060239A1 (en) | 2010-11-01 | 2011-10-24 | Hair cosmetic composition, method for using same, and hair cosmetic product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103298450A true CN103298450A (en) | 2013-09-11 |
| CN103298450B CN103298450B (en) | 2016-08-10 |
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| CN201180052533.9A Active CN103298450B (en) | 2010-11-01 | 2011-10-24 | Cosmetic hair composition, its using method and hair cosmetic product |
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| Country | Link |
|---|---|
| CN (1) | CN103298450B (en) |
| TW (1) | TWI587873B (en) |
| WO (1) | WO2012060239A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106163493A (en) * | 2014-03-04 | 2016-11-23 | 朋友株式会社 | Cosmetic hair composition |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6371156B2 (en) | 2013-07-31 | 2018-08-08 | 花王株式会社 | Hair bleaching or dyeing cosmetics |
| JP6166453B2 (en) * | 2015-12-28 | 2017-07-19 | 花王株式会社 | Aerosol cosmetics |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006124279A (en) * | 2004-10-26 | 2006-05-18 | Kao Corp | Two-agent type hair cosmetic |
| CN101835455A (en) * | 2007-10-24 | 2010-09-15 | 花王株式会社 | Two-part hair dye |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5066341B2 (en) * | 2006-04-25 | 2012-11-07 | 花王株式会社 | Hair cosmetics |
| JP4950749B2 (en) * | 2006-04-25 | 2012-06-13 | 花王株式会社 | Hair cosmetics |
-
2011
- 2011-10-24 CN CN201180052533.9A patent/CN103298450B/en active Active
- 2011-10-24 WO PCT/JP2011/074460 patent/WO2012060239A1/en active Application Filing
- 2011-10-31 TW TW100139590A patent/TWI587873B/en not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006124279A (en) * | 2004-10-26 | 2006-05-18 | Kao Corp | Two-agent type hair cosmetic |
| CN101835455A (en) * | 2007-10-24 | 2010-09-15 | 花王株式会社 | Two-part hair dye |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106163493A (en) * | 2014-03-04 | 2016-11-23 | 朋友株式会社 | Cosmetic hair composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103298450B (en) | 2016-08-10 |
| TWI587873B (en) | 2017-06-21 |
| WO2012060239A1 (en) | 2012-05-10 |
| TW201306870A (en) | 2013-02-16 |
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