CN103298450B - Cosmetic hair composition, its using method and hair cosmetic product - Google Patents
Cosmetic hair composition, its using method and hair cosmetic product Download PDFInfo
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- CN103298450B CN103298450B CN201180052533.9A CN201180052533A CN103298450B CN 103298450 B CN103298450 B CN 103298450B CN 201180052533 A CN201180052533 A CN 201180052533A CN 103298450 B CN103298450 B CN 103298450B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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Abstract
Thering is provided the hair cosmetic composition discharged from non-aerosol foaming vessel with blister dosage form, it can give the sense of touch that hair is good, and without discharging the shortcoming of alveolar substance, does not drip when being applied to hair.Cosmetic hair composition, it is constituted as hair dye or hair decolorising agent, during use, the mixed liquor of the 1st preparation and the 2nd preparation is discharged with blister from non-aerosol foaming vessel, and it is applied to hair, it is characterized in that, (A) composition containing more than 10 mass %: nonionic surfactant, and containing (B) composition: silicone.
Description
Technical field
The present invention relates to cosmetic hair composition, its using method and hair cosmetic product.And then in detail, the present invention
Relate to discharge with blister from non-aerosol foaming vessel and being applied to the cosmetic hair composition of hair, its using method,
With the hair cosmetic product constituted containing this cosmetic hair composition and non-aerosol foaming vessel.
Background technology
The hair cosmetic composition of known hair dye or hair decolorising agent etc. uses with the dosage form of blister in use.General next
Say, when using these hair cosmetic compositions with the dosage form of blister, following advantage can be expected: easily on hair without spot ground all
Even coating, can eliminate the hair caking produced when using the hair cosmetic composition of wide variety of gel or paste such
Trouble etc..
It is broadly divided into aerosol type and non-aerosol type with the hair cosmetic composition that the dosage form of blister uses.For gas
Colloidal sol type, uses the such propellant of liquid gas, and making dosage form by make use of aerocolloidal bubble formation is blister.Right
In non-aerosol type, do not use propellant, and use pump foam maker () or crushed foam generation
Other non-aerosol foaming vessel (hereinafter also referred to as " foaming vessel ") of device forms the bubble having taken in air, makes dosage form
For blister.When in terms of simple from constituting of the container for carrying out blister dosage form, favourable on cost and not preserving or
From the standpoint of danger during operation, preferably non-aerosol foaming vessel.
In following patent documentation 1, patent documentation 2, disclose the oxidation utilizing aerosol and make dosage form use for blister
Hair coloring preparation composition or hair coloring preparation composition.It addition, in following patent documentation 3, patent documentation 4, disclose and utilize non-gas molten
Glue foaming vessel and to make dosage form be the hair dye etc. that blister uses.
[patent documentation 1] Japanese Unexamined Patent Publication 09-136818 publication
[patent documentation 2] Japanese Unexamined Patent Publication 10-287534 publication
[patent documentation 3] Japanese Unexamined Patent Publication 2007-291015 publication
[patent documentation 4] Japanese Unexamined Patent Publication 2008-291020 publication
[patent documentation 5] Japanese Unexamined Patent Publication 2006-124279 publication
[patent documentation 6] Japanese Unexamined Patent Publication 2004-339216 publication
[patent documentation 7] Japanese Unexamined Patent Publication 2010-006803 publication.
Summary of the invention
For the hair cosmetic composition of blister dosage form can discharged from non-aerosol foaming vessel, have above-mentioned various excellent
Point, but then, the problem that there is also the good sense of touch (feel) being difficult to obtain hair.Therefore, as in above-mentioned patent documentation 5
Disclosed double preparation formula () hair cosmetic composition is such, as improving the composition of sense of touch, attempt having coordinated the silicon being currently known
Ketone, or as the double preparation formula blister hair dyes described in above-mentioned patent documentation 6,7, as the composition of raising sense of touch,
Attempt having coordinated the cationization polymer being currently known.
But, silicone has froth breaking effect, and when therefore being coordinated in the hair cosmetic composition of blister dosage form, existing should
Be prone to when hair drippage () problem of such discharge alveolar substance.It addition, when coordinating cationization polymer, hair
The viscosity sending out cosmetics raises, and therefore there is (1) hair cosmetic composition and is difficult to the sieve aperture of the net by non-aerosol foaming vessel, no
Can generate the bubble of the fine and smooth high-quality of texture, (2) alveolar substance the most excessively becomes by force, poor to the affinity of hair, is formed and is difficult to be coated on hair
The problem of the discharge alveolar substance on Faing.
Therefore, the problem that the present invention to be solved is to provide the hair discharged from non-aerosol foaming vessel with blister dosage form
Cosmetic, it can give the sense of touch that hair is good, and without discharging the shortcoming of alveolar substance, not drip when being applied to hair.
(composition of the 1st invention)
In order to solve above-mentioned problem, the composition of the application the 1st invention is cosmetic hair composition, its as hair dye or
Hair decolorising agent is constituted, and is discharged with blister from non-aerosol foaming vessel by the mixed liquor of the 1st preparation and the 2nd preparation during use,
And it is applied to hair, and wherein, (A) composition containing more than 10 mass %: nonionic surfactant, and containing (B) composition:
Silicone.
In the 1st above-mentioned invention, " more than 10 mass % " refer to " be 10 mass % when the 1st preparation and the mixing of the 2nd preparation with
On ".Similarly, in present specification, the numerical value of the content limiting certain composition illustrates as long as no special, all referring to
" content when the 1st preparation and the mixing of the 2nd preparation ".
(composition of the 2nd invention)
In order to solve above-mentioned problem, the composition of the application the 2nd invention is cosmetic hair composition, its as hair dye or
Hair decolorising agent is constituted, and is discharged with blister from non-aerosol foaming vessel by the mixed liquor of the 1st preparation and the 2nd preparation during use,
And it is applied to hair, wherein, contain following (A) composition having more than 10 mass %, and containing following (B1) composition.
(A) nonionic surfactant.
(B1) polyoxyethylene-modified silicone.
(composition of the 3rd invention)
In order to solve above-mentioned problem, the composition of the application the 3rd invention is the cosmetic hair composition of above-mentioned 2nd invention,
Wherein, the content of (A) composition is in the range of 11 mass %～25 mass %.
(composition of the 4th invention)
In order to solve above-mentioned problem, the composition of the application the 4th invention is that the hair of above-mentioned 2nd invention or the 3rd invention is made up
Product compositions, it is that oxide hair dye, acid hair dye, hair decolorising agent or hair take off stain.
(composition of the 5th invention)
In order to solve above-mentioned problem, the composition of the application the 5th invention is the using method of cosmetic hair composition, and it will
Cosmetic hair composition according to any one of 2nd invention～the 4th invention is discharged with blister from non-aerosol foaming vessel, and
It is applied to hair.
(composition of the 6th invention)
In order to solve above-mentioned problem, the composition of the application the 6th invention is hair cosmetic product, and it contains the 2nd invention～the 4th
Cosmetic hair composition according to any one of invention and for the non-gas that this cosmetic hair composition is discharged with blister
Colloidal sol foaming vessel and constitute.
(composition of the 7th invention)
In order to solve above-mentioned problem, the composition of the application the 7th invention is cosmetic hair composition, its as hair dye or
Hair decolorising agent is constituted, and is discharged with blister from non-aerosol foaming vessel by the mixed liquor of the 1st preparation and the 2nd preparation during use,
And it is applied to hair, wherein, containing following (A) compositions more than 10 mass %, and containing following (B) composition and (C) composition.
(A) nonionic surfactant.
(B) silicone.
(C) it is selected from cationization polymer and contains the copolymerization as Component units of diallyl quaternary ammonium and acrylic acid
At least one in thing.
(composition of the 8th invention)
In order to solve above-mentioned problem, the composition of the application the 8th invention is the cosmetic hair composition of above-mentioned 7th invention,
Wherein, the content of (A) composition is in the range of 10～1000 relative to the mass ratio A/C of the content of (C) composition.
(composition of the 9th invention)
In order to solve above-mentioned problem, the composition of the application the 9th invention is that the hair of above-mentioned 7th invention or the 8th invention is made up
Product compositions, wherein, the content of (B) composition is in the range of 0.01～50 relative to the mass ratio B/C of the content of (C) composition.
(composition of the 10th invention)
In order to solve above-mentioned problem, the composition of the application the 10th invention is institute any one of above-mentioned 7th invention～the 9th invention
The cosmetic hair composition stated, wherein, (C) composition is selected from cationised polysaccharide class with containing diallyl quaternary ammonium work
For at least one in the polymer of Component units and copolymer.
(composition of the 11st invention)
In order to solve above-mentioned problem, the composition of the application the 11st invention is any one of above-mentioned 7th invention～the 10th invention
Described cosmetic hair composition, it is that oxide hair dye, acid hair dye, hair decolorising agent or hair take off stain.
(composition of the 12nd invention)
In order to solve above-mentioned problem, the composition of the application the 12nd invention is the using method of cosmetic hair composition, its
Cosmetic hair composition according to any one of 7th invention～the 11st invention is arranged with blister from non-aerosol foaming vessel
Go out, and be applied to hair.
(composition of the 13rd invention)
In order to solve above-mentioned problem, the composition of the application the 13rd invention is hair cosmetic product, and it contains the 7th invention～
Cosmetic hair composition according to any one of 11 inventions and for by this cosmetic hair composition with blister discharge non-
Aerosol foaming vessel and constitute.
According to the 1st invention, following effect can be expected.That is, the hair discharged with blister dosage form from non-aerosol foaming vessel
Send out cosmetics and contain the silicone as (B) composition, contain the nonionic table as (A) composition of more than 10 mass % simultaneously
Face activating agent is used as foaming agent.It is somebody's turn to do (A) even if composition also generates the bubble being particularly difficult to froth breaking in various surfactants, because of
This can resist the froth breaking effect of silicone.Its result is that the hair cosmetic composition of the 1st invention will not cause by answering that silicone causes
Drippage when hair.It addition, (A) is even if composition has in the least feature of various surfactant moderate stimulations.
On the other hand, silicone (1) has the viscosity of suppression hair cosmetic composition and raises, and improves the character of mobility, and (2) have
There is the effect of the arrangement of the surfactant upset in bubble.Therefore, even if assuming the hair cosmetic composition for the 1st invention and then joining
Cations fluidized polymer, the viscosity of the hair cosmetic composition caused with this raises also can be due to above-mentioned (1) of silicone
Character and be suppressed.It addition, cause with cationization polymer " owing to the viscosity of hair cosmetic composition raises, it is impossible to
Generate the bubble of the fine and smooth high-quality of texture ", " alveolar substance also becomes excessively strong and is difficult to be coated on hair " such problem is also due to silicon
The character of above-mentioned (2) of ketone and be suppressed.
Therefore, according to the 1st invention, it is provided that the hair discharged with blister dosage form from non-aerosol foaming vessel is made up
Product, it can give the sense of touch that hair is good, and when being applied to hair, the problem not producing above-mentioned various discharge alveolar substance.
Further, when in cosmetic hair composition, the content of (A) composition is less than 10 mass %, at the hair of application blister dosage form
When sending out cosmetics, it is easy to the problem producing various discharge alveolar substance.
According to the 2nd invention, it is provided that the hair cosmetic composition discharged with blister dosage form from non-aerosol foaming vessel, it can
Give the sense of touch that hair is good, and when being applied to hair, the effect preventing drippage is the most excellent.
In the 2nd invention, the 1st reason obtaining the effect above is that the non-ionic surface containing having more than 10 mass % lives
Property agent.Nonionic surfactant has the speciality generating the bubble being difficult to froth breaking, it addition, it is surfactant, stings simultaneously
Swash few, by coordinating with the amount more than 10 mass %, can fully generate and be difficult to froth breaking, bubble without dripping off.
In view of the remarkable result of the 2nd invention, particularly preferably " more than the nonionic surfactant of 10 mass % ", such as
It is more than more than more than 10.1 mass %, 10.5 mass % or 11 mass %.Containing of particularly preferred nonionic surfactant
Amount is as shown in the 3rd invention.
In the 2nd invention, the 2nd reason obtaining the effect above is containing polyoxyethylene-modified silicone as silicone.Poly-
The ethylene modified silicone of oxygen, compared with other silicone, has a certain degree of water solublity, and shows a part of surface activity work
With.Its result is the most only to give the sense of touch that hair is good, also by the collaborative work with above-mentioned nonionic surfactant
With, can effectively prevent from being applied to drippage during hair.
According to the 3rd invention, by making the content of the nonionic surfactant as (A) composition be 11 mass %～25
In the range of quality %, the effect of above-mentioned 1st invention and then can be significantly improved.If (A) content of composition is more than 25 mass %,
The effect then invented is saturated.
According to the 4th invention, it is provided that as cosmetic hair composition particularly preferred embodiment, oxidation hair-dye
Agent, acid hair dye, hair decolorising agent or hair take off stain.
According to the 5th invention, it is provided that by cosmetic hair composition from non-aerosol foaming vessel with good blister
Discharge and be applied to the effective ways of hair.
According to the 6th invention, it is provided that easy hair cosmetic product, its contain cosmetic hair composition and for
Non-aerosol foaming vessel that this cosmetic hair composition discharges with blister is made to be constituted.
According to the 7th invention, it is provided that the hair cosmetic composition discharged with blister dosage form from non-aerosol foaming vessel, it can
Give hair good sense of touch, and " generation of the bubble of the high-quality that texture is fine and smooth " or " be prone to the discharge bubble being coated on hair
Matter " such effect is the most excellent.The reason of available this effect has described in the 1st invention, and then in detail, can
To estimate as follows.
When being used as in the hair cosmetic composition of foaming agent coordinating containing the nonionic surfactant as (A) composition
(C) during composition, generally can produce the shortcoming discharging alveolar substance, this shortcoming has (a) hair cosmetic composition to be difficult to by non-aerosol to foam
The sieve aperture of the net of container, it is impossible to generate fine bubble, (b) alveolar substance the most excessively becomes by force, to hair affinity poor, formation is difficult to
The bubble etc. being coated on hair.
But, and then when coordinating the silicone as (B) composition, the viscosity of hair cosmetic composition can be suppressed to raise, mobility
Being improved, result eliminates the shortcoming of above-mentioned (a), can generate fine bubble.It addition, (B) composition is lived based on upsetting surface
Property the effect of arrangement of agent and show certain froth breaking effect, thus eliminate the shortcoming of above-mentioned (b), the strongest alveolar substance appropriateness
Die down.And, (B) composition is that sense of touch improves composition originally, and therefore the sense of touch of hair improves further.
On the other hand, (B) composition, based on above-mentioned froth breaking effect, there is also when being applied to the hair cosmetic composition of blister dosage form
It is prone to cause the problem of drippage.But, from being made by (C) composition alveolar substance become strong and contain more than 10 mass % to become as (A)
From the point of view of the nonionic surfactant divided, this problem balance is eliminated well.This is because (A) composition generates difficulty
With the bubble of froth breaking, and stimulating few, therefore (A) compositions more than 10 mass % is on the basis of having few stimulation, also (B) is become
The froth breaking effect divided suppresses in suitable level.
As the 8th invention limits, the content of (A) composition is preferred relative to the mass ratio A/C of the content of (C) composition
In the range of 10～1000.When A/C is less than 10, the negative effect of above-mentioned (C) composition is come to the surface, and has discharge alveolar substance to become strong extremely
Needing the possibility of above degree, if A/C is more than 1000, then the sense of touch of hair is likely deteriorated.
As the 9th invention limits, the content of (B) composition is preferred relative to the mass ratio B/C of the content of (C) composition
In the range of 0.01～50.When B/C is less than 0.01, the negative effect of above-mentioned (C) composition is come to the surface, and has discharge alveolar substance to become strong
To needing the possibility of above degree, if B/C is more than 50, then the balance of (C) composition and (B) composition is likely destroyed, and becomes
It is prone to froth breaking.
As the 10th invention limits, as (C) composition, it is preferably selected from the cationised polysaccharide that water solublity is excellent
Class and containing diallyl quaternary ammonium as at least one in the polymer of Component units and copolymer.
According to the 11st invention, it is provided that as cosmetic hair composition particularly preferred embodiment, oxidation dye
Send out agent, acid hair dye, hair decolorising agent or hair and take off stain.
According to the 12nd invention, it is provided that by cosmetic hair composition from non-aerosol foaming vessel with good blister
Discharge and be applied to the effective ways of hair.
According to the 13rd invention, it is provided that easy hair cosmetic product, its contain cosmetic hair composition and for
Non-aerosol foaming vessel that this cosmetic hair composition discharges with blister is made to be constituted.
Detailed description of the invention
Then, for the mode for implementing the present invention, illustrate in the way of comprising its preferred forms.
In the following description, the 2nd invention～the 6th invention are referred to as " the 2nd invention group ", by the 7th invention～the 13rd
Bright it is referred to as " the 7th invention group ".During referred to simply as " present invention ", refer to the 1st whole inventions～the 13rd invention.
(cosmetic hair composition)
By the mixed liquor of the 1st preparation and the 2nd preparation from non-aerosol when the cosmetic hair composition of the present invention is to use
Foaming vessel is discharged with blister, and is applied to the compositions of hair.
In the cosmetic hair composition of the 1st invention group, as required composition, containing 10 mass % as (A) composition
Above nonionic surfactant, and containing the silicone as (B) composition.Hair cosmetic composition for the 2nd invention group
Compositions, as required composition, contains the nonionic surfactant as (A) composition having more than 10 mass %, and containing making
Polyoxyethylene-modified silicone for (B1) composition.For the cosmetic hair composition of the 7th invention group, as required composition, contain
There is the nonionic surfactant as (A) composition of more than 10 mass %, and containing the silicone as (B) composition, enter one
Step ground, (C) composition is selected from cationization polymer with containing diallyl quaternary ammonium and acrylic acid being total to as Component units
At least one in polymers.
The cosmetic hair composition of the present invention is double preparation formulas, also comprises further to the 1st preparation and/or the 2nd preparation
It is divided into the mode that many group preparations are constituted.
When the cosmetic hair composition of the 1st invention is double preparation formula, (A) composition and (B) composition are to the 1st preparation and the
Fit system in 2 preparations there is no restriction, can at random select.Such as (A) composition can coordinate at the 1st preparation and
In any one of 2nd preparation, it is also possible to dispersion coordinates in both the 1st preparation and the 2nd preparation, so that the 1st preparation and the 2nd system
Use level during agent mixing is more than 10 mass %.It addition, (B) composition can coordinate in any one of the 1st preparation and the 2nd preparation
In, it is also possible to dispersion coordinates in both the 1st preparation and the 2nd preparation.
When the cosmetic hair composition of the 2nd invention group is double preparation formula, (A) composition and (B1) composition are to the 1st preparation
There is no restriction with the fit system in the 2nd preparation, can at random select.Such as (A) composition can coordinate in the 1st system
In any one of agent and the 2nd preparation, it is also possible to dispersion coordinate in both the 1st preparation and the 2nd preparation so that the 1st preparation and
Use level during the 2nd preparation mixing is more than 10 mass %.It addition, (B1) composition can coordinate appointing at the 1st preparation and the 2nd preparation
In one, it is also possible to dispersion coordinates in both the 1st preparation and the 2nd preparation.
When the cosmetic hair composition of the 7th invention group is double preparation formula, (A) composition～(C) composition to the 1st preparation and
Fit system in 2nd preparation there is no restriction, can at random select.Such as (A) composition can coordinate at the 1st preparation
With the 2nd preparation any one in, it is also possible to dispersion coordinates in both the 1st preparation and the 2nd preparation, so that the 1st preparation and the 2nd
Use level during preparation mixing is more than 10 mass %.It addition, (B) composition and (C) composition can coordinate in the 1st preparation and the 2nd system
In any one of agent, it is also possible to dispersion coordinates in both the 1st preparation and the 2nd preparation.
(dosage form etc. of cosmetic hair composition)
When the cosmetic hair composition of the present invention is double preparation formula, as the 1st preparation and the 2nd preparation before foaming
Dosage form, can enumerate that such as solid, shaped, aqueous solution, dispersion be aqueous, emulsion shape, gel, cystose and paste.Solid, shaped
Dosage form can enumerate such as powder and tablet.When for the dosage form of solid, shaped, from when mixing the 1st preparation and 2 preparation
From the point of view of excellent dispersion, preferably powder.Further, such as during the dosage form making the 1st preparation be solid, shaped, the 2nd preparation
For the preparation containing water.In a word, for cosmetic hair composition, as long as can be true when by its 1st preparation and the mixing of the 2nd preparation
Protecting respective mobility, to dosage form, there is no particular limitation.
It addition, for cosmetic hair composition, be used as containing water at least one of the 1st preparation and the 2nd preparation
For the substrate bubbled.The content of water is preferably more than 40 mass %, more than more preferably 50 mass %.
((A) composition)
(A) composition of the present invention in cosmetic hair composition with more than 10 mass % or more than 10 mass %
The nonionic surfactant that amount coordinates.(A) use level of composition is particularly preferably in the range of 11 mass %～25 mass %.
Wherein, in the cosmetic hair composition of the 7th invention group, for the use level of (A) composition, it may be considered that following mass ratio
A/C and set preferred use level.(A) upper limit of the use level of composition does not limit, and can be limited to below 50 mass %.If
More than 50 mass %, then it is unsuitable for non-aerosol foaming vessel.
Nonionic surfactant can enumerate following material, but is not limited to this.Nonionic surfactant is permissible
It is used alone a kind, it is also possible to be two kinds or more.Especially, and if with the nonionic activating agent that HLB is more than 14 and
HLB be 5 less than 14 nonionic activating agent, then the good stability of preparation.HLB(hydrophile-lipophile balance:
Hydrophile-Lipophile Balance) can be calculated by known formula Griffin.
1. polyoxyethylene (hereinafter referred to as POE) cetyl ether, POE stearyl ether, POE behenyl base ether, POE oleyl ether,
POE lauryl ether, POE tridecyl ether, POE octyldodecyl ether, POE hexyl decyl ethers, POE iso stearyl ether, POE last of the ten Heavenly stems
The POE alkyl ether of base pentadecyl ether, POE decyl myristyl ether, POE alkyl (C12～14) ether etc..
The POE alkyl phenyl ether of 2.POE nonylplenyl ether, POE octyl phenyl ether etc..
3. single oleic acid POE sorbitan ester, monostearate POE sorbitan ester, single Palmic acid POE are dehydrated mountain
The POE Sorbitan alcohol ester of pears sugar alcohol, mono laurate POE sorbitan ester, three oleic acid POE sorbitan esters etc.
Fat acid esters.
4. the POE fatty acid monoglyceride of monostearate POE glyceride, single myristic acid POE glyceride etc..
5. four oleic acid POE sorbitol esters, six stearic acid POE sorbitol esters, mono laurate POE sorbitol ester, POE
The POE sorbitan fatty acid ester of Sorbitol Cera Flava etc..
6.POE hardened castor oil, POE Oleum Ricini.
7. single Polyethylene Glycol Oleate, monostearate macrogol ester, mono laurate macrogol ester.
8. lipophilic glyceryl monooleate, lipophilic glyceryl monostearate, self-emulsifying type glyceryl monostearate etc.
Higher fatty acid ester.
9. single oleic acid sorbitan ester, sesquialter oleic acid sorbitan ester, three oleic acid sorbitan esters, list
The dehydration mountain of stearic acid sorbitan ester, single Palmic acid sorbitan ester, sorbitan monolaurate etc.
Pears sugar alcohol fatty acid ester.
The lanolin derivative of 10.POE lanoline, POE lanolin alcohol, POE Sorbitol lanoline etc..
The alkanolamide of 11. lauric acid diethyl amides, fatty acid distribution of coconut oil diglycollic amide etc..
The POE fatty acid amide of 12.POE stearmide etc..
13. sucrose fatty acid ester.
The alkyl amine oxide of 14. dimethyl lauryl amine oxide etc..
The alkyl androstanediol of 15. lauryl glucoside, alkyl (8～16) glucoside etc..
16. lecithin derivative hydrogenated soy phosphatidyl cholines, hydrogenated yolk lecithin etc..
The POEPOP alkyl ether of 17.POE polyoxypropylene (hereinafter referred to as POP) cetyl ether etc..
(surfactant beyond (A) composition)
Further, under the scope not hindering invention effect, in the cosmetic hair composition of the present invention, non-except coordinating
Beyond ionic surfactant, it is also possible to coordinate the surfactant of other kind arbitrary.As these other kinds
Surfactant, can enumerate cationic surfactant, anionic surfactant, amphoteric surfactant.
Cationic surfactant can enumerate such as lauryl trimethyl ammonium chloride, CTAB
(Cetrimonium Chloride), stearyl trimethyl ammonium chloride (Stearyl trimonium Chloride), alkyl three
Ammonio methacrylate, behenyl base trimethyl ammonium chloride (Behentrimonium Chloride), VARISOFT TA100
(Distearyldimonium Chloride), two cocoyl alkyl dimethyl ammonium chlorides, cetyltrimethylammonium bromide, stearyl
Trimethylammonium bromide, ethyl sulfuric acid lanoceric acid ethyldimonium Dimethyl Ammonium, stearyl trimethyl sucramin hydrochlorate, spermaceti
Base trimethyl ammonium saccharin hydrochlorate, behenyl base trimethylammoniumethyl sulfate and quaternary ammonium salt-91 etc., but it is not limited to this.Cationic
Surfactant can be used alone a kind, but from the standpoint of foaming characteristic and sense of touch, preferably be two kinds or more.Cation
The use level of property surfactant is preferably 0.1～10 mass %.
Anionic surfactant can enumerate the alkyl ether sulfate of such as POE sodium laureth sulfate etc., 12
The alkyl sulfate of alkyl sodium sulfate, sodium cetostearylsulphate, sodium hexadecyl sulfate etc., alkenyl ether sulfates, thiazolinyl
Sulfate, alkene sulfonate, alkane sulfonate, saturated or unsaturated fatty acid salt, alkyl or alkenyl ether carboxylate, α-sulfonate grease
The N-acyl amino acid type surfactant of fat hydrochlorate, cocoyl glutamic acid triethanolamine (cocoyl glutamic acid TEA) etc.,
Mono phosphoric acid ester or two ester type surfactants and sulfosuccinate etc..Balance as the anion base of these surfactants
Ion, can enumerate such as sodium ion, potassium ion and triethanolamine.The use level of anionic surfactant is preferably 0.05
～10 mass %.
Amphoteric surfactant can enumerate following material.
1. fatty acid distribution of coconut oil amido propyl dimethylaminoethyl acid glycine betaine, palm oil fatty acid amido propyl dimethylamino
Guanidine-acetic acid glycine betaine, dodecanamide propyl dimethylaminoethyl acid glycine betaine (lauroylamidopropyl betaine), ricinoleic acid acyl
The fatty acid amide propyl dimethylaminoethyl acid glycine betaine of amine propyl-dimethyl oxyneurine etc. and their sodium
Salt, potassium salt or triethanolamine salt.
2. decyl dimethyl oxyneurine, lauryl dimethyl oxyneurine, myristyl dimethyl
Oxyneurine, cetyl dimethyl oxyneurine, stearyl dimethyl oxyneurine, oil base diformazan
Base oxyneurine, behenyl base dimethylaminoethyl acid glycine betaine, cocodimethyl oxyneurine etc.
Alkyl dimethyl oxyneurine and their sodium salt, potassium salt or triethanolamine salt.
3. sodium cocoamphoacetate (N-fatty acid distribution of coconut oil acyl group-N '-carboxymethyl-N '-hydroxyethylethylene diamine), cocos nucifera oil
Acyl both sexes base sodium propionate (N-fatty acid distribution of coconut oil acyl group-N '-carboxyethyl-N '-hydroxyethylethylene diamine), LAA
(N-lauroyl-N '-carboxymethyl-N '-hydroxyethylethylene diamine), Fructus Canarii albi oleoyl both sexes guanidine-acetic acid sodium, cocoa acyl both sexes base second
Acid sodium, Semen Sesami oleoyl both sexes guanidine-acetic acid sodium, Prunus dulcis oleoyl both sexes guanidine-acetic acid sodium, stearoyl both sexes guanidine-acetic acid salt, palmitoleoyl
Both sexes guanidine-acetic acid sodium, Semen arachidis hypogaeae oleoyl both sexes guanidine-acetic acid sodium, heronsbill seed oleoyl both sexes guanidine-acetic acid sodium, Semen Gossypii oleoyl both sexes guanidine-acetic acid
The N-acyl amino ethyl-N-2-Hydroxy-ethylamino carboxylate of sodium etc..
4. cocos nucifera oil acyl both sexes base sodium diacelate, cocos nucifera oil acyl both sexes base dipropionic acid and lauroyl both sexes base sodium diacelate etc.
N-acyl amino ethyl-N-carboxymethoxyl ethylamino carboxylate.
5. hydroxy alkyl (C12-14) hydroxyethyl sarcosine.
The use level of amphoteric surfactant is preferably 0.05～10 mass %.
((B) composition and (B1) composition)
((B) composition)
(B) composition is silicone.(B) use level of composition does not limit, it may be considered that following mass ratio B/C and set
Preferably use level.In general, above-mentioned use level is preferably about 0.01～3 mass % in cosmetic hair composition
In the range of.
As the object lesson of silicone, can enumerate such as dimethyl polysiloxane (INCI name: dimethicone),
There is the dimethyl polysiloxane (INCI name: dimethiconol) of C-terminal base, methyl phenyl silicone, decamethyl ring
Five siloxanes, ten diformazan basic ring six siloxanes, polyether modified silicone, amino modified silicone, glycine betaine modified silicone, alkyl-modified
Silicone, alkoxy-modified silicone, sulfhydryl modified silicone, carboxy-modified silicone, fluorine richness silicone etc..Amino modified silicone preferably arranges
Lift aminoethylaminopropyl methylsiloxane dimethylsiloxane copolymer.Polyether modified silicone can enumerate PEG-10 bis-
Methyl polysiloxane (PEG-10 dimethicone), PEG-11 dimethyl polysiloxane (PEG-11 dimethicone).
((B1) composition)
(B1) composition is polyoxyethylene-modified silicone.It is the one of silicone.(B1) use level of composition does not limit,
Preferably in the range of 0.01～5 mass %, particularly preferably in the range of 0.05～2 mass %.
As polyoxyethylene-modified silicone, except the PEG-10 diformazan as polyoxyethylene methyl polysiloxane polymer
Based polysiloxane (INCI name: the average addition molal quantity of ethylene oxide is the material of 10) or PEG-11 dimethyl polysiloxane with
Outward, other it is also particularly that and enumerates PEG-3 dimethyl polysiloxane, PEG-7 dimethyl polysiloxane, the poly-silicon of PEG-8 dimethyl
Oxygen alkane, PEG-9 dimethyl polysiloxane, PEG-12 dimethyl polysiloxane, PEG-14 dimethyl polysiloxane, PEG-17 diformazan
Based polysiloxane, PEG-6 methyl ether dimethyl polysiloxane, PEG-7 methyl ether dimethyl polysiloxane, PEG-8 methyl ether two
Methyl polysiloxane, PEG-9 methyl ether dimethyl polysiloxane, PEG-10 methyl ether dimethyl polysiloxane, PEG-11 methyl
Ether dimethyl polysiloxane, PEG-32 methyl ether dimethyl polysiloxane, PEG-9 polydimethylsiloxane base ethyl dimethyl are poly-
Siloxanes, lauryl PEG-9 polydimethylsiloxane base ethyl dimethyl polysiloxane etc..
Further, under the scope not hindering invention effect, for the cosmetic hair composition of the 2nd invention group, except making
Polyoxyethylene-modified silicone for (B1) composition, it is also possible to coordinate arbitrary other kinds of silicone.
As these silicones, such as dimethyl polysiloxane (dimethicone), the poly-silicon of aminomethyl phenyl can be enumerated
Oxygen alkane, decamethylcyclopentaandoxane, ten diformazan basic ring six siloxanes, amino modified silicone, glycine betaine modified silicone, alkyl-modified
Silicone, alkoxy-modified silicone, carboxy-modified silicone, fluorine richness silicone.
((C) composition)
(C) composition is selected from cationization polymer and to contain diallyl quaternary ammonium and acrylic acid as Component units
Copolymer at least one.(C) there is no particular limitation for the use level of composition, preferably in the scope of 0.01～2 mass %
In.On the other hand, the content of (A) composition does not limit relative to the mass ratio A/C of the content of (C) composition, preferably 10～
In the range of 1000, in the range of particularly preferred 50～500.(B) content of composition is relative to the mass ratio of the content of (C) composition
B/C does not the most limit, preferably in the range of 0.01～50, in the range of particularly preferred 0.1～20.
Cationization polymer is preferably water miscible cationization polymer.Water miscible cationization polymer is permissible
Enumerate the Poise C-80M as cationised polysaccharide class, cationic starch, JR-125 etc., in addition
Dimethyl diallyl ammonium chloride polymer (polyquaternary ammonium salt-6 (POLYQUATERNIUM-6), such as マ U can also be enumerated
ート100 (MERQUAT 100)；Nalco company), dimethyl diallyl ammonium chloride/acrylamide copolymer (polyquaternary ammonium salt-
7 (POLYQUATERNIUM-7), such as マ U ト 550 (MERQUAT 550)；Nalco company), quaternised polyvinyl base
Ketopyrrolidine etc..
As the object lesson of Poise C-80M, chlorination O-[2-hydroxyl-3-(trimethyl ammonium) propyl group] can be enumerated
Hydroxyethyl cellulose, on hydroxyethyl cellulose addition glycidyltrimetiiylammonium ammonium chloride and the polymer of quaternary ammonium salt that obtains
(Polyquaternium-10 (POLYQUATERNIUM-10), such as レ オ ガ De G (LEOGARD G), レ オ ガ De GP；ラ
イ オ Application company, Port リ マ JR-125, Port リ マ JR-400, Port リ マ JR-30M, Port リ マ LR-400, Port リ マ LR-
30M；Amerchol company), hydroxyethyl cellulose/dimethyl diallyl ammonium chloride copolymer (polyquaternary ammonium salt-4
(POLYQUATERNIUM-4), such as セ Le U ト HC-100 (CELQUAT HC-100), セ Le U ト HC-200, セ Le
コートLC-100、セルコートL-200；Na シ ョ Na Le ス タ チ ア Application De ケ ミ カ Le company) etc..
The object lesson of JR-125 can enumerate chlorination O-[2-hydroxyl-3-(trimethyl ammonium) propyl group] guar gum
Deng.
The object lesson of quaternised polyvinyl base ketopyrrolidine can be enumerated by vinyl pyrrolidone (VP) and methyl-prop
Quaternary ammonium salt (the polyquaternary ammonium salt-11 that the copolymer of olefin(e) acid dimethylamino ethyl ester and dithyl sulfate obtain
(POLYQUATERNIUM-11), such as ガ Off U ト 734 (GAFQUAT 734), ガ Off U ト 755, ガ Off U ト
755N；ア イ エ ス ピ ジ ャ パ Application company) etc..
As containing diallyl quaternary ammonium and acrylic acid as the object lesson of the copolymer of Component units, can enumerate
Dimethyl diallyl ammonium chloride/acrylic copolymer (Merquat 280 (POLYQUATERNIUM-22), such as マ U
ート280 (MERQUAT 280)、マーコート295；Nalco company), acrylic acid/dimethyl diallyl ammonium chloride/propylene
Amide copolymer (polyquaternary ammonium salt-39 (POLYQUATERNIUM-39), such as マ U ト プ ラ ス 3330 (MERQUAT
PLUS3330),3331；Nalco company) etc..
Wherein, if it is considered that cosmetic hair composition viscosity raise, the most particularly preferably selected from cationised polysaccharide class,
With containing diallyl quaternary ammonium as at least one in the polymer of Component units and copolymer.
(polymer beyond (C) composition)
Further, under the scope not hindering invention effect, for the cosmetic hair composition of the 7th invention group, except making
Above-mentioned cationization polymer for (C) composition, it is also possible to coordinate arbitrary other kinds of polymer.
As these polymer, the anionic polymer of such as CVP Carbopol ETD2050 etc., acrylic acid can be enumerated
The eliminating of acrylic acid methyl ester. Methacrylamide hydroxypropyltrimonium chloride copolymer etc. is equivalent to the composition of (C) composition
The department of microbiology of the vegetable polymers of amphiphilic polymers, arabic gum, carrageenan etc., dextran, pulullan polysaccharide etc. gathers
The starch-series polymer of the animality polymer of compound, collagen, casein, gelatin etc., carboxymethyl starch etc., Methyl cellulose
The ethylene base system of the cellulose-based polymer of element, carboxymethyl cellulose, hydroxyethyl cellulose etc., CVP Carbopol ETD2050 etc. is high
Molecule etc..
(kind of cosmetic hair composition)
The cosmetic hair composition of the present invention does not limit, such as can be as oxide hair dye, acid hair dye, hair
Decolorising agent or hair take off stain and constitute.Constitute particularly preferable as oxide hair dye or hair decolorising agent.
(oxide hair dye)
Oxide hair dye comprises containing basic species and the 1st preparation of oxidation dye and the 2nd preparation containing oxidant, and it will
The melanin of hair decomposes, and has hair dyed owing to utilizing the oxidation polymerization of oxidation dye that oxidant produces.Oxidation dye divides
Class is dyestuff intermediate and coupling agent.The direct of basic stain, nitro dye, natural dye, disperse dyes etc. can also be coordinated
Dyestuff replaces oxidation dye.
Dyestuff intermediate can enumerate such as phenylenediamine, aminophenols, diaminotoluene class, diphenyl amine, diamino
Base phenyl amine, N-phenyl phenylenediamine, diamino-pyridine class and their salt.Salt can enumerate hydrochlorate, sulfate
With acetate etc..
Coupling agent is the compound of color development by combination dye intermediate, can be contained in as required in the 1st preparation.Coupling
Agent can enumerate such as resorcinol, pyro acid, catechol, m-aminophenol, m-diaminobenzene., 2,4-diaminophenol, 1,2,
4-benzene triol, Toluene-3,4-dithiol, 4-diamidogen, Toluene-2,4-diisocyanate, 4-diamidogen, hydroquinone, α-naphthalene alcohol, DAP, 1,5-dihydroxy naphthlene,
5-amino orthoresol, p-methylaminophenol, 2,4-diamino phenoxy ethanol, gallic acid, tannic acid, progallin A,
Gallicin, propylgallate, Galla Chinensis, 5-(2-Hydroxy-ethylamino)-2-methylphenol and their salt.
The content of the dyestuff intermediate in oxide hair dye is preferably 0.01～10 mass %, more preferably 0.1～5 mass %.
When the content of dyestuff intermediate is less than 0.01 mass %, it is possible to sufficient dyeability can not be obtained.The content of dyestuff intermediate is i.e.
Making more than 10 mass %, dyeability does not has bigger raising yet, thus the economy having hair dyed is likely to decrease.
1st preparation can suitably contain and is selected from " doctor part outer article raw material lattice " of Japan (in June, 2006 is sent out
OK, Yao Shi newspaper office) described in oxidation dye and at least one of direct dyes, be used as beyond above-mentioned oxidation dye
Dyestuff.
The effect of the oxidant that basic species is contained in the 2nd preparation by promotion, makes hair swell simultaneously, increase dyestuff for
The impregnability of hair, thus can make dyeability improve.Basic species can enumerate such as ammonia, alkanolamine, organic amine, inorganic
Alkali, basic amino acid and sulfate.Organic amine can enumerate such as AMPD and guanidine.Inorganic base
Such as sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, ammonium carbonate, sodium bicarbonate and ammonium hydrogen carbonate can be enumerated.Alkaline ammonia
Base acid can enumerate such as arginine and lysine and alkaline amino acid salt.The salt of basic amino acid can enumerate such as ammonium
Salt.Sulfate can enumerate ammonium sulfate.
The content of basic species, preferably in being mixed with the oxide hair dye of the 1st preparation and the 2nd preparation, is that to make pH be 7～12
The amount of scope.If pH is less than 7, then when containing the hydrogen peroxide as oxidant in the 2nd preparation, it is possible to can not fully promote
Enter the effect of hydrogen peroxide.If pH when using is more than 12, then when being coated on hair by oxide hair dye, it is possible to easily
There is the shortcoming that hair sustains damage etc..
2nd preparation at least contains oxidant.Oxidant makes oxidation dye carry out oxidation polymerization and color development.Oxidant can arrange
Citing is such as hydrogen peroxide, urea peroxide, melamine peroxide, SODIUM PERCARBONATE, potassium percarbonate, Dexol, potassium perborate, mistake
Sodium oxide, potassium peroxide, Magnesium dioxide, Barium dioxide, calper calcium peroxide, strontium peroxide, the hydrogen peroxide adduct of sulfate, phosphorus
The hydrogen peroxide adduct of hydrochlorate and the hydrogen peroxide adduct of pyrophosphate.
In 2nd preparation, the content of oxidant is preferably 0.1～10.0 mass %, more preferably 0.5～8.0 mass %.Oxidant
Content less than 0.1 mass % time, it is possible to be difficult to make oxidation dye fully carry out oxidation polymerization.The content of oxidant exceedes
During 10.0 mass %, it is possible to easily damage hair.
(acid hair dye)
The most single preparation formula of acid hair dye (), fluidity is the acidity of pH2.5～about 4.0, and it is for band
There is the hair of cationic, acid stain can be made to carry out the material of ions binding.Acid stain can enumerate such as nitro dye,
Azo dye, nitroso-dyes, triphenhlmethane dye, ton dyestuff, quinoline dye, anthraquinone dye, indigoid dye etc..
As acid stain, more specifically, can enumerate Amaranth, red No. 3, red No. 102, red No. 104, red
Color 105, redness 106, redness 227, redness 230, yellow 4, Sunset Yellow FCF, yellow 202, yellow 203, orange
Color 205, orange No. 207, orange No. 402, green No. 3, green No. 204, green No. 401, purple 401, blue No. 1, blue
Color 2, blueness 202, brown 201, black 401 etc..
The content of the acid stain in acid hair dye is 0.005～5 mass %, more preferably 0.01～3 mass %.
(hair decolorising agent)
Hair decolorising agent comprises the 1st preparation containing basic species and the 2nd preparation containing oxidant, and it is by the black of hair
Element decomposes, and is decoloured by hair.Hair decolorising agent is not except containing oxidation dye, and other substantially has same with oxide hair dye
The composition of sample.
(hair takes off stain)
Hair take off more than stain usually double preparations many preparations formula (), its main purpose is by the de-of hair
Dye (decomposition of dye dyestuff on hair), compared with hair decolorising agent, difference is in the 1st preparation to coordinate basic species
Meanwhile, and then coordinate and be used as decoloring assistant as a kind of persulfate of basic species.1st preparation is powder or granule
Shape, lamellar etc., the 2nd preparation is aqueous.
Persulfate preferably enumerates the alkali metal salt of persulfuric acid, particularly preferred potassium peroxydisulfate or sodium peroxydisulfate.Persulfate
Use level do not limit, preferably in the range of 2.0～25 mass %, more preferably in the range of 3.5～18 mass %.
(other composition in cosmetic hair composition)
In the 1st preparation or the 2nd preparation of cosmetic hair composition, as required in addition to mentioned component, also may be used
To properly select and to contain such as oil components, water-soluble high-molecular compound, chelating agen, inorganic salt, dispersant etc..
As oil components, except above-mentioned silicone, can enumerate such as higher alcohol, oils and fats, wax, hydrocarbon, higher fatty acids,
Alkyl glycerylether, ester, polyhydric alcohol.
As higher alcohol, can enumerate such as spermol (hexadecanol), 2-hexyldecanol, stearyl alcohol, isooctadecanol, 16
Octadecanol, oleyl alcohol, arachidic alcohol, behenyl alcohol, 2-octyl dodecanol, lauryl alcohol, myristyl alcohol, decyl tetradecyl alcohol and lanolin alcohol.
Higher alcohol has following effects: cosmetic hair composition is being formed the blister dosage form of non-aerosol type and is being coated on hair
When sending out upper, the effect preventing drippage of preparation can be promoted.
Oils and fats can enumerate such as lanoline, olive oil, Chinese toon oil, shea butter, almond oil, safflower oil, Oleum helianthi, big
Oleum Glycines, Oleum Gossypii semen, Oleum sesami, Semen Maydis oil, Oleum Brassicae campestris, Testa oryzae oil, rice germ oil, grapeseed oil, American Avocado Tree oil, macadimia nut
Oil, Oleum Ricini, cocos nucifera oil and Radix Oenotherae erythrosepalae oil.
Wax can enumerate such as Cera Flava, candelilla wax, Brazil wax, Jojoba oil and lanoline.
Hydrocarbon can be enumerated such as paraffin, olefin oligomer, polyisobutylene, Parleam, mineral oil, squalane, gather
Butylene, polyethylene, microwax and vaseline.
Higher fatty acids can enumerate such as lauric acid, myristic acid, Palmic acid, stearic acid, behenic acid, isostearic acid,
12-hydroxy stearic acid, oleic acid and lanoceric acid.
Alkyl glycerylether can enumerate such as batilol .alpha.-hexadecylglyceryl ether, selachyl alcohol and iso stearyl glycerin ether.
Ester can enumerate such as diisopropyl adipate, isopropyl myristate, Octanoic acid, hexadecyl ester, the different nonyl of different n-nonanoic acid
Ester, myristic acid octyldodecyl, isopropyl palmitate, stearyl stearate, myristyl myristate, Semen Myristicae
Acid isotridecyl ester, Palmic acid 2-Octyl Nitrite, castor oil acid octyldodecyl, carbon number are the fat of 10～30
Acid cholesterol ester/lanosterol ester, cetyl lactate, acetoxylation lanoline, two-2 ethyl hexanoic acid glycol ester, tetramethylolmethane
Fatty acid ester, dipentaerythritol fatty acid ester, capric acid cetyl, tricaprin, the different stearyl ester of malic acid two, succinic acid two
Monooctyl ester and 2 ethyl hexanoic acid cetyl.
Polyhydric alcohol can enumerate such as dihydroxylic alcohols and glycerol.Dihydroxylic alcohols can enumerate such as ethylene glycol, diethylene glycol, three second two
Alcohol, Polyethylene Glycol, propylene glycol, dipropylene glycol, isoprene and 1,3 butylene glycol.Glycerol can enumerate such as glycerol, two glycerol
And polyglycereol.
Water-soluble high-molecular compound can enumerate the most natural system macromolecule, semi-synthetic system macromolecule, synthesis be high score
Son.
Natural is that high molecular object lesson can enumerate arabic gum, carrageenan, galactan, guar gum, Semen Fructus Chaenomelis
Glue, locust bean gum, Tragacanth, pectin, mannan, starch, xanthan gum, glucosan, curdlan, succinoglycan, gelatin,
Collagen protein, casein, albumin, tamarind gum etc..
As semi-synthetic be high molecular object lesson, methylcellulose, ethyl cellulose, hydroxy ethyl fiber can be enumerated
The cellulose polymer of element, carboxymethyl cellulose, hydroxypropyl methyl cellulose etc.；Carboxymethyl starch, methyl starch, solubility
The starch-series macromolecule of starch etc.；The alginic acid system macromolecule of alginate, propylene glycol alginate etc.；Guar gum system macromolecule
Deng.
It is high molecular object lesson as synthesis, CVP Carbopol ETD2050, polyacrylamide, propylene can be enumerated
Acids methacrylic acid alkyl ester copolymer, polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl methyl ether, sodium polyacrylate
Deng ethylene base system macromolecule；Polyethylene glycol oxide；Ethyleneoxide propylenenoxide block copolymer；Vinyl pyrrolidone diformazan
The cation compound of aminoethyl methacrylate copolymer；The homopolymer of dimethyl diallyl ammonium chloride, dimethyl diene
The QAS polymer of propyl ammonium chloride acrylamide copolymer, dimethyl diallyl ammonium chloride acrylic copolymer etc. is spread out
Biology, alkyl acrylate copolymer emulsion, alkyl acrylate styrene copolymer latexes, alkyl acrylate methyl-prop
Olefin(e) acid Arrcostab polyoxyethylene (20) stearyl ether copolymer emulsion and the polyxyethylated list in alkyl acrylate itaconic acid
The acrylic acid series aqueous dispersed polymer etc. of ester copolymer emulsion etc..
Chelating agen can enumerate such as ethylenediaminetetraacetic acid (EDTA, edetic acid), hydroxyethylethylene diamine tri-acetic acid (HEDTA)
With its salt, diethylenetriamine pentaacetic acid and its esters and hydroxyethane diphosphonic acid (HEDP, etidronic acid) and its esters.Inorganic
Salt can enumerate such as sodium chloride, sodium sulfate.Dispersant can enumerate such as magnesium stearate.
At the cosmetic hair composition of single preparation formula or the 1st preparation of the cosmetic hair composition of double preparation formula
Or the 2nd in preparation, other can also be containing being selected from saccharide, preservative, stabilizer, pH adjusting agent, plant extract, crude drug
" doctor's part outer article raw material lattice " (in June, 2006 of extract, vitamins, spice and UV absorbent and Japan
Distribution, Yao Shi newspaper office) described in material at least one.
(using method of cosmetic hair composition)
The using method of the cosmetic hair composition of the present invention, is from non-aerosol by above-mentioned cosmetic hair composition
Foaming vessel is discharged with blister, and the method being applied to hair.
As non-aerosol foaming vessel, as long as cosmetic hair composition, have and can carry out non-aerosol type
Foaming and the container of function of discharge, do not limit.Following non-aerosol foaming vessel is preferably used bubble.
(hair cosmetic product)
Form the blister dosage form of non-aerosol type when the hair cosmetic product of the present invention contains use and be applied to hair
Above-mentioned cosmetic hair composition and for non-aerosol foaming vessel that this cosmetic hair composition is discharged with blister
And constitute.
As the representative example of non-aerosol foaming vessel, pump foam maker can be enumerated or crushed foam occurs
Device.Pump foam maker is by the head of pump carries out extrusion operation, and makes collecting liquid (the 1st system of such as hair cosmetic composition
Agent/the 2nd preparation mixed liquor) with blister discharge container, wherein, will collecting liquid be made mix with air, with blister discharge bubble arrange
Go out device and be assemblied in the peristome of container body.Pump foam maker, disclosed in Japanese Unexamined Patent Publication 2007-275777 publication etc., is
Known.Crushed foam generator refers to following equipment, i.e. by using finger to be entered by the container body of soft synthetic resin
Row extruding (repeats the squeeze operation for container and compression solves division operation), and collecting liquid ibid and air are imported foam
Generator discharge head gas-liquid mixed room in and mix, utilize bubble displacer by formed bubble from nozzle discharge.Extruding bubble
Foam generator is recorded in Japanese Unexamined Patent Publication 2008-291024 publication or magazine " Off レ グ ラ Application ス ジ ャ Na Le
(Fragrance Journal) " in June, 2009 number publication document " ヘ ア カ ラ skill new い is to (-blister ヘ
ア カ ラ skill sends out-) " etc. in, be known.
The bubble displacer of non-aerosol foaming vessel has 1 or multiple are for forming the perforated membrane of bubble.The material of perforated membrane
Matter can enumerate nylon, polyester, polyethylene, polypropylene etc..The sieve mesh of perforated membrane the most for example, 50～300 sieve mesh.It addition, gas
Mixing ratio (gas-liquid mixed ratio) preferably gas/liquid=5/1～the scope of 20/1 of body and liquid.
Embodiment
Following description the 2nd invention group and the embodiment of the 7th invention group and comparative example.The technical scope of the present invention is not limited to this
A little embodiments and comparative example.
The embodiment of the 2nd invention group
(compositions of double preparation formula hair dyes)
Prepare the hair dyeing of composition shown in the example 1 of hair dye the 1st preparation of composition shown in table 1 below～example 7 and table 2
The example 1 of agent the 2nd preparation～example 9, by these the 1st preparations and the 2nd preparation selectivity group as shown in " combination " hurdle of table 3
Close, constitute the double preparation formula hair dyes related in embodiment 1～embodiment 9, comparative example 1～comparative example 5.
In Tables 1 and 2, represent that the numerical value of the component content of the 1st preparation or the 2nd preparation is not by the 1st preparation and the 2nd system
Content statement during agent mixing, but the statement of the content in units of quality % in the 1st preparation or the 2nd preparation.For quite
In (A) composition or the composition of (B1) composition of the present invention, the marge in the left side of table is expressed as " A " or " B1 ".Left side at table
Marge be expressed as the composition of " B1 than " and represent the composition of the comparison relative to (B1) composition.As " the B1 shown in table 2
Than " the aminoethylaminopropyl methylsiloxane dimethylsiloxane copolymer of composition uses east レ ダ ウ conning
The FZ-4671 as aminoethylaminopropyl methylsiloxane dimethylsiloxane copolymer (20%) of company.
In table 3, in " the 1st preparation " in " combination " hurdle and the item of " the 2nd preparation ", the numeral of display, is institute in table 1 or table 2
The 1st preparation shown or the example numbering of the 2nd preparation.
(evaluations of double preparation formula hair dyes)
The various embodiments described above, the 1st preparation of each comparative example and the 2nd preparation are accommodated in the ratio that mass ratio is 1: 1
State in non-aerosol foaming vessel (pump foam maker), form mixed liquor, by the head of this pump is carried out extrusion operation, will
Above-mentioned mixed liquor is discharged with infusion type.Pump foam maker uses (strain) lucky wild industrial made trade name W-5721, WP foam
Generator pump L bleed type (gas liquid mixing compares: 13/1, output: 0.9g(1 extruding), perforated membrane: the poly-second of 90 sieve meshes
Alkene メ ッ シ ュ リ Application グ 2).
(evaluation of sense of touch)
After the hair dye of the above-mentioned blister each embodiment, each comparative example related to is discharged, it is utilized respectively conventional method immediately
Coat with judging with on the long topknot of the 30cm of hair.Evaluation hair after washing is coated with after 30 minutes, has one's hair wash 2 times,
Then, after processing, by 10 experimenters, the sense of touch of evaluation hair is evaluated.
Evaluate and carry out according to 8 stages based on following metewand, in the evaluation result of 10 experimenters, use
Many evaluation results.Evaluation result is shown in table 3.
◎: hair does not harden, unusual light, smoothness is good
◎～zero: hair does not harden, smooth, smoothness is good
Zero: hair hardens hardly, smooth
Zero～△: hardening of hair is few, smooth
△: somewhat feeling that hair hardens, hair surface is the most smooth
△～×: feeling that hair hardens, hair surface is the most smooth
×: hair hardens, and hair surface is rough
××: hair is stone, hair surface is rough.
(evaluation of drippage)
After the hair dye of the above-mentioned blister each embodiment, each comparative example related to is discharged, it is immediately plated on wig, then
Carry out under conditions of 40 DEG C 30 minutes through time observe, the drippage complexity of blister hair dye is observed, is evaluated.Comment
Valency was carried out according to 8 stages based on following metewand, and evaluation result is shown in table 3.
◎: entirely without liquefaction, the drippage of bubble
◎～zero: bubble, almost without liquefaction, does not drip
Zero: bubble slightly liquefies, but not drippage
Zero～within △: 30 minutes, the raw liquefaction of steep raising, drippage
Within △: 15 minutes, the raw liquefaction of steep raising, drippage
△～×: within 10 minutes, the raw liquefaction of steep raising, drippage
×: within 5 minutes, the raw liquefaction of steep raising, drippage
××: within 5 minutes, steep raising life is liquefied, is dripped in large quantities.
[table 1]
[table 2]
[table 3]
The embodiment of the 7th invention group
(compositions of double preparation formula hair dyes)
Prepare the hair dyeing of composition shown in the example 1 of hair dye the 1st preparation of composition shown in table 4 below～example 6 and table 5
The example 1 of agent the 2nd preparation～example 13, by these the 1st preparation and the 2nd preparation selectivity as shown in " combination " hurdle of table 6
Combination, constitutes the double preparation formula hair dyes related in embodiment 1～embodiment 14, comparative example 1～comparative example 4.
In table 4 and table 5, represent that the numerical value of the component content of the 1st preparation or the 2nd preparation is not by the 1st preparation and the 2nd system
Content statement during agent mixing, but the statement of the content in units of quality % in the 1st preparation or the 2nd preparation.For quite
In (A) composition, (B) composition or the composition of (C) composition of the present invention, the marge in the left side of table be expressed as " A ", " B " or
“C”.Aminoethylaminopropyl methylsiloxane dimethylsiloxane copolymer as " B " composition shown in table 5 uses
Eastern レ ダ ウ conning company as aminoethylaminopropyl methylsiloxane Dimethicone Copolyol
The FZ-4671 of thing (20%).
In table 6, in " the 1st preparation " in " combination " hurdle and the item of " the 2nd preparation ", the numeral of display, is institute in table 4 or table 5
The 1st preparation shown or the example numbering of the 2nd preparation.Table 6 illustrates each embodiment, the mass ratio A/C of comparative example and matter in the lump
Amount compares B/C.
(evaluations of double preparation formula hair dyes)
The various embodiments described above, the 1st preparation of each comparative example and the 2nd preparation are accommodated in the ratio that mass ratio is 1: 1
State in the pump foam maker that (strain) lucky wild industry is made, form mixed liquor, by the head of this pump is carried out extrusion operation, with
Above-mentioned mixed liquor discharged by infusion type.
(evaluation of alveolar substance)
For each embodiment discharged from non-aerosol foaming vessel, the hair dye of the blister of each comparative example, utilize texture
Fine and smooth () the observation evaluation of volume big (か さ height さ) evaluates " alveolar substance ".
Evaluating and carry out according to 8 stages based on following metewand, evaluation result is shown in table 6.
The texture of ◎: bubble is fine and smooth, in good order, and the bubble that volume is the biggest
The texture of ◎～zero: bubble is neat, the bubble that volume is the biggest
Zero: the texture of bubble is neat, bulky bubble
Zero～△: the texture of bubble is neat, the bubble of a bit deficient on volume
△: slightly bubble (), the bubble that volume is weak
△～×: foaming is many, the bubble that volume is weak
×: foaming is many, washiness and the bubble that spreads
××: bubble many and be engaged big bubble, the bubble that moisture much spreads
Wherein, bubble (bubble か body) does not refer to the state that the texture uniform, so-called of bubble is neat, and refers to containing big
Bubble and from pump foam maker container discharge situation.
(evaluation of sense of touch)
After the hair dye of the above-mentioned blister each embodiment, each comparative example related to is discharged, it is utilized respectively conventional method immediately
Coat with judging with on the long topknot of the 30cm of hair.Evaluation hair after washing is coated with after 30 minutes, has one's hair wash 2 times,
Then, after processing, by 10 experimenters, the sense of touch of evaluation hair is evaluated.
Evaluate and carry out according to 8 stages based on following metewand, in the evaluation result of 10 experimenters, use
Many evaluation results.Evaluation result is shown in table 6.
◎: hair does not harden, unusual light, smoothness is good
◎～zero: hair does not harden, smooth, smoothness is good
Zero: hair hardens hardly, smooth
Zero～△: hardening of hair is few, smooth
△: somewhat feeling that hair hardens, hair surface is the most smooth
△～×: feeling that hair hardens, hair surface is the most smooth
×: hair hardens, and hair surface is rough
××: hair is stone, hair surface is rough.
[table 4]
[table 5]
[table 6]
Industry utilizability
According to the present invention it is possible to provide the hair cosmetic composition discharged from non-aerosol foaming vessel with blister dosage form, it can
Give the sense of touch that hair is good, and without discharging the shortcoming of alveolar substance, do not drip when being applied to hair.
Claims (7)
1. cosmetic hair composition, it is constituted as hair dye or hair decolorising agent, by the 1st preparation and the 2nd system during use
The mixed liquor of agent is discharged with blister from non-aerosol foaming vessel, and is applied to hair, wherein, more than 10 mass %
Following (A) composition, and containing following (B) composition and (C) composition,
(A) nonionic surfactant,
(B) silicone,
(C) it is selected from cationization polymer and contains diallyl quaternary ammonium and acrylic acid as in the copolymer of Component units
At least one.
2. the cosmetic hair composition described in claim 1, it is characterised in that the content of (A) composition becomes relative to above-mentioned (C)
The mass ratio A/C of the content divided is in the range of 10～1000.
3. the cosmetic hair composition described in claim 1, it is characterised in that the content of (B) composition becomes relative to above-mentioned (C)
The mass ratio B/C of the content divided is in the range of 0.01～50.
4. the cosmetic hair composition described in claim 1, it is characterised in that above-mentioned (C) composition is many selected from cationization
Saccharide and containing diallyl quaternary ammonium as at least one in the polymer of Component units and copolymer.
5. the cosmetic hair composition described in claim 1, it is characterised in that above-mentioned cosmetic hair composition is oxidation dye
Send out agent, acid hair dye, hair decolorising agent or hair and take off stain.
6. the using method of cosmetic hair composition, it is characterised in that by the hair according to any one of Claims 1 to 5
Cosmetic composition is discharged with blister from non-aerosol foaming vessel, and is applied to hair.
7. hair cosmetic product, it contains the cosmetic hair composition according to any one of Claims 1 to 5 and for inciting somebody to action
Non-aerosol foaming vessel that this cosmetic hair composition is discharged with blister and constituted.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010245196A JP5687029B2 (en) | 2010-11-01 | 2010-11-01 | Hair cosmetic composition, method of use thereof and hair cosmetic product |
| JP2010245607A JP5687030B2 (en) | 2010-11-01 | 2010-11-01 | Hair cosmetic composition, method of use thereof and hair cosmetic product |
| JP2010-245196 | 2010-11-01 | ||
| JP2010-245607 | 2010-11-01 | ||
| PCT/JP2011/074460 WO2012060239A1 (en) | 2010-11-01 | 2011-10-24 | Hair cosmetic composition, method for using same, and hair cosmetic product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103298450A CN103298450A (en) | 2013-09-11 |
| CN103298450B true CN103298450B (en) | 2016-08-10 |
Family
ID=46024356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201180052533.9A Active CN103298450B (en) | 2010-11-01 | 2011-10-24 | Cosmetic hair composition, its using method and hair cosmetic product |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN103298450B (en) |
| TW (1) | TWI587873B (en) |
| WO (1) | WO2012060239A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015016280A1 (en) | 2013-07-31 | 2015-02-05 | 花王株式会社 | Cosmetic product for hair decoloring or hair coloring |
| WO2015133463A1 (en) * | 2014-03-04 | 2015-09-11 | ホーユー株式会社 | Hair cosmetic composition |
| CN109394551B (en) * | 2015-12-28 | 2022-08-02 | 花王株式会社 | Aerosol cosmetic product |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006124279A (en) * | 2004-10-26 | 2006-05-18 | Kao Corp | Two-agent type hair cosmetic |
| JP4950749B2 (en) * | 2006-04-25 | 2012-06-13 | 花王株式会社 | Hair cosmetics |
| JP5066341B2 (en) * | 2006-04-25 | 2012-11-07 | 花王株式会社 | Hair cosmetics |
| US8002848B2 (en) * | 2007-10-24 | 2011-08-23 | Kao Corporation | Two-part hair dye |
-
2011
- 2011-10-24 CN CN201180052533.9A patent/CN103298450B/en active Active
- 2011-10-24 WO PCT/JP2011/074460 patent/WO2012060239A1/en active Application Filing
- 2011-10-31 TW TW100139590A patent/TWI587873B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN103298450A (en) | 2013-09-11 |
| WO2012060239A1 (en) | 2012-05-10 |
| TWI587873B (en) | 2017-06-21 |
| TW201306870A (en) | 2013-02-16 |
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