JP4950749B2 - Hair cosmetics - Google Patents

Hair cosmetics Download PDF

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JP4950749B2
JP4950749B2 JP2007115215A JP2007115215A JP4950749B2 JP 4950749 B2 JP4950749 B2 JP 4950749B2 JP 2007115215 A JP2007115215 A JP 2007115215A JP 2007115215 A JP2007115215 A JP 2007115215A JP 4950749 B2 JP4950749 B2 JP 4950749B2
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hair
content
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JP2007314524A (en
JP2007314524A5 (en
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真彦 小川
貴史 松尾
宏之 藤沼
剛志 飯崎
宏美 齊宮
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花王株式会社
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Description

  The present invention relates to a two-component hair cosmetic that can be easily applied without unevenness on the hair by discharging a mixture of a two-component hair bleaching agent or a two-component hair dye in the form of foam.

  Conventionally, liquid or cream-like hair cosmetics such as hair bleaching agents and hair dyes have been widely used, but it is difficult to apply them uniformly to hair. In particular, skills such as blocking and a matching mirror are required for applying the root portion and the back of the hair, and a lot of time is required.

  Thus, it has been proposed to simplify the hair dyeing operation by discharging the agent in the form of a foam. For example, a two-agent aerosol type or a one-agent non-aerosol type is known. However, the two-component aerosol type is prone to decolorization and dyeing unevenness, metal pressure-resistant containers are oxidized and corroded by hydrogen peroxide, and the internal pressure of the pressure-resistant container rises excessively due to the decomposition of hydrogen peroxide. In addition, the one-agent non-aerosol type has a problem that it is difficult to leave for a long time after application or to repeat the treatment because the effect obtained by one treatment is poor. .

  On the other hand, there has been proposed one in which a two-component hair bleaching agent or a two-component hair dye is discharged in a foam form from a non-aerosol type former container (see Patent Document 1). This is because the liquid mixture of the first agent and the second agent is discharged from the former container in the form of foam, so that it can be applied to the hair without any unevenness and color unevenness does not occur in the finish. It is useful for eliminating the level difference.

JP 2004-339216 A

  Patent Document 1 discloses a method for containing a large amount of a non-volatile hydrophilic solvent in a mixed solution in order to prevent scalp irritation. However, if a large amount of a non-volatile hydrophilic solvent is used, the hair dyeing power and decoloring power are described. It has been found that there is a problem of lowering.

  An object of the present invention is to solve this problem and to provide a foamy hair cosmetic that does not cause scalp irritation even when the content of a nonvolatile hydrophilic solvent is suppressed, and has high hair dyeing power and decoloring power. .

  The present inventors have made the above object by setting the ratio of the surfactant and the non-volatile hydrophilic solvent in the mixed solution of the first agent and the second agent in the two-component non-aerosol type hair cosmetic composition within a certain range. I found that I can achieve.

That is, the present invention is a two-agent type comprising a first agent containing an alkali agent, a second agent containing hydrogen peroxide, and a former container for discharging a mixture of the first agent and the second agent in the form of foam. A hair cosmetic comprising the following components (A) and (B) in the mixture:
(A) 1-15% by weight of surfactant
(B) Non-volatile hydrophilic solvent 0.1 to 5% by weight
And a two-component hair cosmetic composition in which the weight ratio of component (A) to component (B) (content of component (A) / content of component (B)) is 1 to 20 is there.

  According to the present invention, a two-component hair bleaching agent or a two-component hair dye mixture is discharged in the form of foam, and can be applied to the hair easily and without unevenness. In addition, it has sufficient decoloring power or staining power without causing irritation to the scalp and scattering of the agent. Therefore, the hair cosmetic composition of the present invention can easily and comfortably achieve a uniform decolorization finish or hair dye finish with little unevenness.

  Moreover, the liquid mixture discharged in the form of foam by gas-liquid mixing using the former container easily reaches the base of the hair, but there is no accumulation of liquid and the like, and it spreads to the whole hair moderately thinly. Therefore, the root portion does not become extremely bright as in the case of conventional liquid or cream, and decoloring unevenness or staining unevenness due to uneven adhesion of the mixed liquid does not occur. Therefore, by applying the hair cosmetic composition of the present invention to the hair in the vicinity of the newly formed part such as the dividing line and the face line, the color difference between the newly formed part and the already dyed part can be eliminated, and a natural finish can be obtained. . Moreover, since a liquid mixture can be apply | coated to hair moderately thinly, the damage with respect to hair can be reduced.

[Alkaline agent]
As the alkaline agent contained in the first agent, for example, ammonia, alkanolamines such as monoethanolamine, sodium hydroxide, potassium hydroxide and the like can be used. Further, as a buffering agent, ammonium salts such as ammonium hydrogen carbonate and ammonium chloride, carbonates such as potassium carbonate and sodium hydrogen carbonate, and the like can be added as appropriate.

  The pH of the mixed solution of the first agent and the second agent in the two-component hair cosmetic of the present invention is preferably 8 to 11, particularly 9 to 11, and the amount of the alkaline agent used is the above-mentioned pH of the mixed solution. Is adjusted as appropriate.

〔hydrogen peroxide〕
The content of hydrogen peroxide in the second agent is preferably 1 to 9% by weight, particularly preferably 3 to 6% by weight. The content of hydrogen peroxide in the mixed solution of the first agent and the second agent is 1 to 6% by weight, in particular 2-5% by weight, is preferred. The pH of the second agent is preferably 2 to 6, particularly 2.5 to 4 in order to suppress decomposition of hydrogen peroxide.

[(A): Surfactant]
In order to make the foam easily formed by mixing the air and the hair cosmetic by the foam discharge means of the former container and to stabilize the foam, either the first agent or the second agent, or Both contain a surfactant. As the surfactant, (A1) anionic surfactant, (A2) amphoteric surfactant and (A3) in order to realize good foaming that is easy to apply to hair even when the liquid temperature is low or close to normal temperature Nonionic surfactants are preferred.

  Examples of the anionic surfactant (A1) include alkyl sulfates and polyoxyalkylene alkyl sulfates. The alkyl group preferably has 10 to 24 carbon atoms, particularly preferably 12 to 18 carbon atoms. Those in which the alkyl group is linear are preferred. Further, polyoxyalkylene alkyl sulfates, particularly polyoxyethylene alkyl sulfates are more preferable, and those having an average addition mole number of oxyethylene groups of 1 to 10, particularly 2 to 5 are preferable. Two or more types of (A1) can be used in combination, and the content of the first agent and the second agent in the mixed solution is preferably 0.01 to 14.8% by weight, more preferably 0.05 to 6% by weight, particularly 0.1 to 3%. % By weight is preferred.

  Examples of the amphoteric surfactant (A2) include carbobetaines, amidebetaines, sulfobetaines, hydroxysulfobetaines, amidesulfobetaines, phosphobetas having an alkyl group, alkenyl group or acyl group having 8 to 24 carbon atoms. Examples include betaine-based and imidazolinium-based surfactants, among which carbobetaine-based surfactants and sulfobetaine-based surfactants are preferable. Preferred amphoteric surfactants include lauric acid amidopropyl betaine, coconut oil fatty acid amidopropyl betaine, lauryldimethylaminoacetic acid betaine, lauryl hydroxysulfobetaine and the like. (A2) can also use 2 or more types together, 0.001-5 weight% is preferable in the liquid mixture of the 1st agent and the 2nd agent, Furthermore, 0.005-1 weight%, Especially 0.01-0.4. % By weight is preferred.

  Examples of the nonionic surfactant (A3) include alkyl polyglucoside, polyoxyalkylene alkyl ether, and alkyl glyceryl ether. As the alkyl polyglucoside, those having 8 to 18, more preferably 8 to 14, particularly 9 to 11 carbon atoms of the alkyl group are preferable, and those in which the alkyl group is linear are preferable. The average degree of polymerization of glucoside is 1 to 5, particularly preferably 1 to 2. As the polyoxyalkylene alkyl ether, those in which the alkyl group has 10 to 22 carbon atoms, particularly 12 to 18 carbon atoms, are preferred, and those in which the alkyl group is linear are preferred. Further, polyoxyethylene alkyl ether is more preferable, and those having an average addition mole number of oxyethylene group of 1 to 40, particularly 4 to 30 are preferable. As the alkyl glyceryl ether, those in which the alkyl group has 8 to 18 carbon atoms, particularly 8 to 12 carbon atoms are preferable, and those in which the alkyl group is branched are preferable. (A3) can be used in combination of two or more. The content of the first agent and the second agent in the mixed solution is preferably 0.1 to 14.8% by weight, more preferably 0.4 to 8% by weight, particularly 1 to 5%. % By weight is preferred.

  Two or more kinds of component (A) can be used in combination, and the total content of the first agent and the second agent in the mixed solution is 1 to 15% by weight, preferably 0.5 to 8% by weight, particularly 1 ~ 6% by weight. In order to obtain fine foaming properties, the weight ratio of (A1) anionic surfactant to (A2) amphoteric surfactant (content of (A1) / content of (A2)) is 2 to 18. It is preferably 5 to 17, more preferably 10 to 16. Further, in order to further improve the foam quality when the liquid temperature is low, the total amount of (A1) anionic surfactant and (A2) amphoteric surfactant in the mixed solution with respect to (A3) nonionic surfactant The weight ratio ({(A1) content + (A2) content} / (A3) content) is preferably 0.01 to 1, particularly preferably 0.1 to 0.5.

  When the two-component hair cosmetic of the present invention is a hair dye, the first agent contains an oxidation dye or a direct dye. As the surfactant to be incorporated into the first agent for solubilization of these dyes, (A3) nonionic surfactant is mainly used in view of its high ionic strength due to ammonia and carbonate contained in the first agent. It is preferable to do. On the other hand, (A1) anionic surfactant and (A2) amphoteric surfactant are preferably contained in the second agent in view of the high ionic strength of the first agent.

[(B): Nonvolatile hydrophilic solvent]
The non-volatile hydrophilic solvent of component (B) is a stimulant such as hydrogen peroxide as moisture evaporates from the hair cosmetic while the two-part hair cosmetic of the present invention is applied to the hair and left standing. The irritation | stimulation with respect to a scalp by concentration of a sex component can be reduced. As the non-volatile hydrophilic solvent, those having no defoaming action such as polyols and lower (1 to 4 carbon atoms) alkyl ethers thereof are preferable. As the polyols, those having 2 to 6 carbon atoms are preferable, and examples thereof include glycerin, propylene glycol, dipropylene glycol, 1,3-butanediol, ethylene glycol, diethylene glycol, isoprene glycol, sorbitol and the like. Examples of the lower alkyl ethers of the polyol include mono-lower alkyl ethers and poly-lower alkyl ethers (for example, di-lower alkyl ethers) of the above-described polyols. Of these, monomethyl ether or monoethyl ether of polyol is preferable, and specific examples include ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol monomethyl ether, and diethylene glycol monoethyl ether. Two or more of these can be used in combination.

  The content of the non-volatile hydrophilic solvent in the mixed solution of the first agent and the second agent is 0.1 to 5% by weight because the effect of reducing scalp irritation and the foam quality is good even when the liquid temperature is low. %, Preferably 0.5 to 4% by weight, in particular 1 to 3% by weight.

  Even if the content of the non-volatile hydrophilic solvent is suppressed, the weight ratio of the component (A) to the component (B) (content of the component (A) is not included in order to maintain hair dyeing power and decoloring power without causing scalp irritation. The amount / content of component (B)) is 1-20, preferably 1-10, more preferably 1.5-5, in particular 2-4.

[(C): higher alcohol]
In the two-part hair cosmetic composition of the present invention, a higher alcohol is further added as a component (C) in order to improve the effect of suppressing liquid dripping while improving foaminess and applying to hair. It can be included. As the higher alcohol, those having an alkyl group or alkenyl group having 10 to 30 carbon atoms, more preferably 12 to 24 carbon atoms, particularly 14 to 22 carbon atoms are preferable, and those having an alkyl group, particularly a linear alkyl group are preferable. Examples of the higher alcohol of component (C) include myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, isostearyl alcohol, oleyl alcohol and the like. Two or more of these can be used in combination.

  Two or more components (C) can be used in combination, and can be contained in either one or both of the first agent and the second agent. The content of component (C) in the mixed liquid of the first agent and the second agent does not inhibit the foaming property when the liquid temperature is low, and enhances the effect of suppressing dripping during standing Therefore, 0.01 to 0.8% by weight is preferable, further 0.1 to 0.7% by weight, particularly 0.2 to 0.6% by weight is preferable.

[(D): Dimethyldiallylammonium chloride / acrylamide copolymer]
The two-part hair cosmetic composition of the present invention may further contain a dimethyldiallylammonium chloride / acrylamide copolymer (INCI name polyquaternium-7) as a component (D) in order to improve the dripping prevention effect. . As the component (D), for example, commercially available products such as Marquat 550 (ONDEO Nalco) can be used.

  The content of component (D) in the mixture of the first agent and the second agent realizes good foaming that is easy to apply to hair even when the liquid temperature is low or close to normal temperature, and the mixed liquid is added to the hair. In order to obtain an effect of preventing dripping between application and washing, 0.01 to 3% by weight, more preferably 0.1 to 1% by weight, and particularly preferably 0.2 to 0.5% by weight.

[(E): Dimethyldiallylammonium chloride / acrylic acid copolymer]
In the two-component hair cosmetic composition of the present invention, in order to control the defoaming property after application to the hair, to maintain an appropriate foam residue, and to make it easier to confirm the location where the application has been made, chlorination is further added as a component (E). Dimethyl diallylammonium / acrylic acid copolymer (INCI name: Polyquaternium-22) can be contained. As the component (E), for example, commercially available products such as Marquat 280 and Marquat 295 (above, ONDEO Nalco) can be used.

  The content of the component (E) in the mixed solution of the first agent and the second agent does not inhibit the foaming property when the liquid temperature is low, and in order to obtain the above effect, 0.01 to 0.5% by weight, particularly 0.1 to 0.2% by weight is preferred.

〔dye〕
The two-component hair cosmetic composition of the present invention can be used for decoloring hair when a mixture of the first agent and the second agent does not contain a dye, and can be dyed by containing an oxidative dye or a direct dye. Can be used. When used for hair dyeing, the first agent contains an oxidation dye or a direct dye. As this oxidation dye, paraphenylenediamine, paraaminophenol, toluene-2,5-diamine, N, N-bis (2-hydroxyethyl) paraphenylenediamine, 2- (2-hydroxyethyl) paraphenylenediamine, 4- Dye precursors such as amino-3-methylphenol, 6-amino-3-methylphenol, orthoaminophenol, 1-hydroxyethyl-4,5-diaminopyrazole, resorcin, 2-methylresorcin, metaaminophenol, paraamino ortho Examples include couplers such as cresol, 5- (2-hydroxyethylamino) -2-methylphenol, metaphenylenediamine, 2,4-diaminophenoxyethanol, and 1-naphthol. Examples of the direct dye include paranitroorthophenylenediamine, paranitrometaphenylenediamine, basic yellow 87, basic orange 31, basic red 12, basic red 51, basic blue 99, and acid orange 7.

[Silicones]
The two-component hair cosmetic composition of the present invention can further contain silicones. Examples of silicones include dimethylpolysiloxane, methylphenylpolysiloxane, polyether-modified silicone, amino-modified silicone, oxazoline-modified silicone elastomer, and the like, and emulsions in which these are dispersed in water using a surfactant. Of these, polyether-modified silicones, amino-modified silicones, and emulsions thereof are preferable because they can be stably dispersed in water without using a thickener.

  The polyether-modified silicone includes terminal-modified and side-chain-modified types such as a pendant type (comb type), a both-end modified type, and a one-end modified type. Examples of such modified silicones include dimethylsiloxane / methyl (polyoxyethylene) siloxane copolymer, dimethylsiloxane / methyl (polyoxypropylene) siloxane copolymer, dimethylsiloxane / methyl (polyoxyethylene / polyoxypropylene) siloxane. A copolymer etc. are mentioned. As the polyether-modified silicone, those having HLB of 10 or more, and particularly those of HLB of 10 to 18 are preferable from the viewpoint of compatibility with water. Here, HLB is based on the value obtained from the cloud number (cloud number: an index correlated with HLB and applied to ether type nonionic surfactants).

  Any amino-modified silicone may be used as long as it has an amino group or an ammonium group, but amodimethicone is preferable.

  The content of the silicones in the mixed solution of the first agent and the second agent is preferably 0.01 to 10% by weight in order to make the foam smoothly fit into the hair and to give a high conditioning effect to the hair. 0.1 to 5% by weight, particularly 0.5 to 3% by weight is preferred.

[Other ingredients]
In addition, the first agent and the second agent are fragrances, ultraviolet absorbers, sequestering agents such as edetic acid, bactericides, preservatives such as methyl parahydroxybenzoate, phenacetin, 1-hydroxyethane-1 , Stabilizers such as 1-diphosphonic acid and oxyquinoline sulfate, organic solvents such as ethanol, benzyl alcohol and benzyloxyethanol, water-soluble polymer compounds such as hydroxyethyl cellulose, humectants and the like. The mixed liquid of the first agent and the second agent is preferably water as a main medium.

  In order to further enhance the decoloring effect, a persulfate such as ammonium persulfate can be contained in the mixed solution as the third agent.

〔viscosity〕
The viscosity of the mixed solution of the first agent and the second agent is preferably 0.1 to 30 mPa · s, more preferably 0.5 to 20 mPa · s, and particularly preferably 1 to 10 mPa · s. Here, the viscosity is a value after rotating for 1 minute at 30 rpm using a rotor No. 1 with a B-type rotational viscometer at 25 ° C.

  By adjusting the viscosity of the mixed solution of the first agent and the second agent to be in the above range, it is possible to realize a foam volume that is easy to apply, and to prevent dripping after the mixed solution is applied to the hair. In addition to being able to suppress, it becomes easy to squeeze when discharging bubbles with a squeeze foamer or the like. In order to adjust the viscosity of the mixed solution to the above-described range, a water-soluble solvent such as ethanol may be added, or the content and type of surfactants, polyols, higher alcohols, and the like may be appropriately adjusted.

  The first agent and the second agent are preferably liquid, but if the viscosity of the mixed solution of the first agent and the second agent is within the above range, one of the first agent and the second agent May be in the form of powder, granule, paste or the like.

[Gas-liquid mixture ratio]
The gas / liquid mixing ratio of the air and the mixed liquid by the foam discharge means of the former container is preferably 7 to 40 mL / g, more preferably 15 to 30 mL / g from the viewpoint of ease of application of the agent to the hair and ease of application. preferable. In addition, the gas-liquid mixing ratio here is a value measured as follows.

  First, the gas-liquid mixing ratio is determined by measuring the weight and volume of the foam discharged at 25 ° C. Put 100g of the mixture into a squeeze foamer container (Daiwa Seisakusha, volume 150mL, mesh roughness (mesh) is 200 mesh per mixing chamber (200 mesh per 1 inch (25.4mm)), 255 mesh tip) From the time when the remaining amount is 80 g, 20 g of foam is discharged into a 1000 mL measuring cylinder and the volume of the foam is measured 1 minute after the start of discharge. The gas-liquid mixing ratio (mL / g) is obtained by dividing the volume (mL) of the discharged foam by the weight of 20 g.

[Former container]
In the present invention, the former container is a non-aerosol type container, and is used for mixing the liquid mixture of the first agent and the second agent with air without using a propellant and discharging it in the form of foam. . By using the former container, an effect of preventing scattering of the discharged agent can be obtained. In particular, a non-aerosol type container can manufacture a product at a lower cost than an aerosol type container and does not require a high-pressure gas propellant. Therefore, the product can be handled more safely in distribution.

  As the former container, a known pump former container having a foam discharge means, a squeeze foamer container, an electric frother, a pressure accumulating pump former container or the like can be used. More specifically, for example, food and containers (vol. 35, No. 10, p588 to 593 (1994); vol. 35, No. 11, p624 to 627 (1994); vol. 36, No. 3, p154 ~ 158 (1995)) Pump former E3 type, F2 type (above, Daiwa Steel Co., Ltd.), squeeze foamer (Daiwa Steel Co., Ltd.), electric whisk (Matsushita Electric Works), air spray for Mar (Air Spray International). As the former container used in the two-component hair cosmetic composition of the present invention, a pump former container and a squeeze foamer container are preferable because they are inexpensive and easy to use.

  A pump former container or a squeeze foamer container has a foam-generating part such as a net, and when the liquid mixture of one agent and two agents is dried and solidified to cause clogging, bubbles are generated at the next discharge. It is preferable to have a thin-walled net because the solidified material can be immediately dissolved by this flow to eliminate clogging. In this case, the net mesh is preferably 50 to 500 mesh, particularly 150 to 400 mesh. By using a mesh net in this range, creamy foam can be generated. Moreover, as a material of such a mesh, nylon, polyester, etc. can be illustrated preferably.

  The former container used in the two-component hair cosmetic composition of the present invention is provided with at least one, preferably a plurality of such nets, particularly two in view of economy, foam stability and the like. It is preferable to do.

  In the former container, the parts that come into contact with the contents (the inner wall of the container, the inner wall of the foam discharge means, etc.) are made of a material that does not corrode with alkali and hydrogen peroxide and is permeable to oxygen generated by the decomposition of hydrogen peroxide. It is preferable.

  As the product form of the two-component hair cosmetic composition of the present invention comprising the first agent, the second agent and the former container, the first agent or the second agent is filled in a container separate from the former container, and both are used at the time of use. The agent may be transferred to the former container and mixed, but one agent is filled into the former container, the other agent is filled into a separate container, and the other agent is transferred into the former container at the time of use. You may make it enter. In this case, the second agent is a gas permeable container, particularly an oxygen permeable material (for example, polyethylene) in order to prevent the pressure in the container from rising due to oxygen generated by the decomposition of hydrogen peroxide. It is preferable to fill a former container consisting of On the other hand, in order to prevent the oxidation of the oxidation dye, the first agent needs to use a container that does not easily transmit oxygen.

〔how to use〕
In order to dye or decolorize hair using the two-component hair cosmetic of the present invention, the first agent and the second agent are mixed in the former container, and the foamy agent discharged from the container is directly used. You may apply to hair and you may apply to hair using tools, such as a hand or a brush. After application, leave for about 3 to 60 minutes, preferably about 5 to 45 minutes, and wash away. Then, after shampooing and rinsing as appropriate, the hair is washed and dried.

Examples 1 to 8 and Comparative Examples 1 to 2: Two-component hair cosmetics for hair dyeing First and second agents having a formulation composition (% by weight) shown in Tables 1 to 3 were prepared and obtained. Agent and second agent in a mixing ratio (weight ratio) of 1: 1.5, mixed in a squeeze foamer (Daiwa Seisakusha, volume 150 mL, mesh roughness mixing chamber 200 mesh, tip 255 mesh) It was made to discharge in the shape.

  80 g of the discharged foam was applied to the entire subject's hair, allowed to stand for 30 minutes, then lightly washed with water and shampooed to dye the hair. “Stimulation of scalp” and “foaming” were evaluated according to the following criteria, and are shown in the lower column of the blending compositions in Tables 1 to 3.

Scalp sensation ◎: I do not feel stimulation ○: I hardly feel stimulation △: I feel some stimulation, but it is not an unbearable level ×: I feel stimulation clearly

Foaming ◎: Very uniform and fine foam ○: Uniform and fine foam △: Uneven and coarse foam ×: Cannot be completely foamed, mixed with moisture

The hair dyeing property was evaluated by dyeing a goat hair bundle. 2 g of foam discharged on a hair bundle of goat hair having a length of 10 cm and a weight of 3 g was applied, left in a thermostatic bath at 30 ° C. for 30 minutes, washed with water, and dyed by shampooing. With respect to the dyed hair bundle, the dyeability was evaluated according to the following criteria and shown in the lower column of the blending compositions in Tables 1 and 2.

◎: Excellent hair dyeability ○: Good hair dyeability △: Slightly weak hair dyeability ×: Weak hair dyeability

Claims (10)

  1. Two-component hair dyeing comprising a first agent containing an alkaline agent, a second agent containing hydrogen peroxide, and a non-aerosol-type former container for discharging a mixture of the first and second agents in the form of foam And the following components (A) and (B) in the mixture:
    (A) At least one surfactant selected from the group consisting of (A1) anionic surfactant, (A2) amphoteric surfactant and (A3) nonionic surfactant , 1 to 15% by weight
    (B) Non-volatile hydrophilic solvent 0.1 to 5% by weight
    A two-component hair dye containing 1 to 20 in which the weight ratio of component (A) to component (B) (content of component (A) / content of component (B)) is 1 to 20.
  2. In the mixed liquid of the first agent and the second agent, as the component (A), the following (A1) to (A3):
    (A1) Anionic surfactant 0.01 to 14.8% by weight
    (A2) Amphoteric surfactant 0.001-5% by weight
    (A3) Nonionic surfactant 0.1 to 14.8% by weight
    The two-component hair dye according to claim 1, comprising
  3.   The two-component hair dye according to claim 1 or 2, further comprising 0.01 to 0.8% by weight of a higher alcohol as a component (C) in a mixed solution of the first agent and the second agent.
  4.   Furthermore, as a component (D), the 2 agent type in any one of Claims 1-3 which contains 0.01 to 3weight% of dimethyl diallyl ammonium chloride acrylamide copolymer in the liquid mixture of the 1st agent and the 2nd agent. Hair dye.
  5.   The two-part agent according to any one of claims 1 to 4, further comprising, as a component (E), 0.01 to 0.5% by weight of a dimethyldiallylammonium chloride / acrylic acid copolymer in a mixed liquid of the first and second parts. Formula hair dye.
  6. The weight ratio of (A1) anionic surfactant to (A2) amphoteric surfactant (content of (A1) / content of (A2)) in the mixed liquid of the first agent and the second agent is 2 to 18 The two-component hair dye according to any one of claims 1 to 5.
  7. Weight ratio of the total amount of (A1) anionic surfactant and (A2) amphoteric surfactant to (A3) nonionic surfactant in the mixture of the first agent and the second agent ({content of (A1) + (A2) content} / (A3) content) is 0.01 to 1. The two-component hair dye according to any one of claims 1 to 6.
  8. The two-component hair dye according to any one of claims 1 to 7, wherein the viscosity of the mixed solution of the first agent and the second agent is 0.1 to 30 mPa · s.
  9. The two-component hair dye according to any one of claims 1 to 8, wherein a gas-liquid mixing ratio of air and the mixed liquid by the foam discharge means of the former container is 7 to 40 mL / g.
  10. A hair dyeing method using the two-component hair dye according to any one of claims 1 to 9 , wherein the first agent and the second agent are mixed in a non-aerosol type former container, and then the mixed solution is used. A hair dyeing method in which a foam is discharged from the container and applied to the hair using a hand, and then left to wash for 3 to 60 minutes.
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JP5604039B2 (en) * 2007-10-24 2014-10-08 花王株式会社 Two-component hair dye
DE202008018609U1 (en) 2007-10-24 2016-08-29 Kao Corporation Two-part hair dye
JP5651297B2 (en) * 2007-10-24 2015-01-07 花王株式会社 Two-component hair dye
TWI407973B (en) 2008-05-30 2013-09-11 Kao Corp Two-part foam hair dye
JP5466884B2 (en) * 2008-05-30 2014-04-09 花王株式会社 Two-component foam hair dye
JP5341618B2 (en) * 2009-06-02 2013-11-13 ホーユー株式会社 Aerosol-type foamy hair dye / bleaching agent composition and hair dyeing / bleaching method using the same
JP6067955B2 (en) * 2009-10-27 2017-01-25 ホーユー株式会社 Hydrogen peroxide-containing composition
JP5184486B2 (en) * 2009-10-27 2013-04-17 ホーユー株式会社 Hair cosmetic composition, hair cosmetic product, and method of using the hair cosmetic composition
WO2011075640A1 (en) 2009-12-18 2011-06-23 The Procter & Gamble Company Personal care composition foaming product and foaming dispenser
WO2011075652A1 (en) * 2009-12-18 2011-06-23 The Procter & Gamble Company Personal care composition foaming product
WO2011075659A2 (en) 2009-12-18 2011-06-23 The Procter & Gamble Company Foam hair colorant composition
JP5698933B2 (en) * 2010-07-30 2015-04-08 ホーユー株式会社 Hair cosmetic composition
JP5612955B2 (en) * 2010-07-30 2014-10-22 ホーユー株式会社 Hair cosmetic composition
CN103298448A (en) * 2010-11-01 2013-09-11 朋友株式会社 Hair cosmetic composition, method for using same, and hair cosmetic product
JP5687030B2 (en) * 2010-11-01 2015-03-18 ホーユー株式会社 Hair cosmetic composition, method of use thereof and hair cosmetic product
JP5687029B2 (en) * 2010-11-01 2015-03-18 ホーユー株式会社 Hair cosmetic composition, method of use thereof and hair cosmetic product
CN103298450B (en) * 2010-11-01 2016-08-10 朋友株式会社 The hair cosmetic compositions, methods of use and hair cosmetics
JP5822590B2 (en) * 2011-08-03 2015-11-24 ホーユー株式会社 Hair cosmetic composition
EP2760425B8 (en) 2011-09-30 2019-10-23 Noxell Corporation Foam oxidative hair colorant composition with the free-base of 1, 4-diamino-2-methoxymethyl benzene
JP5956811B2 (en) * 2012-04-09 2016-07-27 花王株式会社 Two-component foam hair dye
JP5956810B2 (en) * 2012-04-09 2016-07-27 花王株式会社 Two-component foam hair dye
JP6347955B2 (en) * 2013-06-17 2018-06-27 ホーユー株式会社 Hair cosmetics and hair cosmetic products

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06271435A (en) * 1993-03-19 1994-09-27 Takara Belmont Co Ltd Hair dye
JP3299141B2 (en) * 1997-04-14 2002-07-08 ホーユー株式会社 Two agents simultaneous discharge hair dye products
JP5214079B2 (en) * 2000-12-27 2013-06-19 ホーユー株式会社 Hair dye composition
JP4500463B2 (en) * 2001-03-23 2010-07-14 ホーユー株式会社 Two-component foam hair dye composition and two-component foam hair dye composition-containing aerosol product
JP4994543B2 (en) * 2001-08-31 2012-08-08 ホーユー株式会社 Foam hair dye composition and foam decolorant composition
JP3981289B2 (en) * 2002-03-29 2007-09-26 株式会社ダイゾー Foamable aerosol composition
US8153108B2 (en) * 2003-04-25 2012-04-10 Kao Corporation Hair cosmetic product
JP2005255536A (en) * 2004-03-09 2005-09-22 Kanebo Cosmetics Inc Hair dye composition

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