JP5871539B2 - Cosmetic composition - Google Patents
Cosmetic composition Download PDFInfo
- Publication number
- JP5871539B2 JP5871539B2 JP2011213640A JP2011213640A JP5871539B2 JP 5871539 B2 JP5871539 B2 JP 5871539B2 JP 2011213640 A JP2011213640 A JP 2011213640A JP 2011213640 A JP2011213640 A JP 2011213640A JP 5871539 B2 JP5871539 B2 JP 5871539B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- cosmetic composition
- skin
- copolymer
- hair
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 46
- 239000002537 cosmetic Substances 0.000 title claims description 33
- -1 trimethylammonio Chemical group 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 12
- 239000011777 magnesium Substances 0.000 claims description 12
- 239000011734 sodium Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 11
- 229910052749 magnesium Inorganic materials 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- 229920002907 Guar gum Polymers 0.000 claims description 6
- 239000000665 guar gum Substances 0.000 claims description 6
- 235000010417 guar gum Nutrition 0.000 claims description 6
- 229960002154 guar gum Drugs 0.000 claims description 6
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 5
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 5
- 241001558929 Sclerotium <basidiomycota> Species 0.000 claims description 5
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 5
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 5
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 5
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 5
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 5
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 3
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 3
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 244000046052 Phaseolus vulgaris Species 0.000 claims 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 description 19
- 229920001577 copolymer Polymers 0.000 description 19
- 238000011156 evaluation Methods 0.000 description 13
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- 239000003921 oil Substances 0.000 description 11
- 235000019198 oils Nutrition 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 8
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 7
- 239000002562 thickening agent Substances 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 239000002734 clay mineral Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 5
- 150000005846 sugar alcohols Polymers 0.000 description 5
- 229940058015 1,3-butylene glycol Drugs 0.000 description 4
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- NCZPCONIKBICGS-UHFFFAOYSA-N 3-(2-ethylhexoxy)propane-1,2-diol Chemical compound CCCCC(CC)COCC(O)CO NCZPCONIKBICGS-UHFFFAOYSA-N 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 235000019437 butane-1,3-diol Nutrition 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004676 glycans Chemical class 0.000 description 4
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 4
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 4
- 229920001282 polysaccharide Polymers 0.000 description 4
- 239000005017 polysaccharide Substances 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- 238000007665 sagging Methods 0.000 description 4
- 230000001953 sensory effect Effects 0.000 description 4
- 229940032094 squalane Drugs 0.000 description 4
- 239000001993 wax Substances 0.000 description 4
- 229940015975 1,2-hexanediol Drugs 0.000 description 3
- 229940031723 1,2-octanediol Drugs 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 229920000161 Locust bean gum Polymers 0.000 description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 239000002738 chelating agent Substances 0.000 description 3
- 229940008099 dimethicone Drugs 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 description 3
- 235000010420 locust bean gum Nutrition 0.000 description 3
- 239000000711 locust bean gum Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000001509 sodium citrate Substances 0.000 description 3
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 3
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 3
- 229940038773 trisodium citrate Drugs 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229920000800 acrylic rubber Polymers 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
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- 229940093629 isopropyl isostearate Drugs 0.000 description 2
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- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
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- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
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- BJDAUCLANVMIOB-UHFFFAOYSA-N (3-decanoyloxy-2,2-dimethylpropyl) decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCCCC BJDAUCLANVMIOB-UHFFFAOYSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Description
本発明は化粧料用組成物に関する。 The present invention relates to a cosmetic composition.
従来より、皮膚や毛髪に用いられる化粧料には、組成物にある程度の粘性を持たせて優れた使用感を付与する観点から、種々の増粘剤やゲル化剤が配合されている。中でも、カルボキシビニルポリマーやアクリル酸・メタクリル酸アルキルコポリマーなどのアクリル酸系増粘剤は最も汎用されている原料である。 Conventionally, various thickeners and gelling agents are blended in cosmetics used for skin and hair from the viewpoint of imparting an excellent feeling of use by imparting a certain degree of viscosity to the composition. Among them, acrylic thickeners such as carboxyvinyl polymer and acrylic acid / alkyl methacrylate copolymer are the most widely used raw materials.
しかしながら、アクリル酸系増粘剤の多くは、耐塩性に劣るといった性質があるため、皮膚に含まれる塩の影響により、組成物の粘度が急激に低下し、皮膚への塗布時や毛髪への塗布時に塗布部位から垂れ落ちが生じるといった問題がある。また、滑らかな延び広がりが悪く、優れた使用感が得られないといった問題もある。 However, since many acrylic acid thickeners have the property of being poor in salt resistance, the viscosity of the composition rapidly decreases due to the influence of salt contained in the skin, and when applied to the skin or on the hair. There is a problem that dripping occurs from the application site during application. In addition, there is a problem that smooth extension and spread are poor and an excellent feeling of use cannot be obtained.
このような問題を解決するために、耐塩性を向上させる試みがなされている。具体的には、例えば、カルボキシビニルポリマーと塩基性物質と疎水性無水ケイ酸と多価アルコールとを含有する水性ゲル状化粧料(例えば、特許文献1を参照)、カルボキシビニルポリマー及び/又はアルキル変性カルボキシビニルポリマーとジェランガムを含有する外用組成物(例えば、特許文献2を参照)などが提案されている。 In order to solve such problems, attempts have been made to improve salt resistance. Specifically, for example, an aqueous gel cosmetic (for example, see Patent Document 1) containing a carboxyvinyl polymer, a basic substance, a hydrophobic silicic acid anhydride and a polyhydric alcohol, a carboxyvinyl polymer and / or an alkyl. An external composition containing a modified carboxyvinyl polymer and gellan gum (for example, see Patent Document 2) has been proposed.
しかしながら、これら試みに拠って、ある程度耐塩性を向上させることはできるものの、滑らかな延び広がりに劣り、優れた使用感が得られ難いといった問題がある。 However, although these attempts can improve salt resistance to some extent, there is a problem that it is inferior in smooth spreading and it is difficult to obtain an excellent feeling of use.
一方、塩の影響を受けない粘土鉱物を用いた処方系で粘度を付与する試みもなされている。具体的には、例えば、粘土鉱物と微粒子シリカ粉末と水とを含有するゲル状組成物(例えば、特許文献3を参照)、粘土鉱物と水と常温で液状の油分とを含有するジェル組成物(例えば、特許文献4を参照)、有機変性粘土鉱物と油剤とを含有するゲル状組成物(例えば、特許文献5を参照)などが提案されている。 On the other hand, attempts have been made to impart viscosity with a prescription system using a clay mineral that is not affected by salt. Specifically, for example, a gel composition containing a clay mineral, fine-particle silica powder, and water (for example, see Patent Document 3), a gel composition containing a clay mineral, water, and an oil component that is liquid at room temperature. (For example, refer patent document 4), the gel-like composition (for example, refer patent document 5) containing an organic modified clay mineral and an oil agent etc. are proposed.
しかしながら、これら試みに拠って、ある程度粘度を付与することはできるものの、塗布部位からの垂れ落ちを抑制するのに十分な量の粘土鉱物を配合すると、延展時にヨレが生じてしまうために、滑らかな延び広がりに劣り、優れた使用感が得られ難いといった問題がある。 However, although it is possible to give a certain degree of viscosity based on these attempts, if a sufficient amount of clay mineral is added to suppress dripping from the application site, a twist will be generated at the time of spreading, and thus smoothness will occur. However, there is a problem that it is difficult to obtain an excellent feeling of use.
本発明は、上記従来技術に鑑みてなされたものであって、塩の影響による塗布時の皮膚又は毛髪からの垂れ落ちがなく、滑らかな延び広がりを示し、延展性に優れた効果を発揮する化粧料用組成物を提供することを課題とする。 The present invention has been made in view of the above prior art, and does not sag from the skin or hair during application due to the influence of salt, exhibits a smooth extension and spread, and exhibits an excellent extensibility effect. It is an object of the present invention to provide a cosmetic composition.
即ち、本発明は、
〔1〕フルオロケイ酸(ナトリウム/マグネシウム)と、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロースおよび塩化O−〔2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル〕ヒドロキシエチルセルロースの群から選ばれる少なくとも1種と、グァーガム、ローカストビーンガムおよびスクレロチウムガムの群から選ばれる少なくとも1種と、水とを含有してなる化粧料用組成物、
〔2〕皮膚に用いられることを特徴とする前記〔1〕に記載の化粧料用組成物、並びに
〔3〕毛髪に用いられることを特徴とする前記〔1〕に記載の化粧料用組成物
に関する。
That is, the present invention
[1] fluorosilicic acid (sodium / magnesium) and at least one selected from the group of hydroxypropylcellulose, hydroxypropylmethylcellulose and chlorinated O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose; A cosmetic composition comprising at least one selected from the group of guar gum, locust bean gum and sclerotium gum, and water;
[2] The cosmetic composition according to [1], which is used for skin, and [3] the cosmetic composition according to [1], which is used for hair. About.
本発明の化粧料用組成物は、塗布時に皮膚又は毛髪からの垂れ落ちがなく、延展時にはヨレがなく滑らかな延び広がりを示し、優れた延展性を発揮するという効果を奏する。 The cosmetic composition of the present invention has the effect that it does not sag from the skin or hair when applied, shows smooth extension and spread when spread, and exhibits excellent spreadability.
本発明の化粧料用組成物は、フルオロケイ酸(ナトリウム/マグネシウム)、特定のセルロース誘導体および水を含有する。 The cosmetic composition of the present invention contains fluorosilicic acid (sodium / magnesium), a specific cellulose derivative and water.
用いられるフルオロケイ酸(ナトリウム/マグネシウム)とは、INCI名(International Cosmetic Ingredient Dictionary and Handbook,第13版,第2巻,CTFA,2010年,p.2868):SODIUM MAGNESIUM FLUOROSILICATEで表記され、組成式:Na2Mg(SiF6)2で表される化合物である。 The fluorosilicic acid (sodium / magnesium) used is an INCI name (International Cosmetic Ingredient Dictionary and Handbook, 13th edition, Volume 2, CTFA, 2010, p. 2868): SODIUM MAGNESIUM FLUOROSILICATE : A compound represented by Na 2 Mg (SiF 6 ) 2 .
尚、上記フルオロケイ酸(ナトリウム/マグネシウム)は、市販品を用いることもできる。フルオロケイ酸(ナトリウム/マグネシウム)の市販品としては、例えば、商品名:ラポナイトXL21(ロックウッド社製)などを例示することができる。 In addition, the said fluorosilicic acid (sodium / magnesium) can also use a commercial item. As a commercial item of fluorosilicic acid (sodium / magnesium), brand name: Laponite XL21 (made by Rockwood) etc. can be illustrated, for example.
フルオロケイ酸(ナトリウム/マグネシウム)の含有量は、所望の効果が十分に付与されるのであれば特に限定されないが、通常、組成物に十分な粘性を与えて、塗布時の皮膚又は毛髪からの垂れ落ちを抑制し、優れた延展性を発揮させる観点から、組成物中、0.01〜8質量%であることが好ましく、より好ましくは0.1〜5質量%である。 The content of fluorosilicic acid (sodium / magnesium) is not particularly limited as long as the desired effect is sufficiently imparted, but usually it gives sufficient viscosity to the composition so that it can be removed from the skin or hair at the time of application. From the viewpoint of suppressing sagging and exhibiting excellent spreadability, it is preferably 0.01 to 8% by mass, more preferably 0.1 to 5% by mass in the composition.
本発明の化粧料用組成物には、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、塩化O−〔2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル〕ヒドロキシエチルセルロースの群から選ばれる少なくとも1種のセルロース誘導体が用いられる。 The cosmetic composition of the present invention contains at least one cellulose derivative selected from the group consisting of hydroxypropylcellulose, hydroxypropylmethylcellulose, and O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride. Used.
セルロース誘導体の含有量は、所望の効果が十分に付与されるのであれば特に限定されないが、通常、組成物に十分な粘性を与えて、塗布時の皮膚又は毛髪からの垂れ落ちを抑制し、優れた延展性を発揮させる観点から、組成物中、0.01〜5質量%であることが好ましく、より好ましくは0.05〜2質量%である。 The content of the cellulose derivative is not particularly limited as long as the desired effect is sufficiently imparted, but usually gives sufficient viscosity to the composition to suppress dripping from the skin or hair during application, From the viewpoint of exhibiting excellent spreadability, the content is preferably 0.01 to 5% by mass, more preferably 0.05 to 2% by mass in the composition.
化粧料用組成物の残部には、水が用いられる。用いられる水は、化粧料原料として使用できるものであれば特に限定はされないが、通常、精製水が用いられる。本発明における水の含有量は、組成物に十分な粘性を与える観点から、組成物中、20〜99.9質量%であることが好ましく、より好ましくは30〜80質量%である。 Water is used for the remainder of the cosmetic composition. The water used is not particularly limited as long as it can be used as a cosmetic raw material, but purified water is usually used. The content of water in the present invention is preferably 20 to 99.9% by mass, more preferably 30 to 80% by mass in the composition from the viewpoint of giving sufficient viscosity to the composition.
本発明の化粧料用組成物には、延展性を向上させる観点から、非イオン性多糖増粘剤を含有させることができる。用いられる非イオン性多糖増粘剤とは、グルコース、ガラクトース、マンノース、アラビノース、キシロースなどの単糖類の1種又は2種以上を主成分として構成されてなる非イオン性の多糖増粘剤のことである。具体的には、例えば、デキストラン、プルラン、アラビノガラクタン、グァーガム、タラガム、ローカストビーンガム、コンニャクマンナン、タマリンド種子ガム、スクレロチウムガムなどを例示することができる。これら成分は、1種を単独で用いてもよく、2種以上を適宜組み合わせて用いることもできる。これら成分の中でも、延展性を更に向上させる観点から、グァーガム、ローカストビーンガム、スクレロチウムガムを用いることが好ましい。 The cosmetic composition of the present invention can contain a nonionic polysaccharide thickener from the viewpoint of improving spreadability. The nonionic polysaccharide thickener used is a nonionic polysaccharide thickener composed mainly of one or more monosaccharides such as glucose, galactose, mannose, arabinose, and xylose. It is. Specific examples include dextran, pullulan, arabinogalactan, guar gum, tara gum, locust bean gum, konjac mannan, tamarind seed gum, sclerotium gum and the like. One of these components may be used alone, or two or more thereof may be used in appropriate combination. Among these components, from the viewpoint of further improving the spreadability, it is preferable to use guar gum, locust bean gum, or sclerotium gum.
非イオン性多糖増粘剤の含有量は特に限定されないが、通常、組成物中、0.01〜5質量%であることが好ましく、より好ましくは0.1〜2質量%である。 Although content of a nonionic polysaccharide thickener is not specifically limited, Usually, it is preferable that it is 0.01-5 mass% in a composition, More preferably, it is 0.1-2 mass%.
本発明の化粧料用組成物には、所望に応じて多価アルコールを含有させることができる。用いられる多価アルコールとしては、特に限定されないが、例えば、エチレングリコール、プロピレングリコール、ジプロピレングリコール、イソプレングリコール、ポリエチレングリコール、1,3−ブチレングリコール、グリセリン、濃グリセリン、ジグリセリン、トリグリセリン、グルコース、マルトース、マルチトール、スクロース、マンニトール、ソルビトール、1,2−ペンタンジオール、1,2−ヘキサンジオール、1,2−オクタンジオールなどを例示することができる。これら多価アルコールは、それぞれ単独で用いてもよく、2種以上を適宜組み合わせて用いることもできる。 The cosmetic composition of the present invention may contain a polyhydric alcohol as desired. The polyhydric alcohol used is not particularly limited. For example, ethylene glycol, propylene glycol, dipropylene glycol, isoprene glycol, polyethylene glycol, 1,3-butylene glycol, glycerin, concentrated glycerin, diglycerin, triglycerin, glucose , Maltose, maltitol, sucrose, mannitol, sorbitol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, and the like. These polyhydric alcohols may be used alone or in appropriate combination of two or more.
多価アルコールの含有量は特に限定されないが、通常、組成物中、0.1〜50質量%であることが好ましく、より好ましくは0.5〜40質量%である。 Although content of a polyhydric alcohol is not specifically limited, Usually, it is preferable that it is 0.1-50 mass% in a composition, More preferably, it is 0.5-40 mass%.
本発明の化粧料用組成物には、所望に応じて油剤を含有させることができる。用いられる油剤としては、特に限定されないが、例えば、油脂、ロウ類、炭化水素油、高級脂肪酸、高級アルコール、脂肪酸エステル、シリコーン(ストレートシリコーン、変性シリコーン環状シリコーン)などが挙げられる。これら油剤は、それぞれ単独で用いてもよく、2種以上を適宜組み合わせて用いることもできる。 The cosmetic composition of the present invention may contain an oil agent as desired. The oil agent to be used is not particularly limited, and examples thereof include fats and oils, waxes, hydrocarbon oils, higher fatty acids, higher alcohols, fatty acid esters, silicone (straight silicone, modified silicone cyclic silicone) and the like. These oil agents may be used alone or in combination of two or more.
具体的な油脂としては、ヒマワリ油、綿実油、大豆油、オリーブ油、ヤシ油、ヒマシ油、ホホバ油、椿油、ミンク油などを例示することができる。 Specific examples of the fats and oils include sunflower oil, cottonseed oil, soybean oil, olive oil, coconut oil, castor oil, jojoba oil, camellia oil, mink oil, and the like.
具体的なロウ類としては、カルナウバロウ、キャンデリラロウ、ミツロウ、コメヌカロウ、セラックロウ、鯨ロウ、ラノリンなどを例示することができる。 Specific examples of waxes include carnauba wax, candelilla wax, beeswax, rice bran wax, shellac wax, whale wax, and lanolin.
具体的な炭化水素油としては、軽質イソパラフィン、軽質流動イソパラフィン、合成スクワラン、植物性スクワラン、スクワラン、セレシン、パラフィン、流動パラフィン、流動イソパラフィン、マイクロクリスタリンワックス、ポリエチレン末、ポリエチレンワックス、ワセリンなどを例示することができる。 Specific hydrocarbon oils include light isoparaffin, light liquid isoparaffin, synthetic squalane, vegetable squalane, squalane, ceresin, paraffin, liquid paraffin, liquid isoparaffin, microcrystalline wax, polyethylene powder, polyethylene wax, petrolatum, etc. be able to.
具体的な高級脂肪酸としては、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、ベヘニン酸、ウンデシレン酸、ラノリン酸、イソステアリン酸などを例示することができる。 Specific examples of the higher fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, undecylenic acid, lanolinic acid, and isostearic acid.
具体的な高級アルコールとしては、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、オレイルアルコール、ラノリンアルコール、ベヘニルアルコール、セトステアリルアルコール、オクチルデカノール、デシルテトラデカノールなどを例示することができる。 Specific examples of the higher alcohol include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, lanolin alcohol, behenyl alcohol, cetostearyl alcohol, octyldecanol, and decyltetradecanol.
具体的な脂肪酸エステルとしては、オレイン酸エチル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸ミリスチル、パルミチン酸セチル、オレイン酸オレイル、ミリスチン酸オクチルドデシル、オレイン酸オクチルドデシル、イソステアリン酸エチル、イソステアリン酸イソプロピル、2−エチルヘキサン酸セチル、2−エチルヘキサン酸セトステアリル、オクタン酸イソセチル、オクタン酸イソステアリル、イソステアリン酸イソプロピル、イソステアリン酸イソセチル、イソステアリン酸オクチルドデシル、ジメチルオクタン酸オクチルドデシル、ジオレイン酸エチレングリコール、ジカプリル酸プロピレングリコール、ジカプリン酸プロピレングリコール、ジ(カプリル/カプリン酸)プロピレングリコール、イソステアリン酸プロピレングリコール、ジカプリン酸ネオペンチルグリコール、トリ2−エチルヘキサン酸グリセリル、トリイソパルミチン酸グリセリル、テトラ2−エチルヘキサン酸ペンタエリスリトールなどを例示することができる。 Specific fatty acid esters include ethyl oleate, isopropyl myristate, isopropyl palmitate, myristyl myristate, cetyl palmitate, oleyl oleate, octyldodecyl myristate, octyldodecyl oleate, ethyl isostearate, isopropyl isostearate, Cetyl 2-ethylhexanoate, cetostearyl 2-ethylhexanoate, isocetyl octoate, isostearyl octoate, isopropyl isostearate, isocetyl isostearate, octyldodecyl isostearate, octyldodecyl dimethyloctanoate, ethylene glycol dioleate, dicaprylic acid Propylene glycol, propylene glycol dicaprate, di (capryl / capric) propylene glycol, Sosutearin propylene glycol, can be exemplified neopentylglycol dicaprate, glyceryl tri-2-ethylhexanoate, triisopalmitate, glyceryl tetra-2-ethylhexanoate, pentaerythritol and the like.
具体的なシリコーンとしては、オクタメチルトリシロキサン、テトラデカメチルヘキサシロキサン、メチルポリシロキサン、高重合メチルポリシロキサン、メチルフェニルポリシロキサン、メチルハイドロジェンポリシロキサンなどのストレートシリコーン;アルコール変性シリコーン、アルキル変性シリコーン、アミノ変性シリコーン、ポリエーテル変性シリコーン、エポキシ変性シリコーンなどの変性シリコーン;メチルシクロポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサンなどの環状シリコーンなどを例示することができる。 Specific silicones include straight silicones such as octamethyltrisiloxane, tetradecamethylhexasiloxane, methylpolysiloxane, highly polymerized methylpolysiloxane, methylphenylpolysiloxane, methylhydrogenpolysiloxane; alcohol-modified silicone, alkyl-modified silicone And modified silicones such as amino-modified silicone, polyether-modified silicone, and epoxy-modified silicone; and cyclic silicones such as methylcyclopolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane. it can.
油剤の含有量は特に限定されないが、通常、組成物中、0.01〜50質量%であることが好ましく、より好ましくは0.1〜30質量%である。 Although content of an oil agent is not specifically limited, Usually, it is preferable that it is 0.01-50 mass% in a composition, More preferably, it is 0.1-30 mass%.
本発明の化粧料用組成物には、所望に応じて被膜形成剤を含有させることができる。用いられる被膜形成剤としては、特に限定されないが、例えば、アニオン性被膜形成剤、カチオン性被膜形成剤、両性被膜形成剤、ノニオン性被膜形成剤などが挙げられる。これら被膜形成剤は、それぞれ単独で用いてもよく、2種以上を適宜組み合わせて用いることもできる。 The cosmetic composition of the present invention can contain a film-forming agent as desired. The film forming agent to be used is not particularly limited, and examples thereof include an anionic film forming agent, a cationic film forming agent, an amphoteric film forming agent, and a nonionic film forming agent. These film forming agents may be used alone or in combination of two or more.
具体的なアニオン性被膜形成剤としては、例えば、アクリル樹脂アルカノールアミン、メチルビニルエーテル/マレイン酸エステル共重合体、酢酸ビニル/クロトン酸共重合体、酢酸ビニル/クロトン酸/ネオデカン酸ビニル共重合体、酢酸ビニル/クロトン酸/プロピオン酸ビニル共重合体、酢酸ビニル/マレイン酸モノブチルエステル/イソボロリルアクリレート共重合体、アクリル酸/アクリル酸アルキルエステル/アルキルアクリルアミド共重合体、ポリビニルピロリドン/アクリレート/(メタ)アクリル酸共重合体、(スチレン/アクリル酸アルキル)共重合体、(スチレン/アクリル酸アミド)共重合体、ウレタン−アクリル系共重合体、ポリスチレンスルホン酸ナトリウムなどを例示することができる。尚、本明細書において、「(メタ)アクリル」とは、「アクリル」および「メタクリル」の双方を意味する。 Specific anionic film forming agents include, for example, acrylic resin alkanolamine, methyl vinyl ether / maleic acid ester copolymer, vinyl acetate / crotonic acid copolymer, vinyl acetate / crotonic acid / vinyl neodecanoate copolymer, Vinyl acetate / crotonic acid / vinyl propionate copolymer, vinyl acetate / maleic acid monobutyl ester / isoborolyl acrylate copolymer, acrylic acid / acrylic acid alkyl ester / alkyl acrylamide copolymer, polyvinyl pyrrolidone / acrylate / ( Examples thereof include a meth) acrylic acid copolymer, a (styrene / alkyl acrylate) copolymer, a (styrene / acrylic acid amide) copolymer, a urethane-acrylic copolymer, and sodium polystyrene sulfonate. In the present specification, “(meth) acryl” means both “acryl” and “methacryl”.
具体的なカチオン性被膜形成剤としては、例えば、ビニルピロリドン・N,N−ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩、塩化О−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]ヒドロキシエチルセルロース、ビニルイミダゾリウムトリクロライド/ビニルピロリドン共重合体、ヒドロキシエチルセルロース/ジメチルジアリルアンモニウムクロリド、ポリビニルピロリドン/アルキルアミノアクリレート/ビニルカプロラクタム共重合体、塩化メチルビニルイミダゾリウム・ビニルピロリドン共重合体、(ビニルピロリドン/ジメチルアミノプロピルメタクリルアミド/ラウリルジメチルアミノプロピルメタクリルアミド)共重合体などを例示することができる。 Specific cationic film forming agents include, for example, vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxy chloride. Ethyl cellulose, vinyl imidazolium trichloride / vinyl pyrrolidone copolymer, hydroxyethyl cellulose / dimethyl diallylammonium chloride, polyvinyl pyrrolidone / alkylamino acrylate / vinyl caprolactam copolymer, methyl vinyl imidazolium chloride / vinyl pyrrolidone copolymer, (vinyl pyrrolidone / Dimethylaminopropyl methacrylamide / lauryl dimethylaminopropyl methacrylamide) copolymer and the like.
具体的な両性被膜形成剤としては、例えば、N−メタクリロイルオキシエチルN,N−ジメチルアンモニウム−α−N−メチルカルボキシベタイン・メタクリル酸アルキルエステル共重合体、N,Nジメチル−N−(2−メタクリロイルオキシエチル)アミン=N−オキシド・メタクリル酸アルキルエステル共重合体、アクリル酸ヒドロキシプロピル/メタクリル酸ブチルアミノエチル/アクリル酸オクチルアミド共重合体、ジアルキルアミノエチルメタクリレート/メタクリル酸アルキルエステル共重合体のモノクロル酢酸両性化物、(イソブチレン/ジエチルアミノプロピルマレイミド/マレイン酸)共重合体などを例示することができる。 Specific examples of amphoteric film forming agents include N-methacryloyloxyethyl N, N-dimethylammonium-α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer, N, N dimethyl-N- (2- Methacryloyloxyethyl) amine = N-oxide / methacrylic acid alkyl ester copolymer, hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer, dialkylaminoethyl methacrylate / alkyl methacrylate ester copolymer Examples include monochloroacetic acid amphoteric compounds and (isobutylene / diethylaminopropylmaleimide / maleic acid) copolymers.
具体的なノニオン性被膜形成剤としては、例えば、ポリビニルピロリドン、ビニルピロリドン/酢酸ビニル共重合体、ビニルピロリドン/メタクリルアミド/ビニルイミダゾール共重合体、ビニルメチルエーテル・マレイン酸エチル共重合体、ポリビニルアルコール、ポリビニルカプロラクタムなどを例示することができる Specific nonionic film forming agents include, for example, polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymer, vinyl pyrrolidone / methacrylamide / vinyl imidazole copolymer, vinyl methyl ether / ethyl maleate copolymer, polyvinyl alcohol. And polyvinyl caprolactam can be exemplified.
被膜形成剤の含有量は特に限定されないが、通常、組成物中、0.0001〜5質量%であることが好ましく、より好ましくは0.001〜2質量%である。 Although content of a film formation agent is not specifically limited, Usually, it is preferable that it is 0.0001-5 mass% in a composition, More preferably, it is 0.001-2 mass%.
尚、本発明に係る化粧料用組成物には、本発明の効果を損なわない範囲であれば、上記に記した成分の他、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤、ノニオン性界面活性剤などの界面活性剤;メントール、メンチルグリセリルエーテル、カンファなどの清涼剤;フェノキシエタノール、グリセリンモノ−2−エチルヘキシルエーテルなどの防腐剤;抗酸化剤、金属封鎖剤、紫外線吸収剤、ビタミン類、動植物抽出エキス、パール化剤、着色剤、各種香料などを目的に応じて適宜配合してもよい。 In addition, in the cosmetic composition according to the present invention, an anionic surfactant, a cationic surfactant, an amphoteric surfactant in addition to the components described above as long as the effects of the present invention are not impaired. Surfactants such as nonionic surfactants; refreshing agents such as menthol, menthyl glyceryl ether, camphor; preservatives such as phenoxyethanol, glycerol mono-2-ethylhexyl ether; antioxidants, sequestering agents, UV absorbers, Vitamins, animal and plant extracts, pearling agents, coloring agents, various fragrances, and the like may be appropriately blended depending on the purpose.
本発明の化粧料用組成物は、前記各構成成分を混合し、公知の方法、例えば、プロペラミキサーなどを用いて攪拌することにより製造することができる。 The cosmetic composition of the present invention can be produced by mixing the components described above and stirring them using a known method such as a propeller mixer.
本発明の化粧料用組成物の粘度(mPa・s)は、塗布時の皮膚又は毛髪からの垂れ落ちを抑制し、優れた延展性を発揮できる粘度範囲であれば特に限定されないが、5,000〜500,000mPa・sの範囲内で調製されることが好ましい。尚、粘度は、B型粘度計(VISCOMETER 東機産業社製)を用いて、測定条件:適宜粘度に合わせて、ローターNo.1〜No.4を用いて0.3〜12rpm、1分間にて測定した値であるが、これら測定条件にのみ限定されるものではない。 The viscosity (mPa · s) of the cosmetic composition of the present invention is not particularly limited as long as it is in a viscosity range in which dripping from the skin or hair during application can be suppressed and excellent spreadability can be exhibited. It is preferably prepared within a range of 000 to 500,000 mPa · s. The viscosity was measured using a B-type viscometer (manufactured by VISCOMETER Toki Sangyo Co., Ltd.) according to the measurement conditions: the viscosity as appropriate. 1-No. 4 is a value measured at 0.3 to 12 rpm for 1 minute, but is not limited to these measurement conditions.
尚、本発明の化粧料用組成物は、塗布時の垂れ落ちがなく、滑らかな延び広がりを奏し、延展性に優れた効果を発揮するものであるから、皮膚用の化粧料、若しくは毛髪用の化粧料として最も好適に用いられる。 The cosmetic composition of the present invention has no dripping at the time of application, exhibits a smooth extension and spread, and exhibits an effect of excellent spreadability. Therefore, the cosmetic composition for skin or hair It is most preferably used as a cosmetic.
以下、本発明を実施例に基づいて更に詳細に説明するが、本発明はこれら実施例にのみ限定されるものではない。尚、配合量は特記しない限り「質量%」を表す。 EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example, this invention is not limited only to these Examples. The blending amount represents “% by mass” unless otherwise specified.
(試料の調製)
表1および表2に記した組成に従い、実施例1〜5および比較例1〜5の各化粧料用組成物を調製し、下記評価試験に供した。結果をそれぞれ表1および表2に併記する。
(Sample preparation)
According to the composition described in Table 1 and Table 2, the cosmetic compositions of Examples 1 to 5 and Comparative Examples 1 to 5 were prepared and subjected to the following evaluation test. The results are shown in Table 1 and Table 2, respectively.
(試験例1;皮膚に用いた時の評価)
官能評価パネル20名により、実施例および比較例で得られた各試料1.5gを実際に前腕内側部に塗布してもらい、塗布時の皮膚からの「垂れ落ち」、並びに延展時の「延び広がり」について、以下の評価基準に従って官能評価した。
(Test Example 1: Evaluation when used on skin)
The sensory evaluation panel 20 people actually applied 1.5 g of each sample obtained in the examples and comparative examples to the inner side of the forearm, and “sagging” from the skin at the time of application, and “extension at the time of extension” Sensory evaluation was performed according to the following evaluation criteria for “spread”.
<皮膚からの垂れ落ちの評価基準>
◎:20名中16名以上が、皮膚からの垂れ落ちはないと回答
○:20名中11〜15名が、皮膚からの垂れ落ちはないと回答
△:20名中6〜10名が、皮膚からの垂れ落ちはないと回答
×:20名中5名以下が、皮膚からの垂れ落ちはないと回答
<Evaluation criteria for dripping from skin>
◎: More than 16 out of 20 responded that there was no dripping from the skin ○: 11-15 out of 20 responded that there was no dripping from the skin △: 6-10 out of 20 answered, Answer that there is no dripping from the skin ×: 5 or less of 20 people answered that there was no dripping from the skin
<皮膚上での延展性の評価基準>
◎:20名中16名以上が、ヨレなく滑らかに延び広がると回答
○:20名中11〜15名が、ヨレなく滑らかに延び広がると回答
△:20名中6〜10名が、ヨレなく滑らかに延び広がると回答
×:20名中5名以下が、ヨレなく滑らかに延び広がると回答
<Evaluation criteria for spreadability on skin>
◎: More than 16 out of 20 people answered that it smoothly extends and spreads. ○: 11-15 people out of 20 responded that it spreads smoothly and smoothly. △: 6 to 10 out of 20 people answered without any errors. Answers that extend smoothly × 5: Less than 5 out of 20 responded that it extends smoothly and spreads smoothly
(試験例2;毛髪に用いた時の評価)
官能評価パネル20名により、23℃、湿度60%の恒温恒湿下で一晩放置した毛束(長さ10cm、幅0.8cm、重量1g)に、実施例および比較例で得られた各試料1.5gを塗布してもらい、塗布時の毛髪からの「垂れ落ち」、並びに延展時の「延び広がり」について、以下の評価基準に従って官能評価した。
(Test Example 2: Evaluation when used on hair)
Each of the hair samples (length 10 cm, width 0.8 cm, weight 1 g) left overnight at 23 ° C. and 60% humidity at a constant temperature and humidity by each of the 20 sensory evaluation panels was obtained in each of the examples and comparative examples. A sample of 1.5 g was applied, and “sagging” from the hair at the time of application and “extension / expansion” at the time of spreading were subjected to sensory evaluation according to the following evaluation criteria.
<毛髪からの垂れ落ちの評価基準>
◎:20名中16名以上が、毛束からの垂れ落ちはないと回答
○:20名中11〜15名が、毛束からの垂れ落ちはないと回答
△:20名中6〜10名が、毛束からの垂れ落ちはないと回答
×:20名中5名以下が、毛束からの垂れ落ちはないと回答
<Evaluation criteria for dripping from hair>
◎: More than 16 out of 20 responded that there was no dripping from the hair bundle ○: 11-15 out of 20 responded that there was no dripping from the hair bundle Δ: 6-10 out of 20 However, it is answered that there is no dripping from the hair bundle ×: 5 or less of 20 people answered that there is no dripping from the hair bundle
<毛髪上での延展性の評価基準>
◎:20名中16名以上が、ヨレなく滑らかに延び広がると回答
○:20名中11〜15名が、ヨレなく滑らかに延び広がると回答
△:20名中6〜10名が、ヨレなく滑らかに延び広がると回答
×:20名中5名以下が、ヨレなく滑らかに延び広がると回答
<Evaluation criteria for spreadability on hair>
◎: More than 16 out of 20 people answered that it smoothly extends and spreads. ○: 11-15 people out of 20 responded that it spreads smoothly and smoothly. △: 6 to 10 out of 20 people answered without any errors. Answers that extend smoothly × 5: Less than 5 out of 20 responded that it extends smoothly and spreads smoothly
表1および表2の結果から、各実施例の化粧料用組成物は、各比較例のものと対比して、皮膚に塗布した場合および毛髪に塗布した場合の何れであっても、塗布部位からの垂れ落ちはなく、滑らかな延び広がり、延展性に優れた効果を発揮していることが分かる。 From the results in Tables 1 and 2, the cosmetic composition of each example was applied to the skin regardless of whether it was applied to the skin or the hair, as compared with the comparative example. It can be seen that there is no dripping from the surface, smooth extension and spread, and an excellent effect in spreadability.
これに対し、本願発明の構成を充足しない比較例1、並びに本願発明の構成を充足せず他の成分へ置き換えた比較例2〜5では、塗布部位からの垂れ落ちが生じる、若しくは延展性に劣る結果となり、本発明の効果を十分に発揮できないものであることが分かる。 On the other hand, in Comparative Example 1 that does not satisfy the configuration of the present invention and Comparative Examples 2 to 5 that do not satisfy the configuration of the present invention and are replaced with other components, sagging from the application site occurs, or in spreadability It turns out that it becomes an inferior result and cannot fully demonstrate the effect of the present invention.
以下、本発明に係る化粧料用組成物の処方例を示す。尚、含有量は質量%である。また、POEとはポリオキシエチレンの略であり、括弧内の数値は、酸化エチレンの付加モル数を表す。 Hereinafter, formulation examples of the cosmetic composition according to the present invention will be shown. In addition, content is mass%. POE is an abbreviation for polyoxyethylene, and the numerical value in parentheses represents the number of added moles of ethylene oxide.
(処方例1:皮膚用化粧料)
モノステアリン酸デカグリセリル 0.5
モノステアリン酸グリセリル 0.5
水素添加大豆レシチン 1.0
フルオロケイ酸(ナトリウム/マグネシウム) 1.0
ヒドロキシプロピルメチルセルロース 1.0
グアーガム 0.15
スクレロチウムガム 0.15
トリ2−エチルヘキサン酸グリセリル 5.0
2−エチルヘキサン酸セチル 2.0
スクワラン 2.0
ジメチコン 0.5
ジプロピレングリコール 5.0
グリセリン 2.0
1,3−ブチレングリコール 5.0
ジプロピレングリコール 5.0
グリセリンモノ−2−エチルヘキシルエーテル 0.1
1,2−ヘキサンジオール 0.5
クエン酸 適 量
クエン酸3ナトリウム 適 量
防腐剤 適 量
金属キレート剤 適 量
塩化ナトリウム 適 量
精製水 残 部
合 計 100.0
(Formulation example 1: skin cosmetics)
Decaglyceryl monostearate 0.5
Glyceryl monostearate 0.5
Hydrogenated soybean lecithin 1.0
Fluorosilicic acid (sodium / magnesium) 1.0
Hydroxypropyl methylcellulose 1.0
Guar gum 0.15
Sclerotium Gum 0.15
Glyceryl tri-2-ethylhexanoate 5.0
Cetyl 2-ethylhexanoate 2.0
Squalane 2.0
Dimethicone 0.5
Dipropylene glycol 5.0
Glycerin 2.0
1,3-butylene glycol 5.0
Dipropylene glycol 5.0
Glycerin mono-2-ethylhexyl ether 0.1
1,2-hexanediol 0.5
Citric acid appropriate amount Trisodium citrate appropriate amount Preservative appropriate amount Metal chelating agent appropriate amount Sodium chloride appropriate amount
Purified water balance part Total 100.0
(処方例2:クレンジング化粧料)
イソステアリン酸POE(8)グリセリル 20.0
モノラウリン酸ポリエチレングリコール(12) 1.0
N−ステアロイル−L−グルタミン酸ナトリウム 0.5
フルオロケイ酸(ナトリウム/マグネシウム) 1.0
ヒドロキシプロピルメチルセルロース 0.5
スクレロチウムガム 0.5
軽質イソパラフィン 5.0
2−エチルヘキサン酸セチル 10.0
パルミチン酸イソプロピル 10.0
流動パラフィン 15.0
ジプロピレングリコール 5.0
グリセリン 2.0
1,3−ブチレングリコール 5.0
ジプロピレングリコール 5.0
グリセリンモノ−2−エチルヘキシルエーテル 0.1
1,2−オクタンジオール 0.5
クエン酸 適 量
クエン酸3ナトリウム 適 量
塩化ナトリウム 適 量
防腐剤 適 量
金属キレート剤 適 量
精製水 残 部
合 計 100.0
(Prescription Example 2: Cleansing Cosmetic)
Isostearic acid POE (8) glyceryl 20.0
Polyethylene glycol monolaurate (12) 1.0
N-stearoyl-sodium L-glutamate 0.5
Fluorosilicic acid (sodium / magnesium) 1.0
Hydroxypropyl methylcellulose 0.5
Sclerotic gum 0.5
Light isoparaffin 5.0
Cetyl 2-ethylhexanoate 10.0
Isopropyl palmitate 10.0
Liquid paraffin 15.0
Dipropylene glycol 5.0
Glycerin 2.0
1,3-butylene glycol 5.0
Dipropylene glycol 5.0
Glycerin mono-2-ethylhexyl ether 0.1
1,2-octanediol 0.5
Citric acid appropriate amount Trisodium citrate appropriate amount Sodium chloride appropriate amount Preservative appropriate amount Metal chelating agent appropriate amount
Purified water balance part Total 100.0
(処方例3:毛髪用化粧料)
ジメチコンコポリオール 3.0
モノラウリン酸ポリエチレングリコール(12) 1.0
ポリオキシエチレン(カルリル・カプリン酸)グリセリル(6) 0.5
フルオロケイ酸(ナトリウム/マグネシウム) 1.0
合成ケイ酸(ナトリウム/マグネシウム) 0.5
アクリル酸アルキルコポリマー 1.5
塩化O−〔2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル〕
ヒドロキシエチルセルロース 0.2
グアーガム 0.15
軽質イソパラフィン 5.0
ジメチコン 10.0
塩化ステアリルトリメチルアンモニウム 0.1
2−エチルヘキサン酸セチル 10.0
ジプロピレングリコール 5.0
グリセリン 2.0
1,3−ブチレングリコール 5.0
ジプロピレングリコール 5.0
グリセリンモノ−2−エチルヘキシルエーテル 0.1
1,2−ヘキサンジオール 0.4
1,2−オクタンジオール 0.4
クエン酸 適 量
クエン酸3ナトリウム 適 量
塩化ナトリウム 適 量
防腐剤 適 量
金属キレート剤 適 量
精製水 残 部
合 計 100.0
(Formulation Example 3: Hair cosmetic)
Dimethicone Copolyol 3.0
Polyethylene glycol monolaurate (12) 1.0
Polyoxyethylene (carryl / capric acid) glyceryl (6) 0.5
Fluorosilicic acid (sodium / magnesium) 1.0
Synthetic silicic acid (sodium / magnesium) 0.5
Alkyl acrylate copolymer 1.5
O- [2-hydroxy-3- (trimethylammonio) propyl] chloride
Hydroxyethyl cellulose 0.2
Guar gum 0.15
Light isoparaffin 5.0
Dimethicone 10.0
Stearyltrimethylammonium chloride 0.1
Cetyl 2-ethylhexanoate 10.0
Dipropylene glycol 5.0
Glycerin 2.0
1,3-butylene glycol 5.0
Dipropylene glycol 5.0
Glycerin mono-2-ethylhexyl ether 0.1
1,2-hexanediol 0.4
1,2-octanediol 0.4
Citric acid appropriate amount Trisodium citrate appropriate amount Sodium chloride appropriate amount Preservative appropriate amount Metal chelating agent appropriate amount
Purified water balance part Total 100.0
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MXPA02009634A (en) * | 2000-03-31 | 2003-03-12 | Procter & Gamble | Hair conditioning composition comprising carboxylic acid carboxylate copolymer and vinylpyrrolidone copolymer. |
JP3884681B2 (en) * | 2002-08-14 | 2007-02-21 | 株式会社ファンケル | Cosmetics |
JP2007297380A (en) * | 2006-04-07 | 2007-11-15 | Lion Corp | Hair detergent composition |
US20090233825A1 (en) * | 2006-11-08 | 2009-09-17 | Colin Christopher David Giles | Conditioning shampoo compositions |
EP2459201B1 (en) * | 2009-07-30 | 2018-06-20 | Sonoma Pharmaceuticals, Inc. | Hydrogel formulation comprising oxidative reductive potential water |
JP5723188B2 (en) * | 2011-03-24 | 2015-05-27 | 株式会社マンダム | Gel cleansing cosmetic |
JP2012240966A (en) * | 2011-05-19 | 2012-12-10 | Lion Corp | Organic-inorganic composite thickened body and method for preparing the same, and gel cosmetic or substrate for external preparation |
JP5837330B2 (en) * | 2011-05-23 | 2015-12-24 | 株式会社マンダム | Viscous composition |
JP5797507B2 (en) * | 2011-09-29 | 2015-10-21 | 株式会社マンダム | Cosmetic composition |
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