CN103298448A - Hair cosmetic composition, method for using same, and hair cosmetic product - Google Patents
Hair cosmetic composition, method for using same, and hair cosmetic product Download PDFInfo
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- CN103298448A CN103298448A CN2011800526026A CN201180052602A CN103298448A CN 103298448 A CN103298448 A CN 103298448A CN 2011800526026 A CN2011800526026 A CN 2011800526026A CN 201180052602 A CN201180052602 A CN 201180052602A CN 103298448 A CN103298448 A CN 103298448A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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Abstract
Provided is a hair cosmetic that discharges in a foam dosage form from a non-aerosol foamer container, imparts a favorable brightness to hair, is excellent for dyeing hair, and does not drip during application to hair. A hair cosmetic composition configured as a hair dye or a hair-bleaching agent, and at time of use entailing the discharge of a liquid mixture of a first agent and a second agent as foam from a non-aerosol foamer container and subsequent application to hair, the hair cosmetic composition containing a non-ionic surfactant component (A) in the amount of 10 mass% or more, and a component (B) comprising, as a higher alcohol, a component (B1), which is a higher alcohol that at 25 DEG C is a liquid.
Description
Technical field
The present invention relates to cosmetic hair composition, its using method and hair cosmetic product.And then at length, the present invention relates to can from the non-aerosol foaming vessel (
) discharge and be applied to cosmetic hair composition, its using method of hair and contain this cosmetic hair composition and non-aerosol foaming vessel and the hair cosmetic product that constitutes with blister.
Background technology
The hair cosmetic composition of known hair dye or hair depigmenting agent etc. uses with the dosage form of blister in use.In general, when using these hair cosmetic compositions with the dosage form of blister, can expect following advantage: the evenly coating on the no spot of hair ground easily, can eliminate the such trouble of the hair caking that when the hair cosmetic composition of the gel that uses extensive use or paste, produces etc.
The hair cosmetic composition that uses with the dosage form of blister is broadly divided into aerosol type and non-aerosol type.For aerosol type, use the such propellant of liquid gas, make dosage form be blister by the formation that has utilized aerocolloidal bubble.For the non-aerosol type, do not use propellant, and use other non-aerosol foaming vessel (following also abbreviate as " foaming vessel ") of pump foam maker (Port Application プ フ ォ ー マ ー) or crushed foam generator to form the bubble of having taken in air, making dosage form is blister.Aspect simple from the formation of the container that is used for carrying out the blister dosage formization, favourable on cost and when not preserving or the considerations such as aspect of the danger during operation, preferred non-aerosol foaming vessel.
In following patent documentation 1, the patent documentation 2, the oxide hair dye composition or the hair coloring preparation composition that utilize aerosol and dosage form is used for blister are disclosed.In addition, in following patent documentation 3, patent documentation 4, disclose and utilized the non-aerosol foaming vessel and make hair dye that dosage form uses for blister etc.
The prior art document
[patent documentation 1] Japanese kokai publication hei 09-136818 communique
[patent documentation 2] Japanese kokai publication hei 10-287534 communique
[patent documentation 3] TOHKEMY 2007-291015 communique
[patent documentation 4] TOHKEMY 2008-291020 communique.
Summary of the invention
Hair cosmetic composition for the blister dosage form that can discharge from the non-aerosol foaming vessel has above-mentioned various advantages, but then, also exists and may not satisfy the brightness of hair or the problem of dyeing.In order to tackle this problem, at present for example as the disclosed pair of preparation formula in the patent documentation 2 (
) the cystose hair coloring preparation composition like this, attempted the cooperation higher alcohol.
But, if cooperate higher alcohol, particularly straight chain type higher alcohol, then by with form the preparation of emulsion type with the interaction of surfactant that must composition as bubbling, therefore different with the material of the such aerosol type of the cystose hair coloring preparation composition of patent documentation 2, hair dye for the non-aerosol type, be difficult to from the non-aerosol foaming vessel, discharge, be difficult to form the bubble of high-quality.Further, if cooperate aqueous higher alcohol, then owing to its froth breaking effect is easy to produce drippage from the hair.Owing to above reason, and exist the use level be difficult to increase higher alcohol to substantially improve the brightness of hair or the problem of dyeing.
Therefore, the problem that the present invention should solve is to provide hair cosmetic composition, it is as hair dye or hair depigmenting agent and constitute, can be discharged with the blister dosage form by the non-aerosol foaming vessel, wherein, by surfactant and the higher alcohol of correctly selecting to cooperate, can give hair good brightness, the dyeing excellence of hair, and drippage not when being applied to hair.
(formation of the 1st invention)
In order to solve above-mentioned problem, the formation of the application's the 1st invention is cosmetic hair composition, it is as hair dye or hair depigmenting agent and constitute, during use the mixed liquor of the 1st preparation and the 2nd preparation is discharged with blister from the non-aerosol foaming vessel, and be applied to hair, wherein, contain above (A) composition of 10 quality %: nonionic surfactant, and contain following (B1) composition conduct (B) composition: higher alcohol
(B1) be to be aqueous higher alcohol at 25 ℃.
In the 1st above-mentioned invention, " more than the 10 quality % " refer to " the 1st preparation and the 2nd preparation are more than the 10 quality % when mixing ".Similarly, in present specification, limit the short of special explanation of numerical value of the content of certain composition, all refer to " content when the 1st preparation and the 2nd preparation mix ".
In addition, for higher alcohol, " being aqueous at 25 ℃ " is even refer to that this higher alcohol is at 25 ℃ of fluids that can not keep specific spatial form in the short time.
(formation of the 2nd invention)
In order to solve above-mentioned problem, the formation of the application's the 2nd invention is the cosmetic hair composition of above-mentioned the 1st invention, and wherein, (B1) composition is the higher alcohol of branched chain type.
(formation of the 3rd invention)
In order to solve above-mentioned problem, the formation of the application's the 3rd invention is the cosmetic hair composition of above-mentioned the 1st invention or the 2nd invention, and it is that oxide hair dye, acid hair dye, hair depigmenting agent or hair take off stain.
(formation of the 4th invention)
In order to solve above-mentioned problem, the formation of the application's the 4th invention is the using method of cosmetic hair composition, and it is discharged from the non-aerosol foaming vessel each described cosmetic hair composition in the 1st invention～the 3 invention with blister, and is applied to hair.
(formation of the 5th invention)
In order to solve above-mentioned problem, the formation of the application the 5th invention is the hair cosmetic product, and it contains each described cosmetic hair composition in the 1st invention～the 3 invention and is used for the non-aerosol foaming vessel that this cosmetic hair composition is discharged with blister and constitutes.
(formation of the 6th invention)
In order to solve above-mentioned problem, the formation of the application's the 6th invention is cosmetic hair composition, it is as hair dye or hair depigmenting agent and constitute, during use the mixed liquor of the 1st preparation and the 2nd preparation is discharged with blister from the non-aerosol foaming vessel, and be applied to hair, wherein, contain following (A1) composition and (A2) composition as (A) composition: nonionic surfactant, and contain following (B1) composition and (B2) composition as (B) composition: higher alcohol.
(A1) the EO number is 2～10 the interior POE alkyl ether of scope,
(A2) the EO number is 11～150 the interior POE alkyl ether of scope,
(B1) be aqueous higher alcohol at 25 ℃,
(B2) myristyl alcohol.
In above-mentioned the 6th invention, " POE " is the abbreviation commonly used of " polyoxyethylene ", and for " POE alkyl ether ", " EO number " refers to the unit number of the ethylene oxide (EO) of the polyoxyethylene part in this POE alkyl ether.
In addition, for higher alcohol, " being aqueous at 25 ℃ " is even refer to that this higher alcohol is at 25 ℃ of fluids that can not keep specific spatial form in the short time.
(formation of the 7th invention)
In order to solve above-mentioned problem, the formation of the application's the 7th invention is the cosmetic hair composition of above-mentioned the 6th invention, wherein, (A1) composition and (A2) composition be the POE alkyl ether of straight chain type.
(formation of the 8th invention)
In order to solve above-mentioned problem, the formation of the application's the 8th invention is the cosmetic hair composition of above-mentioned the 6th invention or the 7th invention, and wherein, (A1) composition is that HLB is more than 5 and less than 14 material, and (A2) composition is that HLB is more than 14 and less than 19 material.
In the 8th invention, " HLB " is hydrophile-lipophile balance: the abbreviation of Hydrophile-Lipophile Balance, generally be the hydrophilic that has of the molecule of presentation surface activating agent and the parameter of oil loving relative intensity, the HLB value is more big, then hydrophilic is more strong, the HLB value is more little, and then lipophile is more strong.The HLB value can be calculated by known formula Griffin.
(formation of the 9th invention)
In order to solve above-mentioned problem, the formation of the application's the 9th invention is each described cosmetic hair composition in above-mentioned the 6th invention～the 8 invention, and it is that oxide hair dye, acid hair dye, hair depigmenting agent or hair take off stain.
(formation of the 10th invention)
In order to solve above-mentioned problem, the formation of the application's the 10th invention is the using method of cosmetic hair composition, and it is discharged from the non-aerosol foaming vessel each described cosmetic hair composition in the 6th invention～the 9 invention with blister, and is applied to hair.
(formation of the 11st invention)
In order to solve above-mentioned problem, the formation of the application the 10th invention is the hair cosmetic product, and it contains each described cosmetic hair composition in the 6th invention～the 9 invention and is used for the non-aerosol foaming vessel that this cosmetic hair composition is discharged with blister and constitutes.
According to the 1st invention, hair cosmetic composition can be provided, it constitutes as hair dye or hair depigmenting agent, discharged with the blister dosage form by the non-aerosol foaming vessel, wherein, can give hair good brightness, the dyeing excellence of hair, and when being applied to hair not drippage (
).It is reason as described below that the reason that obtains this effect is inferred.
When in the hair cosmetic composition of non-aerosol type that with the surfactant is foaming agent, cooperating higher alcohol, can expect the brightness of hair or the improvement of dyeing, but produce following shortcoming as mentioned above: the preparation that forms emulsion type, be difficult to obtain good bubble, and then when hair is coated with, be easy to produce drippage.
But, in the hair cosmetic composition of the 1st invention, as (B) composition, cooperate (B1) composition, should (B1) composition be when using usually as hair cosmetic composition temperature, be assumed to be under 25 ℃ the temperature and be aqueous higher alcohol.This higher alcohol with compare at 25 ℃ of higher alcohols for solid shape or pasty state, the first, not inferior improving on the effect of the brightness of hair or dyeing, the second owing to be aqueous, thereby the preparation of the solvable system that formation is easy to discharge.
Then, be aqueous higher alcohol even be engaged in 25 ℃, surely be caused producing the possibility of hair cosmetic composition drippage by its froth breaking effect, but for this point, in the hair cosmetic composition of the 1st invention, contain the above nonionic surfactant as (A) composition of 10 quality % and be used as foaming agent.
(A) composition has and can generate the bubble that is difficult to froth breaking and stimulate few such speciality.Therefore, cooperate above (A) composition of 10 quality %, can stimulate on few basis, generate the fully bubble of amount, and the froth breaking effect that can resist (B1) composition, and generate the bubble that is difficult to froth breaking.By above (A) composition and (B1) effect of composition, can give hair good brightness, the dyeing excellence of hair is formed on the hair cosmetic composition that does not have drippage when being applied to hair.
And, when the content of (A) composition is less than 10 quality % in the cosmetic hair composition, be easy to cause drippage during the hair cosmetic composition of application blister dosage form.
For the higher alcohol as (B1) composition, the higher alcohol of the branched chain type that the 2nd invention limits can be brought into play particularly preferred effect.
According to the 3rd invention, can be provided as the particularly preferred embodiment of cosmetic hair composition, oxide hair dye, acid hair dye, hair depigmenting agent or hair take off stain.
According to the 4th invention, can provide the effective ways of cosmetic hair composition being discharged and is applied to hair from the non-aerosol foaming vessel with good blister.
According to the 5th invention, easy hair cosmetic product can be provided, it contains cosmetic hair composition and is used for making this cosmetic hair composition to constitute with the non-aerosol foaming vessel of blister discharge.
According to the 6th invention, (B2) composition that has special effect with the higher alcohol as straight chain type: the cooperation of myristyl alcohol is prerequisite, can expect following effect.That is, can provide hair cosmetic composition, it constitutes as hair dye or hair depigmenting agent, discharged with the blister dosage form by the non-aerosol foaming vessel, as the excellent dispersion of the myristyl alcohol of (B2) composition, can give hair good brightness, the dyeing of hair is also excellent.It is reason as described below that the reason that obtains this effect is inferred.
As mentioned above, when in the hair cosmetic composition of non-aerosol type that with the surfactant is foaming agent, cooperating as the higher alcohol of straight chain type but during the short myristyl alcohol of alkyl chain, can improve brightness or the dyeing of hair, also can constitute the preparation of solvable system or disperse system, but be difficult to make myristyl alcohol to disperse well, be difficult to obtain good bubble.
But, in the hair cosmetic composition of the 6th invention, with the myristyl alcohol as (B2) composition, cooperate as (A1) composition, the EO number is few (relatively, lipophile is strong) the POE alkyl ether as nonionic surfactant, and cooperate as the POE alkyl ether as nonionic surfactant (A2) composition, EO number many (relatively, hydrophilic is strong), so cooperate conduct (B1) composition, be aqueous higher alcohol at 25 ℃.Therefore, improved the dispersibility of myristyl alcohol in the preparation of solvable system or disperse system.
And, generally have stimulation less and generate the characteristic of the bubble that is difficult to froth breaking as (A1), (A2) two compositions of nonionic surfactant.Therefore, (A1), (A2) two compositions can resist as the reverse side of the above-mentioned preferred effect of (B1) composition of higher alcohol, worrying froth breaking effect, generate the bubble that is difficult to froth breaking.
According to the 7th invention since (A1) composition and (A2) composition be the POE alkyl ether of straight chain type, therefore can particularly preferably bring into play above-mentioned (A1) composition and (A2) effect of composition.
According to the 8th invention, (A1) composition and (A2) composition be defined as the material with the HLB value in the particular range respectively, therefore can more preferably bring into play above-mentioned (A1) composition and (A2) effect of composition.
According to the 9th invention, can be provided as the particularly preferred embodiment of cosmetic hair composition, oxide hair dye, acid hair dye, hair depigmenting agent or hair take off stain.
According to the 10th invention, can provide the effective ways of cosmetic hair composition being discharged and is applied to hair from the non-aerosol foaming vessel with good blister.
According to the 11st invention, easy hair cosmetic product can be provided, it contains cosmetic hair composition and is used for making this cosmetic hair composition to constitute with the non-aerosol foaming vessel of blister discharge.
The specific embodiment
Then, implement mode of the present invention for being used for, describe in the mode that comprises its preferred forms.
In the following description, the 1st invention～the 5 invention is referred to as " the 1st invention group ", the 6th invention～the 11 invention is referred to as " the 6th invention group ".When being called " the present invention " simply, refer to whole the 1st invention～the 11 inventions.
(cosmetic hair composition)
When cosmetic hair composition of the present invention is to use the mixed liquor of the 1st preparation and the 2nd preparation is discharged with blister from the non-aerosol foaming vessel, and be applied to the compositions of hair.In the cosmetic hair composition of the 1st invention group, as essential composition, contain the above nonionic surfactant of 10 quality % as (A) composition, and contain at 25 ℃ and be aqueous higher alcohol as (B1) composition.In the cosmetic hair composition of the 6th invention group, as essential composition, the EO number that contains EO number as (A1) composition and be POE alkyl ether in 2～10 scopes, conduct (A2) composition be in 11～150 scopes POE alkyl ether, conduct (B1) composition be aqueous higher alcohol and the myristyl alcohol of conduct (B2) composition at 25 ℃.
Cosmetic hair composition of the present invention is two preparation formulas, also comprise with the 1st preparation (
) and/or the 2nd preparation (
) further be divided into the modes that many group preparations constitute.
In the cosmetic hair composition as the 1st invention group of two preparation formulas, (A) composition and (B1) composition is unqualified basically to the fit system in the 1st preparation and the 2nd preparation can at random be selected.For example (A) composition can be engaged in any one of the 1st preparation and the 2nd preparation, also can disperse to be engaged in the 1st preparation and the 2nd preparation in the two, so that the 1st preparation and the 2nd preparation use level when mixing is more than the 10 quality %.In addition, (B1) composition can be engaged in any one of the 1st preparation and the 2nd preparation, also can disperse to be engaged in the 1st preparation and the 2nd preparation in the two.
Even for the cosmetic hair composition of the 6th invention group of two preparation formulas, similarly, (A) composition～(D) composition is also unqualified basically to the fit system in the 1st preparation and the 2nd preparation.
(dosage form of cosmetic hair composition etc.)
The 1st preparation in the cosmetic hair composition of the present invention of two preparation formulas and the dosage form of the 2nd preparation before foaming limit especially, for example can exemplify solid, shaped, water-soluble aqueous, disperse aqueous, emulsion shape, gel, cystose and paste.The dosage form of solid, shaped can be enumerated for example Powdered and tablet.When being the dosage form of solid, shaped, consider from the angle of excellent dispersion when mixing the 1st preparation and the 2nd preparation, be preferably Powdered.And when for example making the 1st preparation be the dosage form of solid, shaped, the 2nd preparation is the preparation that contains water.Wherein, preferably when being mixed, the 1st preparation of cosmetic hair composition and the 2nd preparation can guarantee mobile dosage form, the compositions of special preferably solvable system or disperse system.
In addition, for cosmetic hair composition, at least one of the 1st preparation and the 2nd preparation, contain water and be used as for the substrate of bubbling.The content of water is preferably more than the 40 quality %, more preferably more than the 50 quality %.
((A) composition that in the cosmetic hair composition of the 1st invention group, cooperates)
(A) composition that cooperates in the cosmetic hair composition of the 1st invention group is nonionic surfactant.(A) use level of composition is more than the 10 quality %, in the scope particularly preferably in 11 quality %～25 quality %.(A) upper limit of the use level of composition is unqualified, for example can be limited to below the 50 quality %.
The content of (A) composition in the cosmetic hair composition, unqualified with respect to the mass ratio A/B1 of the content of following (B1) composition, preferably in 1～500 scope, particularly preferably in 5～100 the scope.When mass ratio A/B1 less than 1 the time, might be difficult to guarantee to utilize the non-aerosol foaming vessel and generate good bubble, and when being applied to hair, might produce drippage.When mass ratio A/B1 surpassed 500, brightness that might hair or the improvement of dyeing became insufficient.
Nonionic surfactant as (A) composition can be enumerated following material, but is not limited thereto.Nonionic surfactant can use a kind separately, also can will also use more than 2 kinds.Especially, and if be that nonionic activating agent more than 14 and HLB are more than 5 and less than 14 nonionic activating agent, then stability of formulation is good with HLB.HLB(hydrophile-lipophile balance: Hydrophile-Lipophile Balance) can be calculated by known formula Griffin.
1. the POE alkyl ether of polyoxyethylene (being designated hereinafter simply as POE) cetyl ether, POE stearyl ether, POE mountain Yu base ether, POE oleyl ether, POE lauryl ether, POE tridecyl ether, POE octyl group lauryl ether, POE hexyl decyl ethers, POE iso stearyl ether, POE decyl pentadecyl ether, POE decyl myristyl ether, POE alkyl (C12～14) ether etc.
2.POE the POE alkyl phenyl ether of nonylplenyl ether, POE octyl phenyl ether etc.
3. the POE sorbitan fatty acid esters of single oleic acid POE sorbitan ester, monostearate POE sorbitan ester, single Palmic acid POE sorbitan, mono laurate POE sorbitan ester, three oleic acid POE sorbitan esters etc.
4. the POE fatty acid monoglyceride of monostearate POE glyceride, single myristic acid POE glyceride etc.
5. the POE Sorbitol fatty acid ester of four oleic acid POE sorbitol esters, six stearic acid POE sorbitol esters, mono laurate POE sorbitol ester, POE Sorbitol Cera Flava etc.
6.POE hardened castor oil, POE Oleum Ricini.
7. single oleic acid macrogol ester, monostearate macrogol ester, mono laurate macrogol ester.
8. the higher fatty acids glyceride of lipophilic glyceryl monooleate, lipophilic glyceryl monostearate, self-emulsifying type glyceryl monostearate etc.
9. the sorbitan fatty acid esters of single oleic acid sorbitan ester, sesquialter oleic acid sorbitan ester, three oleic acid sorbitan esters, monostearate sorbitan ester, single Palmic acid sorbitan ester, mono laurate sorbitan ester etc.
10.POE the lanolin derivative of lanoline, POE lanolin alcohol, POE Sorbitol lanoline etc.
11. the alkanolamide of lauric acid diethyl amide, fatty acid distribution of coconut oil diglycollic amide etc.
12.POE the POE fatty acid amide of stearmide etc.
13. sucrose fatty acid ester.
14. the alkyl amine oxide of dimethyllaurylamine oxide etc.
15. the alkyl androstanediol of lauryl glucoside, alkyl (8～16) glucoside etc.
16. lecithin derivant hydrogenated soy phosphatidyl choline, hydrogenated yolk lecithin etc.
17.POE the POEPOP alkyl ether of polyoxypropylene (being designated hereinafter simply as POP) cetyl ether etc.
((A1) composition that in the cosmetic hair composition of the 6th invention group, cooperates, (A2) composition)
(A1) composition that cooperates in the cosmetic hair composition of the 6th invention group is that the EO number is the POE alkyl ether in 2～10 the scope, and (A2) composition is that the EO number is the POE alkyl ether in 11～150 the scope.Preferred these (A1) compositions and (A2) composition be the POE alkyl ether of straight chain type, in addition, preferred (A1) composition is that HLB is more than 5 and less than 14 material, (A2) composition is that HLB is more than 14 and less than 19 material.
(A1) composition in the cosmetic hair composition and (A2) the restriction especially of use level of composition, preferably the use level of (A1) composition is 0.1～10 quality %, (A2) use level of composition is about 0.1～20 quality %, and preferred (A1) composition and (A2) aggregate values of the use level of composition be below the 30 quality %.Numerical value for above use level, (A1) composition and/or (A2) composition disperse, be matched with the aggregate values that refers to use level in the mode of the 1st preparation and the 2nd preparation, (A1) composition and (A2) components matching in the mode of arbitrary preparation of the 1st preparation and the 2nd preparation, refer to the use level of said preparation.
As be equivalent to (A1) composition, the EO number is the POE alkyl ether in 2～10 the scope, and is unqualified, the special preferably POE alkyl ether of straight chain type.As its object lesson, can enumerate POE(3) alkyl (C12～14) ether, namely, the carbon number of alkyl skeleton is 12～14 material (the HLB value is 7.7～8.4), or POE(5) alkyl (C12～14) ether (the HLB value is 10.2～10.9), POE(9) lauryl ether (the HLB value is 13.7), POE(9) tridecyl ether (the HLB value is 13.3) can also be enumerated POE(2 in addition) lauryl ether (the HLB value is 6.5), POE(3) lauryl ether (the HLB value is 8.4), POE(5) lauryl ether (the HLB value is 10.9), POE(7) lauryl ether (the HLB value is 12.5), POE(3) myristyl ether (the HLB value is 7.7), POE(5) myristyl ether (the HLB value is 10.2), POE(7) myristyl ether (the HLB value is 11.8), POE(2) cetyl ether (the HLB value is 5.3), POE(5) cetyl ether (the HLB value is 9.5), POE(5.5) cetyl ether (the HLB value is 10), POE(10) cetyl ether (the HLB value is 12.9), POE(2) stearyl ether (the HLB value is 4.9), POE(4) stearyl ether (the HLB value is 7.9), POE(10) stearyl ether (the HLB value is 12.4), POE(3) oleyl ether (the HLB value is 6.6), POE(10) oleyl ether (the HLB value is 12.4) etc.(A1) composition can use a kind separately, also can will also use more than 2 kinds.Wherein, especially preferred HLB is more than 5 and less than 14 material.
As be equivalent to (A2) composition, the EO number is the POE alkyl ether in 11～150 the scope, and is unqualified, preferred especially straight chain type POE alkyl ether.As its object lesson, can enumerate POE(15) cetyl ether (the HLB value is 14.6), POE(21) lauryl ether (the HLB value is 16.7), POE(150) stearyl ether (the HLB value is 19.2) can also be enumerated POE(11 in addition) lauryl ether (the HLB value is 14.5), POE(20) cetyl ether (the HLB value is 15.7), POE(30) cetyl ether (the HLB value is 16.9), POE(40) cetyl ether (the HLB value is 17.6), POE(20) stearyl ether (the HLB value is 15.3), POE(150) stearyl ether (the HLB value is 19.2), POE(30) mountain Yu base ether (the HLB value is 16), POE(150) mountain Yu base ether (the HLB value is 19.1), POE(40) oleyl ether (the HLB value is 17.4), POE(45) oleyl ether (the HLB value is 17.6), POE(50) oleyl ether (the HLB value is 17.8) etc.(A2) composition can use a kind separately, also can will also use more than 2 kinds.Wherein, especially preferred HLB is more than 14 and less than 19 material.
((A1), the nonionic surfactant beyond (A2) composition)
And, for the cosmetic hair composition of the 6th invention group, can be at the range fit that does not hinder the invention effect above-mentioned (A1), (A2) composition nonionic surfactant in addition.As this nonionic surfactant, the various POE alkyl ethers except can enumerating (A1), (A2) composition can also be enumerated following substances.
1.POE the POE alkyl phenyl ether of nonylplenyl ether, POE octyl phenyl ether etc.
2. the POE sorbitan fatty acid esters of single oleic acid POE sorbitan ester, monostearate POE sorbitan ester, single Palmic acid POE sorbitan ester, mono laurate POE sorbitan ester, three oleic acid POE sorbitan esters etc.
3. the POE glyceryl mono fatty acid ester of monostearate POE glyceride, single myristic acid POE glyceride etc.
4. the POE Sorbitol fatty acid ester of four oleic acid POE sorbitol esters, six stearic acid POE sorbitol esters, mono laurate POE sorbitol ester, POE Sorbitol Cera Flava etc.
5.POE hardened castor oil, POE Oleum Ricini.
6. single oleic acid macrogol ester, monostearate macrogol ester, mono laurate macrogol ester.
7. the higher fatty acids glyceride of lipophilic glyceryl monooleate, lipophilic glyceryl monostearate, self-emulsifying type glyceryl monostearate etc.
8. the sorbitan fatty acid esters of single oleic acid sorbitan ester, sesquialter oleic acid sorbitan ester, three oleic acid sorbitan esters, monostearate sorbitan ester, single Palmic acid sorbitan ester, mono laurate sorbitan ester etc.
9.POE the lanolin derivative of lanoline, POE lanolin alcohol, POE Sorbitol lanoline etc.
10. the alkylolamides of lauric acid diethyl amide, fatty acid distribution of coconut oil diglycollic amide etc.
11.POE the POE fatty acid amide of stearmide etc.
12. sucrose fatty acid ester.
13. the alkyl amine oxide of dimethyl lauryl amine oxide etc.
14. the alkyl androstanediol of lauryl glucoside, alkyl (8～16) glucoside etc.
15. lecithin derivant hydrogenated soy phosphatidyl choline, hydrogenated yolk lecithin etc.
16.POE the POEPOP alkyl ether of polyoxypropylene (being designated hereinafter simply as POP) cetyl ether etc.
(A1), the use level of the nonionic surfactant beyond (A2) composition is preferably 0.1～30 quality %.
((A) surfactant beyond the composition)
And, under the scope that does not hinder the invention effect, for the cosmetic hair composition of the present invention of the 1st invention group or the 6th invention group, except above-mentioned nonionic surfactant, can also cooperate the surfactant of other kinds arbitrarily.The surfactant of these other kinds can be enumerated cationic surfactant, anionic surfactant, amphoteric surfactant.
Cationic surfactant can be enumerated for example lauryl trimethyl ammonium chloride; cetyl trimethyl ammonium chloride (Cetrimonium Chloride); stearyl trimethyl ammonium chloride (Stearyl trimonium Chloride); alkyl trimethyl ammonium chloride; mountain Yu base trimethyl ammonium chloride (Behentrimonium Chloride); VARISOFT TA100 (Distearyldimonium Chloride); two cocoyl alkyl dimethyl ammonium chlorides; the cetyl trimethylammonium bromide; the stearyl trimethylammonium bromide; ethyl sulfuric acid lanoceric acid aminopropyl ethyl Dimethyl Ammonium; stearyl trimethyl ammonium glucide hydrochlorate; cetyl trimethyl ammonium glucide hydrochlorate; mountain Yu base trimethyl ammonium Methylsulfate and quaternary ammonium salt-91 etc., but be not limited thereto.Cationic surfactant can use a kind separately, but considers from the aspect of foaming characteristic and sense of touch, preferably will also use more than 2 kinds.The use level of cationic surfactant is preferably 0.1～10 quality %.
The anionic surfactant can enumerate for example alkyl ether sulfate of POE sodium laureth sulfate etc.; sodium lauryl sulfate; sodium cetostearylsulphate; the alkyl sulfate of cetyl sodium sulfate etc.; alkene ether sulfate; alkenyl sulfate; alkene sulfonate; alkane sulfonate; saturated or unsaturated fatty acid salt; the alkyl or alkenyl ether carboxylate; α-alpha-sulfonated fatty hydrochlorate; the N-acyl amino acid type surfactant of cocoyl glutamic acid triethanolamine (cocoyl glutamic acid TEA) etc.; mono phosphoric acid ester or diester type surfactant; with sulfosuccinate etc.As the equilibrium ion of the anion base of these surfactants, can enumerate for example sodium ion, potassium ion and triethanolamine.Anionic surfactant's use level is preferably 0.05～10 quality %.
Amphoteric surfactant can be enumerated following material.
1. fatty acid amide propyl-dimethyl glycine betanin and their sodium salt, potassium salt or the triethanolamine salt of fatty acid distribution of coconut oil amido propyl dimethylaminoethyl acid betanin, palm oil fatty acid amido propyl dimethylaminoethyl acid betanin, dodecanamide propyl dimethylaminoethyl acid betanin (dodecanamide propyl betanin), ricinoleic acid amide propyl-dimethyl glycine betanin etc.
2. alkyl dimethyl glycine betanin and their sodium salt, potassium salt or the triethanolamine salt of decyl dimethylaminoethyl acid betanin, lauryl dimethyl glycine betanin, myristyl dimethylaminoethyl acid betanin, cetyl dimethylaminoethyl acid betanin, stearyl dimethylaminoethyl acid betanin, oil base dimethylaminoethyl acid betanin, mountain Yu base dimethylaminoethyl acid betanin, cocos nucifera oil alkyl dimethyl glycine betanin etc.
3. cocos nucifera oil acyl both sexes guanidine-acetic acid sodium (N-fatty acid distribution of coconut oil acyl group-N '-carboxymethyl-N '-hydroxyethylethylene diamine); cocos nucifera oil acyl both sexes base sodium propionate (N-fatty acid distribution of coconut oil acyl group-N '-carboxyethyl-N '-hydroxyethylethylene diamine); lauroyl both sexes guanidine-acetic acid sodium (N-lauroyl-N '-carboxymethyl-N '-hydroxyethylethylene diamine); Fructus Canarii albi oleoyl both sexes guanidine-acetic acid sodium; cocoa acyl both sexes guanidine-acetic acid sodium; Semen Sesami oleoyl both sexes guanidine-acetic acid sodium; Prunus dulcis oleoyl both sexes guanidine-acetic acid sodium; stearoyl both sexes guanidine-acetic acid salt; palmitoleoyl both sexes guanidine-acetic acid sodium; Semen arachidis hypogaeae oleoyl both sexes guanidine-acetic acid sodium; heronsbill seed oleoyl both sexes guanidine-acetic acid sodium; the N-acyl amino ethyl-N-2-hydroxyethyl aminocarboxylate of Semen Gossypii oleoyl both sexes guanidine-acetic acid sodium etc.
4. the N-acyl amino ethyl-N-carboxymethoxyl ethylamino carboxylate of cocos nucifera oil acyl both sexes base sodium diacelate, cocos nucifera oil acyl both sexes base dipropionic acid and lauroyl both sexes base sodium diacelate etc.
5. hydroxy alkyl (C12-14) hydroxyethyl sarcosine.
The use level of amphoteric surfactant is preferably 0.05～10 quality %.
((B1) composition)
Being engaged in (B1) composition in the cosmetic hair composition of the 1st invention group and the 6th invention group, is to be aqueous higher alcohol at 25 ℃.The meaning that " is aqueous at 25 ℃ " as mentioned above, " higher alcohol " refers to that carbon number is the monobasic aliphatic alcohol more than 6, comprises the senior aliphat alcohol of saturated or unsaturated, straight chain type or branched chain type.
(B1) carbon number of composition is particularly preferably in 10～24 the scope.As the structure of the carbon skeleton of (B1) composition, special preferably straight chain type or the unsaturated senior aliphat alcohol of branched chain type and the saturated senior aliphat alcohol of branched chain type.(B1) use level of composition is unqualified.But above-mentioned use level is preferably in the cosmetic hair composition of the 1st invention group, in the scope for mass ratio A/B1.In addition, in cosmetic hair composition of the present invention, (B1) use level of composition is preferably in the scope of 0.01～10 quality %, in the scope of preferred especially 0.1～5 quality %.
Be in the aqueous higher alcohol at 25 ℃, as the representative examples of saturated aliphatic alcohol of straight chain type, can enumerate lauryl alcohol.As the representative examples of saturated aliphatic alcohol of branched chain type, can enumerate 2-octyldodecanol, isooctadecanol, hexyldecanol, decyl tetradecyl alchohol etc.In addition, the unsaturated aliphatic alcohol as straight chain type or branched chain type can exemplify oleyl alcohol, inferior oleyl alcohol etc.
((B2) composition)
(B2) composition that cooperates in the cosmetic hair composition of the 6th invention group is myristyl alcohol.The use level of (B2) composition does not limit especially in the cosmetic hair composition, is preferably 0.01～2.0 quality %, preferred especially 0.02～1 quality %.If (B2) use level of composition is less than 0.01 quality %, then the brightness of hair or dyeing improves effect and might become insufficient, if surpass 2.0 quality %, then hair cosmetic composition is difficult to form the preparation of solvable system or disperse system, therefore might be difficult to obtain good bubble.Numerical value for above use level, disperse, be matched with the aggregate values that refers to use level in the mode of the 1st preparation and the 2nd preparation at (B2) composition, in the mode of arbitrary preparation of the 1st preparation and the 2nd preparation, refer to the use level of said preparation in (B2) components matching.
((B1) higher alcohol beyond composition, (B2) composition)
Under the scope that does not hinder the invention effect, the cosmetic hair composition of the 1st invention group can cooperate as the higher alcohol higher alcohol beyond above-mentioned (B1) composition, pasty state or solid, shaped, namely, be not aqueous at 25 ℃, can keep the higher alcohol of specific spatial form in short time or long time.
As this higher alcohol, can enumerate myristyl alcohol, spermol, stearyl alcohol, 16 octadecanol, tadenan, EICOSANOL, lanolin alcohol etc.
Under the scope that does not hinder the invention effect, the cosmetic hair composition of the 6th invention group can cooperate the higher alcohol beyond above-mentioned (B1) composition, (B2) composition.As this higher alcohol, can enumerate spermol, stearyl alcohol, 16 octadecanol, tadenan, EICOSANOL, lanolin alcohol etc.
(kind of cosmetic hair composition)
Cosmetic hair composition of the present invention is unqualified, for example can be used as oxide hair dye, acid hair dye, hair depigmenting agent or hair and takes off stain and constitute.Especially preferably constitute as oxide hair dye or hair depigmenting agent.
(oxide hair dye)
Oxide hair dye comprises the 1st preparation that contains basic species and oxidation dye and the 2nd preparation that contains oxidant, and its melanin with hair decomposes, and utilization is had hair dyed by the oxidation polymerization of the oxidation dye of oxidant generation.Oxidation dye is categorized as dyestuff intermediate and coupling agent.Also can cooperate the direct dyes of basic stain, nitro dye, natural dye, disperse dyes etc. to replace oxidation dye.
Dyestuff intermediate can be enumerated for example phenylenediamine, aminophenols, diaminotoluene class, diphenyl amine, diamino-phenyl amine, N-phenyl phenylenediamine, diamino-pyridine class and their salt.Salt can be enumerated hydrochlorate, sulfate and acetate etc.
Coupling agent is that the chemical compound of color development can be contained in the 1st preparation as required by the combination dye intermediate.Coupling agent can be enumerated for example resorcinol, pyrogallol, catechol, m-aminophenol, m-diaminobenzene., 2,4-diaminophenol, 1,2,4-benzene triol, Toluene-3,4-dithiol, 4-diamidogen, Toluene-2,4-diisocyanate, 4-diamidogen, hydroquinone, α-naphthalene alcohol, 2,6-diamino-pyridine, 1,5-dihydroxy naphthlene, the amino orthoresol of 5-, p-methylaminophenol, 2,4-diamino phenoxy ethanol, gallic acid, tannic acid, progallin A, gallicin, propyl gallate, Galla Chinensis, 5-(2-hydroxyethyl amino)-2-methylphenol and their salt.
The content of the dyestuff intermediate in the oxide hair dye is preferably 0.01～10 quality %, more preferably 0.1～5 quality %.The content of dyestuff intermediate might can not obtain sufficient dyeability during less than 0.01 quality %.Even the content of dyestuff intermediate surpasses 10 quality %, dyeability does not have bigger raising yet, thereby the economy of hair dyeing might reduce.
The 1st preparation can suitably contain at least a of the oxidation dye of record in " the medicine part outer article raw material Regulations lattice " that for example are selected from Japan (in June, 2006 distribution, medicine thing day newspaper office) and direct dyes, is used as the dyestuff beyond the above-mentioned oxidation dye.
Basic species makes the hair swelling simultaneously by promoting to be contained in the effect of the oxidant in the 2nd preparation, increases dyestuff for the impregnability of hair, and dyeability is improved.Basic species can be enumerated for example ammonia, alkanolamine, organic amine, inorganic base, basic amino acid and sulfate.Organic amine can be enumerated for example 2-amino-2-methyl-1, ammediol and guanidine.Inorganic base can be enumerated for example sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, ammonium carbonate, sodium bicarbonate and ammonium bicarbonate.Basic amino acid can be enumerated for example arginine and lysine and alkaline amino acid salt.The salt of basic amino acid can be enumerated for example ammonium salt.Sulfate can be enumerated ammonium sulfate.
The content of basic species is that to make pH be the amount of 7～12 scopes preferably in the oxide hair dye that has mixed the 1st preparation and the 2nd preparation.If when pH less than 7, then contains as the hydrogen peroxide of oxidant, can not fully promote the effect of hydrogen peroxide in the 2nd preparation.If the pH when using surpasses 12, when then being coated on oxide hair dye on the hair, the shortcoming that might take place that hair sustains damage easily etc.
The 2nd preparation contains oxidant at least.Oxidant makes oxidation dye carry out oxidation polymerization and color development.Oxidant can be enumerated for example hydrogen peroxide adduct of hydrogen peroxide adduct, phosphatic hydrogen peroxide adduct and the pyrophosphate of hydrogen peroxide, urea peroxide, peroxidating tripolycyanamide, SODIUM PERCARBONATE, potassium percarbonate, Dexol, potassium perborate, sodium peroxide, potassium peroxide, Magnesium dioxide, Barium dioxide, calper calcium peroxide, strontium peroxide, sulfate.
The content of oxidant is preferably 0.1～10.0 quality % in the 2nd preparation, more preferably 0.5～8.0 quality %.The content of oxidant might be difficult to make oxidation dye fully to carry out oxidation polymerization during less than 0.1 quality %.When the content of oxidant surpasses 10.0 quality %, might damage hair easily.
(acid hair dye)
Acid hair dye is generally single preparation formula, and fluidity is the acidity about pH2.5～4.0, and it is for the hair that has cationic, can make acid stain carry out the material of ions binding.Acid stain can be enumerated for example nitro dye, azo dye, nitroso-dyes, triphenhlmethane dye, ton dyestuff, quinoline dye, anthraquinone dye, indigoid dye etc.
As acid stain, more specifically, can enumerate red No. 2, red No. 3, red No. 102, red No. 104, red No. 105, red No. 106, red No. 227, red No. 230, yellow No. 4, yellow No. 5, yellow No. 202, yellow No. 203, orange No. 205, orange No. 207, orange No. 402, green No. 3, green No. 204, green No. 401, No. 401, purple, blue No. 1, blue No. 2, blue No. 202, No. 201, brown, No. 401, black etc.
The content of the acid stain in the acid hair dye is 0.005～5 quality %, more preferably 0.01～3 quality %.
(hair depigmenting agent)
The hair depigmenting agent comprises the 1st preparation that contains basic species and the 2nd preparation that contains oxidant, and its melanin with hair decomposes, and hair is decoloured.The hair depigmenting agent is not except containing oxidation dye, and other has same formation with oxide hair dye basically.
(hair takes off stain)
Hair take off stain be generally the above many preparations formula of two preparations (
), its main purpose is to carry out taking off of hair to dye (decomposition of dying the dyestuff on hair), compare with the hair depigmenting agent, difference is to cooperate in the basic species in the 1st preparation, and then cooperates a kind of persulfate as basic species to be used as decoloring assistant.The 1st preparation is Powdered or graininess, lamellar etc., and the 2nd preparation is aqueous.
Persulfate is preferably enumerated the alkali metal salt of persulfuric acid, especially preferred potassium peroxydisulfate or sodium peroxydisulfate.The use level of persulfate is unqualified, preferably in the scope of 2.0～25 quality %, more preferably in the scope of 3.5～18 quality %.
(other composition in the cosmetic hair composition)
In the 1st preparation or the 2nd preparation of cosmetic hair composition, as required except mentioned component, can also suitably select to contain oiliness composition beyond the higher alcohol for example, macromolecular compound, chelating agen, inorganic salt, dispersant etc.
The oiliness composition can be enumerated for example silicone, oils and fats, wax, hydrocarbon, higher fatty acids, alkyl glycerylether, ester, polyhydric alcohol.
Dimethicone), have a dimethyl polysiloxane (INCI name: dimethiconol), methyl phenyl silicone, decamethylcyclopentaandoxane, ten diformazan basic rings, six siloxanes, polyether modified silicone, amino modified silicone, betanin modified silicone, alkyl-modified silicone, alkoxy-modified silicone, sulfhydryl modified silicone, carboxy-modified silicone, fluorine modified silicone etc. of C-terminal base silicone can be enumerated (the INCI name: of dimethyl polysiloxane for example.Polyether modified silicone can be enumerated POE methyl polysiloxane copolymer (PEG-10 dimethicone).
Oils and fats can be enumerated for example lanoline, olive oil, Chinese toon oil, shea butter, almond oil, safflower oil, Oleum helianthi, soybean oil, Oleum Gossypii semen, Oleum sesami, Semen Maydis oil, Oleum Brassicae campestris, Testa oryzae oil, rice germ oil, seed of Fructus Vitis viniferae oil, American Avocado Tree oil, macadimia nut oil, Oleum Ricini, cocos nucifera oil and Radix Oenotherae erythrosepalae oil.
Wax can be enumerated for example Cera Flava, candelilla wax, Brazil wax, Jojoba oil and lanoline.
Hydrocarbon can be enumerated for example paraffin, olefin oligomer, polyisobutylene, Parleam, mineral oil, squalane, polybutene, polyethylene, microwax and vaseline.
Higher fatty acids can be enumerated for example lauric acid, myristic acid, Palmic acid, stearic acid, mountain Yu acid, isostearic acid, 12-hydroxy stearic acid, oleic acid and lanoceric acid.
Alkyl glycerylether can be enumerated for example batilol .alpha.-hexadecylglyceryl ether, selachyl alcohol and iso stearyl glycerin ether.
Ester can be enumerated for example diisopropyl adipate, isopropyl myristate, Octanoic acid, hexadecyl ester, the different nonyl ester of different n-nonanoic acid, myristic acid octyl group dodecyl ester, isopropyl palmitate, the stearic acid stearyl, myristyl myristate, myristic acid isotridecyl ester, Palmic acid 2-Octyl Nitrite, castor oil acid octyl group dodecyl ester, carbon number is fatty acid cholesterol ester/lanosterol ester of 10～30, the lactic acid cetyl, the acetoxylation lanoline, two-2 ethyl hexanoic acid glycol ester, pentaerythritol fatty ester, the dipentaerythritol fatty acid ester, the capric acid cetyl, tricaprin, malic acid two different stearyl esters, dioctyl succinate and 2 ethyl hexanoic acid cetyl.
Polyhydric alcohol can be enumerated for example dihydroxylic alcohols and glycerol.Dihydroxylic alcohols can be enumerated for example ethylene glycol, diethylene glycol, triethylene glycol, Polyethylene Glycol, propylene glycol, dipropylene glycol, isoamyl two pure and mild 1,3 butylene glycols.Glycerol can be enumerated for example glycerol, two glycerol and polyglycereol.
As macromolecular compound, at first can enumerate water-soluble high-molecular compound.Water-soluble high-molecular compound for example can enumerate the natural series macromolecule, semi-synthetic be macromolecule, synthetic be macromolecule.
The high molecular object lesson of natural series can be enumerated arabic gum, carrageenan, galactan, guar gum, Semen Fructus Chaenomelis glue, locust bean gum, Tragacanth, pectin, mannan, starch, xanthan gum, glucosan, curdlan, succinoglycan, gelatin, collagen protein, casein, albumin, tamarind gum etc.
As semi-synthetic be high molecular object lesson, can enumerate the cellulose-based macromolecule of methylcellulose, ethyl cellulose, hydroxyethyl-cellulose, carboxymethyl cellulose, hydroxypropyl emthylcellulose, hydroxyethyl-cellulose dimethyl diallyl ammonium chloride, hydroxyethyl-cellulose hydroxypropyl-trimethyl ammonium chloride etc.; The starch of carboxymethyl starch, methyl starch, soluble starch etc. is macromolecule; The alginic acid of alginate, propylene glycol alginate etc. is macromolecule; The guar gum of JR-125 etc. is macromolecule etc.
As synthetic be high molecular object lesson, can enumerate the ethylene base system macromolecule of CVP Carbopol ETD2050, polyacrylamide, acrylic acid alkyl methacrylate copolymer, polyvinyl alcohol, polyvinyl pyrrolidone, quaternized polyvinyl pyrrolidone, polyvinyl methyl ether, sodium polyacrylate etc.; Polyethylene glycol oxide; The ethylene oxide oxypropylene block copolymer; The cationization thing of vinyl pyrrolidone dimethylaminoethyl methacrylic acid copolymer; The homopolymer of dimethyl diallyl ammonium chloride, the dimethyl diallyl ammonium chloride acrylamide copolymer, the QAS polymer derivant of dimethyl diallyl ammonium chloride acrylic copolymer etc., the alkyl acrylate copolymer emulsion, alkyl acrylate styrol copolymer emulsion, the acrylic acid series aqueous dispersed polymer of the polyxyethylated monoester copolymer emulsion of alkyl acrylate alkyl methacrylate polyoxyethylene (20) stearyl ether copolymer emulsion and alkyl acrylate itaconic acid etc. etc.
As macromolecular compound, other can enumerate the natural or synthetic macromolecular compound of anionic property macromolecular compound, cationic macromolecular compound and both sexes.
Chelating agen can be enumerated for example ethylenediaminetetraacetic acid (EDTA, edetic acid), hydroxyethylethylene diamine tri-acetic acid (HEDTA) and its salt, diethylenetriamine pentaacetic acid and its esters and hydroxyl ethane di 2 ethylhexyl phosphonic acid (HEDP, etidronic acid) and its esters.Inorganic salt can be enumerated for example sodium chloride, sodium sulfate.Dispersant can be enumerated for example magnesium stearate.
In the 1st preparation or the 2nd preparation of the cosmetic hair composition of the cosmetic hair composition of single preparation formula or two preparation formulas, other also can contain at least a in the material of record in " the medicine part outer article raw material Regulations lattice " that for example are selected from saccharide, antiseptic, stabilizing agent, pH regulator agent, plant extract, extracts from crude drugs, vitamins, spice and UV absorbent and Japan (in June, 2006 distribution, medicine thing day newspaper office).
(using method of cosmetic hair composition)
The using method of cosmetic hair composition of the present invention is that above-mentioned cosmetic hair composition is discharged with blister from the non-aerosol foaming vessel, and is applied to the method for hair.
As the non-aerosol foaming vessel, as long as for cosmetic hair composition, the container with function of the foaming that can carry out the non-aerosol type and discharge gets final product, and is unqualified.The following non-aerosol foaming vessel of preferred use bubbles.
(hair cosmetic product)
Hair cosmetic product of the present invention contains and forms the blister dosage form of non-aerosol type when using and be applied to the above-mentioned cosmetic hair composition of hair and be used for the non-aerosol foaming vessel that this cosmetic hair composition is discharged with blister and constitute.
As the representative example of non-aerosol foaming vessel, can enumerate pump foam maker or crushed foam generator.The pump foam maker is to carry out extrusion operation by the head to pump, accommodate the container that liquid (for example the 1st preparation of hair cosmetic composition/the 2nd preparation mixed liquor) is discharged with blister and make, wherein, accommodate the peristome that liquid mixes with air, is assemblied in container body with the bubble displacer of blister discharge with making.The pump foam maker is open in TOHKEMY 2007-275777 communique etc., is known.The crushed foam generator refers to following equipment, namely, by using finger the container body of soft synthetic resin system to be pushed (repeating to remove operation for squeeze operation and the compression of container), the same liquid and the air of accommodating imported foam maker with in the gas-liquid mixed chamber of discharging head and mix, and the bubble that utilizes the bubble displacer to form is discharged from nozzle.The crushed foam generator is recorded in the document " the new い of ヘ ア カ ラ ー skill Intraoperative Move is to (blister ヘ ア カ ラ ー skill Intraoperative Open send out-) " of TOHKEMY 2008-291024 communique or number publication magazine " Off レ グ ラ Application ス ジ ャ ー Na Le (Fragrance Journal) " in June, 2009 etc., is known.
The bubble displacer of non-aerosol foaming vessel has 1 or many perforated membrane that is used to form bubble.The material of perforated membrane can be enumerated nylon, polyester, polyethylene, polypropylene etc.The sieve mesh preference of perforated membrane is as being 50～300 sieve meshes.In addition, the mixing ratio of gas and liquid (gas-liquid mixed than) scope of gas/liquid=5/1～20/1 preferably.
Embodiment
Below embodiments of the invention and comparative example are described.Technical scope of the present invention is not limited to these embodiment and comparative example.
The embodiment of the 1st invention group
(formations of two preparation formula hair dyes)
Prepare shown in the following table 1 the example 1～example 3 of hair dye the 2nd preparation formed shown in the example 1～example 11 of hair dye the 1st preparation formed and the table 2, as as shown in " combination " hurdle of table 3, with these the 1st preparations and the combination of the 2nd preparation selectivity, constitute the two preparation formula hair dyes that relate in embodiment 1～embodiment 10, the comparative example 1～comparative example 3.
In table 1 and table 2, the numerical value of representing the component content of the 1st preparation or the 2nd preparation is not the content statement when the 1st preparation and the 2nd preparation are mixed, but is the content statement of unit with quality % in the 1st preparation or the 2nd preparation.(A) composition of the present invention for being equivalent to or (B1) composition of composition, the marge in the left side of table is expressed as " A " or " B1 ".The composition that the marge in left side at table is expressed as " B1 than " is represented the composition with respect to the relatively usefulness of (B1) composition.
In the table 3, the numeral that shows in the item of " the 1st preparation " in " combination " hurdle and " the 2nd preparation " is the example numbering of the 1st preparation shown in table 1 or the table 2 or the 2nd preparation.
(evaluations of two preparation formula hair dyes)
The ratio that the 1st preparation and the 2nd preparation of the various embodiments described above, each comparative example with the mass ratio is 1:1 is accommodated in the non-aerosol foaming vessel (pump foam maker), form mixed liquor, carry out extrusion operation by the head with this pump, above-mentioned mixed liquor is discharged with the infusion type.The pump foam maker uses made trade name W-5721, WP foam maker pump L bleed type (the gas/liquid mixing ratio: 13/1 of (strain) lucky wild industry, output: 0.9g(1 extruding), perforated membrane: 2 of the polyethylene of 90 sieve meshes メ ッ processed シ ュ リ Application グ).
(evaluation of brightness dyeing)
After the hair dye of the above-mentioned blister that each embodiment, each comparative example are related to is discharged, utilize conventional method to coat with judging with on 15cm people's black topknot of hair immediately respectively.Evaluation hair after the after washing coating in 30 minutes is had one's hair wash 2 times, after then handling, estimates estimating with the brightness dyeing of hair.
Estimate basis and carry out based on 4 stages of following metewand, evaluation result is shown in table 3.
◎: brightness dyeing is excellent
Zero: brightness dyeing is good
△: brightness dyeing has insufficient slightly
*: brightness dyeing is insufficient.
(evaluation of drippage)
The hair dye of the above-mentioned blister that each embodiment, each comparative example are related to is coated on the wig after discharging immediately, then carry out under 40 ℃ the condition 30 minutes through the time observe, the drippage complexity of blister hair dye is observed, is estimated.Estimate basis and carry out based on 8 stages of following metewand, evaluation result is shown in table 3.
◎: the liquefaction, the drippage that do not have bubble fully
◎～zero: bubble is not liquefaction almost, not drippage
Zero: bubble has liquefaction slightly, but does not drip
Zero～△: in 30 minutes, steep raising is given birth to liquefaction, drippage
△: in 15 minutes, steep raising is given birth to liquefaction, drippage
△～*: in 10 minutes, steep raising is given birth to liquefaction, drippage
*: in 5 minutes, steep raising is given birth to liquefaction, drippage
In * *: 5 minutes, steep raising is given birth to liquefaction, is dripped in large quantities.
The embodiment of the 6th invention group
(formations of two preparation formula hair dyes)
Prepare shown in the following table 4 the example 1～example 3 of hair dye the 2nd preparation of the solvable system that forms shown in the example 1～example 9 of hair dye the 1st preparation of the solvable system that forms and the table 5, as as shown in " combination " hurdle of table 6, with these the 1st preparations and the combination of the 2nd preparation selectivity, constitute the two preparation formula hair dyes that relate in embodiment 1～embodiment 6, the comparative example 1～comparative example 3.
In table 4 and table 5, the numerical value of representing the component content of the 1st preparation or the 2nd preparation is not the content statement when mixing of the 1st preparation and the 2nd preparation, but is the content statement of unit with quality % in the 1st preparation or the 2nd preparation.The composition of (A1) of the present invention for being equivalent to composition, (A2) composition, (B1) composition, (B2) composition, the marge in the left side of showing is expressed as " A1 ", " A2 ", " B1 ", " B2 " respectively.
In the table 6, the numeral that shows in the item of " the 1st preparation " in " combination " hurdle and " the 2nd preparation " is the example numbering of the 1st preparation shown in table 4 or the table 5 or the 2nd preparation.
(evaluation of hair dye)
(evaluation of drippage)
When the bad dispersibility of myristyl alcohol in the hair cosmetic composition of non-aerosol type, have the bubble that can not obtain high-quality and form the relation of dripping reason, therefore for each embodiment and the hair dye that each comparative example relates to, by the evaluation of following drippage, the dispersibility of myristyl alcohol is estimated.
The ratio that the 1st preparation and the 2nd preparation of the various embodiments described above, each comparative example with the mass ratio is 1:1 is accommodated in the made pump foam maker of above-mentioned (strain) lucky wild industry, form mixed liquor, carry out extrusion operation by the head with this pump, discharge above-mentioned mixed liquor with the infusion type.
After the hair dye of above-mentioned blister discharged, be coated on immediately on the wig, then carry out under 40 ℃ the condition 30 minutes through the time observe, the drippage complexity of blister hair dye is observed, is estimated.Estimate basis and carry out based on 4 stages of following metewand, evaluation result is shown in table 6.
◎: the liquefaction, the drippage that do not have bubble fully
Zero: bubble has liquefaction slightly, but does not drip
△: in 30 minutes, steep raising is given birth to liquefaction, drippage
*: in 15 minutes, steep raising is given birth to liquefaction, drippage.
(evaluation of brightness dyeing)
Use the pump foam maker same with the situation of above-mentioned " evaluation of drippage ", after the mixed liquor that is obtained with the mixed of mass ratio 1:1 by the 1st preparation and the 2nd preparation that each embodiment, each comparative example are related to is discharged with the infusion type, utilize conventional method to be coated on judging with on the 15cm people's black topknot and white goats hair of hair immediately respectively.Evaluation hair after the after washing coating in 30 minutes is had one's hair wash 2 times, after then handling, estimates estimating with the brightness dyeing of hair.
Estimate according to estimating based on 4 stages of following metewand, evaluation result is shown in table 6.
◎: brightness dyeing is excellent
Zero: brightness dyeing is good
△: brightness dyeing is insufficient a little
*: brightness dyeing is insufficient.
The industry utilizability
According to the present invention, the hair cosmetic composition of discharging with the blister dosage form from the non-aerosol foaming vessel can be provided, it gives hair good brightness, the dyeing excellence of hair, and when being applied to hair, do not drip.
Claims (11)
1. cosmetic hair composition, it is as hair dye or hair depigmenting agent and constitute, during use the mixed liquor of the 1st preparation and the 2nd preparation is discharged with blister from the non-aerosol foaming vessel, and be applied to hair, it is characterized in that, contain above (A) composition of 10 quality %: nonionic surfactant
And as (B) composition: higher alcohol, contain following (B1) composition,
(B1) be to be aqueous higher alcohol at 25 ℃.
2. the described cosmetic hair composition of claim 1 is characterized in that, above-mentioned (B1) composition is the higher alcohol of branched chain type.
3. claim 1 or 2 described cosmetic hair compositions is characterized in that, above-mentioned cosmetic hair composition is that oxide hair dye, acid hair dye, hair depigmenting agent or hair take off stain.
4. the using method of cosmetic hair composition is characterized in that, each described cosmetic hair composition in the claim 1～3 is discharged with blister from the non-aerosol foaming vessel, and be applied to hair.
5. the hair cosmetic product is characterized in that, contains each described cosmetic hair composition in the claim 1～3 and is used for the non-aerosol foaming vessel that this cosmetic hair composition is discharged with blister and constitutes.
6. cosmetic hair composition, it is as hair dye or hair depigmenting agent and constitute, during use the mixed liquor of the 1st preparation and the 2nd preparation is discharged with blister from the non-aerosol foaming vessel, and be applied to hair, it is characterized in that, contain following (A1) composition and (A2) composition as (A) composition: nonionic surfactant
And contain following (B1) composition and (B2) composition as (B) composition: higher alcohol,
(A1) the EO number is 2～10 the interior POE alkyl ether of scope,
(A2) the EO number is 11～150 the interior POE alkyl ether of scope,
(B1) be aqueous higher alcohol at 25 ℃,
(B2) myristyl alcohol.
7. the described cosmetic hair composition of claim 6 is characterized in that, above-mentioned (A1) composition and (A2) composition be the POE alkyl ether of straight chain type.
8. claim 6 or 7 described cosmetic hair compositions is characterized in that, above-mentioned (A1) composition is that HLB is more than 5 and less than 14 material, and (A2) composition is that HLB is more than 14 and less than 19 material.
9. each described cosmetic hair composition in the claim 6～8 is characterized in that, above-mentioned cosmetic hair composition is that oxide hair dye, acid hair dye, hair depigmenting agent or hair take off stain.
10. the using method of cosmetic hair composition is characterized in that, each described cosmetic hair composition in the claim 6～9 is discharged with blister from the non-aerosol foaming vessel, and be applied to hair.
11. the hair cosmetic product is characterized in that, contains each described cosmetic hair composition in the claim 6～9 and is used for the non-aerosol foaming vessel that this cosmetic hair composition is discharged with blister and constitutes.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010245608A JP5725801B2 (en) | 2010-11-01 | 2010-11-01 | Hair cosmetic composition, method of use thereof and hair cosmetic product |
| JP2010245609A JP5725802B2 (en) | 2010-11-01 | 2010-11-01 | Hair cosmetic composition, method of use thereof and hair cosmetic product |
| JP2010-245608 | 2010-11-01 | ||
| JP2010-245609 | 2010-11-01 | ||
| PCT/JP2011/074461 WO2012060240A1 (en) | 2010-11-01 | 2011-10-24 | Hair cosmetic composition, method for using same, and hair cosmetic product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103298448A true CN103298448A (en) | 2013-09-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011800526026A Pending CN103298448A (en) | 2010-11-01 | 2011-10-24 | Hair cosmetic composition, method for using same, and hair cosmetic product |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN103298448A (en) |
| TW (1) | TWI511745B (en) |
| WO (1) | WO2012060240A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107440933A (en) * | 2016-05-25 | 2017-12-08 | 朋友株式会社 | Oxide hair dye composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003073240A (en) * | 2001-08-31 | 2003-03-12 | Hoyu Co Ltd | Foamy hair dye composition and foamy hair-bleaching agent composition |
| CN101801337A (en) * | 2007-10-24 | 2010-08-11 | 花王株式会社 | Hair-dyeing method |
| CN101835455A (en) * | 2007-10-24 | 2010-09-15 | 花王株式会社 | Two-part hair dye |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005194206A (en) * | 2003-12-26 | 2005-07-21 | Kao Corp | Two-pack type hair cosmetic |
| JP4950749B2 (en) * | 2006-04-25 | 2012-06-13 | 花王株式会社 | Hair cosmetics |
| JP4463833B2 (en) * | 2007-02-19 | 2010-05-19 | 花王株式会社 | Hair dye composition |
| JP5756258B2 (en) * | 2009-03-11 | 2015-07-29 | 花王株式会社 | Two-component hair dye |
-
2011
- 2011-10-24 WO PCT/JP2011/074461 patent/WO2012060240A1/en active Application Filing
- 2011-10-24 CN CN2011800526026A patent/CN103298448A/en active Pending
- 2011-10-31 TW TW100139588A patent/TWI511745B/en active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003073240A (en) * | 2001-08-31 | 2003-03-12 | Hoyu Co Ltd | Foamy hair dye composition and foamy hair-bleaching agent composition |
| CN101801337A (en) * | 2007-10-24 | 2010-08-11 | 花王株式会社 | Hair-dyeing method |
| CN101835455A (en) * | 2007-10-24 | 2010-09-15 | 花王株式会社 | Two-part hair dye |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107440933A (en) * | 2016-05-25 | 2017-12-08 | 朋友株式会社 | Oxide hair dye composition |
| CN107440933B (en) * | 2016-05-25 | 2023-02-17 | 朋友株式会社 | Oxidation hair dye composition |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012060240A1 (en) | 2012-05-10 |
| TW201304806A (en) | 2013-02-01 |
| TWI511745B (en) | 2015-12-11 |
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Application publication date: 20130911 |