WO2012014570A1

WO2012014570A1 - Hair cosmetic composition, method for using same, and hair-cosmetic-related product

Info

Publication number: WO2012014570A1
Application number: PCT/JP2011/063011
Authority: WO
Inventors: 祐貴笹尾; 奈美子藤城
Original assignee: ホーユー株式会社
Priority date: 2010-07-28
Filing date: 2011-06-07
Publication date: 2012-02-02
Also published as: JP5762701B2; CN103140210A; TWI531378B; TW201204397A; JP2012031072A

Abstract

Disclosed is a hair cosmetic composition that is made into a foam by a non-aerosol foamer container and applied to hair. Said composition produces a good foam, coats well, and does not drip off during application. Said hair cosmetic composition contains: (A) at least 10% by mass of a non-ionic surfactant; (B) a cationic surfactant; and (C) at least one surfactant selected from among anionic surfactants and ampholytic surfactants.

Description

Hair cosmetic composition, method of use thereof and hair cosmetic product

The present invention relates to a hair cosmetic composition, a method for using the same, and a hair cosmetic product. More specifically, the present invention comprises a hair cosmetic composition used in a foamed dosage form with a non-aerosol foamer container, a method for using the same, a hair cosmetic composition and a non-aerosol foamer container. The present invention relates to a hair cosmetic product.

It is known that hair cosmetics such as hair dyes and depigmenting / decoloring agents for hair are used in the form of foam when used. When these hair cosmetics are used in a foamy dosage form, it is easy to apply evenly and uniformly to the hair, and it is possible to prevent dripping at the time of hair application without increasing the viscosity of the hair cosmetic. Advantages such as being able to eliminate the need for hair blocking during the use of gel-like or cream-like hair cosmetics that have been used can be expected.

Hair cosmetics used in foamy dosage forms can be broadly classified into aerosol type and non-aerosol type. The aerosol type uses a propellant such as a liquefied gas and makes the dosage form foam by forming bubbles using the aerosol. Non-aerosol type, without using a propellant, forms a bubble that takes in air using a pump foamer, squeeze foamer or other non-aerosol foamer container (hereinafter also simply referred to as “former container”), Make the dosage form foamy.

[Patent Document 1] JP 09-136818 [Patent Document 2] JP 10-287534 [Patent Document 3] JP 2007-291015 [Patent Document 4] JP 2008-291020 A Patent Document 1 and Patent Document 2 disclose an oxidative hair dye composition or a hair dye composition that is used in the form of foam with aerosol. In addition, Patent Document 3 and Patent Document 4 described above disclose hair dyes and the like that are used by foaming the dosage form with a non-aerosol foamer container.

By the way, in non-aerosol type foamy hair cosmetics, although it is easy to obtain foam that is relatively familiar to hair and stretched at the time of hair application, it tends to form foam that is easily defoamed over time. is there.

In order to eliminate the above-mentioned dissatisfaction with non-aerosol type foamy hair cosmetics, for example, it is conceivable to improve the blending of a surfactant as a foaming agent.

A relatively large amount of a surfactant is blended in the aerosol type foamy hair dye disclosed in Patent Document 1 and Patent Document 2. However, since the foaming mechanism and the structure of the bubbles are different between the aerosol type and the non-aerosol type, it is considered that the action and effect of the surfactant concerning the foaming property and the characteristics of the foam are greatly different. Accordingly, the disclosure of surfactant formulation in these documents is not directly helpful.

In the non-aerosol type foamy two-component hair bleaching / dyeing agent disclosed in Patent Document 3, dripping of the agent at the time of hair application is prevented by blending with higher alcohol and at the time of mixing one agent / two agents The foaming property is improved by adding 2 to 10% by weight of a surfactant. However, the effect of the invention is a special effect of “ensuring foamability at low temperature in relation to higher alcohol blending”. As the surfactant, it is preferable to use a combination of an anionic surfactant and a nonionic surfactant, and the nonionic surfactant is used in such a range that it becomes less than 10% by weight when mixing one agent or two agents. is doing.

In the non-aerosol type foamy hair dye / hair bleaching agent disclosed in Patent Document 4, a surfactant is preferably used as a foaming agent, but the point of the invention is to optimize the viscosity of the agent Also, there is not much disclosure that is substantially meaningful with regard to the type and blending amount of the surfactant to be blended.

The applicant of the present application has disclosed an anionic surfactant in Japanese Patent Application No. 2009-247089 (Japanese Patent Application Laid-Open No. 2011-093820) in relation to the disclosure status regarding the blending of a surfactant in foamy hair cosmetics in the above prior art document. It proposes a hair cosmetic composition that maintains a foamy dosage form by blending surfactants having different ionic properties, that is, an agent and a cationic surfactant, in one agent and two agents, respectively. However, as a result of further research, in this hair cosmetic composition, when one agent and two agents are mixed, a cation-anion complex and an insoluble substance are formed, which is caused by a non-aerosol foamer container. In the case of trying to foam, it was found that such a complex causes ejection failure and high quality foam cannot be obtained. Therefore, the present invention is a hair cosmetic composition that is applied to hair in a foamed dosage form using a non-aerosol foamer container, and obtains high-quality foam, excellent applicability to hair, and application to hair It is a technical problem to be solved to provide a hair cosmetic composition that sometimes does not sag.

(Configuration of the first invention)
The constitution of the first invention of the present application for solving the above-mentioned problem is a hair cosmetic composition for applying to a hair in a foamy dosage form with a non-aerosol foamer container at the time of use, comprising the following component (A) A hair cosmetic composition containing the component (C).
(A) 10% by mass or more of a nonionic surfactant.
(B) Cationic surfactant.
(C) 1 or more types chosen from anionic surfactant and amphoteric surfactant.

In the first invention described above, “10% by mass or more” means “10% by mass or more when the first agent and the second agent are mixed” in the two-component hair cosmetic composition. Similarly, in the present specification, the numerical value defining the content of a certain component is “content at the time of mixing the first agent and the second agent” in the two-component hair cosmetic composition unless otherwise specified. "Means.

(Configuration of the second invention)
The constitution of the second invention of the present application for solving the above problems is that the hair cosmetic composition according to the first invention is applied to the hair by using a mixture of the first agent and the second agent in a foamy dosage form at the time of use. The hair cosmetic composition is a two-component formula to which the first component is blended with the component (B) and the second component is blended with the component (C).

(Configuration of the third invention)
The configuration of the third invention of the present application for solving the above-mentioned problem is a hair cosmetic composition in which the hair cosmetic composition according to the first invention or the second invention is a hair dye, a hair bleaching agent or a hair decoloring agent. It is a thing.

(Configuration of the fourth invention)
The structure of the fourth invention of the present application for solving the above-mentioned problems is that the hair cosmetic composition described in any of the first to third inventions is applied to hair in a foamy dosage form with a non-aerosol foamer container. This is a method for using a hair cosmetic composition.

(Structure of the fifth invention)
The structure of the fifth invention of the present application for solving the above-mentioned problems is that the hair cosmetic composition described in any of the first to third inventions and the hair cosmetic composition are made into a foamy dosage form. A non-aerosol foamer container.

According to the first aspect of the present invention, a high-quality foam can be obtained when a foamed dosage form is formed using a non-aerosol foamer container, and the hair cosmetic has excellent applicability to hair and does not sag when applied to hair. A composition is provided.

That is, the hair cosmetic composition containing the cationic surfactant of component (B) and the anionic surfactant of component (C) has, as a basic effect, a foam that is moist when foamed. Is obtained. On the other hand, however, when a complex is formed by the interaction of these surfactants, application to a non-aerosol foamer container results in poor ejection. In addition, when foam is applied to hair, problems such as sagging when left untreated occur when applied to hair, and the foam is not satisfactory.

However, in the first invention, by adding 10% by mass or more of a nonionic surfactant as the component (A), the discharge failure in the non-aerosol foamer container can be eliminated. The film strength is improved and the bubbles are difficult to disappear, and high-quality bubbles can be obtained in terms of foamability, foam texture, foam hardness, and the like. This foam has good applicability to the hair (familiarity with the hair, elongation at the time of application), and does not sag when left unattended because it maintains a firm foam during application of the hair and is difficult to remove. When the blending amount of the nonionic surfactant is less than 10% by mass, these effects cannot be sufficiently obtained.

In addition, as the component (C), an amphoteric surfactant can be used together with the anionic surfactant or in place of the anionic surfactant. As is well known, amphoteric surfactants exist as anions in the alkaline pH region and as cations in the acidic pH region. The oxidative hair dye and the hair bleaching / destaining dye are alkaline when the first agent and the second agent are mixed. Therefore, in the case of these hair cosmetic compositions, the amphoteric surfactant substantially exhibits the behavior as an anionic surfactant, and similarly exhibits the above-mentioned actions and effects described for the anionic surfactant.

According to the second invention, the component (B) cationic surfactant blended in the first agent and the component (C) anionic surfactant or amphoteric surfactant blended in the second agent. By mixing, foam is generated due to the interaction between the two, but since both do not contact until mixing and foaming of the first agent and the second agent, the stability of each agent is kept good .

According to the third invention, a hair dye, a hair bleaching agent or a hair decoloring agent which is a particularly preferred embodiment of the hair cosmetic composition is provided.

According to the fourth invention, there is provided an effective method for applying the hair cosmetic composition to the hair in the form of a good non-aerosol type foamy dosage form.

According to the fifth invention, a simple hair cosmetic composition comprising a hair cosmetic composition and a non-aerosol foamer container for mixing the hair cosmetic composition into a foamy dosage form. Supplies are provided.

Next, modes for carrying out the present invention will be described including the best mode.

[Hair cosmetic composition]
The hair cosmetic composition according to the present invention is for applying to a hair in a foamy dosage form with a non-aerosol foamer container at the time of use, and a nonionic interface of 10% by mass or more as component (A) The surfactant contains a cationic surfactant as the component (B), and one or more surfactants selected from an anionic surfactant and an amphoteric surfactant as the component (C) as essential components.

As long as the above conditions are met, the type of the hair cosmetic composition is not limited, but is preferably a hair dye, a hair decoloring agent or a hair decoloring agent. Examples of hair dyes include oxidative hair dyes and acidic hair dyes, with oxidative hair dyes being particularly preferred.

The hair cosmetic composition includes a one-component type, but a two-component hair cosmetic composition is particularly preferable. The two-component hair cosmetic composition includes those obtained by further dividing the first agent or the second agent into a plurality of agents. For example, in a two-component oxidative hair dye, the first agent is replaced with a normal oxidative hair dye instead of the composition in which the first agent is blended with the component (B) and the second agent is blended with the component (C). In the case where the agent is divided into an agent containing the first agent component and an agent containing the component (B), or the second agent is an agent containing the second agent component of a normal oxidative hair dye and the component (C). When it divides | segments and comprises the agent which mix | blended, etc. can be illustrated.

[Aspect of blending essential components into first and second agents]
When the hair cosmetic composition is a two-component type, the mode of blending the (A) component to the (C) component into the first agent and the second agent is basically not limited and can be arbitrarily selected. Preferably (B) component and (C) component are mix | blended with a mutually different agent, Especially preferably, (B) component is mix | blended with the 1st agent, and (C) component is mix | blended with the 2nd agent, respectively.

When the component (B) and the component (C) are blended in different agents, the mass ratio (C) / (B) of the blended amount of both is within the range of 0.01-5, The dosage form is more easily maintained. This effect becomes even more remarkable when the mass ratio (C) / (B) is in the range of 0.05 to 2.

In the above case, the component (A) may be blended in either the first agent or the second agent, but is dispersed in both the first agent and the second agent so that the total blending amount is 10% by mass. You may mix.

Further, in a two-component hair cosmetic composition such as a two-component oxidative hair dye in which the first agent is in the alkaline region and the second agent is in the acidic region, an anionic surfactant and amphoteric as the component (C) When used in combination with a surfactant, the amphoteric surfactant is present as an anion in the first agent and as a cation in the second agent, as described above. It is preferable to mix amphoteric surfactants so that the polarities of the surfactants in the agent are the same. Furthermore, the components (A) to (C) may be blended in only one of the first agent and the second agent. When the hair cosmetic composition is a one-component acidic hair dye or the like, the components (A) to (C) are blended in the same agent.

[Dosage form of hair cosmetic composition]
Examples of the dosage form of the one-component hair cosmetic composition or the first agent and the second agent before foaming in the two-component hair cosmetic composition include, for example, solid, aqueous solution, dispersed liquid, and emulsification Examples include physical, gel, foam, and cream. Examples of solid dosage forms include powder and tablets. In the case of a solid dosage form, it is preferably in a powder form from the viewpoint of excellent dispersibility when mixing the first agent and the second agent. For example, when the first agent is a solid dosage form, the second agent is an agent containing water. In short, in the case of a one-component hair cosmetic composition, in the case of a two-component hair cosmetic composition, if the fluidity can be ensured at the time of mixing the first and second agents, the agent The type is not particularly limited.

In addition, the hair cosmetic composition contains water as a base material for foaming in the agent in the case of the one-agent type, and in at least one of the first agent and the second agent in the case of the two-agent type. Has been. The water content is preferably 40% by mass or more, and more preferably 60% by mass or more.

[Component (A)]
(A) component of this invention is a nonionic surfactant mix | blended 10 mass% or more with hair cosmetics composition. (A) Although the upper limit of the compounding quantity of a component is not limited, For example, it can be limited to 40 mass% or less.

Examples of nonionic surfactants include, but are not limited to, the following. One kind of nonionic surfactant may be used alone, or two or more kinds thereof may be used in combination. In particular, when a hydrophilic nonionic active agent having an HLB of 15 or more and a lipophilic nonionic active agent having an HLB of 9 or more and less than 15 are used in combination, the stability of the preparation is good. HLB (Hydrophilic-Lipophile Balance) is calculated from the known Griffin equation.

1. Polyoxyethylene (hereinafter referred to as POE) cetyl ether, POE stearyl ether, POE behenyl ether, POE oleyl ether, POE lauryl ether, POE tridecyl ether, POE octyl decyl ether, POE hexyl decyl ether, POE isostearyl ether, POE decyl POE alkyl ethers such as pentadecyl ether, POE decyl tetradecyl ether, and POE alkyl (C12-14) ether.

2. POE alkyl phenyl ethers such as POE nonyl phenyl ether and POE octyl phenyl ether.

3. POE sorbitan fatty acid esters such as monooleic acid POE sorbitan, monostearic acid POE sorbitan, monopalmitic acid POE sorbitan, monolauric acid POE sorbitan, trioleic acid POE sorbitan.

4. POE glyceryl mono fatty acid esters such as monostearic acid POE glycerin and monomyristic acid POE glycerin.

5. POE sorbitol fatty acid esters such as tetraoleic acid POE sorbit, hexastearic acid POE sorbit, monolauric acid POE sorbit, and POE sorbit beeswax.

6. POE hydrogenated castor oil, POE castor oil.

7. Polyethylene glycol monooleate, polyethylene glycol monostearate, polyethylene glycol monolaurate.

8. Higher fatty acid glycerin esters such as lipophilic glyceryl monooleate, lipophilic glyceryl monostearate, and self-emulsifying glyceryl monostearate.

9. Sorbitan fatty acid esters such as sorbitan monooleate, sorbitan sesquioleate, sorbitan trioleate, sorbitan monostearate, sorbitan monopalmitate, sorbitan monolaurate, and the like.

10. Lanolin derivatives such as POE lanolin, POE lanolin alcohol, and POE sorbitol lanolin.

11. Alkylolamides such as lauric acid diethanolamide and coconut oil fatty acid diethanolamide;

12. POE fatty acid amides such as POE stearamide.

13. Sucrose fatty acid ester.

14. Alkyl amine oxides such as dimethyl lauryl amine oxide;

15. Alkyl glucosides such as lauryl glucoside and alkyl (8-16) glucoside.

16. Lecithin derivative hydrogenated soybean lecithin, hydrogenated egg yolk lecithin, etc.

[(B) component]
(B) component of this invention is a cationic surfactant mix | blended with a hair cosmetic composition. The blending amount of component (B) is not limited, but is preferably in the range of 0.1 to 10% by mass, particularly preferably in the range of 0.5 to 5% by mass.

Examples of the cationic surfactant include lauryltrimethylammonium chloride, cetyltrimethylammonium chloride (cetrimonium chloride), stearyltrimethylammonium chloride (stearyltrimonium chloride), alkyltrimethylammonium chloride, and behenyltrimethylaluminum chloride (behentrimonium chloride). , Distearyldimethylammonium chloride (distearyldimonium chloride), cetyltrimethylammonium bromide, stearyltrimethylammonium bromide, ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium, stearyltrimethylammonium saccharin, cetyltrimethylammonium saccharin, methyl behenyltrimethyl sulfate Ammonium and quaternium-91 Although but is exemplified, without limitation. Although one kind of cationic surfactant may be used alone, it is preferable to use two or more kinds in combination in terms of foamability and feel.

[Component (C)]
(C) component of this invention is an anionic surfactant and / or an amphoteric surfactant mix | blended with a hair cosmetic composition. The amount of component (C) is not limited, but it is preferably in the range of 0.05 to 10% by mass, particularly preferably in the range of 0.1 to 3% by mass.

(C) Although the following are illustrated as a component, it is not limited to them. As the component (C), one type thereof may be used alone, or two or more types thereof may be used in combination.

Examples of the anionic surfactant among the components (C) include alkyl ether sulfates such as POE sodium lauryl ether sulfate, alkyl sulfates such as sodium lauryl sulfate, sodium cetostearyl sulfate and sodium cetyl sulfate, alkenyl ether sulfates, N-acyl such as alkenyl sulfate, olefin sulfonate, alkane sulfonate, saturated or unsaturated fatty acid salt, alkyl or alkenyl ether carboxylate, α-sulfone fatty acid salt, cocoylglutamate triethanolamine (cocoylglutamate TEA) Examples include amino acid type surfactants, phosphate mono- or diester type surfactants, and sulfosuccinate esters. Examples of the counter ion of the anionic group of these surfactants include sodium ion, potassium ion, and triethanolamine.

Examples of amphoteric surfactants among the component (C) include the following.

1. Fatty acid amidopropyl dimethylamino such as palm oil fatty acid amidopropyldimethylaminoacetic acid betaine, palm oil fatty acid amidopropyldimethylaminoacetic acid betaine, lauric acid amidopropyldimethylaminoacetic acid betaine (lauramidopropyl betaine), ricinoleic acid amidopropyldimethylaminoacetic acid betaine Betaine acetate and their sodium, potassium or triethanolamine salts.

2. Decyldimethylaminoacetic acid betaine, lauryldimethylaminoacetic acid betaine, myristyldimethylaminoacetic acid betaine, cetyldimethylaminoacetic acid betaine, stearyldimethylaminoacetic acid betaine, oleyldimethylaminoacetic acid betaine, behenyldimethylaminoacetic acid betaine, coconut oil alkyldimethylaminoacetic acid betaine, etc. Alkyldimethylaminoacetic acid betaines and their sodium, potassium or triethanolamine salts.

3. Cocoamphoacetic acid Na (N-coconut oil fatty acid acyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine), Cocoamphopropionic acid Na (N-coconut oil fatty acid acyl-N′-carboxyethyl-N′-hydroxyethylethylenediamine) ), Lauroamphoacetate Na (N-lauroyl-N′-carboxymethyl-N′-hydroxyethylethylenediamine), Olive Amphoacetate Na, Cacao Fat Amphoacetate Na, Sesame Amphoacetate Na, Sweet Almond Amphoacetate Na, Stearoampho Acetate, Palm Ampho N-acylaminoethyl-N-2-hydroxyethylaminocarboxylates such as sodium acetate, sodium peanut amphoacetate, sodium sunflower seed amphoacetate, and cottonseed amphoacetate Na.

4. N-acylaminoethyl-N-carboxymethoxyethylaminocarboxylates such as Na cocoamphodiacetate, Na cocoamphodipropionate and Nauroamphodiacetate.

5. Hydroxyalkyl (C12-14) hydroxyethyl sarcosine.

[Category of hair cosmetic composition]
Although the hair cosmetic composition of this invention is not limited, For example, it is comprised as an oxidative hair dye, an acidic hair dye, a hair bleaching agent, or a hair decoloring agent. Particularly preferably, it is configured as an oxidative hair dye or a hair bleaching agent.

(Oxidative hair dye)
The oxidative hair dye comprises a first agent containing an alkali agent and an oxidative dye and a second agent containing an oxidant, decomposes melanin in the hair, and results in oxidative polymerization of the oxidative dye by the oxidant. I do. Oxidative dyes are classified as dye intermediates and couplers. Instead of the oxidation dye, a direct dye such as a basic dye, a nitro dye, a natural dye, or a disperse dye may be blended.

Examples of the dye intermediate include phenylenediamines, aminophenols, toluylenediamines, diphenylamines, diaminophenylamines, N-phenylphenylenediamines, diaminopyridines, and salts thereof. Examples of the salts include hydrochloride, sulfate, acetate, and the like.

A coupler is a compound that develops color by binding to a dye intermediate, and is contained in the first agent as necessary. Examples of couplers include resorcin, pyrogallol, catechol, metaaminophenol, metaphenylenediamine, 2,4-diaminophenol, 1,2,4-benzenetriol, toluene-3,4-diamine, and toluene-2,4-diamine. , Hydroquinone, α-naphthol, 2,6-diaminopyridine, 1,5-dihydroxynaphthalene, 5-aminoorthocresol, paramethylaminophenol, 2,4-diaminophenoxyethanol, gallic acid, tannic acid, ethyl gallate, gallic acid Examples include methyl acid, propyl gallate, pentaploid, 5- (2-hydroxyethylamino) -2-methylphenol, and salts thereof.

The content of the dye intermediate in the oxidative hair dye is preferably 0.01 to 10% by mass, more preferably 0.1 to 5% by mass. If the content of the dye intermediate is less than 0.01% by mass, sufficient dyeability may not be obtained. Even if the content of the dye intermediate exceeds 10% by mass, the dyeability does not improve any more, and the economics of hair dyeing may be reduced.

The first agent is suitably selected from dyes other than the above-mentioned oxidation dyes, for example, at least one selected from oxidation dyes and direct dyes listed in "Quasi-drug raw material standards" (issued in June 2006, Yakuji Nippo). You may contain.

The alkali agent promotes the action of the oxidizing agent contained in the second agent and improves the dyeability by swelling the hair and improving the permeability of the dye into the hair. Examples of the alkaline agent include ammonia, alkanolamines, organic amines, inorganic alkalis, basic amino acids, and sulfates. Examples of organic amines include 2-amino-2-methyl-1,3-propanediol and guanidine. Examples of the inorganic alkali include sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, ammonium carbonate, sodium hydrogen carbonate and ammonium hydrogen carbonate. Examples of basic amino acids include arginine and lysine, and basic amino acid salts. Examples of basic amino acid salts include ammonium salts. Examples of the sulfate include ammonium sulfate.

The content of the alkali agent is preferably such an amount that the pH is in the range of 7 to 12 in the oxidative hair dye in which the first agent and the second agent are mixed. When the pH is less than 7, when hydrogen peroxide as an oxidizing agent is contained in the second agent, the action of hydrogen peroxide may not be sufficiently promoted. If the pH during use exceeds 12, when the oxidative hair dye is applied to the hair, problems such as damage to the hair may easily occur.

The second agent contains at least an oxidizing agent. The oxidizing agent develops a color by oxidative polymerization of an oxidation dye. Examples of the oxidizing agent include hydrogen peroxide, urea peroxide, melamine peroxide, sodium percarbonate, potassium percarbonate, sodium perborate, potassium perborate, sodium peroxide, potassium peroxide, magnesium peroxide, peroxide. Barium, calcium peroxide, strontium peroxide, sulfate hydrogen peroxide adduct, phosphate hydrogen peroxide adduct, and pyrophosphate hydrogen peroxide adduct.

The content of the oxidizing agent in the second agent is preferably 0.1 to 10.0% by mass, more preferably 0.5 to 8.0% by mass. When the content of the oxidizing agent is less than 0.1% by mass, it may be difficult to sufficiently oxidatively polymerize the oxidation dye. When the content of the oxidizing agent exceeds 10.0% by mass, the hair may be easily damaged.

(Acid hair dye)
The acidic hair dye is usually of a one-part type, has a liquidity of about pH 2.5 to 4.0, and binds the acidic dye to the cationic hair. Examples of the acid dye include nitro dye, azo dye, nitroso dye, triphenylmethane dye, xanthene dye, quinoline dye, anthraquinone dye, and indigo dye.

More specifically, as the acid dye, Red No. 2, Red No. 3, Red No. 102, Red No. 104, Red No. 105, Red No. 106, Red No. 227, Red No. 230, Yellow No. 4, Yellow No. 5, Yellow 202, yellow 203, orange 205, orange 207, orange 402, green 3, green 204, green 401, purple 401, blue 1, blue 2, blue 202 , Brown 201, black 401 and the like.

The content of the acid dye in the acid hair dye is 0.005 to 5% by mass, more preferably 0.01 to 3% by mass.

(Hair depigmenting agent)
The hair bleaching agent comprises a first agent containing an alkaline agent and a second agent containing an oxidizing agent, and decolorizes the hair by decomposing the melanin of the hair. The hair bleaching agent is basically configured in the same manner as the oxidation hair dye except that it does not contain an oxidation dye.

(Hair destaining agent)
The hair decoloring agent is usually a two-component type and is mainly intended for hair dedying (decomposition of the dye dyed on the hair). Compared with the hair decoloring agent, the first agent is alkaline. A different point is that a persulfate, which is a kind of alkaline agent, is blended as a decoloring aid. The first agent is in the form of powder, granule, tablet or the like, and the second agent is liquid.

As the persulfate, an alkali metal salt of persulfate is preferably exemplified, and potassium persulfate or sodium persulfate is particularly preferably exemplified. The blending amount of persulfate is not limited, but is preferably in the range of 2.0 to 25% by mass, more preferably in the range of 3.5 to 18% by mass.

[Other ingredients in hair cosmetic composition]
For the first agent and the second agent in the one-component hair cosmetic composition or the two-component hair cosmetic composition, for example, an oily component, a water-soluble polymer compound, a chelating agent, Inorganic salts, dispersants and the like may be appropriately selected and contained.

Examples of the oil component include higher alcohols, fats and oils, waxes, hydrocarbons, higher fatty acids, alkyl glyceryl ethers, esters, silicones, and polyhydric alcohols.

Examples of higher alcohols include cetyl alcohol (cetanol), 2-hexyldecanol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol, oleyl alcohol, aralkyl alcohol, behenyl alcohol, 2-octyldodecanol, lauryl alcohol, myristyl alcohol, decyltetra Examples include decanol and lanolin alcohol. The higher alcohol has an effect of enhancing the effect of preventing the agent from dripping when the hair cosmetic composition is applied to the hair in the form of a non-aerosol foam.

Examples of fats and oils include lanolin, olive oil, camellia oil, shea fat, almond oil, safflower oil, sunflower oil, soybean oil, cottonseed oil, sesame oil, corn oil, rapeseed oil, rice bran oil, rice germ oil, grape seed oil, avocado Oil, macadamia nut oil, castor oil, coconut oil, and evening primrose oil.

Examples of waxes include beeswax, candelilla wax, carnauba wax, jojoba oil, and lanolin.

Examples of the hydrocarbon include paraffin, olefin oligomer, polyisobutene, hydrogenated polyisobutene, mineral oil, squalane, polybutene, polyethylene, microcrystalline wax, and petrolatum.

Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, 12-hydroxystearic acid, oleic acid, and lanolin fatty acid.

Examples of the alkyl glyceryl ether include batyl alcohol, chimyl alcohol, seraalkyl alcohol, and isostearyl glyceryl ether.

Examples of esters include diisopropyl adipate, isopropyl myristate, cetyl octanoate, isononyl isononanoate, octyldodecyl myristate, isopropyl stearate, stearyl stearate, myristyl myristate, isotridecyl myristate, 2-ethylhexyl palmitate, Octyldodecyl ricinoleate, fatty acid cholesteryl / lanosteryl having 10 to 30 carbon atoms, cetyl lactate, lanolin acetate, ethylene glycol di-2-ethylhexanoate, pentaerythritol fatty acid ester, dipentaerythritol fatty acid ester, cetyl caprate, tricapryl Examples include glyceryl acid, diisostearyl malate, dioctyl succinate, and cetyl 2-ethylhexanoate.

Examples of the silicone include dimethylpolysiloxane (dimethicone), methylphenylpolysiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, terminal hydroxyl group-modified dimethylpolysiloxane, and a highly polymerized silicone having an average degree of polymerization of 650 to 10,000. , Polyether-modified silicone, amino-modified silicone, betaine-modified silicone, alkyl-modified silicone, alkoxy-modified silicone, carboxy-modified silicone, and fluorine-modified silicone.

Examples of the polyhydric alcohol include glycol and glycerin. Examples of the glycol include ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, isoprene glycol, and 1,3-butylene glycol. Examples of glycerin include glycerin, diglycerin, and polyglycerin.

Examples of the water-soluble polymer compound include carboxymethyl cellulose, hydroxyethyl cellulose, starch, and cyclodextrin. Examples of chelating agents include ethylenediaminetetraacetic acid (EDTA, edetic acid), hydroxyethylethylenediaminetriacetic acid (HEDTA) and salts thereof, diethylenetriaminepentaacetic acid and salts thereof, and hydroxyethanediphosphonic acid (HEDP, etidronic acid) and salts thereof. Is mentioned. Examples of the inorganic salt include sodium chloride and sodium sulfate. Examples of the dispersant include magnesium stearate.

In addition to the first agent and the second agent in the one-component hair cosmetic composition or the two-component hair cosmetic composition, for example, sugars, preservatives, stabilizers, pH adjusters, plants Contains at least one selected from extracts, herbal extracts, vitamins, fragrances, and UV absorbers, and those listed in "Quasi-drug raw material standards" (issued in June 2006, Yakuji Nippo) May be.

[How to use hair cosmetic composition]
The method of using the hair cosmetic composition according to the present invention is a method in which the above-described hair cosmetic composition is applied to the hair in a foamed dosage form using a non-aerosol foamer container.

The non-aerosol foamer container is not limited as long as it has a function capable of foaming and discharging non-aerosol type to the hair cosmetic composition. Preferably, foaming can be performed using a non-aerosol foamer container described later.

[Hair cosmetic supplies]
The hair cosmetic product according to the present invention comprises the above-mentioned hair cosmetic composition for applying to a hair in the form of a non-aerosol foam type when in use, and the hair cosmetic composition into a foam type dosage form. And a non-aerosol foamer container.

A typical example of a non-aerosol foamer container is a pump former or a squeeze foamer. The pump former is a device that presses the pump head to discharge the stored liquid (for example, the first / second mixed liquid of hair cosmetics) in the form of foam. The stored liquid is mixed with air. Then, a foam discharger that discharges in the form of foam is mounted on the mouth of the container body. A pump former is disclosed in Japanese Patent Application Laid-Open No. 2007-275777 and the like, and is well known. The squeeze foamer squeezes the container body made of a soft synthetic resin with fingers (repeating the compression and decompression operations on the container) to mix the liquid and air in the former with the foam discharge head. It introduce | transduces into a chamber, mixes, and the foam formed with the foam discharger is discharged from a nozzle. The squeeze former is described in the document “New trends in hair color technology (-development of foam hair color technology)” published in Japanese Patent Application Laid-Open No. 2008-291024 and the June 2009 issue of the magazine “Fragrance Journal” It is known.

The foam dispenser of a non-aerosol foamer container has one or more porous membranes for forming foam. Examples of the material for the porous membrane include nylon, polyester, polyethylene, and polypropylene. As the mesh of the porous membrane, for example, 50 to 300 mesh is preferable.

Examples of the present invention will be described below. The technical scope of the present invention is not limited by the following examples.

(Configuration of two-component hair dye)
The first hair dye having the composition shown as Example 1-1 to Example 1-5 in the “first agent” column of Table 1 and the examples 2-1 to 2 in the “second agent” column of Table 2 Example 1 to Example in which a second hair dye having the composition shown as −6 was prepared and these first and second agents were selectively combined as shown in the “Combination” column of Table 3. 8. A two-component hair dye according to Comparative Examples 1 to 5 was constructed.

In Tables 1 and 2, the numerical value indicating the content of the component of the first agent or the second agent is a content notation in units of mass in the first agent or the second agent, the first agent and the second agent It is not the content notation when mixing the agent. In addition, regarding the component corresponding to any of the components (A) to (C) of the present invention, the fact is displayed in the margin on the left side of the table. The “POE (7) alkyl (C12-14) ether” and the “POE (5) alkyl (C12-14) ether” which are the components (A) shown in Table 1 and Table 2 have an alkyl chain with 12 to 12 carbon atoms. 14 is a mixed raw material of POE alkyl ether, and the “alkyl (8-16) glucoside” as component (A) shown in Table 1 is a mixed raw material of alkyl glucoside having 8 to 16 carbon atoms in the alkyl chain. is there. Further, in Table 2, the component with [*] mark after the component name is FZ-4671 (aminoethylaminopropylmethylsiloxane / dimethylsiloxane copolymer (20%)) manufactured by Toray Dow Corning.

(Evaluation of two-component hair dye)
The first agent and the second agent according to each of the above examples and comparative examples are contained in the above-described non-aerosol foamer container (pump former) at a mass ratio of 1: 1 to obtain a mixed liquid, and the pump The mixed solution was bubble-discharged by pressing the head portion, and the foam quality, applicability and sagging were evaluated for each example and each comparative example. Here, as a pump former, trade name W-5721 manufactured by Yoshino Kogyo Co., Ltd., WP former pump L nozzle type (gas / liquid mixing ratio: 13/1, discharge amount: 0.9 g (1 push) ), Porous membrane: two 90 mesh polyethylene mesh rings).

Specifically, for “foam quality”, foaming properties, foam texture, and foam hardness were comprehensively evaluated. About "applicability | paintability", the foaming ease at the time of apply | coating to a wig as foamy hair color and the ease of application | coating were evaluated. About "sagging", after applying to a wig as a foamy hair color, the difficulty of dripping for 30 minutes was observed over time and evaluated.

In evaluating each evaluation item of the above “foam quality”, “applicability”, and “dripping”, the content of the component (A) is 9.25% in the mixed state of the first agent and the second agent. Comparative Example 1 was used as a control (standard for evaluation). Each evaluation item was evaluated in six stages by relative evaluation in comparison with the evaluation result of the control as shown in the following evaluation criteria. In addition, for any evaluation item in any of the examples and comparative examples, 10 panelists who were the same member evaluated at the same time, and the most evaluation result was adopted among the evaluation results by those panelists. The evaluation results are shown in the evaluation column of each evaluation item in Table 3.

<Evaluation criteria>
++++: Very good compared to the control ++: Very good compared to the control +: Excellent compared to the control-: Bad compared to the control--: Very bad compared to the control ---: Very bad compared to the control

According to the present invention, a non-aerosol type foam cosmetic composition to be applied to hair, which is capable of obtaining high quality foam, excellent in applicability to hair, and dripping down when applied to hair. There is provided a hair cosmetic composition free of hair.

Claims

A hair cosmetic composition for applying to a hair in a foamed dosage form with a non-aerosol foamer container at the time of use, comprising the following components (A) to (C): Composition.
(A) 10% by mass or more of a nonionic surfactant.
(B) Cationic surfactant.
(C) 1 or more types chosen from anionic surfactant and amphoteric surfactant.
The hair cosmetic composition is a two-component type wherein the mixture of the first agent and the second agent is applied in the form of a foam in the form of a foam at the time of use, and the component (B) is contained in the first agent. The hair cosmetic composition according to claim 1, which is blended and the component (C) is blended in the second agent.
The hair cosmetic composition according to claim 1 or 2, wherein the hair cosmetic composition is a hair dye, a hair decoloring agent or a hair decoloring agent.
A method for using a hair cosmetic composition, comprising applying the hair cosmetic composition according to any one of claims 1 to 3 to a hair in a foamy form using a non-aerosol foamer container.
A hair cosmetic composition according to any one of claims 1 to 3, and a non-aerosol foamer container for making the hair cosmetic composition into a foamy dosage form. Characteristic hair cosmetics.