CN114010511A

CN114010511A - Hair dye, color developing agent and using method of double-agent oxidation type hair dye

Info

Publication number: CN114010511A
Application number: CN202111311262.6A
Authority: CN
Inventors: 解鹏辉; 叶茂权; 邱楀锆; 成晓松; 周龙兵; 郭瑜娟; 朱国飞
Original assignee: Zhanghua Cosmetics Technology Co ltd
Current assignee: Zhanghua Cosmetics Technology Co ltd
Priority date: 2021-11-08
Filing date: 2021-11-08
Publication date: 2022-02-08

Abstract

The invention relates to a hair dye, a color developing agent and a using method of a two-agent oxidation type hair dye. The invention also provides a hair dye, which comprises the following components: dye, alkaline agent, anionic surfactant, higher alcohol, cationic high molecular polymer, nonionic surfactant and ethanol, wherein the pH value of the hair dye is 9-11. The invention provides a color developing agent, which comprises the following components: 1-9% of hydrogen peroxide, nonionic surfactant, higher alcohol, cationic surfactant and polypropylene glycol. The invention has the beneficial effects that: in the hair dye, floc generated by cationic high molecular polymer and anionic surfactant has conditioning effect on hair; the reasonable collocation of higher alcohols is utilized to perform the foam stabilizing function; the stability of the two agents at high and low temperatures and the use stability can be improved by adding polypropylene glycol and a nonionic surfactant.

Description

Hair dye, color developing agent and using method of double-agent oxidation type hair dye

Technical Field

The invention belongs to the technical field of cosmetics, and particularly relates to a hair dye, a color developing agent and a using method of a double-agent oxidation type hair dye.

Background

Most of the bubble hair dyes existing in the market exist: the soaking water quickly causes uneven dyeing and poorer coloring, the poor opsonization causes the dyed hair to be dry and frizzy, the dye is easy to oxidize, the market duration is shorter, and the like.

Disclosure of Invention

In view of the above, the present invention provides a method for using a two-agent oxidation type hair dye.

A method for using a two-agent oxidation type hair dye is characterized in that the hair dye containing dye and alkali agent is mixed with a color developing agent containing hydrogen peroxide, and then bubbles are extruded out through a non-aerosol foaming container for use.

The invention also provides a hair dye, which is characterized by comprising the following components: dye, alkaline agent, anionic surfactant, higher alcohol, cationic high molecular polymer, nonionic surfactant and ethanol, wherein the pH value of the hair dye is 9-11.

According to a further development of the invention, the dyes are p-phenylenediamine, p-aminophenol, toluene-2, 5-diamine sulfate, m-aminophenol, 2-chlorop-phenylenediamine sulfate, resorcinol, 2-nitro-p-phenylenediamine, 4-amino-2-hydroxytoluene, 2-methylresorcinol, 6-amino-m-cresol, phenylmethylpyrazolone, 4-amino-3-nitrophenol, 2, 4-diaminophenoxyethanol hydrochloride, 4-amino-m-cresol, 2-amino-3-hydroxypyridine, p-methylaminophenol sulfate, 2, 6-diaminopyridine, 6-hydroxyindole, 4-chlororesorcinol, 2, 7-naphthalenediol, N-phenylp-phenylenediamine, 1, 5-naphthalenediol and 1-naphthol, m-aminophenol, 2-chloro-cresol, 2-chloropyrazolone, 2, 7-naphthalenediol, 1-naphthol, p-phenylenediamine, m-2-hydroxy-resorcinol, 2-amino-methyl-2-methyl-resorcinol, 6-amino-2-hydroxy-indole, 2-hydroxy-2, 4-amino-2, 4-naphthol, 2-hydroxy-indole, 2-hydroxy-2-hydroxy-phenol, 4-hydroxy-2, 2-hydroxy-phenol, 2-hydroxy-2, 4-hydroxy-2-hydroxy-2, 4-hydroxy-2, 4-hydroxy-phenol, 4-hydroxy-2-hydroxy-2, 4-hydroxy-2-hydroxy-2-hydroxy-2, 4-hydroxy-2-hydroxy-2-hydroxy-2-hydroxy-2, N-hydroxy-2-hydroxy-2-hydroxy-2-hydroxy-2, N-hydroxy-2, N-hydroxy-2-hydroxy-2-hydroxy-2-, 4-nitro o-phenylenediamine, p-nitro m-phenylenediamine, basic yellow (basic yellow)87, basic orange (basic orange)31, basic red 51, HC yellow No. 4 and HC yellow No. 2.

The invention further provides that the alkaline agent is weak alkali or strong alkali, the weak alkali comprises ammonium hydroxide and monoethanolamine, and the strong alkali comprises sodium hydroxide and potassium hydroxide.

The invention further provides that the anionic surfactant is two or more of dialkyl sodium sulfate, sodium dodecyl benzene sulfonate, sodium laureth sulfate, sodium cocoyl glutamate, disodium cocoyl glutamate, sodium lauroyl glutamate and sodium lauroyl sarcosinate.

The invention further provides that the higher alcohol comprises two or more of myristyl alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol, behenyl alcohol and oleyl alcohol.

The invention is further provided that the cationic high molecular polymer is water-soluble cationic high molecular polymer, and one or more of polyquaternium-6, polyquaternium-7, polyquaternium-10, polyquaternium-22 and polyquaternium-39 are selected.

The invention is further provided that the nonionic surfactant is one of alkyl glycoside, polyoxyalkylene alkyl ether and alkylphenol polyoxyethylene.

The nonionic surfactant is polyoxyalkylene alkyl ether, the carbon number of the alkyl is 10-15, the alkyl is branched alkyl, and the average addition mole number of the ethylene oxide groups is 4-10.

The invention also provides a color developing agent which is characterized by comprising the following components: 1-9% of hydrogen peroxide, nonionic surfactant, higher alcohol, cationic surfactant and polypropylene glycol by mass percentage, wherein the higher alcohol comprises two or more of myristyl alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol, behenyl alcohol and oleyl alcohol; examples of the nonionic surfactant include alkyl glycosides, polyoxyalkylene alkyl ethers, and alkylphenol ethoxylates; the cationic surfactant is cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, isostearyl trimethyl ammonium chloride, dodecyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride, coco trimethyl ammonium chloride, cetyl trimethyl ammonium bromide, stearyl trimethyl ammonium bromide and dodecyl trimethyl ammonium bromide, wherein the number of straight-chain carbon atoms is 12-18 of alkyl, and the balance is methyl quaternary ammonium salt.

The invention has the beneficial effects that: in the hair dye, floc generated by cationic high molecular polymer and anionic surfactant has conditioning effect on hair; the reasonable collocation of higher alcohols is utilized to perform the foam stabilizing function; the stability of the two agents at high and low temperatures and the use stability can be improved by adding polypropylene glycol and a nonionic surfactant.

Detailed Description

In order to make the objects, technical solutions and advantages of the embodiments of the present invention more apparent, the technical solutions of the present invention will be clearly and completely described below, and it is apparent that the described embodiments are a part of the embodiments of the present invention, but not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

The invention relates to a two-agent oxidation type hair dye, compared with the traditional cream emulsion hair dye, the hair dye needs to extrude bubbles by a non-aerosol foaming container for use, the use method comprises the steps of mixing the hair dye containing dye and alkali agent with a color developing agent containing hydrogen peroxide and then extruding the bubbles by the non-aerosol foaming container for use, the hair dye also contains anionic surfactant, higher alcohol, cationic high molecular polymer, nonionic surfactant, ethanol and the like, and the color developing agent contains nonionic surfactant, higher alcohol, cationic surfactant, polypropylene glycol and the like.

As the alkaline agent contained in the hair dye, for example, weak bases such as ammonium hydroxide and monoethanolamine, and strong bases such as sodium hydroxide and potassium hydroxide can be used. In addition, ammonium salts such as ammonium bicarbonate, ammonium carbonate, and ammonium chloride may be added as appropriate as a buffer.

The pH value of the hair dye in the two-agent bubble hair dye is preferably 9-11.

Examples of the dye contained in the hair dye include p-phenylenediamine, p-aminophenol, toluene-2, 5-diamine sulfate, m-aminophenol, 2-chloro-p-phenylenediamine sulfate, resorcinol, 2-nitro-p-phenylenediamine, 4-amino-2-hydroxytoluene, 2-methylresorcinol, 6-amino-m-cresol, phenyl methyl pyrazolone, 4-amino-3-nitrophenol, 2, 4-diaminophenoxyethanol hydrochloride, 4-amino-m-cresol, 2-amino-3-hydroxypyridine, p-methylaminophenol sulfate, 2, 6-diaminopyridine, 6-hydroxyindole, 4-chlororesorcinol, 2, 7-naphthalenediol, N-phenylhydroquinone, 1, 5-naphthalenediol and 1-naphthol.

Further, examples of the direct dye include p-4-nitrophthalenediamine, p-nitrom-phenylenediamine, basic yellow (basic yellow)87, basic orange (basic orange)31, basic red 51, HC yellow No. 4, HC yellow No. 2, and the like.

Examples of the anionic surfactant in the hair dye include sodium lauryl sulfate, sodium dodecylbenzenesulfonate, sodium laureth sulfate, sodium cocoyl glutamate, disodium cocoyl glutamate, sodium lauroyl glutamate, and sodium lauroyl sarcosinate. Two or more thereof are preferred.

Most of the existing bubble hair dyes in the market have the defects of quick foam collapse and quick water dissolving, so that the use feeling of customers is poor, and the coloring effect is not ideal. Therefore, in the present invention, a higher alcohol is added to both the agents to prolong the foam stabilization time, improve the foam durability, and suppress the phenomenon of foam water applied to the hair, and examples of the higher alcohol include myristyl alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol, behenyl alcohol, oleyl alcohol, and two or more thereof may be used in combination.

The cationic high molecular polymer contained in the hair dye is an aqueous product, and therefore, a water-soluble cationic high molecular polymer is required, and examples of the cationic high molecular polymer include polyquaternium-6, polyquaternium-7, polyquaternium-10, polyquaternium-22, and polyquaternium-39, more preferably polyquaternium-6, polyquaternium-7, polyquaternium-22, and polyquaternium-39, and further preferably polyquaternium-22. The invention adds non-ionic surface active agent, so it can restrain the complex forming, and it can control the complex flocculate formed by cationic high molecular polymer and anionic surface active agent when washing after dyeing hair, to achieve the effect of conditioning hair, and make hair smooth and not dry after dyeing hair.

In order to ensure the stability of the product and prevent the cationic high molecular polymer and the anionic surfactant from forming complex flocs in the hair dye system, a nonionic surfactant may be added to the hair dye, and examples of the nonionic surfactant contained in the hair dye include alkyl glycoside, polyoxyalkylene alkyl ether, alkylphenol ethoxylate and the like. Among them, polyoxyalkylene alkyl ethers are preferred, in which the number of carbon atoms in the alkyl group is preferably 10 to 15, and the alkyl group is preferably a branched alkyl group, and in which the average molar number of addition of oxyethylene groups is preferably 4 to 10.

Bubble hair dye on the market, the hair dye mostly has the smell stimulation, the hair dye easily bleeds in process of production and leads to abundant contact air, cause the hair dye shortcoming such as oxidation in process of production, this product is through adding anhydrous alcohol, can have certain covering effect to hair dye pungent smell to a certain extent, and anhydrous alcohol is added at the end of the production process, can eliminate the foam that the hair dye produced at the production process, prevent that the hair dye from leading to the oxidation because the bubble in process of production. The preferred concentration of absolute ethanol is 99%.

The content of hydrogen peroxide in the developer is 1 to 9% by mass, preferably 3 to 9% by mass. In addition, in order to increase the stability of hydrogen peroxide during storage, a chelating agent may be added to the color-developer system to adjust the pH of the color-developer system, and the chelating agent may be hydroxyethyl diphosphate, EDTA-2NA, hydroxyquinoline sulfate, or the like, and the pH may preferably be 3 to 4.

The nonionic surfactant in the developer includes alkyl glycoside, polyoxyalkylene alkyl ether, alkylphenol ethoxylate and the like, among which polyoxyalkylene alkyl ether is preferable, the number of carbon atoms of the alkyl group is preferably 10 to 22, particularly preferably 12 to 18, and the alkyl group is preferably a straight-chain alkyl group, and among them, the average number of moles of addition of oxyethylene groups is preferably 1 to 80, particularly preferably 20 to 50.

Examples of the cationic surfactant in the color developer include cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, isostearyltrimethylammonium chloride, dodecyltrimethylammonium chloride, behenyltrimethylammonium chloride, octadecyltrimethylammonium chloride, cocoyltrimethylammonium chloride, cetyltrimethylammonium bromide, stearyltrimethylammonium bromide, dodecyltrimethylammonium bromide, which are preferably alkyl groups having 12 to 18 carbon atoms in a straight chain, and the remaining of which are methyl quaternary ammonium salts, and among them, monoalkyltrimethylammonium salts are particularly preferable.

In order to ensure the stability of the color-developing agent at low temperature and the foam discharge performance of the product at high and low temperatures, polypropylene glycol is added to the color-developing agent, and polypropylene glycol with the weight average molecular weight of 200-800 is added to the color-developing agent in the two-part foam hair dye of the present invention, so that the storage stability at low temperature can be remarkably improved, the foam quality of the mixed liquid of the color-developing agent and the color-developing agent can be improved, and the hair dyeing performance is good. The weight average molecular weight of the polypropylene glycol is preferably 400 to 600.

Other components:

the hair dye of the product has the color developing agent and also has some raw materials with different purposes, such as perfumes for changing smell, chelating agents such as EDTA disodium and hydroxyethyl diphosphonic acid, pH regulators such as phosphoric acid and sodium hydroxide, hydrogen peroxide stabilizers such as hydroxyquinoline sulfate, and humectants such as propylene glycol.

Formulation example 1:

hair dye formulation example 1

Serial number	Name of raw materials	Content (wt.)
			1	Water (W)	Make up the balance

2	Sodium laureth sulfate	2~5
			3	C12-14 secondary alkanol polyether-9	10~20
4	Ascorbic acid	0.3~1.0
			5	Sodium sulfite	0.3~0.6
6	EDTA-2NA	0.05~0.3
			7	Toluene-2, 5 diamine sulfate salt	0.1~2.0
8	P-aminophenol	0.05-1.0
			9	Meta-aminophenol	0.05-1.0
10	4-Chlororesorcinol	0.05~1.0
			11	Myristyl alcohol	0.1~0.5
12	Sodium hydroxide	0.1~0.4
			13	Monoethanolamine	1~4
14	Ammonium hydroxide	1~2
			15	Ammonium chloride	0.5-2
16	Polyquaternium-22	1~5
			17	Cocoiloyl disodium glutamate	1~4
18	Essence	0.5~1.0
			19	Anhydrous ethanol	2~10

Developer formulation example 1

Serial number	Name of raw materials	Content (wt.)
			1	Water (W)	Make up the balance
2	Hydrogen peroxide (50%)	6-18
			3	Stearyl trimethyl ammonium chloride	0.5-1.5
4	Cetyl polyether-40	0.5-1.5
			5	Cetyl alcohol	0.3-0.6
6	Behenyl alcohol	0.3-0.6
			7	Polypropylene glycol-7	0.5-1.5
8	Propylene glycol	0.5-1.5
			9	Sodium hydroxide	0.05-0.1
10	Hydroxyethyl diphosphonic acid	0.05-0.2
			11	Phosphoric acid	0.2-0.5
12	Hydroxyquinoline sulfate salt	0.01-0.1

Formulation example 2:

example Hair dye formulation 2

Serial number	Name of raw materials	Content (wt.)
			1	Water (W)	Make up the balance
2	Sodium laureth sulfate	2~5
			3	C12-14 secondary alkanol polyether-9	10~18
4	Ascorbic acid	0.3~1.0
			5	Sodium sulfite	0.3~0.6
6	EDTA-2NA	0.05~0.3
			7	Toluene-2, 5 diamine sulfate salt	0.1~2.0
8	P-aminophenol	0.05-1.0
			9	Meta-aminophenol	0.05-1.0
10	4-Chlororesorcinol	0.05~1.0
			11	2, 4-diaminophenoxyethanol hydrochloride	0.05~1.0
12	Myristyl alcohol	0.1~0.5
			13	Sodium hydroxide	0.1~0.4
14	Monoethanolamine	1~4
			15	Ammonium hydroxide	1~2
16	Ammonium chloride	0.5-2
			17	Polyquaternium-22	1~5
18	Cocoiloyl disodium glutamate	1~4
			19	Essence	0.5~1.0
20	Anhydrous ethanol	2~10
			21	Alkyl glycosides	2-10
22	Hydrolysed keratins	0.1-2

Developer formulation example 2

Serial number	Name of raw materials	Content (wt.)
			1	Water (W)	Make up the balance
2	Hydrogen peroxide (50%)	6-18
			3	Stearyl trimethyl ammonium chloride	0.5-1.2
4	Cetyl polyether-40	0.5-1.2
			5	Cetyl alcohol	0.2-0.5
6	Behenyl alcohol	0.3-0.6
			7	Polypropylene glycol-7	0.5-1.5
8	Propylene glycol	0.5-1.5
			9	Sodium hydroxide	0.05-0.1
10	Hydroxyethyl diphosphonic acid	0.05-0.2
			11	Phosphoric acid	0.2-0.5
12	Hydroxyquinoline sulfate salt	0.01-0.1

Formulation example 3:

example hair dye formulation 3

Serial number	Name of raw materials	Content (wt.)
			1	Water (W)	Make up the balance
2	Sodium laureth sulfate	2~5
			3	C12-14 secondary alkanol polyether-9	10~18
4	Ascorbic acid	0.3~1.0
			5	Sodium sulfite	0.3~0.6
6	EDTA-2NA	0.05~0.3
			7	1-hydroxyethyl-p-phenylenediamine sulfate	0.1~2.0
8	Meta-aminophenol	0.05-1.0
			9	2, 4-diaminophenoxyethanol hydrochloride	0.05-1.0
10	4-amino-2-hydroxytoluene	0.05~1.0
			11	Myristyl alcohol	0.1~0.5
12	Sodium hydroxide	0.1~0.4
			13	Monoethanolamine	1~4
14	Ammonium hydroxide	1~2
			15	Ammonium chloride	0.5-2
16	Polyquaternium-22	1~5
			17	Sodium cocoyl glutamate	1~4
18	Essence	0.5~1.5
			19	Anhydrous ethanol	2~10
20	Hydrolyzed silk	2-10
			21	Tea leaf extract	0.1-0.2

Developer formulation example 3

Serial number	Name of raw materials	Content (wt.)
			1	Water (W)	Make up the balance
2	Hydrogen peroxide (50%)	6-18
			3	Stearyl trimethyl ammonium chloride	0.5-1.2
4	Cetyl polyether-40	0.5-1.2
			5	Cetyl alcohol	0.2-0.5
6	Behenyl alcohol	0.3-0.6
			7	Polypropylene glycol-7	0.4-1.2

8	Propylene glycol	0.5-1.5
			9	Sodium hydroxide	0.05-0.1
10	Hydroxyethyl diphosphonic acid	0.05-0.2
			11	Phosphoric acid	0.2-0.5
12	Hydroxyquinoline sulfate salt	0.01-0.1

Finally, it should be noted that: the above-mentioned embodiments are only specific embodiments of the present invention, which are used for illustrating the technical solutions of the present invention and not for limiting the same, and the protection scope of the present invention is not limited thereto, although the present invention is described in detail with reference to the foregoing embodiments, those skilled in the art should understand that: any person skilled in the art can modify or easily conceive the technical solutions described in the foregoing embodiments or equivalent substitutes for some technical features within the technical scope of the present disclosure; such modifications, changes or substitutions do not depart from the spirit and scope of the embodiments of the present invention, and they should be construed as being included therein. Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.

Claims

1. A method for using a hair dye, a color developing agent and a two-agent oxidation type hair dye is characterized in that the hair dye containing a dye and an alkaline agent and the color developing agent containing hydrogen peroxide are mixed and extruded into bubbles through a non-aerosol foaming container for use.

2. A hair dye is characterized by comprising the following components: dye, alkaline agent, anionic surfactant, higher alcohol, cationic high molecular polymer, nonionic surfactant and ethanol, wherein the pH value of the hair dye is 9-11.

3. The hair dye according to claim 2, wherein the dye is p-phenylenediamine, p-aminophenol, toluene-2, 5-diamine sulfate, m-aminophenol, 2-chloro-p-phenylenediamine sulfate, resorcinol, 2-nitro-p-phenylenediamine, 4-amino-2-hydroxytoluene, 2-methylresorcinol, 6-amino-m-cresol, phenylmethylpyrazolone, 4-amino-3-nitrophenol, 2, 4-diaminophenoxyethanol hydrochloride, 4-amino-m-cresol, 2-amino-3-hydroxypyridine, p-methylaminophenol sulfate, 2, 6-diaminopyridine, 6-hydroxyindole, 4-chlororesorcinol, 2, 7-naphthalenediol, N-phenyl-p-phenylenediamine, p-methylresorcinol, p-aminotoluene-2, 5-diamine sulfate, p-cresol, p-methylphenol, p-phenylenediamine, p-hydroxyphenol, p-phenylenediamine, p-cresol, p-resorcinol, p-cresol, p-resorcinol, p-cresol, p-resorcinol, p-cresol, p-resorcinol, p-cresol, p-resorcinol, p-cresol, p-resorcinol, p-cresol, p-resorcinol, p-, 1, 5-naphthalenediol and one or more of 1-naphthol, 4-nitrophthalenediamine, p-nitro m-phenylenediamine, basic yellow (basic yellow)87, basic orange (basic orange)31, basic red 51, HC yellow No. 4, and HC yellow No. 2.

4. The hair dye of claim 3, wherein the alkaline agent is a weak base or a strong base, the weak base comprises ammonium hydroxide and monoethanolamine, and the strong base comprises sodium hydroxide and potassium hydroxide.

5. The hair dye according to claim 4, wherein the anionic surfactant is two or more of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, sodium laureth sulfate, sodium cocoyl glutamate, disodium cocoyl glutamate, sodium lauroyl glutamate and sodium lauroyl sarcosinate.

6. The hair dye of claim 5, wherein the higher alcohol comprises two or more of myristyl alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol, behenyl alcohol, and oleyl alcohol.

7. The hair dye according to claim 6, wherein the cationic polymer is a water-soluble cationic polymer, and is selected from one or more of polyquaternium-6, polyquaternium-7, polyquaternium-10, polyquaternium-22 and polyquaternium-39.

8. The hair dye of claim 7, wherein the nonionic surfactant is one of alkyl glycoside, polyoxyalkylene alkyl ether, and alkylphenol ethoxylate.

9. The hair dye according to claim 8, wherein the nonionic surfactant is a polyoxyalkylene alkyl ether, the number of carbon atoms in the alkyl group is 10 to 15, the alkyl group is a branched alkyl group, and the average molar number of addition of the oxyethylene group is 4 to 10.

10. The color developing agent is characterized by comprising the following components: 1-9% of hydrogen peroxide, nonionic surfactant, higher alcohol, cationic surfactant and polypropylene glycol by mass percentage, wherein the higher alcohol comprises two or more of myristyl alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol, behenyl alcohol and oleyl alcohol; examples of the nonionic surfactant include alkyl glycosides, polyoxyalkylene alkyl ethers, and alkylphenol ethoxylates; the cationic surfactant is cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, isostearyl trimethyl ammonium chloride, dodecyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride, coco trimethyl ammonium chloride, cetyl trimethyl ammonium bromide, stearyl trimethyl ammonium bromide and dodecyl trimethyl ammonium bromide, wherein the number of straight-chain carbon atoms is 12-18 of alkyl, and the balance is methyl quaternary ammonium salt.