CN110200823A - A kind of hair dye and its preparation and application based on phenyl boric acid - Google Patents
A kind of hair dye and its preparation and application based on phenyl boric acid Download PDFInfo
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- CN110200823A CN110200823A CN201910505168.0A CN201910505168A CN110200823A CN 110200823 A CN110200823 A CN 110200823A CN 201910505168 A CN201910505168 A CN 201910505168A CN 110200823 A CN110200823 A CN 110200823A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
- A61K8/492—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid having condensed rings, e.g. indol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/882—Mixing prior to application
Abstract
The invention discloses a kind of hair dye and its preparation and application based on phenyl boric acid, the hair dye includes A agent and B agent, A agent is composed of the following components: 5,6- dihydroxy indoles, phenyl boric acid, oleyl alcohol, oleic acid, propylene glycol, isopropanol, dodecyl sodium sulfate, ammonium hydroxide and water；B agent is composed of the following components: hydrogen peroxide, oleyl alcohol, oleic acid, propylene glycol, isopropanol, dodecyl sodium sulfate, phosphoric acid and water；Its preparation method: first preparing A agent, then prepares B agent；Its application method: A agent and B agent being mixed in 1:1 ratio, are applied on hair after mixing evenly, and hair is cleaned after 30min.Intermediate 5 of the present invention in hair dye, 6- dihydroxy indole are not easy to be oxidized in air and easy to maintain, and coloration is fairly obvious, can enter inside the medula of hair, and washing is not easy to fade after dyeing.
Description
Technical field
The present invention relates to hair-dyeing technical field more particularly to a kind of hair dyes based on phenyl boric acid.
Background technique
Hair dye is a kind of cosmetics to hair-dyeing, and Chinese belong to the yellow race, mostly black for beauty with white hair dye, because
This black hair dye is extremely important.
Hair dye generally contains this carcinogen of p-phenylenediamine, research shows that hair is by epidermis scales layer, cortical layer, marrow
Matter layer composition, epidermis scales layer is the outermost layer of hair, usually translucent or colourless, natural hair color can be allowed to appear；Skin
Matter layer accounts for the 80% of hair, natural pigments, that is, melanin deposition of human body synthesis here, due to melanin deposition amount difference, be in
Existing different color development；Medullary substance layer is located at the center of hair, is made of many minute bubbles.
Melanin is formed by intracorporal tyrosine by a series of oxidation process, wherein there are two important intermediates: 5,
6- dihydroxy indole and 5,6- dihydroxy indole acid.5,6- dihydroxy indole and 5,6- dihydroxy indole acid are originally by organism sheet
Body generates, without toxic, side effects to body.Make as p-phenylenediamine and its derivative hair dyeing mechanism as permanent hair dye
It for hair keratin fiber, so that coloration is fairly obvious, enters inside the medula of hair, is washed not after dyeing
Easily fade, it will not be by the larger impact of sunlight.However 5,6- dihydroxy indoles are easily oxidized in air, it is not easy to maintain.
Summary of the invention
In view of the deficiencies of the prior art, technical problem solved by the invention is the intermediate 5 how solved in hair dye,
6- dihydroxy indole is easily oxidized in air, problem not easy to maintain.
In order to solve the above technical problems, the technical solution adopted by the present invention is that a kind of hair dye based on phenyl boric acid, including A
Agent and B agent, the A agent is by following components mass percentage composition: 5,6- dihydroxy indole 1-8%, phenyl boric acid 1-8%, oil
Alcohol 8-16%, oleic acid 8-16%, propylene glycol 8-16%, isopropanol 8-16%, dodecyl sodium sulfate 1-3%, appropriate ammonium hydroxide, water
Surplus, each component mass percent add up to 100%；The B agent is by following components mass percentage composition: hydrogen peroxide 18-
26%, oleyl alcohol 8-16%, oleic acid 8-16%, propylene glycol 8-16%, isopropanol 8-16%, dodecyl sodium sulfate 1-3%, phosphoric acid
In right amount, water surplus, each component mass percent add up to 100%；
Preferably, the A agent is by following components mass percentage composition: 5,6- dihydroxy indole 2-4%, phenyl boric acid 2-
4%, oleyl alcohol 10-12%, oleic acid 10-12%, propylene glycol 10-12%, isopropanol 10-12%, dodecyl sodium sulfate 1% 12
Sodium alkyl sulfonate 1-2%, appropriate ammonium hydroxide, water surplus, each component mass percent add up to 100%；The B agent is by following components
Mass percentage composition: hydrogen peroxide 19-22%, oleyl alcohol 10-12%, oleic acid 10-12%, propylene glycol 10-12%, isopropanol
10-12%, dodecyl sodium sulfate 1-2%, appropriate phosphoric acid, water surplus, each component mass percent add up to 100%；
Further, the A agent is by following components mass percentage composition: 5,6- dihydroxy indoles 2%, phenyl boric acid 2%, oil
Alcohol 10%, oleic acid 10%, propylene glycol 10%, isopropanol 10%, dodecyl sodium sulfate 1%, ammonium hydroxide, appropriate, water surplus, each group
Point mass percent adds up to 100%；The B agent is by following components mass percentage composition: hydrogen peroxide 20%, oleyl alcohol
10%, oleic acid 10%, isopropanol 10%, propylene glycol 10%, dodecyl sodium sulfate 1%, appropriate phosphoric acid, water surplus, each component
Mass percent adds up to 100%；
Further, the A agent is by following components mass percentage composition: 5,6- dihydroxy indoles 4%, phenyl boric acid 4%, oil
Alcohol 12%, oleic acid 12%, propylene glycol 12%, isopropanol 12%, dodecyl sodium sulfate 2%, appropriate ammonium hydroxide, water surplus, each group
Point mass percent adds up to 100%；The B agent is by following components mass percentage composition: hydrogen peroxide 22%, oleyl alcohol
12%, oleic acid 12%, isopropanol 12%, propylene glycol 12%, dodecyl sodium sulfate 2%, appropriate phosphoric acid, water surplus, each component
Mass percent adds up to 100%；
Another technical solution provided by the invention is a kind of preparation method of hair dye based on phenyl boric acid, including following
Specific steps:
(1) prepare A agent, specifically include it is following step by step:
(1) 1h is mixed in 5,6- dihydroxy indole and phenyl boric acid in ethanol, is spin-dried for, obtains the mixing of white powder
Object；
(2) water, propylene glycol, dodecyl sodium sulfate Hybrid Heating are obtained into water phase to 65 degrees Celsius；
(3) oleic acid, oleyl alcohol, isopropanol Hybrid Heating are obtained into oily phase to 65 degrees Celsius；
(4) oil is added to stirring heat preservation 15min in the water phase, being subsequently reduced to solution temperature is 40 Celsius
Degree；
(5) mixture of 5,6- dihydroxy indole and phenyl boric acid is added, 10min, appropriate ammonium hydroxide adjusting pH value, which is added, is about
9-11 obtains A agent；
(2) prepare B agent, specifically include it is following step by step:
(1) water, propylene glycol, dodecyl sodium sulfate Hybrid Heating are obtained into water phase to 65 degrees Celsius；
(2) oleic acid, oleyl alcohol, isopropanol are mixed, Hybrid Heating obtains oily phase to 65 degrees Celsius；
(3) oil is added to stirring heat preservation 15min in the water phase, being subsequently reduced to solution temperature is 40 Celsius
Hydrogen peroxide is added in degree, the use of phosphorus acid for adjusting pH value is about 3 to obtain B agent.
Further, by adjusting the concentration of hydrogen peroxide in (3) step by step, the hair dye of different colours can be made, make
The appearance by black to brown is presented in color development.
Another technical solution provided by the invention is a kind of application method of hair dye based on phenyl boric acid, by the A
Agent and the B agent are mixed in 1:1 ratio, are applied on hair after mixing evenly, and hair is cleaned after 30min.
Compared with prior art, intermediate 5 of the present invention in hair dye, 6- dihydroxy indole be not easy in air by
It aoxidizes and easy to maintain, coloration is fairly obvious, can enter inside the medula of hair, and washing is not easy to fade after dyeing.
Specific embodiment
A specific embodiment of the invention is further described below with reference to embodiment, but is not to limit of the invention
It is fixed.
Embodiment 1: a kind of hair dye based on phenyl boric acid, including A agent and B agent, the A agent is by following components quality percentage
Than composition: 5,6- dihydroxy indole 1%, phenyl boric acid 1%, oleyl alcohol 8%, oleic acid 8%, propylene glycol 8%, isopropanol 8%, dodecane
Base sodium sulfonate 1%, appropriate ammonium hydroxide, water surplus, each component mass percent add up to 100%；The B agent is by following components quality
Percentage composition: hydrogen peroxide 18%, oleyl alcohol 8%, oleic acid 8%, propylene glycol 8%, isopropanol 8%, dodecyl sodium sulfate
1%, appropriate phosphoric acid, water surplus, each component mass percent add up to 100%；
Embodiment 2: a kind of hair dye based on phenyl boric acid, including A agent and B agent, the A agent is by following components quality percentage
Than composition: 5,6- dihydroxy indole 2%, phenyl boric acid 2%, oleyl alcohol 10%, oleic acid 10%, propylene glycol 10%, isopropanol 10%, ten
Dialkyl sulfonates 1%, ammonium hydroxide, appropriate, water surplus, each component mass percent add up to 100%；The B agent is by with the following group
Divide mass percentage composition: hydrogen peroxide 20%, oleyl alcohol 10%, oleic acid 10%, isopropanol 10%, propylene glycol 10%, dodecane
Base sodium sulfonate 1%, appropriate phosphoric acid, water surplus, each component mass percent add up to 100%；
Embodiment 3: a kind of hair dye based on phenyl boric acid, including A agent and B agent, the A agent is by following components quality percentage
Than composition: 5,6- dihydroxy indole 4%, phenyl boric acid 4%, oleyl alcohol 12%, oleic acid 12%, propylene glycol 12%, isopropanol 12%, ten
Dialkyl sulfonates 2%, appropriate ammonium hydroxide, water surplus, each component mass percent add up to 100%；The B agent is by following components
Mass percentage composition: hydrogen peroxide 22%, oleyl alcohol 12%, oleic acid 12%, isopropanol 12%, propylene glycol 12%, dodecyl
Sodium sulfonate 2%, appropriate phosphoric acid, water surplus, each component mass percent add up to 100%；
Embodiment 4: a kind of hair dye based on phenyl boric acid, including A agent and B agent, the A agent is by following components quality percentage
Than composition: 5,6- dihydroxy indole 8%, phenyl boric acid 8%, oleyl alcohol 16%, oleic acid 16%, propylene glycol 16%, isopropanol 16%, ten
Dialkyl sulfonates 3%, appropriate ammonium hydroxide, water surplus, each component mass percent add up to 100%；The B agent is by following components
Mass percentage composition: hydrogen peroxide 18-26%, oleyl alcohol 16%, oleic acid 16%, propylene glycol 16%, isopropanol 16%, dodecane
Base sodium sulfonate 3%, appropriate phosphoric acid, water surplus, each component mass percent add up to 100%.
The preparation method of the hair dye based on phenyl boric acid of above-described embodiment 1 to 4, comprising the following specific steps
(1) prepare A agent, specifically include it is following step by step:
(1) 1h is mixed in 5,6- dihydroxy indole and phenyl boric acid in ethanol, is spin-dried for, obtains the mixing of white powder
Object；
(2) water, propylene glycol, dodecyl sodium sulfate Hybrid Heating are obtained into water phase to 65 degrees Celsius；
(3) oleic acid, oleyl alcohol, isopropanol Hybrid Heating are obtained into oily phase to 65 degrees Celsius；
(4) oil is added to stirring heat preservation 15min in the water phase, being subsequently reduced to solution temperature is 40 Celsius
Degree；
(5) mixture of 5,6- dihydroxy indole and phenyl boric acid is added, 10min, appropriate ammonium hydroxide adjusting pH value, which is added, is about
9-11 obtains A agent；
(2) prepare B agent, specifically include it is following step by step:
(1) water, propylene glycol, dodecyl sodium sulfate Hybrid Heating are obtained into water phase to 65 degrees Celsius；
(2) oleic acid, oleyl alcohol, isopropanol Hybrid Heating are obtained into oily phase to 65 degrees Celsius；
(3) oil is added to stirring heat preservation 15min in the water phase, being subsequently reduced to solution temperature is 40 Celsius
Hydrogen peroxide is added in degree, the use of phosphorus acid for adjusting pH value is about 3 to obtain B agent.
Further, by adjusting the concentration of hydrogen peroxide in (3) step by step, the hair dye of different colours can be made, make
The appearance by black to brown is presented in color development.
Another technical solution provided by the invention is a kind of application method of hair dye based on phenyl boric acid, by the A
Agent and the B agent are mixed in 1:1 ratio, are applied on hair after mixing evenly, and hair is cleaned after 30min；
Beneficial effect to illustrate the invention carries out following experiment:
Experiment 1: by application method of the invention to the hair after dye black, it is placed on 5% dodecyl sodium sulfate stirring
5min is denoted as primary cleaning, and the hair appearance after the hair appearance after cleaning 30 times and cleaning 1 time is compared its appearance face
Color is almost the same, the phenomenon that obviously fades does not occur.
By above-mentioned experiment 1,2 it is found that intermediate 5 of the present invention in hair dye, 6- dihydroxy indole are not allowed in air
It is easily oxidized and easy to maintain, coloration is fairly obvious, can enter inside the medula of hair, and washing is not easy after dyeing
Color.
Above in conjunction with the embodiments and experiment is made that detailed description to embodiments of the present invention, but the present invention is not limited to
Described embodiment.To those skilled in the art, without departing from the principles and spirit of the present invention, right
These embodiments progress various change, modification, replacement and variant are still fallen in protection scope of the present invention.
Claims (7)
1. a kind of hair dye based on phenyl boric acid, including A agent and B agent, which is characterized in that the A agent is by following components quality hundred
Divide than composition: 5,6- dihydroxy indole 1-8%, phenyl boric acid 1-8%, oleyl alcohol 8-16%, oleic acid 8-16%, propylene glycol 8-
16%, isopropanol 8-16%, dodecyl sodium sulfate 1-3%, appropriate ammonium hydroxide, water surplus, each component mass percent add up to
100%；The B agent is by following components mass percentage composition: hydrogen peroxide 18-26%, oleyl alcohol 8-16%, oleic acid 8-16%,
Propylene glycol 8-16%, isopropanol 8-16%, dodecyl sodium sulfate 1-3%, appropriate phosphoric acid, water surplus, each component quality percentage
Than adding up to 100%.
2. the hair dye according to claim 1 based on phenyl boric acid, which is characterized in that the A agent is by following components quality
Percentage composition: 5,6- dihydroxy indole 2-4%, phenyl boric acid 2-4%, oleyl alcohol 10-12%, oleic acid 10-12%, propylene glycol
10-12%, isopropanol 10-12%, dodecyl sodium sulfate 1-2%, appropriate ammonium hydroxide, water surplus, each component mass percent are closed
It is calculated as 100%；The B agent is by following components mass percentage composition: hydrogen peroxide 19-22%, oleyl alcohol 10-12%, oleic acid 10-
12%, propylene glycol 10-12%, isopropanol 10-12%, dodecyl sodium sulfate 1-2%, appropriate phosphoric acid, water surplus, each group sub-prime
Amount percentage adds up to 100%.
3. the hair dye according to claim 2 based on phenyl boric acid, which is characterized in that the A agent is by following components quality
Percentage composition: 5,6- dihydroxy indole 2%, phenyl boric acid 2%, oleyl alcohol 10%, oleic acid 10%, propylene glycol 10%, isopropanol
10%, dodecyl sodium sulfate 1%, ammonium hydroxide, appropriate, water surplus, each component mass percent add up to 100%；The B agent by
Following components mass percentage composition: hydrogen peroxide 20%, oleyl alcohol 10%, oleic acid 10%, isopropanol 10%, propylene glycol 10%,
Dodecyl sodium sulfate 1%, appropriate phosphoric acid, water surplus, each component mass percent add up to 100%.
4. the hair dye according to claim 2 based on phenyl boric acid, which is characterized in that the A agent is by following components quality
Percentage composition: 5,6- dihydroxy indole 4%, phenyl boric acid 4%, oleyl alcohol 12%, oleic acid 12%, propylene glycol 12%, isopropanol
12%, dodecyl sodium sulfate 2%, appropriate ammonium hydroxide, water surplus, each component mass percent add up to 100%；The B agent by
Following components mass percentage composition: hydrogen peroxide 22%, oleyl alcohol 12%, oleic acid 12%, isopropanol 12%, propylene glycol 12%,
Dodecyl sodium sulfate 2%, appropriate phosphoric acid, water surplus, each component mass percent add up to 100%.
5. a kind of preparation method of such as described in any item hair dyes based on phenyl boric acid of Claims 1-4, which is characterized in that
Comprising the following specific steps
(1) prepare A agent, specifically include it is following step by step:
(1) 1h is mixed in 5,6- dihydroxy indole and phenyl boric acid in ethanol, is spin-dried for, obtains the mixture of white powder；
(2) water, propylene glycol, dodecyl sodium sulfate Hybrid Heating are obtained into water phase to 65 degrees Celsius；
(3) oleic acid, oleyl alcohol, isopropanol Hybrid Heating are obtained into oily phase to 65 degrees Celsius；
(4) oil is added to stirring heat preservation 15min in the water phase, being subsequently reduced to solution temperature is 40 degrees Celsius；
(5) mixture of 5,6- dihydroxy indole and phenyl boric acid is added, 10min, it is about 9-11 that appropriate ammonium hydroxide, which is added, and adjusts pH value
Obtain A agent；
(2) prepare B agent, specifically include it is following step by step:
(1) water, propylene glycol, dodecyl sodium sulfate Hybrid Heating are obtained into water phase to 65 degrees Celsius；
(2) oleic acid, oleyl alcohol, isopropanol are mixed, Hybrid Heating obtains oily phase to 65 degrees Celsius；
(3) oil is added to stirring heat preservation 15min in the water phase, being subsequently reduced to solution temperature is 40 degrees Celsius, is added
Enter hydrogen peroxide, the use of phosphorus acid for adjusting pH value is about 3 to obtain B agent.
6. the preparation method of the hair dye according to claim 5 based on phenyl boric acid, which is characterized in that in step (2),
By adjusting the concentration of hydrogen peroxide in (3) step by step, the hair dye of different colours can be made.
7. a kind of application method such as the described in any item hair dyes based on phenyl boric acid of Claims 1-4, by the A agent and
The B agent is mixed in 1:1 ratio, is applied on hair after mixing evenly, and hair is cleaned after 30min.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111840104A (en) * | 2020-09-12 | 2020-10-30 | 桂林长发小寨生物科技有限公司 | Hair dye containing plant polyphenol functional material |
| CN111840120A (en) * | 2020-09-12 | 2020-10-30 | 四川大学 | A hair dye containing antibacterial molecules |
| CN111920695A (en) * | 2020-09-12 | 2020-11-13 | 四川大学 | Hair dye, preparation method and use method thereof |
| CN111973468A (en) * | 2020-09-12 | 2020-11-24 | 四川大学 | Hair dye containing polysaccharide and natural polyphenol |
| CN111991269A (en) * | 2020-09-12 | 2020-11-27 | 四川大学 | A hair dye containing modified glucoside |
| CN111991272A (en) * | 2020-09-12 | 2020-11-27 | 桂林长发小寨生物科技有限公司 | Composite hair dye based on plant polyphenol polymer |
| CN112006935A (en) * | 2020-09-12 | 2020-12-01 | 四川大学 | Hair dye based on modified natural polyphenol molecules |
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| CN87100806A (en) * | 1986-01-20 | 1987-10-28 | 奥里尔股份有限公司 | With 5,6-DHI and hydrogen peroxide are to the painted method of keratin fiber (handling with iodide in advance or then) |
| CN87107844A (en) * | 1986-11-17 | 1988-07-13 | 奥里尔股份有限公司 | Carry out the method for dyeing keratinous fibres with indole derivatives and iodide |
| CN88101714A (en) * | 1987-04-02 | 1988-10-19 | 奥里尔股份有限公司 | With being mixed with 5 of iodide ion, 6-oxyindole and alkaline pH hydrogen peroxide composition carry out the method for dyeing keratinous fibres |
| CN101394829A (en) * | 2006-03-07 | 2009-03-25 | 宝洁公司 | Compositions for oxidatively dyeing keratin fibers and methods for using such compositions |
| CN101460136A (en) * | 2006-06-07 | 2009-06-17 | 花王株式会社 | Aerosol type one-pack type hair dye composition |
| CN105380892A (en) * | 2015-12-21 | 2016-03-09 | 济南益豪环保技术有限公司 | Composite single-agent-type hair dye |
| CN105496807A (en) * | 2015-12-21 | 2016-04-20 | 济南益豪环保技术有限公司 | Single-agent-type hair colorant |
| CN109674680A (en) * | 2019-01-30 | 2019-04-26 | 苏州妮优雅化妆品有限公司 | A kind of hair coloring preparation composition |
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| CN111840104A (en) * | 2020-09-12 | 2020-10-30 | 桂林长发小寨生物科技有限公司 | Hair dye containing plant polyphenol functional material |
| CN111840120A (en) * | 2020-09-12 | 2020-10-30 | 四川大学 | A hair dye containing antibacterial molecules |
| CN111920695A (en) * | 2020-09-12 | 2020-11-13 | 四川大学 | Hair dye, preparation method and use method thereof |
| CN111973468A (en) * | 2020-09-12 | 2020-11-24 | 四川大学 | Hair dye containing polysaccharide and natural polyphenol |
| CN111991269A (en) * | 2020-09-12 | 2020-11-27 | 四川大学 | A hair dye containing modified glucoside |
| CN111991272A (en) * | 2020-09-12 | 2020-11-27 | 桂林长发小寨生物科技有限公司 | Composite hair dye based on plant polyphenol polymer |
| CN112006935A (en) * | 2020-09-12 | 2020-12-01 | 四川大学 | Hair dye based on modified natural polyphenol molecules |
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