CN111991272A - Composite hair dye based on plant polyphenol polymer - Google Patents
Composite hair dye based on plant polyphenol polymer Download PDFInfo
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- CN111991272A CN111991272A CN202010956681.4A CN202010956681A CN111991272A CN 111991272 A CN111991272 A CN 111991272A CN 202010956681 A CN202010956681 A CN 202010956681A CN 111991272 A CN111991272 A CN 111991272A
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- 229920000642 polymer Polymers 0.000 title claims abstract description 79
- 239000000118 hair dye Substances 0.000 title claims abstract description 62
- 235000013824 polyphenols Nutrition 0.000 title claims abstract description 23
- 150000008442 polyphenolic compounds Chemical class 0.000 title claims abstract description 21
- 239000002131 composite material Substances 0.000 title claims abstract description 15
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 99
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 85
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 claims abstract description 72
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 66
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 58
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 57
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 34
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 33
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 33
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000005642 Oleic acid Substances 0.000 claims abstract description 33
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 33
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 33
- 239000008367 deionised water Substances 0.000 claims abstract description 33
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 33
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 33
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 33
- SGNZYJXNUURYCH-UHFFFAOYSA-N 5,6-dihydroxyindole Chemical compound C1=C(O)C(O)=CC2=C1NC=C2 SGNZYJXNUURYCH-UHFFFAOYSA-N 0.000 claims abstract description 18
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 claims abstract description 17
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 17
- 229940055577 oleyl alcohol Drugs 0.000 claims abstract description 17
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000004043 dyeing Methods 0.000 claims abstract description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 62
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 39
- 238000002156 mixing Methods 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 27
- 238000003756 stirring Methods 0.000 claims description 27
- 238000010438 heat treatment Methods 0.000 claims description 24
- 238000002360 preparation method Methods 0.000 claims description 22
- 239000000178 monomer Substances 0.000 claims description 18
- 229920001817 Agar Polymers 0.000 claims description 16
- 239000008272 agar Substances 0.000 claims description 16
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 16
- UFULAYFCSOUIOV-UHFFFAOYSA-N cysteamine Chemical compound NCCS UFULAYFCSOUIOV-UHFFFAOYSA-N 0.000 claims description 13
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 claims description 13
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims description 12
- 229940082500 cetostearyl alcohol Drugs 0.000 claims description 10
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 10
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 10
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 10
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 10
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 239000003054 catalyst Substances 0.000 claims description 9
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 230000009471 action Effects 0.000 claims description 6
- 229940081733 cetearyl alcohol Drugs 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 229940074391 gallic acid Drugs 0.000 claims description 6
- 235000004515 gallic acid Nutrition 0.000 claims description 6
- -1 hydroxypropyl methyl Chemical group 0.000 claims description 6
- 239000005457 ice water Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 230000002794 monomerizing effect Effects 0.000 claims description 6
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- 229940079877 pyrogallol Drugs 0.000 claims description 6
- 230000002194 synthesizing effect Effects 0.000 claims description 6
- 230000004224 protection Effects 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 238000006555 catalytic reaction Methods 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 8
- 238000005406 washing Methods 0.000 abstract description 6
- 230000001054 cortical effect Effects 0.000 abstract description 4
- 230000006866 deterioration Effects 0.000 abstract description 2
- 239000002085 irritant Substances 0.000 abstract description 2
- 231100000021 irritant Toxicity 0.000 abstract description 2
- 230000001590 oxidative effect Effects 0.000 abstract description 2
- 230000006750 UV protection Effects 0.000 description 5
- 239000000975 dye Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000037308 hair color Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 201000004384 Alopecia Diseases 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001448 anilines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 210000005069 ears Anatomy 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000003676 hair loss Effects 0.000 description 1
- 230000007803 itching Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000008832 photodamage Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
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- A—HUMAN NECESSITIES
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
- A61K8/492—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid having condensed rings, e.g. indol
-
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/44—Block-or graft-polymers containing polysiloxane sequences containing only polysiloxane sequences
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
- A61K2800/4324—Direct dyes in preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/882—Mixing prior to application
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a plant polyphenol polymer-based composite hair dye, which comprises an agent A and an agent B, wherein the mass ratio of the agent A to the agent B is 1:1, and the agent B comprises the following components: 18-26% of hydrogen peroxide, 8-15% of oleyl alcohol, 8-15% of oleic acid, 8-15% of propylene glycol, 8-15% of isopropanol, 1-5% of sodium dodecyl sulfate, 1-5% of phosphoric acid and the balance of deionized water; a large amount of phenolic hydroxyl in the POSS linear polymer with the functionalized pyrogallic acid surface can effectively prevent 5, 6-dihydroxyindole from oxidative deterioration, and the hair dyeing efficiency is improved; the polymer has strong adhesiveness and larger molecules, can be well attached to an epidermal scale layer, and seals the synthesized melanin in a cortical layer, thereby ensuring that the hair dyeing effect is stable and washing resistant; the POSS linear polymer with the pyrogallic acid surface functionalized is non-irritant to the skin.
Description
Technical Field
The invention relates to the technical field of hair dyes, in particular to a composite hair dye based on a plant polyphenol polymer.
Background
Hair dyeing is one of the most common means for people to change the appearance, and hair dye is used as a cosmetic with the effect of changing hair color and is beginning to become a daily necessity for more and more people. Human hair consists of three parts, namely an epidermal scale layer, a cortex layer and a medulla layer. The outermost layer is a semitransparent or colorless epidermal scale layer; the cortical layer is the portion that deposits the synthetic melanin of the human body, and the inner layer is the medullary layer. The amount of melanin deposited in the cortical layer determines the difference in color development and is also the core site in the dyeing process. However, the existing hair dye generally contains carcinogenic chemical components (anilines) and harmful health components, which are contrary to the principle that health and safety of consumers are pursued by the continuously improved living standard, so that the natural, environment-friendly, safe and non-toxic hair dye becomes the primary requirement of the consumers.
Disclosure of Invention
In order to solve the problems in the prior art, the invention aims to provide a composite hair dye based on a plant polyphenol polymer.
In order to achieve the purpose, the technical scheme of the invention is as follows: a composite hair dye based on a plant polyphenol polymer comprises an agent A and an agent B, wherein the mass ratio of the agent A to the agent B is 1:1, and the agent B comprises the following components: 18-26% of hydrogen peroxide, 8-15% of oleyl alcohol, 8-15% of oleic acid, 8-15% of propylene glycol, 8-15% of isopropanol, 1-5% of sodium dodecyl sulfate, 1-5% of phosphoric acid and the balance of deionized water.
Preferably, the agent B consists of: 24% of hydrogen peroxide, 15% of oleyl alcohol, 15% of oleic acid, 10% of propylene glycol, 10% of isopropanol, 2% of sodium dodecyl sulfate, 3% of phosphoric acid and the balance of deionized water.
Preferably, the agent a consists of: 1-8% of 5, 6-dihydroxyindole, 6-10% of oleic acid, 6-10% of cetostearyl alcohol, 1.2-1.5% of hydroxypropyl methyl cellulose, 6-12% of propylene glycol, 6-12% of isopropanol, 1-5% of sodium dodecyl sulfate, 5-15% of pyrogallic acid surface functionalized POSS linear polymer, 5-8% of agar, 0.24-3.6% of NaOHA and the balance of deionized water.
Preferably, the agent a consists of: 5, 6-dihydroxyindole 5%, oleic acid 10%, cetearyl alcohol 10%, hydroxypropyl methyl cellulose 1.2%, propylene glycol 12%, isopropanol 12%, sodium dodecyl sulfate 1%, pyrogallic acid surface functionalized POSS linear polymer 12%, agar 8%, NaOH 0.24%, and the balance of deionized water.
Preferably, the pyrogallic acid surface functionalized POSS linear polymer consists of: 600 parts of acetone, 20 parts of phosphorus trichloride, 50 parts of pyrogallic acid, 1 part of 2-aminoethanethiol and 10 parts of T8 type POSS.
Preferably, the preparation method of the pyrogallic acid surface functionalized POSS linear polymer comprises the following steps:
step 1, mixing acetone, phosphorus trichloride and pyrogallic acid, and stirring the mixture for an ice-water bath reaction for 5 to 8 hours to obtain gallic acid protected by acetone;
step 2, reacting the product obtained in the last step with 2-aminoethanethiol under the action of a catalyst to obtain a pyrogallol functional monomer protected by acetone;
step 3, synthesizing hexavinyl dicarboxyl POSS and hexavinyl dihydroxy POSS by taking T8 type POSS as an initial monomer, and polymerizing to generate a POSS linear polymer;
and 4, reacting the pyrogallic acid functional monomer protected by acetone with the POSS linear polymer, and adding acetic acid to remove the acetone protection to obtain the POSS linear polymer with the pyrogallic acid surface functionalized.
Preferably, the catalyst in step 2 is potassium iodide, and the reaction conditions of the acetone-protected pyrogalloc acid functional monomer and the POSS linear polymer in step 4 are as follows: pd \ C is used for catalysis, and hydrogen is introduced.
Preferably, the method for preparing the hair dye comprises the following steps:
(1) the preparation method of the agent A comprises the following steps:
step 1, mixing deionized water, propylene glycol, sodium dodecyl sulfate and POSS linear polymer with functionalized pyrogallic acid surface, and heating to 50-80 ℃ to obtain a water phase;
step 2, mixing oleic acid, cetostearyl alcohol, hydroxypropyl methyl fiber and isopropanol, and heating to 50-80 ℃ to obtain an oil phase;
step 3, adding the oil phase into the water phase, stirring and preserving heat for 10-20min, adding 5, 6-dihydroxyindole, stirring for 5-15min, adding agar, adding NaOH to adjust the pH value to 9-11 to obtain an agent A;
(2) the preparation method of the agent B comprises the following steps:
step 1, mixing and heating deionized water, propylene glycol and sodium dodecyl sulfate to 50-80 ℃ to obtain a water phase;
step 2, mixing and heating oleic acid, oleyl alcohol and isopropanol to 50-80 ℃ to obtain an oil phase;
step 3, adding the oil phase into the water phase, stirring and preserving heat for 10-20min, and then cooling the mixture to 35-45 ℃;
and 4, adding hydrogen peroxide into the mixture, adding phosphoric acid to adjust the pH value to 2-4, and discharging to obtain the agent B.
Preferably, the use method of the hair dye comprises the following steps:
step 1, selecting a hydrogen peroxide component hair dye corresponding to the color according to the color to be dyed by the hair;
and 2, mixing the agent A and the agent B of the hair dye, uniformly stirring, smearing the mixture on hair, and cleaning the hair after 30min to finish dyeing.
Preferably, when the hydrogen peroxide component is increased from 18% to 26%, the color of the dyed hair is changed from black to brown; when the hydrogen peroxide component is 18%, the dyed hair is black; at 26% hydrogen peroxide composition, the dyed hair was brown in color.
Compared with the prior art, the invention has the beneficial effects that:
1. a large amount of phenolic hydroxyl in the POSS linear polymer with the functionalized pyrogallic acid surface can effectively prevent 5, 6-dihydroxyindole from oxidative deterioration, and the hair dyeing efficiency is improved;
2. the POSS linear polymer with the functionalized pyrogallic acid surface has ultraviolet absorptivity and can protect the skin from being damaged by ultraviolet rays;
3. the POSS linear polymer with functionalized pyrogallic acid surface has strong adhesion and larger molecules, can be well attached to an epidermal scale layer, seals the synthesized melanin in a cortical layer, and ensures that the hair dyeing effect is stable and washing resistant;
4. the POSS linear polymer with the pyrogallic acid surface functionalized is non-irritant to the skin.
Detailed Description
The invention will be further described with reference to specific embodiments, and the advantages and features of the invention will become apparent as the description proceeds. The examples are illustrative only and do not limit the scope of the present invention in any way. It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention, and that such changes and modifications may be made without departing from the spirit and scope of the invention.
A composite hair dye based on a plant polyphenol polymer comprises an agent A and an agent B, wherein the mass ratio of the agent A to the agent B is 1:1, and the agent B comprises the following components: 18-26% of hydrogen peroxide, 8-15% of oleyl alcohol, 8-15% of oleic acid, 8-15% of propylene glycol, 8-15% of isopropanol, 1-5% of sodium dodecyl sulfate, 1-5% of phosphoric acid and the balance of deionized water.
Preferably, the agent B consists of: 24% of hydrogen peroxide, 15% of oleyl alcohol, 15% of oleic acid, 10% of propylene glycol, 10% of isopropanol, 2% of sodium dodecyl sulfate, 3% of phosphoric acid and the balance of deionized water.
Preferably, the agent a consists of: 1-8% of 5, 6-dihydroxyindole, 6-10% of oleic acid, 6-10% of cetostearyl alcohol, 1.2-1.5% of hydroxypropyl methyl cellulose, 6-12% of propylene glycol, 6-12% of isopropanol, 1-5% of sodium dodecyl sulfate, 5-15% of pyrogallic acid surface functionalized POSS linear polymer, 5-8% of agar, 0.24-3.6% of NaOHA and the balance of deionized water.
Preferably, the agent a consists of: 5, 6-dihydroxyindole 5%, oleic acid 10%, cetearyl alcohol 10%, hydroxypropyl methyl cellulose 1.2%, propylene glycol 12%, isopropanol 12%, sodium dodecyl sulfate 1%, pyrogallic acid surface functionalized POSS linear polymer 12%, agar 8%, NaOH 0.24%, and the balance of deionized water.
Preferably, the pyrogallic acid surface functionalized POSS linear polymer consists of: 600 parts of acetone, 20 parts of phosphorus trichloride, 50 parts of pyrogallic acid, 1 part of 2-aminoethanethiol and 10 parts of T8 type POSS.
Preferably, the preparation method of the pyrogallic acid surface functionalized POSS linear polymer comprises the following steps:
step 1, mixing acetone, phosphorus trichloride and pyrogallic acid, and stirring the mixture for an ice-water bath reaction for 5 to 8 hours to obtain gallic acid protected by acetone;
step 2, reacting the product obtained in the last step with 2-aminoethanethiol under the action of a catalyst to obtain a pyrogallol functional monomer protected by acetone;
step 3, synthesizing hexavinyl dicarboxyl POSS and hexavinyl dihydroxy POSS by taking T8 type POSS as an initial monomer, and polymerizing to generate a POSS linear polymer;
and 4, reacting the pyrogallic acid functional monomer protected by acetone with the POSS linear polymer, and adding acetic acid to remove the acetone protection to obtain the POSS linear polymer with the pyrogallic acid surface functionalized.
Preferably, the catalyst in step 2 is potassium iodide, and the reaction conditions of the acetone-protected pyrogalloc acid functional monomer and the POSS linear polymer in step 4 are as follows: pd \ C is used for catalysis, and hydrogen is introduced.
Preferably, the method for preparing the hair dye comprises the following steps:
(1) the preparation method of the agent A comprises the following steps:
step 1, mixing deionized water, propylene glycol, sodium dodecyl sulfate and POSS linear polymer with functionalized pyrogallic acid surface, and heating to 50-80 ℃ to obtain a water phase;
step 2, mixing oleic acid, cetostearyl alcohol, hydroxypropyl methyl fiber and isopropanol, and heating to 50-80 ℃ to obtain an oil phase;
step 3, adding the oil phase into the water phase, stirring and preserving heat for 10-20min, adding 5, 6-dihydroxyindole, stirring for 5-15min, adding agar, adding NaOH to adjust the pH value to 9-11 to obtain an agent A;
(2) the preparation method of the agent B comprises the following steps:
step 1, mixing and heating deionized water, propylene glycol and sodium dodecyl sulfate to 50-80 ℃ to obtain a water phase;
step 2, mixing and heating oleic acid, oleyl alcohol and isopropanol to 50-80 ℃ to obtain an oil phase;
step 3, adding the oil phase into the water phase, stirring and preserving heat for 10-20min, and then cooling the mixture to 35-45 ℃;
and 4, adding hydrogen peroxide into the mixture, adding phosphoric acid to adjust the pH value to 2-4, and discharging to obtain the agent B.
Preferably, the use method of the hair dye comprises the following steps:
step 1, selecting a hydrogen peroxide component hair dye corresponding to the color according to the color to be dyed by the hair;
and 2, mixing the agent A and the agent B of the hair dye, uniformly stirring, smearing the mixture on hair, and cleaning the hair after 30min to finish dyeing.
Preferably, when the hydrogen peroxide component is increased from 18% to 26%, the color of the dyed hair is changed from black to brown; when the hydrogen peroxide component is 18%, the dyed hair is black; at 26% hydrogen peroxide composition, the dyed hair was brown in color.
Example 1
A composite hair dye based on a plant polyphenol polymer comprises an agent A and an agent B, wherein the mass ratio of the agent A to the agent B is 1: 1;
the agent B consists of the following components: 18% of hydrogen peroxide, 8% of oleyl alcohol, 8% of oleic acid, 8% of propylene glycol, 8% of isopropanol, 1% of sodium dodecyl sulfate, 1% of phosphoric acid and the balance of deionized water, wherein the mass percentage of the components is 100%;
the agent A consists of the following components: 1% of 5, 6-dihydroxyindole, 6% of oleic acid, 6% of cetearyl alcohol, 1.2% of hydroxypropyl methyl cellulose, 6% of propylene glycol, 6% of isopropanol, 1% of sodium dodecyl sulfate, 5% of POSS linear polymer with pyrogallic acid surface functionalized, 5% of agar, 0.24% of NaOH and the balance of deionized water, wherein the mass percentage of all the components is 100%;
the pyrogallic acid surface functionalized POSS linear polymer consists of: 600 parts of acetone, 20 parts of phosphorus trichloride, 50 parts of pyrogallic acid, 1 part of 2-aminoethanethiol and 10 parts of T8 type POSS.
Example 2
A composite hair dye based on a plant polyphenol polymer comprises an agent A and an agent B, wherein the mass ratio of the agent A to the agent B is 1:1
The agent B consists of the following components: 22% of hydrogen peroxide, 12% of oleyl alcohol, 12% of oleic acid, 12% of propylene glycol, 12% of isopropanol, 3% of sodium dodecyl sulfate, 3% of phosphoric acid and the balance of deionized water, wherein the mass percentage of each component is 100%;
the agent A consists of the following components: 5, 6-dihydroxyindole 5%, oleic acid 8%, cetostearyl alcohol 8%, hydroxypropyl methyl cellulose 1.3%, propylene glycol 9%, isopropanol 9%, sodium dodecyl sulfate 3%, pyrogallic acid surface functionalized POSS linear polymer 10%, agar 6%, NaOH 1.9% and the balance of deionized water, wherein the mass percentage of each component is 100%;
the pyrogallic acid surface functionalized POSS linear polymer consists of: 600 parts of acetone, 20 parts of phosphorus trichloride, 50 parts of pyrogallic acid, 1 part of 2-aminoethanethiol and 10 parts of T8 type POSS.
Example 3
A composite hair dye based on a plant polyphenol polymer comprises an agent A and an agent B, wherein the mass ratio of the agent A to the agent B is 1:1
The agent B consists of the following components: 24% of hydrogen peroxide, 15% of oleyl alcohol, 15% of oleic acid, 10% of propylene glycol, 10% of isopropanol, 2% of sodium dodecyl sulfate, 3% of phosphoric acid and the balance of deionized water, wherein the mass percentage of each component is 100%;
the agent A consists of the following components: 5, 6-dihydroxyindole 5%, oleic acid 10%, cetearyl alcohol 10%, hydroxypropyl methyl cellulose 1.2%, propylene glycol 12%, isopropanol 12%, sodium dodecyl sulfate 1%, pyrogallic acid surface functionalized POSS linear polymer 12%, agar 8%, NaOH 0.24%, and the balance of deionized water, wherein the mass percentage of each component is 100%;
the pyrogallic acid surface functionalized POSS linear polymer consists of: 600 parts of acetone, 20 parts of phosphorus trichloride, 50 parts of pyrogallic acid, 1 part of 2-aminoethanethiol and 10 parts of T8 type POSS.
Example 4
A composite hair dye based on a plant polyphenol polymer comprises an agent A and an agent B, wherein the mass ratio of the agent A to the agent B is 1:1
The agent B consists of the following components: 26% of hydrogen peroxide, 15% of oleyl alcohol, 15% of oleic acid, 15% of propylene glycol, 15% of isopropanol, 5% of sodium dodecyl sulfate, 5% of phosphoric acid and the balance of deionized water, wherein the mass percentage of the components is 100%;
the agent A consists of the following components: 8% of 5, 6-dihydroxyindole, 10% of oleic acid, 10% of cetearyl alcohol, 1.5% of hydroxypropyl methyl cellulose, 12% of propylene glycol, 12% of isopropanol, 5% of sodium dodecyl sulfate, 15% of a pyrogallic acid surface functionalized POSS linear polymer, 8% of agar, 3.6% of NaOH and the balance of deionized water, wherein the mass percentage of all the components is 100%;
the pyrogallic acid surface functionalized POSS linear polymer consists of: 600 parts of acetone, 20 parts of phosphorus trichloride, 50 parts of pyrogallic acid, 1 part of 2-aminoethanethiol and 10 parts of T8 type POSS.
Example 5
The components of the hair dye of example 3 were used, and the preparation method of the hair dye included:
(1) the preparation method of the agent A comprises the following steps:
step 1, mixing deionized water, propylene glycol, sodium dodecyl sulfate and POSS linear polymer with functionalized pyrogallic acid surface, and heating to 50 ℃ to obtain a water phase;
step 2, mixing oleic acid, cetostearyl alcohol, hydroxypropyl methyl fiber and isopropanol, and heating to 50 ℃ to obtain an oil phase;
step 3, adding the oil phase into the water phase, stirring and preserving heat for 10min, adding 5, 6-dihydroxyindole, stirring for 5min, adding agar, adding NaOH, and adjusting the pH value to 9 to obtain an agent A;
(2) the preparation method of the agent B comprises the following steps:
step 1, mixing and heating deionized water, propylene glycol and sodium dodecyl sulfate to 50 ℃ to obtain a water phase;
step 2, mixing and heating oleic acid, oleyl alcohol and isopropanol to 50 ℃ to obtain an oil phase;
step 3, adding the oil phase into the water phase, stirring and preserving heat for 10min, and then cooling the mixture to 35 ℃;
and 4, adding hydrogen peroxide into the mixture, adding phosphoric acid to adjust the pH value to be 2, and discharging to obtain the agent B.
(3) The preparation method of the POSS linear polymer with the pyrogallic acid surface functionalized comprises the following steps:
step 1, mixing acetone, phosphorus trichloride and pyrogallic acid, and stirring the mixture for an ice-water bath reaction for 5 hours to obtain gallic acid protected by acetone;
step 2, reacting the product obtained in the last step with 2-aminoethanethiol under the action of a catalyst to obtain a pyrogallol functional monomer protected by acetone;
step 3, synthesizing hexavinyl dicarboxyl POSS and hexavinyl dihydroxy POSS by taking T8 type POSS as an initial monomer, and polymerizing to generate a POSS linear polymer;
example 6
The components of the hair dye of example 3 were used, and the preparation method of the hair dye included:
(1) the preparation method of the agent A comprises the following steps:
step 1, mixing deionized water, propylene glycol, sodium dodecyl sulfate and a POSS linear polymer with functionalized pyrogallic acid surface, and heating to 60 ℃ to obtain a water phase;
step 2, mixing oleic acid, cetostearyl alcohol, hydroxypropyl methyl fiber and isopropanol, and heating to 60 ℃ to obtain an oil phase;
step 3, adding the oil phase into the water phase, stirring and preserving heat for 15min, adding 5, 6-dihydroxyindole, stirring for 10min, adding agar, adding NaOH, and adjusting the pH value to 10 to obtain an agent A;
(2) the preparation method of the agent B comprises the following steps:
step 1, mixing and heating deionized water, propylene glycol and sodium dodecyl sulfate to 60 ℃ to obtain a water phase;
step 2, mixing and heating oleic acid, oleyl alcohol and isopropanol to 60 ℃ to obtain an oil phase;
step 3, adding the oil phase into the water phase, stirring and preserving heat for 15min, and then cooling the mixture to 40 ℃;
step 4, adding hydrogen peroxide into the mixture, adding phosphoric acid to adjust the pH value to 3, and discharging to obtain a B agent;
(3) the preparation method of the POSS linear polymer with the pyrogallic acid surface functionalized comprises the following steps:
step 1, mixing acetone, phosphorus trichloride and pyrogallic acid, and stirring the mixture for an ice-water bath reaction for 7 hours to obtain gallic acid protected by acetone;
step 2, reacting the product obtained in the last step with 2-aminoethanethiol under the action of a catalyst to obtain a pyrogallol functional monomer protected by acetone;
step 3, synthesizing hexavinyl dicarboxyl POSS and hexavinyl dihydroxy POSS by taking T8 type POSS as an initial monomer, and polymerizing to generate a POSS linear polymer;
example 7
The components of the hair dye of example 2 were used, and the preparation method of the hair dye included:
(1) the preparation method of the agent A comprises the following steps:
step 1, mixing deionized water, propylene glycol, sodium dodecyl sulfate and a POSS linear polymer with functionalized pyrogallic acid surface, and heating to 80 ℃ to obtain a water phase;
step 2, mixing oleic acid, cetostearyl alcohol, hydroxypropyl methyl fiber and isopropanol, and heating to 80 ℃ to obtain an oil phase;
step 3, adding the oil phase into the water phase, stirring and preserving heat for 20min, adding 5, 6-dihydroxyindole, stirring for 15min, adding agar, adding NaOH, and adjusting the pH value to 11 to obtain an agent A;
(2) the preparation method of the agent B comprises the following steps:
step 1, mixing and heating deionized water, propylene glycol and sodium dodecyl sulfate to 80 ℃ to obtain a water phase;
step 2, mixing and heating oleic acid, oleyl alcohol and isopropanol to 80 ℃ to obtain an oil phase;
step 3, adding the oil phase into the water phase, stirring and preserving heat for 10-20min, and then cooling the mixture to 45 ℃;
step 4, adding hydrogen peroxide into the mixture, adding phosphoric acid to adjust the pH value to 4, and discharging to obtain a B agent;
(3) the preparation method of the POSS linear polymer with the pyrogallic acid surface functionalized comprises the following steps:
step 1, mixing acetone, phosphorus trichloride and pyrogallic acid, and stirring the mixture for an ice-water bath reaction for 8 hours to obtain gallic acid protected by acetone;
step 2, reacting the product obtained in the last step with 2-aminoethanethiol under the action of a catalyst to obtain a pyrogallol functional monomer protected by acetone;
step 3, synthesizing hexavinyl dicarboxyl POSS and hexavinyl dihydroxy POSS by taking T8 type POSS as an initial monomer, and polymerizing to generate a POSS linear polymer;
control group
The hair dye composition of example 6, from which the POSS linear polymer surface-functionalized with pyrogallic acid was removed, was subjected to the same conditions as in example 6, to prepare a hair dye free from the POSS linear polymer surface-functionalized with pyrogallic acid.
Example 8
2g of white hair was collected, and the hair dye prepared in example 6 and the hair dye of the control group were used to conduct a smearing test on the sample white hair. The scoring was according to the following criteria:
1 very poor, 2 poor, 3 generally good, 4 good, 5 very good
TABLE 1 example 6 and control Hair dyeing Scale Table
As can be seen from Table 1 above, the addition of pyrogallic acid to the surface-functionalized POSS linear polymer of example 6 resulted in better color fastness to washing, hair softness, and black coverage than the control, and the effect of the surface-functionalized POSS linear polymer of pyrogallic acid was significant.
Example 9
In order to verify the effect of the hair dye of the present application, hair dye was performed using the hair dye prepared in example 6. In the experiment, 2g of white hair is dipped in the mixture of the agent A and the agent B and is smeared, and the mixture is washed after 30min, and the test temperature is as follows: room temperature 28 degrees celsius.
TABLE 2 dyed hair color data sheet
In table 2 above, L, a, b are parameters of the standard international color space diagram, the L value refers to black and white, and the larger the L value, the whiter the L value; the value a refers to red and green, and the larger the value a is, the more red the value a is; the b value means yellow blue, the larger the b value, the more yellow. As can be seen from the above table, the hair dyeing effect of the present invention is good.
The above samples were washed 10 times and then subjected to a color fastness to washing test,
TABLE 3 data sheet of the colorfastness to washing after dyeing
As can be seen from Table 3, the hair dye has good color fastness to washing and stable and durable hair dyeing effect.
Example 10
In order to verify the ultraviolet protection ability of the hair dye, hair dye comparison was performed using p-phenylenediamine conventional dye, the hair dye prepared in example 6 and the hair dye prepared in the control group;
TABLE 4 UVA and UVB transmittance
UVA, UVB and visible light may cause photodamage to hair, the extent of damage varying with wavelength. UVB mainly causes the loss of hair proteins, UVA promotes color change. The ultraviolet protection of hair includes the protection of natural pigments of hair itself and the protection of external products, and can prevent ultraviolet damage by depositing hair dyes on the hair cortex and the cortex, and the ultraviolet protection ability of different dyes is different. The results are shown in the table above using the same uv resistance test method as the fabric.
Thus, compared with the p-phenylenediamine traditional dye, the hair dyed by the POSS linear polymer without pyrogallic acid surface functionalization in the embodiment 6 has certain ultraviolet resistance effect, and the transmittance of UVA and UVB is obviously reduced; the transmittance of UVA and UVB of the linear polymer is further reduced after the POSS linear polymer with the surface functionalized by the pyrogallic acid is added, and the dyed black hair has strong ultraviolet absorption capacity, so that the skin covered by the black hair can be protected.
Example 11
10 volunteers of men and women were randomly searched, and the hair dye prepared in example 6 and the ammonia water-containing hair dye were applied to the ears of the volunteers, respectively, wherein the hair dye was applied to the left ear and the hair dye was applied to the right ear. After 1 hour, more than 80% of the subjects showed varying degrees of itching and irritation in the left ear, but no adverse reaction in the right ear of 20 volunteers. It can be seen that the hair dye of the present invention has no irritation to skin compared to the conventional hair dye containing ammonia water.
Claims (10)
1. The composite hair dye based on the plant polyphenol polymer is characterized by comprising an agent A and an agent B, wherein the mass ratio of the agent A to the agent B is 1:1, and the agent B consists of the following components in parts by mass: 18-26% of hydrogen peroxide, 8-15% of oleyl alcohol, 8-15% of oleic acid, 8-15% of propylene glycol, 8-15% of isopropanol, 1-5% of sodium dodecyl sulfate, 1-5% of phosphoric acid and the balance of deionized water.
2. The plant polyphenol polymer-based complex hair dye as set forth in claim 1, wherein the agent B consists of: 24% of hydrogen peroxide, 15% of oleyl alcohol, 15% of oleic acid, 10% of propylene glycol, 10% of isopropanol, 2% of sodium dodecyl sulfate, 3% of phosphoric acid and the balance of deionized water.
3. The plant polyphenol polymer-based complex hair dye as set forth in claim 1, wherein the agent A is composed of: 1-8% of 5, 6-dihydroxyindole, 6-10% of oleic acid, 6-10% of cetostearyl alcohol, 1.2-1.5% of hydroxypropyl methyl cellulose, 6-12% of propylene glycol, 6-12% of isopropanol, 1-5% of sodium dodecyl sulfate, 5-15% of pyrogallic acid surface functionalized POSS linear polymer, 5-8% of agar, 0.24-3.6% of NaOHA and the balance of deionized water.
4. The plant polyphenol polymer-based complex hair dye as set forth in claim 3, wherein the agent A is composed of: 5, 6-dihydroxyindole 5%, oleic acid 10%, cetearyl alcohol 10%, hydroxypropyl methyl cellulose 1.2%, propylene glycol 12%, isopropanol 12%, sodium dodecyl sulfate 1%, pyrogallic acid surface functionalized POSS linear polymer 12%, agar 8%, NaOH 0.24%, and the balance of deionized water.
5. The plant polyphenol polymer-based complex hair dye of claim 4, wherein the POSS linear polymer with the pyrogallic acid surface functionalized consists of the following components: 600 parts of acetone, 20 parts of phosphorus trichloride, 50 parts of pyrogallic acid, 1 part of 2-aminoethanethiol and 10 parts of T8 type POSS.
6. The plant polyphenol polymer-based complex hair dye as claimed in claim 5, wherein the preparation method of the POSS linear polymer with the pyrogallic acid surface functionalized comprises the following steps:
step 1, mixing acetone, phosphorus trichloride and pyrogallic acid, and stirring the mixture for an ice-water bath reaction for 5 to 8 hours to obtain gallic acid protected by acetone;
step 2, reacting the product obtained in the last step with 2-aminoethanethiol under the action of a catalyst to obtain a pyrogallol functional monomer protected by acetone;
step 3, synthesizing hexavinyl dicarboxyl POSS and hexavinyl dihydroxy POSS by taking T8 type POSS as an initial monomer, and polymerizing to generate a POSS linear polymer;
and 4, reacting the pyrogallic acid functional monomer protected by acetone with the POSS linear polymer, and adding acetic acid to remove the acetone protection to obtain the POSS linear polymer with the pyrogallic acid surface functionalized.
7. The plant polyphenol polymer-based composite hair dye of claim 6, wherein the catalyst in the step 2 is potassium iodide, and the acetone-protected pyrogalloc acid-functional monomer and POSS linear polymer in the step 4 are reacted under the following conditions: pd \ C is used for catalysis, and hydrogen is introduced.
8. The plant polyphenol polymer-based composite hair dye according to any one of claims 1 to 7, wherein the preparation method of the hair dye comprises the following steps:
(1) the preparation method of the agent A comprises the following steps:
step 1, mixing deionized water, propylene glycol, sodium dodecyl sulfate and POSS linear polymer with functionalized pyrogallic acid surface, and heating to 50-80 ℃ to obtain a water phase;
step 2, mixing oleic acid, cetostearyl alcohol, hydroxypropyl methyl fiber and isopropanol, and heating to 50-80 ℃ to obtain an oil phase;
step 3, adding the oil phase into the water phase, stirring and preserving heat for 10-20min, adding 5, 6-dihydroxyindole, stirring for 5-15min, adding agar, adding NaOH to adjust the pH value to 9-11 to obtain an agent A;
(2) the preparation method of the agent B comprises the following steps:
step 1, mixing and heating deionized water, propylene glycol and sodium dodecyl sulfate to 50-80 ℃ to obtain a water phase;
step 2, mixing and heating oleic acid, oleyl alcohol and isopropanol to 50-80 ℃ to obtain an oil phase;
step 3, adding the oil phase into the water phase, stirring and preserving heat for 10-20min, and then cooling the mixture to 35-45 ℃;
and 4, adding hydrogen peroxide into the mixture, adding phosphoric acid to adjust the pH value to 2-4, and discharging to obtain the agent B.
9. The plant polyphenol polymer-based composite hair dye according to any one of claims 1 to 8, wherein the method for using the hair dye comprises the following steps:
step 1, selecting a hydrogen peroxide component hair dye corresponding to the color according to the color to be dyed by the hair;
and 2, mixing the agent A and the agent B of the hair dye, uniformly stirring, smearing the mixture on hair, and cleaning the hair after 30min to finish dyeing.
10. The plant polyphenol polymer-based complex hair dye as claimed in claim 9, wherein when the hydrogen peroxide component is increased from 18% to 26%, the color of dyed hair is changed from black to brown; when the hydrogen peroxide component is 18%, the dyed hair is black; at 26% hydrogen peroxide composition, the dyed hair was brown in color.
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Application publication date: 20201127 |