CN110123670A - A kind of dendritic macromole catalysis hair dye and its preparation and application - Google Patents
A kind of dendritic macromole catalysis hair dye and its preparation and application Download PDFInfo
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
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- A—HUMAN NECESSITIES
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
- A61K8/492—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid having condensed rings, e.g. indol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
- A61K2800/4324—Direct dyes in preparations for permanently dyeing the hair
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Abstract
The invention discloses a kind of dendritic macromole catalysis hair dye and its preparation and application, including A agent and B agent, A agent is composed of the following components: 5,6- dihydroxy indoles, cetostearyl alcohol, oleic acid, propylene glycol, isopropanol, dodecyl sodium sulfate, polyethyene diamine dendritic, ammonium hydroxide and water；B agent is composed of the following components: hydrogen peroxide, cetostearyl alcohol, oleic acid, propylene glycol, isopropanol, dodecyl sodium sulfate, phosphoric acid and；Its preparation method: first preparing A agent, then prepares B agent；Its application method: A agent and B agent being mixed in 1:1 ratio, are applied on hair after mixing evenly, and hair is cleaned after 30min.5,6- dihydroxy indole of the present invention in hair dye is not easy to be oxidized in air and easy to maintain, and coloration is fairly obvious, can enter inside the medula of hair, and washing is not easy to fade after dyeing.
Description
Technical field
The present invention relates to hair-dyeing technical field more particularly to a kind of dendritic macromole catalysis hair dye and its preparations
And application method.
Background technique
Hair dye is a kind of cosmetics to hair-dyeing, and Chinese belong to the yellow race, mostly black for beauty with white hair dye, because
This black hair dye is extremely important.
Hair dye generally contains this carcinogen of p-phenylenediamine, research shows that hair is by epidermis scales layer, cortical layer, marrow
Matter layer composition, epidermis scales layer is the outermost layer of hair, usually translucent or colourless, natural hair color can be allowed to appear；Skin
Matter layer accounts for the 80% of hair, natural pigments, that is, melanin deposition of human body synthesis here, due to melanin deposition amount difference, be in
Existing different color development；Medullary substance layer is located at the center of hair, is made of many minute bubbles.
Melanin is formed by intracorporal tyrosine by a series of oxidation process, wherein there are two important intermediates: 5,
6- dihydroxy indole and 5,6- dihydroxy indole acid.5,6- dihydroxy indole and 5,6- dihydroxy indole acid are originally by organism sheet
Body generates, without toxic, side effects to body.Make as p-phenylenediamine and its derivative hair dyeing mechanism as permanent hair dye
It for hair keratin fiber, so that coloration is fairly obvious, enters inside the medula of hair, is washed not after dyeing
Easily fade, it will not be by the larger impact of sunlight.However 5,6- dihydroxy indoles are easily oxidized in air, it is not easy to maintain.
Summary of the invention
In view of the deficiencies of the prior art, technical problem solved by the invention is the intermediate 5 how solved in hair dye,
6- dihydroxy indole is easily oxidized in air, problem not easy to maintain.
In order to solve the above technical problems, the technical solution adopted by the present invention is that a kind of dendritic macromole be catalyzed hair dye,
Including A agent and B agent, which is characterized in that the A agent is by following components mass percentage composition: 5,6- dihydroxy indole 1-6%,
Cetostearyl alcohol 6-14%, oleic acid 6-14%, propylene glycol 6-14%, isopropanol 6-14%, dodecyl sodium sulfate 1-5%, gather
Ethylenediamine dendritic 1-4%, appropriate ammonium hydroxide, water surplus, each component mass percent add up to 100%；The B agent by
Following components mass percentage composition: hydrogen peroxide 16-24%, cetostearyl alcohol 6-14%, oleic acid 6-14%, propylene glycol 6-
14%, isopropanol 6-14%, dodecyl sodium sulfate 1-5%, appropriate phosphoric acid, water surplus, each component mass percent add up to
100%；
Preferably, the A agent is by following components mass percentage composition: 5,6- dihydroxy indole 2-5%, cetearyl alcohol
Alcohol 10-12%, oleic acid 10-12%, propylene glycol 10-12%, isopropanol 10-12%, dodecyl sodium sulfate 1-3%, poly- second two
Amine dendritic 1-2%, appropriate ammonium hydroxide, water surplus, each component mass percent add up to 100%；The B agent is by following
Constituent mass percentage composition: hydrogen peroxide 20-23%, cetostearyl alcohol 10-13%, oleic acid 10-13%, propylene glycol 10-
13%, isopropanol 10-13%, dodecyl sodium sulfate 1-3%, appropriate phosphoric acid, water surplus, each component mass percent add up to
100%；
Further, the A agent is by following components mass percentage composition: 5,6- dihydroxy indoles 2%, cetostearyl alcohol
10%, oleic acid 10%, propylene glycol 10%, isopropanol 10%, dodecyl sodium sulfate 1%, polyethyene diamine dendritic
1%, appropriate ammonium hydroxide, water surplus, each component mass percent add up to 100%；The B agent is by following components mass percent group
At: hydrogen peroxide 20%, cetostearyl alcohol 10%, oleic acid 10%, propylene glycol 10%, isopropanol 10%, dodecyl sodium sulfate
1%, appropriate phosphoric acid, water surplus, each component mass percent add up to 100%；
Further, the A agent is by following components mass percentage composition: 5,6- dihydroxy indoles 5%, cetostearyl alcohol
12%, oleic acid 12%, propylene glycol 12%, isopropanol 12%, dodecyl sodium sulfate 3%, polyethyene diamine dendritic
2%, appropriate ammonium hydroxide, water surplus, each component mass percent add up to 100%；The B agent is by following components mass percent group
At: hydrogen peroxide 23%, cetostearyl alcohol 13%, oleic acid 13%, propylene glycol 13%, isopropanol 13%, dodecyl sodium sulfate
3%, appropriate phosphoric acid, water surplus, each component mass percent add up to 100%.
Another technical solution provided by the invention is a kind of preparation method of dendritic macromole catalysis hair dye, including
Step in detail below:
(1) prepare A agent, specifically include it is following step by step:
(1) water, propylene glycol, dodecyl sodium sulfate Hybrid Heating are obtained into water phase to 65 degrees Celsius；
(2) oleic acid, cetostearyl alcohol, isopropanol Hybrid Heating are obtained into oily phase to 65 degrees Celsius；
(3) oil is added to stirring heat preservation 15min in water phase, being subsequently reduced to solution temperature is 40 degrees Celsius；
(4) 5,6- dihydroxy indole is added and stirs 10min, it is about 9 to 11 that appropriate ammonium hydroxide, which is added, and adjusts pH value, blowing, tank
Dress obtains A agent；
(2) prepare B agent, specifically include it is following step by step:
(1) water, propylene glycol, dodecyl sodium sulfate Hybrid Heating are obtained into water phase to 65 degrees Celsius；
(2) oleic acid, cetostearyl alcohol, isopropanol Hybrid Heating are obtained into oily phase to 65 degrees Celsius；
(3) oil is added to stirring heat preservation 15min in water phase, being subsequently reduced to solution temperature is 40 degrees Celsius；
(4) hydrogen peroxide is added, the use of phosphorus acid for adjusting pH value is about 2 to 4, blowing is canned to obtain B agent.
Further, by adjusting the concentration of hydrogen peroxide in (4) step by step, the hair dye of different colours can be made, make
The appearance by black to brown is presented in color development.
Another technical solution provided by the invention is a kind of application method of dendritic macromole catalysis hair dye, by institute
It states A agent and the B agent is mixed in 1:1 ratio, is applied on hair after mixing evenly, hair is cleaned after 30min.
Compared with prior art, intermediate 5 of the present invention in hair dye, 6- dihydroxy indole be not easy in air by
It aoxidizes and easy to maintain, coloration is fairly obvious, can enter inside the medula of hair, and washing is not easy to fade after dyeing.
Specific embodiment
A specific embodiment of the invention is further described below with reference to embodiment, but is not to limit of the invention
It is fixed.
Embodiment 1: a kind of dendritic macromole catalysis hair dye, including A agent and B agent, the A agent is by following components quality
Percentage composition: 5,6- dihydroxy indole 1%, cetostearyl alcohol 6%, oleic acid 6%, propylene glycol 6%, isopropanol 6%, dodecane
Base sodium sulfonate 1%, polyethyene diamine dendritic 1%, appropriate ammonium hydroxide, water surplus, each component mass percent add up to
100%；The B agent is by following components mass percentage composition: hydrogen peroxide 16%, cetostearyl alcohol 6%, oleic acid 6%, the third two
Alcohol 6%, isopropanol 6%, dodecyl sodium sulfate 1%, appropriate phosphoric acid, water surplus, each component mass percent add up to
100%；
Embodiment 2: a kind of dendritic macromole catalysis hair dye, including A agent and B agent, the A agent is by following components quality
Percentage composition: 5,6- dihydroxy indole 2%, cetostearyl alcohol 10%, oleic acid 10%, propylene glycol 10%, isopropanol 10%, ten
Dialkyl sulfonates 1%, polyethyene diamine dendritic 1%, appropriate ammonium hydroxide, water surplus, each component mass percent are total
It is 100%；The B agent is by following components mass percentage composition: hydrogen peroxide 20%, cetostearyl alcohol 10%, oleic acid 10%,
Propylene glycol 10%, isopropanol 10%, dodecyl sodium sulfate 1%, appropriate phosphoric acid, water surplus, each component mass percent are total
It is 100%；
Embodiment 3: a kind of dendritic macromole catalysis hair dye, including A agent and B agent, the A agent is by following components quality
Percentage composition: 5,6- dihydroxy indole 5%, cetostearyl alcohol 12%, oleic acid 12%, propylene glycol 12%, isopropanol 12%, ten
Dialkyl sulfonates 3%, polyethyene diamine dendritic 2%, appropriate ammonium hydroxide, water surplus, each component mass percent are total
It is 100%；The B agent is by following components mass percentage composition: hydrogen peroxide 23%, cetostearyl alcohol 13%, oleic acid 13%,
Propylene glycol 13%, isopropanol 13%, dodecyl sodium sulfate 3%, appropriate phosphoric acid, water surplus, each component mass percent are total
It is 100%.
Embodiment 4: a kind of dendritic macromole is catalyzed hair dye, including A agent and B agent, which is characterized in that the A agent by
Following components mass percentage composition: 5,6- dihydroxy indole 6%, cetostearyl alcohol 14%, oleic acid 14%, propylene glycol 14%,
Isopropanol 14%, dodecyl sodium sulfate 5%, polyethyene diamine dendritic 4%, appropriate ammonium hydroxide, water surplus, each group sub-prime
Amount percentage adds up to 100%；The B agent is by following components mass percentage composition: hydrogen peroxide 24%, cetostearyl alcohol
14%, oleic acid 14%, propylene glycol 14%, isopropanol 14%, dodecyl sodium sulfate 5%, appropriate phosphoric acid, water surplus, each component
Mass percent adds up to 100%；
The preparation method of the dendritic macromole catalysis hair dye of above-described embodiment 1 to 4, comprising the following specific steps packet
Include step in detail below:
(1) prepare A agent, specifically include it is following step by step:
(1) water, propylene glycol, dodecyl sodium sulfate Hybrid Heating are obtained into water phase to 65 degrees Celsius；
(2) oleic acid, cetostearyl alcohol, isopropanol Hybrid Heating are obtained into oily phase to 65 degrees Celsius；
(3) oil is added to stirring heat preservation 15min in water phase, being subsequently reduced to solution temperature is 40 degrees Celsius；
(4) 5,6- dihydroxy indole is added and stirs 10min, it is about 9 to 11 that appropriate ammonium hydroxide, which is added, and adjusts pH value, blowing, tank
Dress obtains A agent；
(2) prepare B agent, specifically include it is following step by step:
(1) water, propylene glycol, dodecyl sodium sulfate Hybrid Heating are obtained into water phase to 65 degrees Celsius；
(2) oleic acid, cetostearyl alcohol, isopropanol Hybrid Heating are obtained into oily phase to 65 degrees Celsius；
(3) oil is added to stirring heat preservation 15min in water phase, being subsequently reduced to solution temperature is 40 degrees Celsius；
(4) hydrogen peroxide is added, the use of phosphorus acid for adjusting pH value is about 2 to 4, blowing is canned to obtain B agent.
Further, by adjusting the concentration of hydrogen peroxide in (4) step by step, the hair dye of different colours can be made, make
The appearance by black to brown is presented in color development.
Another technical solution provided by the invention is a kind of application method of dendritic macromole catalysis hair dye, by institute
It states A agent and the B agent is mixed in 1:1 ratio, is applied on hair after mixing evenly, hair is cleaned after 30min.
Beneficial effect to illustrate the invention carries out following experiment:
Experiment 1: test blackness: taking wisp of hair, after color difference meter is calibrated, measures ten times, is averaged.
L in upper table, a, b are the parameters of standard world colour space figure, and L value refers to that the black and white, L value value the big then whiter；A value refers to red
Green, the bigger a value the redder；B value refers to champac, and the bigger b value the more yellow.As can be known from the above table, hair dyeing effect of the invention is good.
Experiment 2: by application method of the invention to the hair after dye black, it is placed on 5% dodecyl sodium sulfate stirring
5min is denoted as primary cleaning, and the hair appearance after the hair appearance after cleaning 30 times and cleaning 1 time is compared its appearance face
Color is almost the same, the phenomenon that obviously fades does not occur.
By above-mentioned experiment 1,2 it is found that intermediate 5 of the present invention in hair dye, 6- dihydroxy indole are not allowed in air
It is easily oxidized and easy to maintain, coloration is fairly obvious, can enter inside the medula of hair, and washing is not easy after dyeing
Color.
Above in conjunction with the embodiments and experiment is made that detailed description to embodiments of the present invention, but the present invention is not limited to
Described embodiment.To those skilled in the art, without departing from the principles and spirit of the present invention, right
These embodiments progress various change, modification, replacement and variant are still fallen in protection scope of the present invention.
Claims (7)
1. a kind of dendritic macromole is catalyzed hair dye, including A agent and B agent, which is characterized in that the A agent is by following components matter
Measure percentage composition: 5,6- dihydroxy indole 1-6%, cetostearyl alcohol 6-14%, oleic acid 6-14%, propylene glycol 6-14%, different
Propyl alcohol 6-14%, dodecyl sodium sulfate 1-5%, polyethyene diamine dendritic 1-4%, appropriate ammonium hydroxide, water surplus, each group
Point mass percent adds up to 100%；The B agent is by following components mass percentage composition: hydrogen peroxide 16-24%, spermaceti
Stearyl alcohol 6-14%, oleic acid 6-14%, propylene glycol 6-14%, isopropanol 6-14%, dodecyl sodium sulfate 1-5%, phosphoric acid are suitable
Amount, water surplus, each component mass percent add up to 100%.
2. dendritic macromole according to claim 1 is catalyzed hair dye, which is characterized in that the A agent is by following components
Mass percentage composition: 5,6- dihydroxy indole 2-5%, cetostearyl alcohol 10-12%, oleic acid 10-12%, propylene glycol 10-
12%, isopropanol 10-12%, dodecyl sodium sulfate 1-3%, polyethyene diamine dendritic 1-2%, appropriate ammonium hydroxide, water
Surplus, each component mass percent add up to 100%；The B agent is by following components mass percentage composition: hydrogen peroxide 20-
23%, cetostearyl alcohol 10-13%, oleic acid 10-13%, propylene glycol 10-13%, isopropanol 10-13%, dodecyl sodium sulfate
1-3%, appropriate phosphoric acid, water surplus, each component mass percent add up to 100%.
3. dendritic macromole according to claim 2 is catalyzed hair dye, which is characterized in that the A agent is by following components
Mass percentage composition: 5,6- dihydroxy indole 2%, cetostearyl alcohol 10%, oleic acid 10%, propylene glycol 10%, isopropanol
10%, dodecyl sodium sulfate 1%, polyethyene diamine dendritic 1%, appropriate ammonium hydroxide, water surplus, each component quality percentage
Than adding up to 100%；The B agent is by following components mass percentage composition: hydrogen peroxide 20%, cetostearyl alcohol 10%, oil
Sour 10%, propylene glycol 10%, isopropanol 10%, dodecyl sodium sulfate 1%, appropriate phosphoric acid, water surplus, each component quality percentage
Than adding up to 100%.
4. dendritic macromole according to claim 2 is catalyzed hair dye, which is characterized in that the A agent is by following components
Mass percentage composition: 5,6- dihydroxy indole 5%, cetostearyl alcohol 12%, oleic acid 12%, propylene glycol 12%, isopropanol
12%, dodecyl sodium sulfate 3%, polyethyene diamine dendritic 2%, appropriate ammonium hydroxide, water surplus, each component quality percentage
Than adding up to 100%；The B agent is by following components mass percentage composition: hydrogen peroxide 23%, cetostearyl alcohol 13%, oil
Sour 13%, propylene glycol 13%, isopropanol 13%, dodecyl sodium sulfate 3%, appropriate phosphoric acid, water surplus, each component quality percentage
Than adding up to 100%.
5. a kind of preparation method for being catalyzed hair dyes such as the described in any item dendritic macromoles of Claims 1-4, feature exist
In, comprising the following specific steps
(1) prepare A agent, specifically include it is following step by step:
(1) water, propylene glycol, dodecyl sodium sulfate Hybrid Heating are obtained into water phase to 65 degrees Celsius；
(2) oleic acid, cetostearyl alcohol, isopropanol Hybrid Heating are obtained into oily phase to 65 degrees Celsius；
(3) oil is added to stirring heat preservation 15min in water phase, being subsequently reduced to solution temperature is 40 degrees Celsius；
(4) 5,6- dihydroxy indole is added and stirs 10min, it is about 9 to 11 that appropriate ammonium hydroxide, which is added, and adjusts pH value, blowing, canned
To A agent；
(2) prepare B agent, specifically include it is following step by step:
(1) water, propylene glycol, dodecyl sodium sulfate Hybrid Heating are obtained into water phase to 65 degrees Celsius；
(2) oleic acid, cetostearyl alcohol, isopropanol Hybrid Heating are obtained into oily phase to 65 degrees Celsius；
(3) oil is added to stirring heat preservation 15min in water phase, being subsequently reduced to solution temperature is 40 degrees Celsius；
(4) hydrogen peroxide is added, the use of phosphorus acid for adjusting pH value is about 2 to 4, blowing is canned to obtain B agent.
6. the preparation method of dendritic macromole catalysis hair dye according to claim 5, which is characterized in that step (2)
In, by adjusting the concentration of hydrogen peroxide in (4) step by step, the hair dye of different colours can be made, color development is presented by black
Appearance of the color to brown.
7. a kind of application method for being catalyzed hair dyes such as the described in any item dendritic macromoles of Claims 1-4, feature exist
In the A agent and the B agent are mixed in 1:1 ratio, are applied on hair after mixing evenly, hair is cleaned after 30min
?.
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| CN111840120A (en) * | 2020-09-12 | 2020-10-30 | 四川大学 | A hair dye containing antibacterial molecules |
| CN111840105A (en) * | 2020-09-12 | 2020-10-30 | 桂林长发小寨生物科技有限公司 | Hair dye catalyzed by streptomyces extracted polysaccharide |
| CN111840119A (en) * | 2020-09-12 | 2020-10-30 | 桂林长发小寨生物科技有限公司 | A hair dye containing saccharide compounds |
| CN111840104A (en) * | 2020-09-12 | 2020-10-30 | 桂林长发小寨生物科技有限公司 | Hair dye containing plant polyphenol functional material |
| CN111920695A (en) * | 2020-09-12 | 2020-11-13 | 四川大学 | Hair dye, preparation method and use method thereof |
| CN111920696A (en) * | 2020-09-14 | 2020-11-13 | 四川大学 | Artificial melanin hair-perming and dyeing agent and preparation and hair-perming and dyeing integrated use method thereof |
| CN111973468A (en) * | 2020-09-12 | 2020-11-24 | 四川大学 | Hair dye containing polysaccharide and natural polyphenol |
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| CN111991269A (en) * | 2020-09-12 | 2020-11-27 | 四川大学 | A hair dye containing modified glucoside |
| CN112006935A (en) * | 2020-09-12 | 2020-12-01 | 四川大学 | Hair dye based on modified natural polyphenol molecules |
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| CN111973468A (en) * | 2020-09-12 | 2020-11-24 | 四川大学 | Hair dye containing polysaccharide and natural polyphenol |
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| CN111920695A (en) * | 2020-09-12 | 2020-11-13 | 四川大学 | Hair dye, preparation method and use method thereof |
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| CN112006935A (en) * | 2020-09-12 | 2020-12-01 | 四川大学 | Hair dye based on modified natural polyphenol molecules |
| CN111920696A (en) * | 2020-09-14 | 2020-11-13 | 四川大学 | Artificial melanin hair-perming and dyeing agent and preparation and hair-perming and dyeing integrated use method thereof |
| CN112022744A (en) * | 2020-09-14 | 2020-12-04 | 四川大学 | A hair dye containing functional surfactant, and its preparation method and application method |
| CN112022744B (en) * | 2020-09-14 | 2021-06-15 | 四川大学 | A hair dye containing functional surfactant, and its preparation method and application method |
| CN111920696B (en) * | 2020-09-14 | 2021-07-16 | 四川大学 | Artificial melanin hair-perming and dyeing agent and preparation and hair-perming and dyeing integrated use method thereof |
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Application publication date: 20190816 |