CN109457463A - 一种羊毛面料的防毡缩整理工艺 - Google Patents
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- 210000002268 wool Anatomy 0.000 title claims abstract description 32
- 239000004744 fabric Substances 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 19
- -1 rare-earth compound Chemical class 0.000 claims abstract description 25
- 239000007788 liquid Substances 0.000 claims abstract description 22
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 21
- 239000012530 fluid Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 108010029541 Laccase Proteins 0.000 claims abstract description 13
- 108010059345 keratinase Proteins 0.000 claims abstract description 10
- CZMAIROVPAYCMU-UHFFFAOYSA-N lanthanum(3+) Chemical compound [La+3] CZMAIROVPAYCMU-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052771 Terbium Inorganic materials 0.000 claims abstract description 4
- 238000007598 dipping method Methods 0.000 claims abstract description 3
- 238000009950 felting Methods 0.000 claims description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 4
- NCOYDQIWSSMOEW-UHFFFAOYSA-K 2-hydroxypropane-1,2,3-tricarboxylate;lanthanum(3+) Chemical compound [La+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NCOYDQIWSSMOEW-UHFFFAOYSA-K 0.000 claims description 3
- ICAKDTKJOYSXGC-UHFFFAOYSA-K lanthanum(iii) chloride Chemical compound Cl[La](Cl)Cl ICAKDTKJOYSXGC-UHFFFAOYSA-K 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- OXHNIMPTBAKYRS-UHFFFAOYSA-H lanthanum(3+);oxalate Chemical compound [La+3].[La+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O OXHNIMPTBAKYRS-UHFFFAOYSA-H 0.000 claims description 2
- JLRJWBUSTKIQQH-UHFFFAOYSA-K lanthanum(3+);triacetate Chemical compound [La+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JLRJWBUSTKIQQH-UHFFFAOYSA-K 0.000 claims description 2
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- 230000004048 modification Effects 0.000 description 2
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- 230000001590 oxidative effect Effects 0.000 description 2
- GFISHBQNVWAVFU-UHFFFAOYSA-K terbium(iii) chloride Chemical compound Cl[Tb](Cl)Cl GFISHBQNVWAVFU-UHFFFAOYSA-K 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 238000010006 anti-felting Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 108010005400 cutinase Proteins 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004546 feltproofing Methods 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/17—Halides of elements of Groups 3 or 13 of the Periodic Table
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
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- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/45—Shrinking resistance, anti-felting properties
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Abstract
本发明公开了一种羊毛面料的防毡缩整理工艺，包括以下步骤：S1：配置防毡缩整理液，整理液的主要组成为漆酶、角蛋白酶、能电离产生镧离子和/或铽离子的水溶性稀土化合物和水，其中漆酶的浓度为10～20U/mL，角蛋白酶的浓度为3～8U/mL；S2：将防毡缩整理液导入整理槽中，将防毡缩整理液加热至45～55℃，将面料浸渍于防毡缩整理液中反应4～6h；S3：将S2所得面料置于85～95℃的热水中浸渍5～10min，然后依次经过热水和冷水清洗，干燥。该羊毛面料的防毡缩整理工艺采用含有水溶性稀土化合物的整理液，利用稀土离子对于漆酶活性的激活作用，促进酶促反应的进行，降低整理液中酶浓度、反应时间和生产成本。
Description
技术领域
本发明涉及面料整理技术领域，具体涉及一种羊毛面料的防毡缩整理工艺。
背景技术
羊毛具有定向摩擦效应和弹性。由于毛纤维逆鳞片的摩擦阻力大于顺鳞片的摩擦阻力，因此在一组不同方向力的作用下毛纤维总是向根部方向移动，这种现象称毛纤维的定向摩擦效应。当纤维不能自由移动时，在这些力的作用下就会产生弯曲缠绕毡并。羊毛的弹性使羊毛在外力除去后，变形能够充分恢复，这种作用也能促使缠绕毡并加速进行。影响毡缩性的还有羊毛鳞片密度、鳞片形状、纤维的卷曲和细度等。
传统的防毡缩整理采用氧化法，破坏羊毛鳞片层的二硫键，但是氧化法不仅对纤维损伤明显，而且会导致纤维色泽的改变。改进的技术方案采用蛋白酶、壳聚糖、等离子体、纳米溶胶-凝胶等方法或者整理液处理羊毛纤维。
根据羊毛纤维毡缩产业的原因和羊毛鳞片层的组成和结构特点，改进的技术方案如CN102965955 A所述的，将角质酶、角蛋白酶和蛋白酶三种酶联合和一浴法处理羊毛，通过它们的协同作用，有效去除羊毛表面的鳞片层，达到理想的防毡缩效果，但是整理液中酶含量较高，处理时间长，生产成本较高。
发明内容
本发明的目的在于克服现有技术中存在的缺陷，提供一种羊毛面料的防毡缩整理工艺，在防毡缩整理的整理液中含有游离的稀土离子，对漆酶具有活化作用，促进漆酶与羊毛表面基团的反应，降低生产成本。
为实现上述目的，本发明的技术方案为：一种羊毛面料的防毡缩整理工艺，其特征在于，包括以下步骤：
S1：配置防毡缩整理液，整理液的主要组成为漆酶、角蛋白酶、能电离产生镧离子和/或铽离子的水溶性稀土化合物和水，其中漆酶的浓度为10～20U/mL，角蛋白酶的浓度为3～8U/mL；
S2：将防毡缩整理液导入整理槽中，将防毡缩整理液加热至45～55℃，将面料浸渍于防毡缩整理液中反应4～6h；
S3：将S2所得面料置于85～95℃的热水中浸渍5～10min，然后依次经过热水和冷水清洗，干燥。
优选的技术方案为，水溶性稀土化合物为能电离产生镧离子的化合物。
优选的技术方案为，水溶性稀土化合物为选自氯化镧、乙酸镧、草酸镧、柠檬酸镧中的一种或两种以上的组合。
优选的技术方案为，防毡缩整理液中水溶性稀土化合物的重量百分比为0.1～0.5%。
优选的技术方案为，防毡缩整理液中还含有C12～C16的阴离子表面活性剂。
本发明的优点和有益效果在于：
该羊毛面料的防毡缩整理工艺采用含有水溶性稀土化合物的整理液，利用稀土离子对于漆酶活性的激活作用，促进酶促反应的进行，降低整理液中酶浓度和反应时间，有助于降低生产成本。
具体实施方式
下面结合实施例，对本发明的具体实施方式作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
实施例1
实施例1的羊毛面料的防毡缩整理工艺包括以下步骤：
S1：配置防毡缩整理液，整理液的主要组成为漆酶、角蛋白酶、能电离产生铽离子的水溶性稀土化合物和水，其中漆酶的浓度为10U/mL，角蛋白酶的浓度为8U/mL；
S2：将防毡缩整理液导入整理槽中，将防毡缩整理液加热至45℃，将面料浸渍于防毡缩整理液中反应6h；
S3：将S2所得面料置于85℃的热水中浸渍10min，然后依次经过热水和冷水清洗，干燥。
水溶性稀土化合物为氯化铽。
防毡缩整理液中水溶性稀土化合物的重量百分比为0.1%。
实施例2
实施例2与实施例1的区别在于：
整理液中漆酶的浓度为20U/mL，角蛋白酶的浓度为3U/mL；
S2：将防毡缩整理液加热至55℃，将面料浸渍于防毡缩整理液中反应4h；
S3：将S2所得面料置于95℃的热水中浸渍5min。
水溶性稀土化合物为氯化铽和氯化镧以重量比2:1组合而成。
防毡缩整理液中水溶性稀土化合物的重量百分比为0.1%。
实施例3
实施例3与实施例1的区别在于：
水溶性稀土化合物为柠檬酸镧。
防毡缩整理液中还含有十二烷基磺酸钠的阴离子表面活性剂。
对比例
对比例与实施例1的区别在于，对比例不包括稀土化合物。
相较于实施例，对比例羊毛面料的纤维表面鳞片层损伤小，整理液对于羊毛的定向摩擦效应改善不明显，处理后的面料仍然具有较强的毡缩性能。
加入阴离子表面活性剂的整理液处理羊毛面料，由于整理液更容易深入羊毛鳞片之间，实施例整理液对鳞片层的剥离量较大，处理后的羊毛纤维表面较为光滑。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。
Claims (5)
1.一种羊毛面料的防毡缩整理工艺，其特征在于，包括以下步骤：
S1：配置防毡缩整理液，整理液的主要组成为漆酶、角蛋白酶、能电离产生镧离子和/或铽离子的水溶性稀土化合物和水，其中漆酶的浓度为10～20U/mL，角蛋白酶的浓度为3～8U/mL；
S2：将防毡缩整理液导入整理槽中，将防毡缩整理液加热至45～55℃，将面料浸渍于防毡缩整理液中反应4～6h；
S3：将S2所得面料置于85～95℃的热水中浸渍5～10min，然后依次经过热水和冷水清洗，干燥。
2.根据权利要求1所述的羊毛面料的防毡缩整理工艺，其特征在于，水溶性稀土化合物为能电离产生镧离子的化合物。
3.根据权利要求1所述的羊毛面料的防毡缩整理工艺，其特征在于，水溶性稀土化合物为选自氯化镧、乙酸镧、草酸镧、柠檬酸镧中的一种或两种以上的组合。
4.根据权利要求1所述的羊毛面料的防毡缩整理工艺，其特征在于，防毡缩整理液中水溶性稀土化合物的重量百分比为0.1～0.5%。
5.根据权利要求1所述的羊毛面料的防毡缩整理工艺，其特征在于，防毡缩整理液中还含有C12～C16的阴离子表面活性剂。
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114108151A (zh) * | 2021-12-03 | 2022-03-01 | 王文俊 | 一种抗静电柔顺羊毛面料及其制备方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102965958A (zh) * | 2012-10-31 | 2013-03-13 | 江南大学 | 一种基于复合生物酶的羊毛制品二浴法防毡缩整理工艺 |
| CN105506951A (zh) * | 2015-12-30 | 2016-04-20 | 江阴市长泾花园毛纺织有限公司 | 一种透气型轻薄双面镂空面料 |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102965958A (zh) * | 2012-10-31 | 2013-03-13 | 江南大学 | 一种基于复合生物酶的羊毛制品二浴法防毡缩整理工艺 |
| CN105506951A (zh) * | 2015-12-30 | 2016-04-20 | 江阴市长泾花园毛纺织有限公司 | 一种透气型轻薄双面镂空面料 |
Non-Patent Citations (4)
| Title |
|---|
| MAJID MONTAZER等: "Treatment of Wool with Laccase and Dyeing with Madder", 《APPLIED BIOCHEMISTRY BIOTECHNOLOGY》 * |
| 徐淑霞等: "镧和铈对杂色云芝生长及其漆酶活性的影响", 《河南农业大学学报》 * |
| 滑钧凯等: "论稀土元素在羊毛染色中的效果 ", 《毛纺科技》 * |
| 田俊莹等: "《纺织品功能整理》", 31 October 2015, 中国纺织出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114108151A (zh) * | 2021-12-03 | 2022-03-01 | 王文俊 | 一种抗静电柔顺羊毛面料及其制备方法 |
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