CN109393682A - 一种美肤伞 - Google Patents

一种美肤伞 Download PDF

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CN109393682A
CN109393682A CN201811212021.4A CN201811212021A CN109393682A CN 109393682 A CN109393682 A CN 109393682A CN 201811212021 A CN201811212021 A CN 201811212021A CN 109393682 A CN109393682 A CN 109393682A
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Abstract

本发明涉及生活用品领域,具体涉及一种美肤伞,包括伞面与伞架,该美肤伞伞面的制备方法包括如下步骤:(1)抗紫外线层的制作:将生产塑料的原料与抗紫外线剂混合制成一层薄膜,得到抗紫外线层;(2)反射层的制作:制备一层塑料薄膜,使该塑料薄膜的上端面分布有不规则的凸起颗粒,然后在该塑料薄膜的上端面喷涂一层隔热涂料,得到反射层;(3)整合处理:将抗紫外线层、反射层由上至下依次设置,在两层之间喷涂胶粘剂,经过热压工艺形成一体,即得到所述美肤伞的伞面。本发明的美肤伞,实用性强,适合在领域推广应用。

Description

一种美肤伞
技术领域
本发明涉及生活用品领域,具体涉及一种美肤伞。
背景技术
伞是一种提供阴凉环境或遮蔽雨、雪的工具,使用时以手将之举起,伞最初的用途是用来遮雨的,随着社会的进步,伞也分为多种,最常用的就是雨伞和阳伞。现在用来挡雨的伞叫雨伞,用来遮蔽阳光的伞称作阳伞或遮阳伞,可固定于露台桌等户外家具上,或用在海滩上。随着社会的不断发展,人们生活在一个节奏快、压力较大的时代,压力大会使人的皮肤变差,因此人们在工作之余总是需要进行放松活动,以缓解紧张的工作压力,达到身心健康。夏天人们外出时,常常会使用太阳伞遮光,以免被强烈的紫外线晒伤。但太阳光中,含有对人体皮肤有益的可见光,因此人们还会时不时地进行日光浴,以改善皮肤状况。现有的遮阳伞中,会将紫外线与对人体皮肤有益的可见光全部隔绝在外,达不到使用可见光进行美肤的效果,因此,需要一种美肤伞,在隔绝掉紫外线的同时,能够让对人体皮肤有益的可见光照射到皮肤上。
发明内容
本发明的目的在于:针对上述问题,提供一种美肤伞。
为了实现上述目的,本发明采用的技术方案如下:
一种美肤伞,包括伞面与伞架,该美肤伞伞面的制备方法包括如下步骤:
(1)抗紫外线层的制作:将生产塑料的原料与抗紫外线剂混合制成一层薄膜,得到抗紫外线层;
所述抗紫外线剂由以下重量份的原料组成:聚氨酯树脂20-40份、十二碳醇酯10-14份、1,6-己二异氰酸酯12-15份、改性聚氨酯乳液10-20份、水性环氧树脂乳液10-20份、十二烷基硫酸钠8-12份、顺丁橡胶20-24份、二氯苯70-90份、聚乙烯吡咯烷酮8-10份、偶氮二异丁腈4-6份、高碘酸钠3-4份、氢化锂铝8-10份、丙三醇5-8份、聚丙烯酰胺5-6份、二甲苯150-200份、正丁醇120-150份、纳米二氧化铈12-15份、石英砂15-20份、月桂醇聚醚硫酸钠6-8份、2-(2H-苯并三唑-2)-4,6-二(1-甲基-1-苯基乙基)苯酚6-8份、N,N-二(2-羟丙基)苯胺5-6份、氯仿20-30份;
(2)反射层的制作:制备一层塑料薄膜,使该塑料薄膜的上端面分布有不规则的凸起颗粒,然后在该塑料薄膜的上端面喷涂一层隔热涂料,得到反射层;
(3)整合处理:将抗紫外线层、反射层由上至下依次设置,在两层之间喷涂胶粘剂,经过热压工艺形成一体,即得到所述美肤伞的伞面。
进一步地,所述抗紫外线剂的制备方法为:(1)将顺丁橡胶加入到二氯苯中,搅拌20-30min,加入聚乙烯吡咯烷酮和偶氮二异丁腈,升高温度至70-80℃,搅拌反应10-12h;降低温度至50-60℃,加入高碘酸钠,搅拌反应2-3h,加入氢化锂铝,升高温度至140-150℃,搅拌反应18-20h,得到多羟基化的顺丁橡胶;(2)将多羟基化的顺丁橡胶加入反应釜中,加入改性聚氨酯乳液、水性环氧树脂乳液,升温至100-110℃,进行真空脱气20-30min,真空脱气后降到常温,加入1,6-己二异氰酸酯,升温至80-90℃,搅拌反应3-5h,加入丙三醇,继续搅拌反应6-8h,真空脱气20-30min,降温出料,得到基料A;(3)将聚丙烯酰胺和月桂醇聚醚硫酸钠,溶于二甲苯和正丁醇组成的混合溶剂中,室温下超声波分散均匀后,在搅拌状态下缓慢加入干燥的纳米二氧化铈和石英砂,待物料加完并搅拌均匀后,继续超声波分散2-3h,加入聚氨酯树脂和十二碳醇酯,升温至95-105℃,抽真空30-40min,降温至50-60℃,加入步骤(2)得到的基料A,再升温至90-100℃,搅拌反应5-8h,加入十二烷基硫酸钠、2-(2H-苯并三唑-2)-4,6-二(1-甲基-1-苯基乙基)苯酚,超声波分散后再用搅拌机高速分散30-40min,缓慢加入N,N-二(2-羟丙基)苯胺和氯仿配置的溶液,继续搅拌2-3h,得到抗紫外线剂。
进一步地,步骤(1)中,所述隔热涂料由以下方法制备得到:将20-24份丙烯酸乳液、22-26份硅丙乳液、6-8份甲基三乙氧基硅烷、2-5份正硅酸甲酯、5-9份硅烷偶联剂、8-14份的二苯基二甲氧基硅烷、2-4份保护胶、6-8份气凝胶、12-14份空心玻璃微珠、4-6份多功能助剂混合后,通过分散机搅拌均匀后,即得。
综上所述,由于采用了上述技术方案,本发明的有益效果是:
本发明专利的美肤伞,分为抗紫外线层和反射层,抗紫外线层能够将紫外线过滤掉,反射层上分布的不规则的凸起颗粒能够反射多余的紫外线,同时进一步降低透过伞面的可见光的强度,使透过伞面的可见光的强度保持在一个适合人体皮肤的范围;反射层上的隔热涂料,隔绝了热量,更加实用。本发明的美肤伞的伞面,采用的原料均对人体无害,安全性高,实用性强,适合在领域推广应用。
具体实施方式
实施例1:
一种美肤伞,包括伞面与伞架,该美肤伞伞面的制备方法包括如下步骤:
(1)抗紫外线层的制作:将生产塑料的原料与抗紫外线剂混合制成一层薄膜,得到抗紫外线层;
(2)反射层的制作:制备一层塑料薄膜,使该塑料薄膜的上端面分布有不规则的凸起颗粒,然后在该塑料薄膜的上端面喷涂一层隔热涂料,得到反射层;
(3)整合处理:将抗紫外线层、反射层由上至下依次设置,在两层之间喷涂胶粘剂,经过热压工艺形成一体,即得到所述美肤伞的伞面;
所述抗紫外线剂由以下重量份的原料组成:聚氨酯树脂20份、十二碳醇酯10份、1,6-己二异氰酸酯12份、改性聚氨酯乳液10份、水性环氧树脂乳液10份、十二烷基硫酸钠8份、顺丁橡胶20份、二氯苯70份、聚乙烯吡咯烷酮8份、偶氮二异丁腈4份、高碘酸钠3份、氢化锂铝8份、丙三醇5份、聚丙烯酰胺5份、二甲苯150份、正丁醇120份、纳米二氧化铈12份、石英砂15份、月桂醇聚醚硫酸钠6份、2-(2H-苯并三唑-2)-4,6-二(1-甲基-1-苯基乙基)苯酚6份、N,N-二(2-羟丙基)苯胺5份、氯仿20份;
所述抗紫外线剂的制备方法为:(1)将顺丁橡胶加入到二氯苯中,搅拌20min,加入聚乙烯吡咯烷酮和偶氮二异丁腈,升高温度至70℃,搅拌反应10h;降低温度至50℃,加入高碘酸钠,搅拌反应2h,加入氢化锂铝,升高温度至140℃,搅拌反应18h,得到多羟基化的顺丁橡胶;(2)将多羟基化的顺丁橡胶加入反应釜中,加入改性聚氨酯乳液、水性环氧树脂乳液,升温至100℃,进行真空脱气20min,真空脱气后降到常温,加入1,6-己二异氰酸酯,升温至80℃,搅拌反应3h,加入丙三醇,继续搅拌反应6h,真空脱气20min,降温出料,得到基料A;(3)将聚丙烯酰胺和月桂醇聚醚硫酸钠,溶于二甲苯和正丁醇组成的混合溶剂中,室温下超声波分散均匀后,在搅拌状态下缓慢加入干燥的纳米二氧化铈和石英砂,待物料加完并搅拌均匀后,继续超声波分散2h,加入聚氨酯树脂和十二碳醇酯,升温至95℃,抽真空30min,降温至50℃,加入步骤(2)得到的基料A,再升温至90℃,搅拌反应5h,加入十二烷基硫酸钠、2-(2H-苯并三唑-2)-4,6-二(1-甲基-1-苯基乙基)苯酚,超声波分散后再用搅拌机高速分散30min,缓慢加入N,N-二(2-羟丙基)苯胺和氯仿配置的溶液,继续搅拌2h,得到抗紫外线剂;
所述隔热涂料由以下方法制备得到:将20份丙烯酸乳液、22份硅丙乳液、6份甲基三乙氧基硅烷、2份正硅酸甲酯、5份硅烷偶联剂、8份的二苯基二甲氧基硅烷、2份保护胶、6份气凝胶、12份空心玻璃微珠、4份多功能助剂混合后,通过分散机搅拌均匀后,即得。
实施例2:
一种美肤伞,包括伞面与伞架,该美肤伞伞面的制备方法包括如下步骤:
(1)抗紫外线层的制作:将生产塑料的原料与抗紫外线剂混合制成一层薄膜,得到抗紫外线层;
(2)反射层的制作:制备一层塑料薄膜,使该塑料薄膜的上端面分布有不规则的凸起颗粒,然后在该塑料薄膜的上端面喷涂一层隔热涂料,得到反射层;
(3)整合处理:将抗紫外线层、反射层由上至下依次设置,在两层之间喷涂胶粘剂,经过热压工艺形成一体,即得到所述美肤伞的伞面;
所述抗紫外线剂由以下重量份的原料组成:聚氨酯树脂30份、十二碳醇酯12份、1,6-己二异氰酸酯13份、改性聚氨酯乳液15份、水性环氧树脂乳液15份、十二烷基硫酸钠10份、顺丁橡胶22份、二氯苯80份、聚乙烯吡咯烷酮9份、偶氮二异丁腈5份、高碘酸钠3.5份、氢化锂铝9份、丙三醇6.5份、聚丙烯酰胺5.5份、二甲苯175份、正丁醇135份、纳米二氧化铈13份、石英砂17份、月桂醇聚醚硫酸钠7份、2-(2H-苯并三唑-2)-4,6-二(1-甲基-1-苯基乙基)苯酚7份、N,N-二(2-羟丙基)苯胺5.5份、氯仿25份;
所述抗紫外线剂的制备方法为:(1)将顺丁橡胶加入到二氯苯中,搅拌25min,加入聚乙烯吡咯烷酮和偶氮二异丁腈,升高温度至75℃,搅拌反应11h;降低温度至55℃,加入高碘酸钠,搅拌反应2.5h,加入氢化锂铝,升高温度至145℃,搅拌反应19h,得到多羟基化的顺丁橡胶;(2)将多羟基化的顺丁橡胶加入反应釜中,加入改性聚氨酯乳液、水性环氧树脂乳液,升温至105℃,进行真空脱气25min,真空脱气后降到常温,加入1,6-己二异氰酸酯,升温至85℃,搅拌反应4h,加入丙三醇,继续搅拌反应7h,真空脱气25min,降温出料,得到基料A;(3)将聚丙烯酰胺和月桂醇聚醚硫酸钠,溶于二甲苯和正丁醇组成的混合溶剂中,室温下超声波分散均匀后,在搅拌状态下缓慢加入干燥的纳米二氧化铈和石英砂,待物料加完并搅拌均匀后,继续超声波分散2.5h,加入聚氨酯树脂和十二碳醇酯,升温至100℃,抽真空35min,降温至55℃,加入步骤(2)得到的基料A,再升温至95℃,搅拌反应6h,加入十二烷基硫酸钠、2-(2H-苯并三唑-2)-4,6-二(1-甲基-1-苯基乙基)苯酚,超声波分散后再用搅拌机高速分散35min,缓慢加入N,N-二(2-羟丙基)苯胺和氯仿配置的溶液,继续搅拌2.5h,得到抗紫外线剂;
所述隔热涂料由以下方法制备得到:将22份丙烯酸乳液、24份硅丙乳液、7份甲基三乙氧基硅烷、3.5份正硅酸甲酯、7份硅烷偶联剂、11份的二苯基二甲氧基硅烷、3份保护胶、7份气凝胶、13份空心玻璃微珠、5份多功能助剂混合后,通过分散机搅拌均匀后,即得。
实施例3:
一种美肤伞,包括伞面与伞架,该美肤伞伞面的制备方法包括如下步骤:
(1)抗紫外线层的制作:将生产塑料的原料与抗紫外线剂混合制成一层薄膜,得到抗紫外线层;
(2)反射层的制作:制备一层塑料薄膜,使该塑料薄膜的上端面分布有不规则的凸起颗粒,然后在该塑料薄膜的上端面喷涂一层隔热涂料,得到反射层;
(3)整合处理:将抗紫外线层、反射层由上至下依次设置,在两层之间喷涂胶粘剂,经过热压工艺形成一体,即得到所述美肤伞的伞面;
所述抗紫外线剂由以下重量份的原料组成:聚氨酯树脂40份、十二碳醇酯14份、1,6-己二异氰酸酯15份、改性聚氨酯乳液20份、水性环氧树脂乳液20份、十二烷基硫酸钠12份、顺丁橡胶24份、二氯苯90份、聚乙烯吡咯烷酮10份、偶氮二异丁腈6份、高碘酸钠4份、氢化锂铝10份、丙三醇8份、聚丙烯酰胺6份、二甲苯200份、正丁醇150份、纳米二氧化铈15份、石英砂20份、月桂醇聚醚硫酸钠8份、2-(2H-苯并三唑-2)-4,6-二(1-甲基-1-苯基乙基)苯酚8份、N,N-二(2-羟丙基)苯胺6份、氯仿30份;
所述抗紫外线剂的制备方法为:(1)将顺丁橡胶加入到二氯苯中,搅拌30min,加入聚乙烯吡咯烷酮和偶氮二异丁腈,升高温度至80℃,搅拌反应12h;降低温度至60℃,加入高碘酸钠,搅拌反应3h,加入氢化锂铝,升高温度至150℃,搅拌反应20h,得到多羟基化的顺丁橡胶;(2)将多羟基化的顺丁橡胶加入反应釜中,加入改性聚氨酯乳液、水性环氧树脂乳液,升温至110℃,进行真空脱气30min,真空脱气后降到常温,加入1,6-己二异氰酸酯,升温至90℃,搅拌反应5h,加入丙三醇,继续搅拌反应8h,真空脱气30min,降温出料,得到基料A;(3)将聚丙烯酰胺和月桂醇聚醚硫酸钠,溶于二甲苯和正丁醇组成的混合溶剂中,室温下超声波分散均匀后,在搅拌状态下缓慢加入干燥的纳米二氧化铈和石英砂,待物料加完并搅拌均匀后,继续超声波分散3h,加入聚氨酯树脂和十二碳醇酯,升温至105℃,抽真空40min,降温至60℃,加入步骤(2)得到的基料A,再升温至100℃,搅拌反应8h,加入十二烷基硫酸钠、2-(2H-苯并三唑-2)-4,6-二(1-甲基-1-苯基乙基)苯酚,超声波分散后再用搅拌机高速分散40min,缓慢加入N,N-二(2-羟丙基)苯胺和氯仿配置的溶液,继续搅拌3h,得到抗紫外线剂;
所述隔热涂料由以下方法制备得到:将24份丙烯酸乳液、26份硅丙乳液、8份甲基三乙氧基硅烷、5份正硅酸甲酯、9份硅烷偶联剂、14份的二苯基二甲氧基硅烷、4份保护胶、8份气凝胶、14份空心玻璃微珠、6份多功能助剂混合后,通过分散机搅拌均匀后,即得。
上述说明是针对本发明较佳可行实施例的详细说明,但实施例并非用以限定本发明的专利申请范围,凡本发明所提示的技术精神下所完成的同等变化或修饰变更,均应属于本发明所涵盖专利范围。

Claims (3)

1.一种美肤伞,包括伞面与伞架,其特征在于:该美肤伞伞面的制备方法包括如下步骤:
(1)抗紫外线层的制作:将生产塑料的原料与抗紫外线剂混合制成一层薄膜,得到抗紫外线层;
所述抗紫外线剂由以下重量份的原料组成:聚氨酯树脂20-40份、十二碳醇酯10-14份、1,6-己二异氰酸酯12-15份、改性聚氨酯乳液10-20份、水性环氧树脂乳液10-20份、十二烷基硫酸钠8-12份、顺丁橡胶20-24份、二氯苯70-90份、聚乙烯吡咯烷酮8-10份、偶氮二异丁腈4-6份、高碘酸钠3-4份、氢化锂铝8-10份、丙三醇5-8份、聚丙烯酰胺5-6份、二甲苯150-200份、正丁醇120-150份、纳米二氧化铈12-15份、石英砂15-20份、月桂醇聚醚硫酸钠6-8份、2-(2H-苯并三唑-2)-4,6-二(1-甲基-1-苯基乙基)苯酚6-8份、N,N-二(2-羟丙基)苯胺5-6份、氯仿20-30份;
(2)反射层的制作:制备一层塑料薄膜,使该塑料薄膜的上端面分布有不规则的凸起颗粒,然后在该塑料薄膜的上端面喷涂一层隔热涂料,得到反射层;
(3)整合处理:将抗紫外线层、反射层由上至下依次设置,在两层之间喷涂胶粘剂,经过热压工艺形成一体,即得到所述美肤伞的伞面。
2.根据权利要求1所述的一种美肤伞,其特征在于:所述抗紫外线剂的制备方法为:(1)将顺丁橡胶加入到二氯苯中,搅拌20-30min,加入聚乙烯吡咯烷酮和偶氮二异丁腈,升高温度至70-80℃,搅拌反应10-12h;降低温度至50-60℃,加入高碘酸钠,搅拌反应2-3h,加入氢化锂铝,升高温度至140-150℃,搅拌反应18-20h,得到多羟基化的顺丁橡胶;(2)将多羟基化的顺丁橡胶加入反应釜中,加入改性聚氨酯乳液、水性环氧树脂乳液,升温至100-110℃,进行真空脱气20-30min,真空脱气后降到常温,加入1,6-己二异氰酸酯,升温至80-90℃,搅拌反应3-5h,加入丙三醇,继续搅拌反应6-8h,真空脱气20-30min,降温出料,得到基料A;(3)将聚丙烯酰胺和月桂醇聚醚硫酸钠,溶于二甲苯和正丁醇组成的混合溶剂中,室温下超声波分散均匀后,在搅拌状态下缓慢加入干燥的纳米二氧化铈和石英砂,待物料加完并搅拌均匀后,继续超声波分散2-3h,加入聚氨酯树脂和十二碳醇酯,升温至95-105℃,抽真空30-40min,降温至50-60℃,加入步骤(2)得到的基料A,再升温至90-100℃,搅拌反应5-8h,加入十二烷基硫酸钠、2-(2H-苯并三唑-2)-4,6-二(1-甲基-1-苯基乙基)苯酚,超声波分散后再用搅拌机高速分散30-40min,缓慢加入N,N-二(2-羟丙基)苯胺和氯仿配置的溶液,继续搅拌2-3h,得到抗紫外线剂。
3.根据权利要求1所述的一种美肤伞,其特征在于:步骤(1)中,所述隔热涂料由以下方法制备得到:将20-24份丙烯酸乳液、22-26份硅丙乳液、6-8份甲基三乙氧基硅烷、2-5份正硅酸甲酯、5-9份硅烷偶联剂、8-14份的二苯基二甲氧基硅烷、2-4份保护胶、6-8份气凝胶、12-14份空心玻璃微珠、4-6份多功能助剂混合后,通过分散机搅拌均匀后,即得。
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