CN109392239A - A kind of heat-resisting flame-retardant ceramic printed-circuit board - Google Patents

A kind of heat-resisting flame-retardant ceramic printed-circuit board Download PDF

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Publication number
CN109392239A
CN109392239A CN201811146393.1A CN201811146393A CN109392239A CN 109392239 A CN109392239 A CN 109392239A CN 201811146393 A CN201811146393 A CN 201811146393A CN 109392239 A CN109392239 A CN 109392239A
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CN
China
Prior art keywords
layer
heat
printed
retardant
circuit board
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
CN201811146393.1A
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Chinese (zh)
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CN109392239B (en
Inventor
张文杰
谢亮
金湘亮
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Jiangsu Core Z-Tek Electronic Science And Technology Co Ltd
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Jiangsu Core Z-Tek Electronic Science And Technology Co Ltd
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Priority to CN201811146393.1A priority Critical patent/CN109392239B/en
Publication of CN109392239A publication Critical patent/CN109392239A/en
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Publication of CN109392239B publication Critical patent/CN109392239B/en
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Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/0201Thermal arrangements, e.g. for cooling, heating or preventing overheating
    • H05K1/0203Cooling of mounted components
    • H05K1/0209External configuration of printed circuit board adapted for heat dissipation, e.g. lay-out of conductors, coatings
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/01Dielectrics
    • H05K2201/0104Properties and characteristics in general
    • H05K2201/0108Transparent
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/01Dielectrics
    • H05K2201/0104Properties and characteristics in general
    • H05K2201/012Flame-retardant; Preventing of inflammation
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/01Dielectrics
    • H05K2201/0137Materials
    • H05K2201/0145Polyester, e.g. polyethylene terephthalate [PET], polyethylene naphthalate [PEN]
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/01Dielectrics
    • H05K2201/0183Dielectric layers
    • H05K2201/0195Dielectric or adhesive layers comprising a plurality of layers, e.g. in a multilayer structure

Abstract

The invention discloses a kind of heat-resisting flame-retardant ceramic printed-circuit boards, including ceramic substrate, the metallic circuit that is printed on ceramic substrate upper layer, are laid on metallic circuit upper layer equipped with clear dope layer, the refractory layer for being laid on ceramic substrate lower layer, the flame-retardant layer for being laid on refractory layer lower layer.A kind of heat-resisting flame-retardant ceramic printed-circuit board of the invention realizes heat-proof combustion-resistant performance, increases the security performance of printed circuit board by the effect of refractory layer and flame-retardant layer;Meanwhile the present invention is equipped with clear dope layer composite ceramics nanometer tungsten oxide, can effectively realize the heat-proof quality outside metallic circuit, improves the heat resistance of printed circuit board entirety.

Description

A kind of heat-resisting flame-retardant ceramic printed-circuit board
Technical field
The present invention relates to a kind of heat-resisting flame-retardant ceramic printed-circuit boards, belong to printed-board technology field.
Background technique
Ceramic substrate, which refers to, to be bonded directly to aluminium oxide or aluminium nitride ceramic substrate surface by copper foil at high temperature (single side is double Face) on special process plate, the system of circuit board is applied to due to having many advantages, such as chemical corrosion resistance, applicable mechanical strength Make.But in use there may be poor heat resistance, when the temperature is excessively high may occur burning etc. security risks.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the deficiencies of existing technologies, a kind of heat-resisting flame-retardant ceramics print is provided Printed circuit board realizes heat-proof combustion-resistant performance, increases the security performance of printed circuit board.
In order to solve the above technical problems, the present invention provides a kind of heat-resisting flame-retardant ceramic printed-circuit board, including ceramic base Plate, the metallic circuit for being printed on ceramic substrate upper layer, be laid on metallic circuit upper layer equipped with clear dope layer, be laid on ceramic base The refractory layer of plate lower layer, the flame-retardant layer for being laid on refractory layer lower layer.
Preferably, the clear dope layer is composite ceramics nanometer tungsten oxide.
Preferably, the component of the refractory layer and the parts by weight of each component are as follows: 60 ~ 80 parts of polyester resin, 30 ~ 40 parts Epoxy acrylate, 2 ~ 5 parts of surfactants.
Preferably, the component of the flame-retardant layer and the parts by weight of each component are as follows: 60 ~ 80 parts of polyester resin, 10 ~ 20 parts Polypropylene carbonate, 2 ~ 5 parts of surfactants.
Preferably, the polyester resin is polyethylene terephthalate.
Preferably, the surfactant is methacrylic acid polyoxyethylene enester.
Preferably, the metallic circuit is printed on ceramic substrate by metal paste and is obtained.
Preferably, metal paste is one of copper or aluminium.
Advantageous effects of the invention: a kind of heat-resisting flame-retardant ceramic printed-circuit board of the invention, by heat-resisting The effect of layer and flame-retardant layer realizes heat-proof combustion-resistant performance, increases the security performance of printed circuit board;Meanwhile the present invention is equipped with thoroughly Bright dope layer composite ceramics nanometer tungsten oxide can effectively realize the heat-proof quality outside metallic circuit, and it is whole to improve printed circuit board The heat resistance of body.
Detailed description of the invention
Fig. 1 is the schematic diagram of heat-resisting flame-retardant ceramic printed-circuit board of the invention;
Appended drawing reference is as follows:
1, ceramic substrate;2, metal circuit board;3, clear dope layer;4, refractory layer;5, flame-retardant layer.
Specific embodiment
The invention will be further described below in conjunction with the accompanying drawings.Following embodiment is only used for clearly illustrating the present invention Technical solution, and not intended to limit the protection scope of the present invention.
As shown in Figure 1, a kind of heat-resisting flame-retardant ceramic printed-circuit board, including ceramic substrate 1, it is printed on ceramic substrate 1 The metallic circuit on upper layer is laid on the refractory layer that metallic circuit upper layer is equipped with clear dope layer 3, is laid on 1 lower layer of ceramic substrate 4, it is laid on the flame-retardant layer 5 of 4 lower layer of refractory layer.
By the effect of refractory layer and flame-retardant layer, realizes heat-proof combustion-resistant performance, increase the security performance of printed circuit board.
Embodiment 1
As shown in Figure 1, a kind of heat-resisting flame-retardant ceramic printed-circuit board, including ceramic substrate 1, it is printed on 1 upper layer of ceramic substrate Metallic circuit, be laid on metallic circuit upper layer equipped with clear dope layer 3, be laid on 1 lower layer of ceramic substrate refractory layer 4, paving It is located at the flame-retardant layer 5 of 4 lower layer of refractory layer.Clear dope layer 3 is composite ceramics nanometer tungsten oxide.The component and each group of refractory layer 4 The parts by weight divided are as follows: 60 parts of polyethylene terephthalate, 30 parts of epoxy acrylate, 2 parts of methacrylic acid polyoxies Change vinyl acetate.The component of flame-retardant layer 5 and the parts by weight of each component are as follows: 80 parts of polyethylene terephthalate, 20 parts poly- Propene carbonate, 5 parts of methacrylic acid polyoxyethylene enesters.Metallic circuit is printed on ceramic substrate 1 by metal paste and is obtained, Metal paste is copper.
Embodiment 2
As shown in Figure 1, a kind of heat-resisting flame-retardant ceramic printed-circuit board, including ceramic substrate 1, it is printed on 1 upper layer of ceramic substrate Metallic circuit, be laid on metallic circuit upper layer equipped with clear dope layer 3, be laid on 1 lower layer of ceramic substrate refractory layer 4, paving It is located at the flame-retardant layer 5 of 4 lower layer of refractory layer.Clear dope layer 3 is composite ceramics nanometer tungsten oxide.The component and each group of refractory layer 4 The parts by weight divided are as follows: 80 parts of polyethylene terephthalate, 40 parts of epoxy acrylate, 5 parts of methacrylic acid polyoxies Change vinyl acetate.The component of flame-retardant layer 5 and the parts by weight of each component are as follows: 60 parts of polyethylene terephthalate, 10 parts poly- Propene carbonate, 2 parts of methacrylic acid polyoxyethylene enesters.Metallic circuit is printed on ceramic substrate 1 by metal paste and is obtained, Metal paste is aluminium.
Embodiment 3
As shown in Figure 1, a kind of heat-resisting flame-retardant ceramic printed-circuit board, including ceramic substrate 1, it is printed on 1 upper layer of ceramic substrate Metallic circuit, be laid on metallic circuit upper layer equipped with clear dope layer 3, be laid on 1 lower layer of ceramic substrate refractory layer 4, paving It is located at the flame-retardant layer 5 of 4 lower layer of refractory layer.Clear dope layer 3 is composite ceramics nanometer tungsten oxide.The component and each group of refractory layer 4 The parts by weight divided are as follows: 70 parts of polyethylene terephthalate, 35 parts of epoxy acrylate, 3 parts of methacrylic acid polyoxies Change vinyl acetate.The component of flame-retardant layer 5 and the parts by weight of each component are as follows: 70 parts of polyethylene terephthalate, 15 parts poly- Propene carbonate, 3 parts of methacrylic acid polyoxyethylene enesters.Metallic circuit is printed on ceramic substrate 1 by metal paste and is obtained, Metal paste is aluminium.
A kind of heat-resisting flame-retardant ceramic printed-circuit board of the invention is realized by the effect of refractory layer 4 and flame-retardant layer 5 Heat-proof combustion-resistant performance increases the security performance of printed circuit board;Meanwhile the present invention is equipped with 3 composite ceramics nanometer of clear dope layer Tungsten oxide can effectively realize the heat-proof quality outside metallic circuit, improve the heat resistance of printed circuit board entirety.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, several improvement and deformations can also be made, these improvement and deformations Also it should be regarded as protection scope of the present invention.

Claims (8)

1. a kind of heat-resisting flame-retardant ceramic printed-circuit board, characterized in that including ceramic substrate, be printed on ceramic substrate upper layer Metallic circuit, be laid on metallic circuit upper layer equipped with clear dope layer, be laid on ceramic substrate lower layer refractory layer, be laid on it is resistance to The flame-retardant layer of thermosphere lower layer.
2. heat-resisting flame-retardant ceramic printed-circuit board according to claim 1, characterized in that the clear dope layer is multiple Close ceramic nano tungsten oxide.
3. heat-resisting flame-retardant ceramic printed-circuit board according to claim 1, characterized in that the component of the refractory layer and The parts by weight of each component are as follows: 60 ~ 80 parts of polyester resin, 30 ~ 40 parts of epoxy acrylate, 2 ~ 5 parts of surfactants.
4. heat-resisting flame-retardant ceramic printed-circuit board according to claim 1, characterized in that the component of the flame-retardant layer and The parts by weight of each component are as follows: 60 ~ 80 parts of polyester resin, 10 ~ 20 parts of polypropylene carbonate, 2 ~ 5 parts of surfactants.
5. heat-resisting flame-retardant ceramic printed-circuit board according to claim 3 or 4, characterized in that the polyester resin is Polyethylene terephthalate.
6. heat-resisting flame-retardant ceramic printed-circuit board according to claim 3 or 4, characterized in that the surfactant For methacrylic acid polyoxyethylene enester.
7. heat-resisting flame-retardant ceramic printed-circuit board according to claim 1, characterized in that the metallic circuit is by metal Slurry is printed on ceramic substrate and obtains.
8. heat-resisting flame-retardant ceramic printed-circuit board according to claim 7, characterized in that metal paste is in copper or aluminium One kind.
CN201811146393.1A 2018-09-29 2018-09-29 Heat-resistant flame-retardant ceramic printed circuit board Active CN109392239B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811146393.1A CN109392239B (en) 2018-09-29 2018-09-29 Heat-resistant flame-retardant ceramic printed circuit board

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Application Number Priority Date Filing Date Title
CN201811146393.1A CN109392239B (en) 2018-09-29 2018-09-29 Heat-resistant flame-retardant ceramic printed circuit board

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CN109392239A true CN109392239A (en) 2019-02-26
CN109392239B CN109392239B (en) 2021-01-08

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Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201830547U (en) * 2010-10-28 2011-05-11 都江堰市三美科技有限公司 Ceramic printed circuit board
CN104703307A (en) * 2015-02-10 2015-06-10 孙庄 Ceramic heating slice
CN105755819A (en) * 2016-03-24 2016-07-13 临沂中瑞防辐射科技有限公司 Fireproof electromagnetic shielding and radiation protection cloth
CN205395301U (en) * 2016-03-07 2016-07-27 广州乐高建筑科技有限公司 Anti high temperature flame -resistant resin board
CN206402530U (en) * 2017-02-14 2017-08-11 丰顺县和生电子有限公司 A kind of low-power consumption type printed circuit board (PCB)
CN207150943U (en) * 2017-08-11 2018-03-27 温州市永利电子有限公司 A kind of waterproof circuit board
CN207274034U (en) * 2017-06-29 2018-04-27 浙江美成电子科技有限公司 A kind of high temperature resistant type glass refill composite-based copper clad plate
CN207305042U (en) * 2017-09-11 2018-05-01 佛山市南海厚博电子技术有限公司 A kind of highly integrated heat-resisting circuit board
CN207460589U (en) * 2017-07-26 2018-06-05 哈尔滨工业大学(威海) A kind of graphite composite circuit board
CN108207089A (en) * 2016-12-20 2018-06-26 无锡深南电路有限公司 A kind of method for cancelling communication IC Metal Substrate support plate copper block oxides
CN207560443U (en) * 2017-11-21 2018-06-29 深圳市恒讯通电子有限公司 A kind of composite circuit board
US20180206328A1 (en) * 2017-01-17 2018-07-19 Northrop Grumman Systems Corporation Alloy bonded graphene sheets for enhanced thermal spreaders
CN108419358A (en) * 2018-03-09 2018-08-17 生益电子股份有限公司 A kind of high heat dissipation PCB and preparation method thereof

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201830547U (en) * 2010-10-28 2011-05-11 都江堰市三美科技有限公司 Ceramic printed circuit board
CN104703307A (en) * 2015-02-10 2015-06-10 孙庄 Ceramic heating slice
CN205395301U (en) * 2016-03-07 2016-07-27 广州乐高建筑科技有限公司 Anti high temperature flame -resistant resin board
CN105755819A (en) * 2016-03-24 2016-07-13 临沂中瑞防辐射科技有限公司 Fireproof electromagnetic shielding and radiation protection cloth
CN108207089A (en) * 2016-12-20 2018-06-26 无锡深南电路有限公司 A kind of method for cancelling communication IC Metal Substrate support plate copper block oxides
US20180206328A1 (en) * 2017-01-17 2018-07-19 Northrop Grumman Systems Corporation Alloy bonded graphene sheets for enhanced thermal spreaders
CN206402530U (en) * 2017-02-14 2017-08-11 丰顺县和生电子有限公司 A kind of low-power consumption type printed circuit board (PCB)
CN207274034U (en) * 2017-06-29 2018-04-27 浙江美成电子科技有限公司 A kind of high temperature resistant type glass refill composite-based copper clad plate
CN207460589U (en) * 2017-07-26 2018-06-05 哈尔滨工业大学(威海) A kind of graphite composite circuit board
CN207150943U (en) * 2017-08-11 2018-03-27 温州市永利电子有限公司 A kind of waterproof circuit board
CN207305042U (en) * 2017-09-11 2018-05-01 佛山市南海厚博电子技术有限公司 A kind of highly integrated heat-resisting circuit board
CN207560443U (en) * 2017-11-21 2018-06-29 深圳市恒讯通电子有限公司 A kind of composite circuit board
CN108419358A (en) * 2018-03-09 2018-08-17 生益电子股份有限公司 A kind of high heat dissipation PCB and preparation method thereof

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