CN109382097A - 一种微乳液法制备铂铱钌复合纳米颗粒的方法 - Google Patents
一种微乳液法制备铂铱钌复合纳米颗粒的方法 Download PDFInfo
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- CN109382097A CN109382097A CN201811147744.0A CN201811147744A CN109382097A CN 109382097 A CN109382097 A CN 109382097A CN 201811147744 A CN201811147744 A CN 201811147744A CN 109382097 A CN109382097 A CN 109382097A
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- Prior art keywords
- platinoiridita
- microemulsion
- ruthenium composite
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- solution
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- 239000002131 composite material Substances 0.000 title claims abstract description 37
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 229910052707 ruthenium Inorganic materials 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 19
- 239000002245 particle Substances 0.000 title claims abstract description 16
- 238000000593 microemulsion method Methods 0.000 title claims abstract description 14
- 239000002105 nanoparticle Substances 0.000 claims abstract description 27
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 23
- 229910021638 Iridium(III) chloride Inorganic materials 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims description 19
- 239000002243 precursor Substances 0.000 claims description 18
- 239000000725 suspension Substances 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 17
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 9
- 238000010907 mechanical stirring Methods 0.000 claims description 9
- 239000011541 reaction mixture Substances 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 235000019441 ethanol Nutrition 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- 238000005119 centrifugation Methods 0.000 claims 1
- 229910019891 RuCl3 Inorganic materials 0.000 abstract description 9
- 239000000463 material Substances 0.000 abstract description 5
- 238000002360 preparation method Methods 0.000 abstract description 5
- 239000007772 electrode material Substances 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 3
- 229910002621 H2PtCl6 Inorganic materials 0.000 abstract description 2
- 239000000470 constituent Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 24
- 239000003795 chemical substances by application Substances 0.000 description 8
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 7
- DANYXEHCMQHDNX-UHFFFAOYSA-K trichloroiridium Chemical compound Cl[Ir](Cl)Cl DANYXEHCMQHDNX-UHFFFAOYSA-K 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910019020 PtO2 Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- CJTCBBYSPFAVFL-UHFFFAOYSA-N iridium ruthenium Chemical compound [Ru].[Ir] CJTCBBYSPFAVFL-UHFFFAOYSA-N 0.000 description 1
- HTXDPTMKBJXEOW-UHFFFAOYSA-N iridium(IV) oxide Inorganic materials O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
- B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/468—Iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/33—Electric or magnetic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y20/00—Nanooptics, e.g. quantum optics or photonic crystals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biophysics (AREA)
- Optics & Photonics (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (7)
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CN201811147744.0A CN109382097B (zh) | 2018-09-29 | 2018-09-29 | 一种微乳液法制备铂铱钌复合纳米颗粒的方法 |
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CN109382097A true CN109382097A (zh) | 2019-02-26 |
CN109382097B CN109382097B (zh) | 2021-09-17 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110560049A (zh) * | 2019-09-25 | 2019-12-13 | 陕西科技大学 | 一种用微乳液法制备铂钌钛复合纳米颗粒的方法 |
CN111704211A (zh) * | 2020-06-26 | 2020-09-25 | 陕西科技大学 | 一种铂钌钛钇dsa电极的制备方法 |
CN112658275A (zh) * | 2020-12-02 | 2021-04-16 | 山东大学 | 一种利用激光辐照声悬浮液滴制备钌铱纳米合金的方法 |
Citations (5)
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US20060166811A1 (en) * | 2004-12-30 | 2006-07-27 | Industrial Technology Research Institute | Hollow mesoporous carbon electrode-catalyst for direct methanol fuel cell and preparation thereof |
CN101157034A (zh) * | 2007-11-13 | 2008-04-09 | 上海师范大学 | 一种非晶态合金催化剂及其制备方法和用途 |
CN101260299A (zh) * | 2008-04-03 | 2008-09-10 | 沈阳化工学院 | 一种微乳液法制备氧化钇、钆、铕纳米发光粉体的方法 |
CN102451688A (zh) * | 2010-10-27 | 2012-05-16 | 中国科学院大连化学物理研究所 | 一种空心纳米复合氧化物材料及其制备 |
CN104858413A (zh) * | 2014-02-21 | 2015-08-26 | 中国科学院大连化学物理研究所 | 一种二氧化硅负载贵金属纳米颗粒的制备方法 |
-
2018
- 2018-09-29 CN CN201811147744.0A patent/CN109382097B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060166811A1 (en) * | 2004-12-30 | 2006-07-27 | Industrial Technology Research Institute | Hollow mesoporous carbon electrode-catalyst for direct methanol fuel cell and preparation thereof |
CN101157034A (zh) * | 2007-11-13 | 2008-04-09 | 上海师范大学 | 一种非晶态合金催化剂及其制备方法和用途 |
CN101260299A (zh) * | 2008-04-03 | 2008-09-10 | 沈阳化工学院 | 一种微乳液法制备氧化钇、钆、铕纳米发光粉体的方法 |
CN102451688A (zh) * | 2010-10-27 | 2012-05-16 | 中国科学院大连化学物理研究所 | 一种空心纳米复合氧化物材料及其制备 |
CN104858413A (zh) * | 2014-02-21 | 2015-08-26 | 中国科学院大连化学物理研究所 | 一种二氧化硅负载贵金属纳米颗粒的制备方法 |
Non-Patent Citations (2)
Title |
---|
J. SOLLA-GULLON ET AL.: "Electrochemical characterization of platinum–ruthenium nanoparticles prepared by water-in-oil microemulsion", 《ELECTROCHIMICA ACTA》 * |
V. BAGLIO ET AL.: "IrO2 as a promoter of Pt–Ru for methanol electro-oxidation", 《PHYS. CHEM. CHEM. PHYS.》 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110560049A (zh) * | 2019-09-25 | 2019-12-13 | 陕西科技大学 | 一种用微乳液法制备铂钌钛复合纳米颗粒的方法 |
CN110560049B (zh) * | 2019-09-25 | 2022-08-12 | 陕西科技大学 | 一种用微乳液法制备铂钌钛复合纳米颗粒的方法 |
CN111704211A (zh) * | 2020-06-26 | 2020-09-25 | 陕西科技大学 | 一种铂钌钛钇dsa电极的制备方法 |
CN112658275A (zh) * | 2020-12-02 | 2021-04-16 | 山东大学 | 一种利用激光辐照声悬浮液滴制备钌铱纳米合金的方法 |
CN112658275B (zh) * | 2020-12-02 | 2022-03-29 | 山东大学 | 一种利用激光辐照声悬浮液滴制备钌铱纳米合金的方法 |
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CN109382097B (zh) | 2021-09-17 |
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Address after: 710086 room 034, F2002, 20 / F, block 4-A, Xixian financial port, Fengdong new town energy Jinmao District, Xixian New District, Xi'an, Shaanxi Province Patentee after: Shaanxi Haofeng Jingcheng Environmental Technology Co.,Ltd. Address before: 215537 building 4, No. 2, Jianye Road, high tech Industrial Park, Changshu Economic and Technological Development Zone, Suzhou City, Jiangsu Province Patentee before: Shaanxi Haofeng Jingcheng Environmental Technology Co.,Ltd. |
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