CN109380251A - One kind having synergic bactericide composition - Google Patents
One kind having synergic bactericide composition Download PDFInfo
- Publication number
- CN109380251A CN109380251A CN201710659776.8A CN201710659776A CN109380251A CN 109380251 A CN109380251 A CN 109380251A CN 201710659776 A CN201710659776 A CN 201710659776A CN 109380251 A CN109380251 A CN 109380251A
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- CN
- China
- Prior art keywords
- agent
- tebuconazole
- carbendazim
- filler
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
- A01N25/14—Powders or granules wettable
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
Abstract
The present invention relates to one kind to have synergic bactericide composition, shows extremely strong bactericidal activity, applies for preventing and treating in all kinds of diseases of wheat, apple tree, grape, tomato, cucumber, strawberry.There is protection and therapeutic effect, the composition fungicide to be different from other existing agriculture chemicals fungicides crop.Composition fungicide effective component is made of carbendazim, Tebuconazole, and composition fungicide raw material weight per distribution ratio is carbendazim 5 ~ 45%, Tebuconazole 2 ~ 43%, auxiliary agent 2~25%, filler 10~91%.A kind of microbicide compositions with synergistic function are applied in wheat, apple tree, grape, tomato, cucumber, all kinds of diseases of strawberry.
Description
Technical field
The present invention relates to one kind to have synergic bactericide composition, shows extremely strong antibacterial and sterilization is lived
Property, it is applied to agricultural plant chemoproection field, it is all kinds of is mainly used for prevention and treatment wheat, apple tree, grape, tomato, cucumber, strawberry
It is applied in disease, there is protective effect and therapeutic effect to crops, the composition fungicide is different from other existing sterilizations
Agent composition.
Background technique
Carbendazim, English common name: carbendazim is a kind of broad-spectrum germicide, to various crop by fungi (such as
Fungi Imperfecti, more sac fungus) caused by disease have control efficiency.It can be used for foliar spray, seed treatment and soil treatment etc.., right
Crop, people, animal and beneficial organism safety, it is substantially pollution-free to environment.
Tebuconazole, English common name: tebuconazole is systemic fungicide, inhibits sterol demethylation, can be fabulous
Prevention and treatment Rust, Erysiphe, beak genuss, Pyrenophora and Sales needle spore belong to caused by disease, but phytophthora, dry rot fungus are imitated
Fruit is poor.
Summary of the invention
It is a kind of with synergic bactericide composition the purpose of the present invention is in view of the above shortcomings, providing: more bacterium
Spirit is compounded with Tebuconazole, with apparent synergistic effect, while expanding fungicidal spectrum, to apple tree, grape, tomato, cucumber, small
It is applied in all kinds of diseases of wheat, control efficiency is good, is applied alone better than carbendazim, Tebuconazole two medicaments, while can reduce agriculture sheet, two
No interactions resistance between person.
A kind of microbicide compositions with synergistic function take following scheme to realize: composition fungicide by
Two kinds of effective component carbendazim and Tebuconazole composition, are added auxiliary agent and filler can be made into wettable powder or suspending agent, composition
Fungicide prepares raw material accounting example each by weight percentage are as follows: carbendazim 5 ~ 45%, Tebuconazole 2 ~ 43%, auxiliary agent 2~25%, filler
10~91%.
The auxiliary agent of wettable powder is made of dispersing agent 1.95~20% and wetting agent 0.05~5%.In wettable powder
Dispersing agent uses lignosulfonates (calcium salt or sodium salt), NNO, one of pull open powder or mixture；Wetting agent uses alkyl
Benzene sulfonate (calcium salt or sodium salt)；Filler uses silica-based (such as clay, kaolin, diatomite), and precipitated calcium carbonate is white
One of carbon black or mixture.
The auxiliary agent of suspending agent is by dispersion moisture agent 1~15%, antifreeze 1~3%, thickener 2~5%, defoaming agent 0.05
~2% composition.Dispersion moisture agent in suspending agent uses polyoxyethylene triphenyl phosphate, alkylnaphthalene sulfonate, and alkyl phenol gathers
One of ethylene oxide ether or mixture；Antifreeze uses alcohols, such as propylene glycol or glycerine or ethylene glycol；Thickener uses
Xanthan gum or aluminium-magnesium silicate；Defoaming agent uses organic silicon defoamer；Filler uses water, one of White Carbon black or mixture.
A kind of microbicide compositions process of preparing with synergistic function: composition is weighed more by said ratio
Bacterium spirit and Tebuconazole are wettable powder or suspending agent according to product form obtained is wanted, and use the auxiliary agent being respectively formulated
And filler, it is sufficiently mixed uniformly, after airslide disintegrating mill crushes or sand mill grinds, remixes uniformly to get to finished product,
Finished product meets indices requirement of the country to wettable powder or suspending agent.
A kind of microbicide compositions with synergistic function are sick in prevention and treatment wheat, apple tree, grape, cucumber, strawberry
It is applied in evil, to crop safety, at low cost, preventive effect is good.It proving after tested, microbicide compositions chemical property of the present invention is stablized,
Synergy is significant, shows apparent synergy and complementation to controlling object.
Embodiment:
The present invention is further discussed below below with reference to embodiment.
Embodiment 1:40% carbendazim tebuconazole suspension concentrates
Tebuconazole 5%
Carbendazim 35%
Nonylphenol polyoxyethylene ether (NP-9) (dispersion moisture agent) 8%
Propylene glycol (antifreeze) 0.5%
Xanthan gum (thickener) 1%
Organic silicon defoamer (SAG612) 2%
Water (filler) 48.5%
2000~3000 times of liquid of the preparation being made into according to the above ratio to the preventive effect of wheat scab 70% or more, better than being applied alone.
40% carbendazim Tebuconazole SC prevents and treats 7 days preventive effects (%) (Yancheng, Jiangsu Province) after wheat scab medicine
30 days investigation preventive effect tables after secondary medicine
Embodiment 2:50% carbendazim tebuconazole suspension concentrates
Tebuconazole 5%
Carbendazim 45%
Polyoxyethylene triphenyl calcium phosphate (dispersion moisture agent) 6%
Ethylene glycol (antifreeze) 1%
Aluminium-magnesium silicate (thickener) 3%
Organic silicon defoamer (Sag587) 0.6%
White Carbon black (filler) 2%
Water (filler) 31.4%
2000~3000 times of liquid of the preparation being made into according to the above ratio to the preventive effect of graw mold of tomato 80% or more, better than being applied alone.
60% carbendazim Tebuconazole SC prevents and treats graw mold of tomato preventive effect (Hefei ,Anhui) 10 days preventive effect tables after medicine three times
3 45% carbendazim tebuconazole suspension concentrates of embodiment
Tebuconazole 40%
Carbendazim 5%
Negel (soprophor FL) (dispersion moisture agent) 8%
Glycerine (antifreeze) 2%
Xanthan gum (thickener) 4%
Organic silicon defoamer (Sag722) 0.3%
Water (filler) 45.7%
1000~2000 times of liquid of the preparation being made into according to the above ratio 70% or more, are better than single the preventive effect of powdery mildew of strawberry disease
With.
45% carbendazim Tebuconazole SC prevents and treats powdery mildew of strawberry disease drug effect (Transition In Jurong, Jiangsu)
10 days preventive effect tables after third time medicine
Embodiment 4:30% carbendazim tebuconazole suspension concentrates
Tebuconazole 5%
Carbendazim 25%
Alkyl naphthalene sulfonic acid calcium (soprophor FL) (dispersion moisture agent) 8%
Propylene glycol (antifreeze) 2%
Xanthan gum (thickener) 8%
Organic silicon defoamer (Sag72) 0.2%
White Carbon black (filler) 10%
Water (filler) 41.8%
1000~2000 times of liquid of the suspending agent being made into according to the above ratio 70% or more, are better than single the preventive effect of graw mold of tomato
With.
30% carbendazim Tebuconazole SC prevents and treats 7 days preventive effect tables after graw mold of tomato preventive effect (Nantong) medicine
Embodiment 5:47% carbendazim tebuconazole suspension concentrates
Carbendazim 45%
Tebuconazole 2%
Negel (soprophor FL) (dispersion moisture agent) 6%
Glycerine (antifreeze) 3%
Aluminium-magnesium silicate (thickener) 5%
Organic silicon defoamer (Sag22) 0.1%
White Carbon black (filler) 10%
Water (filler) 31.9%
1500~2500 times of liquid of the suspending agent being made into according to the above ratio 80% or more, are better than normal the preventive effect of wheat powdery mildew disease
Advise the carbendazim medicament used.
47% carbendazim Tebuconazole SC prevents and treats 5 days preventive effect tables after wheat powdery mildew preventive effect (Jiangsu Jiangdu) medicine
Embodiment 6:88% carbendazim Tebuconazole wettable powder
Carbendazim 65%
Tebuconazole 23%
NNO(dispersing agent) 2%
Sodium lignin sulfonate (dispersing agent) 3%
Sodium alkyl benzene sulfonate (wetting agent) 0.5%
White Carbon black (filler) 6.5%
1500~2500 times of liquid of the preparation being made into according to the above ratio 80% or so, are better than single the preventive effect of apple tree ring spot
With.
88% carbendazim Tebuconazole WP prevents and treats 7 days preventive effects (%) (Jiangsu Feng County) after ring rot of apple medicine
| Processing | I | II | III | IV | It is average |
| 1500 times | 90.12 | 94.52 | 92.96 | 93.65 | 93.06 |
| 2000 times | 85.38 | 86.82 | 85.32 | 87.21 | 86.18 |
| 2500 times | 78.47 | 77.21 | 76.89 | 77.88 | 77.61 |
| 50% 2000 times of carbendazim SC | 72.38 | 73.52 | 72.42 | 73.60 | 72.98 |
| 25% 2000 times of Tebuconazole EW | 58.81 | 57.93 | 56.88 | 60.12 | 58.44 |
88% carbendazim Tebuconazole WP prevents and treats fortnight preventive effect (%) (Jiangsu Feng County) after scab of apple disease medicine
| Processing | I | II | III | IV | It is average |
| 2000 times | 86.11 | 87.17 | 88.04 | 89.05 | 87.59 |
| 2500 times | 73.86 | 75.33 | 78.18 | 76.54 | 75.98 |
| 3000 times | 70.08 | 71.33 | 68.54 | 69.24 | 69.79 |
| 50% 2500 times of carbendazim SC | 63.88 | 62.58 | 68.07 | 67.44 | 65.49 |
| 25% 2000 times of Tebuconazole EW | 54.13 | 50.09 | 54.76 | 52.38 | 52.84 |
Embodiment 7:7% carbendazim Tebuconazole wettable powder
Carbendazim 5%
Tebuconazole 2%
NNO(dispersing agent) 5%
Pull open powder (dispersing agent) 3%
Alkyl benzene calcium sulfonate (wetting agent) 1%
White Carbon black (filler) 5%
Diatomite (filler) 79%
600~800 times of liquid of the preparation being made into according to the above ratio to the preventive effect of gray mold of cucumber 70% or more, better than being applied alone.
7% carbendazim Tebuconazole wettable powder prevents and treats gray mold of cucumber preventive effect (Jiangsu)
Embodiment 8:40% carbendazim Tebuconazole wettable agent
Tebuconazole 5%
Carbendazim 35%
Calcium lignosulfonate (dispersing agent) 8%
Alkyl benzene calcium sulfonate (wetting agent) 1%
Clay (filler) 25%
Precipitated calcium carbonate (filler) 26%
1000~2000 times of liquid of the preparation being made into according to the above ratio to the preventive effect of fruit white rot of grape 70% or more, better than being applied alone.
40% carbendazim Tebuconazole wettable powder prevents and treats fruit white rot of grape preventive effect (Hebei Changli)
Claims (5)
1. one kind has synergic bactericide composition, which is characterized in that pesticide composition is by effective component carbendazim
It is formed with Tebuconazole, it is respectively carbendazim 5 ~ 45%, Tebuconazole 2 ~ 43%, auxiliary agent that composition fungicide, which prepares raw material weight percentage,
2~25%, filler 10~91%.
2. a kind of microbicide compositions with synergistic function according to claim 1, which is characterized in that one kind has
Suspending agent or wettable powder can be made in the microbicide compositions of synergistic function.
3. a kind of microbicide compositions with synergistic function according to claim 1 or claim 2, which is characterized in that suspend
The auxiliary agent of agent is made of dispersion moisture agent 1~15%, antifreeze 1~3%, thickener 2~5%, defoaming agent 0.05~2%；It is outstanding
Dispersion moisture agent in floating agent uses polyoxyethylene triphenyl phosphate, alkylnaphthalene sulfonate, in alkyl phenol polyoxyethylene ether
A kind of or mixture；Antifreeze uses alcohols, such as propylene glycol or glycerine or ethylene glycol；Thickener uses xanthan gum or silicic acid
Magnalium；Defoaming agent uses organic silicon defoamer；Filler uses water, one of White Carbon black or mixture.
4. a kind of microbicide compositions with synergistic function according to claim 1 or claim 2, which is characterized in that wettable
The auxiliary agent of property pulvis is made of dispersing agent 1.95~20% and wetting agent 0.05~5%；Dispersing agent is using wood in wettable powder
Mahogany sulfonate (calcium salt or sodium salt), NNO, one of pull open powder or mixture；Wetting agent uses alkylbenzene sulfonate (calcium salt
Or sodium salt)；Filler use silica-based (such as clay, kaolin, diatomite), precipitated calcium carbonate, one of White Carbon black or
Mixture.
5. the microbicide compositions described in claim 1 with synergistic effect are in prevention and treatment wheat, apple tree, grape, tomato, Huang
It is applied in all kinds of diseases of melon, strawberry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710659776.8A CN109380251A (en) | 2017-08-04 | 2017-08-04 | One kind having synergic bactericide composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710659776.8A CN109380251A (en) | 2017-08-04 | 2017-08-04 | One kind having synergic bactericide composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109380251A true CN109380251A (en) | 2019-02-26 |
Family
ID=65413299
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710659776.8A Pending CN109380251A (en) | 2017-08-04 | 2017-08-04 | One kind having synergic bactericide composition |
Country Status (1)
| Country | Link |
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| CN (1) | CN109380251A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019179310A1 (en) * | 2018-03-22 | 2019-09-26 | Jiangsu Rotam Chemistry Co., Ltd | Fungicidal compositions having carbendazim and tebuconazole and methods for using such compositions |
-
2017
- 2017-08-04 CN CN201710659776.8A patent/CN109380251A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019179310A1 (en) * | 2018-03-22 | 2019-09-26 | Jiangsu Rotam Chemistry Co., Ltd | Fungicidal compositions having carbendazim and tebuconazole and methods for using such compositions |
| CN112236038A (en) * | 2018-03-22 | 2021-01-15 | 江苏龙灯化学有限公司 | Fungicidal compositions having carbendazim and tebuconazole and methods of using such compositions |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190226 |
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| WD01 | Invention patent application deemed withdrawn after publication |