CN100473279C - Germicide composition containing thiophanate and tricyclazole - Google Patents
Germicide composition containing thiophanate and tricyclazole Download PDFInfo
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- CN100473279C CN100473279C CNB2007100256944A CN200710025694A CN100473279C CN 100473279 C CN100473279 C CN 100473279C CN B2007100256944 A CNB2007100256944 A CN B2007100256944A CN 200710025694 A CN200710025694 A CN 200710025694A CN 100473279 C CN100473279 C CN 100473279C
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- CN
- China
- Prior art keywords
- tricyclazole
- thiophanate
- methyl
- rice
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 239000000203 mixture Substances 0.000 title claims description 28
- 230000002070 germicidal effect Effects 0.000 title abstract description 8
- YFNCATAIYKQPOO-UHFFFAOYSA-N thiophanate Chemical compound CCOC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OCC YFNCATAIYKQPOO-UHFFFAOYSA-N 0.000 title 1
- 239000005842 Thiophanate-methyl Substances 0.000 claims abstract description 50
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 claims abstract description 50
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 40
- 235000009566 rice Nutrition 0.000 claims abstract description 40
- 201000010099 disease Diseases 0.000 claims abstract description 21
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 239000000654 additive Substances 0.000 claims abstract description 8
- 230000000996 additive effect Effects 0.000 claims abstract description 8
- 239000004480 active ingredient Substances 0.000 claims abstract description 5
- 230000003641 microbiacidal effect Effects 0.000 claims description 17
- 229940124561 microbicide Drugs 0.000 claims description 17
- 239000002855 microbicide agent Substances 0.000 claims description 17
- 239000000375 suspending agent Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 7
- 238000009736 wetting Methods 0.000 claims description 4
- 240000007594 Oryza sativa Species 0.000 claims 1
- 241000209094 Oryza Species 0.000 abstract description 39
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 7
- 239000004563 wettable powder Substances 0.000 abstract description 7
- 230000002265 prevention Effects 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000003905 agrochemical Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 230000003449 preventive effect Effects 0.000 description 26
- 239000002270 dispersing agent Substances 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 238000005303 weighing Methods 0.000 description 11
- 239000003814 drug Substances 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- 230000002528 anti-freeze Effects 0.000 description 7
- -1 antifreeze Substances 0.000 description 7
- 239000002562 thickening agent Substances 0.000 description 7
- 239000000080 wetting agent Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 239000006229 carbon black Substances 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000002518 antifoaming agent Substances 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- 229920001285 xanthan gum Polymers 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 229940077388 benzenesulfonate Drugs 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 3
- 230000002554 disease preventive effect Effects 0.000 description 3
- 230000000855 fungicidal effect Effects 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 206010059866 Drug resistance Diseases 0.000 description 2
- 206010034133 Pathogen resistance Diseases 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 2
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
- 230000001225 therapeutic effect Effects 0.000 description 2
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000005839 Tebuconazole Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000011278 mitosis Effects 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000004763 spore germination Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a germicide combination which comprises thiophanate-methyl and tricyclazole, which has strong antibacterial and germicidal activity, and is applicable for the agricultural chemical protection field. The invention is mainly used for various diseases prevention and cure of the rice and has protection and cure functions to the rice, and the germicide combination is different from the prior other germicide combinations. The active ingredients of the invention are made from thiophanate-methyl and tricyclazole; the percentage of the weight distribution of the raw materials of the germicide combination is that: the thiophanate-methyl is from 20 percent to 50 percent; the tricyclazole is from 10 percent to 45 percent; the additive agent is ranged from 5 percent to 70 percent. The germicide combination can be made into wettable powder and suspension. The invention can be applicable for the various diseases prevention and cure of the rice.
Description
Technical field
What the present invention relates to is a kind of microbicide compositions that contains thiophanate-methyl and tricyclazole; show extremely strong antibiotic and bactericidal activity; be applied to agricultural plant chemoproection field; be mainly used in all kinds of diseases of control paddy rice; paddy rice is had protection and therapeutic action, and this microbicide compositions is different from existing other microbicide compositions.
Background technology
Tricyclazole is a kind of agricultural production bactericide commonly used, suppress spore germination and adhere to spore to form, stop germ to be invaded and reduce the rice blast spore to produce, thus antibacterial, sterilization, but along with using in the agricultural production continuously for many years, resistance is also in continuous growth, effect is reducing, and dosage needs constantly to increase, and agriculture production cost constantly increases, controlling object is more single simultaneously, and is effective to rice blast.
Thiophanate-methyl is wide spectrum, interior absorption benzimidazole germicide, disturbs the formation of spindle in the bacterium mitosis, and then influences cell division, can be used for preventing and treating rice disease, and certain production-increasing function is arranged, but control efficiency is not obvious, and dosage is bigger.
Summary of the invention
The objective of the invention is at above-mentioned weak point, a kind of microbicide compositions that contains thiophanate-methyl and tricyclazole is provided, thiophanate-methyl and tricyclazole are composite, has obvious synergistic effect, raising is to the rice disease preventive effect, because two active ingredient bactericidal action mechanism are different, and no cross resistance, but delaying drug resistance development, enlarged the fungicidal spectrum of tricyclazole simultaneously, to rice sheath blight disease, rice diseases such as rice blast are all effective, and preventive effect is good, can prevent and treat, be better than thiophanate-methyl, two medicament lists of tricyclazole usefulness is used before the paddy rice fringe, and volume increase obviously, reduce dosage simultaneously, reduce farming originally.
A kind of microbicide compositions that contains thiophanate-methyl and tricyclazole takes following scheme to realize: a kind of microbicide compositions that contains thiophanate-methyl and tricyclazole is made up of two kinds of active ingredient thiophanate-methyls and tricyclazole, and composition fungicide prepares each accounting example of raw materials by weight and is: thiophanate-methyl 20～50%, tricyclazole 10～45%, additive 5～70%.
Additive comprises dispersant, wetting agent, antifreeze, thickener, defoamer, assistant carrier.The Synergistic bactericidal composition that contains tricyclazole and Tebuconazole is made wetting powder or suspending agent.
Dispersant in the additive adopts lignosulfonates, draws back a kind of or mixture in powder, NNO, polyoxyethylene triphenylethylene phosphenylic acid salt, alkylnaphthalene sulfonate, the alkylphenol polyoxyethylene; Wetting agent adopts alkylbenzenesulfonate; Antifreeze adopts a kind of or mixture in ethylene glycol, the propane diols; Thickener adopts a kind of or mixture in xanthans, the aluminium-magnesium silicate; Defoamer adopts silicone defoaming agent; Assistant carrier adopts a kind of or mixture in white carbon black, precipitated calcium carbonate, kaolin, diatomite, the water.
A kind of microbicide compositions preparation technology method that contains thiophanate-methyl and tricyclazole: microbicide compositions is made wetting powder, by said ratio weighing thiophanate-methyl, tricyclazole, additive, fully mix, after airslide disintegrating mill is pulverized, mix again, through being up to the standards, promptly obtain finished product, finished product meets the every index request of country to wetting powder; Microbicide compositions is made suspending agent, by dispersant and the assistant carrier in said ratio weighing thiophanate-methyl, tricyclazole, the additive, fully mix, after the thickness sand mill evenly grinds, mix again, add thickener and antifreeze in the additive, stir again, through being up to the standards, promptly obtain finished product, finished product meets the every index request of country to suspending agent.
A kind of microbicide compositions that contains thiophanate-methyl and tricyclazole is used in preventing and treating rice disease, to rice safety, cost is low, preventive effect good.Thiophanate-methyl and tricyclazole are composite, has obvious synergistic effect, raising is to the rice disease preventive effect, because two active ingredient bactericidal action mechanism are different, no cross resistance, but delaying drug resistance development, enlarged the fungicidal spectrum of tricyclazole simultaneously, all effective to rice diseases such as rice sheath blight disease, rice blast, prove after tested, microbicide compositions chemical property of the present invention is stable, synergy is remarkable, and rice disease is had prevention and therapeutic action, shows tangible complementation and synergistic effect, can improve paddy rice fringe grain degree of saturation, improve output.
Embodiment
Further narrate the present invention below in conjunction with embodiment.
Embodiment 1:95% thiophanate-methyl tricyclazole wettable powder
| Title | Consumption | Remarks |
| Thiophanate-methyl | 50％ | —? |
| Tricyclazole | 45％ | — |
| NNO | 2％ | Dispersant |
| Sodium lignin sulfonate | 2.5％ | Wetting agent |
| White carbon black | 0.5％ | Assistant carrier |
Take by weighing raw material by above-mentioned part by weight and be made into preparation through comminution by gas stream processing, 20～30 gram/mus about 80%, are better than single usefulness to the preventive effect of rice sheath blight disease.
95% thiophanate-methyl tricyclazole WP prevents and treats 14 days preventive effects (%) (Hefei ,Anhui) behind the rice sheath blight disease medicine
| Handle | I | II | III | IV | Average preventive effect % |
| 95%WP 30 gram/mus | 90.12 | 84.52 | 89.96 | 90.65 | 88.81 |
| 95%WP 25 gram/mus | 85.38 | 80.82 | 85.32 | 87.21 | 84.56 |
| 95%WP 20 gram/mus | 78.47 | 77.21 | 76.89 | 77.88 | 77.61 |
| 50% thiophanate-methyl, 30 gram/mus | 72.38 | 73.52 | 72.42 | 73.60 | 72.98 |
| 25% 2 ring azoles WP50 gram/mu | 58.81 | 57.93 | 56.88 | 60.12 | 58.44 |
Embodiment 2:60% thiophanate-methyl tricyclazole wettable powder
| Title | Consumption | Remarks |
| Thiophanate-methyl | 50％ | — |
| Tricyclazole | 10％ | — |
| NNO | 5％ | Dispersant |
| Draw back powder | 3％ | Dispersant |
| Sodium alkyl benzene sulfonate | 2％ | Wetting agent |
| White carbon black | 5％ | Assistant carrier |
| Diatomite | 25％ | Assistant carrier |
Take by weighing raw material by above-mentioned part by weight and be made into preparation through comminution by gas stream processing, 30～40 gram/mus more than 70%, are better than single usefulness to the preventive effect of rice sheath blight disease.
60% thiophanate-methyl tricyclazole wettable powder is prevented and treated rice sheath blight disease preventive effect (Nantong)
The agent of embodiment 3:65% thiophanate-methyl tricyclazole wettable
| Title | Consumption | Remarks |
| Thiophanate-methyl | 20％ | — |
| Tricyclazole | 45％ | — |
| NNO | 5％ | Dispersant |
| Draw back powder | 3％ | Dispersant |
| Sodium alkyl benzene sulfonate | 2％ | Wetting agent |
| Potter's clay | 20％ | Assistant carrier |
Take by weighing raw material by above-mentioned part by weight and be made into preparation through comminution by gas stream processing, 40-60 gram/mu, is compared 40-50 gram/mu preventive effects with the contrast medicament and is lower than the contrast medicament about 70% the preventive effect of rice blast, 60 gram/mu preventive effects and contrast suitable.
65% thiophanate-methyl tricyclazole wettable powder control rice blast preventive effect (Nantong)
Embodiment 4:30% thiophanate-methyl tricyclazole suspending agent
| Title | Consumption | Remarks |
| Thiophanate-methyl | 20％ | — |
| Tricyclazole | 10％ | — |
| Negel | 6％ | Dispersant |
| Glycerine | 1％ | Antifreeze |
| Xanthans | 5％ | Thickener |
| Sag622 | 1％ | Defoamer |
| Water | 57％ | Assistant carrier |
Take by weighing raw material by above-mentioned part by weight and grind processing through sand mill and be made into preparation, 80～120ml/ mu more than 70%, is better than single usefulness to the preventive effect of rice sheath blight disease.
30% thiophanate-methyl tricyclazole SC prevents and treats 7 days preventive effect tables behind sick preventive effect (Hefei ,Anhui) medicine of rice sheath blight disease
Embodiment 5:72.5% thiophanate-methyl tricyclazole wettable powder
| Title | Consumption | Remarks |
| Thiophanate-methyl | 35％ | — |
| Tricyclazole | 37.5％ | — |
| NNO | 5％ | Dispersant |
| Sodium lignin sulfonate | 4％ | Dispersant |
| Sodium alkyl benzene sulfonate | 1％ | Wetting agent |
| Kaolin | 17.5％ | Assistant carrier |
Take by weighing raw material by above-mentioned part by weight and be made into preparation through comminution by gas stream processing, 40～60 gram/mus, are better than singly with 25% tricyclazole WP, 50 gram/mus more than 80% the preventive effect of rice blast.
7 days preventive effects (%) (Jiangdu, Jiangsu) behind the sick medicine of 72.5% thiophanate-methyl tricyclazole WP control rice blast
Embodiment 6:50% thiophanate-methyl tricyclazole suspending agent
| Title | Consumption | Remarks |
| Thiophanate-methyl | 25％ | — |
| Tricyclazole | 25％ | — |
| Polyoxyethylene triphenyl phosphoric acid calcium | 6％ | Dispersant |
| Ethylene glycol | 1％ | Antifreeze |
| Aluminium-magnesium silicate | 3％ | Thickener |
| Sag622 | 0.6％ | Silicone defoaming agent |
| White carbon black | 8％ | Assistant carrier |
| Water | 31.4％ | Assistant carrier |
Take by weighing raw material by above-mentioned part by weight and grind processing through sand mill and be made into preparation, 40～60 milliliters of/mu preventive effects to rice blast are better than single usefulness more than 80%.
10 days preventive effect tables behind three medicines of the sick preventive effect (Hefei ,Anhui) of 50% thiophanate-methyl tricyclazole SC control rice blast
Embodiment 7:65% thiophanate-methyl tricyclazole suspending agent
| Title | Consumption | Remarks |
| Thiophanate-methyl | 25％ | — |
| Tricyclazole | 40％ | — |
| Negel | 6％ | Dispersant |
| Glycerine | 1％ | Antifreeze |
| Xanthans | 3％ | Thickener |
| Sag622 g | 1％ | Silicone defoaming agent |
| Kaolin | 5％ | Assistant carrier |
| Water | 20％ | Assistant carrier |
Take by weighing raw material by above-mentioned part by weight and grind processing through sand mill and be made into preparation, 60～80 gram/mus more than 70%, are better than single usefulness to the preventive effect of rice sheath blight disease.
65% thiophanate-methyl tricyclazole SC prevents and treats 10 days preventive effect tables (Jurong, Jiangsu) behind the rice sheath blight disease medicine
Embodiment 8:80% thiophanate-methyl tricyclazole wettable powder
| Title | Consumption | Remarks |
| Thiophanate-methyl | 40％ | — |
| Tricyclazole | 40％ | — |
| Alkyl naphthalene sulfonic acid calcium | 6％ | Dispersant |
| NNO | 3％ | Dispersant |
| Neopelex | 1％ | Wetting agent |
| White carbon black | 10％ | Assistant carrier |
Take by weighing raw material by above-mentioned part by weight and be made into preparation through comminution by gas stream processing, 60～80 gram/mus more than 70%, are better than single usefulness to the preventive effect of rice blast disease.
7 days preventive effect tables behind sick preventive effect (Nantong) medicine of 80% thiophanate-methyl tricyclazole WP control rice blast
Embodiment 9:60% thiophanate-methyl tricyclazole suspending agent
| Title | Consumption | Remarks |
| Thiophanate-methyl | 25％ | — |
| Tricyclazole | 35％ | — |
| Negel | 6％ | Dispersant |
| Glycerine | 1％ | Antifreeze |
| Xanthans | 3％ | Thickener |
| Sag622 | 0.6％ | Silicone defoaming agent |
| Water | 30.4％ | Assistant carrier |
Take by weighing raw material by above-mentioned part by weight and grind processing through sand mill and be made into preparation, 60～80 gram/mus more than 70%, are better than single usefulness to the preventive effect of rice sheath blight disease.
60% thiophanate-methyl tricyclazole SC prevents and treats 7 days preventive effect tables behind sick preventive effect (Jiangdu, the Jiangsu) medicine of rice sheath blight disease
Claims (3)
1, a kind of microbicide compositions that contains thiophanate-methyl and tricyclazole, it is characterized in that microbicide compositions is to be made by active ingredient thiophanate-methyl and tricyclazole combination, microbicide compositions prepares raw material weight percentage and is respectively thiophanate-methyl 20～50%, tricyclazole 10～45%, additive 5～70%.
2, according to the described a kind of microbicide compositions that contains thiophanate-methyl and tricyclazole of claim 1, it is characterized in that making wetting powder or suspending agent.
3, the described a kind of microbicide compositions that contains thiophanate-methyl and tricyclazole of claim 1 is used in preventing and treating rice disease.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100256944A CN100473279C (en) | 2007-08-14 | 2007-08-14 | Germicide composition containing thiophanate and tricyclazole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100256944A CN100473279C (en) | 2007-08-14 | 2007-08-14 | Germicide composition containing thiophanate and tricyclazole |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101103726A CN101103726A (en) | 2008-01-16 |
| CN100473279C true CN100473279C (en) | 2009-04-01 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100256944A Active CN100473279C (en) | 2007-08-14 | 2007-08-14 | Germicide composition containing thiophanate and tricyclazole |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100473279C (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009020099A1 (en) * | 2007-08-06 | 2009-02-12 | Nippon Soda Co., Ltd. | Agrochemical composition, bactericide for agricultural and horticultural use, and method for controlling plant disease |
| CN101543223A (en) * | 2009-01-09 | 2009-09-30 | 陕西韦尔奇作物保护有限公司 | Composition containing thiophonate-methyl and hexaconazole with bactericidal effect |
| CN103120170B (en) * | 2011-11-18 | 2014-07-16 | 深圳诺普信农化股份有限公司 | Bactericidal composition |
| CN103563955B (en) * | 2012-08-08 | 2015-08-19 | 陕西美邦农药有限公司 | A kind of bactericidal composition containing bromuconazole |
| CN102960338B (en) * | 2012-12-11 | 2015-05-13 | 江苏龙灯化学有限公司 | Method for preparing solid preparation |
| CN106719765A (en) * | 2016-11-28 | 2017-05-31 | 河池市金城江区科学技术情报研究所 | A kind of method for preventing and treating mulberry tree leaf blight |
| CN114790041A (en) | 2021-01-26 | 2022-07-26 | 埃科莱布美国股份有限公司 | Antifreezing dispersant and manufacturing process thereof |
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- 2007-08-14 CN CNB2007100256944A patent/CN100473279C/en active Active
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| CN101103726A (en) | 2008-01-16 |
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