CN101911940A - Germicide compounded from azoxystrobin, difenoconazole and cyproconazole and preparation method thereof - Google Patents
Germicide compounded from azoxystrobin, difenoconazole and cyproconazole and preparation method thereof Download PDFInfo
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- CN101911940A CN101911940A CN2010102753820A CN201010275382A CN101911940A CN 101911940 A CN101911940 A CN 101911940A CN 2010102753820 A CN2010102753820 A CN 2010102753820A CN 201010275382 A CN201010275382 A CN 201010275382A CN 101911940 A CN101911940 A CN 101911940A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
Abstract
The invention relates to a composite germicide, which simultaneously comprises three components, namely azoxystrobin, difenoconazole and cyproconazole. The germicide is prepared from the following active ingredients in percentage by weight: 1 to 40 percent of azoxystrobin, 1 to 30 percent of difenoconazole, 1 to 40 percent of cyproconazole, a wetting agent, a dispersant, an emulsifying agent, a thickening agent, a stabilizer, an antifreezing agent, an antifoaming agent and a solid carrier or a solvent. The composite germicide has effects and use which are obviously superior to those of germicides comprising one or two components.
Description
Technical field
What the present invention relates to is the bactericide that is mixed, especially a kind of methoxy acrylic bactericide: a Fluoxastrobin and a class triazole bactericidal agent: Cyproconazole and the composite bactericide of Difenoconazole three components belong to technical field of compounded pesticide.
Background technology
Fluoxastrobin (english common name azoxystrobin) commodity Amici by name reaches, and peace is gone out and reached, and 25%, 80% water dispersible granules is arranged, 22.9% suspending agent etc., be used for cereal crop, paddy rice, peanut, grape, fruit tree prevents and treats powdery mildew, rust, downy mildew, rice blast etc.
The commodity of Difenoconazole (english common name difenoconazole) are called Difenoconazole, oppose the pellet that withers, the generation height.Formulation products has 3% suspension seed-coating agent, 10% water dispersion granule.Be mainly used in and prevent and treat pear scab, alternaria leaf spot of apple, early blight of tomato, the climing rot of western pawl etc.
The main preparation of cyproconazole (english common name cyproconazole) has suspending agent and granule, can prevent and treat wheat powdery mildew, barley banded sclerotial blight, alternaria leaf spot of apple, pear scab etc.
Above product mainly exists with single agent on the market, and long-term single agent is used, to some resistance germ such as powdery mildew, and anthracnose, control efficiency such as scab are relatively poor, can not stop generation and the development of resistance germ effectively.Systemic fungicide has can be by the plant absorbing and the performance of conduction in vivo, thereby to invading in the plant corpus or the germ of seed embryo inside has good control efficiency, this be protective fungicide can't be obtained.Though composite dose of the mixing of two kinds of bactericide is also arranged on the market, be not clearly on the effect yet.
After the seventies, systemic fungicide begins sizable application on agricultural, but has in use also exposed the shortcoming of this class medicament, mainly be to make germ produce resistance easily, and secondly be that cost is higher.The systemic fungicide great majority are biosynthesis inhibitors, and it only plays inhibition or interference effect to a certain metabolic process of pathogen, secondly is that application point is more single, and this is the main cause that easily produces resistance.Non-internal-absorting bactericide is the mechanism of action more complicated then, and application point is many, and the dangerous low of anti-medicine taken place.For the advantage of giving full play to systemic fungicide overcomes its shortcoming, many countries have carried out a large amount of research, and have obtained progress.Simultaneously also groped some and overcome drug-fast approach, adopting protective fungicide and the composite of systemic fungicide is a kind of main development trend, and its reason mainly is the mode of action difference of two series bactericidal agents to pathogen.
Summary of the invention
Technical problem to be solved by this invention is to overcome the shortcoming that above-mentioned prior art exists, a kind of Fluoxastrobin that contains simultaneously is provided, Difenoconazole, the composite bactericide of cyproconazole three components, mainly be the principle that two series bactericidal agents are different to the mode of action of pathogen, increase the application point and inhibition pathogen influence to the metabolic pathway of medicament of medicament pathogen.More can effectively prevent and treat and be used for cereal crop, paddy rice, peanut, grape, fruit tree powdery mildew, rust, downy mildew, rice blast, early blight of tomato, the climing rot of western pawl, wheat powdery mildew, barley banded sclerotial blight, alternaria leaf spot of apple, pear scab etc.
For this reason, the present invention is by the following technical solutions: composite bactericide, it is characterized in that containing Fluoxastrobin that the active ingredient percentage by weight is 1-40% and Difenoconazole and the 1-40% cyproconazole of 1-30%, and wetting agent, dispersant, emulsifier, thickener, stabilizing agent, antifreezing agent, defoamer and solid carrier or solvent are formulated, and the percentage by weight of wherein said each component is:
Difenoconazole 1--40%
Fluoxastrobin 1---30%
Cyproconazole 1--40%
Emulsifier 1---10%
Dispersant 1----10%
Wetting agent 1---6%
Thickener 1---5%
Stabilizing agent 0.5--20%
Antifreezing agent 1----5%
Defoamer 0.1----2%
Solid carrier or solvent surplus
Further preferably the percentage by weight of Difenoconazole is 10--20%, and the percentage by weight of Fluoxastrobin is 10---30%, and the percentage by weight of cyproconazole is 5---15%; Or the percentage by weight of Difenoconazole is 12--20%, and the percentage by weight of Fluoxastrobin is 13---30%, and the percentage by weight of cyproconazole is 5---10%; Or the percentage by weight of Difenoconazole is 12--20%, and the percentage by weight of Fluoxastrobin is 10---20%, and the percentage by weight of cyproconazole is 5---8%; Or the percentage by weight of Difenoconazole is 10--12%, and the percentage by weight of Fluoxastrobin is 13---18%, and the percentage by weight of cyproconazole is 5---6%.Further more preferably the percentage by weight of Difenoconazole is 12%, and the percentage by weight of Fluoxastrobin is 20%, and the percentage by weight of cyproconazole is 8%; Or the percentage by weight of Difenoconazole is 10%, and the percentage by weight of Fluoxastrobin is 18%, and the percentage by weight of cyproconazole is 6%.Further most preferably the percentage by weight of Difenoconazole is 12%, and the percentage by weight of Fluoxastrobin is 13%, and the percentage by weight of cyproconazole is 5%; Or the percentage by weight of Difenoconazole is 12%, and the percentage by weight of Fluoxastrobin is 20%, and the percentage by weight of cyproconazole is 8%.
Described emulsifier is selected from any or multiple in alkylphenol polyoxyethylene formaldehyde condensation products, farming breast 500, castor oil polyoxyethylene ether, alkylphenol-polyethenoxy polyethenoxy ether, APEO oleoyl carboxylic ester, alkyl phenol formaldehyde resin polyoxyethylene ether, Span60, polyoxyethylene sorbitan stearate, the triphen ethyl phenol polyoxyethylene polyoxypropylene block polymer.
Described wetting agent is selected from any or multiple in lauryl sodium sulfate, neopelex, alkylnaphthalene sulfonate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy base ether phosphate, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, the alkylphenol polyoxyethylene formaldehyde condensation products succinate sodium sulfonate.
Described dispersant is selected from any or multiple in dispersing agent MF, alkyl naphthalene formaldehyde condensate sulfonates, polycarboxylate, calcium lignosulfonate, the sodium lignin sulfonate.
Described thickener is selected from any or multiple in carboxymethyl cellulose, xanthans, white carbon, polyvinyl alcohol, bentonite, the aluminium-magnesium silicate.
Described stabilizing agent selects any or multiple in order Sodium Benzoate, sodium sorbate, formaldehyde, epoxidized soybean oil, triphenyl phosphite, the epoxychloropropane.
Described antifreezing agent is selected from any any or multiple in propane diols, glycerine, ethylene glycol, urea, the mineral salt.
Described defoamer is selected from any or multiple in tributyl phosphate, dimethicone defoamer, organic silicon modified by polyether defoamer, the polyethers defoamer.
Described solid carrier or solvent are selected from any or multiple in kaolin, talcum powder, potter's clay, diatomite, bentonite, white carbon or deionized water, dimethylbenzene, toluene, methyl alcohol, ethanol, ring ethyl ketone, certain herbaceous plants with big flowers alkane, the dimethyl formamide.
The preparation that described composite bactericide composition can be processed into has suspending agent, wetting powder, water dispersion granule.To be processed into suspending agent is first-selection.
The suspending agent of described composite bactericide (SC) preparation method is for being by pesticide original medicine (disperse phase), and water and organic solvent (continuous phase) and a series of auxiliary agent mix, and grinds to reach certain fineness and make.
Requirement to former medicine: be difficult for decomposing in solvent, solvability is lower, and fusing point must be more than 60 ℃
Fluoxastrobin: 116 ℃ of fusing points, solvability 6 mg/litre (20 ℃) in the water are stable to water; Difenoconazole: fusing point 78.6 ℃, solvability 15 mg/litre (25 ℃) are stable to water in the water; Cyproconazole: 106 ℃ of fusing points, solvability 140 mg/litre (25 ℃) are stable to water in the water.
More than the physicochemical property of three kinds of former medicines meet of the requirement of preparation suspending agent formulation fully to former medicine, and the composite anti-phenomenon of knot that can not produce of three components, compatibility is good.The preparation stable performance.
At first, the method with machinery or comminution by gas stream is machined to the former medicine of water-insoluble solid more than the 325-800 order, and then with other the batching as surfactant, antifreezing agent, water-soluble additive mixing preparations such as tackifier disperse, or fusion is mixed with slurry, grind 1-2 time through horizontal sand mill, adjust pH value at last, flowability, technical indicators such as wetability, after quality examination is qualified, can pack and finished product.Can be referring to accompanying drawing 1 suspending agent schematic diagram of fabrication technology.
The preparation that processes by above process is light yellow flowable thick unit for uniform suspension.Said preparation (behind sand milling) particle fineness is at the 0.5-5 micron.The using method of said preparation is the spray-on process dispenser.
The present invention has following characteristics and excellent beneficial effect:
1. said preparation environmental protection, safety, easy to use, during the dilution spraying, have good adhesivity and plate-out ability, ability to resist splash erosion is stronger.
2. composition of the present invention still shows high control activity to the germ of methoxy acrylic acid series bactericidal agents such as Fluoxastrobin generation resistance.
3. contain Fluoxastrobin simultaneously through evidence, Difenoconazole, cyproconazole three component complex preparations obviously are better than its single agent and two component complex preparations to the powdery mildew of control vegetable melon and fruit on preventive effect, obtained unexpected technique effect for composite dose that promptly contains above-mentioned three components.
4. use and not only improved preventive effect by containing the composite form of Fluoxastrobin, Difenoconazole, cyproconazole three components, and reduced and used cost, improved the availability of active ingredient.
Embodiment
One. formulation examples
Embodiment 1:40% Difenoconazole Fluoxastrobin cyproconazole suspending agent, each component and percentage by weight are as follows:
Difenoconazole 12%
Fluoxastrobin 20%
Cyproconazole 8%
Alkylphenol polyoxyethylene formaldehyde condensation products 10%
Sodium lignin sulfonate 8%
Lauryl sodium sulfate 3%
Aluminium-magnesium silicate 2%
Epoxidized soybean oil 1%
Ethylene glycol 4%
Dimethicone defoamer 0.5%
Deionized water polishing to 100%
Preparation method: with the method for machinery or comminution by gas stream, the former medicine of water-insoluble solid is machined to more than the 325-800 order, and then with above-mentioned other the batching as water-soluble additive mixing preparations such as emulsifier, antifreezing agent, tackifier, disperse, or fusion is mixed with slurry, grinds 1-2 time through horizontal sand mill, adjust pH value at last, flowability, technical indicators such as wetability, after quality examination is qualified, can pack and finished product.
Embodiment 2:34% Difenoconazole+Fluoxastrobin+cyproconazole suspending agent, each component and percentage by weight are as follows:
Difenoconazole 10%
Fluoxastrobin 18%
Cyproconazole 6%
Alkylphenol polyoxyethylene formaldehyde condensation products 10%
Sodium lignin sulfonate 8%
Lauryl sodium sulfate 3%
Aluminium-magnesium silicate 2%
Epoxidized soybean oil 1%
Ethylene glycol 4%
Dimethicone defoamer 0.5%
Deionized water polishing to 100%
Preparation method: with embodiment 1
Embodiment 3:40% Difenoconazole+Fluoxastrobin+cyproconazole wetting powder, each component and percentage by weight are as follows:
Difenoconazole 12%
Fluoxastrobin 20%
Cyproconazole 8%
Alkylphenol polyoxyethylene formaldehyde condensation products 10%
Sodium lignin sulfonate 8%
Lauryl sodium sulfate 3%
White carbon 2%
Epoxidized soybean oil 1%
Ethylene glycol 4%
Dimethicone defoamer 0.5%
Diatomite polishing to 100%
Preparation method: after the weighings by a certain percentage such as first dispersant, wetting agent, filler with Fluoxastrobin, Difenoconazole, cyproconazole and solid, shaped, just mix after behind the comminution by gas stream, with mixing, carry out sample analysis more again through other good liquid parts mixture of white carbon absorption.
Embodiment 4:40% Difenoconazole+Fluoxastrobin+cyproconazole water dispersion granule, each component and percentage by weight are as follows:
Difenoconazole 12%
Fluoxastrobin 20%
Cyproconazole 8%
Alkylphenol polyoxyethylene formaldehyde condensation products 10%
Sodium lignin sulfonate 8%
Lauryl sodium sulfate 3%
Epoxidized soybean oil 1%
Ethylene glycol 4%
Dimethicone defoamer 0.5%
Deionized water 12%
Bentonite polishing to 100%
Preparation method: after the weighings by a certain percentage such as first dispersant, wetting agent, filler with Fluoxastrobin, Difenoconazole, cyproconazole and solid, shaped, just mix after behind the comminution by gas stream, adding deionized water more evenly squirts with other liquid parts mixture and mixes, extruder grain moulding again, sample analysis is carried out in oven dry at last.
Embodiment 5:30% Difenoconazole+Fluoxastrobin+cyproconazole suspending agent, each component and percentage by weight are as follows:
Difenoconazole 12%
Fluoxastrobin 13%
Cyproconazole 5%
Alkylphenol polyoxyethylene formaldehyde condensation products 10%
Sodium lignin sulfonate 8%
Lauryl sodium sulfate 3%
Aluminium-magnesium silicate 2%
Epoxidized soybean oil 1%
Ethylene glycol 4%
Dimethicone defoamer 0.5%
Deionized water polishing to 100%
Preparation method: with embodiment 1
Two. biological Examples
1. indoor pot biologically active
The potted plant determination method of seedling is adopted in test. and trial crops is cultured to 2 leaf periods in the greenhouse. and on the crop sprayer, to carry out foliar spray by design flow and handle. inoculation in 24 hours is for the spore suspension of examination pathogen after the chemicals treatment. and postvaccinal test material is positioned in the phytotron to be cultivated. when fully falling ill, the blank of not dispenser carries out result's investigation, the disease classification is also calculated preventive effect, do regression analysis according to each drug concentration numerical value and corresponding control probability value, calculate the EC of each medicament
50Value. disease grade scale, preventive effect computational methods, EC
50Value calculating method all is total to various countries' national standards " agricultural chemicals indoor bioassay test rule " bactericide the 11st part with reference to the Chinese people: control cucurbits powdery mildew test pot-culture method.
Result of the test shows, Fluoxastrobin, Difenoconazole, the composite microbicide compositions of cyproconazole three components, to having very excellent control efficiency for the examination target, the potted plant biologically active of three component mixtures is apparently higher than composite dose of single agent and two components thereof, and obvious synergistic effect is all arranged, and result of the test sees example 1 for details.
Example 1 powdery mildew of cucumber
| Reagent agent | EC 50(mg/L) | ATI | TTI | CTC |
| 12.5% Cyproconazole SC | 0.92 | 100.00 | ||
| 25% Fluoxastrobin SC | 1.32 | 65 | 67 | 140 |
| 30% Fluoxastrobin phenylate first SC | 0.75 | 72 | 75 | 160 |
| 28% Fluoxastrobin cyproconazole SC | 0.71 | 76 | 74 | 163 |
| Formulation examples 1 (40%SC) | 0.52 | 154 | 78 | 202.3 |
| Formulation examples 4 (40%WDG) | 0.58 | 163 | 76 | 196 |
| Formulation examples 3 (40%WP) | 0.59 | 145 | 74 | 152 |
| Formulation examples 5 (30%SC) | 0.53 | 150 | 72 | 185 |
2. drug effect test of field zone result
Test is carried out under the natural conditions of field, routine according to agricultural production requires trial crops is carried out cultivation management. and the reagent agent of field plot trial is all established 3 dosage, other establishes the blank of not dispenser agent, repeating for 4 times. insecticide-applying way is a blade spraying, spraying equipment is a knapsack hand sprayer. all small plot experiments are natural occurrence, carry out result's investigation when the blank of not dispenser is fully fallen ill, the result sees example 2～4 for details.Disease classification, preventive effect computational methods are all carried out State Standard of the People's Republic of China's " pesticide field efficacy medicine test criterion ".
Result of the test shows: each chemicals treatment all has good preventive effect to grape, rose, powdery mildew of strawberry, the present invention is Fluoxastrobin, Difenoconazole, the composite microbicide compositions of cyproconazole three components, on consumption, obviously reduce, but preventive effect is significantly higher than its active component and uses separately and the composite use of two components, illustrate that the present invention's three component complex compositions have improved the activity to powdery mildew, the preventive effect height has reduced consumption.Test does not see that crop is had harmful effect.
Example 2 grape powdery mildews
Example 3 rose powdery mildews
Example 4 powdery mildew of strawberries
Claims (10)
1. composite bactericide that contains Fluoxastrobin, Difenoconazole, cyproconazole is characterized in that each component and weight percent content are as follows:
Difenoconazole 1---40% Fluoxastrobin 1---30%
Cyproconazole 1---40% emulsifier 1---10%
Dispersant 1---10% wetting agent 1---6%
Thickener 1---5% stabilizing agent 0.5---20%
Antifreezing agent 1---5% defoamer 0.1---2%
Solid carrier or solvent surplus;
Further preferably the percentage by weight of Difenoconazole is 10--20%, and the percentage by weight of Fluoxastrobin is 10---30%, and the percentage by weight of cyproconazole is 5---15%; Or the percentage by weight of Difenoconazole is 12--20%, and the percentage by weight of Fluoxastrobin is 13---30%, and the percentage by weight of cyproconazole is 5---10%; Or the percentage by weight of Difenoconazole is 12--20%, and the percentage by weight of Fluoxastrobin is 10---20%, and the percentage by weight of cyproconazole is 5---8%; Or the percentage by weight of Difenoconazole is 10--12%, and the percentage by weight of Fluoxastrobin is 13---18%, and the percentage by weight of cyproconazole is 5---6%;
Further more preferably the percentage by weight of Difenoconazole is 12%, and the percentage by weight of Fluoxastrobin is 20%, and the percentage by weight of cyproconazole is 8%; Or the percentage by weight of Difenoconazole is 10%, and the percentage by weight of Fluoxastrobin is 18%, and the percentage by weight of cyproconazole is 6%;
Further most preferably the percentage by weight of Difenoconazole is 12%, and the percentage by weight of Fluoxastrobin is 13%, and the percentage by weight of cyproconazole is 5%; Or the percentage by weight of Difenoconazole is 12%, and the percentage by weight of Fluoxastrobin is 20%, and the percentage by weight of cyproconazole is 8%.
2. composite bactericide according to claim 1 and 2 is characterized in that described emulsifier is selected from any or multiple in alkylphenol polyoxyethylene formaldehyde condensation products, farming breast 500, castor oil polyoxyethylene ether, alkylphenol-polyethenoxy polyethenoxy ether, APEO oleoyl carboxylic ester, alkyl phenol formaldehyde resin polyoxyethylene ether, Span60, polyoxyethylene sorbitan stearate, the triphen ethyl-phenol polyoxyethylene polyoxypropylene block polymer.
3. composite bactericide according to claim 1 and 2 is characterized in that described wetting agent is selected from any or multiple in lauryl sodium sulfate, neopelex, alkylnaphthalene sulfonate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy base ether phosphate, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, the alkylphenol polyoxyethylene formaldehyde condensation products succinate sodium sulfonate.
4. composite bactericide according to claim 1 and 2 is characterized in that described dispersant is selected from any or multiple in dispersing agent MF, alkyl naphthalene formaldehyde condensate sulfonates, polycarboxylate, calcium lignosulfonate, the sodium lignin sulfonate.
5. composite bactericide according to claim 1 and 2 is characterized in that described thickener is selected from any or multiple in carboxymethyl cellulose, xanthans, white carbon, polyvinyl alcohol, bentonite, the aluminium-magnesium silicate.
6. composite bactericide according to claim 1 and 2 is characterized in that described stabilizing agent is selected from any or multiple in Sodium Benzoate, sodium sorbate, formaldehyde, epoxidized soybean oil, triphenyl phosphite, the epoxychloropropane.
7. composite bactericide according to claim 1 and 2 is characterized in that described antifreezing agent is selected from any or multiple in propane diols, glycerine, ethylene glycol, urea, the mineral salt.
8. composite bactericide according to claim 1 and 2 is characterized in that described defoamer is selected from any or multiple in tributyl phosphate, dimethicone defoamer, organic silicon modified by polyether defoamer, the polyethers defoamer.
9. composite bactericide according to claim 1 and 2, it is characterized in that described solid carrier is any or multiple of kaolin, talcum powder, potter's clay, diatomite, bentonite, white carbon, or solvent is any or multiple in deionized water, dimethylbenzene, toluene, methyl alcohol, ethanol, ring ethyl ketone, certain herbaceous plants with big flowers alkane, the dimethyl formamide.
10. composite bactericide according to claim 1 and 2 is characterized in that described composite bactericide can be processed as suspending agent, wetting powder, water dispersion granule.
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| CN102057912A (en) * | 2010-12-19 | 2011-05-18 | 惠州市银农科技有限公司 | Water suspending agent mixed by difenoconazole and azoxystrobin and preparation method thereof |
| CN102067881A (en) * | 2011-01-12 | 2011-05-25 | 青岛农业大学 | Difenoconazole and sulfur compounded suspending agent and preparation method thereof |
| CN105766935A (en) * | 2016-04-08 | 2016-07-20 | 山东潍坊润丰化工股份有限公司 | Fungicidal composition containing azoxystrobin, difenoconazole and hexaconazole and application thereof |
| EP3162208A1 (en) * | 2015-10-29 | 2017-05-03 | Helm AG | Fungicidal composition for controlling fungal infections in the soybean plant |
| AU2016102057B4 (en) * | 2016-10-27 | 2017-06-01 | Shandong Weifang Rainbow Chemical Co., Ltd. | Water dispersible granule containing azoxystrobin and cyproconazole and preparation method thereof |
| CN110432279A (en) * | 2019-08-28 | 2019-11-12 | 安徽省农业科学院园艺研究所 | A kind of efficient strawberry red-leaf disease treatment suspending agent and preparation method thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102057912A (en) * | 2010-12-19 | 2011-05-18 | 惠州市银农科技有限公司 | Water suspending agent mixed by difenoconazole and azoxystrobin and preparation method thereof |
| CN102057912B (en) * | 2010-12-19 | 2013-04-17 | 惠州市银农科技有限公司 | Water suspending agent mixed by difenoconazole and azoxystrobin and preparation method thereof |
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| CN102067881B (en) * | 2011-01-12 | 2013-04-03 | 青岛农业大学 | Difenoconazole and sulfur compounded suspending agent and preparation method thereof |
| EP3162208A1 (en) * | 2015-10-29 | 2017-05-03 | Helm AG | Fungicidal composition for controlling fungal infections in the soybean plant |
| CN105766935A (en) * | 2016-04-08 | 2016-07-20 | 山东潍坊润丰化工股份有限公司 | Fungicidal composition containing azoxystrobin, difenoconazole and hexaconazole and application thereof |
| CN105766935B (en) * | 2016-04-08 | 2018-10-02 | 山东潍坊润丰化工股份有限公司 | A kind of bactericidal composition and its application of Fluoxastrobin, difenoconazole and hexaconazole |
| AU2016102057B4 (en) * | 2016-10-27 | 2017-06-01 | Shandong Weifang Rainbow Chemical Co., Ltd. | Water dispersible granule containing azoxystrobin and cyproconazole and preparation method thereof |
| CN107980787A (en) * | 2016-10-27 | 2018-05-04 | 山东潍坊润丰化工股份有限公司 | A kind of water dispersible granules containing Fluoxastrobin and cyproconazole and preparation method thereof |
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Application publication date: 20101215 |